A simple and convenient copper-catalyzed direct oxyphosphorylation of enamides with P（O）-H compounds and dioxygen has been developed under mild conditions. This methodology can allow the synthesis of a series of val...A simple and convenient copper-catalyzed direct oxyphosphorylation of enamides with P（O）-H compounds and dioxygen has been developed under mild conditions. This methodology can allow the synthesis of a series of valuable β-ketophosphine oxides β-ketophosphonates in moderate to good yields with a broad substrate scope simply by using readily-available starting materials.展开更多
基金We gratefully acknowledge financial support from the National Natural Science Foundation of China （Nos. 21572217, 21402184, 21172213, and 21302109）.
文摘A simple and convenient copper-catalyzed direct oxyphosphorylation of enamides with P（O）-H compounds and dioxygen has been developed under mild conditions. This methodology can allow the synthesis of a series of valuable β-ketophosphine oxides β-ketophosphonates in moderate to good yields with a broad substrate scope simply by using readily-available starting materials.
