Natural gas hydrates widely accumulate in submarine sediments composed of clay minerals.However,due to the complex physiochemistry and micron-sized particles of clay minerals,their effects on methane hydrate(MH)format...Natural gas hydrates widely accumulate in submarine sediments composed of clay minerals.However,due to the complex physiochemistry and micron-sized particles of clay minerals,their effects on methane hydrate(MH)formation and dissociation are still in controversy.In this study,montmorillonite and illite were separately mixed with quartz sand to investigate their effects on MH formation and dissociation.The microstructure of synthesized samples was observed by cryo-SEM innovatively to understand the effects of montmorillonite and illite on MH phase transition in micron scale.Results show that montmorillonite and illite both show the inhibition on MH formation kinetics and water-to-hydrate conversion,and illite shows a stronger inhibition.The 10 wt%montmorillonite addition significantly retards MH formation rate,and the 20 wt%montmorillonite has a less inhibition on the rate.The increase of illite mass ratio(0-20 wt%)retards the rate of MH formation.As the content of clay minerals increase,the water-to-hydrate conversion decreases.Cryo-SEM images presented that montmorillonite aggregates separate as individual clusters while illite particles pack as face-to-face configuration under the interaction with water.The surface-overlapped illite aggregates would make sediments pack tightly,hinder the contact between gas and water,and result in the more significant inhibition on MH formation kinetics.Under the depressurization method,the addition of clay minerals facilitates MH dissociation rate.Physicochemical properties of clay minerals and MH distribution in the pore space lead to the faster dissociation rate in clay-containing sediments.The results of this study would provide beneficial guides on geological investigations and optimizing strategies of natural gas production in marine hydrate-bearing sediments.展开更多
Morphology and growth rate of carbon dioxide hydrate on the interface between liquid carbon dioxide and humic acid solutions were studied in this work.It was found that after the growth of the hydrate film at the inte...Morphology and growth rate of carbon dioxide hydrate on the interface between liquid carbon dioxide and humic acid solutions were studied in this work.It was found that after the growth of the hydrate film at the interface,further growth of hydrate due to the suction of water in the capillary system formed between the wall of the cuvette and the end boundary of the hydrate layer occurs.Most probably,substantial effects on the formation of this capillary system may be caused by variations in reactor wall properties,for example,hydrophobic-hydrophilic balance,roughness,etc.We found,that the rate of CO_(2) hydrate film growth on the surface of the humic acid aqueous solution is 4-fold to lower in comparison with the growth rate on the surface of pure water.We suppose that this is caused by the adsorption of humic acid associates on the surface of hydrate particles and,as a consequence,by the deceleration of the diffusion of dissolved carbon dioxide to the growing hydrate particle.展开更多
Gas hydrate(GH)is an unconventional resource estimated at 1000-120,000 trillion m^(3)worldwide.Research on GH is ongoing to determine its geological and flow characteristics for commercial produc-tion.After two large-...Gas hydrate(GH)is an unconventional resource estimated at 1000-120,000 trillion m^(3)worldwide.Research on GH is ongoing to determine its geological and flow characteristics for commercial produc-tion.After two large-scale drilling expeditions to study the GH-bearing zone in the Ulleung Basin,the mineral composition of 488 sediment samples was analyzed using X-ray diffraction(XRD).Because the analysis is costly and dependent on experts,a machine learning model was developed to predict the mineral composition using XRD intensity profiles as input data.However,the model’s performance was limited because of improper preprocessing of the intensity profile.Because preprocessing was applied to each feature,the intensity trend was not preserved even though this factor is the most important when analyzing mineral composition.In this study,the profile was preprocessed for each sample using min-max scaling because relative intensity is critical for mineral analysis.For 49 test data among the 488 data,the convolutional neural network(CNN)model improved the average absolute error and coefficient of determination by 41%and 46%,respectively,than those of CNN model with feature-based pre-processing.This study confirms that combining preprocessing for each sample with CNN is the most efficient approach for analyzing XRD data.The developed model can be used for the compositional analysis of sediment samples from the Ulleung Basin and the Korea Plateau.In addition,the overall procedure can be applied to any XRD data of sediments worldwide.展开更多
An efficient acetic acid mediated metal-free oxidative C—H cross coupling of imidazo[1,2-a]pyridines with glyoxal hydrates has been developed under air atmosphere.The present protocol exhibits broad substrate scope,g...An efficient acetic acid mediated metal-free oxidative C—H cross coupling of imidazo[1,2-a]pyridines with glyoxal hydrates has been developed under air atmosphere.The present protocol exhibits broad substrate scope,good functional group tolerance,and enables the construction of a series of 1,2-dicarbonyl imidazo[1,2-a]pyridines in good yields.The reaction mechanism studies suggest that the reactions proceed through the electrophilic substitution and subsequent oxidation pathway.展开更多
During the production of natural gas hydrates,micron-sized sand particles coexist with hydrate within the transportation pipeline,posing a significant threat to the safety of pipeline flow.However,the influence of san...During the production of natural gas hydrates,micron-sized sand particles coexist with hydrate within the transportation pipeline,posing a significant threat to the safety of pipeline flow.However,the influence of sand particles on hydrate formation mechanisms and rheological properties remains poorly understood.Consequently,using a high-pressure reactor system,the phase equilibrium conditions,hydrate formation characteristics,hydrate concentration,and the slurry viscosity in micron-sized sand system are investigated in this work.Furthermore,the effects of sand particle size,sand concentration,and initial pressure on these properties are analyzed.The results indicate that a high concentration of micron-sized sand particles enhances the formation of methane hydrates.When the volume fraction of sand particles exceeds or equals 3%,the phase equilibrium conditions of the methane hydrate shift to the left relative to that of the pure water system(lower temperature,higher pressure).This shift becomes more pronounced with smaller particle sizes.Besides,under these sand concentration conditions,methane hydrates exhibit secondary or even multiple formation events,though the formation rate decreases.Additionally,the torque increases significantly and fluctuates considerably.The Roscoe-Brinkman model yields the most accurate slurry viscosity calculations,and as sand concentration increases,both hydrate concentration and slurry viscosity also increase.展开更多
Shear strength of hydrate-bearing sediment is an essential parameter for assessing landslide potential ofhydrate reservoirs under exploration conditions. However, the characteristics and simulation of thisshear streng...Shear strength of hydrate-bearing sediment is an essential parameter for assessing landslide potential ofhydrate reservoirs under exploration conditions. However, the characteristics and simulation of thisshear strength under varying dissociation conditions have not been thoroughly investigated. To this end,a series of triaxial compression tests were first carried out on sediments with varying initial hydratesaturations along dissociation pathways. Combining measured data with microscale analysis, the underlyingmechanism for the evolution of shear strength in hydrate-bearing sediment was studied undervarying partial dissociation pathways. Moreover, a shear strength model for hydrate-bearing sedimentwas proposed, taking into account the hydrate saturation and the unhydrated water content. Apart fromthe parameters derived from the hydrate characteristic curve, only one additional model parameter isrequired. The proposed model was validated using measured data on hydrate sediments. The resultsindicate that the proposed model can effectively capture the shear strength behavior of hydrate-bearingsediment under varying dissociation paths. Finally, a sensitivity analysis of the model parameters wasconducted to characterize the proposed model.展开更多
The commercial exploitation of natural gas hydrates is currently facing several challenges,including low production rates,limited recovery areas,and brief periods of continuous production.To address these issues,we pr...The commercial exploitation of natural gas hydrates is currently facing several challenges,including low production rates,limited recovery areas,and brief periods of continuous production.To address these issues,we propose a novel dual-enhanced stimulation(DES)method for marine hydrate reservoirs.This method involves injecting a special slurry that solidifies into porous,high-permeability,and highstrength slurry veins.These veins not only enhance permeability,allowing for faster gas and water flow,but also improve reservoir stability.This study experimentally investigated the split grouting of clayey-silty sediments with dual-enhanced slurry to assess the feasibility of DES and to explo re the slurry diffusion mechanism and micro-pore structure of the veins.The results showed that split grouting with dual-enhanced slurry exhibited frequent fracture initiation with quick pressure spikes and sharp declines,suggesting shorter fractures in clayey-silty sediments.As vertical stress increased,the primary diffusion direction of the dual-enhanced slurry shifted from horizontal to vertical,aligning with fracture propagation patterns observed during fracturing.Unlike hydraulic fracturing in hard rocks,split grouting in clayey-silty sediments encountered more difficult conditions.These veins formed through a recurring cycle of splitting into fractures and filling with slurry,occurring more frequently in weaker sediments with slower injection rates and higher vertical stress.Increased vertical stress hindered slurry vein diffu sion,easily resulting in compaction grouting near the grouting pipe.Additionally,three-dimensional laser scanning of the veins showed that those formed through split grouting were continuous and stable,with their thickness decreasing as diffusion distance increased.The morphology of these veins was shaped by factors such as grouting rate,formation stress,and elastic modulus,with higher rates and elastic moduli facilitating the formation of complex vein networks.Mercury intrusion porosimetry demonstrated that the DES method resulted in veins with consistent effective porosity between 65%and70%and median pore sizes of 11-15μm across different locations.These veins formed a well-connected porous network of smaller pores,significantly enhancing both permeability and sand control.The research findings validate the effectiveness of the DES method for marine hydrate reservoirs,providing a strategy for the safe and efficient exploitation of NGH resources.展开更多
Natural gas hydrate is a clean energy source with substantial resource potential.In contrast to conventional oil and gas,natural gas hydrate exists as a multi-phase system consisting of solids,liquids,and gases,which ...Natural gas hydrate is a clean energy source with substantial resource potential.In contrast to conventional oil and gas,natural gas hydrate exists as a multi-phase system consisting of solids,liquids,and gases,which presents unique challenges and complicates the mechanisms of seepage and exploitation.Both domestic and international natural gas hydrate production tests typically employ a single-well production model.Although this approach has seen some success,it continues to be hindered by low production rates and short production cycles.Therefore,there is an urgent need to explore a new well network to significantly increase the production of a single well.This paper provides a comprehensive review of the latest advancements in natural gas hydrate research,including both laboratory studies and field tests.It further examines the gas production processes and development outcomes for single wells,dual wells,multi-branch wells,and multi-well systems under conditions of depressurization,thermal injection,and CO_(2) replacement.On this basis,well types and well networks suitable for commercial exploitation of natural gas hydrate were explored,and the technical direction of natural gas hydrate development was proposed.The study shows that fully exploiting the flexibility of complex structural wells and designing a well network compatible with the reservoir is the key to improving production from a single well.Moreover,multi-well joint exploitation is identified as an effective strategy for achieving large-scale,efficient development of natural gas hydrate.展开更多
The oil-based mud(OBM) borehole measurement environment presents significant limitations on the application of existing electrical logging instruments in high-resistance formations. In this paper, we propose a novel l...The oil-based mud(OBM) borehole measurement environment presents significant limitations on the application of existing electrical logging instruments in high-resistance formations. In this paper, we propose a novel logging method for detection of high-resistance formations in OBM using highfrequency electrodes. The method addresses the issue of shallow depth of investigation(DOI) in existing electrical logging instruments, while simultaneously ensuring the vertical resolution. Based on the principle of current continuity, the total impedance of the loop is obtained by equating the measurement loop to the series form of a capacitively coupled circuit. and its validity is verified in a homogeneous formation model and a radial two-layer formation model with a mud standoff. Then, the instrument operating frequency and electrode system parameters were preferentially determined by numerical simulation, and the effect of mud gap on impedance measurement was investigated. Subsequently, the DOI of the instrument was investigated utilizing the pseudo-geometric factor defined by the real part of impedance. It was determined that the detection depth of the instrument is 8.74 cm, while the effective vertical resolution was not less than 2 cm. Finally, a focused high-frequency electrode-type instrument was designed by introducing a pair of focused electrodes, which effectively enhanced the DOI of the instrument and was successfully deployed in the Oklahoma formation model. The simulation results demonstrate that the novel method can achieve a detection depth of 17.40 cm in highly-resistive formations drilling with OBM, which is approximately twice the depth of detection of the existing oil-based mud microimager instruments. Furthermore, its effective vertical resolution remains at or above 2 cm,which is comparable to the resolution of the existing OBM electrical logging instrument.展开更多
Two-dimensional(2D) nanomaterials have always been regarded as having great development potential in the field of oil-based lubrication due to their designable structures,functional groups,and abundant active sites.Ho...Two-dimensional(2D) nanomaterials have always been regarded as having great development potential in the field of oil-based lubrication due to their designable structures,functional groups,and abundant active sites.However,understanding the structure-performance relationship between the chemical structure of 2D nanomaterials and their lubrication performance from a comprehensive perspective is crucial for guiding their future development.This review provides a timely and comprehensive overview of the applications of 2D nanomaterials in oil-based lubrication.First,the bottlenecks and mechanisms of action of 2D nanomaterials are outlined,including adsorption protective films,charge adsorption effects,tribochemical reaction films,interlayer slip,and synergistic effects.On this basis,the review summarizes recent structural regulation strategies for 2D nanomaterials,including doping engineering,surface modification,structural optimization,and interfacial mixing engineering.Then,the focus was on analyzing the structure-performance relationship between the chemical structure of 2D nanomaterials and their lubrication performance.The effects of thickness,number of layers,sheet diameter,interlayer spacing,Moiré patterns,wettability,functional groups,concentration,as well as interfacial compatibility and dispersion behavior of 2D nanomaterials were systematically investigated in oil-based lubrication,with the intrinsic correlations resolved through computational simulations.Finally,the review offers a preliminary summary of the significant challenges and future directions for 2D nanomaterials in oil-based lubrication.This review aims to provide valuable insights and development strategies for the rational design of high-performance oil-based lubrication materials.展开更多
Field tests have demonstrated that depressurization with controlled sand production is an effective technique for natural gas hydrate extraction.Variations in depositional environments and processes result in signific...Field tests have demonstrated that depressurization with controlled sand production is an effective technique for natural gas hydrate extraction.Variations in depositional environments and processes result in significant heterogeneity within subsea natural gas hydrate-bearing sediments.However,the influence of permeability heterogeneity on production performance during depressurization with controlled sand production remains inadequately understood.In this study,a multiphase,multi-component mathematical model is developed to simulate depressurization with controlled sand production in methane hydrate-bearing sediments,incorporating geological conditions representative of unconsolidated argillaceous siltstone hydrate deposits in the Shenhu area of the South China Sea.The effects of permeability heterogeneity-specifically,horizontal autocorrelation length and global permeability heterogeneity-on production performance during depressurization with sand production are investigated using geostatistical modeling combined with finite difference method based numerical simulations.Results show that as the horizontal autocorrelation length of permeability distribution increases,cumulative gas production first rises and then declines,reaching its peak at λ_(Dh)=0.1,whereas sand production steadily increases.In addition,higher formation permeability heterogeneity results in increased cumulative gas and sand production,suggesting that greater heterogeneity promotesmethane hydrate decomposition and gas recovery.These findings can offer valuable insights for optimizing future field development of hydrate-bearing sediments by depressurization with controlled sand production.展开更多
BACKGROUND Oil-based iodinated contrast media have excellent contrast properties and are widely used for hysterosalpingographic evaluation of female infertility.On abdominal radiography and computed tomography(CT)scan...BACKGROUND Oil-based iodinated contrast media have excellent contrast properties and are widely used for hysterosalpingographic evaluation of female infertility.On abdominal radiography and computed tomography(CT)scans,their radiodensity is similar to that of metallic objects,which can sometimes lead to diagnostic confusion in the postoperative settings.In this case,retained oil-based contrast medium was observed on an abdominal radiograph following a cesarean section,making it difficult to differentiate from an intraperitoneal foreign body from surgery.The patient was a 37-year-old pregnant woman who was referred to our hospital at 32 weeks and 1 day of pregnancy due to complete placenta previa for mana-gement of pregnancy and delivery.An elective cesarean section was performed at 37 weeks and 3 days.A plain abdominal radiograph taken immediately after surgery revealed a near-round,hyperdense,mass-like shadow with a regular margin in the pelvic cavity.An intraperitoneal foreign body was suspected;therefore,an abdominal CT scan was performed.The foreign body was located on the left side of the pouch of Douglas and had a CT value of 7000 Hounsfield units,similar to that of metals.The CT value strongly suggested the presence of an artificial object.However,further inquiries with the patient and her previous physician revealed a history of hysterosalpingography.Accordingly,retained oil-based iodinated contrast medium was suspected,and observation of the object’s course was adopted.CONCLUSION When intraperitoneal foreign bodies are suspected on postoperative radiographs,the possibility of oil-based iodinated contrast medium retention should be considered.展开更多
As a kind of novel environmental-friendly surfactant,Gemini surfactant has attracted extensive research interests in its effects on gas hydrate formation.We investigated the effects of dioctyl sodium sulfosuccinate(AO...As a kind of novel environmental-friendly surfactant,Gemini surfactant has attracted extensive research interests in its effects on gas hydrate formation.We investigated the effects of dioctyl sodium sulfosuccinate(AOT)on the formation thermodynamics/kinetics of CH_(4)and CO_(2)hydrates.Experimental results indicate that while AOT does not exhibit significant thermodynamic promotion for hydrate formation,it demonstrates favorable kinetic promotion effects.Its promotion effect surpasses that of the traditional kinetic promoter SDS and can enhance the gas storage capacity of hydrates.Utilizing the Chen-Guo hydrate model and adsorption kinetic model,we established a kinetic model for AOT with a predictive deviation of 7.17%and fitted key parameters accordingly.展开更多
Molecular dynamics simulations were performed to study the microscopic working mechanism of fast hydrate formation from active ice.We successfully simulated the cyclic process of ice melt-hydrate formation-ice melt.Th...Molecular dynamics simulations were performed to study the microscopic working mechanism of fast hydrate formation from active ice.We successfully simulated the cyclic process of ice melt-hydrate formation-ice melt.The simulation results showed that active ice could significantly accelerate the formation of hydrates and exhibit high gas sto rage capacity.The oxygen atoms of the sulfate group in SDS formed hydrogen bonds with the hydrogen atoms of water molecules in the ice,destroying the orderly arranged structures of the ice surface.SDS also acted as a promoter to accelerate the mass transfer of vips in the liquid phase,thereby promoting the nucleation and growth of hydrates.The ordered structures of liquid phase formed by ice melting and the formation of cage-like structures facilitated by ice surface defects were beneficial to the nucleation and growth of hydrates.The formation of the hydrate shell accelerated the migration of the vips from the gas phase to the liquid phase.As the ice continued to melt,sufficient vips and water molecules ensured the stable growth of hydrates.展开更多
Natural gas hydrates are crystalline solid complexes with different morphologies found in marine sediments and permafrost zones. The petrophysical properties of gas hydrate-bearing sediments(GHBS) are crucial for unde...Natural gas hydrates are crystalline solid complexes with different morphologies found in marine sediments and permafrost zones. The petrophysical properties of gas hydrate-bearing sediments(GHBS) are crucial for understanding the characteristics of gas hydrate reservoirs, the spatial distribution of natural gas hydrates, and their exploitation potential. Geophysical exploration remains the primary approach for investigating the petrophysical properties of GHBS. However, limitations in resolution make it challenging to accurately characterize complex sediment structures, leading to difficulties in precisely interpreting petrophysical properties. Laboratory-based petrophysical experiments provide highly accurate results for petrophysical properties. Despite their accuracy, these experiments are costly, and difficulties in controlling variables may introduce uncertainties into geophysical exploration models.Advances in imaging and simulation techniques have established digital rock technology as an indispensable tool for enhancing petrophysical experimentation. This technology offers a novel microscopic perspective for elucidating the three-dimensional(3D) spatial distribution and multi-physical responses of GHBS. This paper presents an in-depth discussion of digital rock technology as applied to GHBS, with an emphasis on digital rock reconstruction and simulation of petrophysical properties. First, we summarize two common methods for constructing digital rocks of GHBS: petrophysical experimental methods and numerical reconstruction methods, followed by analyses of their respective advantages and limitations. Next, we delve into numerical simulation methods for evaluating GHBS petrophysical properties, including electrical, elastic, and fluid flow characteristics. Finally, we conduct a comprehensive analysis of the current trends in digital rock reconstruction and petrophysical simulation techniques for GHBS, emphasizing the necessity of multi-scale, multi-component, high-resolution 3D digital rock models to facilitate the precise characterization of complex gas hydrate reservoirs. Future applications of microscopic digital rock technology should be integrated with macroscopic geophysical exploration to enable more comprehensive and precise analyses of GHBS petrophysical properties.展开更多
Natural gas hydrate widely exists in the South China Sea as clean energy.A three-phase transition layer widely exists in low permeability Class I hydrates in the Shenhu offshore area.Therefore,taking into account the ...Natural gas hydrate widely exists in the South China Sea as clean energy.A three-phase transition layer widely exists in low permeability Class I hydrates in the Shenhu offshore area.Therefore,taking into account the low-permeability characteristics with an average permeability of 5.5 mD and moderate heterogeneity,a 3-D geological model of heterogeneous Class I hydrate reservoirs with three-phase transition layers is established by Kriging interpolation and stochastic modeling method,and a numerical simulation model is used to describe the depressurization production performance of the reservoir.With the development of depressurization,a specific range of complete decomposition zones appear both in the hydrate and transition layers.The entire decomposition zone of the whole reservoir tends to outward and upward diffusion.There is apparent methane escape in the three-phase transition layer.Due to the improvement of local permeability caused by the phase transition of hydrate dissociation,some methane accumulation occurs at the bottom of the hydrate layer,forming a local methane enrichment zone.The methane migration trends in reservoirs are mainly characterized by movement toward production wells and hydrate layers under the influence of gravity.However,due to the permeability limitation of hydrate reservoirs,many fluids have not been effectively produced and remain in the reservoir.Therefore,to improve the effective pressure drop of the reservoir,the perforation method and pressure reduction method were optimized by analyzing the influencing factors based on the gas production rate.The comparative study demonstrates that perforating through the free gas layer combined with one-time depressurization can enhance the effective depressurization and improve production performance.The gas production rate from perforating through the free gas layer can be twice as high as that from perforating through the transition layer.This study can provide theoretical support for the utilization of marine energy.展开更多
Natural gas hydrates are widely distributed in marine and permafrost environments.As a novel energy resource,accurately describing reservoir characteristics and assessing energy potential is crucial for its commercial...Natural gas hydrates are widely distributed in marine and permafrost environments.As a novel energy resource,accurately describing reservoir characteristics and assessing energy potential is crucial for its commercial development.Resistivity logging serves as a valuable approach for achieving these goals.Nevertheless,due to inadequate comprehension of the electrical conductivity mechanism in hydrate-bearing sediments,existing data processing models still encounter certain challenges.This study conducts both core-scale and pore-scale simulation experiments to examine the relationship between resistivity variations and the distribution of gas hydrate porosity.The results indicate that the characteristics of resistivity variation is associated with the gas hydrate formation process,and the gas hydrate saturation index,denoted as‘n',varies between 0 and 3 depending on different gas hydrate distribution patterns.As the saturation increases,gas hydrate distribution in pore spaces transitions from floating to contacting and cementing patterns.It is proposed that the aqueous pore tortuosity can be utilized to correct the saturation index‘n'in Archie's equation.Based on the analysis of experimental data,a correction method for Archie's equation is suggested,and its effectiveness in controlling relative error has been validated.展开更多
The National Gas Hydrate Program expeditions(NGHP-01 and-02)have conclusively proven the presence of hydrate deposits on the eastern coast of India.The novelty of the present study lies in its investigation of the ric...The National Gas Hydrate Program expeditions(NGHP-01 and-02)have conclusively proven the presence of hydrate deposits on the eastern coast of India.The novelty of the present study lies in its investigation of the richest gas hydrate deposit(hydrate saturation[Sh]>0.75),NGHP-01-10D,in the Krishna-Godavari(KG)Basin,India.The study presents a first look at the long-term gas production viability using a single vertical well,subjected to variations in production interval and bottom hole pressure.Specifically,we compared the gas production at bottom hole pressures of 3-6 MPa and production intervals of 20-40 m.The results indicate production rates that are technically feasible but lower than commercially acceptable standards.Increasing the bottom hole pressure drawdown from 6 MPa to 3 MPa increased the gas production from 1297 m^(3)/d to 4902 m^(3)/d(i.e.,more than tripling the average daily gas production).Meanwhile,while expanding the production interval from 20 m to 40 m led to an increase in gas production,it also resulted in higher water production.As a result,the average gas-to-water ratio(RGW)decreased from 9.5 to 5.3 with the expansion of the production interval,thereby highlighting the need to optimize the interval length.Furthermore,the spatial evolution of certain thermodynamic parameters,including pressure,temperature,and phase saturation(methane,water,and hydrate),underscores the critical role of heat transfer from the UB.Our study findings offer valuable insights for long-term production forecasting,the delineation of phase evolution patterns,and the identification of potential flow barriers that may impede deliverability.展开更多
Natural gas hydrates(hereinafter referred to as hydrates)are a promising clean energy source.However,their current development is far from reaching commercial exploitation.Reservoir stimulation tech-nology provides ne...Natural gas hydrates(hereinafter referred to as hydrates)are a promising clean energy source.However,their current development is far from reaching commercial exploitation.Reservoir stimulation tech-nology provides new approaches to enhance hydrate development effectiveness.Addressing the current lack of quantitative and objective methods for evaluating the fracability of hydrate reservoirs,this study clarifies the relationship between geological and engineering fracability and proposes a comprehensive evaluation model for hydrate reservoir fracability based on grey relational analysis and the criteria importance through intercriteria correlation method.By integrating results from hydraulic fracturing experiments on hydrate sediments,the fracability of hydrate reservoirs is assessed.The concept of critical construction parameter curves for hydrate reservoirs is introduced for the first time.Additionally,two-dimensional fracability index evaluation charts and three-dimensional fracability construction condition discrimination charts are established.The results indicate that as the comprehensive fracability index increases,the feasibility of forming fractures in hydrate reservoirs improves,and the required normalized fracturing construction parameters gradually decrease.The accuracy rate of the charts in judging experimental results reached 89.74%,enabling quick evaluations of whether hydrate reservoirs are worth fracturing,easy to fracture,and capable of being fractured.This has significant engineering implications forthehydraulicfracturingof hydratereservoirs.展开更多
Extracted natural gas hydrate is a multi-phase and multi-component mixture,and its complex composition poses significant challenges for transmission and transportation,including phase changes following extraction and ...Extracted natural gas hydrate is a multi-phase and multi-component mixture,and its complex composition poses significant challenges for transmission and transportation,including phase changes following extraction and sediment deposition within the pipeline.This study examines the flow and heat transfer characteristics of hydrates in a riser,focusing on the multi-phase flow behavior of natural gas hydrate in the development riser.Additionally,the effects of hydrate flow and seawater temperature on heat exchange are analyzed by simulating the ambient temperature conditions of the South China Sea.The findings reveal that the increase in unit pressure drop is primarily attributed to higher flowvelocities,which result in increased friction of the hydrate flowwithin the development riser.For example,at a hydrate volume fraction of 10%,the unit pressure drop rises by 166.65%and 270.81% when the average inlet velocity is increased from1.0 to 3.0m/s(a two-fold increase)and 5.0 m/s(a four-fold increase),respectively.Furthermore,the riser outlet temperature rises with increasing hydrate flowrates.Under specific heat loss conditions,the flowratemust exceed a minimum threshold to ensure safe transportation.The study also indicates that the riser outlet temperature increases with higher seawater temperatures.Within the seawater temperature range of 5℃ to 15℃,the heat transfer efficiency is reduced compared to the range of 15℃ to 20℃.This discrepancy is due to the fact that as the seawater temperature rises,the convective heat transfer coefficient between the hydrate and the inner wall of the riser also increases,leading to improved overall heat transfer between the hydrate and the pipeline.展开更多
基金supported by the Key Research Program of the Institute of Geology&Geophysics,CAS(Grant No.IGGCAS-201903).
文摘Natural gas hydrates widely accumulate in submarine sediments composed of clay minerals.However,due to the complex physiochemistry and micron-sized particles of clay minerals,their effects on methane hydrate(MH)formation and dissociation are still in controversy.In this study,montmorillonite and illite were separately mixed with quartz sand to investigate their effects on MH formation and dissociation.The microstructure of synthesized samples was observed by cryo-SEM innovatively to understand the effects of montmorillonite and illite on MH phase transition in micron scale.Results show that montmorillonite and illite both show the inhibition on MH formation kinetics and water-to-hydrate conversion,and illite shows a stronger inhibition.The 10 wt%montmorillonite addition significantly retards MH formation rate,and the 20 wt%montmorillonite has a less inhibition on the rate.The increase of illite mass ratio(0-20 wt%)retards the rate of MH formation.As the content of clay minerals increase,the water-to-hydrate conversion decreases.Cryo-SEM images presented that montmorillonite aggregates separate as individual clusters while illite particles pack as face-to-face configuration under the interaction with water.The surface-overlapped illite aggregates would make sediments pack tightly,hinder the contact between gas and water,and result in the more significant inhibition on MH formation kinetics.Under the depressurization method,the addition of clay minerals facilitates MH dissociation rate.Physicochemical properties of clay minerals and MH distribution in the pore space lead to the faster dissociation rate in clay-containing sediments.The results of this study would provide beneficial guides on geological investigations and optimizing strategies of natural gas production in marine hydrate-bearing sediments.
基金supported by the Russian Science Foundation(23-29-00830).
文摘Morphology and growth rate of carbon dioxide hydrate on the interface between liquid carbon dioxide and humic acid solutions were studied in this work.It was found that after the growth of the hydrate film at the interface,further growth of hydrate due to the suction of water in the capillary system formed between the wall of the cuvette and the end boundary of the hydrate layer occurs.Most probably,substantial effects on the formation of this capillary system may be caused by variations in reactor wall properties,for example,hydrophobic-hydrophilic balance,roughness,etc.We found,that the rate of CO_(2) hydrate film growth on the surface of the humic acid aqueous solution is 4-fold to lower in comparison with the growth rate on the surface of pure water.We suppose that this is caused by the adsorption of humic acid associates on the surface of hydrate particles and,as a consequence,by the deceleration of the diffusion of dissolved carbon dioxide to the growing hydrate particle.
基金supported by the Gas Hydrate R&D Organization and the Korea Institute of Geoscience and Mineral Resources(KIGAM)(GP2021-010)supported by the National Research Foundation of Korea(NRF)grant funded by the Korean government(MSIT)(No.2021R1C1C1004460)Korea Institute of Energy Technology Evaluation and Planning(KETEP)grant funded by the Korean government(MOTIE)(20214000000500,Training Program of CCUS for Green Growth).
文摘Gas hydrate(GH)is an unconventional resource estimated at 1000-120,000 trillion m^(3)worldwide.Research on GH is ongoing to determine its geological and flow characteristics for commercial produc-tion.After two large-scale drilling expeditions to study the GH-bearing zone in the Ulleung Basin,the mineral composition of 488 sediment samples was analyzed using X-ray diffraction(XRD).Because the analysis is costly and dependent on experts,a machine learning model was developed to predict the mineral composition using XRD intensity profiles as input data.However,the model’s performance was limited because of improper preprocessing of the intensity profile.Because preprocessing was applied to each feature,the intensity trend was not preserved even though this factor is the most important when analyzing mineral composition.In this study,the profile was preprocessed for each sample using min-max scaling because relative intensity is critical for mineral analysis.For 49 test data among the 488 data,the convolutional neural network(CNN)model improved the average absolute error and coefficient of determination by 41%and 46%,respectively,than those of CNN model with feature-based pre-processing.This study confirms that combining preprocessing for each sample with CNN is the most efficient approach for analyzing XRD data.The developed model can be used for the compositional analysis of sediment samples from the Ulleung Basin and the Korea Plateau.In addition,the overall procedure can be applied to any XRD data of sediments worldwide.
文摘An efficient acetic acid mediated metal-free oxidative C—H cross coupling of imidazo[1,2-a]pyridines with glyoxal hydrates has been developed under air atmosphere.The present protocol exhibits broad substrate scope,good functional group tolerance,and enables the construction of a series of 1,2-dicarbonyl imidazo[1,2-a]pyridines in good yields.The reaction mechanism studies suggest that the reactions proceed through the electrophilic substitution and subsequent oxidation pathway.
基金supported by the Natural Science Starting Project of Sichuan Provincial Youth Foundation Project(2025ZNSFSC1356)Southwest Petroleum University,China(2023QHZ019)+1 种基金General Project of the Sichuan Provincial Natural Science Foundation,China(24NSFSC1295)Open fund of Dazhou Industrial Technology Institute of Intelligent Manufacturing,China(ZNZZ2215).
文摘During the production of natural gas hydrates,micron-sized sand particles coexist with hydrate within the transportation pipeline,posing a significant threat to the safety of pipeline flow.However,the influence of sand particles on hydrate formation mechanisms and rheological properties remains poorly understood.Consequently,using a high-pressure reactor system,the phase equilibrium conditions,hydrate formation characteristics,hydrate concentration,and the slurry viscosity in micron-sized sand system are investigated in this work.Furthermore,the effects of sand particle size,sand concentration,and initial pressure on these properties are analyzed.The results indicate that a high concentration of micron-sized sand particles enhances the formation of methane hydrates.When the volume fraction of sand particles exceeds or equals 3%,the phase equilibrium conditions of the methane hydrate shift to the left relative to that of the pure water system(lower temperature,higher pressure).This shift becomes more pronounced with smaller particle sizes.Besides,under these sand concentration conditions,methane hydrates exhibit secondary or even multiple formation events,though the formation rate decreases.Additionally,the torque increases significantly and fluctuates considerably.The Roscoe-Brinkman model yields the most accurate slurry viscosity calculations,and as sand concentration increases,both hydrate concentration and slurry viscosity also increase.
基金supported by the National Natural Science Foundation of China(Grant No.51939011)the Science and Technology Program of CNOOC Research Institute(Grant No.2023OTKK03)supported by the program of the Youth Innovation Promotion Association,Chinese Academy of Sciences(Grant No.2020326).
文摘Shear strength of hydrate-bearing sediment is an essential parameter for assessing landslide potential ofhydrate reservoirs under exploration conditions. However, the characteristics and simulation of thisshear strength under varying dissociation conditions have not been thoroughly investigated. To this end,a series of triaxial compression tests were first carried out on sediments with varying initial hydratesaturations along dissociation pathways. Combining measured data with microscale analysis, the underlyingmechanism for the evolution of shear strength in hydrate-bearing sediment was studied undervarying partial dissociation pathways. Moreover, a shear strength model for hydrate-bearing sedimentwas proposed, taking into account the hydrate saturation and the unhydrated water content. Apart fromthe parameters derived from the hydrate characteristic curve, only one additional model parameter isrequired. The proposed model was validated using measured data on hydrate sediments. The resultsindicate that the proposed model can effectively capture the shear strength behavior of hydrate-bearingsediment under varying dissociation paths. Finally, a sensitivity analysis of the model parameters wasconducted to characterize the proposed model.
基金financial support received from the National Natural Science Foundation of China(Nos.51991364,and 42202347)。
文摘The commercial exploitation of natural gas hydrates is currently facing several challenges,including low production rates,limited recovery areas,and brief periods of continuous production.To address these issues,we propose a novel dual-enhanced stimulation(DES)method for marine hydrate reservoirs.This method involves injecting a special slurry that solidifies into porous,high-permeability,and highstrength slurry veins.These veins not only enhance permeability,allowing for faster gas and water flow,but also improve reservoir stability.This study experimentally investigated the split grouting of clayey-silty sediments with dual-enhanced slurry to assess the feasibility of DES and to explo re the slurry diffusion mechanism and micro-pore structure of the veins.The results showed that split grouting with dual-enhanced slurry exhibited frequent fracture initiation with quick pressure spikes and sharp declines,suggesting shorter fractures in clayey-silty sediments.As vertical stress increased,the primary diffusion direction of the dual-enhanced slurry shifted from horizontal to vertical,aligning with fracture propagation patterns observed during fracturing.Unlike hydraulic fracturing in hard rocks,split grouting in clayey-silty sediments encountered more difficult conditions.These veins formed through a recurring cycle of splitting into fractures and filling with slurry,occurring more frequently in weaker sediments with slower injection rates and higher vertical stress.Increased vertical stress hindered slurry vein diffu sion,easily resulting in compaction grouting near the grouting pipe.Additionally,three-dimensional laser scanning of the veins showed that those formed through split grouting were continuous and stable,with their thickness decreasing as diffusion distance increased.The morphology of these veins was shaped by factors such as grouting rate,formation stress,and elastic modulus,with higher rates and elastic moduli facilitating the formation of complex vein networks.Mercury intrusion porosimetry demonstrated that the DES method resulted in veins with consistent effective porosity between 65%and70%and median pore sizes of 11-15μm across different locations.These veins formed a well-connected porous network of smaller pores,significantly enhancing both permeability and sand control.The research findings validate the effectiveness of the DES method for marine hydrate reservoirs,providing a strategy for the safe and efficient exploitation of NGH resources.
基金This work was supported by the projects of the China Geological Survey(DD 20221703).
文摘Natural gas hydrate is a clean energy source with substantial resource potential.In contrast to conventional oil and gas,natural gas hydrate exists as a multi-phase system consisting of solids,liquids,and gases,which presents unique challenges and complicates the mechanisms of seepage and exploitation.Both domestic and international natural gas hydrate production tests typically employ a single-well production model.Although this approach has seen some success,it continues to be hindered by low production rates and short production cycles.Therefore,there is an urgent need to explore a new well network to significantly increase the production of a single well.This paper provides a comprehensive review of the latest advancements in natural gas hydrate research,including both laboratory studies and field tests.It further examines the gas production processes and development outcomes for single wells,dual wells,multi-branch wells,and multi-well systems under conditions of depressurization,thermal injection,and CO_(2) replacement.On this basis,well types and well networks suitable for commercial exploitation of natural gas hydrate were explored,and the technical direction of natural gas hydrate development was proposed.The study shows that fully exploiting the flexibility of complex structural wells and designing a well network compatible with the reservoir is the key to improving production from a single well.Moreover,multi-well joint exploitation is identified as an effective strategy for achieving large-scale,efficient development of natural gas hydrate.
基金the National Natural Science Foundation of China(42074134,42474152,42374150)CNPC Innovation Found(2024DQ02-0152).
文摘The oil-based mud(OBM) borehole measurement environment presents significant limitations on the application of existing electrical logging instruments in high-resistance formations. In this paper, we propose a novel logging method for detection of high-resistance formations in OBM using highfrequency electrodes. The method addresses the issue of shallow depth of investigation(DOI) in existing electrical logging instruments, while simultaneously ensuring the vertical resolution. Based on the principle of current continuity, the total impedance of the loop is obtained by equating the measurement loop to the series form of a capacitively coupled circuit. and its validity is verified in a homogeneous formation model and a radial two-layer formation model with a mud standoff. Then, the instrument operating frequency and electrode system parameters were preferentially determined by numerical simulation, and the effect of mud gap on impedance measurement was investigated. Subsequently, the DOI of the instrument was investigated utilizing the pseudo-geometric factor defined by the real part of impedance. It was determined that the detection depth of the instrument is 8.74 cm, while the effective vertical resolution was not less than 2 cm. Finally, a focused high-frequency electrode-type instrument was designed by introducing a pair of focused electrodes, which effectively enhanced the DOI of the instrument and was successfully deployed in the Oklahoma formation model. The simulation results demonstrate that the novel method can achieve a detection depth of 17.40 cm in highly-resistive formations drilling with OBM, which is approximately twice the depth of detection of the existing oil-based mud microimager instruments. Furthermore, its effective vertical resolution remains at or above 2 cm,which is comparable to the resolution of the existing OBM electrical logging instrument.
基金supported by the National Natural Science Foundation of China(No.51874036)the Natural Science Foundation of Ningxia(No.2024AAC02034)。
文摘Two-dimensional(2D) nanomaterials have always been regarded as having great development potential in the field of oil-based lubrication due to their designable structures,functional groups,and abundant active sites.However,understanding the structure-performance relationship between the chemical structure of 2D nanomaterials and their lubrication performance from a comprehensive perspective is crucial for guiding their future development.This review provides a timely and comprehensive overview of the applications of 2D nanomaterials in oil-based lubrication.First,the bottlenecks and mechanisms of action of 2D nanomaterials are outlined,including adsorption protective films,charge adsorption effects,tribochemical reaction films,interlayer slip,and synergistic effects.On this basis,the review summarizes recent structural regulation strategies for 2D nanomaterials,including doping engineering,surface modification,structural optimization,and interfacial mixing engineering.Then,the focus was on analyzing the structure-performance relationship between the chemical structure of 2D nanomaterials and their lubrication performance.The effects of thickness,number of layers,sheet diameter,interlayer spacing,Moiré patterns,wettability,functional groups,concentration,as well as interfacial compatibility and dispersion behavior of 2D nanomaterials were systematically investigated in oil-based lubrication,with the intrinsic correlations resolved through computational simulations.Finally,the review offers a preliminary summary of the significant challenges and future directions for 2D nanomaterials in oil-based lubrication.This review aims to provide valuable insights and development strategies for the rational design of high-performance oil-based lubrication materials.
基金funded by the National Key Research and Development Program of China(grant number 2023YFC3009204)the National Natural Science Foundation of China(grant number 52174015).
文摘Field tests have demonstrated that depressurization with controlled sand production is an effective technique for natural gas hydrate extraction.Variations in depositional environments and processes result in significant heterogeneity within subsea natural gas hydrate-bearing sediments.However,the influence of permeability heterogeneity on production performance during depressurization with controlled sand production remains inadequately understood.In this study,a multiphase,multi-component mathematical model is developed to simulate depressurization with controlled sand production in methane hydrate-bearing sediments,incorporating geological conditions representative of unconsolidated argillaceous siltstone hydrate deposits in the Shenhu area of the South China Sea.The effects of permeability heterogeneity-specifically,horizontal autocorrelation length and global permeability heterogeneity-on production performance during depressurization with sand production are investigated using geostatistical modeling combined with finite difference method based numerical simulations.Results show that as the horizontal autocorrelation length of permeability distribution increases,cumulative gas production first rises and then declines,reaching its peak at λ_(Dh)=0.1,whereas sand production steadily increases.In addition,higher formation permeability heterogeneity results in increased cumulative gas and sand production,suggesting that greater heterogeneity promotesmethane hydrate decomposition and gas recovery.These findings can offer valuable insights for optimizing future field development of hydrate-bearing sediments by depressurization with controlled sand production.
文摘BACKGROUND Oil-based iodinated contrast media have excellent contrast properties and are widely used for hysterosalpingographic evaluation of female infertility.On abdominal radiography and computed tomography(CT)scans,their radiodensity is similar to that of metallic objects,which can sometimes lead to diagnostic confusion in the postoperative settings.In this case,retained oil-based contrast medium was observed on an abdominal radiograph following a cesarean section,making it difficult to differentiate from an intraperitoneal foreign body from surgery.The patient was a 37-year-old pregnant woman who was referred to our hospital at 32 weeks and 1 day of pregnancy due to complete placenta previa for mana-gement of pregnancy and delivery.An elective cesarean section was performed at 37 weeks and 3 days.A plain abdominal radiograph taken immediately after surgery revealed a near-round,hyperdense,mass-like shadow with a regular margin in the pelvic cavity.An intraperitoneal foreign body was suspected;therefore,an abdominal CT scan was performed.The foreign body was located on the left side of the pouch of Douglas and had a CT value of 7000 Hounsfield units,similar to that of metals.The CT value strongly suggested the presence of an artificial object.However,further inquiries with the patient and her previous physician revealed a history of hysterosalpingography.Accordingly,retained oil-based iodinated contrast medium was suspected,and observation of the object’s course was adopted.CONCLUSION When intraperitoneal foreign bodies are suspected on postoperative radiographs,the possibility of oil-based iodinated contrast medium retention should be considered.
基金supported by National Natural Science Foundation of China(22278424,22127812,22008257).
文摘As a kind of novel environmental-friendly surfactant,Gemini surfactant has attracted extensive research interests in its effects on gas hydrate formation.We investigated the effects of dioctyl sodium sulfosuccinate(AOT)on the formation thermodynamics/kinetics of CH_(4)and CO_(2)hydrates.Experimental results indicate that while AOT does not exhibit significant thermodynamic promotion for hydrate formation,it demonstrates favorable kinetic promotion effects.Its promotion effect surpasses that of the traditional kinetic promoter SDS and can enhance the gas storage capacity of hydrates.Utilizing the Chen-Guo hydrate model and adsorption kinetic model,we established a kinetic model for AOT with a predictive deviation of 7.17%and fitted key parameters accordingly.
基金National Natural Science Foundation of China(22178378,22127812 and 22468054)“Tianchi Talent”Recruitment Program,Xinjiang Tianshan Innovation Team(2022TSYCTD0002)Xinjiang Uygur Region“One Case,One Policy”Strategic Talent Introduction Project(XQZX20240054)。
文摘Molecular dynamics simulations were performed to study the microscopic working mechanism of fast hydrate formation from active ice.We successfully simulated the cyclic process of ice melt-hydrate formation-ice melt.The simulation results showed that active ice could significantly accelerate the formation of hydrates and exhibit high gas sto rage capacity.The oxygen atoms of the sulfate group in SDS formed hydrogen bonds with the hydrogen atoms of water molecules in the ice,destroying the orderly arranged structures of the ice surface.SDS also acted as a promoter to accelerate the mass transfer of vips in the liquid phase,thereby promoting the nucleation and growth of hydrates.The ordered structures of liquid phase formed by ice melting and the formation of cage-like structures facilitated by ice surface defects were beneficial to the nucleation and growth of hydrates.The formation of the hydrate shell accelerated the migration of the vips from the gas phase to the liquid phase.As the ice continued to melt,sufficient vips and water molecules ensured the stable growth of hydrates.
基金the National Key R&D Program of China(2023YEE0119900)National Natural Science Foundation of China(Nos.92058211,42204105 and 42121005)+4 种基金Fundamental Research Funds for the Central Universities(No.862201013140)111 project(No.B20048)the International(Regional)Cooperation and Exchange Programs(No.12411530092)the Young Talent Fund of Association for Science and Technology in Shaanxi(No.20230703)Technology Innovation Leading Program of Shaanxi(No.2024 ZC-YYDP-27).
文摘Natural gas hydrates are crystalline solid complexes with different morphologies found in marine sediments and permafrost zones. The petrophysical properties of gas hydrate-bearing sediments(GHBS) are crucial for understanding the characteristics of gas hydrate reservoirs, the spatial distribution of natural gas hydrates, and their exploitation potential. Geophysical exploration remains the primary approach for investigating the petrophysical properties of GHBS. However, limitations in resolution make it challenging to accurately characterize complex sediment structures, leading to difficulties in precisely interpreting petrophysical properties. Laboratory-based petrophysical experiments provide highly accurate results for petrophysical properties. Despite their accuracy, these experiments are costly, and difficulties in controlling variables may introduce uncertainties into geophysical exploration models.Advances in imaging and simulation techniques have established digital rock technology as an indispensable tool for enhancing petrophysical experimentation. This technology offers a novel microscopic perspective for elucidating the three-dimensional(3D) spatial distribution and multi-physical responses of GHBS. This paper presents an in-depth discussion of digital rock technology as applied to GHBS, with an emphasis on digital rock reconstruction and simulation of petrophysical properties. First, we summarize two common methods for constructing digital rocks of GHBS: petrophysical experimental methods and numerical reconstruction methods, followed by analyses of their respective advantages and limitations. Next, we delve into numerical simulation methods for evaluating GHBS petrophysical properties, including electrical, elastic, and fluid flow characteristics. Finally, we conduct a comprehensive analysis of the current trends in digital rock reconstruction and petrophysical simulation techniques for GHBS, emphasizing the necessity of multi-scale, multi-component, high-resolution 3D digital rock models to facilitate the precise characterization of complex gas hydrate reservoirs. Future applications of microscopic digital rock technology should be integrated with macroscopic geophysical exploration to enable more comprehensive and precise analyses of GHBS petrophysical properties.
基金supported by the Sinopec Technology Research and Development Project(No.30000000-22-ZC0607-0235,No.33550000-22-ZC0607-0009)the National Natural Science Foundation of China(No.52334002).
文摘Natural gas hydrate widely exists in the South China Sea as clean energy.A three-phase transition layer widely exists in low permeability Class I hydrates in the Shenhu offshore area.Therefore,taking into account the low-permeability characteristics with an average permeability of 5.5 mD and moderate heterogeneity,a 3-D geological model of heterogeneous Class I hydrate reservoirs with three-phase transition layers is established by Kriging interpolation and stochastic modeling method,and a numerical simulation model is used to describe the depressurization production performance of the reservoir.With the development of depressurization,a specific range of complete decomposition zones appear both in the hydrate and transition layers.The entire decomposition zone of the whole reservoir tends to outward and upward diffusion.There is apparent methane escape in the three-phase transition layer.Due to the improvement of local permeability caused by the phase transition of hydrate dissociation,some methane accumulation occurs at the bottom of the hydrate layer,forming a local methane enrichment zone.The methane migration trends in reservoirs are mainly characterized by movement toward production wells and hydrate layers under the influence of gravity.However,due to the permeability limitation of hydrate reservoirs,many fluids have not been effectively produced and remain in the reservoir.Therefore,to improve the effective pressure drop of the reservoir,the perforation method and pressure reduction method were optimized by analyzing the influencing factors based on the gas production rate.The comparative study demonstrates that perforating through the free gas layer combined with one-time depressurization can enhance the effective depressurization and improve production performance.The gas production rate from perforating through the free gas layer can be twice as high as that from perforating through the transition layer.This study can provide theoretical support for the utilization of marine energy.
基金financially supported by the National Natural Science Foundation of China(No.42376067)the Natural Science Foundation of Shandong Province(No.ZR202011030013)+1 种基金the Laoshan Laboratory(No.LSKJ202203506)the China Geological Survey Program(No.DD20230064)。
文摘Natural gas hydrates are widely distributed in marine and permafrost environments.As a novel energy resource,accurately describing reservoir characteristics and assessing energy potential is crucial for its commercial development.Resistivity logging serves as a valuable approach for achieving these goals.Nevertheless,due to inadequate comprehension of the electrical conductivity mechanism in hydrate-bearing sediments,existing data processing models still encounter certain challenges.This study conducts both core-scale and pore-scale simulation experiments to examine the relationship between resistivity variations and the distribution of gas hydrate porosity.The results indicate that the characteristics of resistivity variation is associated with the gas hydrate formation process,and the gas hydrate saturation index,denoted as‘n',varies between 0 and 3 depending on different gas hydrate distribution patterns.As the saturation increases,gas hydrate distribution in pore spaces transitions from floating to contacting and cementing patterns.It is proposed that the aqueous pore tortuosity can be utilized to correct the saturation index‘n'in Archie's equation.Based on the analysis of experimental data,a correction method for Archie's equation is suggested,and its effectiveness in controlling relative error has been validated.
文摘The National Gas Hydrate Program expeditions(NGHP-01 and-02)have conclusively proven the presence of hydrate deposits on the eastern coast of India.The novelty of the present study lies in its investigation of the richest gas hydrate deposit(hydrate saturation[Sh]>0.75),NGHP-01-10D,in the Krishna-Godavari(KG)Basin,India.The study presents a first look at the long-term gas production viability using a single vertical well,subjected to variations in production interval and bottom hole pressure.Specifically,we compared the gas production at bottom hole pressures of 3-6 MPa and production intervals of 20-40 m.The results indicate production rates that are technically feasible but lower than commercially acceptable standards.Increasing the bottom hole pressure drawdown from 6 MPa to 3 MPa increased the gas production from 1297 m^(3)/d to 4902 m^(3)/d(i.e.,more than tripling the average daily gas production).Meanwhile,while expanding the production interval from 20 m to 40 m led to an increase in gas production,it also resulted in higher water production.As a result,the average gas-to-water ratio(RGW)decreased from 9.5 to 5.3 with the expansion of the production interval,thereby highlighting the need to optimize the interval length.Furthermore,the spatial evolution of certain thermodynamic parameters,including pressure,temperature,and phase saturation(methane,water,and hydrate),underscores the critical role of heat transfer from the UB.Our study findings offer valuable insights for long-term production forecasting,the delineation of phase evolution patterns,and the identification of potential flow barriers that may impede deliverability.
基金support of the National Natural Science Foundation of China(Grant No.52074332).
文摘Natural gas hydrates(hereinafter referred to as hydrates)are a promising clean energy source.However,their current development is far from reaching commercial exploitation.Reservoir stimulation tech-nology provides new approaches to enhance hydrate development effectiveness.Addressing the current lack of quantitative and objective methods for evaluating the fracability of hydrate reservoirs,this study clarifies the relationship between geological and engineering fracability and proposes a comprehensive evaluation model for hydrate reservoir fracability based on grey relational analysis and the criteria importance through intercriteria correlation method.By integrating results from hydraulic fracturing experiments on hydrate sediments,the fracability of hydrate reservoirs is assessed.The concept of critical construction parameter curves for hydrate reservoirs is introduced for the first time.Additionally,two-dimensional fracability index evaluation charts and three-dimensional fracability construction condition discrimination charts are established.The results indicate that as the comprehensive fracability index increases,the feasibility of forming fractures in hydrate reservoirs improves,and the required normalized fracturing construction parameters gradually decrease.The accuracy rate of the charts in judging experimental results reached 89.74%,enabling quick evaluations of whether hydrate reservoirs are worth fracturing,easy to fracture,and capable of being fractured.This has significant engineering implications forthehydraulicfracturingof hydratereservoirs.
基金This work was supported by the Ministry of Industry and Information Technology High Tech Ship Special Project(Grant No.CBG3N21-2-6).
文摘Extracted natural gas hydrate is a multi-phase and multi-component mixture,and its complex composition poses significant challenges for transmission and transportation,including phase changes following extraction and sediment deposition within the pipeline.This study examines the flow and heat transfer characteristics of hydrates in a riser,focusing on the multi-phase flow behavior of natural gas hydrate in the development riser.Additionally,the effects of hydrate flow and seawater temperature on heat exchange are analyzed by simulating the ambient temperature conditions of the South China Sea.The findings reveal that the increase in unit pressure drop is primarily attributed to higher flowvelocities,which result in increased friction of the hydrate flowwithin the development riser.For example,at a hydrate volume fraction of 10%,the unit pressure drop rises by 166.65%and 270.81% when the average inlet velocity is increased from1.0 to 3.0m/s(a two-fold increase)and 5.0 m/s(a four-fold increase),respectively.Furthermore,the riser outlet temperature rises with increasing hydrate flowrates.Under specific heat loss conditions,the flowratemust exceed a minimum threshold to ensure safe transportation.The study also indicates that the riser outlet temperature increases with higher seawater temperatures.Within the seawater temperature range of 5℃ to 15℃,the heat transfer efficiency is reduced compared to the range of 15℃ to 20℃.This discrepancy is due to the fact that as the seawater temperature rises,the convective heat transfer coefficient between the hydrate and the inner wall of the riser also increases,leading to improved overall heat transfer between the hydrate and the pipeline.
