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Economical operation of Baosteel's oxygen generating system
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作者 ZHU Huizhong GAO Yuan GU Yunjie MA Yi 《Baosteel Technical Research》 CAS 2009年第3期27-31,共5页
Baosteel's 60000 m^3/h air separation unit (ASU) is the largest oxygen generating system in China. The operational cost of such a giant system is very high. How to reduce the operational cost is a critical issue. T... Baosteel's 60000 m^3/h air separation unit (ASU) is the largest oxygen generating system in China. The operational cost of such a giant system is very high. How to reduce the operational cost is a critical issue. This paper discusses the system's characteristics,the current operational status and the difficulties in reducing the cost,and analyzes relevant indicators, such as the technical and economical indicators of individual units and systems as well as the indicators concerning the costs. The relationship between the cost and each economical indicator and measures to optimize an economical operation of the oxygen generating system are also discussed in this paper. 展开更多
关键词 large-scale air separation unit oxygen generating system oxygen dispersion rate
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Quantifying the contribution of reactive nitrogen loss through anaerobic ammonium oxidation in global wetlands and oxygen minimum zones
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作者 Bangrui Lan Shuci Liu +4 位作者 Shanyun Wang Yanting Zhang Longbin Yu Chunlei Liu Guibing Zhu 《Journal of Environmental Sciences》 2026年第2期355-363,共9页
Anaerobic ammonium oxidation(anammox)plays a vital role in the global nitrogen cycle by mitigating reactive nitrogen.In recent years,its ecological importance has drawn increasing attention.Despite its widespread occu... Anaerobic ammonium oxidation(anammox)plays a vital role in the global nitrogen cycle by mitigating reactive nitrogen.In recent years,its ecological importance has drawn increasing attention.Despite its widespread occurrence,the distribution and quantitative contribution of anammox to global nitrogen loss remain unclear.We collected 390 reported anammox activity measurements which were obtained using 15N isotope tracing techniques and analyzed anammox rate and environmental factors including soil/sediment and water property using generalized additive models(GAMs).Moreover,based on the division of the anammox activity region,we estimated anammox-driven nitrogen loss across different ecosystems including wetlands and oxygen minimum zones(OMZs)ecosystems.Our findings revealed that soil moisture content was the most significant predictor of anammox activity in wetlands ecosystems.Paddy fields contributed 51%of anammox-driven nitrogen loss(32.0 Tg N/yr),followed by rivers/lakes(29%)and wetlands(20%).Asia emerged as the dominant region for anammoxdriven nitrogen loss(30.7 Tg N/yr),with paddy fields making a substantial contribution.North America was the second-largest contributor(25.4 Tg N/yr),with rivers/lakes being the main sources of nitrogen loss.In OMZs ecosystems,nitrate and dissolved oxygen were key factors influencing anammox rates.OMZs were hotspots for anammox,with peak activity at 300 m depth and nitrogen loss totaling 68.6 Tg N/yr,mostly between 100 and 500 m depths.This study underscores the critical role of anammox in global nitrogen cycling and offers a basis for environmental nitrogen management through predictive anammox modeling. 展开更多
关键词 Anaerobic ammonium oxidation Nitrogen loss generalized additive model WETLANDS oxygen minimum zones
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A review on chemical oxygen supply technology within confined spaces: Challenges, strategies, and opportunities toward chemical oxygen generators(COGs) 被引量:1
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作者 Jian-guo Liu Long-zhe Jin +3 位作者 Na Gao Sheng-nan Ou Shu Wang Wei-xiang Wang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2019年第8期925-937,共13页
Chemical oxygen generators(COGs)have been used worldwide in confined spaces as an emergency oxygen supply technology,mainly because they are independent and have a long shelf life.However,a number of challenges relate... Chemical oxygen generators(COGs)have been used worldwide in confined spaces as an emergency oxygen supply technology,mainly because they are independent and have a long shelf life.However,a number of challenges related to COGs remain unsolved,and a literature review of the current state of the technology is needed.First,the present article summarizes the basic information and applications of COGs,including their oxygen production mechanism,components,forming technology,and ignition system.Four current challenges encountered in applying COGs are discussed,along with the strategies adopted thus far to solve these problems,as found in the published literature.The literature survey reveals that,although much effort has been devoted to controlling the oxygen production rate and the heat output of COGs,the mechanism of producing toxic gases remains unclear and a reliable and safe ignition system has not been fully developed.Finally,future opportunities in the development of COGs are briefly listed. 展开更多
关键词 CHEMICAL oxygen generators oxygen supply TECHNOLOGY thermal DECOMPOSITION CATALYTIC metal fuel combustion
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O_(2)-generating multifunctional polymeric micelles for highly efficient and selective photodynamic-photothermal therapy in melanoma 被引量:2
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作者 Yu Qin Mingyang Huang +3 位作者 Chenlu Huang Hannah LPerry Linhua Zhang Dunwan Zhu 《Chinese Chemical Letters》 SCIE CAS CSCD 2024年第7期394-399,共6页
Photothermal therapy(PTT)and photodynamic therapy(PDT)have received tremendous attention owing to their great potential for tumor treatment.However,two main issues hamper the antitumor performance of PDT:overexpressio... Photothermal therapy(PTT)and photodynamic therapy(PDT)have received tremendous attention owing to their great potential for tumor treatment.However,two main issues hamper the antitumor performance of PDT:overexpression of glutathione(GSH)in tumors,which consumes PDT-induced reactive oxygen species(ROS),and hypoxia within the tumor microenvironment.The drawbacks of PTT include uneven temperature distribution and the upregulation of the heat-shock proteins in tumors,both of which result in ineffective treatment.To address these issues,a MnO_(2)doped nano-delivery system(HTIM-PMs)was synthesized by one-step self-assembly of disulfide bond bridged copolymers for indocyanine green(ICG)and MnO_(2)loading.The surface of polymeric micelles was layered with hyaluronan(HA)and transactivator(TAT)peptides to improve active targeting and increase cell penetration.After internalization,HTIM-PMs showed responsiveness to the tumor microenvironment(acid pH,high glutathione,high H_(2)O_(2)).Breaking the disulfide bond reduced the intratumoral GSH level and simultaneously released the MnO_(2)and ICG.The released MnO_(2)further reduced the GSH level and promoted O_(2)generation,thus enhancing the PDT effect.The PTT-mediated hyperthermia accelerated blood flow,which is beneficial for O_(2)distribution,and promotes ROS diffusion.These PTT-mediated adjuvant effects further overcame the limitations of PDT and the robust PDT effect in turn compensated for the deficiency of PTT.This promising platform exhibited a significant improvement in the PTT-PDT cancer treatment strategy compared to previously reported nanostructures. 展开更多
关键词 Photodynamic therapy Photothermal therapy oxygen generating One-step self-assembly Stimuli-responsive nanoparticles
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The effects of PaCO_2 on balance of cerebral oxygen supply and consumption during intravenous general anesthesia 被引量:2
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作者 陈绍洋 王强 +5 位作者 曾祥龙 董海龙 胡文能 曾毅 张玉勤 熊利泽 《Journal of Medical Colleges of PLA(China)》 CAS 1999年第4期274-277,共4页
Objective: To evaluate the effects of various degrees of hyperventilation on balance of cerebral oxygensupply and consumption during intravenous general anesthesia with jugular venous oxygen saturation monitoringMetbo... Objective: To evaluate the effects of various degrees of hyperventilation on balance of cerebral oxygensupply and consumption during intravenous general anesthesia with jugular venous oxygen saturation monitoringMetbods: Sixty-six patients with supratentorial tumor undergoing intravenous general anesthesia for brain surgerywere randomly divided into three groups. In group Ⅰ, Ⅱ and Ⅲ, end-tidal pressure of Co2(PETCO2) were maintained at 3. 5, 4. 0 and 4. 5 kPa respectively. Radial arterial blood samples and jugular bulb blood samples weretaken synchronously at 60 min after hyperventilation to measure jugular venous oxygen saturation (SjvO2), cerebral extraction of oxygen (CEO2) and cerebral arteriovenous oxygen content difference (AVDO2) were calculatedResults: In group Ⅰ after hyperventilation, SjvO, and jugular venous oxygen content (CjvO2) were decreasedmarkedly while CEO2 was increased significantly, which was different significantly compared with the baseline andcorresponding value in group Ⅱ and Ⅲ (P<0. 05). After hyperventilation in group, and, SjvO2 CjvO2, CEO2and AVDO, remained unchanged. Conclusion: This study shows that sustained excessive hyperventilation (PETCO23.5 kPa) may account for the less favorable cerebral oxygen supply and consumption balance and maintained PETCO, at 4. 0~4. 5 kPa was optimal hyperventilation for brain surgery anesthesia. 展开更多
关键词 INTRAVENOUS general anesthesia HYPERVENTILATION JUGULAR VENOUS oxygen saturation CEREBRAL oxygen supply and consumption balance
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Oxidation of Dibenzothiophene in Model Diesel Using Hydroperoxide Generated via In-Situ Reaction of Octane with Oxygen 被引量:1
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作者 Guo Erliang Li Jianxin +4 位作者 Huang Xiaoqiao Duan Yongshen Zhang Lingcong Yan Lijun Lu Shuxiang 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2018年第1期116-122,共7页
The potential of carrying out oxidative desulfurization(ODS) using oxygen as an oxidant was explored in this work. n-Octane firstly reacted with oxygen to produce hydroperoxides in-situ, which were then used as oxidan... The potential of carrying out oxidative desulfurization(ODS) using oxygen as an oxidant was explored in this work. n-Octane firstly reacted with oxygen to produce hydroperoxides in-situ, which were then used as oxidants to oxidize the dibenzothiophene(DBT) in the absence of catalysts. The hydroperoxides generated in-situ were effective in oxidizing DBT to its corresponding dibenzothiophene sulfone(DBTO_2) which was characterized by FT-IR and ~1H-NMR. The removal rate of DBT could reached 98.4% under conditions covering a temperaure of 140℃, a rection duration of 4 h, and an oxygen partial pressure of 0.4 MPa. The influences of different hydrocarbon components in diesel on DBT removal were investigated. The results showed that cyclohexane and n-dodecane had no effect on the removal of DBT, but xylene had a slight negative effect on DBT removal. A possible oxidation mechanism was proposed and the concentration of hydroperoxides in both O_2-oxidized octane and model diesel were detected. 展开更多
关键词 oxidative desulfurization oxygen DIBENZOTHIOPHENE HYDROPEROXIDES generATED in-situ
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Effect of Inert Gases on Ozone Generation Using Dielectric Barrier Discharge in Oxygen 被引量:2
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作者 WEI Linsheng TAN Zhihong 《高电压技术》 EI CAS CSCD 北大核心 2012年第7期1608-1612,共5页
关键词 惰性气体 电子能量 臭氧 电离能
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Experimental study on ceramic membrane technology for onboard oxygen generation 被引量:1
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作者 Jiang Dongsheng Bu Xueqin +4 位作者 Sun Bing Lin Guiping Zhao Hongtao Cai Yan Fang Ling 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2016年第4期863-873,共11页
The ceramic membrane oxygen generation technology has advantages of high concentration of produced oxygen and potential nuclear and biochemical protection capability. The present paper studies the ceramic membrane tec... The ceramic membrane oxygen generation technology has advantages of high concentration of produced oxygen and potential nuclear and biochemical protection capability. The present paper studies the ceramic membrane technology for onboard oxygen generation. Comparisons are made to have knowledge of the effects of two kinds of ceramic membrane separation technologies on oxygen generation, namely electricity driven ceramic membrane separation oxygen generation technology (EDCMSOGT) and pressure driven ceramic membrane separation oxygen generation technology (PDCMSOGT). Experiments were conducted under different temperatures, pressures of feed air and produced oxygen flow rates. On the basis of these experiments, the flow rate of feed air, electric power provided, oxygen recovery rate and concentration of produced oxygen are compared under each working condition. It is concluded that the EDCMSOGT is the oxygen generation means more suitable for onboard conditions. (C) 2016 Chinese Society of Aeronautics and Astronautics. Production and hosting by Elsevier Ltd. 展开更多
关键词 Ceramic membrane Electricity driven EXPERIMENT Onboard oxygen generation Pressure driven
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The preparation of high performance carbon electrode in electrochemical oxygen generator
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作者 LUO Zhi-yong CHEN Mao-bin ZHANG Sheng-tao 《Journal of Chemistry and Chemical Engineering》 2008年第4期57-61,70,共6页
The electrochemical oxygen generator has been popularized for its virtues, such as high oxygen concentration output, electricity saving, easy operation and maintenance. The key part of electrochemical oxygen generator... The electrochemical oxygen generator has been popularized for its virtues, such as high oxygen concentration output, electricity saving, easy operation and maintenance. The key part of electrochemical oxygen generator is carbon electrode used as the cathode. The preparation of high performance carbon electrode was introduced in this paper. The properties of carbon electrode was tested. The electrochemical oxygen generator using carbon electrode as the cathode was prepared. The oxygen concentration and flow of this machine is hi,yher thnn |hal of others in china. 展开更多
关键词 the electrochemical oxygen generator carbonelectrode PREPARATION
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Evaluation of Pressure of Arterial Oxygen by Age in Supine Position during General Anesthesia
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作者 Kenichi Satoh Ayako Ohashi +3 位作者 Miho Kumagai Masahito Sato Akiyoshi Kuji Shigeharu Joh 《Open Journal of Anesthesiology》 2015年第3期37-42,共6页
Background: The concentration of supplemental O2 should be measured during general anesthesia to determine whether patients’ pressure of arterial oxygen (PaO2) is correct. Nevertheless, we do not know standard value ... Background: The concentration of supplemental O2 should be measured during general anesthesia to determine whether patients’ pressure of arterial oxygen (PaO2) is correct. Nevertheless, we do not know standard value of PaO2 by age in supine position during general anesthesia. In this study, we evaluated the PaO2 by age at 33% or 40% O2 concentration. Materials and Methods: We retrospectively reviewed the anesthetic charts of 660 patients who were received general anesthesia from January 2001 to December 2013. Patients were divided into two groups by concentration of fraction of inspiratory oxygen: group at 33% or 40%. Second, patients aged 16 - 85 years were classified into 7 groups by age with each group covering one decade. Results: The PaO2 was 185.1 ± 19.2 mmHg (33%) and 209.8 ± 19.8 mmHg (40%) at age 16 - 25 years, 178.7 ± 23.6 mmHg (33%) and 202.7 ± 26.0 mmHg (40%) at age 26 - 35 years, 165.8 ± 30.6 mmHg (33%) and 188.9 ± 22.2 (40%) mmHg at age 36 - 45 years, 154.1 ± 22.8 mmHg (33%) and 181.8 ± 19.2 (40%) mmHg at age 46 - 55 years, 153.7 ± 21.7 mmHg (33%) and 177.5 ± 18.1 mmHg (40%) at age 56 - 65 years, 152.2 ± 24.5 mmHg and 171.0 ± 22.1 mmHg at age 66 - 75 years, and 154.6 ± 24.3 mmHg and 174.1 ± 20.2 mmHg at age 76 - 85 years. Conclusion: The PaO2 tended to decrease with age at both 33% and 40% O2 concentration. 展开更多
关键词 PRESSURE of ARTERIAL oxygen SUPINE POSITION Age general ANESTHESIA
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Synthesis,Characterization,and Linear and Nonlinear Optical Properties of Phenylene-vinylene Based Chromophores for Singlet Oxygen Generation
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作者 王淑容 汤昌泉 郑庆东 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2013年第11期1687-1695,共9页
A series of symmetrical and unsymmetrical phenylene-vinylene (PV) based chro- mophores with the molecular configuration of donor-π-donor (D-g-D) were prepared and characterized. Iodine was first introduced into t... A series of symmetrical and unsymmetrical phenylene-vinylene (PV) based chro- mophores with the molecular configuration of donor-π-donor (D-g-D) were prepared and characterized. Iodine was first introduced into the Jr-conjugation backbone of the PV based chromophores in order to study the heavy atom effect on their linear absorption, two-photon absorption (TPA) properties, as well as singlet oxygen generation properties. TPA cross-sections of these chromophores were investigated by using the two-photon excited fluorescence method. The unsymmetrical chromophores were found to have larger TPA cross-section values compared to their symmetrical counterparts. For one of the unsymmetrical chromophores with the iodine incorporation, a large TPA cross section value with quenched emission was found. The decreased fluorescence quantum yield of a molecule can be ascribed to the increased intersystem crossing, which is favorable for enhancing the singlet oxygen generation. Therefore, the unsymmetrical PV based chromophores with heavy atom incorporation are promising singlet oxygen sensitizers for the photodynamic therapy application. 展开更多
关键词 two-photon absorption phenylene-vinylene based chromophore singlet oxygen generation heavy atom effect
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Evaluation of Partial Pressure of Arterial Oxygen in Obese Patients in Supine Position during General Anesthesia
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作者 Kenichi Satoh Mami Chikuda +3 位作者 Ayako Ohashi Miho Kumagai Akiyoshi Kuji Shigeharu Joh 《Open Journal of Anesthesiology》 2015年第5期85-92,共8页
Background: Anesthetists should measure the concentration of supplemental oxygen to determine whether patients’ partial pressure of arterial oxygen (PaO2) is correct during general anesthesia. However, the standard P... Background: Anesthetists should measure the concentration of supplemental oxygen to determine whether patients’ partial pressure of arterial oxygen (PaO2) is correct during general anesthesia. However, the standard PaO2 value in obese patients in the supine position is unknown. We evaluated the PaO2 with respect to the Broca-Katsura obesity index. Materials and Methods: From January 2001 to December 2013, we evaluated 472 patients aged ≥16 years old that underwent general anesthesia in the supine position. The anesthetic charts of 472 patients with an American Society of Anesthesiologists physical status of I or II were retrospectively reviewed to investigate the PaO2. Results: In patients aged 16 to 2 was 165.7 ± 25.6 mmHg at a Broca-Katsura index of 2 was 152.1 ± 23.8 mmHg at a Broca-Katsura index of 2 tended to decrease with age from 16 to 2 tended to decrease with age from 16 to <65 years at a Broca-Katsura index of 20% to <40%. 展开更多
关键词 ARTERIAL Partial Pressure of oxygen Broca-Katsura Index general ANESTHESIA OBESITY SUPINE Position
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右美托咪定对食管癌根治手术全麻患者苏醒期并发症及肺氧合功能的影响
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作者 李彬 朱洁芳 +1 位作者 董真真 赵俊 《实用癌症杂志》 2026年第2期191-194,共4页
目的分析右美托咪定对食管癌根治手术全麻患者苏醒期并发症及肺氧合功能的影响。方法选择80例食管癌患者,按随机数字表法分为对照组(丙泊酚)及观察组(右美托咪定),各40例。比较2组围术期相关指标、手术不同时间点肺氧合指数、手术前后... 目的分析右美托咪定对食管癌根治手术全麻患者苏醒期并发症及肺氧合功能的影响。方法选择80例食管癌患者,按随机数字表法分为对照组(丙泊酚)及观察组(右美托咪定),各40例。比较2组围术期相关指标、手术不同时间点肺氧合指数、手术前后炎症因子水平以及苏醒期并发症发生情况。 结果2组手术时间、失血量、补液量比较,差异无统计学意义(P>0.05);2组肺氧合指数均随手术时间的推移逐渐下降,T0>T1>T2>T3,且观察组T1~T3肺氧合指数与对照组比较,差异有统计学意义(P<0.05)。术后2组炎症因子水平均高于手术前,但观察组炎症因子水平低于对照组(P<0.05)。观察组苏醒期并发症发生率为7.50%,显著低于对照组的25.00%(P<0.05)。结论右美托咪定可有效减少食管癌根治手术全麻患者苏醒期的并发症,保护肺氧合功能,减轻炎症反应,值得临床推广。 展开更多
关键词 右美托咪定 食管癌 全麻 并发症 肺氧合功能
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不同下垫面-气象条件下小流域分层径流混合产流机理解析
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作者 马昱斐 马啸赞 +4 位作者 陈璐 廖爱民 刘翠善 鞠琴 王国庆 《水资源保护》 北大核心 2026年第1期232-242,共11页
以南大洼流域为研究对象,基于水文地貌特征将流域径流划分为地表径流(SR)、地下0~50 cm径流(SSR50)及地下50~100 cm径流(SSR100),通过典型降雨事件下各水体(降雨、土壤水、地下水、分层径流)氢氧同位素-水化学指标测试,结合高分辨率水... 以南大洼流域为研究对象,基于水文地貌特征将流域径流划分为地表径流(SR)、地下0~50 cm径流(SSR50)及地下50~100 cm径流(SSR100),通过典型降雨事件下各水体(降雨、土壤水、地下水、分层径流)氢氧同位素-水化学指标测试,结合高分辨率水文气象监测数据,解析了不同下垫面-气象条件下的分层径流形成机制,并耦合水文示踪技术与端元混合模型,揭示了各水源对分层径流贡献比例的动态变化。结果表明:不同下垫面-气象条件下分层径流产流机制及水分来源差异显著,湿润-多段式降雨模式下多呈超渗和蓄满的混合产流模式(SR大于SSR100大于SSR50),湿润-短时强降雨模式下以地表的超渗产流为主导(SR大于SSR100大于SSR50),干旱-连续型降雨模式下则由超渗向蓄满产流过渡(SSR100大于SR大于SSR50);分层径流水分来源整体呈现沿深度增加方向,事件水贡献比例降低、事件前水贡献比例升高的特征;SSR50作为径流分层的过渡层,其水分来源受下垫面条件影响显著,呈现“主导-均衡”的动态转换特征。 展开更多
关键词 氢氧同位素 分层径流 端元混合模型 径流分割 产流机理 南大洼流域
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基于风电制氧的纯氧燃烧减碳系统多场景容量优化配置
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作者 丁英 王维庆 +3 位作者 李笑竹 丁明 闫文涛 高帅 《太阳能学报》 北大核心 2026年第1期662-673,共12页
为提高区域电网新能源消纳能力、降低碳排放量与碳捕集能耗,构建基于风电制氧的纯氧燃烧减碳系统,并计及不同场景下纯氧燃烧所需氧气需求,提出多场景容量优化配置策略。首先,提出并使用基于主从分析与近似流投影法的K-均值聚类法改进聚... 为提高区域电网新能源消纳能力、降低碳排放量与碳捕集能耗,构建基于风电制氧的纯氧燃烧减碳系统,并计及不同场景下纯氧燃烧所需氧气需求,提出多场景容量优化配置策略。首先,提出并使用基于主从分析与近似流投影法的K-均值聚类法改进聚类算法获得源荷典型场景。其次,为使系统经济性最佳,对不同场景提出运行方式与配置方案,在此基础上构建基于风电制氧的纯氧燃烧减碳系统多场景优化配置模型。最后,以比利时不同地区的全年源荷数据为例进行仿真验证并对不同场景配置结果与影响因素进行对比分析。结果表明:考虑不同场景进行配置能使系统的后期利润提高约47.83%;引入纯氧燃烧的同时会让系统的降碳成本降低约8.71%的同时捕碳能力提高14.90%以上。 展开更多
关键词 风电 制氢 碳捕捉 优化配置 纯氧燃烧 场景生成
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基于流化床分析的PSA制氧机吸附塔结构设计与研制
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作者 李昌才 郭松 +7 位作者 刘林青 陶瑞杰 李帅 褚婷婷 吕涛 史菊俊 孙广 杜娟 《医学工程与医用气体》 2026年第1期23-30,共8页
现有PSA制氧机中使用的吸附塔的结构均根据现有结构更改参数试验方式设计研制,无法准确地提升结构的制氧效率。本文基于流化床的分析方式,对于应用变压吸附制氧工艺的制氧机吸附塔结构进行设计,对吸附塔总体结构、吸附剂用量、分流板、... 现有PSA制氧机中使用的吸附塔的结构均根据现有结构更改参数试验方式设计研制,无法准确地提升结构的制氧效率。本文基于流化床的分析方式,对于应用变压吸附制氧工艺的制氧机吸附塔结构进行设计,对吸附塔总体结构、吸附剂用量、分流板、储气能力等分别进行了优化,设计了以Skarstrom循环的立体式轴向流体式分子筛床结构,对吸附剂性能进行测定并控制用量;根据吸附塔内床层的流速要求对床层内径进行控制,研究吸附塔合适的高度;根据塔进气空间对富集氧气的效率影响,分析设计吸附塔内的预留空间、分流板;研究储气罐对吸附塔系统应有的稳压储气能力。通过开展空分能力实验,对本文设计的吸附塔结构进行验证,结果证明设计的吸附塔结构较现用的立体式轴向流体式吸附塔结构能够提升制氧效率40%以上。 展开更多
关键词 医用分子筛制氧机 结构设计 流化床 PSA制氧 Skarstrom循环
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煤自燃诱发隅角CO超限临界值确定及分级预警指标体系研究
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作者 张泽钊 李金亮 《工矿自动化》 北大核心 2026年第1期64-72,共9页
采空区遗煤氧化产生CO逸出会造成煤矿回风隅角CO超限,明确隅角CO超限临界值和建立分级预警指标体系对于采空区煤自燃预警具有重要意义。为精准预警煤矿采空区煤自燃灾害,以中变质程度的烟煤为例,通过实验与现场观测相结合的方法,系统分... 采空区遗煤氧化产生CO逸出会造成煤矿回风隅角CO超限,明确隅角CO超限临界值和建立分级预警指标体系对于采空区煤自燃预警具有重要意义。为精准预警煤矿采空区煤自燃灾害,以中变质程度的烟煤为例,通过实验与现场观测相结合的方法,系统分析了常温及升温阶段煤的氧化特性及标志气体产生规律。实验结果表明,煤在常温下存在消耗O_(2)并生成CO的迟滞现象,确定常温氧化CO体积分数背景值为18×10^(-6)。在升温氧化阶段,煤的耗氧速率与CO产生速率在70℃出现显著增大转折点,100℃时开始产生特征气体C2H4,据此将煤低温氧化过程划分为缓慢氧化(30~70℃)、加速氧化(70~100℃)和剧烈氧化(>100℃)3个阶段。结合实验数据与现场监测历史数据,构建了以隅角CO浓度为核心指标的煤自燃4级预警指标体系,为基于隅角CO浓度进行煤自燃早期判识和分级防控提供了理论依据与实践指导。 展开更多
关键词 煤自燃 CO超限 临界值 分级预警 耗氧速率 CO产生速率
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基于程序升温实验研究大佛寺煤产热特性及临界氧浓度
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作者 黄磊 赵永杰 《煤矿现代化》 2026年第2期57-61,共5页
为探究氧浓度对煤低温氧化特性的影响并确定大佛寺煤的自然发火临界氧浓度,本文以该矿40204工作面为研究对象,在3%、6%、11%、16%、21%五种氧浓度条件下开展程序升温氧化实验。结果显示:氧浓度降低使交叉点温度升高,3%氧浓度时无交叉点... 为探究氧浓度对煤低温氧化特性的影响并确定大佛寺煤的自然发火临界氧浓度,本文以该矿40204工作面为研究对象,在3%、6%、11%、16%、21%五种氧浓度条件下开展程序升温氧化实验。结果显示:氧浓度降低使交叉点温度升高,3%氧浓度时无交叉点;指标气体初始生成温度升高、浓度降低,70℃后低氧抑制作用更显著;耗氧速率和产热速率随氧浓度降低而降低,干裂温度后低氧抑制效果更明显。综合确定大佛寺煤自然发火临界氧浓度为6%,低于此浓度时煤自燃进程受极大抑制。 展开更多
关键词 程序升温 指标气体 临界氧浓度 耗氧速率 产热速率
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热分解型化学产氧器工艺技术研究进展
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作者 丁建明 魏冲 +2 位作者 刘辉 孔庆平 朱耿溪 《当代化工研究》 2026年第4期54-56,共3页
化学产氧器可以在密闭场景中紧急供氧,介绍了化学产氧器的组成结构和产氧原理,其中化学核心是影响产氧性能的关键。多层设计的化学核心可以满足不同需求下的氧气流量,湿法压制成型的方式使物料在微观角度上接触更紧密。为降低表面温度,... 化学产氧器可以在密闭场景中紧急供氧,介绍了化学产氧器的组成结构和产氧原理,其中化学核心是影响产氧性能的关键。多层设计的化学核心可以满足不同需求下的氧气流量,湿法压制成型的方式使物料在微观角度上接触更紧密。为降低表面温度,减少热损失可以使用二氧化硅气凝胶等保温材料或镀膜钛合金壳体材料。使用过滤棉、霍加拉特剂和碱性化合物可以去除副反应产生的固体颗粒、一氧化碳和氯气,为后续高性能化学产氧器的结构设计、组分优化及工程化研制提供理论参考。 展开更多
关键词 化学产氧器 氯酸盐/高氯酸盐热分解反应 工艺技术
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基于模糊ABC-XYZ分类方法的高原制氧设备配件库存管理研究
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作者 李婷华 梁雷 +5 位作者 马帅 华政斐 郝江辉 周峰 徐灿华 张涛 《医疗卫生装备》 2026年第1期90-95,共6页
介绍了高原制氧设备常用的配件,分析了高原制氧设备维修配件的管理现状,基于模糊ABC分类方法和XYZ分类方法提出了模糊ABC-XYZ分类方法,实现了对高原制氧设备常用维修配件的精细分类以及对安全库存的预测,对于高原制氧设备维修配件管理... 介绍了高原制氧设备常用的配件,分析了高原制氧设备维修配件的管理现状,基于模糊ABC分类方法和XYZ分类方法提出了模糊ABC-XYZ分类方法,实现了对高原制氧设备常用维修配件的精细分类以及对安全库存的预测,对于高原制氧设备维修配件管理水平和高原制氧设备维修保障效能的提升具有重要意义。 展开更多
关键词 高原制氧设备 配件管理 模糊ABC分类法 XYZ分类法 安全库存
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