The difficulty in achieving high removal efficiency for contaminants in textile wastewater over a wide range of p H impedes the progress of its treatment technique greatly.Herein,a facile and sustainable strategy was ...The difficulty in achieving high removal efficiency for contaminants in textile wastewater over a wide range of p H impedes the progress of its treatment technique greatly.Herein,a facile and sustainable strategy was adopted for constructing magnetic ordered mesoporous polymers(M-OMPs)without the assistance of organic solvent and catalyst.The prepared M-OMPs were endowed with high special surface area and good superparamagnetism simultaneously,and exhibited high removal efficiency(>99%)for Methylene Blue(MB)within a short time(10 min)at a concentration of 50 mg/L.What’s more,high removal efficiency was achieved over a wide range of p H 2-12 and the adsorption capacity for MB on M-OMPs was substantially retained even after 5 adsorption-desorption cycles,further demonstrating the application potential of M-OMPs in the decontamination of textile wastewater.展开更多
Bearing unique redox nature and high oxygen storage capacity,ceria(CeO_(2))has always been a promising CO oxidation catalyst support for gold(Au)catalysts and the like.Herein,a series of Au-CeO_(2)-P(P stands for pH v...Bearing unique redox nature and high oxygen storage capacity,ceria(CeO_(2))has always been a promising CO oxidation catalyst support for gold(Au)catalysts and the like.Herein,a series of Au-CeO_(2)-P(P stands for pH value)samples was prepared by a co-precipitation method with the assistance of an alkaline environment and amino groups functionalized ordered mesoporous polymer(OMP-NH_(2)).Afterward,all samples described above were characterized that the Au-CeO_(2)-P catalysts are made of Au-Ce-O solid solution and Au nanoparticles(NPs)supported on CeO_(2).It turns out that OMP-NH_(2) is not just a simple sacrificial template for mesoporous structure,but also plays an important role as an amino source,explaining the presence of rich oxygen vacancies.Due to the concentration of oxygen vacancies in Au-Ce-O solid solution is the key factor for the oxygen mobility of CO oxidation,the catalytic results also demonstrate that the catalytic activity of Au-CeO_(2)-P catalysts is related to the concentration of their oxygen vacancies.Moreover,Au-CeO_(2)-9.6 with a highest concentration of oxygen vacancies(as high as 13.98%)in Au-CeO_(2)-P catalysts exhibits the best catalytic activity(complete conversion at 10℃).展开更多
基金the National Nature Science Foundation of China(Nos.21775113 and 21974100)the Science Fund for Creative Research Groups of NSFC(No.20921062)。
文摘The difficulty in achieving high removal efficiency for contaminants in textile wastewater over a wide range of p H impedes the progress of its treatment technique greatly.Herein,a facile and sustainable strategy was adopted for constructing magnetic ordered mesoporous polymers(M-OMPs)without the assistance of organic solvent and catalyst.The prepared M-OMPs were endowed with high special surface area and good superparamagnetism simultaneously,and exhibited high removal efficiency(>99%)for Methylene Blue(MB)within a short time(10 min)at a concentration of 50 mg/L.What’s more,high removal efficiency was achieved over a wide range of p H 2-12 and the adsorption capacity for MB on M-OMPs was substantially retained even after 5 adsorption-desorption cycles,further demonstrating the application potential of M-OMPs in the decontamination of textile wastewater.
基金Project supported by the National Natural Science Foundation of China(22002056,21663016,21961021)the Key Laboratory of Jiangxi Province for Environment and Energy Catalysis(20181BCD40004)the Research Project on Teaching Reform of Degree and Graduate Education of Jiangxi Province(JXYJG-2018-007)。
文摘Bearing unique redox nature and high oxygen storage capacity,ceria(CeO_(2))has always been a promising CO oxidation catalyst support for gold(Au)catalysts and the like.Herein,a series of Au-CeO_(2)-P(P stands for pH value)samples was prepared by a co-precipitation method with the assistance of an alkaline environment and amino groups functionalized ordered mesoporous polymer(OMP-NH_(2)).Afterward,all samples described above were characterized that the Au-CeO_(2)-P catalysts are made of Au-Ce-O solid solution and Au nanoparticles(NPs)supported on CeO_(2).It turns out that OMP-NH_(2) is not just a simple sacrificial template for mesoporous structure,but also plays an important role as an amino source,explaining the presence of rich oxygen vacancies.Due to the concentration of oxygen vacancies in Au-Ce-O solid solution is the key factor for the oxygen mobility of CO oxidation,the catalytic results also demonstrate that the catalytic activity of Au-CeO_(2)-P catalysts is related to the concentration of their oxygen vacancies.Moreover,Au-CeO_(2)-9.6 with a highest concentration of oxygen vacancies(as high as 13.98%)in Au-CeO_(2)-P catalysts exhibits the best catalytic activity(complete conversion at 10℃).
