期刊文献+
共找到8篇文章
< 1 >
每页显示 20 50 100
Theory and Realization of GPS Orbit Integration 被引量:1
1
作者 YAO Yibin 《Geo-Spatial Information Science》 2008年第1期1-5,共5页
The algorithm of using one-day-arc to integrate n-days-arc by orbit overlaying is discussed in detail. An example is given, which proves that the orbit integration method can improve the precision of the orbit efficie... The algorithm of using one-day-arc to integrate n-days-arc by orbit overlaying is discussed in detail. An example is given, which proves that the orbit integration method can improve the precision of the orbit efficiently, especially in the determination of a local area's orbit. 展开更多
关键词 orbit integration one-day-arc n-days-arc
在线阅读 下载PDF
无底物情况下来自Rhodococcus zopfii的腈水解酶中亲核进攻试剂CYS165的活性状态的探究(英文)
2
作者 张慧珠 高旭丹 梅晔 《南京大学学报(自然科学版)》 北大核心 2025年第1期129-139,共11页
腈水解酶作为一类在工业应用中具有巨大价值的绿色生物催化剂,能够高效地催化腈基化合物转化为羧酸.尽管其应用广泛,但腈水解酶的具体催化机制仍然不明确.先前的研究揭示了腈水解酶活性中心的GLU-LYS-GLU-CYS四联体在催化中起到关键作用... 腈水解酶作为一类在工业应用中具有巨大价值的绿色生物催化剂,能够高效地催化腈基化合物转化为羧酸.尽管其应用广泛,但腈水解酶的具体催化机制仍然不明确.先前的研究揭示了腈水解酶活性中心的GLU-LYS-GLU-CYS四联体在催化中起到关键作用,其中CYS残基作为亲核试剂攻击腈基,其硫醇基团的电离是反应中的一个关键步骤,然而,CYS的去质子化过程尚未被清晰揭示.研究聚焦于来自Rhodococcus zopfii(RzNIT)的腈水解酶,并研究了底物尚未进入酶活性位点时CYS165的质子化状态.通过对CYS165去质子化可能路径的详细分析,确认了在无底物状态下RzNIT中的CYS165处于中性状态.这一发现为进一步研究RzNIT的催化机制奠定了基础. 展开更多
关键词 ONIOM(the Own n-Layered Integrated Molecular orbital and Molecular Mechanics) 腈水解酶 能垒 催化机制
在线阅读 下载PDF
Analyses and Solutions of Errors on GPS/GLONASS Positioning 被引量:2
3
作者 ZHANG Yongjun WANG Zemin 《Geo-Spatial Information Science》 2002年第2期6-12,共7页
This paper focuses mainly on the major errors and their reduction approaches pertaining to combined GPS/GLONASS positioning.To determine the difference in the time reference systems,different receiver clock offsets ar... This paper focuses mainly on the major errors and their reduction approaches pertaining to combined GPS/GLONASS positioning.To determine the difference in the time reference systems,different receiver clock offsets are introduced with respect to GPS and GLONASS system time.A more desirable method for introducing a independent unknown parameter of fifth receiver,which can be canceled out when forming difference measurements,is discussed.The error of orbit integration and the error of transformation parameters are addressed in detail.Results of numerical integration are given.To deal with the influence of ionospheric delay,a method for forming dual_frequency ionospheric free carrier phase measurements is detailed. 展开更多
关键词 GPS/GLONASS difference of system time orbit integration coordinate transformation Ionospheric correction
在线阅读 下载PDF
Predicting Rate Constants for Nucleophilic Reactions of Amines with Diarylcarbenium Ions Using an ONIOM Method
4
作者 张志平 王晨 +1 位作者 傅尧 郭庆祥 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2010年第6期669-674,745,共7页
The rate constants of the nucleophilic reactions between amines and benzhydrylium ions were calculated using first-principles theoretical methods. Solvation models including PCM, CPCM, and COSMORS, as well as differen... The rate constants of the nucleophilic reactions between amines and benzhydrylium ions were calculated using first-principles theoretical methods. Solvation models including PCM, CPCM, and COSMORS, as well as different types of atomic radii including UA0, UAKS, UAHF, Bondi, and UFF, and several single-point energy calculation methods (B3LYP, B3P86, B3PW91, BHANDH, PBEPBE, BMK, M06, MP2, and ONIOM method) were examined. By comparing the correlation between experimental rate constants and the calculated values, the ONIOM(CCSD(T)/6-311++G(2df,2p):B3LYP/6-311++G(2df,2p))//B3LYP/6- 31G(d)/PCM/UFF) method was found to perform the best. This method was then employed to calculate the rate constants of the reactions between diverse amines and diarylcarbenium ions. The calculated rate constants for 65 reactions of amines with diarylcarbenium ions are in agreement with the experimental values, indicating that it is feasible to predict the rate constant of a reaction between an amine and a diarylcarbenium ion through ab initio calculation. 展开更多
关键词 AMINE Diarylcarbenium ion Nucleophilic reaction Rate constant N-layered integrated molecule orbit and molecule mechanics
在线阅读 下载PDF
Linear Gyro-Kinetic Response Function for Zonal Flows
5
作者 T.WATARI Y.HAMADA 《Plasma Science and Technology》 SCIE EI CAS CSCD 2011年第2期157-161,共5页
A linear response function for zonal flows is obtained by solving the gyro-kinetic equation. This is an extension of a previous work which adopted the method of "integrating along particle orbit" to solve the drift ... A linear response function for zonal flows is obtained by solving the gyro-kinetic equation. This is an extension of a previous work which adopted the method of "integrating along particle orbit" to solve the drift kinetic equation. The formula derived in this paper is used to calculate the dispersion relation of geodesic acoustic mode, which is then compared with that of the gyro-kinetic analytic formula. 展开更多
关键词 zonal flow geodesic acoustic mode integrating along particle orbits
在线阅读 下载PDF
On all-propulsion design of integrated orbit and attitude control for inner-formation gravity field measurement satellite 被引量:2
6
作者 JI Li LIU Kun XIANG JunHua 《Science China(Technological Sciences)》 SCIE EI CAS 2011年第12期3233-3242,共10页
The inner-formation gravity field measurement satellite (IFS) is a novel pure gravitational orbiter. It aims to measure the Earth's gravity field with unprecedented accuracy and spatial resolution by means of preci... The inner-formation gravity field measurement satellite (IFS) is a novel pure gravitational orbiter. It aims to measure the Earth's gravity field with unprecedented accuracy and spatial resolution by means of precise orbit determination (POD) and relative state measurement. One of the key factors determining the measurement level is the outer-satellite control used for keeping the inner-satellite flying in a pure gravitational orbit stably. In this paper the integrated orbit and attitude control of IFS during steady-state phase was investigated using only thrusters. A six degree-of-freedom translational and rotational dynamics model was constructed considering nonlinearity resulted from quaternion expression and coupling induced by community thrusters. A feasible quadratic optimization model was established for the integrated orbit and attitude control using con- strained nonlinear model predictive control (CNMPC) techniques. Simulation experiment demonstrated that the presented CNMPC aigorithm can achieve rapid calculation and overcome the non-convexity of partial constraints. The thruster layout is rational with low thrust consumption, and the mission requirements of IFS are fully satisfied. 展开更多
关键词 gravity field measurement satellite inner-formation integrated orbit and attitude control model predictive techniques
原文传递
Integrated precise orbit determination of Shenzhou IV unmanned spacecraft 被引量:1
7
作者 L Congmin1,2, GU Yidong3, LIN Baojun3 & GUO Jiong3 1. Center for Space Science and Applied Research, Chinese Academy of Sciences, Beijing 100080, China 2. Graduate School of the Chinese Academy of Sciences, Beijing 100039, China +1 位作者 3. General Establishment of Space Science and Application, Chinese Academy of Sciences, Beijing 100080, China Correspondence should be addressed to L Congmin 《Science China(Technological Sciences)》 SCIE EI CAS 2004年第5期518-525,共8页
Considering the characteristic orbit of Shenzhou IV spacecraft and the advantages and disadvantages of several types of domestic orbit measurements, a scheme of IPOD is determined, which uses GPS, SLR and USB observat... Considering the characteristic orbit of Shenzhou IV spacecraft and the advantages and disadvantages of several types of domestic orbit measurements, a scheme of IPOD is determined, which uses GPS, SLR and USB observation data jointly plus precise ionosphere corrections to GPS observation data. IPOD system and mathematic models of OD are introduced. The results of different joint OD are analyzed using true observation data, and show that radial accuracy is better than 2 m. 展开更多
关键词 Shenzhou IV unmanned spacecraft integrated precise orbit determination GPS SLR USB.
原文传递
The Wave Front Set Correspondence for Dual Pairs with One Member Compact
8
作者 Mark MCKEE Angela PASQUALE Tomasz PRZEBINDA 《Acta Mathematica Sinica,English Series》 SCIE CSCD 2024年第3期823-869,共47页
Let W be a real symplectic space and(G,G')an irreducible dual pair in Sp(W),in the sense of Howe,with G compact.Let G be the preimage of G in the metaplectic group Sp(W).Given an irreducible unitary representation... Let W be a real symplectic space and(G,G')an irreducible dual pair in Sp(W),in the sense of Howe,with G compact.Let G be the preimage of G in the metaplectic group Sp(W).Given an irreducible unitary representation II of G that occurs in the restriction of the Weil representation to G,let On denote its character.We prove that,for a suitable embedding T of Sp(W)in the space of tempered distributions on W,the distribution T(On)admits an asymptotic limit,and the limit is a nilpotent orbital integral.As an application,we compute the wave front set of II',the representation of G dual to II,by elementary means. 展开更多
关键词 Reductive dual pairs Howe duality Weil representation wave front set orbital integrals
原文传递
上一页 1 下一页 到第
使用帮助 返回顶部