The Fushan Depression is one of the petroliferous depressions in the Beibuwan Basin,South China Sea.Previous studies have preliminarily explored the origin and source of crude oils in some areas of this depression.Nev...The Fushan Depression is one of the petroliferous depressions in the Beibuwan Basin,South China Sea.Previous studies have preliminarily explored the origin and source of crude oils in some areas of this depression.Nevertheless,no systematic investigations on the classification and origin of oils and hy-drocarbon migration processes have been made for the entire petroleum system in this depression,which has significantly hindered the hydrocarbon exploration in the region.A total of 32 mudstone and 58 oil samples from the Fushan Depression were analyzed to definite the detailed oil-source correlation within the sequence and sedimentary framework.The organic matter of third member of Paleogene Liushagang Formation(Els(3))source rocks,both deltaic and lacustrine mudstone,are algal-dominated with high abundance of C_(23)tricyclic terpane and C_(30)4-methylsteranes.The deltaic source rocks occur-ring in the first member(Els_(1))and second member(Els_(2))of the Paleogene Liushagang Formation are characterized by high abundance of C_(19+20)tricyclic terpane and oleanane,reflecting a more terrestrial plants contribution.While lacustrine source rocks of Els_(1)and Els_(2)display the reduced input of terrige-nous organic matter with relatively low abundance of C 19+20 tricyclic terpane and oleanane.Three types of oils were identified by their biomarker compositions in this study.Most of the oils discovered in the Huachang and Bailian Els_(1)reservoir belong to group A and were derived from lacustrine source rocks of Els_(1)and Els_(2).Group B oils are found within the Els_(1)and Els_(2)reservoirs,showing a close relation to the deltaic source rocks of Els_(1)and Els_(2),respectively.Group C oils,occurring in the Els3 reservoirs,have a good affinity with the Els3 source rocks.The spatial distribution and accumulation of different groups of oils are mainly controlled by the sedimentary facies and specific structural conditions.The Els_(2)reservoir in the Yong'an area belonging to Group B oil,are adjacent to the source kitchen and could be considered as the favorable exploration area in the future.展开更多
Series of 2-alkyl-1,3,4-trimethylbenzenes(ATMBs)were detected in most of crude oils and source rocks collected from various strata and locations of the Tarim Basin.They appeared to have heavy carbon isotopic signatur...Series of 2-alkyl-1,3,4-trimethylbenzenes(ATMBs)were detected in most of crude oils and source rocks collected from various strata and locations of the Tarim Basin.They appeared to have heavy carbon isotopic signatures(δ13C,up to~-16‰)compared to those hydrocarbons from oxygenic phototrophic organisms,indicating that the unequivocal source of green sulfur bacteria(GSB)and photic zone euxinia(PZE)existed in the original environment.Considering the high paleoproductivity,the PZE may have enhanced the preservation of organic matter,which triggered the formation of extremely organic-rich source rocks with TOC up to 29.8%for the Lower Cambrian Yuertus Formation(€1y).The coexistence of ATMBs and the diagnostic products from secondary alterations(e.g.,abundant 25-norhopanes,thiadiamondoids,and diamondoids)indicated a stronger ability of anti-second-alterations.Combined with the results of quantitatively de-convoluting mixed oil,the oil-source correlation based on ATMBs from a large number of Lower Paleozoic samples of the Tarim Basin suggested that the abundant deep crude oil resources co ntained a dominant contribution(>50%)from the€1y source rocks.Therefore,the ATMBs,as diagnostic biomarkers indicating unequivocal precursors under special habitat conditions,might provide important insights for the exploration of deep Lower Paleozoic crude oils in the Tarim Basin.展开更多
Understanding the origins of potential source rocks and unraveling the intricate connections between reservoir oils and their source formations in the Siwa Basin(Western Desert,Egypt)necessitate a thorough oil-source ...Understanding the origins of potential source rocks and unraveling the intricate connections between reservoir oils and their source formations in the Siwa Basin(Western Desert,Egypt)necessitate a thorough oil-source correlation investigation.This objective is achieved through a meticulous analysis of well-log responses,Rock-Eval pyrolysis,and biomarker data.The analysis of Total Organic Carbon across 31 samples representing Paleozoic formations in the Siwa A-1X well reveals a spectrum of organic richness ranging from 0.17 wt%to 2.04 wt%,thereby highlighting diverse levels of organic content and the presence of both Type II and Type III kerogen.Examination of the fingerprint characteristics of eight samples from the well suggests that the Dhiffah Formation comprises a blend of terrestrial and marine organic matter.Notably,a significant contribution from more oxidized residual organic matter and gas-prone Type III kerogen is observed.Contrarily,the Desouky and Zeitoun formations exhibit mixed organic matter indicative of a transitional environment,and thus featuring a pronounced marine influence within a more reducing setting,which is associated with Type II kerogen.Through analysis of five oil samples from different wells—SIWA L-1X,SIWA R-3X,SIWA D-1X,PTAH 5X,and PTAH 6X,it is evident that terrestrial organic matter,augmented by considerable marine input,was deposited in an oxidizing environment,and contains Type III kerogen.Geochemical scrutiny confirms the coexistence of mixed terrestrial organic matter within varying redox environments.Noteworthy is the uniformity of identified kerogen Types II and III across all samples,known to have potential for hydrocarbon generation.The discovery presented in this paper unveils captivating prospects concerning the genesis of oil in the Jurassic Safa reservoir,suggesting potential links to Paleozoic sources or even originating from the Safa Member itself.These revelations mark a substantial advancement in understanding source rock dynamics and their intricate relationship with reservoir oils within the Siwa Basin.By illuminating the processes of hydrocarbon genesis in the region,this study significantly enriches our knowledge base.展开更多
There are abundant bitumens and oil seepages stored in vugs in a Lower-Triassic Daye formation(T_1d)marlite in Ni'erguan village in the Southern Guizhou Depression. However, the source of those oil seepages has no...There are abundant bitumens and oil seepages stored in vugs in a Lower-Triassic Daye formation(T_1d)marlite in Ni'erguan village in the Southern Guizhou Depression. However, the source of those oil seepages has not been determined to date. Multiple suites of source rocks of different ages exist in the depression. Both the oil seepages and potential source rocks have undergone complicated secondary alterations, which have added to the difficulty of an oil-source correlation. For example, the main source rock, a Lower-Cambrian Niutitang Formation"(∈_1n) mudstone, is over mature, and other potential source rocks, both from the Permian and the Triassic, are still in the oil window. In addition, the T_1d oil seepages underwent a large amount of biodegradation. To minimize the influence of biodegradation and thermal maturation, special methods were employed in this oil-source correlation study. These methods included catalytic hydropyrolysis, to release covalently bound biomarkers from the over mature"kerogen of ∈_1n mudstone, sequential extraction, to obtain chloroform bitumen A and chloroform bitumen C from the T_1d marlite, and anhydrous pyrolysis, to release pyrolysates from the kerogen of T_1d marlite. Using the methods above, the biomarkers and n-alkanes releasedfrom the oil samples and source rocks were analysed by GC–MS and GC-C-IRMS. The oil-source correlation indicated that the T_1d oil seepage primarily originated from"the ∈_1n mudstone and was partially mixed with oil generated from the T_1d marlite. Furthermore, the seepage also demonstrated that the above methods were effective for the complicated oil-source correlation in the Southern Guizhou Depression.展开更多
The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphaltenes in heavy oils from the Lunnan and Tahe oilfields and Well TD2 with ruth...The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphaltenes in heavy oils from the Lunnan and Tahe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations. The RICO products included n-alkanoic acids, α, ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields are different from those of Well TD2. The biomarkers bounded on the asphaltenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C-{30} sterane and C-{31} 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4|methylsterane carboxylic acids are C-{28} sterane and C-{29} 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tahe oilfields.展开更多
Stable carbon isotopes were used together with molecular markers to constrain genetic relationships between sandstone extracts and potential source rocks in the pre-Tertiary in the Huanghua Depression,North China.Comp...Stable carbon isotopes were used together with molecular markers to constrain genetic relationships between sandstone extracts and potential source rocks in the pre-Tertiary in the Huanghua Depression,North China.Comparison of the extracts from Permo-Carboniferous terrigenous mudstones and Ordovician marine carbonates indicated that their prominent differences are in stable carbon isotopes,molecular markers and thermal maturity.Although the extracts of the Mesozoic and Lower Permian Xiashihezi Formation sandstones have some similar iso-topic characteristics,molecular markers data provide a good correlation between the Upper Jurassic-Lower Cretaceous oils and the Upper Carboniferous Taiyuan Formation mudstones,and between the Lower Permian Xiashihezi Formation oils and the Lower Permian mudstones.The results showed that the Upper Jurassic-Lower Cretaceous sandstone oils were derived chiefly from the Upper Carboniferous Taiyuan Formation terrigenous mudstones and that the Lower Permian Xiashihezi Formation oils were sourced from the Lower Permian Shanxi Formation and Xiashihezi Formation terrigenous mudstones.展开更多
The oleanane parameter, i.e., OP （oleananes/（oleananes＋C30hopanes）） in the two sedimentary columns of the Beibuwan Basin, South China Sea, can be used to delimit the top of oil generation window, with Ro （/%） o...The oleanane parameter, i.e., OP （oleananes/（oleananes＋C30hopanes）） in the two sedimentary columns of the Beibuwan Basin, South China Sea, can be used to delimit the top of oil generation window, with Ro （/%） of 0.53 in Well M1 and 0.55 in Wells H1/Hd1/Hd2, respectively. Comparing with vitrinite reflectance （Ro/%）, the OP features a dynamic range and can indicate the oil generation window more precisely. By using OP and other geochemical indices, the oil-source correlation is also conducted. It suggests that the oils in wells M1 and M2 are derived from the source rocks in situ. The mudstone in Huachang uplift is not the main source rocks for oils in this area, The OP is also a useful oil-source correlation parameter in some Tertiary lacustrine basins.展开更多
It is known that correlation does not imply causality.Some relationships identified in the analysis of data are coincidental or unknown,and some are produced by real-world causality of the situation,which is problemat...It is known that correlation does not imply causality.Some relationships identified in the analysis of data are coincidental or unknown,and some are produced by real-world causality of the situation,which is problematic,since there is a need to differentiate between these two scenarios.Until recently,the proper−semantic−causality of the relationship could have been determined only by human experts from the area of expertise of the studied data.This has changed with the advance of large language models,which are often utilized as surrogates for such human experts,making the process automated and readily available to all data analysts.This motivates the main objective of this work,which is to introduce the design and implementation of a large language model-based semantic causality evaluator based on correlation analysis,together with its visual analysis model called Causal heatmap.After the implementation itself,the model is evaluated from the point of view of the quality of the visual model,from the point of view of the quality of causal evaluation based on large language models,and from the point of view of comparative analysis,while the results reached in the study highlight the usability of large language models in the task and the potential of the proposed approach in the analysis of unknown datasets.The results of the experimental evaluation demonstrate the usefulness of the Causal heatmap method,supported by the evident highlighting of interesting relationships,while suppressing irrelevant ones.展开更多
The respiratory-circulatory system, including organs such as the nose, pharynx, larynx, trachea, bronchi, and heart, is an organic community responsible for ventilation and gas exchange. The integrity of its anatomica...The respiratory-circulatory system, including organs such as the nose, pharynx, larynx, trachea, bronchi, and heart, is an organic community responsible for ventilation and gas exchange. The integrity of its anatomical structure directly affects the evolution of pathological processes, and the analysis of their correlation is a core entry point for clinical disease diagnosis, treatment, and mechanism research. Based on this, this paper mainly explores the correlation between the anatomical and pathological characteristics of the respiratory-circulatory system, aiming to provide anatomical and pathological theoretical support for clinical accurate diagnosis, targeted therapy, and prognosis evaluation.展开更多
Objective: To understand the current status of peer caring behavior and empathy among undergraduate nursing students and to explore the relationship between the two. Method: Using the convenience sampling method, a qu...Objective: To understand the current status of peer caring behavior and empathy among undergraduate nursing students and to explore the relationship between the two. Method: Using the convenience sampling method, a questionnaire survey was conducted among 292 nursing students from a medical college in Jiangxi Province, using the Peer Caring Behavior Scale and the Jefferson Scale of Empathy. Results: The score for peer caring behavior among undergraduate nursing students was 85.00 (78.00-92.00), and the score for empathy was 101.00 (92.00-110.00). A positive correlation was found between the two (r = 0.362, p < 0.05). Conclusion: The level of peer caring behavior among undergraduate nursing students is above average, while their empathy level is moderate, with a positive correlation between the two. This suggests that nursing educators should strengthen the development of peer caring behavior, which may help enhance the empathy of undergraduate nursing students.展开更多
The Kagome metal CsV3Sb5 transitions from a weakly correlated state to a strongly correlated state upon Cr substitution;however,the mechanism driving this enhancement remains an open question.Here,we employed a combin...The Kagome metal CsV3Sb5 transitions from a weakly correlated state to a strongly correlated state upon Cr substitution;however,the mechanism driving this enhancement remains an open question.Here,we employed a combination of density functional theory and dynamical mean-field theory(DFT+DMFT)to systematically investigate the evolution of electronic correlations in the CsV_(3−x)Cr_(x)Sb_(5)(x=0,1,and 3)series.Our calculations revealed that Cr doping drives the system into a strongly correlated Hund’s metal phase,which is characterized by significant and orbital-dependent enhancements in the quasiparticle effective masses and electronic scattering rates.We trace the origin of this transition to the doping-induced shift from low-to high-spin atomic configurations.This preference for high-spin states,which is promoted by near-half-filling of the Cr-d orbitals,induces a pronounced orbital blocking effect that strengthens the correlations.Our findings establish that Hund’s coupling is the decisive factor governing the rich correlation physics in the CsV_(3−x)Cr_(x)Sb_(5) family,providing a tunable platform for exploring Hund’s metallicity.展开更多
BACKGROUND Anxiety,depression,and other negative emotions are common among patients with chronic renal failure(CRF).Analyzing the factors related to negative emotions is necessary to provide targeted nursing care.AIM ...BACKGROUND Anxiety,depression,and other negative emotions are common among patients with chronic renal failure(CRF).Analyzing the factors related to negative emotions is necessary to provide targeted nursing care.AIM To explore the correlations among life satisfaction,pleasure levels,and negative emotions in patients with CRF.METHODS One hundred patients with CRF who received therapy at the First Affiliated Hospital of Jinzhou Medical University between December 2022 and February 2025 were included.The Depression,Anxiety,and Stress Scale(DASS-21),Satisfaction with Life Scale(SWLS),and Temporal Experience of Pleasure Scale(TEPS)were used to evaluate negative emotions,life satisfaction,and pleasure level,respectively.Pearson’s correlation coefficient analyzed the correlation between life satisfaction,pleasure level,and negative emotions.Linear regression analysis identified the factors affecting negative emotions.RESULTS The average DASS-21 score among patients with CRF was 51.90±2.30,with subscale scores of 17.90±1.50 for depression,18.53±1.18 for anxiety,and 15.47±2.36 for stress,all significantly higher than the domestic norm(P<0.05).The average SWLS score was 22.17±4.90.Correlation analysis revealed a negative correlation between the SWLS and total DASS-21 scores(P<0.05),but not with the individual depression,anxiety,or stress dimensions.The average TEPS score was 67.80±8.34.TEPS scores were negatively correlated with the DASS-21 score and the stress dimension(P<0.05),but not with depression or anxiety.Linear regression analysis showed that TEPS scores significantly influenced DASS-21 scores(P<0.05).CONCLUSION Patients with CRF experience high levels of negative emotions,which are negatively correlated with life satisfaction and pleasure.Furthermore,pleasure level had an impact on negative emotions.展开更多
We investigate numerically the effects of long-range temporal and spatial correlations based on the rescaled distributions of the squared interface width W^(2)(L, t) and the interface height h(x, t)in the(1+1)-dimensi...We investigate numerically the effects of long-range temporal and spatial correlations based on the rescaled distributions of the squared interface width W^(2)(L, t) and the interface height h(x, t)in the(1+1)-dimensional Kardar-Parisi-Zhang(KPZ) growth system within the early growth regime. Through extensive numerical simulations, we find that long-range temporally correlated noise does not significantly impact the distribution form of the interface width. Generally,W^(2)(L, t) approximately obeys a lognormal distribution when the temporal correlation exponentθ ≥0. On the other hand, the effects of long-range spatially correlated noise are evidently different from the temporally correlated case. Our results show that, when the spatial correlation exponent ρ ≤ 0.20, the distribution forms of W^(2)(L, t) approach the lognormal distribution, and when ρ > 0.20, the distribution becomes more asymmetric, steep, and fat-tailed, and tends to an unknown distribution form. As a comparison, probability distributions of the interface height are also provided in the temporally and spatially correlated KPZ system, exhibiting quite different characteristics from each other within the whole correlated strengths. For the temporal correlation, the height distributions follow Tracy-Widom Gaussian orthogonal ensemble(TW-GOE) when θ → 0, and with increasing θ, the height distributions crossover continuously to an unknown distribution. However, for the spatial correlation, the height distributions gradually transition from the TW-GOE distribution to the standard Gaussian form.展开更多
Programmable two-particle quantum walks are crucial for advancing quantum simulation,computation,and information processing.Although disorder is traditionally associated with information loss,it can also facilitate em...Programmable two-particle quantum walks are crucial for advancing quantum simulation,computation,and information processing.Although disorder is traditionally associated with information loss,it can also facilitate emergent phenomena such as enhanced energy transport.Here,we experimentally realize a 12-step discrete-time quantum walk in programmable integrated photonic circuits,introducing tunable static and dynamic disorder to explore quantum transport dynamics.In periodic lattices,disorder induces light localization and drives a transition from quantum ballistic to classical diffusive behavior.In particular,quantum walks of correlated photons exhibit a disorder-induced bunching effect,accompanied by enhanced nonclassical correlations.Our platform provides a scalable framework for investigating multiparticle quantum dynamics in engineered environments,promoting the development of quantum optics toward large-scale applications.展开更多
In multi-orbital systems,the correlation strength is typically attributed to Coulomb interactions and Hund's couplings.However,this study demonstrates that on-site inter-orbital hybridization can also significant ...In multi-orbital systems,the correlation strength is typically attributed to Coulomb interactions and Hund's couplings.However,this study demonstrates that on-site inter-orbital hybridization can also significant influence the correlation strength of the system.We investigate the impact of on-site inter-orbital hybridization on the correlation strength of a two-orbital Hubbard model on a square lattice using the dynamical mean-field theory combined with Lanczos exact diagonalization.Our findings reveal a distinct Janus effect:on-site inter-orbital hybridization enhances correlation strength in the non-half-filled regime while suppresses it at half-filling.This dual role of on-site inter-orbital hybridization provides a fundamental mechanism for tuning the strength of correlations in multi-orbital systems.展开更多
The energy correlations of prompt fission neutrons have not yet been considered in the related coincidence and multiplication measurement techniques.To measure and verify the energy correlations,an experiment was perf...The energy correlations of prompt fission neutrons have not yet been considered in the related coincidence and multiplication measurement techniques.To measure and verify the energy correlations,an experiment was performed with a total measurement duration of approximately 1200 h.In the experiment,eight CLYC detectors and sixteen EJ309 liquid scintillation detectors were utilized,and the fission moment was tagged with the measured fissionγ-rays.The relative ratios of the energy spectra of the neutrons correlated with different energy neutrons to the^(252)Cf fission neutron energy spectra were obtained.The present results may be helpful for studying fission physics and nuclear technology applications.展开更多
When two layers of graphene are stacked with a twist angle of approximately 1.1°,strong interlayer coupling gives rise to a pair of flat bands in twisted bilayer graphene(TBG),resulting in pronounced electron–el...When two layers of graphene are stacked with a twist angle of approximately 1.1°,strong interlayer coupling gives rise to a pair of flat bands in twisted bilayer graphene(TBG),resulting in pronounced electron–electron interactions.At half filling of the flat bands,TBG exhibits correlated insulating states.Here,we investigate the electrical transport properties of heterostructures composed of TBG and the antiferromagnetic insulator chromium oxychloride(CrOCl),and propose a strategy to modulate the correlated insulating states in TBG.During the transition from a conventional phase to a strong interfacial coupling phase,kink-like features are observed in the charge neutrality point(CNP),correlated insulating state,and band insulating state.Under a perpendicular magnetic field,the system exhibits broadened quantum Hall plateaus in the strong interfacial coupling regime.Electrons localized in the CrOCl layer screen the bottom gate,rendering the carrier density in TBG less sensitive to variations in the bottom gate voltage.These phenomena are well captured by a charge-transfer model between TBG and CrOCl.Our results provide insights into the control of electronic correlations and topological states in graphene moirésystems via interfacial charge coupling.展开更多
The octupole correlations of the K^(π)=5/2^(+)ground state and the rotational spectrum built on it in^(229)Th are studied using the microscopic relativistic density functional theory on a three-dimensional lattice sp...The octupole correlations of the K^(π)=5/2^(+)ground state and the rotational spectrum built on it in^(229)Th are studied using the microscopic relativistic density functional theory on a three-dimensional lattice space and the reflection-asymmetric triaxial particle rotor model.It is found that^(229)Th has a ground state with static axial octupole and quadrupole deformations.The occurrence of octupole correlations,driven by the octupole deformation,is analyzed through the evolution of single-particle levels around the Fermi surface.The experimental energy spectrum and the electromagnetic transition probabilities,including B(E2)and B(M1),are reasonably well reproduced.展开更多
An important feature of quantum chromodynamics(QCD)is that the strong force grows as the distance between partons increases,which confines partons into hadrons,commonly known as QCD confinement.Perturbative QCD(pQCD)d...An important feature of quantum chromodynamics(QCD)is that the strong force grows as the distance between partons increases,which confines partons into hadrons,commonly known as QCD confinement.Perturbative QCD(pQCD)does not work at large distance,such as the length scale of a hadron,which is the regime of non-perturbative QCD.The detailed QCD mechanisms through which confinement occurs from partons to hadrons(usually known as hadronization),and how it manifests itself in partonic structure of hadrons(usually known as parton distribution),remain unresolved puzzles of first-principle QCD calculations.展开更多
Ironmaking process(IP)is indispensable to modern iron and steel industry,where real-time monitoring is crucial for achieving high molten iron quality(MIQ)with low energy consumption.While neural network-based models s...Ironmaking process(IP)is indispensable to modern iron and steel industry,where real-time monitoring is crucial for achieving high molten iron quality(MIQ)with low energy consumption.While neural network-based models show some promising results,they are generally limited by non-negligible drawbacks such as interpretability issues of feature learning.To address these issues,we propose a novel concept based on the shallow-to-deep correlation network representation regression(Sh-to-De CNRR).Our approach,shallow correlation network representation regression(ShCNRR),combines neural network and canonical correlation analysis thoughts to generate explainable features via shallow correlation network representation(CNR).A twin inverse network is then derived to obtain the explicit model output,leveraging the shallow CNR.To capture deeper nonlinear information,we extend ShCNRR into a hierarchical deep correlation network representation regression(DeCNRR)model that features stacked neural networks,enabling us to learn deeper CNR from process data.The feasibility and advantages of our proposals are validated by theoretical derivations and practical IP cases,which contain one MIQ regression and three MIQ-related fault detection tasks.The results reveal that highly fused statistical and neural network models yield superior monitoring performance compared to current state-of-the-art models,while statistical tests verify the convincing feature mining.展开更多
基金funded by the South Oil Exploration and Development Company of PetroChina(2021-HNYJ-010).
文摘The Fushan Depression is one of the petroliferous depressions in the Beibuwan Basin,South China Sea.Previous studies have preliminarily explored the origin and source of crude oils in some areas of this depression.Nevertheless,no systematic investigations on the classification and origin of oils and hy-drocarbon migration processes have been made for the entire petroleum system in this depression,which has significantly hindered the hydrocarbon exploration in the region.A total of 32 mudstone and 58 oil samples from the Fushan Depression were analyzed to definite the detailed oil-source correlation within the sequence and sedimentary framework.The organic matter of third member of Paleogene Liushagang Formation(Els(3))source rocks,both deltaic and lacustrine mudstone,are algal-dominated with high abundance of C_(23)tricyclic terpane and C_(30)4-methylsteranes.The deltaic source rocks occur-ring in the first member(Els_(1))and second member(Els_(2))of the Paleogene Liushagang Formation are characterized by high abundance of C_(19+20)tricyclic terpane and oleanane,reflecting a more terrestrial plants contribution.While lacustrine source rocks of Els_(1)and Els_(2)display the reduced input of terrige-nous organic matter with relatively low abundance of C 19+20 tricyclic terpane and oleanane.Three types of oils were identified by their biomarker compositions in this study.Most of the oils discovered in the Huachang and Bailian Els_(1)reservoir belong to group A and were derived from lacustrine source rocks of Els_(1)and Els_(2).Group B oils are found within the Els_(1)and Els_(2)reservoirs,showing a close relation to the deltaic source rocks of Els_(1)and Els_(2),respectively.Group C oils,occurring in the Els3 reservoirs,have a good affinity with the Els3 source rocks.The spatial distribution and accumulation of different groups of oils are mainly controlled by the sedimentary facies and specific structural conditions.The Els_(2)reservoir in the Yong'an area belonging to Group B oil,are adjacent to the source kitchen and could be considered as the favorable exploration area in the future.
基金financial support provided by the National Science and Technology Major Project of the Ministry of Science and Technology of China (2016ZX04004-004)National Natural Science Foundation of China (41672125)
文摘Series of 2-alkyl-1,3,4-trimethylbenzenes(ATMBs)were detected in most of crude oils and source rocks collected from various strata and locations of the Tarim Basin.They appeared to have heavy carbon isotopic signatures(δ13C,up to~-16‰)compared to those hydrocarbons from oxygenic phototrophic organisms,indicating that the unequivocal source of green sulfur bacteria(GSB)and photic zone euxinia(PZE)existed in the original environment.Considering the high paleoproductivity,the PZE may have enhanced the preservation of organic matter,which triggered the formation of extremely organic-rich source rocks with TOC up to 29.8%for the Lower Cambrian Yuertus Formation(€1y).The coexistence of ATMBs and the diagnostic products from secondary alterations(e.g.,abundant 25-norhopanes,thiadiamondoids,and diamondoids)indicated a stronger ability of anti-second-alterations.Combined with the results of quantitatively de-convoluting mixed oil,the oil-source correlation based on ATMBs from a large number of Lower Paleozoic samples of the Tarim Basin suggested that the abundant deep crude oil resources co ntained a dominant contribution(>50%)from the€1y source rocks.Therefore,the ATMBs,as diagnostic biomarkers indicating unequivocal precursors under special habitat conditions,might provide important insights for the exploration of deep Lower Paleozoic crude oils in the Tarim Basin.
基金the research project is funded by Abdullah Alrushaid Chair for Earth Science Remote Sensing Research at King Saud University,Riyadh,Saudi Arabia.。
文摘Understanding the origins of potential source rocks and unraveling the intricate connections between reservoir oils and their source formations in the Siwa Basin(Western Desert,Egypt)necessitate a thorough oil-source correlation investigation.This objective is achieved through a meticulous analysis of well-log responses,Rock-Eval pyrolysis,and biomarker data.The analysis of Total Organic Carbon across 31 samples representing Paleozoic formations in the Siwa A-1X well reveals a spectrum of organic richness ranging from 0.17 wt%to 2.04 wt%,thereby highlighting diverse levels of organic content and the presence of both Type II and Type III kerogen.Examination of the fingerprint characteristics of eight samples from the well suggests that the Dhiffah Formation comprises a blend of terrestrial and marine organic matter.Notably,a significant contribution from more oxidized residual organic matter and gas-prone Type III kerogen is observed.Contrarily,the Desouky and Zeitoun formations exhibit mixed organic matter indicative of a transitional environment,and thus featuring a pronounced marine influence within a more reducing setting,which is associated with Type II kerogen.Through analysis of five oil samples from different wells—SIWA L-1X,SIWA R-3X,SIWA D-1X,PTAH 5X,and PTAH 6X,it is evident that terrestrial organic matter,augmented by considerable marine input,was deposited in an oxidizing environment,and contains Type III kerogen.Geochemical scrutiny confirms the coexistence of mixed terrestrial organic matter within varying redox environments.Noteworthy is the uniformity of identified kerogen Types II and III across all samples,known to have potential for hydrocarbon generation.The discovery presented in this paper unveils captivating prospects concerning the genesis of oil in the Jurassic Safa reservoir,suggesting potential links to Paleozoic sources or even originating from the Safa Member itself.These revelations mark a substantial advancement in understanding source rock dynamics and their intricate relationship with reservoir oils within the Siwa Basin.By illuminating the processes of hydrocarbon genesis in the region,this study significantly enriches our knowledge base.
基金supported jointly by the National Science and Technology Major Project of China (Grant Nos: 2011ZX05008002 and 2011ZX05005-001)
文摘There are abundant bitumens and oil seepages stored in vugs in a Lower-Triassic Daye formation(T_1d)marlite in Ni'erguan village in the Southern Guizhou Depression. However, the source of those oil seepages has not been determined to date. Multiple suites of source rocks of different ages exist in the depression. Both the oil seepages and potential source rocks have undergone complicated secondary alterations, which have added to the difficulty of an oil-source correlation. For example, the main source rock, a Lower-Cambrian Niutitang Formation"(∈_1n) mudstone, is over mature, and other potential source rocks, both from the Permian and the Triassic, are still in the oil window. In addition, the T_1d oil seepages underwent a large amount of biodegradation. To minimize the influence of biodegradation and thermal maturation, special methods were employed in this oil-source correlation study. These methods included catalytic hydropyrolysis, to release covalently bound biomarkers from the over mature"kerogen of ∈_1n mudstone, sequential extraction, to obtain chloroform bitumen A and chloroform bitumen C from the T_1d marlite, and anhydrous pyrolysis, to release pyrolysates from the kerogen of T_1d marlite. Using the methods above, the biomarkers and n-alkanes releasedfrom the oil samples and source rocks were analysed by GC–MS and GC-C-IRMS. The oil-source correlation indicated that the T_1d oil seepage primarily originated from"the ∈_1n mudstone and was partially mixed with oil generated from the T_1d marlite. Furthermore, the seepage also demonstrated that the above methods were effective for the complicated oil-source correlation in the Southern Guizhou Depression.
文摘The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphaltenes in heavy oils from the Lunnan and Tahe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations. The RICO products included n-alkanoic acids, α, ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields are different from those of Well TD2. The biomarkers bounded on the asphaltenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C-{30} sterane and C-{31} 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4|methylsterane carboxylic acids are C-{28} sterane and C-{29} 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tahe oilfields.
文摘Stable carbon isotopes were used together with molecular markers to constrain genetic relationships between sandstone extracts and potential source rocks in the pre-Tertiary in the Huanghua Depression,North China.Comparison of the extracts from Permo-Carboniferous terrigenous mudstones and Ordovician marine carbonates indicated that their prominent differences are in stable carbon isotopes,molecular markers and thermal maturity.Although the extracts of the Mesozoic and Lower Permian Xiashihezi Formation sandstones have some similar iso-topic characteristics,molecular markers data provide a good correlation between the Upper Jurassic-Lower Cretaceous oils and the Upper Carboniferous Taiyuan Formation mudstones,and between the Lower Permian Xiashihezi Formation oils and the Lower Permian mudstones.The results showed that the Upper Jurassic-Lower Cretaceous sandstone oils were derived chiefly from the Upper Carboniferous Taiyuan Formation terrigenous mudstones and that the Lower Permian Xiashihezi Formation oils were sourced from the Lower Permian Shanxi Formation and Xiashihezi Formation terrigenous mudstones.
基金supported by the Natural Science Foundation of China(Grant No.40672093)CNPC Innovation Fund(07El001)the ESS-China Hydrocarbon Geosciences Collaboration Project under Natural Resources Canada's International Opportunities Program.
文摘The oleanane parameter, i.e., OP （oleananes/（oleananes＋C30hopanes）） in the two sedimentary columns of the Beibuwan Basin, South China Sea, can be used to delimit the top of oil generation window, with Ro （/%） of 0.53 in Well M1 and 0.55 in Wells H1/Hd1/Hd2, respectively. Comparing with vitrinite reflectance （Ro/%）, the OP features a dynamic range and can indicate the oil generation window more precisely. By using OP and other geochemical indices, the oil-source correlation is also conducted. It suggests that the oils in wells M1 and M2 are derived from the source rocks in situ. The mudstone in Huachang uplift is not the main source rocks for oils in this area, The OP is also a useful oil-source correlation parameter in some Tertiary lacustrine basins.
基金supported by University Grant Agency of Matej Bel University in Banská Bystrica project number UGA-14-PDS-2025.
文摘It is known that correlation does not imply causality.Some relationships identified in the analysis of data are coincidental or unknown,and some are produced by real-world causality of the situation,which is problematic,since there is a need to differentiate between these two scenarios.Until recently,the proper−semantic−causality of the relationship could have been determined only by human experts from the area of expertise of the studied data.This has changed with the advance of large language models,which are often utilized as surrogates for such human experts,making the process automated and readily available to all data analysts.This motivates the main objective of this work,which is to introduce the design and implementation of a large language model-based semantic causality evaluator based on correlation analysis,together with its visual analysis model called Causal heatmap.After the implementation itself,the model is evaluated from the point of view of the quality of the visual model,from the point of view of the quality of causal evaluation based on large language models,and from the point of view of comparative analysis,while the results reached in the study highlight the usability of large language models in the task and the potential of the proposed approach in the analysis of unknown datasets.The results of the experimental evaluation demonstrate the usefulness of the Causal heatmap method,supported by the evident highlighting of interesting relationships,while suppressing irrelevant ones.
文摘The respiratory-circulatory system, including organs such as the nose, pharynx, larynx, trachea, bronchi, and heart, is an organic community responsible for ventilation and gas exchange. The integrity of its anatomical structure directly affects the evolution of pathological processes, and the analysis of their correlation is a core entry point for clinical disease diagnosis, treatment, and mechanism research. Based on this, this paper mainly explores the correlation between the anatomical and pathological characteristics of the respiratory-circulatory system, aiming to provide anatomical and pathological theoretical support for clinical accurate diagnosis, targeted therapy, and prognosis evaluation.
基金2024 University-level Research Project of Fuzhou Medical College,Fuzhou Medical College of Nanchang University(Project No.:fykj202406)。
文摘Objective: To understand the current status of peer caring behavior and empathy among undergraduate nursing students and to explore the relationship between the two. Method: Using the convenience sampling method, a questionnaire survey was conducted among 292 nursing students from a medical college in Jiangxi Province, using the Peer Caring Behavior Scale and the Jefferson Scale of Empathy. Results: The score for peer caring behavior among undergraduate nursing students was 85.00 (78.00-92.00), and the score for empathy was 101.00 (92.00-110.00). A positive correlation was found between the two (r = 0.362, p < 0.05). Conclusion: The level of peer caring behavior among undergraduate nursing students is above average, while their empathy level is moderate, with a positive correlation between the two. This suggests that nursing educators should strengthen the development of peer caring behavior, which may help enhance the empathy of undergraduate nursing students.
基金supported by the Development Program of China and the National Key Research (Grant Nos.2023YFA1406200 and 2022YFA1402304)the National Natural Science Foundation of China (Grant Nos.12274169 and 12122405)+3 种基金the Fundamental Research Funds for the Central Universitiesthe Innovation Team for Functional Materials and Devices for Informatics at Anhui Higher Education Institutes (Grant No.2024AH010024)the Natural Science Research Project of Education Department of Anhui Province (Grant No.2025AHGXZK31203)the PHD Research Startup Foundation of Fuyang Normal University (Grant No.2025KYQD0072)。
文摘The Kagome metal CsV3Sb5 transitions from a weakly correlated state to a strongly correlated state upon Cr substitution;however,the mechanism driving this enhancement remains an open question.Here,we employed a combination of density functional theory and dynamical mean-field theory(DFT+DMFT)to systematically investigate the evolution of electronic correlations in the CsV_(3−x)Cr_(x)Sb_(5)(x=0,1,and 3)series.Our calculations revealed that Cr doping drives the system into a strongly correlated Hund’s metal phase,which is characterized by significant and orbital-dependent enhancements in the quasiparticle effective masses and electronic scattering rates.We trace the origin of this transition to the doping-induced shift from low-to high-spin atomic configurations.This preference for high-spin states,which is promoted by near-half-filling of the Cr-d orbitals,induces a pronounced orbital blocking effect that strengthens the correlations.Our findings establish that Hund’s coupling is the decisive factor governing the rich correlation physics in the CsV_(3−x)Cr_(x)Sb_(5) family,providing a tunable platform for exploring Hund’s metallicity.
文摘BACKGROUND Anxiety,depression,and other negative emotions are common among patients with chronic renal failure(CRF).Analyzing the factors related to negative emotions is necessary to provide targeted nursing care.AIM To explore the correlations among life satisfaction,pleasure levels,and negative emotions in patients with CRF.METHODS One hundred patients with CRF who received therapy at the First Affiliated Hospital of Jinzhou Medical University between December 2022 and February 2025 were included.The Depression,Anxiety,and Stress Scale(DASS-21),Satisfaction with Life Scale(SWLS),and Temporal Experience of Pleasure Scale(TEPS)were used to evaluate negative emotions,life satisfaction,and pleasure level,respectively.Pearson’s correlation coefficient analyzed the correlation between life satisfaction,pleasure level,and negative emotions.Linear regression analysis identified the factors affecting negative emotions.RESULTS The average DASS-21 score among patients with CRF was 51.90±2.30,with subscale scores of 17.90±1.50 for depression,18.53±1.18 for anxiety,and 15.47±2.36 for stress,all significantly higher than the domestic norm(P<0.05).The average SWLS score was 22.17±4.90.Correlation analysis revealed a negative correlation between the SWLS and total DASS-21 scores(P<0.05),but not with the individual depression,anxiety,or stress dimensions.The average TEPS score was 67.80±8.34.TEPS scores were negatively correlated with the DASS-21 score and the stress dimension(P<0.05),but not with depression or anxiety.Linear regression analysis showed that TEPS scores significantly influenced DASS-21 scores(P<0.05).CONCLUSION Patients with CRF experience high levels of negative emotions,which are negatively correlated with life satisfaction and pleasure.Furthermore,pleasure level had an impact on negative emotions.
文摘We investigate numerically the effects of long-range temporal and spatial correlations based on the rescaled distributions of the squared interface width W^(2)(L, t) and the interface height h(x, t)in the(1+1)-dimensional Kardar-Parisi-Zhang(KPZ) growth system within the early growth regime. Through extensive numerical simulations, we find that long-range temporally correlated noise does not significantly impact the distribution form of the interface width. Generally,W^(2)(L, t) approximately obeys a lognormal distribution when the temporal correlation exponentθ ≥0. On the other hand, the effects of long-range spatially correlated noise are evidently different from the temporally correlated case. Our results show that, when the spatial correlation exponent ρ ≤ 0.20, the distribution forms of W^(2)(L, t) approach the lognormal distribution, and when ρ > 0.20, the distribution becomes more asymmetric, steep, and fat-tailed, and tends to an unknown distribution form. As a comparison, probability distributions of the interface height are also provided in the temporally and spatially correlated KPZ system, exhibiting quite different characteristics from each other within the whole correlated strengths. For the temporal correlation, the height distributions follow Tracy-Widom Gaussian orthogonal ensemble(TW-GOE) when θ → 0, and with increasing θ, the height distributions crossover continuously to an unknown distribution. However, for the spatial correlation, the height distributions gradually transition from the TW-GOE distribution to the standard Gaussian form.
基金supported by the National Natural Science Foundation of China(Grant Nos.T2325022,U23A2074,12204462,62275240,62435009,12474494,and 12204468)the Chinese Academy of Sciences(CAS)Project for Young Scientists in Basic Research(Grant No.253 YSBR-049)+3 种基金the Key Research and Development Program of Anhui Province(Grant No.2022b1302007)the China Postdoctoral Science Foundation(Grant No.2024M753083)the National Postdoctoral Program for Innovative Talents(Grant No.BX20240353)the Fundamental Research Funds for the Central Universities(Grant Nos.WK2030000107,WK2030000108,and WK2030000081)。
文摘Programmable two-particle quantum walks are crucial for advancing quantum simulation,computation,and information processing.Although disorder is traditionally associated with information loss,it can also facilitate emergent phenomena such as enhanced energy transport.Here,we experimentally realize a 12-step discrete-time quantum walk in programmable integrated photonic circuits,introducing tunable static and dynamic disorder to explore quantum transport dynamics.In periodic lattices,disorder induces light localization and drives a transition from quantum ballistic to classical diffusive behavior.In particular,quantum walks of correlated photons exhibit a disorder-induced bunching effect,accompanied by enhanced nonclassical correlations.Our platform provides a scalable framework for investigating multiparticle quantum dynamics in engineered environments,promoting the development of quantum optics toward large-scale applications.
基金Project supported by the National Natural Science Foundation of China(Grant No.12174327)the Natural Science Foundation of Shandong Province,China(Grant No.ZR2023ZD09)。
文摘In multi-orbital systems,the correlation strength is typically attributed to Coulomb interactions and Hund's couplings.However,this study demonstrates that on-site inter-orbital hybridization can also significant influence the correlation strength of the system.We investigate the impact of on-site inter-orbital hybridization on the correlation strength of a two-orbital Hubbard model on a square lattice using the dynamical mean-field theory combined with Lanczos exact diagonalization.Our findings reveal a distinct Janus effect:on-site inter-orbital hybridization enhances correlation strength in the non-half-filled regime while suppresses it at half-filling.This dual role of on-site inter-orbital hybridization provides a fundamental mechanism for tuning the strength of correlations in multi-orbital systems.
基金supported by the National Natural Science Foundation of China(No.12105257)the Research and Development Fund(No.JMJJ202401)。
文摘The energy correlations of prompt fission neutrons have not yet been considered in the related coincidence and multiplication measurement techniques.To measure and verify the energy correlations,an experiment was performed with a total measurement duration of approximately 1200 h.In the experiment,eight CLYC detectors and sixteen EJ309 liquid scintillation detectors were utilized,and the fission moment was tagged with the measured fissionγ-rays.The relative ratios of the energy spectra of the neutrons correlated with different energy neutrons to the^(252)Cf fission neutron energy spectra were obtained.The present results may be helpful for studying fission physics and nuclear technology applications.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.52225207 and 52350001)the Shanghai Pilot Program for Basic Research–Fudan University 21TQ1400100(Grant No.21TQ006)the Shanghai Municipal Science and Technology Major Project(Grant No.2019SHZDZX01)。
文摘When two layers of graphene are stacked with a twist angle of approximately 1.1°,strong interlayer coupling gives rise to a pair of flat bands in twisted bilayer graphene(TBG),resulting in pronounced electron–electron interactions.At half filling of the flat bands,TBG exhibits correlated insulating states.Here,we investigate the electrical transport properties of heterostructures composed of TBG and the antiferromagnetic insulator chromium oxychloride(CrOCl),and propose a strategy to modulate the correlated insulating states in TBG.During the transition from a conventional phase to a strong interfacial coupling phase,kink-like features are observed in the charge neutrality point(CNP),correlated insulating state,and band insulating state.Under a perpendicular magnetic field,the system exhibits broadened quantum Hall plateaus in the strong interfacial coupling regime.Electrons localized in the CrOCl layer screen the bottom gate,rendering the carrier density in TBG less sensitive to variations in the bottom gate voltage.These phenomena are well captured by a charge-transfer model between TBG and CrOCl.Our results provide insights into the control of electronic correlations and topological states in graphene moirésystems via interfacial charge coupling.
基金supported by the National Natural Science Foundation of China(Grant Nos.12205097,12141501,12475117,and 12435006)the National Key Laboratory of Neutron Science and Technology(Grant No.NST202401016)+1 种基金the National Key R&D Program of China(Grant Nos.2024YFA1612600 and 2024YFE0109803)the High-performance Computing Platform of Peking University。
文摘The octupole correlations of the K^(π)=5/2^(+)ground state and the rotational spectrum built on it in^(229)Th are studied using the microscopic relativistic density functional theory on a three-dimensional lattice space and the reflection-asymmetric triaxial particle rotor model.It is found that^(229)Th has a ground state with static axial octupole and quadrupole deformations.The occurrence of octupole correlations,driven by the octupole deformation,is analyzed through the evolution of single-particle levels around the Fermi surface.The experimental energy spectrum and the electromagnetic transition probabilities,including B(E2)and B(M1),are reasonably well reproduced.
基金supported in part by the National Natural Science Foundation of China(No.12575145)the National Key Research and Development Program of China(No.2022YFA1604900)。
文摘An important feature of quantum chromodynamics(QCD)is that the strong force grows as the distance between partons increases,which confines partons into hadrons,commonly known as QCD confinement.Perturbative QCD(pQCD)does not work at large distance,such as the length scale of a hadron,which is the regime of non-perturbative QCD.The detailed QCD mechanisms through which confinement occurs from partons to hadrons(usually known as hadronization),and how it manifests itself in partonic structure of hadrons(usually known as parton distribution),remain unresolved puzzles of first-principle QCD calculations.
基金supported in part by the Pioneer Research and Development Program of Zhejiang(2025C01021)Zhejiang Province Postdoctoral Research Project Selection Fund(ZJ2025061)+3 种基金the National Science and Technology Major Project-Intelligent Manufacturing Systems and Robotics of China(2025ZD1602000,2025ZD1601800)the National Natural Science Foundation of China(61933015,62273030,62573387)the Natural Science Foundation of Zhejiang province,China(LY24F030004)the Fundamental Research Funds of Zhejiang Sci-Tech University(25222139-Y)。
文摘Ironmaking process(IP)is indispensable to modern iron and steel industry,where real-time monitoring is crucial for achieving high molten iron quality(MIQ)with low energy consumption.While neural network-based models show some promising results,they are generally limited by non-negligible drawbacks such as interpretability issues of feature learning.To address these issues,we propose a novel concept based on the shallow-to-deep correlation network representation regression(Sh-to-De CNRR).Our approach,shallow correlation network representation regression(ShCNRR),combines neural network and canonical correlation analysis thoughts to generate explainable features via shallow correlation network representation(CNR).A twin inverse network is then derived to obtain the explicit model output,leveraging the shallow CNR.To capture deeper nonlinear information,we extend ShCNRR into a hierarchical deep correlation network representation regression(DeCNRR)model that features stacked neural networks,enabling us to learn deeper CNR from process data.The feasibility and advantages of our proposals are validated by theoretical derivations and practical IP cases,which contain one MIQ regression and three MIQ-related fault detection tasks.The results reveal that highly fused statistical and neural network models yield superior monitoring performance compared to current state-of-the-art models,while statistical tests verify the convincing feature mining.
