The optical effects of anion adsorption on silver sol have been studied, It was found that the anion adsorption can make the absorption peak of pure silver sol shifting to longer vevelenngth, which is attributed to th...The optical effects of anion adsorption on silver sol have been studied, It was found that the anion adsorption can make the absorption peak of pure silver sol shifting to longer vevelenngth, which is attributed to the reduction of the free electron density in the surface layer of the silver particle.展开更多
Two new ethoxycarbonylmethyl viologen induced metal halide-based hybrids,(Ae V)(BiI)(DMF)(1)and(Ae V)(CoCl)(2)(AeV=N,N?-bis(ethoxycarbonylmethyl)-4,4?-bipyridinium)have been synthesized and structurally determined by ...Two new ethoxycarbonylmethyl viologen induced metal halide-based hybrids,(Ae V)(BiI)(DMF)(1)and(Ae V)(CoCl)(2)(AeV=N,N?-bis(ethoxycarbonylmethyl)-4,4?-bipyridinium)have been synthesized and structurally determined by X-ray diffraction method.Under the direction of a new template AeV,the(BiI)tetramer constructed from four edge-sharing BiIoctahedra(for 1)and(CoCl)mono-nuclear(for 2)were obtained.Furthermore,C–H···O and C–H···X(X=I,Cl)hydrogen bonds contribute to the extension of structures from 0-D to 1-D chains.Their energy band gaps of 2.18 and 2.41 eV indicate their semiconductor properties,and the photoluminescence was detected on 1.Interestingly,2 exhibits good photocurrent response behavior.Electronic structure analysis was executed to correlate the structure/property.展开更多
Aerogel materials possess a wide variety of excellent functions,hence a striking number of applications have developed for them.In this paper,we present a historic review of the aerogel materials,showing the main conc...Aerogel materials possess a wide variety of excellent functions,hence a striking number of applications have developed for them.In this paper,we present a historic review of the aerogel materials,showing the main concepts,research methods,important scientific problems,formation mechanism,structure characteristics and essence of aerogel.More applications are evolving as the scientific and engineering community,which becomes familiar with the unusual and exceptional physical properties of aerogels.In addition,we also discuss the huge development potential and prospect of polysaccharide aerogels as the research trend in the future.展开更多
文摘The optical effects of anion adsorption on silver sol have been studied, It was found that the anion adsorption can make the absorption peak of pure silver sol shifting to longer vevelenngth, which is attributed to the reduction of the free electron density in the surface layer of the silver particle.
基金supported by the Science and Technology Funding Project of Fujian Provincial Department of Transportation(No.201337)
文摘Two new ethoxycarbonylmethyl viologen induced metal halide-based hybrids,(Ae V)(BiI)(DMF)(1)and(Ae V)(CoCl)(2)(AeV=N,N?-bis(ethoxycarbonylmethyl)-4,4?-bipyridinium)have been synthesized and structurally determined by X-ray diffraction method.Under the direction of a new template AeV,the(BiI)tetramer constructed from four edge-sharing BiIoctahedra(for 1)and(CoCl)mono-nuclear(for 2)were obtained.Furthermore,C–H···O and C–H···X(X=I,Cl)hydrogen bonds contribute to the extension of structures from 0-D to 1-D chains.Their energy band gaps of 2.18 and 2.41 eV indicate their semiconductor properties,and the photoluminescence was detected on 1.Interestingly,2 exhibits good photocurrent response behavior.Electronic structure analysis was executed to correlate the structure/property.
基金supported by the National Natural Science Foundation of China(31471704 and 31271837)Major Project of the Department of Science and Technology of Fujian Province(2013N5003)
文摘Aerogel materials possess a wide variety of excellent functions,hence a striking number of applications have developed for them.In this paper,we present a historic review of the aerogel materials,showing the main concepts,research methods,important scientific problems,formation mechanism,structure characteristics and essence of aerogel.More applications are evolving as the scientific and engineering community,which becomes familiar with the unusual and exceptional physical properties of aerogels.In addition,we also discuss the huge development potential and prospect of polysaccharide aerogels as the research trend in the future.
