Combining a detailed catalytic surface reaction mechanism with noble metal and promoter elementary reactions, a new three-way catalytic converter(TWC) reaction mechanism is established. Based on the new mechanism, ste...Combining a detailed catalytic surface reaction mechanism with noble metal and promoter elementary reactions, a new three-way catalytic converter(TWC) reaction mechanism is established. Based on the new mechanism, steady condition numerical simulation is carried out, and the change of light-off temperatures and conversion efficiency with various SO2 contents is obtained. By grey relational analysis(GRA), the relational grade between conversion efficiency and SO2 content is obtained. And, the result shows that SO2 content has the most important influence on C3H6 and NOX conversion efficiency. This provides an important reference to the improvement of activity design of TWC, and may provide guidance for the condition design and optimization of TWC.展开更多
Immiscible water-alternating-gas（WAG） flooding is an EOR technique that has proven successful for water drive reservoirs due to its ability to improve displacement and sweep efficiency.Nevertheless,considering the c...Immiscible water-alternating-gas（WAG） flooding is an EOR technique that has proven successful for water drive reservoirs due to its ability to improve displacement and sweep efficiency.Nevertheless,considering the complicated phase behavior and various multiphase flow characteristics,gas tends to break through early in production wells in heterogeneous formations because of overriding,fingering,and channeling,which may result in unfavorable recovery performance.On the basis of phase behavior studies,minimum miscibility pressure measurements,and immiscible WAG coreflood experiments,the cubic B-spline model（CBM） was employed to describe the three-phase relative permeability curve.Using the Levenberg-Marquardt algorithm to adjust the vector of unknown model parameters of the CBM sequentially,optimization of production performance including pressure drop,water cut,and the cumulative gas-oil ratio was performed.A novel numerical inversion method was established for estimation of the water-oil-gas relative permeability curve during the immiscible WAG process.Based on the quantitative characterization of major recovery mechanisms,the proposed method was validated by interpreting coreflood data of the immiscible WAG experiment.The proposed method is reliable and can meet engineering requirements.It provides a basic calculation theory for implicit estimation of oil-water-gas relative permeability curve.展开更多
基金Project(2009CK2001) supported by the Science & Technology Development Key Program of Hunan Province STA of ChinaProject supported by the Young Teachers Program of Hunan University,China
文摘Combining a detailed catalytic surface reaction mechanism with noble metal and promoter elementary reactions, a new three-way catalytic converter(TWC) reaction mechanism is established. Based on the new mechanism, steady condition numerical simulation is carried out, and the change of light-off temperatures and conversion efficiency with various SO2 contents is obtained. By grey relational analysis(GRA), the relational grade between conversion efficiency and SO2 content is obtained. And, the result shows that SO2 content has the most important influence on C3H6 and NOX conversion efficiency. This provides an important reference to the improvement of activity design of TWC, and may provide guidance for the condition design and optimization of TWC.
基金the financial support of the Important National Science and Technology Specific Projects of China (Grant No. 2011ZX05010-002)the Important Science and Technology Specific Projects of Petro China (Grant No. 2014E-3203)
文摘Immiscible water-alternating-gas（WAG） flooding is an EOR technique that has proven successful for water drive reservoirs due to its ability to improve displacement and sweep efficiency.Nevertheless,considering the complicated phase behavior and various multiphase flow characteristics,gas tends to break through early in production wells in heterogeneous formations because of overriding,fingering,and channeling,which may result in unfavorable recovery performance.On the basis of phase behavior studies,minimum miscibility pressure measurements,and immiscible WAG coreflood experiments,the cubic B-spline model（CBM） was employed to describe the three-phase relative permeability curve.Using the Levenberg-Marquardt algorithm to adjust the vector of unknown model parameters of the CBM sequentially,optimization of production performance including pressure drop,water cut,and the cumulative gas-oil ratio was performed.A novel numerical inversion method was established for estimation of the water-oil-gas relative permeability curve during the immiscible WAG process.Based on the quantitative characterization of major recovery mechanisms,the proposed method was validated by interpreting coreflood data of the immiscible WAG experiment.The proposed method is reliable and can meet engineering requirements.It provides a basic calculation theory for implicit estimation of oil-water-gas relative permeability curve.
