With the increasing complexity of the current electromagnetic environment,excessive microwave radi-ation not only does harm to human health but also forms various electromagnetic interference to so-phisticated electro...With the increasing complexity of the current electromagnetic environment,excessive microwave radi-ation not only does harm to human health but also forms various electromagnetic interference to so-phisticated electronic instruments.Therefore,the design and preparation of electromagnetic absorbing composites represent an efficient approach to mitigate the current hazards of electromagnetic radiation.However,traditional electromagnetic absorbers are difficult to satisfy the demands of actual utilization in the face of new challenges,and emerging absorbents have garnered increasing attention due to their structure and performance-based advantages.In this review,several emerging composites of Mxene-based,biochar-based,chiral,and heat-resisting are discussed in detail,including their synthetic strategy,structural superiority and regulation method,and final optimization of electromagnetic absorption ca-pacity.These insights provide a comprehensive reference for the future development of new-generation electromagnetic-wave absorption composites.Moreover,the potential development directions of these emerging absorbers have been proposed as well.展开更多
Fiber-reinforced composites are an ideal material for the lightweight design of aerospace structures. Especially in recent years, with the rapid development of composite additive manufacturing technology, the design o...Fiber-reinforced composites are an ideal material for the lightweight design of aerospace structures. Especially in recent years, with the rapid development of composite additive manufacturing technology, the design optimization of variable stiffness of fiber-reinforced composite laminates has attracted widespread attention from scholars and industry. In these aerospace composite structures, numerous cutout panels and shells serve as access points for maintaining electrical, fuel, and hydraulic systems. The traditional fiber-reinforced composite laminate subtractive drilling manufacturing inevitably faces the problems of interlayer delamination, fiber fracture, and burr of the laminate. Continuous fiber additive manufacturing technology offers the potential for integrated design optimization and manufacturing with high structural performance. Considering the integration of design and manufacturability in continuous fiber additive manufacturing, the paper proposes linear and nonlinear filtering strategies based on the Normal Distribution Fiber Optimization (NDFO) material interpolation scheme to overcome the challenge of discrete fiber optimization results, which are difficult to apply directly to continuous fiber additive manufacturing. With minimizing structural compliance as the objective function, the proposed approach provides a strategy to achieve continuity of discrete fiber paths in the variable stiffness design optimization of composite laminates with regular and irregular holes. In the variable stiffness design optimization model, the number of candidate fiber laying angles in the NDFO material interpolation scheme is considered as design variable. The sensitivity information of structural compliance with respect to the number of candidate fiber laying angles is obtained using the analytical sensitivity analysis method. Based on the proposed variable stiffness design optimization method for complex perforated composite laminates, the numerical examples consider the variable stiffness design optimization of typical non-perforated and perforated composite laminates with circular, square, and irregular holes, and systematically discuss the number of candidate discrete fiber laying angles, discrete fiber continuous filtering strategies, and filter radius on structural compliance, continuity, and manufacturability. The optimized discrete fiber angles of variable stiffness laminates are converted into continuous fiber laying paths using a streamlined process for continuous fiber additive manufacturing. Meanwhile, the optimized non-perforated and perforated MBB beams after discrete fiber continuous treatment, are manufactured using continuous fiber co-extrusion additive manufacturing technology to verify the effectiveness of the variable stiffness fiber optimization framework proposed in this paper.展开更多
With the development of composite materials,their lightweight and high-strength characteristics have caused more widespread use from aerospace applications to automotive and rail transportation sectors,significantly r...With the development of composite materials,their lightweight and high-strength characteristics have caused more widespread use from aerospace applications to automotive and rail transportation sectors,significantly reducing the energy consumption during the operation of EMUs(Electric Multiple Units).This study aims to explore the application of composite materials in the lightweight design of EMU front skirts and proposes a design method based on threedimensional Hashin failure criteria and the Cheetah Optimizer(CO)to achieve maximum lightweight efficiency.The UMAT subroutine was developed based on the three-dimensional Hashin failure criteria to calculate failure parameters,which were used as design parameters in the CO.The model calculations and result extraction were implemented in MATLAB,and the Cheetah Optimizer iteratively determined the optimal laminating angle design that minimized the overall failure factor.After 100 iterations,ensuring structural integrity,the optimized design reduced the weight of the skirt panel by 60% compared to the original aluminum alloy structure,achieving significant lightweight benefits.This study provides foundational data for the lightweight design of EMUs.展开更多
The design of unmanned aerial vehicles(UAVs)revolves around the careful selection of materials that are both lightweight and robust.Carbon fiber-reinforced polymer(CFRP)emerged as an ideal option for wing construction...The design of unmanned aerial vehicles(UAVs)revolves around the careful selection of materials that are both lightweight and robust.Carbon fiber-reinforced polymer(CFRP)emerged as an ideal option for wing construction,with its mechanical qualities thoroughly investigated.In this study,we developed and optimized a conceptual UAV wing to withstand structural loads by establishing progressive composite stacking sequences,and we conducted a series of experimental characterizations on the resulting material.In the optimization phase,the objective was defined as weight reduction,while the Hashin damage criterion was established as the constraint for the optimization process.The optimization algorithm adaptively monitors regional damage criterion values,implementing necessary adjustments to facilitate the mitigation process in a cost-effective manner.Optimization of the analytical model using Simulia Abaqus~(TM)and a Python-based user-defined sub-routine resulted in a 34.7%reduction in the wing's structural weight after 45 iterative rounds.Then,the custom-developed optimization algorithm was compared with a genetic algorithm optimization.This comparison has demonstrated that,although the genetic algorithm explores numerous possibilities through hybridization,the custom-developed algorithm is more result-oriented and achieves optimization in a reduced number of steps.To validate the structural analysis,test specimens were fabricated from the wing's most critically loaded segment,utilizing the identical stacking sequence employed in the optimization studies.Rigorous mechanical testing revealed unexpectedly high compressive strength,while tensile and bending strengths fell within expected ranges.All observed failure loads remained within the established safety margins,thereby confirming the reliability of the analytical predictions.展开更多
The stiffness properties of variable stiffness(VS) composite plates can be controlled by manipulating the variation in the fiber angle, thereby significantly improving their buckling properties. Nonlinear fiber paths ...The stiffness properties of variable stiffness(VS) composite plates can be controlled by manipulating the variation in the fiber angle, thereby significantly improving their buckling properties. Nonlinear fiber paths have attracted attention in the field of composites due to their large design space. The major challenge in adopting nonlinear fiber paths is obtaining a fiber path function within the design space that is easily computable and efficiently yields the highest buckling load of a VS plate. In this investigation, an innovative nonlinear function was proposed to describe the fiber orientation by integrating a center fiber angle into the conventional linear function. The parameters of the nonlinear function can directly represent the fiber angles at a fixed position. This novel approach has promising potential for improving the optimal efficiency of fiber paths because the linear and nonlinear functions are simplified with two identical path parameters. Furthermore, a multilevel optimization method was developed by combining finite element analysis(FEA) with an adaptive radial basis function(RBF) surrogate model, and it was found that the number of FEA cases could be reduced by iteratively inheriting training points. The integration of this nonlinear function with a surrogate model is a significant advancement in the structural optimization of composites. Subsequently, the optimal linear and nonlinear fiber paths were computed to maximize the buckling load of VS plates. The FEA results show that the computational efficiency was greatly improved by the proposed nonlinear function and optimization method. The buckling resistance could be enhanced by the nonlinear fiber path, and the reinforcement mechanism was the redistribution and reduction of in-plane compressive stress.展开更多
Bifunctional oxide-zeolite-based composites(OXZEO)have emerged as promising materials for the direct conversion of syngas to olefins.However,experimental screening and optimization of reaction parameters remain resour...Bifunctional oxide-zeolite-based composites(OXZEO)have emerged as promising materials for the direct conversion of syngas to olefins.However,experimental screening and optimization of reaction parameters remain resource-intensive.To address this challenge,we implemented a three-stage framework integrating machine learning,Bayesian optimization,and experimental validation,utilizing a carefully curated dataset from the literature.Our ensemble-tree model(R^(2)>0.87)identified Zn-Zr and Cu-Mg binary mixed oxides as the most effective OXZEO systems,with their light olefin space-time yields confirmed by physically mixing with HSAPO-34 through experimental validation.Density functional theory calculations further elucidated the activity trends between Zn-Zr and Cu-Mg mixed oxides.Among 16 catalyst and reaction condition descriptors,the oxide/zeolite ratio,reaction temperature,and pressure emerged as the most significant factors.This interpretable,data-driven framework offers a versatile approach that can be applied to other catalytic processes,providing a powerful tool for experiment design and optimization in catalysis.展开更多
Inspired by natural biomimetic structures exemplified by femoral bones,the shell-infill composite design has emerged as a research focus in structural optimization.However,existing studies predominantly focus on unifo...Inspired by natural biomimetic structures exemplified by femoral bones,the shell-infill composite design has emerged as a research focus in structural optimization.However,existing studies predominantly focus on uniform-thickness shell designs and lack robust methodologies for generating high-resolution porous infill configurations.To address these challenges,a novel topology optimization framework for full-scale shell-filled composite structures is developed in this paper.First,a physics-driven,non-uniform partial differential equation(PDE)filter is developed,enabling precise control of variable-thickness shells by establishing explicit mapping relationships between shell thickness and filter radii.Second,this study addresses the convergence inefficiency of traditional full-scale topology optimization methods based on local volume constraints.It is revealed that a reduced influence radius exacerbates algorithm convergence challenges,thereby impeding the design of intricate porous structures.To overcome this bottleneck,a physics-driven stress skeleton generation method is developed.By integrating stress trajectories and rasterization processing,this method constructs an initial density field,effectively guiding material evolution and significantly enhancing convergence in porous structural optimization within the full-scale framework.Classical numerical examples demonstrate that our proposed optimization framework achieves biomimetic non-uniform shell thickness optimization and enables precise control of the shell thickness.Additionally,density preprocessing effectively eliminates intermediate density regions and void aggregation.Moreover,the generated trabecular-like infill patterns with spatially graded porosity,akin to multiscale topology optimization(MTO),provide an innovative solution for multifunctional,lightweight,complex shell-infill composite structures in aerospace and biomedical applications.展开更多
The recent development in Lucknow shows that the amount of built mass may increase significantly soon,which may affect outdoor thermal comfort.This study aims to achieve a better alternative to the geometrical configu...The recent development in Lucknow shows that the amount of built mass may increase significantly soon,which may affect outdoor thermal comfort.This study aims to achieve a better alternative to the geometrical configuration of vertical surfaces that helps improve the outdoor thermal comfort level.The study primarily deals with the exploration of built forms by altering the planar forms,heights,and orientations to arrive at a better composition of vertical surfaces.144 typologies were finally generated,which were then simulated in ENVI-met.The results show that,with the I-shaped typology it is difficult to reduce solar access,whereas in terms of ventilation,the typology performed better than L-shaped and C-shaped typologies.For this reason,the hours of solar access,as well as wind speed,should be seen together while developing the built-form typology.Urban neighborhoods can be designed with streets and open spaces oriented primarily to northeast-southwest and northwest-southeast directions which allow the open spaces to be thermally more comfortable than the rest of the orientation.This research highlights the importance of varying building heights to enhance thermal comfort.The findings provide valuable insights for composite climate cities like lucknow and can serve as a framework for future design strategies aimed at mitigating outdoor thermal discomfort.It is therefore important for planners,urban designers,and architects to design considering the minimal impact of the upcoming development on the thermal comfort level.展开更多
This paper presents a deep learning-based topology optimization method for the joint design of material layout and fiber orientation in continuous fiber-reinforced composite structure(CFRCS).The proposed method mainly...This paper presents a deep learning-based topology optimization method for the joint design of material layout and fiber orientation in continuous fiber-reinforced composite structure(CFRCS).The proposed method mainly includes three steps:(1)a ResUNet-involved generative and adversarial network(ResUNet-GAN)is developed to establish the end-to-end mapping from structural design parameters to fiber-reinforced composite optimized structure,and a fiber orientation chromatogram is presented to represent continuous fiber angles;(2)to avoid the local optimum problem,the independent continuous mapping method(ICM method)considering the improved principal stress orientation interpolated continuous fiber angle optimization(PSO-CFAO)strategy is utilized to construct CFRCS topology optimization dataset;(3)the well-trained ResUNet-GAN is deployed to design the optimal structural material distribution together with the corresponding continuous fiber orientations.Numerical simulations for benchmark structure verify that the proposed method greatly improves the design efficiency of CFRCS along with high design accuracy.Furthermore,the CFRCS topology configuration designed by ResUNet-GAN is fabricated by additive manufacturing.Compression experiments of the specimens show that both the stiffness structure and peak load of the CFRCS topology configuration designed by the proposed method have significantly enhanced.The proposed deep learning-based topology optimization method will provide great flexibility in CFRCS for engineering applications.展开更多
PM_(2.5)constitutes a complex and diversemixture that significantly impacts the environment,human health,and climate change.However,existing observation and numerical simulation techniques have limitations,such as a l...PM_(2.5)constitutes a complex and diversemixture that significantly impacts the environment,human health,and climate change.However,existing observation and numerical simulation techniques have limitations,such as a lack of data,high acquisition costs,andmultiple uncertainties.These limitations hinder the acquisition of comprehensive information on PM_(2.5)chemical composition and effectively implement refined air pollution protection and control strategies.In this study,we developed an optimal deep learning model to acquire hourly mass concentrations of key PM_(2.5)chemical components without complex chemical analysis.The model was trained using a randomly partitioned multivariate dataset arranged in chronological order,including atmospheric state indicators,which previous studies did not consider.Our results showed that the correlation coefficients of key chemical components were no less than 0.96,and the root mean square errors ranged from 0.20 to 2.11μg/m^(3)for the entire process(training and testing combined).The model accurately captured the temporal characteristics of key chemical components,outperforming typical machine-learning models,previous studies,and global reanalysis datasets(such asModern-Era Retrospective analysis for Research and Applications,Version 2(MERRA-2)and Copernicus Atmosphere Monitoring Service ReAnalysis(CAMSRA)).We also quantified the feature importance using the random forest model,which showed that PM_(2.5),PM_(1),visibility,and temperature were the most influential variables for key chemical components.In conclusion,this study presents a practical approach to accurately obtain chemical composition information that can contribute to filling missing data,improved air pollution monitoring and source identification.This approach has the potential to enhance air pollution control strategies and promote public health and environmental sustainability.展开更多
A combination of casting and laser remelting was employed to develop a high-strength and heat-resistant Al-Si-Fe alloy suitable for powder bed fusion using a laser beam(PBF-LB).By clarifying the effects of the incorpo...A combination of casting and laser remelting was employed to develop a high-strength and heat-resistant Al-Si-Fe alloy suitable for powder bed fusion using a laser beam(PBF-LB).By clarifying the effects of the incorporated elements and their contents on the microstructure and mechanical performance of Al-Si-Fe alloys,the composition was optimized as Al-11Si-2.5Fe-2Mn-1.2Ni-0.4Cr(in wt.%).The optimized alloy was subsequently validated using PBF-LB,which exhibited favorable machinability,achieving a density of 99.8%.The room-temperature tensile strength of the PBF-LB manufactured Al-Si-Fe alloy reached(512.76±3.26)MPa,with a yield strength of(337.79±2.36)MPa and an elongation of(2.98±0.07)%.The enhanced room-temperature mechanical properties could be mainly attributed to the combined effects of fine-grain strengthening,solid solution strengthening,and precipitation strengthening.At 300°C,the high-temperature tensile strength of the developed alloy reached(222.47±6.41)MPa,with a yield strength of(164.25±11.40)MPa and an elongation of(8.88±0.33)%,outperforming those of existing alloys documented in the literature.The improved high-temperature mechanical performance was primarily provided by the three-dimensional network comprising cellular heat-resistant Al17(FeMnNiCr)4Si2 andα-Al(FeMn)Si phases.展开更多
Near-space airship is a frontier and hotspot in current military research and development,and the near-space composite propeller is the key technology for its development.In order to obtain higher aerodynamic efficien...Near-space airship is a frontier and hotspot in current military research and development,and the near-space composite propeller is the key technology for its development.In order to obtain higher aerodynamic efficiency at an altitude of 22 km,a certain near-space composite propeller is designed as a long and slender aerodynamic shape with a 10 m diameter,which brings many challenges to the composite structure design.The initial design is obtained by the composite structure variable stiffness design method using based on fixed region division blending model.However,it weighs 23.142 kg,exceeding the required 20 kg.In order to meet the structural design requirements of the propeller,a variable stiffness design method using the adaptive region division blending model is proposed in this paper.Compared with the methods using the fixed region division blending model,this method optimizes region division,stacking thickness and stacking sequence in a single level,considering the coupling effect among them.Through a more refined region division,this method can provide a more optimal design for composite tapered structures.Additionally,to improve the efficiency of optimization subjected to manufacturing constraints,a hierarchical penalty function is proposed to quickly filter out the solutions that do not meet manufacturing constraints.The above methods combined with a Genetic Algorithm(GA)using specific encoding are adopted to optimize the near-space composite propeller.The optimal design of the structure weighs 18.831 kg,with all manufacturing constraints and all structural response constraints being satisfied.Compared with the initial design,the optimal design has a more refined region division,and achieves a weight reduction of 18.6%.This demonstrates that a refined region division can significantly improve the mechanical performance of the composite tapered structure.展开更多
Water-based aerosol is widely used as an effective strategy in electro-optical countermeasure on the battlefield used to the preponderance of high efficiency,low cost and eco-friendly.Unfortunately,the stability of th...Water-based aerosol is widely used as an effective strategy in electro-optical countermeasure on the battlefield used to the preponderance of high efficiency,low cost and eco-friendly.Unfortunately,the stability of the water-based aerosol is always unsatisfactory due to the rapid evaporation and sedimentation of the aerosol droplets.Great efforts have been devoted to improve the stability of water-based aerosol by using additives with different composition and proportion.However,the lack of the criterion and principle for screening the effective additives results in excessive experimental time consumption and cost.And the stabilization time of the aerosol is still only 30 min,which could not meet the requirements of the perdurable interference.Herein,to improve the stability of water-based aerosol and optimize the complex formulation efficiently,a theoretical calculation method based on thermodynamic entropy theory is proposed.All the factors that influence the shielding effect,including polyol,stabilizer,propellant,water and cosolvent,are considered within calculation.An ultra-stable water-based aerosol with long duration over 120 min is obtained with the optimal fogging agent composition,providing enough time for fighting the electro-optic weapon.Theoretical design guideline for choosing the additives with high phase transition temperature and low phase transition enthalpy is also proposed,which greatly improves the total entropy change and reduce the absolute entropy change of the aerosol cooling process,and gives rise to an enhanced stability of the water-based aerosol.The theoretical calculation methodology contributes to an abstemious time and space for sieving the water-based aerosol with desirable performance and stability,and provides the powerful guarantee to the homeland security.展开更多
Water permeability can be used as a parameter to evaluate the effects of chitosan / nano-TiO2 composite film on the preservation of fruits and vegetables. In this study, using water permeability as the objective funct...Water permeability can be used as a parameter to evaluate the effects of chitosan / nano-TiO2 composite film on the preservation of fruits and vegetables. In this study, using water permeability as the objective function, an L9 （3）3 orthogonal experiment was conducted with addition amounts of chitosan, nano-TiO2 and glycerin as three factors at three levels. According to the experimental results, when the percentages of chitosan, nano-TiO2 and glycerin in chitosan / nano-TiO2 composite film was 2%, 0.03% and 2.5%, respectively （ i. e. , there were 2.0 g of chitosan, 0.03 g of nano-TiO2 and 2.5 g of glycerin per 1130 g composite film solution）, the water permeability of chitesan / nano-TiO2 composite fdm reached the minimum. Chitosan / nano-TiO2 composite film prepared with the optimal composition was used for preservation of Jinqiu pear. The water loss rate, respiratory intensity and good fruit rate of preserved Jinqiu pear were determined, which indicated that the prepared chitosan / nano-TiO2 composite film exhibited good preservative effects.展开更多
A novel layered method was proposed to solve the problem of Web services composition.In this method,services composition problem was formally transformed into the optimal matching problem of every layer,then optimal m...A novel layered method was proposed to solve the problem of Web services composition.In this method,services composition problem was formally transformed into the optimal matching problem of every layer,then optimal matching problem was modeled based on the hypergraph theory,and solved by computing the minimal transversals of the hypergraph.Meanwhile,two optimization algorithms were designed to discard some useless states at the intermediary steps of the composition algorithm.The effectiveness of the composition method was tested by a set of experiments,in addition,an example regarding the travel services composition was also given.The experimental results show that this method not only can automatically generate composition tree whose leaf nodes correspond to services composition solutions,but also has better performance on execution time and solution quality by adopting two proposed optimization algorithms.展开更多
The goal of web service composition is to choose an optimal scheme according to Quantity of Service （QoS） which selects instances in a distributed network. The networks are clustered with some web services such as o...The goal of web service composition is to choose an optimal scheme according to Quantity of Service （QoS） which selects instances in a distributed network. The networks are clustered with some web services such as ontologies, algorithms and rule engines with similar function and interfaces. In this scheme, web services acted as candidate service construct a distributed model which can＇t obtain the global services＇ information. The model is utilized to choose instances according to local QoS information in the progress of service composition. Some QoS matrixes are used to record and compare the instance paths and then choose a better one. Simulation result has proven that our ~pproach has a tradeoff between efficiency and ~quality.展开更多
Multiple value structure of religious cultural landscape resources influences and determines development and regulation of cultural landscape resources. In the multiple value structure consisting of cultural inheritan...Multiple value structure of religious cultural landscape resources influences and determines development and regulation of cultural landscape resources. In the multiple value structure consisting of cultural inheritance, spiritual needs, industrial expansion, leisure and entertainment, development and utilization of religious cultural landscape resources should adhere to scientific classification, relatively independent policy orientation, make and implement specific countermeasures, so as to meet various requirements of the public and other relevant subjects using more refined and improved policy measures, and to realize the optimal utilization and comprehensive value of religious cultural landscapes.展开更多
In order to reduce the cost of ABs-type hydrogen storage alloys, effects of substitution of Ce for La （A side） and Fe, Mn, Al for Ni （B side） on structural and electrochemical properties of （LaCe）;（NiFeMnAl）s ...In order to reduce the cost of ABs-type hydrogen storage alloys, effects of substitution of Ce for La （A side） and Fe, Mn, Al for Ni （B side） on structural and electrochemical properties of （LaCe）;（NiFeMnAl）s alloys were studied systematically. To make component uniform and operation easy, uniform design （UD） method was introduced into the study of composition optimization of Co-free Fe-containing ABs-type alloys for the first time. X-ray diffraction （XRD） results showed that the designed alloys were of single CaCus-type structure phase. The replacement of Fe had a severe effect on electrochemical capacity, and the substitution of Fe and A1 had a synergetic action among the unit cell volume, cycling stability and high rate discharge property. Interestingly, it was found that the hydrogen storage alloys with excessively high plateau pressure showed a tilted line in Nyquist plot instead of the semicircle, and the current decayed rapidly to near zero at the beginning of the step in constant potential step （CPS）, indicating that electrochemical impedance spectra （EIS） and CPS cannot accurately measure the electrochemical kinetics process of the hydrogen storage alloys with excessively high plateau pressure.展开更多
We developed a mathematical optimization model coupling chemical compositions and high-temperature characteristics of sintering materials, targeting the best quality and lowest cost. The simplex algorithm was adopted ...We developed a mathematical optimization model coupling chemical compositions and high-temperature characteristics of sintering materials, targeting the best quality and lowest cost. The simplex algorithm was adopted to solve this model. Four kinds of imported iron ores, two kinds of Chinese iron ore concentrates, and two kinds of fluxes were selected to verify both the model and the algorithm. The results confirmed the possibility of considering both chemical compositions and high-temperature characteristics of iron ores in the optimization model. This model provides a technical roadmap to obtain a precise mathematical correlation between the lowest cost and the grade of iron in sinters based on the condition of given raw materials, which can provide a reference to adjust the grade of iron in the sintering process for enterprise.展开更多
Magnetic carbon-based composites are the most attractive candidates for electromagnetic(EM)absorption because they can terminate the propagation of surplus EM waves in space by interacting with both electric and magne...Magnetic carbon-based composites are the most attractive candidates for electromagnetic(EM)absorption because they can terminate the propagation of surplus EM waves in space by interacting with both electric and magnetic branches.Metal-organic frameworks(MOFs)have demonstrated their great potential as sacrificing precursors of magnetic metals/carbon composites,because they provide a good platform to achieve high dispersion of magnetic nanoparticles in carbon matrix.Nevertheless,the chemical composition and microstructure of these composites are always highly dependent on their precursors and cannot promise an optimal EM state favorable for EM absorption,which more or less discount the superiority of MOFs-derived strategy.It is hence of great importance to develop some accompanied methods that can regulate EM properties of MOFs-derived magnetic carbon-based composites e ectively.This review comprehensively introduces recent advancements on EM absorption enhancement in MOFs-derived magnetic carbon-based composites and some available strategies therein.In addition,some challenges and prospects are also proposed to indicate the pending issues on performance breakthrough and mechanism exploration in the related field.展开更多
基金supported by the Surface Project of Local De-velopment in Science and Technology Guided by Central Govern-ment(No.2021ZYD0041)the National Natural Science Founda-tion of China(Nos.52377026 and 52301192)+3 种基金the Natural Science Foundation of Shandong Province(No.ZR2019YQ24)the Taishan Scholars and Young Experts Program of Shandong Province(No.tsqn202103057)the Special Financial of Shandong Province(Struc-tural Design of High-efficiency Electromagnetic Wave-absorbing Composite Materials and Construction of Shandong Provincial Tal-ent Teams)the“Sanqin Scholars”Innovation Teams Project of Shaanxi Province(Clean Energy Materials and High-Performance Devices Innovation Team of Shaanxi Dongling Smelting Co.,Ltd.).
文摘With the increasing complexity of the current electromagnetic environment,excessive microwave radi-ation not only does harm to human health but also forms various electromagnetic interference to so-phisticated electronic instruments.Therefore,the design and preparation of electromagnetic absorbing composites represent an efficient approach to mitigate the current hazards of electromagnetic radiation.However,traditional electromagnetic absorbers are difficult to satisfy the demands of actual utilization in the face of new challenges,and emerging absorbents have garnered increasing attention due to their structure and performance-based advantages.In this review,several emerging composites of Mxene-based,biochar-based,chiral,and heat-resisting are discussed in detail,including their synthetic strategy,structural superiority and regulation method,and final optimization of electromagnetic absorption ca-pacity.These insights provide a comprehensive reference for the future development of new-generation electromagnetic-wave absorption composites.Moreover,the potential development directions of these emerging absorbers have been proposed as well.
基金supports for this research were provided by the National Natural Science Foundation of China(No.12272301,12002278,U1906233)the Guangdong Basic and Applied Basic Research Foundation,China(Nos.2023A1515011970,2024A1515010256)+1 种基金the Dalian City Supports Innovation and Entrepreneurship Projects for High-Level Talents,China(2021RD16)the Key R&D Project of CSCEC,China(No.CSCEC-2020-Z-4).
文摘Fiber-reinforced composites are an ideal material for the lightweight design of aerospace structures. Especially in recent years, with the rapid development of composite additive manufacturing technology, the design optimization of variable stiffness of fiber-reinforced composite laminates has attracted widespread attention from scholars and industry. In these aerospace composite structures, numerous cutout panels and shells serve as access points for maintaining electrical, fuel, and hydraulic systems. The traditional fiber-reinforced composite laminate subtractive drilling manufacturing inevitably faces the problems of interlayer delamination, fiber fracture, and burr of the laminate. Continuous fiber additive manufacturing technology offers the potential for integrated design optimization and manufacturing with high structural performance. Considering the integration of design and manufacturability in continuous fiber additive manufacturing, the paper proposes linear and nonlinear filtering strategies based on the Normal Distribution Fiber Optimization (NDFO) material interpolation scheme to overcome the challenge of discrete fiber optimization results, which are difficult to apply directly to continuous fiber additive manufacturing. With minimizing structural compliance as the objective function, the proposed approach provides a strategy to achieve continuity of discrete fiber paths in the variable stiffness design optimization of composite laminates with regular and irregular holes. In the variable stiffness design optimization model, the number of candidate fiber laying angles in the NDFO material interpolation scheme is considered as design variable. The sensitivity information of structural compliance with respect to the number of candidate fiber laying angles is obtained using the analytical sensitivity analysis method. Based on the proposed variable stiffness design optimization method for complex perforated composite laminates, the numerical examples consider the variable stiffness design optimization of typical non-perforated and perforated composite laminates with circular, square, and irregular holes, and systematically discuss the number of candidate discrete fiber laying angles, discrete fiber continuous filtering strategies, and filter radius on structural compliance, continuity, and manufacturability. The optimized discrete fiber angles of variable stiffness laminates are converted into continuous fiber laying paths using a streamlined process for continuous fiber additive manufacturing. Meanwhile, the optimized non-perforated and perforated MBB beams after discrete fiber continuous treatment, are manufactured using continuous fiber co-extrusion additive manufacturing technology to verify the effectiveness of the variable stiffness fiber optimization framework proposed in this paper.
文摘With the development of composite materials,their lightweight and high-strength characteristics have caused more widespread use from aerospace applications to automotive and rail transportation sectors,significantly reducing the energy consumption during the operation of EMUs(Electric Multiple Units).This study aims to explore the application of composite materials in the lightweight design of EMU front skirts and proposes a design method based on threedimensional Hashin failure criteria and the Cheetah Optimizer(CO)to achieve maximum lightweight efficiency.The UMAT subroutine was developed based on the three-dimensional Hashin failure criteria to calculate failure parameters,which were used as design parameters in the CO.The model calculations and result extraction were implemented in MATLAB,and the Cheetah Optimizer iteratively determined the optimal laminating angle design that minimized the overall failure factor.After 100 iterations,ensuring structural integrity,the optimized design reduced the weight of the skirt panel by 60% compared to the original aluminum alloy structure,achieving significant lightweight benefits.This study provides foundational data for the lightweight design of EMUs.
基金supported by the Istanbul Technical University Office of Scientific Research Projects(ITUBAPSIS),under grant MYL-2022-43776。
文摘The design of unmanned aerial vehicles(UAVs)revolves around the careful selection of materials that are both lightweight and robust.Carbon fiber-reinforced polymer(CFRP)emerged as an ideal option for wing construction,with its mechanical qualities thoroughly investigated.In this study,we developed and optimized a conceptual UAV wing to withstand structural loads by establishing progressive composite stacking sequences,and we conducted a series of experimental characterizations on the resulting material.In the optimization phase,the objective was defined as weight reduction,while the Hashin damage criterion was established as the constraint for the optimization process.The optimization algorithm adaptively monitors regional damage criterion values,implementing necessary adjustments to facilitate the mitigation process in a cost-effective manner.Optimization of the analytical model using Simulia Abaqus~(TM)and a Python-based user-defined sub-routine resulted in a 34.7%reduction in the wing's structural weight after 45 iterative rounds.Then,the custom-developed optimization algorithm was compared with a genetic algorithm optimization.This comparison has demonstrated that,although the genetic algorithm explores numerous possibilities through hybridization,the custom-developed algorithm is more result-oriented and achieves optimization in a reduced number of steps.To validate the structural analysis,test specimens were fabricated from the wing's most critically loaded segment,utilizing the identical stacking sequence employed in the optimization studies.Rigorous mechanical testing revealed unexpectedly high compressive strength,while tensile and bending strengths fell within expected ranges.All observed failure loads remained within the established safety margins,thereby confirming the reliability of the analytical predictions.
基金supported by the National Natural Science Foundation of China (No. 52305026)the China Postdoctoral Science Foundation (No. 2023M741941)。
文摘The stiffness properties of variable stiffness(VS) composite plates can be controlled by manipulating the variation in the fiber angle, thereby significantly improving their buckling properties. Nonlinear fiber paths have attracted attention in the field of composites due to their large design space. The major challenge in adopting nonlinear fiber paths is obtaining a fiber path function within the design space that is easily computable and efficiently yields the highest buckling load of a VS plate. In this investigation, an innovative nonlinear function was proposed to describe the fiber orientation by integrating a center fiber angle into the conventional linear function. The parameters of the nonlinear function can directly represent the fiber angles at a fixed position. This novel approach has promising potential for improving the optimal efficiency of fiber paths because the linear and nonlinear functions are simplified with two identical path parameters. Furthermore, a multilevel optimization method was developed by combining finite element analysis(FEA) with an adaptive radial basis function(RBF) surrogate model, and it was found that the number of FEA cases could be reduced by iteratively inheriting training points. The integration of this nonlinear function with a surrogate model is a significant advancement in the structural optimization of composites. Subsequently, the optimal linear and nonlinear fiber paths were computed to maximize the buckling load of VS plates. The FEA results show that the computational efficiency was greatly improved by the proposed nonlinear function and optimization method. The buckling resistance could be enhanced by the nonlinear fiber path, and the reinforcement mechanism was the redistribution and reduction of in-plane compressive stress.
基金funded by the KRICT Project (KK2512-10) of the Korea Research Institute of Chemical Technology and the Ministry of Trade, Industry and Energy (MOTIE)the Korea Institute for Advancement of Technology (KIAT) through the Virtual Engineering Platform Program (P0022334)+1 种基金supported by the Carbon Neutral Industrial Strategic Technology Development Program (RS-202300261088) funded by the Ministry of Trade, Industry & Energy (MOTIE, Korea)Further support was provided by research fund of Chungnam National University。
文摘Bifunctional oxide-zeolite-based composites(OXZEO)have emerged as promising materials for the direct conversion of syngas to olefins.However,experimental screening and optimization of reaction parameters remain resource-intensive.To address this challenge,we implemented a three-stage framework integrating machine learning,Bayesian optimization,and experimental validation,utilizing a carefully curated dataset from the literature.Our ensemble-tree model(R^(2)>0.87)identified Zn-Zr and Cu-Mg binary mixed oxides as the most effective OXZEO systems,with their light olefin space-time yields confirmed by physically mixing with HSAPO-34 through experimental validation.Density functional theory calculations further elucidated the activity trends between Zn-Zr and Cu-Mg mixed oxides.Among 16 catalyst and reaction condition descriptors,the oxide/zeolite ratio,reaction temperature,and pressure emerged as the most significant factors.This interpretable,data-driven framework offers a versatile approach that can be applied to other catalytic processes,providing a powerful tool for experiment design and optimization in catalysis.
基金supported by the Defense Industrial Technology Development Program.
文摘Inspired by natural biomimetic structures exemplified by femoral bones,the shell-infill composite design has emerged as a research focus in structural optimization.However,existing studies predominantly focus on uniform-thickness shell designs and lack robust methodologies for generating high-resolution porous infill configurations.To address these challenges,a novel topology optimization framework for full-scale shell-filled composite structures is developed in this paper.First,a physics-driven,non-uniform partial differential equation(PDE)filter is developed,enabling precise control of variable-thickness shells by establishing explicit mapping relationships between shell thickness and filter radii.Second,this study addresses the convergence inefficiency of traditional full-scale topology optimization methods based on local volume constraints.It is revealed that a reduced influence radius exacerbates algorithm convergence challenges,thereby impeding the design of intricate porous structures.To overcome this bottleneck,a physics-driven stress skeleton generation method is developed.By integrating stress trajectories and rasterization processing,this method constructs an initial density field,effectively guiding material evolution and significantly enhancing convergence in porous structural optimization within the full-scale framework.Classical numerical examples demonstrate that our proposed optimization framework achieves biomimetic non-uniform shell thickness optimization and enables precise control of the shell thickness.Additionally,density preprocessing effectively eliminates intermediate density regions and void aggregation.Moreover,the generated trabecular-like infill patterns with spatially graded porosity,akin to multiscale topology optimization(MTO),provide an innovative solution for multifunctional,lightweight,complex shell-infill composite structures in aerospace and biomedical applications.
文摘The recent development in Lucknow shows that the amount of built mass may increase significantly soon,which may affect outdoor thermal comfort.This study aims to achieve a better alternative to the geometrical configuration of vertical surfaces that helps improve the outdoor thermal comfort level.The study primarily deals with the exploration of built forms by altering the planar forms,heights,and orientations to arrive at a better composition of vertical surfaces.144 typologies were finally generated,which were then simulated in ENVI-met.The results show that,with the I-shaped typology it is difficult to reduce solar access,whereas in terms of ventilation,the typology performed better than L-shaped and C-shaped typologies.For this reason,the hours of solar access,as well as wind speed,should be seen together while developing the built-form typology.Urban neighborhoods can be designed with streets and open spaces oriented primarily to northeast-southwest and northwest-southeast directions which allow the open spaces to be thermally more comfortable than the rest of the orientation.This research highlights the importance of varying building heights to enhance thermal comfort.The findings provide valuable insights for composite climate cities like lucknow and can serve as a framework for future design strategies aimed at mitigating outdoor thermal discomfort.It is therefore important for planners,urban designers,and architects to design considering the minimal impact of the upcoming development on the thermal comfort level.
基金supported by the National Natural Science Foundation of China(Grant No.11872080)Beijing Natural Science Foundation(Grant No.3192005).
文摘This paper presents a deep learning-based topology optimization method for the joint design of material layout and fiber orientation in continuous fiber-reinforced composite structure(CFRCS).The proposed method mainly includes three steps:(1)a ResUNet-involved generative and adversarial network(ResUNet-GAN)is developed to establish the end-to-end mapping from structural design parameters to fiber-reinforced composite optimized structure,and a fiber orientation chromatogram is presented to represent continuous fiber angles;(2)to avoid the local optimum problem,the independent continuous mapping method(ICM method)considering the improved principal stress orientation interpolated continuous fiber angle optimization(PSO-CFAO)strategy is utilized to construct CFRCS topology optimization dataset;(3)the well-trained ResUNet-GAN is deployed to design the optimal structural material distribution together with the corresponding continuous fiber orientations.Numerical simulations for benchmark structure verify that the proposed method greatly improves the design efficiency of CFRCS along with high design accuracy.Furthermore,the CFRCS topology configuration designed by ResUNet-GAN is fabricated by additive manufacturing.Compression experiments of the specimens show that both the stiffness structure and peak load of the CFRCS topology configuration designed by the proposed method have significantly enhanced.The proposed deep learning-based topology optimization method will provide great flexibility in CFRCS for engineering applications.
基金supported by the National Key Research and Development Program for Young Scientists of China(No.2022YFC3704000)the National Natural Science Foundation of China(No.42275122)the National Key Scientific and Technological Infrastructure project“Earth System Science Numerical Simulator Facility”(EarthLab).
文摘PM_(2.5)constitutes a complex and diversemixture that significantly impacts the environment,human health,and climate change.However,existing observation and numerical simulation techniques have limitations,such as a lack of data,high acquisition costs,andmultiple uncertainties.These limitations hinder the acquisition of comprehensive information on PM_(2.5)chemical composition and effectively implement refined air pollution protection and control strategies.In this study,we developed an optimal deep learning model to acquire hourly mass concentrations of key PM_(2.5)chemical components without complex chemical analysis.The model was trained using a randomly partitioned multivariate dataset arranged in chronological order,including atmospheric state indicators,which previous studies did not consider.Our results showed that the correlation coefficients of key chemical components were no less than 0.96,and the root mean square errors ranged from 0.20 to 2.11μg/m^(3)for the entire process(training and testing combined).The model accurately captured the temporal characteristics of key chemical components,outperforming typical machine-learning models,previous studies,and global reanalysis datasets(such asModern-Era Retrospective analysis for Research and Applications,Version 2(MERRA-2)and Copernicus Atmosphere Monitoring Service ReAnalysis(CAMSRA)).We also quantified the feature importance using the random forest model,which showed that PM_(2.5),PM_(1),visibility,and temperature were the most influential variables for key chemical components.In conclusion,this study presents a practical approach to accurately obtain chemical composition information that can contribute to filling missing data,improved air pollution monitoring and source identification.This approach has the potential to enhance air pollution control strategies and promote public health and environmental sustainability.
基金supported by the National Natural Science Foundation of China(Nos.52375393,52071299)the Science and Technology Innovation Talent Team of Shanxi Province,China(No.202304051001029)+3 种基金the Scientific and Technological Achievements Transformation Guidance Project of Shanxi Province,China(No.202204021301048)the Key R&D Program of Shanxi Province,China(Nos.2210300058MZ,202202150401020)the Hai’an&Taiyuan University of Technology Advanced Manufacturing and Intelligent Equipment Industrial Research Institute,China(No.2023HA-TYUTKFYF020)the Young Elite Scientists Sponsorship Program by CAST,China(No.2023QNRC001).
文摘A combination of casting and laser remelting was employed to develop a high-strength and heat-resistant Al-Si-Fe alloy suitable for powder bed fusion using a laser beam(PBF-LB).By clarifying the effects of the incorporated elements and their contents on the microstructure and mechanical performance of Al-Si-Fe alloys,the composition was optimized as Al-11Si-2.5Fe-2Mn-1.2Ni-0.4Cr(in wt.%).The optimized alloy was subsequently validated using PBF-LB,which exhibited favorable machinability,achieving a density of 99.8%.The room-temperature tensile strength of the PBF-LB manufactured Al-Si-Fe alloy reached(512.76±3.26)MPa,with a yield strength of(337.79±2.36)MPa and an elongation of(2.98±0.07)%.The enhanced room-temperature mechanical properties could be mainly attributed to the combined effects of fine-grain strengthening,solid solution strengthening,and precipitation strengthening.At 300°C,the high-temperature tensile strength of the developed alloy reached(222.47±6.41)MPa,with a yield strength of(164.25±11.40)MPa and an elongation of(8.88±0.33)%,outperforming those of existing alloys documented in the literature.The improved high-temperature mechanical performance was primarily provided by the three-dimensional network comprising cellular heat-resistant Al17(FeMnNiCr)4Si2 andα-Al(FeMn)Si phases.
基金This study was co-supported by stable funding from the National Key Laboratory of Aerofoil and Grille Aerodynamics,China.
文摘Near-space airship is a frontier and hotspot in current military research and development,and the near-space composite propeller is the key technology for its development.In order to obtain higher aerodynamic efficiency at an altitude of 22 km,a certain near-space composite propeller is designed as a long and slender aerodynamic shape with a 10 m diameter,which brings many challenges to the composite structure design.The initial design is obtained by the composite structure variable stiffness design method using based on fixed region division blending model.However,it weighs 23.142 kg,exceeding the required 20 kg.In order to meet the structural design requirements of the propeller,a variable stiffness design method using the adaptive region division blending model is proposed in this paper.Compared with the methods using the fixed region division blending model,this method optimizes region division,stacking thickness and stacking sequence in a single level,considering the coupling effect among them.Through a more refined region division,this method can provide a more optimal design for composite tapered structures.Additionally,to improve the efficiency of optimization subjected to manufacturing constraints,a hierarchical penalty function is proposed to quickly filter out the solutions that do not meet manufacturing constraints.The above methods combined with a Genetic Algorithm(GA)using specific encoding are adopted to optimize the near-space composite propeller.The optimal design of the structure weighs 18.831 kg,with all manufacturing constraints and all structural response constraints being satisfied.Compared with the initial design,the optimal design has a more refined region division,and achieves a weight reduction of 18.6%.This demonstrates that a refined region division can significantly improve the mechanical performance of the composite tapered structure.
基金supported by the Preparation and Characterization of Fogging Agents,Cooperative Project of China(Grant No.1900030040)Preparation and Test of Fogging Agents,Cooperative Project of China(Grant No.2200030085)。
文摘Water-based aerosol is widely used as an effective strategy in electro-optical countermeasure on the battlefield used to the preponderance of high efficiency,low cost and eco-friendly.Unfortunately,the stability of the water-based aerosol is always unsatisfactory due to the rapid evaporation and sedimentation of the aerosol droplets.Great efforts have been devoted to improve the stability of water-based aerosol by using additives with different composition and proportion.However,the lack of the criterion and principle for screening the effective additives results in excessive experimental time consumption and cost.And the stabilization time of the aerosol is still only 30 min,which could not meet the requirements of the perdurable interference.Herein,to improve the stability of water-based aerosol and optimize the complex formulation efficiently,a theoretical calculation method based on thermodynamic entropy theory is proposed.All the factors that influence the shielding effect,including polyol,stabilizer,propellant,water and cosolvent,are considered within calculation.An ultra-stable water-based aerosol with long duration over 120 min is obtained with the optimal fogging agent composition,providing enough time for fighting the electro-optic weapon.Theoretical design guideline for choosing the additives with high phase transition temperature and low phase transition enthalpy is also proposed,which greatly improves the total entropy change and reduce the absolute entropy change of the aerosol cooling process,and gives rise to an enhanced stability of the water-based aerosol.The theoretical calculation methodology contributes to an abstemious time and space for sieving the water-based aerosol with desirable performance and stability,and provides the powerful guarantee to the homeland security.
基金Supported by Science and Technology Fund of Guizhou Province[QKHJZ(2012)2179]
文摘Water permeability can be used as a parameter to evaluate the effects of chitosan / nano-TiO2 composite film on the preservation of fruits and vegetables. In this study, using water permeability as the objective function, an L9 （3）3 orthogonal experiment was conducted with addition amounts of chitosan, nano-TiO2 and glycerin as three factors at three levels. According to the experimental results, when the percentages of chitosan, nano-TiO2 and glycerin in chitosan / nano-TiO2 composite film was 2%, 0.03% and 2.5%, respectively （ i. e. , there were 2.0 g of chitosan, 0.03 g of nano-TiO2 and 2.5 g of glycerin per 1130 g composite film solution）, the water permeability of chitesan / nano-TiO2 composite fdm reached the minimum. Chitosan / nano-TiO2 composite film prepared with the optimal composition was used for preservation of Jinqiu pear. The water loss rate, respiratory intensity and good fruit rate of preserved Jinqiu pear were determined, which indicated that the prepared chitosan / nano-TiO2 composite film exhibited good preservative effects.
基金Project(2010CB328101) supported by the National Basic Research Program of ChinaProject(2009AA01Z401) supported by the National High Technology Research and Development Program of China+4 种基金Projects(60803032,90818023) supported by the National Natural Science Foundation of ChinaProjects(09510701300,09JC1414200,09DZ1120403) supported by the Shanghai Science and Technology Commission,China"Shu Guang" Project(10SG23) supported by Shanghai Municipal Education Commission and Shanghai Education Development Foundation,ChinaProject(09QA1405800) supported by Shanghai Science and Technology Commission Rising-Star Program,ChinaProject(NCET-10-0598) supported by Program for New Century Excellent Talents in Chinese University
文摘A novel layered method was proposed to solve the problem of Web services composition.In this method,services composition problem was formally transformed into the optimal matching problem of every layer,then optimal matching problem was modeled based on the hypergraph theory,and solved by computing the minimal transversals of the hypergraph.Meanwhile,two optimization algorithms were designed to discard some useless states at the intermediary steps of the composition algorithm.The effectiveness of the composition method was tested by a set of experiments,in addition,an example regarding the travel services composition was also given.The experimental results show that this method not only can automatically generate composition tree whose leaf nodes correspond to services composition solutions,but also has better performance on execution time and solution quality by adopting two proposed optimization algorithms.
基金National Natural Science Foundation of China，Major National Science and Technology Projects of New Generation Broadband Wireless Mobile Communication Network，the National High Technology Research and Development Program of China (863 Program)
文摘The goal of web service composition is to choose an optimal scheme according to Quantity of Service （QoS） which selects instances in a distributed network. The networks are clustered with some web services such as ontologies, algorithms and rule engines with similar function and interfaces. In this scheme, web services acted as candidate service construct a distributed model which can＇t obtain the global services＇ information. The model is utilized to choose instances according to local QoS information in the progress of service composition. Some QoS matrixes are used to record and compare the instance paths and then choose a better one. Simulation result has proven that our ~pproach has a tradeoff between efficiency and ~quality.
基金Sponsored by Interdisciplinary Research Team of Culture,Sociology and Economics of Henan Provincial Department of Science and Technology(B20140539)
文摘Multiple value structure of religious cultural landscape resources influences and determines development and regulation of cultural landscape resources. In the multiple value structure consisting of cultural inheritance, spiritual needs, industrial expansion, leisure and entertainment, development and utilization of religious cultural landscape resources should adhere to scientific classification, relatively independent policy orientation, make and implement specific countermeasures, so as to meet various requirements of the public and other relevant subjects using more refined and improved policy measures, and to realize the optimal utilization and comprehensive value of religious cultural landscapes.
基金Project supported by the Guangdong-Ministry of Education (GD-MOE) Coordination Project of Industry Academic and Research (2008B090500274)Chengdu Key Technologies R&D Program (10GGYB897GX-023)
文摘In order to reduce the cost of ABs-type hydrogen storage alloys, effects of substitution of Ce for La （A side） and Fe, Mn, Al for Ni （B side） on structural and electrochemical properties of （LaCe）;（NiFeMnAl）s alloys were studied systematically. To make component uniform and operation easy, uniform design （UD） method was introduced into the study of composition optimization of Co-free Fe-containing ABs-type alloys for the first time. X-ray diffraction （XRD） results showed that the designed alloys were of single CaCus-type structure phase. The replacement of Fe had a severe effect on electrochemical capacity, and the substitution of Fe and A1 had a synergetic action among the unit cell volume, cycling stability and high rate discharge property. Interestingly, it was found that the hydrogen storage alloys with excessively high plateau pressure showed a tilted line in Nyquist plot instead of the semicircle, and the current decayed rapidly to near zero at the beginning of the step in constant potential step （CPS）, indicating that electrochemical impedance spectra （EIS） and CPS cannot accurately measure the electrochemical kinetics process of the hydrogen storage alloys with excessively high plateau pressure.
基金financially supported by the National Natural Science Foundation of China and Baosteel Group Co., Ltd., of Shanghai (U1260202)the Postdoctoral Science Foundation of China (2012T50045)
文摘We developed a mathematical optimization model coupling chemical compositions and high-temperature characteristics of sintering materials, targeting the best quality and lowest cost. The simplex algorithm was adopted to solve this model. Four kinds of imported iron ores, two kinds of Chinese iron ore concentrates, and two kinds of fluxes were selected to verify both the model and the algorithm. The results confirmed the possibility of considering both chemical compositions and high-temperature characteristics of iron ores in the optimization model. This model provides a technical roadmap to obtain a precise mathematical correlation between the lowest cost and the grade of iron in sinters based on the condition of given raw materials, which can provide a reference to adjust the grade of iron in the sintering process for enterprise.
基金supported by the financial support from Natural Science Foundation of China(21776053 and 21676065)。
文摘Magnetic carbon-based composites are the most attractive candidates for electromagnetic(EM)absorption because they can terminate the propagation of surplus EM waves in space by interacting with both electric and magnetic branches.Metal-organic frameworks(MOFs)have demonstrated their great potential as sacrificing precursors of magnetic metals/carbon composites,because they provide a good platform to achieve high dispersion of magnetic nanoparticles in carbon matrix.Nevertheless,the chemical composition and microstructure of these composites are always highly dependent on their precursors and cannot promise an optimal EM state favorable for EM absorption,which more or less discount the superiority of MOFs-derived strategy.It is hence of great importance to develop some accompanied methods that can regulate EM properties of MOFs-derived magnetic carbon-based composites e ectively.This review comprehensively introduces recent advancements on EM absorption enhancement in MOFs-derived magnetic carbon-based composites and some available strategies therein.In addition,some challenges and prospects are also proposed to indicate the pending issues on performance breakthrough and mechanism exploration in the related field.
