In this paper,we study the eigenvalue problem of the Markov diffusion operator L^(2),and give generalized inequalities for eigenvalues of the operator L^(2)on a Markov diffusion triple.By applying these inequalities,w...In this paper,we study the eigenvalue problem of the Markov diffusion operator L^(2),and give generalized inequalities for eigenvalues of the operator L^(2)on a Markov diffusion triple.By applying these inequalities,we then get some new universal bounds for eigenvalues of a special Markov diffusion operator L^(2)on bounded domains in an Euclidean space.Moreover,our results can reveal the relationship between the(k+1)-th eigenvalue and the first k eigenvalues in a relatively straightforward manner.展开更多
With the growing demand for high-precision flow field simulations in computational science and engineering,the super-resolution reconstruction of physical fields has attracted considerable research interest.However,tr...With the growing demand for high-precision flow field simulations in computational science and engineering,the super-resolution reconstruction of physical fields has attracted considerable research interest.However,tradi-tional numerical methods often entail high computational costs,involve complex data processing,and struggle to capture fine-scale high-frequency details.To address these challenges,we propose an innovative super-resolution reconstruction framework that integrates a Fourier neural operator(FNO)with an enhanced diffusion model.The framework employs an adaptively weighted FNO to process low-resolution flow field inputs,effectively capturing global dependencies and high-frequency features.Furthermore,a residual-guided diffusion model is introduced to further improve reconstruction performance.This model uses a Markov chain for noise injection in phys-ical fields and integrates a reverse denoising procedure,efficiently solved by an adaptive time-step ordinary differential equation solver,thereby ensuring both stability and computational efficiency.Experimental results demonstrate that the proposed framework significantly outperforms existing methods in terms of accuracy and efficiency,offering a promising solution for fine-grained data reconstruction in scientific simulations.展开更多
In this article, we consider a backward problem in time of the diffusion equation with local and nonlocal operators. This inverse problem is ill-posed because the solution does not depend continuously on the measured ...In this article, we consider a backward problem in time of the diffusion equation with local and nonlocal operators. This inverse problem is ill-posed because the solution does not depend continuously on the measured data. Inspired by the classical Landweber iterative method and Fourier truncation technique, we develops a modified Landweber iterative regularization method to restore the continuous dependence of solution on the measurement data. Under the a-priori and a-posteriori choice rules for the regularized parameter, the convergence estimates for the regularization method are derived. Some results of numerical simulation are provided to verify the stability and feasibility of our method in dealing with the considered problem.展开更多
In this article,we prove the boundedness for commutators of fractional Hardy and Hardy-Littlewood-Pólya operators on grand p-adic variable Herz spaces,where the symbols of the commutators belong to Lipschitz spaces.
In this paper,we present a necessary and sufficient condition for hyponormal block Toeplitz operators T on the vector-valued weighted Bergman space with symbolsΦ(z)=G^(*)(z)+F(z),where F(z)=∑^(N)_(i)=1 A_(i)z^(i)and...In this paper,we present a necessary and sufficient condition for hyponormal block Toeplitz operators T on the vector-valued weighted Bergman space with symbolsΦ(z)=G^(*)(z)+F(z),where F(z)=∑^(N)_(i)=1 A_(i)z^(i)and G(z)=∑^(N)_(i)=1 A_(−i)z^(i),A_(i)ae culants.展开更多
The goal of this paper is to establish the boundedness of the p-adic fractional integral operator with rough kernel I_(β,Ω′)^(p)and its commutators generated by b∈Λ_(γ)(Q_(p)^(n))(0<γ<1)and the I_(β,Ω′...The goal of this paper is to establish the boundedness of the p-adic fractional integral operator with rough kernel I_(β,Ω′)^(p)and its commutators generated by b∈Λ_(γ)(Q_(p)^(n))(0<γ<1)and the I_(β,Ω′)^(p) on grand p-adic Herz spaces.展开更多
Dual-polarization(dual-pol)radar variables provide information about the quantity,type,size,and water content of hydrometeors.Assimilating these dual-pol radar variables into numerical weather prediction models can en...Dual-polarization(dual-pol)radar variables provide information about the quantity,type,size,and water content of hydrometeors.Assimilating these dual-pol radar variables into numerical weather prediction models can enhance forecast accuracy.Observation operators are essential for radar data assimilation.This study focuses on applying a realistic dual-pol radar observation operator to more accurately calculate dual-pol radar variables.Previously reported dual-pol radar observation operators tended to overestimate radar variables near 0℃ in convective precipitation and simulate unrealistic dual-pol radar variables in subfreezing regions.To address this,the improved operator(KNU dual-pol radar observation operator;K-DROP)limits the distribution of mixed-phase hydrometeors,which have both solid and liquid properties,in areas with strong updrafts and downdrafts,improving the overestimation of radar variables near the melting layer.Additionally,by applying the observed snow axis ratio during winter to K-DROP,the issue of differential reflectivity(Z_(DR))being calculated as a constant value in subfreezing regions has been improved.By incorporating the observed maximum radius of hydrometeors into K-DROP,the overestimation of reflectivity(Z_(H))in subfreezing regions,the overestimation of Z_(DR)in warm regions,and the underestimation of specific differential phase(K_(DP))in subfreezing regions and overestimation in warm regions,are improved.Compared to previous operators,the enhanced version reported in the present work produces more realistic dual-pol radar variables.展开更多
Scalable simulation leveraging real-world data plays an essential role in advancing autonomous driving,owing to its efficiency and applicability in both training and evaluating algorithms.Consequently,there has been i...Scalable simulation leveraging real-world data plays an essential role in advancing autonomous driving,owing to its efficiency and applicability in both training and evaluating algorithms.Consequently,there has been increasing attention on generating highly realistic and consistent driving videos,particularly those involving viewpoint changes guided by the control commands or trajectories of ego vehicles.However,current reconstruction approaches,such as Neural Radiance Fields and 3D Gaussian Splatting,frequently suffer from limited generalization and depend on substantial input data.Meanwhile,2D generative models,though capable of producing unknown scenes,still have room for improvement in terms of coherence and visual realism.To overcome these challenges,we introduce GenScene,a world model that synthesizes front-view driving videos conditioned on trajectories.A new temporal module is presented to improve video consistency by extracting the global context of each frame,calculating relationships of frames using these global representations,and fusing frame contexts accordingly.Moreover,we propose an innovative attention mechanism that computes relations of pixels within each frame and pixels in the corresponding window range of the initial frame.Extensive experiments show that our approach surpasses various state-of-the-art models in driving video generation,and the introduced modules contribute significantly to model performance.This work establishes a new paradigm for goal-oriented video synthesis in autonomous driving,which facilitates on-demand simulation to expedite algorithm development.展开更多
Hard carbon(HC)in sodium-ion batteries is searched by numerous investigations,which can offer the excellent performance of reversible Na^(+)insertion and extraction.The covalent heteroatom doping in HC is recently wor...Hard carbon(HC)in sodium-ion batteries is searched by numerous investigations,which can offer the excellent performance of reversible Na^(+)insertion and extraction.The covalent heteroatom doping in HC is recently worth concentrating,which can dilate the interlayer spacing of graphite to adjust the electrochemical storage performance in carbon anodes.However,the reported doping strategies of the modified HC have only resulted in limited improvement,especially unobvious effects on tuning porous structure.In this study,tannin extract and K_(2)SO_(4) are respectively utilized as carbon source and sulfur source for the fabrication of HC,in which K_(2)SO_(4) can contribute to the heteroatom doping,and the pore forming as well.The tannin-derived sulfur-doped carbon anode shows the excellent cycle stability,achieving a high reversible capacity of 520.5 mAh/g at a current density of 100 mA/g.Even after 500 cycles at a current density of 3 A/g,a high specific capacity of 236.7 mAh/g and a capacity retention rate of 92.6%can be reserved.Compared with the initial carbon,the adsorption energy of Na^(+)is multifold times higher,whereas Na^(+)diffusion energy barriers manyfold decrease.Moreover,the full battery assembled with Na_(3)V_(2)(PO_(4))_(3)/tannin-based HC demonstrates a stable cycling performance.This work can manifest the potentiality of the tannin-based electrode as anode for a high-performance sodium-ion batteries(SIBs),which could especially offer an explanation of Na^(+)storage and solid-electrolyte interface(SEI)stability to the electrochemical performance.展开更多
In this paper,we are concerned with the stability of traveling wavefronts of a Belousov-Zhabotinsky model with mixed nonlocal and degenerate diffusions.Such a system can be used to study the competition among nonlocal...In this paper,we are concerned with the stability of traveling wavefronts of a Belousov-Zhabotinsky model with mixed nonlocal and degenerate diffusions.Such a system can be used to study the competition among nonlocally diffusive species and degenerately diffusive species.We prove that the traveling wavefronts are exponentially stable,when the initial perturbation around the traveling waves decays exponentially as x→-∞,but in other locations,the initial data can be arbitrarily large.The adopted methods are the weighted energy with the comparison principle and squeezing technique.展开更多
With the rapid development of generative artificial intelligence(GenAI),the task of story visualization,which transforms natural language narratives into coherent and consistent image sequences,has attracted growing r...With the rapid development of generative artificial intelligence(GenAI),the task of story visualization,which transforms natural language narratives into coherent and consistent image sequences,has attracted growing research attention.However,existing methods still face limitations in balancing multi-frame character consistency and generation efficiency,which restricts their feasibility for large-scale practical applications.To address this issue,this study proposes a modular cloud-based distributed system built on Stable Diffusion.By separating the character generation and story generation processes,and integratingmulti-feature control techniques,a cachingmechanism,and an asynchronous task queue architecture,the system enhances generation efficiency and scalability.The experimental design includes both automated and human evaluations of character consistency,performance testing,and multinode simulation.The results show that the proposed system outperforms the baseline model StoryGen in both CLIP-I and human evaluation metrics.In terms of performance,under the experimental environment of this study,dual-node deployment reduces average waiting time by approximately 19%,while the four-node simulation further reduces it by up to 65%.Overall,this study demonstrates the advantages of cloud-distributed GenAI in maintaining character consistency and reducing generation latency,highlighting its potential value inmulti-user collaborative story visualization applications.展开更多
Injecting impure CO_(2)for enhanced gas recovery(CO_(2)-EGR)offers a dual benefit by improving natural gas extraction while enabling CO_(2)sequestration.However,the interactions between CO_(2),N_(2),and CH_(4)under re...Injecting impure CO_(2)for enhanced gas recovery(CO_(2)-EGR)offers a dual benefit by improving natural gas extraction while enabling CO_(2)sequestration.However,the interactions between CO_(2),N_(2),and CH_(4)under reservoir conditions require further investigation.This study employs Grand Canonical Monte Carlo(GCMC)and Molecular Dynamics(MD)simulations to quantify the adsorption and diffusion behaviors of CO_(2),N_(2),and CH_(4)in quartz nanopores over a pressure range of 1-24 MPa under varying water saturations and gas compositions.The results indicate that:(1)CO_(2)exhibits the broadest energy distribution and the strongest adsorption stability,occupying about 20%-30%more adsorption sites than CH_(4)or N_(2)and showing the least sensitivity to water saturation,with only a 30%reduction at 50%saturation,compared to 60%for CH_(4),giving CO_(2)a clear competitive advantage.(2)The adsorption and desorption behaviors are strongly pressure dependent,as increasing pressure reduces the adsorption layer area and shifts gas distribution from adsorption dominated to free phase.Competitive adsorption analysis reveals that while CO_(2)dominates displacement at low pressures,mixtures that contain N_(2)achieve higher CH_(4)desorption efficiency above 13 MPa by mitigating diffusion resistance.(3)A higher N_(2)fraction improves CH_(4)diffusion coefficients,thereby facilitating gas mobility and ensuring superior recovery performance under high-pressure conditions.This study advances the fundamental knowledge of microscale gas behavior in tight sandstones and supports the feasibility of impure CO_(2)injection as a practical strategy for sustainable gas production.展开更多
Letα>0 and letμbe a positive Borel measure on the interval[0,1).The Hankel matrix■with entries■induces,formally,the generalized-Hilbert operator■where f(z)■is an analytic function in D.This article is devoted...Letα>0 and letμbe a positive Borel measure on the interval[0,1).The Hankel matrix■with entries■induces,formally,the generalized-Hilbert operator■where f(z)■is an analytic function in D.This article is devoted to study the measuresμfor which Hμ,αis a bounded(resp.,compact)operator from Hp(0<p≤1)into H^(p)(1≤q<∞).We also study the analogous problem in the Hardy spaces H^(p)(1≤p≤2).Finally,we obtain the essential norm of H_(μ,α)from H^(p)(0<p≤1)into H^(p)(1≤q<∞).展开更多
With the development of technology,diffusion model-based solvers have shown significant promise in solving Combinatorial Optimization(CO)problems,particularly in tackling Non-deterministic Polynomial-time hard(NP-hard...With the development of technology,diffusion model-based solvers have shown significant promise in solving Combinatorial Optimization(CO)problems,particularly in tackling Non-deterministic Polynomial-time hard(NP-hard)problems such as the Traveling Salesman Problem(TSP).However,existing diffusion model-based solvers typically employ a fixed,uniform noise schedule(e.g.,linear or cosine annealing)across all training instances,failing to fully account for the unique characteristics of each problem instance.To address this challenge,we present GraphGuided Diffusion Solvers(GGDS),an enhanced method for improving graph-based diffusion models.GGDS leverages Graph Neural Networks(GNNs)to capture graph structural information embedded in node coordinates and adjacency matrices,dynamically adjusting the noise levels in the diffusion model.This study investigates the TSP by examining two distinct time-step noise generation strategies:cosine annealing and a Neural Network(NN)-based approach.We evaluate their performance across different problem scales,particularly after integrating graph structural information.Experimental results indicate that GGDS outperforms previous methods with average performance improvements of 18.7%,6.3%,and 88.7%on TSP-500,TSP-100,and TSP-50,respectively.Specifically,GGDS demonstrates superior performance on TSP-500 and TSP-50,while its performance on TSP-100 is either comparable to or slightly better than that of previous methods,depending on the chosen noise schedule and decoding strategy.展开更多
Prussian blue analogs(PBAs)have emerged as environmentally friendly and structurally tunable cathode materials for aqueous ammonium-ion batteries(AIBs).However,the fundamental role of crystalline H_(2)O in regulating ...Prussian blue analogs(PBAs)have emerged as environmentally friendly and structurally tunable cathode materials for aqueous ammonium-ion batteries(AIBs).However,the fundamental role of crystalline H_(2)O in regulating ammonium-ion storage and transport remains poorly understood.In this study,we present a comprehensive comparison between hydrated NH_(4)NiHCF-H_(2)O and its anhydrous counterpart NH_(4)NiHCF,revealing the critical contribution of interstitial water to electrochemical performance.Structural and spectroscopic analyses confirm that interstitial water forms robust hydrogen bonds with NH_(4)+ions,stabilizing the PBA framework and mitigating structural degradation during cycling.Electrochemical measurements show that NH_(4)NiHCF-H_(2)O delivers a significantly higher specific capacity of 61 mA h g^(−1)at 0.2 C and markedly improved rate performance compared to NH_(4)NiHCF(48 mA h g^(−1)at 0.2 C).Kinetic analysis reveals that interstitial water enhances NH_(4)+diffusion,as evidenced by higher diffusion coefficients.Furthermore,density functional theory(DFT)calculations demonstrate that crystal water acts as a hydrogen bond acceptor,preferentially interacting with NH_(4)+and reducing the migration energy barrier,thereby facilitating fast ion transport.This work provides fundamental insights into the role of crystal water in PBAs and offers a rational design strategy for improving the kinetics,structural stability of PBAs cathodes for AIBs.展开更多
Aqueous hydrogen(H_(2))gas batteries with unmatched lifespan are ideal for grid-scale energy storage,yet their deployment remains limited by the lack of low-cost,efficient,and durable hydrogen electrodes.Here,we repor...Aqueous hydrogen(H_(2))gas batteries with unmatched lifespan are ideal for grid-scale energy storage,yet their deployment remains limited by the lack of low-cost,efficient,and durable hydrogen electrodes.Here,we report a high-throughput and durable gas diffusion electrode(GDE)based on a simply preparable carbon-coated nickel(Ni@C)catalyst and the design of H_(2) diffusion channels.By optimizing the carbon layer structure,a balance between the intrinsic activity and stability of the catalyst can be achieved.This Ni@C catalyst exhibits a hydrogen oxidation reaction(HOR)activity of 44 A g^(-1) as well as remarkable hydrogen evolution reaction(HER)performance.Experimental results and theoretical calculations confirm the electronic interaction between the carbon shell and Ni.In combination with a hydrophobic design,a robust and durable Ni@C-GDE has been fabricated.This electrode achieves a low HOR polarization of only 91 mV at 30 mA cm^(-2),outperforming Pt/C-GDE(154 mV),and operates stably over 4500cycles(3200 h)for HOR/HER reversing.Enabled by this electrode,a 10 Ah Ni-H_(2) battery with an energy density of 156.3 Wh kg^(-1) and cost of 62.2$kWh^(-1) is demonstrated.This work offers a viable strategy for practical and scalable hydrogen gas batteries.展开更多
In this paper,we propose a new privacy-aware transmission scheduling algorithm for 6G ad hoc networks.This system enables end nodes to select the optimum time and scheme to transmit private data safely.In 6G dynamic h...In this paper,we propose a new privacy-aware transmission scheduling algorithm for 6G ad hoc networks.This system enables end nodes to select the optimum time and scheme to transmit private data safely.In 6G dynamic heterogeneous infrastructures,unstable links and non-uniform hardware capabilities create critical issues regarding security and privacy.Traditional protocols are often too computationally heavy to allow 6G services to achieve their expected Quality-of-Service(QoS).As the transport network is built of ad hoc nodes,there is no guarantee about their trustworthiness or behavior,and transversal functionalities are delegated to the extreme nodes.However,while security can be guaranteed in extreme-to-extreme solutions,privacy cannot,as all intermediate nodes still have to handle the data packets they are transporting.Besides,traditional schemes for private anonymous ad hoc communications are vulnerable against modern intelligent attacks based on learning models.The proposed scheme fulfills this gap.Findings show the probability of a successful intelligent attack reduces by up to 65%compared to ad hoc networks with no privacy protection strategy when used the proposed technology.While congestion probability can remain below 0.001%,as required in 6G services.展开更多
基金Supported by the Open Research Fund of Key Laboratory of Nonlinear Analysis and Applications(Central China Normal University),Ministry of Education,P.R.China(Grant No.NAA2025ORG011)Science and Technology Plan Project of Jingmen(Grant No.2024YFZD076)+3 种基金Research Team Project of Jingchu University of Technology(Grant No.TD202006)Research Project of Jingchu University of Technology(Grant Nos.HX20240049HX20240200)the Teaching Reform Research Project of Hubei Province(Grant No.2024496)。
文摘In this paper,we study the eigenvalue problem of the Markov diffusion operator L^(2),and give generalized inequalities for eigenvalues of the operator L^(2)on a Markov diffusion triple.By applying these inequalities,we then get some new universal bounds for eigenvalues of a special Markov diffusion operator L^(2)on bounded domains in an Euclidean space.Moreover,our results can reveal the relationship between the(k+1)-th eigenvalue and the first k eigenvalues in a relatively straightforward manner.
基金supported by the National Natural Science Foundation of China(Grant Nos.42005003 and 41475094)National Key R&D Program of China(Grant No.2018YFC1506704).
文摘With the growing demand for high-precision flow field simulations in computational science and engineering,the super-resolution reconstruction of physical fields has attracted considerable research interest.However,tradi-tional numerical methods often entail high computational costs,involve complex data processing,and struggle to capture fine-scale high-frequency details.To address these challenges,we propose an innovative super-resolution reconstruction framework that integrates a Fourier neural operator(FNO)with an enhanced diffusion model.The framework employs an adaptively weighted FNO to process low-resolution flow field inputs,effectively capturing global dependencies and high-frequency features.Furthermore,a residual-guided diffusion model is introduced to further improve reconstruction performance.This model uses a Markov chain for noise injection in phys-ical fields and integrates a reverse denoising procedure,efficiently solved by an adaptive time-step ordinary differential equation solver,thereby ensuring both stability and computational efficiency.Experimental results demonstrate that the proposed framework significantly outperforms existing methods in terms of accuracy and efficiency,offering a promising solution for fine-grained data reconstruction in scientific simulations.
基金supported by the NSF of Ningxia(2022AAC03234)the NSF of China(11761004),the Construction Project of First-Class Disciplines in Ningxia Higher Education(NXYLXK2017B09)the Postgraduate Innovation Project of North Minzu University(YCX23074).
文摘In this article, we consider a backward problem in time of the diffusion equation with local and nonlocal operators. This inverse problem is ill-posed because the solution does not depend continuously on the measured data. Inspired by the classical Landweber iterative method and Fourier truncation technique, we develops a modified Landweber iterative regularization method to restore the continuous dependence of solution on the measurement data. Under the a-priori and a-posteriori choice rules for the regularized parameter, the convergence estimates for the regularization method are derived. Some results of numerical simulation are provided to verify the stability and feasibility of our method in dealing with the considered problem.
基金Supported by Chizhou University High Level Talent Research Start up Fund (No.CZ2025YJRC52)。
文摘In this article,we prove the boundedness for commutators of fractional Hardy and Hardy-Littlewood-Pólya operators on grand p-adic variable Herz spaces,where the symbols of the commutators belong to Lipschitz spaces.
文摘In this paper,we present a necessary and sufficient condition for hyponormal block Toeplitz operators T on the vector-valued weighted Bergman space with symbolsΦ(z)=G^(*)(z)+F(z),where F(z)=∑^(N)_(i)=1 A_(i)z^(i)and G(z)=∑^(N)_(i)=1 A_(−i)z^(i),A_(i)ae culants.
基金Supported by Natural Science Foundation of China(12461021)。
文摘The goal of this paper is to establish the boundedness of the p-adic fractional integral operator with rough kernel I_(β,Ω′)^(p)and its commutators generated by b∈Λ_(γ)(Q_(p)^(n))(0<γ<1)and the I_(β,Ω′)^(p) on grand p-adic Herz spaces.
基金supported by the National Research Foundation(NRF)funded by the Korean government(MSIT)(Grant Nos.2022R1A2C1012361,2022R1A6A3A 13073165 and RS-2025-02242970).
文摘Dual-polarization(dual-pol)radar variables provide information about the quantity,type,size,and water content of hydrometeors.Assimilating these dual-pol radar variables into numerical weather prediction models can enhance forecast accuracy.Observation operators are essential for radar data assimilation.This study focuses on applying a realistic dual-pol radar observation operator to more accurately calculate dual-pol radar variables.Previously reported dual-pol radar observation operators tended to overestimate radar variables near 0℃ in convective precipitation and simulate unrealistic dual-pol radar variables in subfreezing regions.To address this,the improved operator(KNU dual-pol radar observation operator;K-DROP)limits the distribution of mixed-phase hydrometeors,which have both solid and liquid properties,in areas with strong updrafts and downdrafts,improving the overestimation of radar variables near the melting layer.Additionally,by applying the observed snow axis ratio during winter to K-DROP,the issue of differential reflectivity(Z_(DR))being calculated as a constant value in subfreezing regions has been improved.By incorporating the observed maximum radius of hydrometeors into K-DROP,the overestimation of reflectivity(Z_(H))in subfreezing regions,the overestimation of Z_(DR)in warm regions,and the underestimation of specific differential phase(K_(DP))in subfreezing regions and overestimation in warm regions,are improved.Compared to previous operators,the enhanced version reported in the present work produces more realistic dual-pol radar variables.
基金supported by the Cultivation Program for Major Scientific Research Projects of Harbin Institute of Technology(ZDXMPY20180109).
文摘Scalable simulation leveraging real-world data plays an essential role in advancing autonomous driving,owing to its efficiency and applicability in both training and evaluating algorithms.Consequently,there has been increasing attention on generating highly realistic and consistent driving videos,particularly those involving viewpoint changes guided by the control commands or trajectories of ego vehicles.However,current reconstruction approaches,such as Neural Radiance Fields and 3D Gaussian Splatting,frequently suffer from limited generalization and depend on substantial input data.Meanwhile,2D generative models,though capable of producing unknown scenes,still have room for improvement in terms of coherence and visual realism.To overcome these challenges,we introduce GenScene,a world model that synthesizes front-view driving videos conditioned on trajectories.A new temporal module is presented to improve video consistency by extracting the global context of each frame,calculating relationships of frames using these global representations,and fusing frame contexts accordingly.Moreover,we propose an innovative attention mechanism that computes relations of pixels within each frame and pixels in the corresponding window range of the initial frame.Extensive experiments show that our approach surpasses various state-of-the-art models in driving video generation,and the introduced modules contribute significantly to model performance.This work establishes a new paradigm for goal-oriented video synthesis in autonomous driving,which facilitates on-demand simulation to expedite algorithm development.
基金supported by National Natural Science Foundation of China(Nos.32271791,32171709 and 22475053)Hunan Provincial Natural Science Foundation of China(No.2024JJ7643)Natural Science Foundation of Shanghai(No.22ZR1404100).
文摘Hard carbon(HC)in sodium-ion batteries is searched by numerous investigations,which can offer the excellent performance of reversible Na^(+)insertion and extraction.The covalent heteroatom doping in HC is recently worth concentrating,which can dilate the interlayer spacing of graphite to adjust the electrochemical storage performance in carbon anodes.However,the reported doping strategies of the modified HC have only resulted in limited improvement,especially unobvious effects on tuning porous structure.In this study,tannin extract and K_(2)SO_(4) are respectively utilized as carbon source and sulfur source for the fabrication of HC,in which K_(2)SO_(4) can contribute to the heteroatom doping,and the pore forming as well.The tannin-derived sulfur-doped carbon anode shows the excellent cycle stability,achieving a high reversible capacity of 520.5 mAh/g at a current density of 100 mA/g.Even after 500 cycles at a current density of 3 A/g,a high specific capacity of 236.7 mAh/g and a capacity retention rate of 92.6%can be reserved.Compared with the initial carbon,the adsorption energy of Na^(+)is multifold times higher,whereas Na^(+)diffusion energy barriers manyfold decrease.Moreover,the full battery assembled with Na_(3)V_(2)(PO_(4))_(3)/tannin-based HC demonstrates a stable cycling performance.This work can manifest the potentiality of the tannin-based electrode as anode for a high-performance sodium-ion batteries(SIBs),which could especially offer an explanation of Na^(+)storage and solid-electrolyte interface(SEI)stability to the electrochemical performance.
基金Supported by the National Natural Science Foundation of China(Grant No.12261081).
文摘In this paper,we are concerned with the stability of traveling wavefronts of a Belousov-Zhabotinsky model with mixed nonlocal and degenerate diffusions.Such a system can be used to study the competition among nonlocally diffusive species and degenerately diffusive species.We prove that the traveling wavefronts are exponentially stable,when the initial perturbation around the traveling waves decays exponentially as x→-∞,but in other locations,the initial data can be arbitrarily large.The adopted methods are the weighted energy with the comparison principle and squeezing technique.
文摘With the rapid development of generative artificial intelligence(GenAI),the task of story visualization,which transforms natural language narratives into coherent and consistent image sequences,has attracted growing research attention.However,existing methods still face limitations in balancing multi-frame character consistency and generation efficiency,which restricts their feasibility for large-scale practical applications.To address this issue,this study proposes a modular cloud-based distributed system built on Stable Diffusion.By separating the character generation and story generation processes,and integratingmulti-feature control techniques,a cachingmechanism,and an asynchronous task queue architecture,the system enhances generation efficiency and scalability.The experimental design includes both automated and human evaluations of character consistency,performance testing,and multinode simulation.The results show that the proposed system outperforms the baseline model StoryGen in both CLIP-I and human evaluation metrics.In terms of performance,under the experimental environment of this study,dual-node deployment reduces average waiting time by approximately 19%,while the four-node simulation further reduces it by up to 65%.Overall,this study demonstrates the advantages of cloud-distributed GenAI in maintaining character consistency and reducing generation latency,highlighting its potential value inmulti-user collaborative story visualization applications.
基金supported by the National Natural Science Foundation of China(Grant No.U23A2022)the National Natural Science Foundation of China(Grant No.52474047)+2 种基金the Natural Science Foundation of Chongqing(Grant No.CSTB2024NSCQ-MSX0951)the Natural Science Foundation of Sichuan Province(Grant No.2025ZNSFSC1357)the National Science and Technology Major Project(Grant No.2025ZD1404307).
文摘Injecting impure CO_(2)for enhanced gas recovery(CO_(2)-EGR)offers a dual benefit by improving natural gas extraction while enabling CO_(2)sequestration.However,the interactions between CO_(2),N_(2),and CH_(4)under reservoir conditions require further investigation.This study employs Grand Canonical Monte Carlo(GCMC)and Molecular Dynamics(MD)simulations to quantify the adsorption and diffusion behaviors of CO_(2),N_(2),and CH_(4)in quartz nanopores over a pressure range of 1-24 MPa under varying water saturations and gas compositions.The results indicate that:(1)CO_(2)exhibits the broadest energy distribution and the strongest adsorption stability,occupying about 20%-30%more adsorption sites than CH_(4)or N_(2)and showing the least sensitivity to water saturation,with only a 30%reduction at 50%saturation,compared to 60%for CH_(4),giving CO_(2)a clear competitive advantage.(2)The adsorption and desorption behaviors are strongly pressure dependent,as increasing pressure reduces the adsorption layer area and shifts gas distribution from adsorption dominated to free phase.Competitive adsorption analysis reveals that while CO_(2)dominates displacement at low pressures,mixtures that contain N_(2)achieve higher CH_(4)desorption efficiency above 13 MPa by mitigating diffusion resistance.(3)A higher N_(2)fraction improves CH_(4)diffusion coefficients,thereby facilitating gas mobility and ensuring superior recovery performance under high-pressure conditions.This study advances the fundamental knowledge of microscale gas behavior in tight sandstones and supports the feasibility of impure CO_(2)injection as a practical strategy for sustainable gas production.
基金supported by the Zhejiang Province Natural Science Foundation of China(LY23A010003).
文摘Letα>0 and letμbe a positive Borel measure on the interval[0,1).The Hankel matrix■with entries■induces,formally,the generalized-Hilbert operator■where f(z)■is an analytic function in D.This article is devoted to study the measuresμfor which Hμ,αis a bounded(resp.,compact)operator from Hp(0<p≤1)into H^(p)(1≤q<∞).We also study the analogous problem in the Hardy spaces H^(p)(1≤p≤2).Finally,we obtain the essential norm of H_(μ,α)from H^(p)(0<p≤1)into H^(p)(1≤q<∞).
基金supported by the National Science and Technology Council,Taiwan,under grant no.NSTC 114-2221-E-197-005-MY3.
文摘With the development of technology,diffusion model-based solvers have shown significant promise in solving Combinatorial Optimization(CO)problems,particularly in tackling Non-deterministic Polynomial-time hard(NP-hard)problems such as the Traveling Salesman Problem(TSP).However,existing diffusion model-based solvers typically employ a fixed,uniform noise schedule(e.g.,linear or cosine annealing)across all training instances,failing to fully account for the unique characteristics of each problem instance.To address this challenge,we present GraphGuided Diffusion Solvers(GGDS),an enhanced method for improving graph-based diffusion models.GGDS leverages Graph Neural Networks(GNNs)to capture graph structural information embedded in node coordinates and adjacency matrices,dynamically adjusting the noise levels in the diffusion model.This study investigates the TSP by examining two distinct time-step noise generation strategies:cosine annealing and a Neural Network(NN)-based approach.We evaluate their performance across different problem scales,particularly after integrating graph structural information.Experimental results indicate that GGDS outperforms previous methods with average performance improvements of 18.7%,6.3%,and 88.7%on TSP-500,TSP-100,and TSP-50,respectively.Specifically,GGDS demonstrates superior performance on TSP-500 and TSP-50,while its performance on TSP-100 is either comparable to or slightly better than that of previous methods,depending on the chosen noise schedule and decoding strategy.
基金supported by the National Natural Science Foundation of China (52172227)the Natural Science Foundation of Hubei Province (2023AFA114)+2 种基金the Guizhou Provincial Key Technology R&D Program (ZD[2025]019)provided by the Startup Fund (20QD80 and 22QD28)support from the Science&Technology Top Talents Program of Guizhou Province ([2024]349)
文摘Prussian blue analogs(PBAs)have emerged as environmentally friendly and structurally tunable cathode materials for aqueous ammonium-ion batteries(AIBs).However,the fundamental role of crystalline H_(2)O in regulating ammonium-ion storage and transport remains poorly understood.In this study,we present a comprehensive comparison between hydrated NH_(4)NiHCF-H_(2)O and its anhydrous counterpart NH_(4)NiHCF,revealing the critical contribution of interstitial water to electrochemical performance.Structural and spectroscopic analyses confirm that interstitial water forms robust hydrogen bonds with NH_(4)+ions,stabilizing the PBA framework and mitigating structural degradation during cycling.Electrochemical measurements show that NH_(4)NiHCF-H_(2)O delivers a significantly higher specific capacity of 61 mA h g^(−1)at 0.2 C and markedly improved rate performance compared to NH_(4)NiHCF(48 mA h g^(−1)at 0.2 C).Kinetic analysis reveals that interstitial water enhances NH_(4)+diffusion,as evidenced by higher diffusion coefficients.Furthermore,density functional theory(DFT)calculations demonstrate that crystal water acts as a hydrogen bond acceptor,preferentially interacting with NH_(4)+and reducing the migration energy barrier,thereby facilitating fast ion transport.This work provides fundamental insights into the role of crystal water in PBAs and offers a rational design strategy for improving the kinetics,structural stability of PBAs cathodes for AIBs.
基金financially supported by the“National Natural Science Foundation of China”(No.22279082)the“Natural Science Foundation of Sichuan”(2025YFHZ0056)。
文摘Aqueous hydrogen(H_(2))gas batteries with unmatched lifespan are ideal for grid-scale energy storage,yet their deployment remains limited by the lack of low-cost,efficient,and durable hydrogen electrodes.Here,we report a high-throughput and durable gas diffusion electrode(GDE)based on a simply preparable carbon-coated nickel(Ni@C)catalyst and the design of H_(2) diffusion channels.By optimizing the carbon layer structure,a balance between the intrinsic activity and stability of the catalyst can be achieved.This Ni@C catalyst exhibits a hydrogen oxidation reaction(HOR)activity of 44 A g^(-1) as well as remarkable hydrogen evolution reaction(HER)performance.Experimental results and theoretical calculations confirm the electronic interaction between the carbon shell and Ni.In combination with a hydrophobic design,a robust and durable Ni@C-GDE has been fabricated.This electrode achieves a low HOR polarization of only 91 mV at 30 mA cm^(-2),outperforming Pt/C-GDE(154 mV),and operates stably over 4500cycles(3200 h)for HOR/HER reversing.Enabled by this electrode,a 10 Ah Ni-H_(2) battery with an energy density of 156.3 Wh kg^(-1) and cost of 62.2$kWh^(-1) is demonstrated.This work offers a viable strategy for practical and scalable hydrogen gas batteries.
基金funding from the European Commission by the Ruralities project(grant agreement no.101060876).
文摘In this paper,we propose a new privacy-aware transmission scheduling algorithm for 6G ad hoc networks.This system enables end nodes to select the optimum time and scheme to transmit private data safely.In 6G dynamic heterogeneous infrastructures,unstable links and non-uniform hardware capabilities create critical issues regarding security and privacy.Traditional protocols are often too computationally heavy to allow 6G services to achieve their expected Quality-of-Service(QoS).As the transport network is built of ad hoc nodes,there is no guarantee about their trustworthiness or behavior,and transversal functionalities are delegated to the extreme nodes.However,while security can be guaranteed in extreme-to-extreme solutions,privacy cannot,as all intermediate nodes still have to handle the data packets they are transporting.Besides,traditional schemes for private anonymous ad hoc communications are vulnerable against modern intelligent attacks based on learning models.The proposed scheme fulfills this gap.Findings show the probability of a successful intelligent attack reduces by up to 65%compared to ad hoc networks with no privacy protection strategy when used the proposed technology.While congestion probability can remain below 0.001%,as required in 6G services.