Based on the crystal structures of two cucurbit[6]uril/calix[n]arene-based supramolecular frameworks reported by Long and co-workers,we further investigated the interactions of cucurbit[6]uril with 4-sulfocalix[4]aren...Based on the crystal structures of two cucurbit[6]uril/calix[n]arene-based supramolecular frameworks reported by Long and co-workers,we further investigated the interactions of cucurbit[6]uril with 4-sulfocalix[4]arene and 4-sulfocalix[6]arene using ^(1)H NMR spectroscopy and isothermal titration calorimetry(ITC),respectively.Moreover,solid fluorescent materials were prepared via the adsorption of fluorescent dyes by these porous supramolecular frameworks,which exhibit a selective response to certain volatile organic compounds.展开更多
Curcurbit[n]uril(Q[n])-based supramolecular frameworks(QSFs) constructed from the outer surface interaction of Q[n]s(OSIQ) have the characteristic of simplicity,diversity and modulability.Their simplicity is reflected...Curcurbit[n]uril(Q[n])-based supramolecular frameworks(QSFs) constructed from the outer surface interaction of Q[n]s(OSIQ) have the characteristic of simplicity,diversity and modulability.Their simplicity is reflected in their simple composition and preparation methods used for QSFs.The diversity of supramolecular organic frameworks(SOFs) is reflected in the synthesis methods and structural characteristics of the as-obtained QSFs,as well as the variety of structural directing agents and basic building blocks used to prepare QSFs.The modulability is reflected by the controllable channel size in the QSFs,which can be adjusted using different sizes of Q[n]s.In this work,the first re ported cucurbituril Q[6]was selected as the basic building block and three Q[6]-based su p ramolecular frameworks were obtained from aqueous HCl solutions in the presence of [CdCl_(4)]^(2-)respectively.The OSIQs are the main driving forces for the formation of these frameworks.This study shows the diversity of the QSFs.展开更多
Morphology and dispersity are key factors for activating peroxymonosulfate(PMS).In this study,we designed a recyclable open-type NiCo_(2)O_(4) hollow microsphere via a simple hydrothermal method with the assistance of...Morphology and dispersity are key factors for activating peroxymonosulfate(PMS).In this study,we designed a recyclable open-type NiCo_(2)O_(4) hollow microsphere via a simple hydrothermal method with the assistance of an NH_(3) vesicle.The physical structure and chemical properties were characterized using techniques such as scanning electron microscope(SEM),transmission electron microscope(TEM),X-ray diffraction(XRD),N2 adsorption and X-ray photoelectron spectroscopy(XPS).The test results confirm that the inner and outer surfaces of open-type NiCo_(2)O_(4) hollow-sphere can be efficiently utilized because of the hole on the surface of the catalyst,which can minimize the diffusion resistance of the reactants and products.Under optimized conditions,the total orga nic carbon(TOC) removal efficiency of rhodamine B(RhB) can reach up to 80% in 40 min,which is almost 50% shorter than the reported values.The reactive radicals were identified and the proposed reaction mechanism was well described.Moreover,the disturbances of HCO_(3)^(-),NO_(3)^(-),Cl^(-)and H_(2) PO_(4)^(-)were further investigated.As a result,HCO_(3)-and NO_(3)-suppressed the reaction while Cl-and H_(2) PO4-had a double effect on reaction.展开更多
Since the outer surface interaction of Q[n]s (OSIQ, including self-, anion- and aromatic-induced OSIQs) was proposed in 2014, it has become the most important research area in our group to construct various Q[n]-based...Since the outer surface interaction of Q[n]s (OSIQ, including self-, anion- and aromatic-induced OSIQs) was proposed in 2014, it has become the most important research area in our group to construct various Q[n]-based supramolecular frameworks via the OSIQ strategy. Herein, we report a novel supramolecular framework constructed using cucurbit[8]uril (Q[8]) and 4-sulfocalix[6]arene (SC[6]A). This Q[8]/SC[6]A-based supramolecular framework is a product via the perfect combination of self-, anion- and aromatic-induced OSIQs. This framework has the characteristics of easy preparation and high stability with the most important feature being the sequence selective capture of specific metal cations, such as common alkali- and alkaline earth metal ions, and renewability. Thus, this framework may be used in seawater desalination, potassium ion enrichment, radioactive cesium ion pollution source treatment, Gruinard's treatment or water softening and other applications.展开更多
The mud film thickness on the outer surface of casing and its distribution laws are important factors affecting the cementation quality at casing-cement interfaces.So far,however,the distribution laws of mud film thic...The mud film thickness on the outer surface of casing and its distribution laws are important factors affecting the cementation quality at casing-cement interfaces.So far,however,the distribution laws of mud film thickness on the outer surface of casing at different inclinations and its effect on the interfacial cementing strength have never been reported in literatures.In this paper,the mud film thickness at different parts on the outer surface of simulated casing(steel pipe)was measured at the inclination of 0°,30°,60°and 86°,respectively,using the independently designed experimental device.Then,the distribution law of mud film thickness on the outer surface of casing and its effect on the interfacial cementing strength were summarized.And the following research results were obtained.First,when the inclination increases from 0°to 86°,the mud film thickness changes from uniform distribution to thin-and-thick distribution,and the area proportions of thinner and thicker mud films both increase.And especially at the inclination of 86°,the mud film thickness on the upper surface is very large,and there are large exposed areas on the left and right surfaces of the steel pipe.Second,the cementing strength at the casing-cement interface of the exposed casing is much higher than that at the interface with mud film.And with the increase of inclination,the interfacial cementing strength with mud film tends to increase.Third,with the increase of inclination,the interfacial cementing strength increases successively,which is closely related to the area proportion of the exposed steel pipe to the solid mud film on the outer surface.In conclusion,the exposed area of the simulated casing on the outer surface is a key factor affecting its interfacial cementing strength.展开更多
基金the financial support of National Natural Science Foundation of China(Nos.51663005,21761007 and21871064)Science and Technology Plan Project of Guizhou Province(Nos.20175788 and 20185781)+2 种基金the Creative Research Groups of Guizhou Provincial Education Department(No.2017028)the Innovation Program for High-level Talents of Guizhou Province(No.20165657)“Chun-Hui” Fund of Chinese Ministry of Education(No.Z2017005)。
文摘Based on the crystal structures of two cucurbit[6]uril/calix[n]arene-based supramolecular frameworks reported by Long and co-workers,we further investigated the interactions of cucurbit[6]uril with 4-sulfocalix[4]arene and 4-sulfocalix[6]arene using ^(1)H NMR spectroscopy and isothermal titration calorimetry(ITC),respectively.Moreover,solid fluorescent materials were prepared via the adsorption of fluorescent dyes by these porous supramolecular frameworks,which exhibit a selective response to certain volatile organic compounds.
基金the financial support of the National Natural Science Foundation of China(Nos.21761007,51663005 and 21871064)Science and Technology Plan Project of Guizhou Province(Nos.20175788 and 20185781)。
文摘Curcurbit[n]uril(Q[n])-based supramolecular frameworks(QSFs) constructed from the outer surface interaction of Q[n]s(OSIQ) have the characteristic of simplicity,diversity and modulability.Their simplicity is reflected in their simple composition and preparation methods used for QSFs.The diversity of supramolecular organic frameworks(SOFs) is reflected in the synthesis methods and structural characteristics of the as-obtained QSFs,as well as the variety of structural directing agents and basic building blocks used to prepare QSFs.The modulability is reflected by the controllable channel size in the QSFs,which can be adjusted using different sizes of Q[n]s.In this work,the first re ported cucurbituril Q[6]was selected as the basic building block and three Q[6]-based su p ramolecular frameworks were obtained from aqueous HCl solutions in the presence of [CdCl_(4)]^(2-)respectively.The OSIQs are the main driving forces for the formation of these frameworks.This study shows the diversity of the QSFs.
基金supported by the Hebei Natural Science Foundation (No.B2020208064)the Double Tops Joint Fund of the Yunnan Science and Technology Bureau and Yunnan University (No.2019FY003025)Shijiazhuang Science and Technology Department (No.191240263A)。
文摘Morphology and dispersity are key factors for activating peroxymonosulfate(PMS).In this study,we designed a recyclable open-type NiCo_(2)O_(4) hollow microsphere via a simple hydrothermal method with the assistance of an NH_(3) vesicle.The physical structure and chemical properties were characterized using techniques such as scanning electron microscope(SEM),transmission electron microscope(TEM),X-ray diffraction(XRD),N2 adsorption and X-ray photoelectron spectroscopy(XPS).The test results confirm that the inner and outer surfaces of open-type NiCo_(2)O_(4) hollow-sphere can be efficiently utilized because of the hole on the surface of the catalyst,which can minimize the diffusion resistance of the reactants and products.Under optimized conditions,the total orga nic carbon(TOC) removal efficiency of rhodamine B(RhB) can reach up to 80% in 40 min,which is almost 50% shorter than the reported values.The reactive radicals were identified and the proposed reaction mechanism was well described.Moreover,the disturbances of HCO_(3)^(-),NO_(3)^(-),Cl^(-)and H_(2) PO_(4)^(-)were further investigated.As a result,HCO_(3)-and NO_(3)-suppressed the reaction while Cl-and H_(2) PO4-had a double effect on reaction.
基金National Natural Science Foundation of China(Nos. 21871064, 21601090, 21761007, 51663005)Science and Technology Plan Project of Guizhou Province (Nos. 20175788 and20185781)+1 种基金Basic Research Program of Shenzhen (No. JCYJ20190812151405298)Shenzhen Peacock Plan。
文摘Since the outer surface interaction of Q[n]s (OSIQ, including self-, anion- and aromatic-induced OSIQs) was proposed in 2014, it has become the most important research area in our group to construct various Q[n]-based supramolecular frameworks via the OSIQ strategy. Herein, we report a novel supramolecular framework constructed using cucurbit[8]uril (Q[8]) and 4-sulfocalix[6]arene (SC[6]A). This Q[8]/SC[6]A-based supramolecular framework is a product via the perfect combination of self-, anion- and aromatic-induced OSIQs. This framework has the characteristics of easy preparation and high stability with the most important feature being the sequence selective capture of specific metal cations, such as common alkali- and alkaline earth metal ions, and renewability. Thus, this framework may be used in seawater desalination, potassium ion enrichment, radioactive cesium ion pollution source treatment, Gruinard's treatment or water softening and other applications.
基金Project supported by the Sub-project of National Major Science and Technology Project(No.:2017ZX05009003-003)the National Natural Science Foundation of China(No.:51774258,41572142).
文摘The mud film thickness on the outer surface of casing and its distribution laws are important factors affecting the cementation quality at casing-cement interfaces.So far,however,the distribution laws of mud film thickness on the outer surface of casing at different inclinations and its effect on the interfacial cementing strength have never been reported in literatures.In this paper,the mud film thickness at different parts on the outer surface of simulated casing(steel pipe)was measured at the inclination of 0°,30°,60°and 86°,respectively,using the independently designed experimental device.Then,the distribution law of mud film thickness on the outer surface of casing and its effect on the interfacial cementing strength were summarized.And the following research results were obtained.First,when the inclination increases from 0°to 86°,the mud film thickness changes from uniform distribution to thin-and-thick distribution,and the area proportions of thinner and thicker mud films both increase.And especially at the inclination of 86°,the mud film thickness on the upper surface is very large,and there are large exposed areas on the left and right surfaces of the steel pipe.Second,the cementing strength at the casing-cement interface of the exposed casing is much higher than that at the interface with mud film.And with the increase of inclination,the interfacial cementing strength with mud film tends to increase.Third,with the increase of inclination,the interfacial cementing strength increases successively,which is closely related to the area proportion of the exposed steel pipe to the solid mud film on the outer surface.In conclusion,the exposed area of the simulated casing on the outer surface is a key factor affecting its interfacial cementing strength.
