Electron spin resonance trapping technique with phenyl t-butyl nitrone (PBN)have been used to study the process of electroreduction of p-toluene sulfonamide at mercury electrode. The results showed that the reaction i...Electron spin resonance trapping technique with phenyl t-butyl nitrone (PBN)have been used to study the process of electroreduction of p-toluene sulfonamide at mercury electrode. The results showed that the reaction is a free radical one. p-toluene/benzyl radicals formed yia a stage of detaching sulfonamide group have been identified by the hyperfine spectrum of the radical adducts.展开更多
The p-PYNN and its derivatives have been studied using the UHF INDO method in CASSIAN 94 procedure package. Their magnetism and stability have been discussed considering the related geometries and different substituen...The p-PYNN and its derivatives have been studied using the UHF INDO method in CASSIAN 94 procedure package. Their magnetism and stability have been discussed considering the related geometries and different substituents. The ferromagnetic transition temperature of their dimers are predicted using the spin-wave method and the relationship between the transition temperature and molecular stacking modes are revealed.展开更多
Approximate analytical bound-state solutions of the Dirac particle in the fields of attractive and repulsive Rosen–Morse （RM） potentials including the Coulomb-like tensor （CLT） potential are obtained for arbitrar...Approximate analytical bound-state solutions of the Dirac particle in the fields of attractive and repulsive Rosen–Morse （RM） potentials including the Coulomb-like tensor （CLT） potential are obtained for arbitrary spin–orbit quantum number κ. The Pekeris approximation is used to deal with the spin–orbit coupling terms κ（κ ± 1）r 2 . In the presence of exact spin and pseudospin （p-spin） symmetries, the energy eigenvalues and the corresponding normalized two-component wave functions are found by using the parametric generalization of the Nikiforov–Uvarov （NU） method. The numerical results show that the CLT interaction removes degeneracies between the spin and p-spin state doublets.展开更多
A relativistic Mie-type potential for spin-1/2 particles is studied. The Dirac Hamiltonian contains a scalar S（r） and a vector V（r） Mie-type potential in the radial coordinates, as well as a tensor potential U（r...A relativistic Mie-type potential for spin-1/2 particles is studied. The Dirac Hamiltonian contains a scalar S（r） and a vector V（r） Mie-type potential in the radial coordinates, as well as a tensor potential U（r） in the form of Coulomb potential. In the pseudospin（p-spin） symmetry setting Σ = Cps and Δ = V（r）, an analytical solution for exact bound states of the corresponding Dirac equation is found. The eigenenergies and normalized wave functions are presented and particular cases are discussed with any arbitrary spin–orbit coupling number κ. Special attention is devoted to the caseΣ = 0 for which p-spin symmetry is exact. The Laplace transform approach（LTA） is used in our calculations. Some numerical results are obtained and compared with those of other methods.展开更多
In the presence of spin and pseudospin （p-spin） symmetries, the approximate analytical bound states of the Dirac equation for scalar-vector-tensor Hulth6n potentials are obtained with any arbitrary spin-orbit coupli...In the presence of spin and pseudospin （p-spin） symmetries, the approximate analytical bound states of the Dirac equation for scalar-vector-tensor Hulth6n potentials are obtained with any arbitrary spin-orbit coupling number using the Pekeris approximation. The Hulth6n tensor interaction is studied instead of the commonly used Coulomb or linear terms. The generalized parametric Nikiforov-Uvarov （NU） method is used to obtain energy eigenvalues and corresponding wave functions in their closed forms. It is shown that tensor interaction removes degeneracy between spin and p-spin doublets. Some numerical results are also given.展开更多
文摘Electron spin resonance trapping technique with phenyl t-butyl nitrone (PBN)have been used to study the process of electroreduction of p-toluene sulfonamide at mercury electrode. The results showed that the reaction is a free radical one. p-toluene/benzyl radicals formed yia a stage of detaching sulfonamide group have been identified by the hyperfine spectrum of the radical adducts.
文摘The p-PYNN and its derivatives have been studied using the UHF INDO method in CASSIAN 94 procedure package. Their magnetism and stability have been discussed considering the related geometries and different substituents. The ferromagnetic transition temperature of their dimers are predicted using the spin-wave method and the relationship between the transition temperature and molecular stacking modes are revealed.
基金Project partially supported by the Scientific and Technological Research Council of Turkey (Grant No. TBíTAK)
文摘Approximate analytical bound-state solutions of the Dirac particle in the fields of attractive and repulsive Rosen–Morse （RM） potentials including the Coulomb-like tensor （CLT） potential are obtained for arbitrary spin–orbit quantum number κ. The Pekeris approximation is used to deal with the spin–orbit coupling terms κ（κ ± 1）r 2 . In the presence of exact spin and pseudospin （p-spin） symmetries, the energy eigenvalues and the corresponding normalized two-component wave functions are found by using the parametric generalization of the Nikiforov–Uvarov （NU） method. The numerical results show that the CLT interaction removes degeneracies between the spin and p-spin state doublets.
文摘A relativistic Mie-type potential for spin-1/2 particles is studied. The Dirac Hamiltonian contains a scalar S（r） and a vector V（r） Mie-type potential in the radial coordinates, as well as a tensor potential U（r） in the form of Coulomb potential. In the pseudospin（p-spin） symmetry setting Σ = Cps and Δ = V（r）, an analytical solution for exact bound states of the corresponding Dirac equation is found. The eigenenergies and normalized wave functions are presented and particular cases are discussed with any arbitrary spin–orbit coupling number κ. Special attention is devoted to the caseΣ = 0 for which p-spin symmetry is exact. The Laplace transform approach（LTA） is used in our calculations. Some numerical results are obtained and compared with those of other methods.
文摘In the presence of spin and pseudospin （p-spin） symmetries, the approximate analytical bound states of the Dirac equation for scalar-vector-tensor Hulth6n potentials are obtained with any arbitrary spin-orbit coupling number using the Pekeris approximation. The Hulth6n tensor interaction is studied instead of the commonly used Coulomb or linear terms. The generalized parametric Nikiforov-Uvarov （NU） method is used to obtain energy eigenvalues and corresponding wave functions in their closed forms. It is shown that tensor interaction removes degeneracy between spin and p-spin doublets. Some numerical results are also given.
