Permeation of Cu（Ⅱ） from its aqueous solution through a supported liquid membrane （SLM） containing di（2-ethylhexyl）phosphoric acid （D2EHPA） carrier dissolved in coconut oil has been studied. The effects of C...Permeation of Cu（Ⅱ） from its aqueous solution through a supported liquid membrane （SLM） containing di（2-ethylhexyl）phosphoric acid （D2EHPA） carrier dissolved in coconut oil has been studied. The effects of Cu（Ⅱ）, pH （in feed）, H2SO4 （stripping） and D2EHPA （in membrane） concentrations have been investigated. The stability of the D2EHPA-coconut oil has also been evaluated. High Cu（Ⅱ） concentration in the feed leads to an increase in flux from 4.1 × 10^-9 to 8.9 × 10^-9 mol/（m^2·s） within the Cu（Ⅱ） concentration range 7.8×10^-4-78.6×10^-4 mol/L at pH of 4.0 in the feed and 12.4 × 10^-4 mol/L D2EHPA in the membrane phase. Increase in H2SO4 concentration in strip solution leads to an increase in copper ions flux up to 0.25 mol/L H2SO4, providing a maximum flux of 7.4 × 10^-9 mol/（m^2·s）. The optimum conditions for Cu（Ⅱ） transport are, pH of feed 4.0, 0.25 mol/L H2SO4 in strip phase and 12.4 × 10^-4 mol/L D2EHPA （membrane） in 0.5 μm pore size polytetrafluoroethylene （PTFE） membrane. It has been observed that Cu（Ⅱ） flux across the membrane tends to increase with the concentration of copper ions. Application of the method developed to copper plating bath rinse solutions has been found to be successful in the recovery of Cu（Ⅱ）.展开更多
Marine oil spills have caused major threats to marine environment over the past few years.The early detection of the oil spill is of great significance for the prevention and control of marine disasters.At present,rem...Marine oil spills have caused major threats to marine environment over the past few years.The early detection of the oil spill is of great significance for the prevention and control of marine disasters.At present,remote sensing is one of the major approaches for monitoring the oil spill.Full polarization synthetic aperture radarc SAR data are employed to extract polarization decomposition parameters including entropy（H） and reflection entropy（A）.The characteristic spectrum of the entropy and reflection entropy combination has analyzed and the polarization characteristic spectrum of the oil spill has developed to support remote sensing of the oil spill.The findings show that the information extracted from（1-A）×（1-H） and（1-H）×A parameters is relatively evident effects.The results of extraction of the oil spill information based on H×A parameter are relatively not good.The combination of the two has something to do with H and A values.In general,when H〉0.7,A value is relatively small.Here,the extraction of the oil spill information using（1-A）×（1-H） and（1-H）×A parameters obtains evident effects.Whichever combined parameter is adopted,oil well data would cause certain false alarm to the extraction of the oil spill information.In particular the false alarm of the extracted oil spill information based on（1-A）×（1-H） is relatively high,while the false alarm based on（1-A）×H and（1-H）×A parameters is relatively small,but an image noise is relatively big.The oil spill detection employing polarization characteristic spectrum support vector machine can effectively identify the oil spill information with more accuracy than that of the detection method based on single polarization feature.展开更多
文摘Permeation of Cu（Ⅱ） from its aqueous solution through a supported liquid membrane （SLM） containing di（2-ethylhexyl）phosphoric acid （D2EHPA） carrier dissolved in coconut oil has been studied. The effects of Cu（Ⅱ）, pH （in feed）, H2SO4 （stripping） and D2EHPA （in membrane） concentrations have been investigated. The stability of the D2EHPA-coconut oil has also been evaluated. High Cu（Ⅱ） concentration in the feed leads to an increase in flux from 4.1 × 10^-9 to 8.9 × 10^-9 mol/（m^2·s） within the Cu（Ⅱ） concentration range 7.8×10^-4-78.6×10^-4 mol/L at pH of 4.0 in the feed and 12.4 × 10^-4 mol/L D2EHPA in the membrane phase. Increase in H2SO4 concentration in strip solution leads to an increase in copper ions flux up to 0.25 mol/L H2SO4, providing a maximum flux of 7.4 × 10^-9 mol/（m^2·s）. The optimum conditions for Cu（Ⅱ） transport are, pH of feed 4.0, 0.25 mol/L H2SO4 in strip phase and 12.4 × 10^-4 mol/L D2EHPA （membrane） in 0.5 μm pore size polytetrafluoroethylene （PTFE） membrane. It has been observed that Cu（Ⅱ） flux across the membrane tends to increase with the concentration of copper ions. Application of the method developed to copper plating bath rinse solutions has been found to be successful in the recovery of Cu（Ⅱ）.
基金The National Natural Science Foundation of China under contract No.41376183the Oceanography Public Welfare Scientific Research Project "Marine oil spill risk assessment and key technologies of emergency response integration and demonstration" under contract No.201205012
文摘Marine oil spills have caused major threats to marine environment over the past few years.The early detection of the oil spill is of great significance for the prevention and control of marine disasters.At present,remote sensing is one of the major approaches for monitoring the oil spill.Full polarization synthetic aperture radarc SAR data are employed to extract polarization decomposition parameters including entropy（H） and reflection entropy（A）.The characteristic spectrum of the entropy and reflection entropy combination has analyzed and the polarization characteristic spectrum of the oil spill has developed to support remote sensing of the oil spill.The findings show that the information extracted from（1-A）×（1-H） and（1-H）×A parameters is relatively evident effects.The results of extraction of the oil spill information based on H×A parameter are relatively not good.The combination of the two has something to do with H and A values.In general,when H〉0.7,A value is relatively small.Here,the extraction of the oil spill information using（1-A）×（1-H） and（1-H）×A parameters obtains evident effects.Whichever combined parameter is adopted,oil well data would cause certain false alarm to the extraction of the oil spill information.In particular the false alarm of the extracted oil spill information based on（1-A）×（1-H） is relatively high,while the false alarm based on（1-A）×H and（1-H）×A parameters is relatively small,but an image noise is relatively big.The oil spill detection employing polarization characteristic spectrum support vector machine can effectively identify the oil spill information with more accuracy than that of the detection method based on single polarization feature.
