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On ADRC for non-minimum phase systems: canonical form selection and stability conditions 被引量:9
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作者 Wenchao XUE Yi HUANG Zhiqiang GAO 《Control Theory and Technology》 EI CSCD 2016年第3期199-208,共10页
Active disturbance rejection control (ADRC), as proposed by Prof. Jingqing Han, reduces first the plant dynamics to its canonical form, normally in the form of cascade integrators, for which the standard controller ... Active disturbance rejection control (ADRC), as proposed by Prof. Jingqing Han, reduces first the plant dynamics to its canonical form, normally in the form of cascade integrators, for which the standard controller can be employed to meet the design specifications. This paper concerns with the selection of the canonical form for non-minimum phase systems. In particular, it is shown that, by employing the well known controllable canonical form, the uncertainties of such systems can be divided into two terms in the state space model, one in the control channel and the other in the output channel. The necessary and sufficient condition is obtained for the stability of the closed-loop system with the proposed canonical form and ADRC. Also, by showing the necessity of the detectability of the extended system as well as certain information of the system-s "zeros", we present the fundamental guidelines of design ADRC for non-minimum phase uncertain systems. 展开更多
关键词 Active disturbance rejection control (ADRC) extended state observer (ESO) rejector uncertain systems non-minimum phase
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Output-feedback Dynamic Surface Control for a Class of Nonlinear Non-minimum Phase Systems 被引量:5
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作者 Shanwei Su 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI 2016年第1期96-104,共9页
In this paper, an output-feedback tracking controller is proposed for a class of nonlinear non-minimum phase systems.To keep the unstable internal dynamics bounded, the method of output redefinition is applied to let ... In this paper, an output-feedback tracking controller is proposed for a class of nonlinear non-minimum phase systems.To keep the unstable internal dynamics bounded, the method of output redefinition is applied to let the stability of the internal dynamics depend on that of redefined output, thus we only need to consider the new external dynamics rather than internal dynamics in the process of designing control law. To overcome the explosion of complexity problem in traditional backstepping design, the dynamic surface control(DSC) method is firstly used to deal with the problem of tracking control for the nonlinear non-minimum phase systems. The proposed outputfeedback DSC controller not only forces the system output to asymptotically track the desired trajectory, but also drives the unstable internal dynamics to follow its corresponding bounded and causal ideal internal dynamics, which is solved via stable system center method. Simulation results illustrate the validity of the proposed output-feedback DSC controller. 展开更多
关键词 non-minimum phase system OUTPUT-FEEDBACK trajectory tracking internal dynamics dynamic surface control(DSC)
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Adaptive fault-tolerant control for non-minimum phase hypersonic vehicles based on adaptive dynamic programming 被引量:4
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作者 Le WANG Ruiyun QI Bin JIANG 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2024年第3期290-311,共22页
In this paper,a novel adaptive Fault-Tolerant Control(FTC)strategy is proposed for non-minimum phase Hypersonic Vehicles(HSVs)that are affected by actuator faults and parameter uncertainties.The strategy is based on t... In this paper,a novel adaptive Fault-Tolerant Control(FTC)strategy is proposed for non-minimum phase Hypersonic Vehicles(HSVs)that are affected by actuator faults and parameter uncertainties.The strategy is based on the output redefinition method and Adaptive Dynamic Programming(ADP).The intelligent FTC scheme consists of two main parts:a basic fault-tolerant and stable controller and an ADP-based supplementary controller.In the basic FTC part,an output redefinition approach is designed to make zero-dynamics stable with respect to the new output.Then,Ideal Internal Dynamic(IID)is obtained using an optimal bounded inversion approach,and a tracking controller is designed for the new output to realize output tracking of the nonminimum phase HSV system.For the ADP-based compensation control part,an ActionDependent Heuristic Dynamic Programming(ADHDP)adopting an actor-critic learning structure is utilized to further optimize the tracking performance of the HSV control system.Finally,simulation results are provided to verify the effectiveness and efficiency of the proposed FTC algorithm. 展开更多
关键词 Hypersonic vehicle Fault-tolerant control non-minimum phase system Adaptive control Nonlinear control Adaptive dynamic programming
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Distributed Adaptive Output Consensus of Unknown Heterogeneous Non-Minimum Phase Multi-Agent Systems 被引量:5
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作者 Wenji Cao Lu Liu Gang Feng 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2023年第4期997-1008,共12页
This article addresses the leader-following output consensus problem of heterogeneous linear multi-agent systems with unknown agent parameters under directed graphs.The dynamics of followers are allowed to be non-mini... This article addresses the leader-following output consensus problem of heterogeneous linear multi-agent systems with unknown agent parameters under directed graphs.The dynamics of followers are allowed to be non-minimum phase with unknown arbitrary individual relative degrees.This is contrary to many existing works on distributed adaptive control schemes where agent dynamics are required to be minimum phase and often of the same relative degree.A distributed adaptive pole placement control scheme is developed,which consists of a distributed observer and an adaptive pole placement control law.It is shown that under the proposed distributed adaptive control scheme,all signals in the closed-loop system are bounded and the outputs of all the followers track the output of the leader asymptotically.The effectiveness of the proposed scheme is demonstrated by one practical example and one numerical example. 展开更多
关键词 Adaptive pole placement control heterogeneous multi-agent systems leader-following output consensus non-minimum phase
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Robust adaptive leaderless consensus of unknown non-minimum phase linear multi-agent systems subject to disturbances and/or unmodeled dynamics 被引量:1
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作者 Wenji Cao Gang Feng 《Journal of Automation and Intelligence》 2024年第2期92-100,共9页
This article investigates the problem of robust adaptive leaderless consensus for heterogeneous uncertain nonminimumphase linear multi-agent systems over directed communication graphs. Each agent is assumed tobe of un... This article investigates the problem of robust adaptive leaderless consensus for heterogeneous uncertain nonminimumphase linear multi-agent systems over directed communication graphs. Each agent is assumed tobe of unknown nominal dynamics and also subject to external disturbances and/or unmodeled dynamics. Anovel distributed robust adaptive control strategy is proposed. It is shown that the robust adaptive leaderlessconsensus problem is solved with the proposed control strategy under some sufficient conditions. Two examplesare provided to demonstrate the efficacy of the proposed control strategy. 展开更多
关键词 Cooperative control non-minimum phase Leaderless consensus Multi-agent systems Robust adaptive control
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Multiple Models Direct Adaptive Controller for a Stochastic Non-minimum Phase System
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作者 郑益慧 王昕 +1 位作者 李少远 姜建国 《Journal of Shanghai Jiaotong university(Science)》 EI 2010年第5期578-586,共9页
For a stochastic non-minimum phase multivariable system,a multiple models direct adaptive controller is presented.It is composed of multiple fixed models with two adaptive models.The fixed models are used to cover the... For a stochastic non-minimum phase multivariable system,a multiple models direct adaptive controller is presented.It is composed of multiple fixed models with two adaptive models.The fixed models are used to cover the region where the system parameters jump and improve the transient response,while another two adaptive models are used to guarantee the stability.Utilizing generalized minimum variance design method,it adopts the stochastic system estimation algorithm with optimal controller design method to identify the controller parameter directly.Finally,the global convergence is given.The simulation proves the effectives of the controller proposed. 展开更多
关键词 multiple models stochastic system non-minimum phase direct adaptive control multivariable system
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AN IMPROVEMENT OF THE RECURSIVE CLOSED-FORM ALGORITHM FOR NON-MINIMUM PHASE FIR SYSTEM IDENTIFICATION
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作者 梁应敞 王树勋 戴逸松 《Journal of Electronics(China)》 1993年第2期188-192,共5页
An improved algorithm which is based on the recursive closed-form algorithm fornon-minimum phase FIR system identification via higher order statistics is presented.In order toincrease the parametric estimation accurac... An improved algorithm which is based on the recursive closed-form algorithm fornon-minimum phase FIR system identification via higher order statistics is presented.In order toincrease the parametric estimation accuracy,the improved algorithm uses the optimal iterativemethod to seek the nonlinear least-square solution.Finally,the simulation examples are alsogiven. 展开更多
关键词 non-minimum phase FIR system HIGHER order STATISTICS Parameter estimation ITERATIVE method
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Distributed Adaptive Output Containment Control of Unknown Heterogeneous Non-Minimum Phase Linear Multi-Agent Systems
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作者 CAO Wenji FENG Gang 《Journal of Systems Science & Complexity》 2025年第2期654-670,共17页
This paper investigates the output containment control problem of unknown heterogeneous non-minimum phase linear multi-agent systems over directed communication graphs.The dynamics of each follower are allowed to be u... This paper investigates the output containment control problem of unknown heterogeneous non-minimum phase linear multi-agent systems over directed communication graphs.The dynamics of each follower are allowed to be unknown.A novel distributed adaptive pole placement control strategy is developed to address the output containment control problem of the concerned multi-agent system.It is shown that the proposed distributed adaptive control strategy guarantees the boundedness of all the signals in the resulting closed-loop system and the convergence of the followers'outputs to a convex hull spanned by the leaders'outputs.The efficacy of the proposed control strategy is demonstrated by two simulation examples. 展开更多
关键词 Adaptive pole placement control multi-agent systems non-minimum phase output containment control
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Phase Transformation on Chemically Corroded Surface of a Single-Crystal Superalloy During In-Situ Tension at Elevated Temperatures
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作者 Wang Rui Li Jiarong +2 位作者 Yue Xiaodai Zhao Jinqian Yang Wanpeng 《稀有金属材料与工程》 北大核心 2026年第3期595-601,共7页
In-situ tensile tests were conducted on a chemically corroded third-generation single-crystal superalloy DD9 at 980 and 1100℃.The phase transformation in the surface areas during the tensile process was analyzed usin... In-situ tensile tests were conducted on a chemically corroded third-generation single-crystal superalloy DD9 at 980 and 1100℃.The phase transformation in the surface areas during the tensile process was analyzed using field emission scanning electron microscope,energy dispersive X-ray spectroscope,electron probe X-ray microanalysis,and transmission electron microscope.The phase transformation mechanism on the surface and the influence mechanism were studied through observation and dynamic calculation.During tensile tests at elevated temperatures,chemical corrosion promotes the precipitation of topologically close-packed(tcp)μphase andσphase on the alloy surface.Both the precipitation amount and size of these two phases on the surface at 1100℃are greater than those at 980℃.The precipitation of tcp phase on the alloy surface results in the formation of an influence layer on the surface area,and the distribution characteristics of alloying elements are significantly different from those of the substrate.The depth of the influence layer at 1100℃is greater than that at 980℃.The precipitation of tcp phase prompts the phase transition fromγphase toγ′phase around the tcp phase. 展开更多
关键词 single-crystal superalloy in-situ tension tcp phase phase transformation alloying element
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Peak current reduction in presence of RF phase modulationin the dual RF system
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作者 Jiang Bocheng Zhang Yao Tsai Cheng-Ying 《强激光与粒子束》 北大核心 2026年第1期160-165,共6页
[Background]High harmonic cavities are widely used in electron storage rings to lengthen thebunch,lower the bunch peak current,thereby reducing the IBS effect,enhancing the Touschek lifetime,as well asproviding Landau... [Background]High harmonic cavities are widely used in electron storage rings to lengthen thebunch,lower the bunch peak current,thereby reducing the IBS effect,enhancing the Touschek lifetime,as well asproviding Landau damping,which is particularly important for storage rings operating with ultra-low emittance or atlow beam energy.[Purpose]To further increase the bunch length without additional hardware costs,the phasemodulation in a dual-RF system is considered.[Methods]In this paper,turn-by-turn simulations incorporating randomsynchrotron radiation excitation are conducted,and a brief analysis is presented to explain the bunch lengtheningmechanism.[Results]Simulation results reveal that the peak current can be further reduced,thereby mitigating IBSeffects and enhancing the Touschek lifetime.Although the energy spread increases,which tends to reduce thebrightness of higher-harmonic radiation from the undulator,the brightness of the fundamental harmonic can,in fact,beimproved. 展开更多
关键词 dual high-frequency system phase modulation beam bunch stretching intra-beam scattering
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Effect of Addition of Er-TiB_(2)Dual-Phase Nanoparticles on Strength-Ductility of Al-Mn-Mg-Sc-Zr Alloy Prepared by Laser Powder Bed Fusion
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作者 Li Suli Zhang Yanze +5 位作者 Yang Mengjia Zhang Longbo Xie Qidong Yang Laixia MaoFeng Chen Zhen 《稀有金属材料与工程》 北大核心 2026年第1期9-17,共9页
A dual-phase synergistic enhancement method was adopted to strengthen the Al-Mn-Mg-Sc-Zr alloy fabricated by laser powder bed fusion(LPBF)by leveraging the unique advantages of Er and TiB_(2).Spherical powders of 0.5w... A dual-phase synergistic enhancement method was adopted to strengthen the Al-Mn-Mg-Sc-Zr alloy fabricated by laser powder bed fusion(LPBF)by leveraging the unique advantages of Er and TiB_(2).Spherical powders of 0.5wt%Er-1wt%TiB_(2)/Al-Mn-Mg-Sc-Zr nanocomposite were prepared using vacuum homogenization technique,and the density of samples prepared through the LPBF process reached 99.8%.The strengthening and toughening mechanisms of Er-TiB_(2)were investigated.The results show that Al_(3)Er diffraction peaks are detected by X-ray diffraction analysis,and texture strength decreases according to electron backscatter diffraction results.The added Er and TiB_(2)nano-reinforcing phases act as heterogeneous nucleation sites during the LPBF forming process,hindering grain growth and effectively refining the grains.After incorporating the Er-TiB_(2)dual-phase nano-reinforcing phases,the tensile strength and elongation at break of the LPBF-deposited samples reach 550 MPa and 18.7%,which are 13.4%and 26.4%higher than those of the matrix material,respectively. 展开更多
关键词 Al-Mn-Mg-Sc-Zr alloy laser powder bed fusion nano-reinforcing phase synergistic enhancement
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CTA联合PHASES评分对颅内动脉瘤破裂出血预后的价值分析
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作者 张杰 鲁东 吕维富 《影像研究与医学应用》 2026年第2期17-21,共5页
目的:探讨头颈部CT血管造影(CTA)联合PHASES评分对颅内动脉瘤破裂导致动脉瘤性蛛网膜下腔出血(aSAH)预后的价值。方法:回顾性分析2022年1月—2024年10月在亳州市中医院接受诊疗的67例aSAH患者病例资料。根据格拉斯哥预后评分,将患者分... 目的:探讨头颈部CT血管造影(CTA)联合PHASES评分对颅内动脉瘤破裂导致动脉瘤性蛛网膜下腔出血(aSAH)预后的价值。方法:回顾性分析2022年1月—2024年10月在亳州市中医院接受诊疗的67例aSAH患者病例资料。根据格拉斯哥预后评分,将患者分为预后良好组(n=37)和预后不良组(n=30)。采用单因素及多因素Logistic回归分析比较组间临床、影像及PHASES评分,筛选aSAH患者预后的独立预测因素并构建回归模型。绘制受试者工作特征(ROC)曲线,评估各单一独立预测因素及回归模型预测aSAH患者预后的效能。结果:预后不良组患者Hunt-Hess分级Ⅳ~Ⅴ级的占比、AR值、SR值、入射夹角和PHASES评分均高于预后良好组,发病至治疗时间>3 d的占比高于预后良好组,差异有统计学意义(P<0.05)。多因素Logistic回归分析结果显示,Hunt-Hess分级、入射夹角和PHASES评分为aSAH患者不良结局的影响因素(P<0.05),其曲线下面积(AUC)分别为0.613、0.658、0.761;以三者联合构建的回归模型预测患者预后的诊断灵敏度为0.733,特异度为0.919,AUC为0.898。结论:CTA联合PHASES评分能够有效提升对aSAH患者预后的预测效能,有助于临床进行预后判断。 展开更多
关键词 颅内动脉瘤 破裂出血 CT血管造影 phaseS评分 预后价值
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Design of electrocaloric materials based on E–T phase diagrams
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作者 Fei Han Rongju Zhong +2 位作者 Jikun Yang Chuanbao Liu Yang Bai 《Chinese Physics B》 2026年第2期71-83,共13页
As electronic technology continues to evolve towards miniaturization and integration,the demand for micro-refrigeration technology in microelectronic systems is increasing.Ferroelectric(FE)refrigeration technology bas... As electronic technology continues to evolve towards miniaturization and integration,the demand for micro-refrigeration technology in microelectronic systems is increasing.Ferroelectric(FE)refrigeration technology based on the electrocaloric effect(ECE)has emerged as a highly promising candidate in this field,due to its advantages of high energy efficiency,simple structure,easy miniaturization,low cost,and environmental friendliness.The EC performance of FE materials essentially depends on the phase transition features under the coupled electric and thermal fields,making the E–T phase diagram a core tool for decoding the underlying mechanism of ECE.This paper reviews the development of EC materials,focusing on the comprehensive study of E–T phase diagrams.By correlating the microscopic phase structure of FE materials with the macroscopic physical properties,it clarifies the manipulation mechanism for enhanced ECE performance,providing theoretical support for the targeted design of high-performance EC materials.In the future,the introduction of data-driven methods is expected to enable the high-throughput construction of FE phase diagrams,thereby accelerating the optimization of high-performance EC materials and promoting the practical application of FE refrigeration technology. 展开更多
关键词 ferroelectric material electrocaloric effect phase diagram phase transition sold-state refrigeration
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Recent advances in the properties,synthesis,and applications of oriented composite phase change materials
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作者 Jun Tong Zui Tao +5 位作者 Wenjie Hou Chaoxing Yang Tiantian Yuan Huimin Liao Xiubing Huang Ge Wang 《Journal of Energy Chemistry》 2026年第1期902-944,I0020,共44页
In the context of the global energy low-carbon transition,phase change energy storage technology becomes a key technology to solve the problem of intermittent renewable energy.Oriented phase change composites(OCPCMs)r... In the context of the global energy low-carbon transition,phase change energy storage technology becomes a key technology to solve the problem of intermittent renewable energy.Oriented phase change composites(OCPCMs)receive widespread attention in practical energy storage applications due to their unique oriented thermally conductive structure,which achieves significant thermal conductivity enhancement in specific directions while retaining the high energy storage capacity of the phase change components.This review systematically summarizes the overall analysis of OCPCMs from synthesis and preparation to application scenarios in recent years.Herein,we introduce the analysis of the heat transfer mechanism of the materials and explore the advantages of the oriented structure in OCPCMs in the heat transfer behavior from a bionic perspective.We then focus on summarizing and generalizing the methods for preparing OCPCMs,giving suggestions for suitable methods according to different scenarios.Besides,we discuss the application of finite element simulation methods to the monitoring of the thermal management behavior of OCPCMs,and look into the potential future application areas of such materials.Finally,it is hoped that this review will provide guidance for the academic community in developing high-performance OCPCMs. 展开更多
关键词 phase change materials Oriented phase change composites Oriented thermal conduction Thermal conductivity enhancements
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Illusion Optics via Phase-Gradient Metasurfaces
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作者 Zhaoyao Pan Jinpeng Yang Yadong Xu 《Chinese Physics Letters》 2026年第1期31-36,共6页
Optical phase-gradient metasurfaces have garnered significant attention for enabling flexible light manipulation,with applications across diverse domains.In this work,we will demonstrate that the metasurfaces with pha... Optical phase-gradient metasurfaces have garnered significant attention for enabling flexible light manipulation,with applications across diverse domains.In this work,we will demonstrate that the metasurfaces with phase gradient modulation can be used to achieve illusion optics,featuring the advantages of simple geometric structure and feasible implementation compared with the well-known transformation optics method.The underlying mechanism is the anomalous diffraction law caused by the phase gradient,which provides a theoretical basis for freely manipulating the propagation path of light.By considering a specific example,we will demonstrate that the phase gradient can transform spatial coordinates in real space into illusion space,thereby converting a plane in real space into a curved surface structure in illusion space to achieve the illusion effect.This approach provides a viable alternative to transformation optics for designing illusion devices. 展开更多
关键词 transformation optics anomalous diffraction law illusion opticsfeaturing flexible light manipulationwith illusion optics anomalous diffraction phase gradient modulation phase gradient metasurfaces
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Volume change and creep behaviors related to stress-phase transition path in methane hydrate-bearing silty sand
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作者 Jiazuo Zhou Qi Fan +1 位作者 Zhenyu Zhu Changfu Wei 《Journal of Rock Mechanics and Geotechnical Engineering》 2026年第2期1526-1540,共15页
The volume change behavior of natural gas hydrate-bearing sediment is essential as it influences settlement,strength,and stiffness,which directly affect the stability of hydrate reservoirs during hydrate extraction or... The volume change behavior of natural gas hydrate-bearing sediment is essential as it influences settlement,strength,and stiffness,which directly affect the stability of hydrate reservoirs during hydrate extraction or in response to environmental changes.The volume change is influenced not only by stress but also by the formation and dissociation of hydrates.This study adopted a customized apparatus for one-dimensional compression tests,allowing independent control of gas pressure and effective stress.Tests were conducted on samples with different hydrate saturations along various temperature-gas pressure-effective stress paths,yielding some conclusions related to compressibility and creep.An unusual phenomenon was observed under low-stress conditions:hydrate formation led to shrinkage rather than expansion.Three potential mechanisms behind this occurrence were discussed.As hydrate saturation increases,the yield stress rises while the compression and swelling indexes remain minimally affected.After hydrate dissociation,the compression curve of hydrate-bearing sediment drops to that of hydrate-free sediment.Once hydrate is formed,the compression curve of hydrate-free sediment gradually approaches that of hydrate-bearing sediment during the subsequent loading.Under low-stress conditions,the creep of both hydrate-free and hydrate-bearing sediments is very weak.However,when stress increases,significantly beyond the yield stress,the creep of both sediments increases significantly,with hydrate-bearing sediment exhibiting much greater creep than hydrate-free sediment. 展开更多
关键词 Hydrate-bearing sediment phase transition Volume change Creep behavior
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Phase geometric propagation model of spherical projectile impacting thin plate based on shock wave propagation
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作者 Lvtan Chen Qiguang He +3 位作者 Chenyang Wu Ying Chen Qunyi Tang Xiaowei Chen 《Defence Technology(防务技术)》 2026年第2期14-31,共18页
Material phase-transition represents a significant phenomenon and mechanism in the context of hypervelocity protection.This study presents a thorough analysis of the phase-transition phenomena induced by shock pressur... Material phase-transition represents a significant phenomenon and mechanism in the context of hypervelocity protection.This study presents a thorough analysis of the phase-transition phenomena induced by shock pressure as the shock wave propagates initially to the rear of the projectile.The shock wave that induces a phase-transition is commonly referred to as a macroscopic phase-transition wave,whereas the interface that separates the distinct phases is referred to as macroscopic phase-boundary.The contact interface between the spherical projectile and the thin plate,characterized by its curved surface,plays a significant role in the nonlinear propagation and evolution of wave systems.The pressure distribution along the central axis of a spherical projectile is derived in accordance with the linear decay law observed for axial pressure.On this basis,a quadratic function is employed to characterize the trend of changes in wave front pressure,thereby facilitating the establishment of a model for wave front pressure distribution.Using the phase-transition pressure criterion for materials,the wave front phase evolution process is derived,and the macroscopic phase-boundary is determined.Based on the geometric propagation model(GPM)and the pressure distribution of the wave front,a phase geometric propagation model(PGPM)is proposed.The phase distribution of a spherical projectile impacting a thin plate is obtained by theoretical methods.The accuracy of the PGPM is subsequently validated through a comparison of its results with those obtained from numerical simulations. 展开更多
关键词 Hypervelocity impact Debris cloud phase-TRANSITION Pressure distribution phase distribution
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Eliminating Schottky Barrier via interface state manipulation on phase-tailored 2D/3D perovskite solar cells
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作者 Junmin Xia Hao Gu +15 位作者 Ziyi Wang Mengting Chen Hui Hong Zhifeng Li Bo Cai Kun Cao Jia Guo Guangbao Wu Ke Guo Shengwen Li Annan Zhu Shi Chen Yongqing Cai Chao Liang Shufen Chen Guichuan Xing 《Journal of Energy Chemistry》 2026年第1期760-769,I0017,共11页
Surface passivation via two-dimensional(2D)perovskite has emerged as a promising strategy to enhance the performance of perovskite solar cells(PSCs)due to the effective compensation of interfacial states.However,the i... Surface passivation via two-dimensional(2D)perovskite has emerged as a promising strategy to enhance the performance of perovskite solar cells(PSCs)due to the effective compensation of interfacial states.However,the in situ grown 2D perovskite passivation layers typically comprise a mixture of multiple dimensionalities at the interface,where band alignment has only been portrayed qualitatively and empirically.Herein,the interface states for precisely phase-tailored 2D perovskite passivated PSCs are quantitatively investigated.In comparison to traditional passivation molecules,2D perovskite layers based on 4-trifluoromethyl-phenylethylammonium iodide(CF3PEAI)exhibit an increased work function,introducing desirable downward band bending to eliminate the Schottky Barrier.Furthermore,precisely phase-tailored 2D layers could modulate the interface trap density and energetics.The n=1 film delivers optimal performance with a hole extraction efficiency of 95.1%.The optimized n-i-p PSCs in the two-step method significantly improve PCE to 25.40%,along with enhanced photostability and negligible hysteresis.It highlights that tailoring in the composition and phase distribution of the 2D perovskite layer could modulate the interface states at the 2D/3D interface. 展开更多
关键词 Perovskite solar cells Interface states Band alignment phase tailoring
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W/V Dual-Atom Doping MoS_(2)-Mediated Phase Transition for Efficient Polysulfide Adsorption/Conversion Kinetics in Lithium-Sulfur Battery
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作者 Zhe Cui Ping Feng +2 位作者 Gang Zhong Qingdong Ou Mingkai Liu 《Nano-Micro Letters》 2026年第4期700-717,共18页
The dissolvable polysulfides and sluggish Li_2S conversion kinetics are acknowledged as two significant challenges in the application lithium-sulfur(Li-S)batteries.Herein,we introduce a dual-doping strategy to modulat... The dissolvable polysulfides and sluggish Li_2S conversion kinetics are acknowledged as two significant challenges in the application lithium-sulfur(Li-S)batteries.Herein,we introduce a dual-doping strategy to modulate the electronic structure of MoS_(2),thereby obtaining a multifunctional catalyst that serves as an efficient sulfur host.The W/V dual single-atomdoped MoS_(2)grown on carbon nanofibers(CMWVS)demonstrates a strong adsorption ability for lithium polysulfides,suppressing the shuttle effects.Additionally,the doping process also results in the phase transition from 2H-MoS_(2)to 1T-MoS_(2)and generates sufficient edge sulfur atoms,promoting the charge/electron transfer and enriching the reaction sites.All these merits contribute to the superior conversion reaction kinetics,leading to the outstanding Li-S battery performance.When fabricated as cathodes by compositing with sulfur,the CMWVS/S cathode delivers a high capacity of 1481.7 mAh g^(-1)at 0.1 C(1 C=1672 mAh g^(-1))and maintains 816.3 m Ah g^(-1)after 1000 cycles at 1.0 C,indicating outstanding cycling stability.Even under a high sulfur loading of 7.9 mg cm^(-2)and lean electrolyte conditions(E/S ratio of 9.0μL mg^(-1)),the cathode achieves a high areal capacity of 8.2 m Ah cm^(-2),showing great promise for practical Li-S battery applications.This work broadens the scope of doping strategies in transition-metal dichalcogenides by tailoring their electronic structures,providing insightful direction for the rational development of high-efficiency electrocatalysts for advanced Li-S battery applications. 展开更多
关键词 lithium-sulfur batteries ELECTROCATALYST phase transition Dual single atoms Molybdenum disulfide
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8-inch free-standing GaN substrates grown by hydride vapor phase epitaxy
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作者 Ruihua Zhang Fang Liu +12 位作者 Yao Wu Hongfen Xu Jinmi He Ming Liu Jianhui Wang Kunyang Li Ping Wang Jiejun Wu Tongjun Yu Qi Wang Jingquan Lu Guoyi Zhang Xinqiang Wang 《Journal of Semiconductors》 2026年第2期80-86,共7页
The absence of large-size gallium nitride(GaN) substrates with low dislocation density remains a primary bottleneck for advancing GaN-based devices. Here, we demonstrate the achievement of 8-inch freestanding GaN subs... The absence of large-size gallium nitride(GaN) substrates with low dislocation density remains a primary bottleneck for advancing GaN-based devices. Here, we demonstrate the achievement of 8-inch freestanding GaN substrates grown by hydride vapor phase epitaxy. Critical to this achievement is the improvement in gas-flow uniformity, which ensures exceptional thickness homogeneity and enables the crack-free growth of GaN. After laser lift-off(LLO) separation, the freestanding GaN substrate exhibits superior crystal quality, evidenced by full width at half maximum values of 68 and 54 arcsec for X-ray diffraction rocking curves of(002) and(102) planes, alongside a low dislocation density of 1.6 × 10^(6) cm^(-2). This approach establishes a robust pathway for the production of large-size GaN substrates, which are essential for advancing next-generation power electronics and high-efficiency photonics. 展开更多
关键词 gallium nitride single-crystal substrates large size hydride vapor phase epitaxy
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