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The Proof of the Existence of One-way Fluxes in a Chemical Reaction Network
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作者 SHENG Ying QIAO Luyao YI Hua 《数学进展》 北大核心 2025年第3期637-648,共12页
Peng et al.in[Phys.Rev.Research,2020,2(3):033089,11 pp.]formulated one-way fluxes for a general chemical reaction far from equilibrium,with arbitrary complex mechanisms,multiple intermediates,and internal kinetic cycl... Peng et al.in[Phys.Rev.Research,2020,2(3):033089,11 pp.]formulated one-way fluxes for a general chemical reaction far from equilibrium,with arbitrary complex mechanisms,multiple intermediates,and internal kinetic cycles.They defined the limit of the ratio of mesoscopic one-way fluxes and the volume of the tank reactor when the volume tends to infinity as macroscopic one-way fluxes,but a rigorous proof of existence of the limit is still awaiting.In this article,we fill this gap under a mild hypothesis:the Markov chain associated with the chemical master equation has finite states and any two columns in the stoichiometric matrices are not identical.In fact,an explicit expression of the limit is obtained. 展开更多
关键词 non-equilibrium chemical reaction network kinetic one-way flux Markov chain
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Hydrogen-bonded Three-Dimensional Networks Encapsulating One-dimensional Covalent Chains: [Cu(3-ampy)(H_2O)_4](SO_4)·(H_2O) (3-ampy = 3-Aminopyridine)
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作者 潘万龙 黄坤林 +1 位作者 许颜清 胡长文 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2007年第7期822-826,共5页
A three-dimensional complex [Cu(3-ampy)(HEO)4](SO4)·(H2O) (3-ampy = 3-amino- pyridine) has been synthesized. Crystallographic data: C5H16CuN2O9S, Mr = 343.80, triclinic, space group P1, a = 7.675(2),... A three-dimensional complex [Cu(3-ampy)(HEO)4](SO4)·(H2O) (3-ampy = 3-amino- pyridine) has been synthesized. Crystallographic data: C5H16CuN2O9S, Mr = 343.80, triclinic, space group P1, a = 7.675(2), b = 8.225(3), c = 10.845(3)A, α= 86.996(4), β = 76.292(4), γ= 68.890(4)°, V = 620.0(3)A^3, Z = 2, Dc = 1.841 g/cm^3, F(000) = 354 and μ = 1.971 mm^-1. The structure was refined to R = 0.0269 and wR = 0.0659 for 1838 observed reflections (I 〉 2a(/)). The structure consists of [Cu(3-ampy)(H2O)4]^2+ cations, SO4^2- anions and lattice water molecules. 3-Ampy acting as a bidentate bridging ligand generates a 1D covalent chain. A supramolecular 2D framework is formed through π-π stacking of pyridine rings. The lattice water molecules and SO4^2- anions are located between the adjacent 2D frameworks. The hydrogen bonding interactions from lattice water molecules and SO4^2- anions to coordinate water extend the 2D framework into a 3D network. 展开更多
关键词 three-dimension covalent chains 3-aminopyridine hydrogen bonds π-π stacking
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Innovation in two contrasting value chains:Constraints and opportunities for adopting alternative crop production in the Vietnamese Mekong River Delta
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作者 Sang Thanh LE Nhu Huynh MAO +1 位作者 Paul KRISTIANSEN Michael COLEMAN 《Regional Sustainability》 2025年第1期75-89,共15页
Agricultural production(especially intensive rice production)is a primary income source for over 2.0×10^(7) people in the Vietnamese Mekong River Delta.However,adverse climate change impacts,socio-economic change... Agricultural production(especially intensive rice production)is a primary income source for over 2.0×10^(7) people in the Vietnamese Mekong River Delta.However,adverse climate change impacts,socio-economic change,and high dependence on farm inputs for intensive production constrain the longer-term sustainability of rice systems.Government and agribusiness actors are encouraging more farmers to grow non-rice crops and supporting the upscaling of alternative crops to paddy rice.We used a qualitative approach to investigate the value chain characteristics,as well as constraints and opportunities of alternative crops via two case studies(baby corn and honeydew melon)in An Giang and Hau Giang provinces,Vietnam.Data collection involved focus group discussions with local farmers and interviews with farmers and industry experts.Thematic analysis was used to compile the findings,and the results were validated with local government staff.The baby corn value chain featured on-going and stable market demand(including value-addition)and better vertical coordination(e.g.,written contracts and financial support).The honeydew melon value chain featured positive relationships between farmers and traders despite less-developed vertical coordination.There are opportunities for value chain engagement through product quality certification,value-addition,and accessing high-value domestic and export markets.However,farmers require crop-specific and generic support from private and public sectors.Increased labour requirements and limited access to finance and credit limit value chain participation.Upscaling and marketing alternative crops can enhance farmer profitability and support non-farming agricultural business establishment,economic growth,and community development.Efficient value chains will be critical to ensure the adoption of alternative crops and development of crop-specific agribusiness models.These findings can inform policy-makers and change facilitators in designing targeted interventions to support the adoption of alternative crops in the study area as well as in Vietnam and globally. 展开更多
关键词 Value chain Transformative adaptation Alternative crop Honeydew melon Baby corn Vietnamese Mekong River Delta
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The Integration of the Four Chains in the Chengdu-Chongqing Economic Zone:Measurement and Pathways for Enhancement
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作者 Zhang Xia Liu Yu 《Contemporary Social Sciences》 2025年第6期36-52,共17页
Promoting the deep integration of the innovation,industrial,capital,and talent chains is of great significance to driving high-quality economic and social development.Using the entropy method,a coupling coordination d... Promoting the deep integration of the innovation,industrial,capital,and talent chains is of great significance to driving high-quality economic and social development.Using the entropy method,a coupling coordination degree model,and a grey relational model,we measure the integration level and subsystem interactions within the Chengdu-Chongqing economic zone from 2019 to 2023.The findings indicate a generally positive trajectory and gradual improvement in overall integration,making a transition from early-stage factor accumulation to deep inter-chain synergy.However,development across the chains remains uneven.Although the talent and innovation chains show relative strength,the innovation chain has weak spillover effects on the industrial chain,with low technological conversion efficiency.The underdeveloped industrial chain further limits overall synergy.Synergistic effects are gradually emerging,but coordination barriers persist.To address these challenges,we recommend optimizing policies for the integration of the four chains,accelerating the conversion of innovations into industrial applications,strengthening alignment between capital and the industrial chain,and enhancing mechanisms for talent attraction and development.These measures are essential for fostering deeper regional integration of the four chains and optimizing the overall development framework. 展开更多
关键词 Chengdu-Chongqing economic zone the integration of the four chains measurement and enhancement
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Resilience and risk management in railway supply chains:the interplay of leadership,innovation and competitive advantage
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作者 Meisam Karami 《Railway Sciences》 2026年第1期117-135,共19页
Purpose-This study explores how managerial leadership and organizational innovation interact to enhance resilience and risk management in railway supply chains and how these capabilities contribute to sustained compet... Purpose-This study explores how managerial leadership and organizational innovation interact to enhance resilience and risk management in railway supply chains and how these capabilities contribute to sustained competitive advantage.It emphasizes the strategic importance of resilience in railway systems that face operational complexity,regulatory pressures and increasing exposure to systemic risks.Design/methodology/approach-A mixed-methods design was employed,integrating survey data from 186 railway organizations with six case studies involving railway operators,rolling stock manufacturers and supply chain partners across multiple regions.Constructs were measured using validated scales and hypothesized relationships were tested using Structural Equation Modeling(SEM).Case study interviews were analyzed thematically to provide contextual understanding of leadership practices and innovation strategies.Findings-The results confirm that transformational managerial leadership significantly predicts innovation adoption,which in turn strengthens resilience and risk management capabilities.Resilience emerged as a powerful driver of competitive advantage,reinforcing its role as a strategic capability rather than a reactive response to disruptions.Furthermore,innovation was shown to partially mediate the relationship between leadership and resilience,highlighting its function as the operational channel through which vision translates into capability.Originality/value-This study contributes to the literature by integrating the Resource-Based View(RBV)and Dynamic Capabilities(DC)framework into the context of railway supply chains.It is among the first to empirically validate the mediating role of innovation between leadership and resilience,offering both theoretical advancements and actionable strategies for building resilient and competitive railway systems. 展开更多
关键词 Railway supply chains RESILIENCE Risk management LEADERSHIP INNOVATION Competitive advantage
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Social Network and Value Chain Integration:Unraveling the Formation and Evolution of Meizhou Pomelo Industry Cluster in China
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作者 YANG Ren LIN Yuancheng ZHANG Xin 《Chinese Geographical Science》 2026年第2期239-255,共17页
The shift toward specialized and large-scale agricultural production has spurred the emergence of agricultural clusters as key forces of rural vitalization and sustainable development.This paper explored the formation... The shift toward specialized and large-scale agricultural production has spurred the emergence of agricultural clusters as key forces of rural vitalization and sustainable development.This paper explored the formation and evolution of Meizhou pomelo industry cluster in China,focusing on its role in restructuring rural socio-economic systems and integrating the whole value chains.Based on a case study employing qualitative methods such as in-depth interviews and participatory observation,the agricultural cluster evolution of Meizhou pomelo was categorized into three key phases of initial decentralization,self-organized scaling,and reorganized clustering.Geographical proximity and industrial agglomeration constitute the physical foundation,while vertical/horizontal linkages,technologic-al innovation,and policy support enhance competitiveness.Special mechanisms emerge through localized social networks,farmer co-operatives’activation,and cross-regional market expansion.The cluster’s impact is manifested in the shift from extensive to standard-ized and modernized production,diversified and flexible livelihood of farmers,and the integration of agriculture with industry and ser-vices.The development of the whole value chain based on agricultural cluster represents a critical pathway for achieving agricultural modernization,encompassing both internal and external value chain optimization.Through quality assurance systems,product diversi-fication strategies,operational efficiency improvements,and brand enhancement,these clusters amplify product value propositions and market competitiveness.This systemic approach facilitates supply-demand coordination,enables resource synergies,and optimizes eco-nomic returns across the horizontal and vertical value chain.This paper argues that agricultural clusters serve as strategic catalysts for sustainable rural development by reconstructing local production systems,fostering innovation ecosystems,and aligning agricultural modernization.It contributes to debates on rural vitalization by demonstrating how agricultural clustering can reconfigure rural areas as hubs of ecological modernization,rather than mere urban peripheries. 展开更多
关键词 agricultural cluster sustainable rural development agricultural systems social network whole value chain China
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CAFTA 3.0:A Catalyst for Indonesia's Economic Ascent
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作者 Antony Hardi 《China Report ASEAN》 2026年第2期32-33,共2页
The shift to the China-ASEAN Free Trade Area(CAFTA)3.0 version marked more than just a technical update to an existing trade agreement.It signaled a recalibration ofregional economic cooperation as global trade has in... The shift to the China-ASEAN Free Trade Area(CAFTA)3.0 version marked more than just a technical update to an existing trade agreement.It signaled a recalibration ofregional economic cooperation as global trade has increasingly become shaped by digitalization,sustainability concerns,and fragile supply chains.For Indonesia,Southeast Asia’s largest economy and one of its most demographically dynamic,CAFTA 3.0 offers a framework that could materially strengthen its long-term economic position,if navigated with care and intent. 展开更多
关键词 SUSTAINABILITY supply chains recalibration ofregional economic cooperation CAFTA regional economic cooperation Indonesia economic ascent DIGITALIZATION
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Synthesis,Structure,and Luminescent and Dielectric Properties of Two Novel 1D Chains Based on a T-Shaped Tripodal Ligand 4-(4,5-Dicarboxy-1H-imidazol-2-yl)pyridine Loxide 被引量:7
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作者 陈立庄 吉沁 丹媛媛 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2016年第11期1728-1735,共8页
Two 1D chain metal-organic framework complexes, {Co[(C10H5N3O5)- (H2O)2?H2O]}n (1) and {Cd[(C10H5N3O5)(H2O)2]}n (2), based on a T-shaped tripodal ligand 4-(4,5-dicarboxy- 1H-imidazol-2-yl) pyridine 1-ox... Two 1D chain metal-organic framework complexes, {Co[(C10H5N3O5)- (H2O)2?H2O]}n (1) and {Cd[(C10H5N3O5)(H2O)2]}n (2), based on a T-shaped tripodal ligand 4-(4,5-dicarboxy- 1H-imidazol-2-yl) pyridine 1-oxide (H3DCImPyO) have been reacted under hydrothermal conditions, and were characterized by single-crystal X-ray structure analysis, fluorescent analysis and thermal gravimetric analysis. According to single-crystal X-ray determination, complex 1 crystallizes in the monoclinic system, space group P21/n with a = 9.4930(13), b = 13.2024(18), c = 10.5203(14) A^°, β = 98.402(2)°, Z = 4, V = 1304.4(3)A^°3; and complex 2 crystallizes in the monoclinic system, space group C2/c with a = 13.557(3), b = 13.568(3), c = 6.7804(13) A^°, β = 105.095(2)°, Z = 4 and V = 1204.2(4) A^°3. Fluorescent analysis of complex 2 showed an intense emission band at 466 nm when the exciting radiation was set at 360 nm. Dielectric constants of complexes 1 and 2 were measured at different frequencies with temperature variation. 展开更多
关键词 1D chain coordination polymers hydrothermal condition dielectric constants FLUORESCENCE
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A Novel Inorganic-organic Hybrid Borate with Unique One-dimensional Infinite Aluminium-oxygen Chains 被引量:2
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作者 吴淑莉 童冠军 +1 位作者 李星 梁云霄 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2011年第1期139-143,共5页
A novel inorganic-organic hybrid borate,[Al2(fum)(H3BO3)(OH) 4]n·n(H3BO3) (1,H2fum = fumaric acid) ,has been synthesized and characterized by single-crystal X-ray diffraction,FTIR and elemental analysis... A novel inorganic-organic hybrid borate,[Al2(fum)(H3BO3)(OH) 4]n·n(H3BO3) (1,H2fum = fumaric acid) ,has been synthesized and characterized by single-crystal X-ray diffraction,FTIR and elemental analysis. Crystal data for compound 1: orthorhombic,space group Pnma,a = 14.108(3) ,b = 6.9412(14) ,c = 14.995(3)A,V = 1468.3(5)A^3,Z = 4,Mr = 359.72,Dc = 1.627 g/cm^3,μ = 0.254 mm^-1,F(000) = 736,the final R = 0.0492 and wR = 0.1650 with I 〉 2σ(I) . In compound 1,each Al^Ⅲ ion is coordinated by six oxygen atoms to adopt a distorted octahedral geometry. Both fumarate anion and the coordinated boric acid act as bidentate bridging ligands to link two neighboring Al^Ⅲ centers simultaneously. Each Al^Ⅲ ion is bridged by two μ2-hydroxyl ligands to construct an infinite wave-like [Al2(fum)(H3BO3)(OH) 4]n chain. These one-dimensional chains form hydrogen bonds with free boric acid molecules giving rise to a three-dimensional supramolecular network. 展开更多
关键词 BORATE inorganic-organic hybrid crystal structure aluminium-oxygen chain
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Head-on collision between two solitary waves in a one-dimensional bead chain 被引量:1
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作者 Fu-Gang Wang Yang-Yang Yang +1 位作者 Juan-Fang Han Wen-Shan Duan 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第4期327-334,共8页
The head on collision between two opposite propagating solitary waves is studied in the present paper both numerically and analytically.The interesting result is that no phase shift is observed which is different from... The head on collision between two opposite propagating solitary waves is studied in the present paper both numerically and analytically.The interesting result is that no phase shift is observed which is different from that found in other branches of physics.It is found that the maximum amplitude in the process of the head on collision is close to the linear sum of two colliding solitary waves. 展开更多
关键词 discrete system bead chain solitary waves
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The phase behaviour of single polyethylene chains with and without fixing one end 被引量:1
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作者 苏加叶 章林溪 《Chinese Physics B》 SCIE EI CAS CSCD 2008年第8期3115-3122,共8页
The phase behaviour of a single polyethylene chain is studied by using molecular dynamics simulations. A free chain and a chain with fixing one end are considered here, since the atomic force microscope (AFM) tip ca... The phase behaviour of a single polyethylene chain is studied by using molecular dynamics simulations. A free chain and a chain with fixing one end are considered here, since the atomic force microscope (AFM) tip can play a significant role in polymer crystallization in experiment. For a free chain, it is confirmed in our calculation that the polymer chain exhibits an extended coil state at high temperatures, collapses into a condensed state at low temperatures, i.e. the coil-to-globule transition that is determined by a high temperature shoulder of the heat capacity curve, and an additional liquid-to-solid transition that is described by a low temperature peak of the same heat curve. These results accord with previous studies of square-well chains and Lennard-Jones homopolymers. However, when one of the end monomers of the same chain is fixed the results become very different, and the chain cannot reach an extended coil-like state as a free chain does at high temperatures, i.e. there exists no coil-to-globule-like transition. These results may provide some insights into the influence of AFM tip when it is used to study the phase behaviour of polymer chains. If the interaction force between AFM tip and polymer monomers is strong, some monomers or one of them can be seen as being fixed by the tip, which is similar to our simulation model, and it is also found that AFM tip could induce polymer crystallization. 展开更多
关键词 molecular dynamics simulations coil-to-globule transition polyethylene chains
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Better Choice:Linear Long Chains Rather than Branched Ones to Improve Mechanical Performance of Polyethylene through Generating Shish-Kebabs 被引量:1
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作者 Lu-Feng Deng Xi-Xi Zhang +4 位作者 Dong Zhou Jian-Hua Tang Jun Lei Jun-Fang Li Zhong-Ming Li 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2020年第7期715-729,I0006,共16页
We utilized two structurally different long chains(linear and branched ultra-high molecular weight polyethylene)to reveal the dependence of flow-induced crystallization on long chain architecture,and prepared two bi-d... We utilized two structurally different long chains(linear and branched ultra-high molecular weight polyethylene)to reveal the dependence of flow-induced crystallization on long chain architecture,and prepared two bi-disperse systems of 98 wt%short chain and 2 wt%long chain.A flow field was applied to the bi-disperse polyethylene melt by a modified injection-molding machine,known as oscillation shear injection molding(OSIM).For the first time,the structural influence of long chains on flow-induced shish-kebab formation was systematically investigated.For the intermediate layer of OSIM samples,the branched long chains were better than the linear long chains at inducing shish-kebab formation,agreeing with the reported literatures,because the branches can maintain their oriented conformations longer.But unexpectedly,the reverse is the case for the core layer of OSIM samples,where the shear flow was much weaker than the intermediate layer.To understand the unexpected phenomenon,the lifetime of shishes induced by different long chains was compared.Result demonstrated that the linear-induced shishes possessed higher thermal stability than the branched-induced ones so that the linear-induced shishes could survive in the core layer of OSIM samples.Additionally,unlike other methods for flow-induced crystallization,OSIM could create samples for measuring mechanical properties,and thus offer the chance to reveal the relationship between structure and performance.The mechanical results demonstrated that both long chains remarkably enhanced the mechanical properties because of the significant promoting effect of long chains and intense flow fields on shish-kebab formation.However,the linear long chains induced more stable and flawless shishes with higher tensile strength and modulus(80.4 and 1613.5 Mpa,respectively)than the branched ones(74.4 and 1489.3 Mpa).Our research not only helps elucidate the mechanism of shish-kebab formation but also provides a better choice to reinforce polymers by adding long chains with suitable structure. 展开更多
关键词 POLYETHYLENE Crystallization Shear-induced Long chain Short chain
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Design,Synthesis and Crystal Structure of Two One-dimensional Zigzag Chain-like Compounds 被引量:1
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作者 秦政涛 盛天录 +5 位作者 胡胜民 项生昌 傅瑞标 王欣 沈超君 吴新涛 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2008年第8期1013-1019,共7页
Two one-dimensional chain-like cyanide-bridged compounds, [Fe(Phen)2(CN)2Ni(Cyclam)](ClO4)2·DMF-2H2O 1 (Cyclam = 1,4,8,11-tetraaza-cyclotetradecane, Phen = 1,10-phenanthroline, and DMF = N,N-dimethylform... Two one-dimensional chain-like cyanide-bridged compounds, [Fe(Phen)2(CN)2Ni(Cyclam)](ClO4)2·DMF-2H2O 1 (Cyclam = 1,4,8,11-tetraaza-cyclotetradecane, Phen = 1,10-phenanthroline, and DMF = N,N-dimethylformamide) and [Fe(Phen)2(CN)2Zn(Cyclam)](PF6)2·CH3CN 2, were prepared by the reaction of [Fe(Phen)2(CN)2]·2H2O with M(Cyclam)^2+ (M = Ni, Zn). In complexes 1 and 2, the metal atoms are connected alternatively with CN groups. X-ray structure and IR analyses for 1 and 2 were performed. Structure analysis revealed that both complexes are centrosymmetric and the geometry around each metal atom is an octahedron. The two complexes crystallize in triclinic with space group of P^1-. For 1, a = 10.439(4), b = 14.976(7), c = 15.914(8)A,α = 83.168(15), β = 74.338(15), γ = 78.023(15)°, V = 2338.3(18)A^3, Z = 2, Mr = 1035.37, Dc = 1.471 g/cm^3, F(000) = 1076,μ = 0.895 mm^-1, the final R = 0.0616 and wR = 0.1414 for 5849 observed reflections (1 〉 2σ(I)). For 2, a = 9.656(6), b = 15.404(9), c = 15.822(10)A, α = 78.68(2), β= 78.917(19), γ = 77.15(2)°, V = 2223(2)A^3, Z = 2, Mr = 1064.87, Dc = 1.587 g/cm^3, F(000) = 1078,μ = 1.032 mm^-1, the final R = 0.0672 and wR = 0.1595 for 6819 observed reflections (I 〉 2σ(I)). 展开更多
关键词 CN bridge iron crystal structure zigzag chain π-π stacking
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Oil-gas reservoir lithofacies stochastic modeling based on one-to three-dimensional Markov chains 被引量:2
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作者 WANG Zhi-zhong HUANG Xiang LIANGYu-ru 《Journal of Central South University》 SCIE EI CAS CSCD 2018年第6期1399-1408,共10页
Stochastic modeling techniques have been widely applied to oil-gas reservoir lithofacies.Markov chain simulation~however~is still under development~mainly because of the difficulties in reasonably defining conditional... Stochastic modeling techniques have been widely applied to oil-gas reservoir lithofacies.Markov chain simulation~however~is still under development~mainly because of the difficulties in reasonably defining conditional probabilities for multi-dimensional Markov chains and determining transition probabilities for horizontal strike and dip directions.The aim of this work is to solve these problems.Firstly~the calculation formulae of conditional probabilities for multi-dimensional Markov chain models are proposed under the full independence and conditional independence assumptions.It is noted that multi-dimensional Markov models based on the conditional independence assumption are reasonable because these models avoid the small-class underestimation problem.Then~the methods for determining transition probabilities are given.The vertical transition probabilities are obtained by computing the transition frequencies from drilling data~while the horizontal transition probabilities are estimated by using well data and the elongation ratios according to Walther's law.Finally~these models are used to simulate the reservoir lithofacies distribution of Tahe oilfield in China.The results show that the conditional independence method performs better than the full independence counterpart in maintaining the true percentage composition and reproducing lithofacies spatial features. 展开更多
关键词 independence assumption Markov chain reservoir lithofacies small-class underestimation transitionprobability
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Coupled Band Gap Solitons in One-Dimensional Alternating Heisenberg Ferromagnetic Chains 被引量:1
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作者 ZHU Shan-Hua HUANG Guo-Xiang 《Communications in Theoretical Physics》 SCIE CAS CSCD 2001年第10期477-482,共6页
The dynamics of coupled band gap solitons in one-dimensional Heisenberg ferromagnetic chains with bond alternation is considered analytically. Using the method of multiple scales the nonlinear coupled-mode equations (... The dynamics of coupled band gap solitons in one-dimensional Heisenberg ferromagnetic chains with bond alternation is considered analytically. Using the method of multiple scales the nonlinear coupled-mode equations (i.e.Manakov equations) for the upper cutoff mode of acoustic band and the lower cutoff mode of optical band are derived under the quasi-discreteness approximation. Due to the cross-phase modulation the type of soliton excitations may be changed and the vibrating frequencies of these soliton excitations may locate within or outside the gap of magnon frequency bands. 展开更多
关键词 gap solitons HEISENBERG FERROMAGNETIC chains
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Syntheses,Structures,and Photoluminescent Properties of Two Zn(Ⅱ)Coordination Polymers with Helical Chains Structures 被引量:1
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作者 徐伏 李付安 +1 位作者 杨维春 李松田 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2017年第5期831-840,共10页
Two novel coordination polymers with helical chains, {[Zn(L)(H2O)]·H2O}n(1) and {[Zn(L)(p-bix)]·3.5H2O}n(2), where H2 L = 5-(4-hydroxypyridinium-1-ylmethyl) isophthalic acid and p-bix = 1,4-bis... Two novel coordination polymers with helical chains, {[Zn(L)(H2O)]·H2O}n(1) and {[Zn(L)(p-bix)]·3.5H2O}n(2), where H2 L = 5-(4-hydroxypyridinium-1-ylmethyl) isophthalic acid and p-bix = 1,4-bis(imidazol-1-ylmethyl)benzene, have been hydrothermally synthesized, and charac-terized by elemental analysis, powder X-ray diffraction(PXRD), IR, thermal gravimetric analyses(TGA) and also by single-crystal X-ray diffraction. Both complexes 1 and 2 crystallize inmonoclinic, space group P21/c. Compound 1 displays a two-dimensional(2D) structure with two distinct types of helical chains; 2 shows a layered coordination polymer with two types of helical chains and features an interesting 2D→3D interdigitated architecture. Meanwhile, the luminescent properties of 1 and 2 have also been investigated in detail. 展开更多
关键词 ZINC 5-(4-hydroxypyridinium-l-ylmethyl)isophthalic acid coordination polymer helical chains
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Literature Review on Network Design Problems in Closed Loop and Reverse Supply Chains 被引量:1
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作者 Muthusamy Aravendan Ramasamy Panneerselvam 《Intelligent Information Management》 2014年第3期104-117,共14页
The productivity of an organization is very much affected by non-value adding activity like logistics, which moves the resources from suppliers to factory, raw materials/semi-finished items within the factory and fini... The productivity of an organization is very much affected by non-value adding activity like logistics, which moves the resources from suppliers to factory, raw materials/semi-finished items within the factory and finished goods from factory to customers via a designated distribution channel called as forward logistics. In some cases, parts of the products such as automobiles, computers, cameras, mobile phones, washing machines, refrigerators, garments, footwear and empty glass bottles of beverages, etc. will be brought back to the factories as a product recovery strategy through reverse logistics network which is integrated in a sustainable closed loop supply chain network. So, it is highly essential to optimize the movement of the items in the reverse logistics network. This paper gives a comprehensive review of literature of the design of networks for the reverse logistics as well as for the reverse logistics coupled with forward logistics. The contributions of the researchers are classified into nine categories based on the methods used to design the logistics network. 展开更多
关键词 Supply CHAIN Network Design CLOSED-LOOP REVERSE LOGISTICS Models HEURISTICS Algorithms
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Macroscopic Electromagnetic Cooperative Network‑Enhanced MXene/Ni Chains Aerogel‑Based Microwave Absorber with Ultra‑Low Matching Thickness 被引量:9
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作者 Fei Pan Yanping Rao +7 位作者 Dan Batalu Lei Cai Yanyan Dong Xiaojie Zhu Yuyang Shi Zhong Shi Yaowen Liu Wei Lu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2022年第8期283-299,共17页
Electromagnetic cooperative strategy has been presented as a mainstream approach that can effectively optimize the matching thickness of dielectric loss dominant system.However,it is still challenging for dielectric–... Electromagnetic cooperative strategy has been presented as a mainstream approach that can effectively optimize the matching thickness of dielectric loss dominant system.However,it is still challenging for dielectric–magnetic loss coexisting-type absorber to develop electromagnetic wave(EMW)performance with ultra-low matching thickness(≤1 mm).Breaking the limitation of traditional electromagnetic response at microscopic/mesoscopic scale,a ficus microcarpa-like magnetic aerogel with macroscopical electromagnetic cooperative effect was fabricated through highly oriented self-assembly engineering.The highly oriented Ni chains with unique macroscopic morphology(~1 cm in length)were achieved via a special magnetic field-induced growth.Strong magnetic coupling was observed in the Ni chains confirmed by the micromagnetic simulation.The deductive calculation validates that maintaining high value of electromagnetic parameters at high frequencies is the prerequisites of ultrathin absorber.The electromagnetic cooperative networks with uninterrupted and dual pathways spread through the entire aerogel skeleton,resulting in the impressive permittivity even at high frequencies.Consequently,the aerogel exhibits a remarkable EMW performance at an ultrathin thickness of 1 mm.Thus,based on the modulation of electromagnetic parameters,this work proposed a macroscopic ordered structure with the electromagnetic cooperative effect useful to develop a suitable strategy for achieving ultrathin EMW absorbers. 展开更多
关键词 Electromagnetic wave absorption Ti_(3)CNT_(x)MXene Highly oriented Ni chains Electromagnetic cooperation Magnetic coupling
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Parameterless Pruning Algorithms for Similarity-Weight Network and Its Application in Extracting the Backbone of Global Value Chain 被引量:2
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作者 Lizhi Xing Yu Han 《Journal of Data and Information Science》 CSCD 2022年第1期57-75,共19页
Purpose:With the availability and utilization of Inter-Country Input-Output(ICIO)tables,it is possible to construct quantitative indices to assess its impact on the Global Value Chain(GVC).For the sake of visualizatio... Purpose:With the availability and utilization of Inter-Country Input-Output(ICIO)tables,it is possible to construct quantitative indices to assess its impact on the Global Value Chain(GVC).For the sake of visualization,ICIO networks with tremendous low-weight edges are too dense to show the substantial structure.These redundant edges,inevitably make the network data full of noise and eventually exert negative effects on Social Network Analysis(SNA).In this case,we need a method to filter such edges and obtain a sparser network with only the meaningful connections.Design/methodology/approach:In this paper,we propose two parameterless pruning algorithms from the global and local perspectives respectively,then the performance of them is examined using the ICIO table from different databases.Findings:The Searching Paths(SP)method extracts the strongest association paths from the global perspective,while Filtering Edges(FE)method captures the key links according to the local weight ratio.The results show that the FE method can basically include the SP method and become the best solution for the ICIO networks.Research limitations:There are still two limitations in this research.One is that the computational complexity may increase rapidly while processing the large-scale networks,so the proposed method should be further improved.The other is that much more empirical networks should be introduced to testify the scientificity and practicability of our methodology.Practical implications:The network pruning methods we proposed will promote the analysis of the ICIO network,in terms of community detection,link prediction,and spatial econometrics,etc.Also,they can be applied to many other complex networks with similar characteristics.Originality/value:This paper improves the existing research from two aspects,namely,considering the heterogeneity of weights and avoiding the interference of parameters.Therefore,it provides a new idea for the research of network backbone extraction. 展开更多
关键词 Inter-Country Input-Output Table Global Production System Global Value Chain Network Backbone Extraction
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Antibiotic susceptibility and molecular characterization of resistance genes among Escherichia coli and among Salmonella subsp. in chicken food chains 被引量:1
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作者 Yith Vuthy Kruy Sun Lay +2 位作者 Heng Seiha Alexandra Kerleguer Awa Aidara-Kane 《Asian Pacific Journal of Tropical Biomedicine》 SCIE CAS 2017年第7期670-674,共5页
Objective: To investigate the occurrence of resistance genes among Escherichia coli(E. coli) and Salmonella subsp. isolated in chicken food chains in Phnom Penh, 2012–2013.Methods: Six hundred eighty two E. coli and ... Objective: To investigate the occurrence of resistance genes among Escherichia coli(E. coli) and Salmonella subsp. isolated in chicken food chains in Phnom Penh, 2012–2013.Methods: Six hundred eighty two E. coli and 181 Salmonella Albany, Corvallis, and Kentucky strains were examined for susceptibilities to eight antimicrobials and following resistance genes were identified by PCR: blaTem, Str A, aad A, sul1, sul2, gyr A, Tet(A), and Tet(B).Results: E. coli presented high resistances to tetracycline, amoxicillin, and sulfamethoxazole(63.1%–76.1%). Salmonella Albany and Salmonella Kentucky traduced high resistance percentages to amoxicillin, tetracycline, sulfamethoxazole, and nalidixic acid(84.6%–100%). Among amoxicillin-resistant isolates, blaTemgenes were observed for 62% of E. coli isolates and 20% of 65 Salmonella Kentucky. The Str A gene was prevalent in 36% of 331 aminoglycoside-resistant E. coli and 90% of 40 aminoglycoside-resistant Salmonella Corvallis. The sul2 gene was predominant among sulfamethoxazole-resistant isolates, for 56% of 431 E. coli and 53% of 66 Salmonella Corvallis; the sul1 gene was observed in 54% of Salmonella Albany. The Tet(A) resistance gene was prevalent in E.coli(86%), Salmonella Corvallis(82%), Salmonella Kentucky(84%). High percentages of gyr A genes observed among nalidixic-acid resistant E. coli(91%), Salmonella Albany(92%), Salmonella Corvallis(75%) and Salmonella Kentucky(85%).Conclusions: Important occurrences of resistance gene were observed among E. coli and Salmonella in chicken food chains in Cambodia. 展开更多
关键词 Chicken food chains Escherichia coli SALMoneLLA Resistance gene Susceptibility
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