In this work,Bi-based catalysts were prepared by one pot method(PM)and incipient wetness impregnation method(IM)and preparation conditions of the PM were researched.Catalytic activity of catalysts was evaluated using ...In this work,Bi-based catalysts were prepared by one pot method(PM)and incipient wetness impregnation method(IM)and preparation conditions of the PM were researched.Catalytic activity of catalysts was evaluated using a fixed-bed reactor for acetylene hydrochlorination.The results displayed that the PM catalyst was prepared at 160℃for 2 h possessed a superior catalytic performance compared to the IM catalyst.The characterizations of XRD,BET,EDS and SEM demonstrated that the PM catalyst was microspheres structure,which could provide richer channel structures,larger specific surface areas and more active centres,thus improving the catalytic performances of catalysts.In addition,carbon deposition in the reaction was a possible reason for Bi-based catalysts deactivation.展开更多
A facile tandem route has been developed for constructing quinazolinones from various aminobenzamides and in-situ generated aldehydes.Visible light was found to play a dual role:first oxidizes the alcohol to the aldeh...A facile tandem route has been developed for constructing quinazolinones from various aminobenzamides and in-situ generated aldehydes.Visible light was found to play a dual role:first oxidizes the alcohol to the aldehyde and then facilitates its cyclization with o-substituted aniline.Furthermore,alcohols are perfe ct alternatives to aldehydes because they are greene r,more available,more economical,more stable,and less toxic tha n aldehydes.The first reaction step continuously provides material for the second step,which effectively reduces loss through volatilization,oxidation,and polymerization of the aldehyde,while avoiding its toxicity.A variety of quinazolinones can be prepared in the presence of visible light without any additional photocatalyst.The developed synthesis protocol proceeds with the merits of mild conditions,broad substrate scope,operational simplicity,a nd high atom efficiency,with an eco-energy source under metal-free,photocatalyst-free,and ambient conditions.展开更多
Bis-silicon-bridged stilbene derivatives were synthesized in a modified procedure that combined the preparation of bis[2- （silyl）phenyl]acetylene and its intramolecular reductive cyclization in one pot. The results ...Bis-silicon-bridged stilbene derivatives were synthesized in a modified procedure that combined the preparation of bis[2- （silyl）phenyl]acetylene and its intramolecular reductive cyclization in one pot. The results indicated that the one pot approach produced target products in a comparable yield to that of the two-step method reported previously.展开更多
A one pot protocol for the synthesis of dibenzodiazepinones was developed. The substituted ethyl 2- halobenzoates are cross-coupled with o-phenylenediamine utilizing a ligand-free, Cul catalyzed system, which spontane...A one pot protocol for the synthesis of dibenzodiazepinones was developed. The substituted ethyl 2- halobenzoates are cross-coupled with o-phenylenediamine utilizing a ligand-free, Cul catalyzed system, which spontaneously undergo an intramolecular N-acylation in ethylene glycol to give the corresponding products in high yields. This synthetic protocol provides a concise and efficient access to a wide variety of dibenzodiazepinone, including biologically active molecules.展开更多
In the past century,industrial and economic growth relied heavily on fossil fuels such as coal,oil,and natural gas.As the society energy demands continue to grow,these fossil fuel reserves are depleted,leading to sign...In the past century,industrial and economic growth relied heavily on fossil fuels such as coal,oil,and natural gas.As the society energy demands continue to grow,these fossil fuel reserves are depleted,leading to significant environmental issues[1].Currently,sustainable biomass resources have attracted much attention as potential substitutes to fossil fuels for producing biofuels and commodity chemicals[2].展开更多
African swine fever(ASF),caused by the African swine fever virus(ASFV),has brought enormous economic loss and represents a major threat to the global pig industry(Vergne et al.2017).ASFVs are divided into 24 genotypes...African swine fever(ASF),caused by the African swine fever virus(ASFV),has brought enormous economic loss and represents a major threat to the global pig industry(Vergne et al.2017).ASFVs are divided into 24 genotypes based on their B646L gene,with only genotypes Ⅰ and Ⅱ circulating globally(Dixon et al.2019).展开更多
Dear Editor,The frequent emergence of life-threatening infectious diseases has posed a constant global threat in recent decades.Since the first identification of Ebola Virus Disease(EVD)in the Democratic Republic of C...Dear Editor,The frequent emergence of life-threatening infectious diseases has posed a constant global threat in recent decades.Since the first identification of Ebola Virus Disease(EVD)in the Democratic Republic of Congo(then Zaire)in 1976,there have been approximately 40 outbreaks.展开更多
A combination of sodium borohydride and a catalytic amount of indium（Ⅲ） chloride in acetonitrile reduces imines formed in-situ from aldehydes and amines to the corresponding functionalised secondary and tertiary am...A combination of sodium borohydride and a catalytic amount of indium（Ⅲ） chloride in acetonitrile reduces imines formed in-situ from aldehydes and amines to the corresponding functionalised secondary and tertiary amines in moderate to good yields. Noteworthy is that highly chemoselective reactions were achieved in the presence of other functional groups such as halogens, carbon-carbon double bonds and hydroxyl groups.展开更多
Diammonium hydrogen phosphate and potassium carbonate-catalyzed one-pot synthesis of 1,4- phenylene-bis（2-amino-4H-pyran-3-carbonitrile and 2-amino-4-aryl-4H-pyran-3-carbonitrile deriva- tives has been achieved by a ...Diammonium hydrogen phosphate and potassium carbonate-catalyzed one-pot synthesis of 1,4- phenylene-bis（2-amino-4H-pyran-3-carbonitrile and 2-amino-4-aryl-4H-pyran-3-carbonitrile deriva- tives has been achieved by a three-component cyclocondensation of aldehydes, malononitrile, and different nucleophiles in aqueous medium in high yields.展开更多
Two new different Cu(Ⅱ) MOFs with the same 1,3,5-tris(1-imidazolyl) benzene(tib) ligand {[Cu(tib)2]·(H2O)2·Br2}n(1) and {[Cu2(tib)·Br·Cl]·2Br}n(2) were obtained by one pot synthesized of tib ...Two new different Cu(Ⅱ) MOFs with the same 1,3,5-tris(1-imidazolyl) benzene(tib) ligand {[Cu(tib)2]·(H2O)2·Br2}n(1) and {[Cu2(tib)·Br·Cl]·2Br}n(2) were obtained by one pot synthesized of tib with CuBr in the presences of HCl and water. X-ray single crystal diffraction analyses indicate that both complexes 1 and 2 have two dimensional frameworks containing different building blocks. Each Cu(Ⅱ) atom in complex 1 is coordinated by four N atoms from different tib ligands. However, there are two different cryptographic Cu(Ⅱ) atoms in complex 2, one is four coordinated by two bromine atoms and two N atoms from different tib ligands, the other is six coordinated by two chloride atoms and four N atoms from different tib ligands. The thermal gravimetric analysis of complexes 1 and 2 are depicted in the paper.展开更多
A convenient one-pot three-component method for the preparation of tetra-substituted thiophene derivatives has been developed. Reaction ofacetyl acetone 1, phenyl isothiocynate 2 and 2-chloromethyI derivatives 3a-3c i...A convenient one-pot three-component method for the preparation of tetra-substituted thiophene derivatives has been developed. Reaction ofacetyl acetone 1, phenyl isothiocynate 2 and 2-chloromethyI derivatives 3a-3c in the presence of potassium carbonate afforded the target compounds, namely ethyl 2-（4-acetyl-3-methyl-5-（phenylamino）thiophen-2-yl）-2-oxoacetate derivatives 4a-4e, ethyl 3-（4- acetyl-3-methyl-5-（phenylamino）thiophen-2-yl）-3-oxopropanoate derivatives 4f-4i, di（（4-acetyl-3- methyl-5-phenylamino）thiophen-2-yl）ketone derivatives 4j-4n in reasonable overall yields. The synthesized compounds were screened for antirnicrobial activity. The detailed synthesis, spectroscopic data and antimicrobial activities of synthesized compounds were reported.展开更多
This paper describes the combustion synthesis ofα-Fe2O3 nanopowder at much lower temperature and its catalytic activity for the one-pot preparation of 3,4-dihydropyrano[c]chromenes.The combustion derivedα-Fe_2O_3 na...This paper describes the combustion synthesis ofα-Fe2O3 nanopowder at much lower temperature and its catalytic activity for the one-pot preparation of 3,4-dihydropyrano[c]chromenes.The combustion derivedα-Fe_2O_3 nanopowder was characterized by powder X-ray diffraction（PXRD）,Braunauer,Emmett and Teller（BET） surface area,scanning electron microscopy（SEM） and Fourier transform infrared spectroscopy（FTIR）.Highly efficient,three-component condensation of aromatic aldehyde,malanonitrile and 4- hydroxycoumarin catalyzed byα-Fe2O3 nanoparticles at room temperature is described.The method offers an excellent alternative to the synthesis of 3,4-dihydropyrano[c]chromenes.The reactions are rapid,clean,and the products with good yield and high purity.展开更多
We report a new, effective and simple method for preparing a,fl-unsaturated carbonyl compounds by reacting ketones and aromatic alcohols at 56 ℃ in the presence of CrO3 （CrO3 acts as an oxidant and also a catalyst）...We report a new, effective and simple method for preparing a,fl-unsaturated carbonyl compounds by reacting ketones and aromatic alcohols at 56 ℃ in the presence of CrO3 （CrO3 acts as an oxidant and also a catalyst） for around 10 h. The condensation reactions occurred effectively among a wide combination of ketones and alcohols. The procedure is simple and the yields can be high up to 98%. And a probable mechanism is proposed.展开更多
The practical deployment of polyester-based solid electrolytes such as poly(ε-caprolactone)(PCL)is hindered by two inherent material-level constraints:the semicrystalline nature of PCL chains severely restricts segme...The practical deployment of polyester-based solid electrolytes such as poly(ε-caprolactone)(PCL)is hindered by two inherent material-level constraints:the semicrystalline nature of PCL chains severely restricts segmental mobility and limits ionic conductivity,whereas interfacial instability against lithium metal anodes jeopardizes long-term cycling.Based on orthogonal polymerization technology combined with electrolyte structural design concepts,this work achieved a one-step fabrication of a polyester-based block copolymer electrolyte(BCPE)system comprising fluorinated segments(PTFEA)and poly(ε-caprolactone)(PCL).Structurally,this design enables a dual breakthrough in electrochemical performance:on one hand,the introduction of fluorinated segments with steric hindrance effects can effectively disrupt the regular arrangement of the PCL main chain,reduce the crystallinity of PCL within the polymer electrolyte,and significantly enhance the segmental mobility of the polymer matrix;on the other hand,during the charge/discharge cycles of lithium batteries,fluorinated segments can induce the formation of a LiF-rich solid electrolyte interphase(SEI)through in situ decomposition reactions,achieving interface stabilization and homogeneous lithiumion deposition regulation.展开更多
Direct one-pot synthesis of delaminated layered zeolitic materials aims to create two-dimensionally confined catalysts for reactions involving sterically bulky reactants,which are too large to benefit from conventiona...Direct one-pot synthesis of delaminated layered zeolitic materials aims to create two-dimensionally confined catalysts for reactions involving sterically bulky reactants,which are too large to benefit from conventional three-dimensional confinement in micropores.As a prototypical system,several efforts have focused on the development of post-synthetic approaches for delamination of silica-rich MWW layered zeolite precursors.展开更多
The title compound was synthesized by a one pot synthesis method with ethanolamine ,ketone and dichloroacetyl chloride. The product was characterization by IR, 1 HNMR,UV, and elementary analysis.
Herein we reported a one-pot synthesis of arylsubstituted imidazolin-2-ones by the cyclization of α-aminoacetophenone hydrochloride analogues 2 with arylisocyanates 3. Compared with other known synthetic route, this ...Herein we reported a one-pot synthesis of arylsubstituted imidazolin-2-ones by the cyclization of α-aminoacetophenone hydrochloride analogues 2 with arylisocyanates 3. Compared with other known synthetic route, this method resulted in higher yield.展开更多
In the present work,Au@Pd nanoparticles,which serve as catalytic active centers,were first implanted in amphiphilic hollow vinyl-pyridyl group-doped periodic mesoporous organosilica(PMO)shells,and yolk-shell smart Pic...In the present work,Au@Pd nanoparticles,which serve as catalytic active centers,were first implanted in amphiphilic hollow vinyl-pyridyl group-doped periodic mesoporous organosilica(PMO)shells,and yolk-shell smart Pickering Au@Pd@Py-PMO nanoreactors were obtained.Herein,two smart aspects of the novel nanoreactor are demonstrated:one is the adsorption and the other is the catalytic process.Interestingly,it was found that the obtained vinyl-pyridyl group-doped nanoreactors can easily adsorb hydrophobic molecules containing nitro-groups or vinyl-groups into their interior rather than simply indiscriminately adsorb organic substances.展开更多
Photocatalysis is an expanding tool designed to synthesize organic molecules in a very efficient and selective way,using mild and environmentally friendly conditions.Thus,the development of new photosensitizers and ph...Photocatalysis is an expanding tool designed to synthesize organic molecules in a very efficient and selective way,using mild and environmentally friendly conditions.Thus,the development of new photosensitizers and photocatalytic protocols can further boost the applicability of photocatalysis in preparative chemistry.In this paper,we have conceived a family of Ru(Ⅱ)polypyridyl complexes of general formula[Ru(bpy)_(2)(N^N)]Cl_(2)(bpy=2,2’-bipyridine)bearing the 2-pyridylbenzimidazole(Hpybim)scaffold in the ancillary ligands(N^N=R-pybim).Moreover,using these Ru(Ⅱ)derivatives as photosensitizers we have described a protocol for the synthesis of imines from primary and secondary amines and also a simple,efficient and selective methodology for the one-pot preparation of α-amino nitriles from primary and secondary amines involving the consecutive photooxidation of the amine substrate and the cyanation of the imine intermediate.In addition,we have formulated a mechanism for the afore-mentioned transformations based on the participation of singlet oxygen.展开更多
A highly active phosphine-free ruthenium-arene complex,[(η^(6)-C_(6)H_(6))RuCl_(2)(C_(6)H_(5)NH_(2))],exhibits excellent catalytic performance for a one-pot conversion of aldehydes to primary amides at low temperatur...A highly active phosphine-free ruthenium-arene complex,[(η^(6)-C_(6)H_(6))RuCl_(2)(C_(6)H_(5)NH_(2))],exhibits excellent catalytic performance for a one-pot conversion of aldehydes to primary amides at low temperature(60°C),in water and without any inert gas protection.The reported catalyst performed exceptionally well for a huge range of aldehydes,including aromatic,heteroaromatic,aliphatic and conjugated systems,with a high tolerance for other functional groups.The development of such highly active catalysts using simple reagents will offer new opportunities for the development of improved phosphine-free catalytic systems for this and other related catalytic reactions.展开更多
基金Natural Scientific Foundation of China(21263025,U1403293)
文摘In this work,Bi-based catalysts were prepared by one pot method(PM)and incipient wetness impregnation method(IM)and preparation conditions of the PM were researched.Catalytic activity of catalysts was evaluated using a fixed-bed reactor for acetylene hydrochlorination.The results displayed that the PM catalyst was prepared at 160℃for 2 h possessed a superior catalytic performance compared to the IM catalyst.The characterizations of XRD,BET,EDS and SEM demonstrated that the PM catalyst was microspheres structure,which could provide richer channel structures,larger specific surface areas and more active centres,thus improving the catalytic performances of catalysts.In addition,carbon deposition in the reaction was a possible reason for Bi-based catalysts deactivation.
基金supported by the National Natural Science Foundation of China (No.21462001)a Science and Technology Project of Jiangxi Province (No.20192BBH80012)。
文摘A facile tandem route has been developed for constructing quinazolinones from various aminobenzamides and in-situ generated aldehydes.Visible light was found to play a dual role:first oxidizes the alcohol to the aldehyde and then facilitates its cyclization with o-substituted aniline.Furthermore,alcohols are perfe ct alternatives to aldehydes because they are greene r,more available,more economical,more stable,and less toxic tha n aldehydes.The first reaction step continuously provides material for the second step,which effectively reduces loss through volatilization,oxidation,and polymerization of the aldehyde,while avoiding its toxicity.A variety of quinazolinones can be prepared in the presence of visible light without any additional photocatalyst.The developed synthesis protocol proceeds with the merits of mild conditions,broad substrate scope,operational simplicity,a nd high atom efficiency,with an eco-energy source under metal-free,photocatalyst-free,and ambient conditions.
文摘Bis-silicon-bridged stilbene derivatives were synthesized in a modified procedure that combined the preparation of bis[2- （silyl）phenyl]acetylene and its intramolecular reductive cyclization in one pot. The results indicated that the one pot approach produced target products in a comparable yield to that of the two-step method reported previously.
基金National Natural Science Foundation of China(No.81102322)the Global Alliance for TB Drug Development(TB alliance)for their financial supports
文摘A one pot protocol for the synthesis of dibenzodiazepinones was developed. The substituted ethyl 2- halobenzoates are cross-coupled with o-phenylenediamine utilizing a ligand-free, Cul catalyzed system, which spontaneously undergo an intramolecular N-acylation in ethylene glycol to give the corresponding products in high yields. This synthetic protocol provides a concise and efficient access to a wide variety of dibenzodiazepinone, including biologically active molecules.
基金funded by the Master,PhD Scholarship Programme of Vingroup Innovation Foundation(VINIF),code VINIF.2024.TS.035funded by Vietnam National University,Ho Chi Minh City(VNUHCM)under grant number NCM2024-18-01。
文摘In the past century,industrial and economic growth relied heavily on fossil fuels such as coal,oil,and natural gas.As the society energy demands continue to grow,these fossil fuel reserves are depleted,leading to significant environmental issues[1].Currently,sustainable biomass resources have attracted much attention as potential substitutes to fossil fuels for producing biofuels and commodity chemicals[2].
基金supported by the National Natural Science Fund for Distinguished Young Scholars of China(31925036 and 32025034)the Shandong Provincial Key R&D Program,China(2021LZGC001)+3 种基金the Biological Breeding-Major Projects,Institute of Zoology,Chinese Academy of Sciences and Institute of Animal Science,Chinese Academy of Agricultural Sciences(2023ZD04074 and 2023ZD0404604)the Special Project of Longhu Laboratory,China(LHLab_ZD20230012)the National Natural Science Foundation of China(32230100,32330099 and 32201257)the National Key Research and Development Program of China(2020YFA0509503,2022YFF0710703,2021YFA0805902 and 2022XAGG0121,2022YFF1002803).
文摘African swine fever(ASF),caused by the African swine fever virus(ASFV),has brought enormous economic loss and represents a major threat to the global pig industry(Vergne et al.2017).ASFVs are divided into 24 genotypes based on their B646L gene,with only genotypes Ⅰ and Ⅱ circulating globally(Dixon et al.2019).
基金financially supported by the National Key Research and Development Program of China(grant No.2021YFF0703600)the Science and Technology Development Program of Jilin Province(Grant20250601001RC).
文摘Dear Editor,The frequent emergence of life-threatening infectious diseases has posed a constant global threat in recent decades.Since the first identification of Ebola Virus Disease(EVD)in the Democratic Republic of Congo(then Zaire)in 1976,there have been approximately 40 outbreaks.
文摘A combination of sodium borohydride and a catalytic amount of indium（Ⅲ） chloride in acetonitrile reduces imines formed in-situ from aldehydes and amines to the corresponding functionalised secondary and tertiary amines in moderate to good yields. Noteworthy is that highly chemoselective reactions were achieved in the presence of other functional groups such as halogens, carbon-carbon double bonds and hydroxyl groups.
文摘Diammonium hydrogen phosphate and potassium carbonate-catalyzed one-pot synthesis of 1,4- phenylene-bis（2-amino-4H-pyran-3-carbonitrile and 2-amino-4-aryl-4H-pyran-3-carbonitrile deriva- tives has been achieved by a three-component cyclocondensation of aldehydes, malononitrile, and different nucleophiles in aqueous medium in high yields.
基金funded by the National Natural Science Foundation of China(21261009)Young Scientist Foundation of Jiangxi Provincethe Education Fund of Jiangxi Province(GJJ13434)
文摘Two new different Cu(Ⅱ) MOFs with the same 1,3,5-tris(1-imidazolyl) benzene(tib) ligand {[Cu(tib)2]·(H2O)2·Br2}n(1) and {[Cu2(tib)·Br·Cl]·2Br}n(2) were obtained by one pot synthesized of tib with CuBr in the presences of HCl and water. X-ray single crystal diffraction analyses indicate that both complexes 1 and 2 have two dimensional frameworks containing different building blocks. Each Cu(Ⅱ) atom in complex 1 is coordinated by four N atoms from different tib ligands. However, there are two different cryptographic Cu(Ⅱ) atoms in complex 2, one is four coordinated by two bromine atoms and two N atoms from different tib ligands, the other is six coordinated by two chloride atoms and four N atoms from different tib ligands. The thermal gravimetric analysis of complexes 1 and 2 are depicted in the paper.
文摘A convenient one-pot three-component method for the preparation of tetra-substituted thiophene derivatives has been developed. Reaction ofacetyl acetone 1, phenyl isothiocynate 2 and 2-chloromethyI derivatives 3a-3c in the presence of potassium carbonate afforded the target compounds, namely ethyl 2-（4-acetyl-3-methyl-5-（phenylamino）thiophen-2-yl）-2-oxoacetate derivatives 4a-4e, ethyl 3-（4- acetyl-3-methyl-5-（phenylamino）thiophen-2-yl）-3-oxopropanoate derivatives 4f-4i, di（（4-acetyl-3- methyl-5-phenylamino）thiophen-2-yl）ketone derivatives 4j-4n in reasonable overall yields. The synthesized compounds were screened for antirnicrobial activity. The detailed synthesis, spectroscopic data and antimicrobial activities of synthesized compounds were reported.
基金VTU(VTU/Aca./2009-10/A-9/11714) for the financial support and Chemistry-TEQIP Laboratory of MSRIT and SSMRV College, Chemistry Research Center
文摘This paper describes the combustion synthesis ofα-Fe2O3 nanopowder at much lower temperature and its catalytic activity for the one-pot preparation of 3,4-dihydropyrano[c]chromenes.The combustion derivedα-Fe_2O_3 nanopowder was characterized by powder X-ray diffraction（PXRD）,Braunauer,Emmett and Teller（BET） surface area,scanning electron microscopy（SEM） and Fourier transform infrared spectroscopy（FTIR）.Highly efficient,three-component condensation of aromatic aldehyde,malanonitrile and 4- hydroxycoumarin catalyzed byα-Fe2O3 nanoparticles at room temperature is described.The method offers an excellent alternative to the synthesis of 3,4-dihydropyrano[c]chromenes.The reactions are rapid,clean,and the products with good yield and high purity.
基金Project supported by the National Natural Science Foundation of China （NSFC） （Nos. 50825303 and 30890140） and the Ministry of Science and Technology of China （No. 2009CB-930400）.
文摘We report a new, effective and simple method for preparing a,fl-unsaturated carbonyl compounds by reacting ketones and aromatic alcohols at 56 ℃ in the presence of CrO3 （CrO3 acts as an oxidant and also a catalyst） for around 10 h. The condensation reactions occurred effectively among a wide combination of ketones and alcohols. The procedure is simple and the yields can be high up to 98%. And a probable mechanism is proposed.
基金financially supported by the National Natural Science Foundation of China(No.52573079)the Innovation and Talent Recruitment Base of New Energy Chemistry and Device(No.B21003).
文摘The practical deployment of polyester-based solid electrolytes such as poly(ε-caprolactone)(PCL)is hindered by two inherent material-level constraints:the semicrystalline nature of PCL chains severely restricts segmental mobility and limits ionic conductivity,whereas interfacial instability against lithium metal anodes jeopardizes long-term cycling.Based on orthogonal polymerization technology combined with electrolyte structural design concepts,this work achieved a one-step fabrication of a polyester-based block copolymer electrolyte(BCPE)system comprising fluorinated segments(PTFEA)and poly(ε-caprolactone)(PCL).Structurally,this design enables a dual breakthrough in electrochemical performance:on one hand,the introduction of fluorinated segments with steric hindrance effects can effectively disrupt the regular arrangement of the PCL main chain,reduce the crystallinity of PCL within the polymer electrolyte,and significantly enhance the segmental mobility of the polymer matrix;on the other hand,during the charge/discharge cycles of lithium batteries,fluorinated segments can induce the formation of a LiF-rich solid electrolyte interphase(SEI)through in situ decomposition reactions,achieving interface stabilization and homogeneous lithiumion deposition regulation.
基金Department of Energy,Office of Science,Basic Energy Sciences(DE-FG02-05ER15696)for supporting the catalysis and materials characterization aspects of this workthe Management and Transfer of Hydrogen via Catalysis Program funded by Chevron Corporation for supporting the materials synthesis work in this manuscript.
文摘Direct one-pot synthesis of delaminated layered zeolitic materials aims to create two-dimensionally confined catalysts for reactions involving sterically bulky reactants,which are too large to benefit from conventional three-dimensional confinement in micropores.As a prototypical system,several efforts have focused on the development of post-synthetic approaches for delamination of silica-rich MWW layered zeolite precursors.
文摘The title compound was synthesized by a one pot synthesis method with ethanolamine ,ketone and dichloroacetyl chloride. The product was characterization by IR, 1 HNMR,UV, and elementary analysis.
文摘Herein we reported a one-pot synthesis of arylsubstituted imidazolin-2-ones by the cyclization of α-aminoacetophenone hydrochloride analogues 2 with arylisocyanates 3. Compared with other known synthetic route, this method resulted in higher yield.
基金supported by the National Natural Science Foundation of China(21390394,21771082,21771081,and 21703128)“111”project(BP0719036)the Natural Science Foundation of Jilin Province(no.20190201207JC).
文摘In the present work,Au@Pd nanoparticles,which serve as catalytic active centers,were first implanted in amphiphilic hollow vinyl-pyridyl group-doped periodic mesoporous organosilica(PMO)shells,and yolk-shell smart Pickering Au@Pd@Py-PMO nanoreactors were obtained.Herein,two smart aspects of the novel nanoreactor are demonstrated:one is the adsorption and the other is the catalytic process.Interestingly,it was found that the obtained vinyl-pyridyl group-doped nanoreactors can easily adsorb hydrophobic molecules containing nitro-groups or vinyl-groups into their interior rather than simply indiscriminately adsorb organic substances.
基金the financial support provided by the Spanish Ministerio de Ciencia,Innovación y Universidades(RTI2018-100709-B-C21 and CTQ(QMC)-RED2018-102471-T)Junta de Castilla y León(BU087G19)the European Social Fund+2 种基金Consejería de Educación de la Junta de Castilla y León(EDU/1100/2017)the financial support received from the Consejería de Educación-Junta de Castilla y León-FEDER(BU042U16-BU305P18)for the postdoctoral grantMinisterio de Ciencia,Innovación y Universidades(RTI2018-102040-B-100).
文摘Photocatalysis is an expanding tool designed to synthesize organic molecules in a very efficient and selective way,using mild and environmentally friendly conditions.Thus,the development of new photosensitizers and photocatalytic protocols can further boost the applicability of photocatalysis in preparative chemistry.In this paper,we have conceived a family of Ru(Ⅱ)polypyridyl complexes of general formula[Ru(bpy)_(2)(N^N)]Cl_(2)(bpy=2,2’-bipyridine)bearing the 2-pyridylbenzimidazole(Hpybim)scaffold in the ancillary ligands(N^N=R-pybim).Moreover,using these Ru(Ⅱ)derivatives as photosensitizers we have described a protocol for the synthesis of imines from primary and secondary amines and also a simple,efficient and selective methodology for the one-pot preparation of α-amino nitriles from primary and secondary amines involving the consecutive photooxidation of the amine substrate and the cyanation of the imine intermediate.In addition,we have formulated a mechanism for the afore-mentioned transformations based on the participation of singlet oxygen.
文摘A highly active phosphine-free ruthenium-arene complex,[(η^(6)-C_(6)H_(6))RuCl_(2)(C_(6)H_(5)NH_(2))],exhibits excellent catalytic performance for a one-pot conversion of aldehydes to primary amides at low temperature(60°C),in water and without any inert gas protection.The reported catalyst performed exceptionally well for a huge range of aldehydes,including aromatic,heteroaromatic,aliphatic and conjugated systems,with a high tolerance for other functional groups.The development of such highly active catalysts using simple reagents will offer new opportunities for the development of improved phosphine-free catalytic systems for this and other related catalytic reactions.
