[Objective] Effects of nitrogen amount and nitrogen form on 1-deoxynojimycin（DNJ）content in mulberry leaf was explored in order to provide a reference for improving DNJ content in mulberry leaf and its medicinal val...[Objective] Effects of nitrogen amount and nitrogen form on 1-deoxynojimycin（DNJ）content in mulberry leaf was explored in order to provide a reference for improving DNJ content in mulberry leaf and its medicinal value.[Method] Effects of nitrogen amount（NO-3-N and NH＋4-N）and nitrogen form（NO-3-N/NH＋4-N）on DNJ content in mulberry leaf were studied by changing nitrogen amount and nitrogen form in water culture solution.[Result] DNJ contents in mulberry leaf both increased at first and then decreased with the increase of nitrogen amount,furthermore compared with NH＋4-N,NO-3-N was more beneficial to the accumulation of DNJ;DNJ content in mulberry leaf obviously increased at first and then decreased with the decrease of NO-3-N/NH＋4-N,among them when its rate was 25/75,DNJ content reached the highest.[Conclusion] Proper nitrogen amount and nitrogen form could effectively improve the DNJ content in mulberry leaf.展开更多
[Objective] The experiment was conducted to explore the suitable planting density and nitrogen amount for summer maize in Sichuan Basin with the objective to provide technical reservation and scientific basis for high...[Objective] The experiment was conducted to explore the suitable planting density and nitrogen amount for summer maize in Sichuan Basin with the objective to provide technical reservation and scientific basis for high-yielding cultivation technique.[Method] A widely planted maize cultivar ＇Chengdan 30＇ was used as experimental material to study the effects of planting density and nitrogen amount on the stalk agronomic traits,stalk lodging-resistance mechanical characters,stalk breaking percentage and yield of maize.Experiment was arranged in a two-factor split plot design with three replicates.The planting density was the main factor with three density gradients（4.5×10^4,6.0×10^4 and 7.5×10^4 plants/hm^2） and the nitrogen amount was the second factor with two different levels of nitrogen content（300 and 375 kg/hm^2）.[Result] The stalk lodging-resistance and yield were affected by planting density significantly.The increase of planting density would result in an increase of internode length and decrease of internode diameter,dry matter weight of per unit stalk length,rind penetration strength and breaking resistance of 3rd and 4th basal internodes.When planting density increased from 6.0×10^4 plants/hm2 to 7.5×10^4 plants/hm^2,the stalk breaking percentage in the whole growing season increased by 17.17%,and the yield reduced by 17.58%.The interaction between planting density and nitrogen amount affected the stalk breaking percentage in the whole growing season and yield significantly.The treatment with planting density of 6.0×104 plants/hm^2 and nitrogen amount of 375 kg/hm^2 of pure N was an optimal combination,which may not only control the stalk breaking percentage of whole growing stage effectively,but also could obtain an optimum grain yield.[Conclusion] In Sichuan Basin,the appropriate planting density and nitrogen amount for summer maize were 6.0×10^4 plants/hm^2 and 375 kg/hm^2.展开更多
[Objective] The aim of this study is to investigate the optimum application amount of nitrogen in Lycium barbarum based on considering the relationship between main secondary metabolites and polysaccharide.[Method]Und...[Objective] The aim of this study is to investigate the optimum application amount of nitrogen in Lycium barbarum based on considering the relationship between main secondary metabolites and polysaccharide.[Method]Under field conditions,the effects of different application amounts of nitrogen on main secondary metabolites of betaine,carotenoid and flavone of Lycium barbarum and the relationship between main secondary metabolites and polysaccharide.[Result] The main secondary metabolites of betaine,carotenoid and flavone of Lycium barbarum varied under different application amounts of nitrogen.The proper application amount of nitrogen(600-900 kg/hm2)was beneficial to the formation and accumulation of secondary metabolites such as carotenoids.Correlation analysis results showed that polysaccharide were negatively correlated with betaine,carotenoid and flavone at significant probability level.[Conclusion]Considering the relationship between the output and quality of the fruits of Lycium barbarum,the optimum nitrogen application amount should be 600-900 kg/hm2.展开更多
[ Objective] The aim of the research was to provide reference for reasonable application of nitrogen fertilizer for high yield.cultivation of hybrid rape cuhivar Youyan 9 and Youyan 10. [ Method] The net increment cha...[ Objective] The aim of the research was to provide reference for reasonable application of nitrogen fertilizer for high yield.cultivation of hybrid rape cuhivar Youyan 9 and Youyan 10. [ Method] The net increment changes of individual plant fresh weight and dry matter weight of Youyan 9 and Youyan 10 with different nitrogen application treatments were studied. [ Result] The differences among average fresh weight increments of individual plant and average dry matter weight increment of individual plant with different treatments reached 0. 01 extremely significant level. Fresh weight increment and dry matter weight net increment of individual plant declined gradually with the increase of nitrogen application. In growtheourse ,fresh weight net increment of individual plant increased firstly then decreased and the maximum was in beginning flowering stage, besides that dry matter net increment increased gradually and the maximum was in mature period. The correlations among fresh net increment, dry matter weight net increment and yield net increment were positive or extremely positive. [ Conclusion] Under experimental condition, when nitrogen application was 225 kg/hm^2, hybrid rape Yanyou 9 and Yanyou 10 with low erucic,low glucosinolate could obtain high yield.展开更多
[Objective] This study aimed to explore an optimum application amount of nitrogen for cotton cultivation. [Method] In this study, a field experiment was conducted to investigate the effects of nitrogen application amo...[Objective] This study aimed to explore an optimum application amount of nitrogen for cotton cultivation. [Method] In this study, a field experiment was conducted to investigate the effects of nitrogen application amount on the growth characteristics, boll development and lint yield of high quality cotton line FZ-1. [Result] Compared with the nitrogen level of 225 kg/hm2, the lint yield had increased by 28.46% and 18.73%, respectively, with the nitrogen application amount of 300 and 375 kg/hm2. When the nitrogen application amount had increased from 225 to 300 kg/hm2, boll number per plant, boll weight and lint yield had significantly increased. At the nitrogen level of 375 kg/hm2, however, the effects of increasing lint yield were significantly less than that at the nitrogen level of 300 kg/hm2. Compared with the nitrogen levels of 225 and 375, 300 kg/hm2 of nitrogen was the optimum application amount to improve the plant height, daily increment of plant height, number of fruit branches, number ratio of nodes to fruit branches, boll volume and seed cotton weight per boll. [Conclusion] The rational management of nitrogen is the most effective way to promote the growth and development of cotton plants, ensure high yielding ability and minimize the environmental pollution caused by the overuse of nitrogen. This study had provided a sound nitrogen application strategy for the cultivation of this high-quality cotton line in the field plantation.展开更多
[Objective] The paper was to study the nitrogen application amount and nitrogen application model for high grade hybrid rapeseed （Brassica napus L.） to get high yield. [Method] With ＂Youyan 599＂ and ＂Sanbei 98＂ ...[Objective] The paper was to study the nitrogen application amount and nitrogen application model for high grade hybrid rapeseed （Brassica napus L.） to get high yield. [Method] With ＂Youyan 599＂ and ＂Sanbei 98＂ as materials, using quadratic regression orthogonal gyration combination design, the impact of nitrogen application amount during various periods on rapeseed yield was studied. [Result] The combinations of factors to obtain the highest yield index （2 898.211 kg / hm 2 ） of ＂Youyan 599＂ were as follows： living rape fertilizer 89.27 kg / hm 2 , opening fertilizer 120 kg / hm 2 , 12 th lunar month fertilizer 101.12 kg / hm 2 , total nitrogen application amount 310.39 kg / hm 2 . The proportions of living rape fertilizer, opening fertilizer and 12th lunar month fertilizer were 28.76%, 38.66% and 32.58%, respectively. The combinations of factors to obtain the highest yield index （2 870.14 kg/hm 2 ） of ＂Sanbei 98＂ were as follows： living rape fertilizer 120 kg / hm 2 , opening fertilizer 120 kg / hm 2 , 12 th lunar month fertilizer 37.55kg / hm 2 , total nitrogen application amount 277.55 kg / hm 2 . The proportions of living rape fertilizer, opening fertilizer and 12 th lunar month fertilizer were 43.24%, 43.24% and 13.53%, respectively. The combinations of factors to obtain the highest yield index of two combined varieties （2 813.82 kg/hm 2 ）were as follows： living rape fertilizer 120 kg/hm 2 , opening fertilizer 120 kg/hm 2 , 12 th lunar month fertilizer 76.23 kg/hm 2 , total nitrogen application amount 316.23 kg/hm 2 . The proportions of living rape fertilizer, opening fertilizer and 12 th lunar month fertilizer were 37.95% , 37.95% and 24.11% , respectively. [Conclusion] The paper provided theoretical basis for high yield cultivation of high grade hybridized rapeseed.展开更多
[Objective] This study aimed to provide certain scientific basis for reasonable application of nitrogen fertilizer in the pollution-free cultivation of Phaseolus vulgaris. [Method] A field experiment was conducted to ...[Objective] This study aimed to provide certain scientific basis for reasonable application of nitrogen fertilizer in the pollution-free cultivation of Phaseolus vulgaris. [Method] A field experiment was conducted to investigate the effects of different nitrogen fertilization amounts on the prophase yield and economic efficiency of P. vulgaris and available nitrogen content of soil. [Result] With the increased application amount of nitrogen fertilizer, the prophase yield and economic efficiency of P. vulgaris reached the peaks in the Treatment 3 （8 690.48 kg/ hm^2 and 32 222 yuan/hm^2）, and significant differences were found among different treatment groups. With the increased nitrogen fertilization amount, the soil available nitrogen content increased, showing a positive correlation with correlation coefficient of 0.856 5. Excess nitrogen fertilizer reduced the prophase yield and economic efficiency of P. vulgaris. For the open field cultivation of P. vulgaris, the optimum application amount of nitrogen fertilizer was 178 kg/hm^2. [Conclusion] Application of nitrogen fertilizer could effectively increase the soil available nitrogen content.展开更多
[Objective] This study aimed to determine the effects of supplemental irrigation on yield and nitrogen uptake in winter wheat. [Method] Three supplemental irrigation levels were set based on the target soil contents ...[Objective] This study aimed to determine the effects of supplemental irrigation on yield and nitrogen uptake in winter wheat. [Method] Three supplemental irrigation levels were set based on the target soil contents of 60%, 70% and 80%） at jointing stage of wheat. Moreover, three nitrogen levels （0, 195 and 255 kg/hm^2） were designed. The experimental plots were arranged fol owing a split-plot design. Zhoumai 18 was selected as the experimental material. [Result] Supplemental irrigation and nitrogen application in combination had significant or extremely significant effects on yield, yield components and nitrogen uptake in winter wheat. The interaction between irrigation and nitrogen fertilization had significant or extremely significant influence on the number of ears, number of grains per ear, 1 000-grain weight, grain yield and nitrogen accumulation in winter wheat. Under different combinations of supplemental irrigation and nitrogen application, the maximum yield of winter wheat was obtained at W2 N195, while the minimum at W1 N255. [Conclusion] With the increase of irrigation, negative effect of nitrogen on number of ears, number of grains per ear, 1 000-grain weight, grain yield and nitrogen accumulation decrease under lower nitrogen application rate.展开更多
[Objective] This study was conducted to optimize the suitable application amounts of nitrogen fertilizer and phosphate fertilizer for winter wheat.[Method] A field experiment was carried out to investigate the effects...[Objective] This study was conducted to optimize the suitable application amounts of nitrogen fertilizer and phosphate fertilizer for winter wheat.[Method] A field experiment was carried out to investigate the effects of the application amounts of nitrogen fertilizer and phosphate fertilizer on the yield of winter wheat.[Result]The quadratic simulation function between the application of nitrogen fertilizer and wheat yield was y =-0.6611x^2＋20.091 x ＋234.85,with a correlation coefficient of0.970 8,and the yield of winter wheat was the highest at the application amount of nitrogen fertilizer of 228.0 kg/hm^2.The quadratic simulation function between the application of phosphate fertilizer and wheat yield was y =-0.572 6x^2＋13.168 x ＋340.4,with a correlation coefficient of 0.921 95,and the yield of winter wheat was the highest at the application amount of phosphate fertilizer of 172.5 kg/hm^2.[Conclusion] This study provides a scientific basis for the rational application of nitrogen fertilizer and phosphate fertilizer on winter wheat.展开更多
Available irrigation resources are becoming increasingly scarce in the North China Plain (NCP),and nitrogen-use efficiency of crop production is also relatively low.Thus,it is imperative to improve the water-use effic...Available irrigation resources are becoming increasingly scarce in the North China Plain (NCP),and nitrogen-use efficiency of crop production is also relatively low.Thus,it is imperative to improve the water-use efficiency (WUE) and nitrogen fertilizer productivity on the NCP.Here,we conducted a two-year field experiment to explore the effects of different irrigation amounts (S60,60 mm;S90,90 mm;S120,120 mm;S150,150 mm) and nitrogen application rates (150,195 and 240 kg ha^(–1);denoted as N1,N2 and N3,respectively) under micro-sprinkling with water and nitrogen combined on the grain yield(GY),yield components,leaf area index (LAI),flag leaf chlorophyll content,dry matter accumulation (DM),WUE,and nitrogen partial factor productivity (NPFP).The results indicated that the GY and NPFP increased significantly with increasing irrigation amount,but there was no significant difference between S120 and S150;WUE significantly increased first but then decreased with increasing irrigation and S120 achieved the highest WUE.The increase in nitrogen was beneficial to improving the GY and WUE in S60 and S90,while the excessive nitrogen application (N3) significantly reduced the GY and WUE in S120 and S150 compared with those in the N2 treatment.The NPFP significantly decreased with increasing nitrogen rate under the same irrigation treatments.The synchronous increase in spike number (SN) and 1 000-grain weight (TWG)was the main reason for the large increase in GY by micro-sprinkling with increasing irrigation,and the differences in SN and TGW between S120 and S150 were small.Under S60 and S90,the TGW increased with increasing nitrogen application,which enhanced the GY,while N2 achieved the highest TWG in S120 and S150.At the filling stage,the LAI increased with increasing irrigation,and greater amounts of irrigation significantly increased the chlorophyll content in the flag leaf,which was instrumental in increasing DM after anthesis and increasing the TGW.Micro-sprinkling with increased amounts of irrigation or excessive nitrogen application decreased the WUE mainly due to the increase in total water consumption (ET)and the small increase or decrease in GY.Moreover,the increase in irrigation increased the total nitrogen accumulation or contents (TNC) of plants at maturity and reduced the residual nitrate-nitrogen in the soil (SNC),which was conducive to the increase in NPFP,but there was no significant difference in TNC between S120 and S150.Under the same irrigation treatments,an increase in nitrogen application significantly increased the residual SNC and decreased the NPFP.Overall,micro-sprinkling with 120 mm of irrigation and a total nitrogen application of 195 kg ha^(–1) can lead to increases in GY,WUE and NPFP on the NCP.展开更多
In order to screen suitable high hybrid wheat seed production technology,the split-plot experiment design was adopted and study was carried out about the effects of the different row ratios of male and female parents ...In order to screen suitable high hybrid wheat seed production technology,the split-plot experiment design was adopted and study was carried out about the effects of the different row ratios of male and female parents and application amount of nitrogen fertilizer on hybrid wheat seed production and its component factors. The results showed that the seed production increased with the increase in the number of female parent row. When the row ratio of male and female parents was 2 ∶ 6,the seed production was 3 683. 8 kg/ha; when the application amount of nitrogen fertilization was 50 kg/ha,the seed production was 3 649. 4 kg/ha; the interaction between the row ratio of male and female parents and the application amount of nitrogen fertilizer indicated that when the row ratio of male and female parents was 2∶ 6 and the application amount of nitrogen fertilizer was 300 kg/ha,the seed production reached the highest( 4160. 6 kg/ha). The row ratio of male and female parents and application amount of nitrogen fertilizer had significant effect on the component factors of seed production,including the number of grains per spike,spike weight and setting percentage. When the row ratio of male and female parents was 2∶ 5,the number of grains per spike,spike weight and setting percentage were the highest at 26. 7 grains,1. 12 g,and 62. 6% respectively; when application amount of nitrogen fertilizer was 450 kg/ha,the number of grains per spike,spike weight and setting percentage were the highest at 26. 0 grains,1. 08 g,and59. 2% respectively; the interaction of row ratio of male and female parents and application amount of nitrogen fertilizer had significant effect on the number of grains per spike,spike weight and setting percentage; when the row ratio of male and female parents was 2∶ 5 and the application amount of nitrogen fertilizer was 300 kg/ha,the number of grains per spike,spike weight and setting percentage were the highest at 29. 6grains,1. 24 g,and 71. 6% respectively. The number of grains per spike is the largest component factor for seed production. Increasing the number of grains per spike can increase the seed production. According to the effects of row ratio of male and female parents and application amount of nitrogen fertilizer on the component factors of seed production,the optimal condition was 2∶ 5-2∶ 6 for row ratio of male and female parents and 300-450 kg/ha for application amount of nitrogen fertilizer.展开更多
Corn, with C4 photosynthetic metabolism, often has no photosynthetic or yield response to elevated carbon dioxide concentrations. In C3 species, the yield stimulation at elevated carbon dioxide concentrations often de...Corn, with C4 photosynthetic metabolism, often has no photosynthetic or yield response to elevated carbon dioxide concentrations. In C3 species, the yield stimulation at elevated carbon dioxide concentrations often decreases with nitrogen limitation. I tested whether such a nitrogen interaction occurred in corn, by growing sweet corn in field plots in open top chambers at ambient and elevated (ambient + 180 mmol·mol-1) carbon dioxide concentrations for four seasons, with six nitrogen application rates, ranging from half to twice the locally recommended rate. At the recommended rate of nitrogen application, no carbon dioxide effect on production occurred. However, both ear and leaf plus stem biomass were lower for the elevated carbon dioxide treatment than for the ambient treatment at less than the recommended rate of nitrogen application, and higher at the highest rates of nitrogen application. There were no significant responses of mid-day leaf gas exchange rates to nitrogen application rate for either carbon dioxide treatment, and elevated carbon dioxide did not significantly increase leaf carbon dioxide assimilation rates at any nitrogen level. Leaf area index during vegetative growth increased more with nitrogen application rate at elevated than at ambient carbon dioxide. It is concluded that elevated carbon dioxide increased the responsiveness of corn growth to nitrogen application by increasing the response of leaf area to nitrogen application rate, and that elevated carbon dioxide increased the amount of nitrogen required to achieve maximum yields.展开更多
WNxfilms are deposited by reactive chemical vapor deposition at different amounts of nitrogen in gas mixtures.Experimental data demonstrate that nitrogen amount has a strong effect on microstructure, phase formation,t...WNxfilms are deposited by reactive chemical vapor deposition at different amounts of nitrogen in gas mixtures.Experimental data demonstrate that nitrogen amount has a strong effect on microstructure, phase formation,texture morphology, mechanical and optical properties of the WNxfilms. With increasing nitrogen a phase transition from a single WNxphase with low crystallinity structure to a well-mixed crystallized hexagonal WNxand face-centered-cubic W2N phases appears. Relatively smooth morphology at lower N2concentration changes to a really smooth morphology and then granular with coarse surface at higher N2concentration. The SEM observation clearly shows a columnar structure at lower N2concentration and a dense nanoplates one for higher nitrogen content. The hardness of WNxthin films mainly depends on the film microstructure. The absorbance peak position shifts to shorter wavelength continuously with increasing nitrogen amount and decreasing particle size.展开更多
The increase in soil temperature associated with climate change has introduced considerable challenges to crop production.Split nitrogen application(SN)represents a potential strategy for improving crop nitrogen use e...The increase in soil temperature associated with climate change has introduced considerable challenges to crop production.Split nitrogen application(SN)represents a potential strategy for improving crop nitrogen use efficiency and enhancing crop stress resistance.Nevertheless,the precise interaction between soil warming(SW)and SN remains unclear.In order to ascertain the impact of SW on maize growth and whether SN can improve the tolerance of maize to SW,a two-year field experiment was conducted(2022-2023).The aim was to examine the influence of two SW ranges(MT,warming 1.40℃;HT,warming 2.75℃)and two nitrogen application methods(N1,one-time basal application of nitrogen fertilizer;N2,one third of base nitrogen fertilizer+two thirds of jointing stage supplemental nitrogen fertilizer)on maize root growth,photosynthetic characteristics,nitrogen use efficiency,and yield.The results demonstrated that SW impeded root growth and precipitated the premature aging of maize leaves following anthesis,particularly in the HT,which led to a notable reduction in maize yield.In comparison to N1,SN has been shown to increase root length density by 8.54%,root bleeding rate by 8.57%,and enhance root distribution ratio in the middle soil layers(20-60 cm).The interaction between SW and SN had a notable impact on maize growth and yield.The SN improved the absorption and utilization efficiency of nitrogen by promoting root development and downward canopy growth,thus improving the tolerance of maize to SW at the later stage of growth.In particular,the N2HT resulted in a 14.51%increase in the photosynthetic rate,a 18.58%increase in nitrogen absorption efficiency,and a 18.32%increase in maize yield compared with N1HT.It can be posited that the SN represents a viable nitrogen management measure with the potential to enhance maize tolerance to soil high-temperature stress.展开更多
Nitrogen(N)uptake is regulated by water availability,and a water deficit can limit crop N responses by reducing N uptake and utilization.The complex and multifaceted interplay between water availability and the crop N...Nitrogen(N)uptake is regulated by water availability,and a water deficit can limit crop N responses by reducing N uptake and utilization.The complex and multifaceted interplay between water availability and the crop N response makes it difficult to predict and quantify the effect of water deficit on crop N status.The nitrogen nutrition index(NNI)has been widely used to accurately diagnose crop N status and to evaluate the effectiveness of N application.The decline of NNI under water-limiting conditions has been documented,although the underlying mechanism governing this decline is not fully understood.This study aimed to elucidate the reason for the decline of NNI under waterlimiting conditions and to provide insights into the accurate utilization of NNI for assessing crop N status under different water-N interaction treatments.Rainout shelter experiments were conducted over three growing seasons from 2018 to 2021 under different N(75 and 225 kg N ha^(-1),low N and high N)and water(120 to 510 mm,W0 to W3)co-limitation treatments.Plant N accumulation,shoot biomass(SB),plant N concentration(%N),soil nitrate-N content,actual evapotranspiration(ET_a),and yield were recorded at the stem elongation,booting,anthesis and grain filling stages.Compared to W0,W1 to W3 treatments exhibited NNI values that were greater by 10.2 to 20.5%,12.6to 24.8%,14 to 24.8%,and 16.8 to 24.8%at stem elongation,booting,anthesis,and grain filling,respectively,across the 2018-2021 seasons.This decline in NNI under water-limiting conditions stemmed from two main factors.First,reduced ET_(a) and SB led to a greater critical N concentration(%N_(c))under water-limiting conditions,which contributed to the decline in NNI primarily under high N conditions.Second,changes in plant%N played a more significant role under low N conditions.Plant N accumulation exhibited a positive allometric relationship with SB and a negative relationship with soil nitrate-N content under water-limiting conditions,indicating co-regulation by SB and the soil nitrate-N content.However,this regulation was influenced by water availability.Plant N accumulation sourced from the soil nitrate-N content reflects soil N availability.Greater soil water availability facilitated greater absorption of soil nitrate-N into the plants,leading to a positive correlation between plant N accumulation and ET_(a)across the different water-N interaction treatments.Therefore,considering the impact of soil water availability is crucial when assessing soil N availability under water-limiting conditions.The findings of this study provide valuable insights into the factors contributing to the decline in NNI among different water-N interaction treatments and can contribute to the more accurate utilization of NNI for assessing winter wheat N status.展开更多
The trade-off between yield and environmental effects caused by nitrogen fertilizer application is an important issue in wheat production.A reduction in fertile florets is one of the main reasons for the lower yields ...The trade-off between yield and environmental effects caused by nitrogen fertilizer application is an important issue in wheat production.A reduction in fertile florets is one of the main reasons for the lower yields under low nitrogen application rates.Brassinosteroids(BRs)have been found to play a role in nitrogen-induced rice spikelet degeneration.However,whether BRs play a role in wheat floret development and the mechanisms involved are not clear.Therefore,a nitrogen gradient experiment and exogenous spraying experiment were conducted to investigate the role and mechanism of BRs in wheat floret development under low nitrogen stress.The results showed that as the nitrogen application decreased,the endogenous BRs content of the spikes decreased,photosynthesis weakened,and total carbon,soluble sugar and starch in the spikes decreased,leading to a reduction in the number of fertile florets.Under low nitrogen stress,exogenous spraying of 24-epibrassinolide promoted photosynthesis,and stimulated stem fructan hydrolysis and the utilization and storage of sucrose in spikes,which directed more carbohydrates to the spikes and increased the number of fertile florets.In conclusion,BRs mediate the effects of nitrogen fertilizer on wheat floret development,and under low nitrogen stress,foliar spraying of 24-epibrassinolide promotes the flow of carbohydrates from the stem to the spikes,alleviating wheat floret degeneration.展开更多
The thermochemical non-equilibrium phenomena encountered by hypersonic vehicles present significant challenges in their design.To investigate the thermochemical reaction flow behind shock waves,the non-equilibrium rad...The thermochemical non-equilibrium phenomena encountered by hypersonic vehicles present significant challenges in their design.To investigate the thermochemical reaction flow behind shock waves,the non-equilibrium radiation in the visible range using a shock tube was studied.Experiments were conducted with a shock velocity of 4.7 km/s,using nitrogen at a pressure of 20 Pa.To address measurement difficulties associated with weak radiation,a special square section shock tube with a side length of 380 mm was utilized.A high-speed camera characterized the shock wave’s morphology,and a spectrograph and a monochromator captured the radiation.The spectra were analyzed,and the numerical spectra were compared with experimental results,showing a close match.Temperature changes behind the shock wave were obtained and compared with numerical predictions.The findings indicate that the vibrational temperatures are overestimated,while the vibrational relaxation time is likely underestimated,due to the oversimplified portrayals of the non-equilibrium relaxation process in the models.Additionally,both experimental and simulated time-resolved profiles of radiation intensity at specific wavelengths were analyzed.The gathered data aims to enhance computational fluid dynamics codes and radiation models,improving their predictive accuracy.展开更多
Ammonia and nitric acid,versatile industrial feedstocks,and burgeoning clean energy vectors hold immense promise for sustainable development.However,Haber–Bosch and Ostwald processes,which generates carbon dioxide as...Ammonia and nitric acid,versatile industrial feedstocks,and burgeoning clean energy vectors hold immense promise for sustainable development.However,Haber–Bosch and Ostwald processes,which generates carbon dioxide as massive by-product,contribute to greenhouse effects and pose environmental challenges.Thus,the pursuit of nitrogen fixation through carbon–neutral pathways under benign conditions is a frontier of scientific topics,with the harnessing of solar energy emerging as an enticing and viable option.This review delves into the refinement strategies for scale-up mild photocatalytic nitrogen fixation,fields ripe with potential for innovation.The narrative is centered on enhancing the intrinsic capabilities of catalysts to surmount current efficiency barriers.Key focus areas include the in-depth exploration of fundamental mechanisms underpinning photocatalytic procedures,rational element selection,and functional planning,state-of-the-art experimental protocols for understanding photo-fixation processes,valid photocatalytic activity evaluation,and the rational design of catalysts.Furthermore,the review offers a suite of forward-looking recommendations aimed at propelling the advancement of mild nitrogen photo-fixation.It scrutinizes the existing challenges and prospects within this burgeoning domain,aspiring to equip researchers with insightful perspectives that can catalyze the evolution of cutting-edge nitrogen fixation methodologies and steer the development of next-generation photocatalytic systems.展开更多
In contrast to research on active sites in nanomaterials,lithium tantalate single crystals,known for their exceptional optical properties and long-range ordered lattice structure,present a promising avenue for in-dept...In contrast to research on active sites in nanomaterials,lithium tantalate single crystals,known for their exceptional optical properties and long-range ordered lattice structure,present a promising avenue for in-depth exploration of photocatalytic reaction systems with fewer constraints imposed by surface chemistry.Typically,the isotropy of a specific facet provides a perfect support for studying heteroatom doping.Herein,this work delves into the intrinsic catalytic sites for photocatalytic nitrogen fixation in iron-doped lithium tantalate single crystals.The presence of iron not only modifies the electronic structure of lithium tantalate,improving its light absorption capacity,but also functions as an active site for the nitrogen adsorption and activation.The photocatalytic ammonia production rate of the iron-doped lithium tantalate in pure water is maximum 26.95μg cm^(−2)h^(−1),which is three times higher than that of undoped lithium tantalate.The combination of first-principles simulations with in situ characterizations confirms that iron doping promotes the rate-determining step and changes the pathway of hydrogenation to associative alternating.This study provides a new perspective on in-depth investigation of intrinsic catalytic active sites in photocatalysis and other catalytic processes.展开更多
To more accurately describe the coal damage and fracture evolution law during liquid nitrogen(LN_(2))fracturing under true triaxial stress,a thermal-hydraulic-mechanical-damage(THMD)coupling model for LN_(2) fracturin...To more accurately describe the coal damage and fracture evolution law during liquid nitrogen(LN_(2))fracturing under true triaxial stress,a thermal-hydraulic-mechanical-damage(THMD)coupling model for LN_(2) fracturing coal was developed,considering the coal heterogeneity and thermophysical parameters of nitrogen.The accuracy and applicability of model were verified by comparing with LN_(2) injection pre-cooling and fracturing experimental data.The effects of different pre-cooling times and horizontal stress ratios on coal damage evolution,permeability,temperature distribution,and fracture characteristics were analyzed.The results show that the permeability and damage of the coal increase exponentially,while the temperature decreases exponentially during the fracturing process.As the pre-cooling time increases,the damage range of the coal expands,and the fracture propagation becomes more pronounced.The initiation pressure and rupture pressure decrease and tend to stabilize with longer precooling times.As the horizontal stress ratio increases,fractures preferentially extend along the direction of maximum horizontal principal stress,leading to a significant decrease in both initiation and rupture pressures.At a horizontal stress ratio of 3,the initiation pressure drops by 48.07%,and the rupture pressure decreases by 41.36%.The results provide a theoretical basis for optimizing LN_(2) fracturing techniques and improving coal seam modification.展开更多
基金Supported by Key Technology Innovation Project of Sichuan Province(2008NC00365)~~
文摘[Objective] Effects of nitrogen amount and nitrogen form on 1-deoxynojimycin（DNJ）content in mulberry leaf was explored in order to provide a reference for improving DNJ content in mulberry leaf and its medicinal value.[Method] Effects of nitrogen amount（NO-3-N and NH＋4-N）and nitrogen form（NO-3-N/NH＋4-N）on DNJ content in mulberry leaf were studied by changing nitrogen amount and nitrogen form in water culture solution.[Result] DNJ contents in mulberry leaf both increased at first and then decreased with the increase of nitrogen amount,furthermore compared with NH＋4-N,NO-3-N was more beneficial to the accumulation of DNJ;DNJ content in mulberry leaf obviously increased at first and then decreased with the decrease of NO-3-N/NH＋4-N,among them when its rate was 25/75,DNJ content reached the highest.[Conclusion] Proper nitrogen amount and nitrogen form could effectively improve the DNJ content in mulberry leaf.
基金Supported by the Special Fund for Agricultural and Rural Research in the Public Interest of Sichuan Province(12ZC1930)~~
文摘[Objective] The experiment was conducted to explore the suitable planting density and nitrogen amount for summer maize in Sichuan Basin with the objective to provide technical reservation and scientific basis for high-yielding cultivation technique.[Method] A widely planted maize cultivar ＇Chengdan 30＇ was used as experimental material to study the effects of planting density and nitrogen amount on the stalk agronomic traits,stalk lodging-resistance mechanical characters,stalk breaking percentage and yield of maize.Experiment was arranged in a two-factor split plot design with three replicates.The planting density was the main factor with three density gradients（4.5×10^4,6.0×10^4 and 7.5×10^4 plants/hm^2） and the nitrogen amount was the second factor with two different levels of nitrogen content（300 and 375 kg/hm^2）.[Result] The stalk lodging-resistance and yield were affected by planting density significantly.The increase of planting density would result in an increase of internode length and decrease of internode diameter,dry matter weight of per unit stalk length,rind penetration strength and breaking resistance of 3rd and 4th basal internodes.When planting density increased from 6.0×10^4 plants/hm2 to 7.5×10^4 plants/hm^2,the stalk breaking percentage in the whole growing season increased by 17.17%,and the yield reduced by 17.58%.The interaction between planting density and nitrogen amount affected the stalk breaking percentage in the whole growing season and yield significantly.The treatment with planting density of 6.0×104 plants/hm^2 and nitrogen amount of 375 kg/hm^2 of pure N was an optimal combination,which may not only control the stalk breaking percentage of whole growing stage effectively,but also could obtain an optimum grain yield.[Conclusion] In Sichuan Basin,the appropriate planting density and nitrogen amount for summer maize were 6.0×10^4 plants/hm^2 and 375 kg/hm^2.
基金Supported by Natural Science Foundation of Ningxia Hui Antonomous Region(NZ0603)Natural Science Foundation of Ningxia University(NS0506)~~
文摘[Objective] The aim of this study is to investigate the optimum application amount of nitrogen in Lycium barbarum based on considering the relationship between main secondary metabolites and polysaccharide.[Method]Under field conditions,the effects of different application amounts of nitrogen on main secondary metabolites of betaine,carotenoid and flavone of Lycium barbarum and the relationship between main secondary metabolites and polysaccharide.[Result] The main secondary metabolites of betaine,carotenoid and flavone of Lycium barbarum varied under different application amounts of nitrogen.The proper application amount of nitrogen(600-900 kg/hm2)was beneficial to the formation and accumulation of secondary metabolites such as carotenoids.Correlation analysis results showed that polysaccharide were negatively correlated with betaine,carotenoid and flavone at significant probability level.[Conclusion]Considering the relationship between the output and quality of the fruits of Lycium barbarum,the optimum nitrogen application amount should be 600-900 kg/hm2.
基金Funds for Transformation of Scientific and Technological Achievements of Ministry of Science and Technology of China (04EFN215200268)the Nomarch Special Foundation for the Excellent Science and Technology Talents of Guizhou Province[(2005(77)]the Science and Technology Program of Guizhou Province[(2006)6001]~~
文摘[ Objective] The aim of the research was to provide reference for reasonable application of nitrogen fertilizer for high yield.cultivation of hybrid rape cuhivar Youyan 9 and Youyan 10. [ Method] The net increment changes of individual plant fresh weight and dry matter weight of Youyan 9 and Youyan 10 with different nitrogen application treatments were studied. [ Result] The differences among average fresh weight increments of individual plant and average dry matter weight increment of individual plant with different treatments reached 0. 01 extremely significant level. Fresh weight increment and dry matter weight net increment of individual plant declined gradually with the increase of nitrogen application. In growtheourse ,fresh weight net increment of individual plant increased firstly then decreased and the maximum was in beginning flowering stage, besides that dry matter net increment increased gradually and the maximum was in mature period. The correlations among fresh net increment, dry matter weight net increment and yield net increment were positive or extremely positive. [ Conclusion] Under experimental condition, when nitrogen application was 225 kg/hm^2, hybrid rape Yanyou 9 and Yanyou 10 with low erucic,low glucosinolate could obtain high yield.
基金Supported by Natural Science Foundation of China(NSFC No.30771272,31171483)the Priority Academic Development Program of Jiangsu Higher Education Institutions+1 种基金Jiangsu Innovation Project for Agriculture Science and Technology(cx(11)2054)Jiangsu Agriculture Science and Technology Support Program(SBE2010307)~~
文摘[Objective] This study aimed to explore an optimum application amount of nitrogen for cotton cultivation. [Method] In this study, a field experiment was conducted to investigate the effects of nitrogen application amount on the growth characteristics, boll development and lint yield of high quality cotton line FZ-1. [Result] Compared with the nitrogen level of 225 kg/hm2, the lint yield had increased by 28.46% and 18.73%, respectively, with the nitrogen application amount of 300 and 375 kg/hm2. When the nitrogen application amount had increased from 225 to 300 kg/hm2, boll number per plant, boll weight and lint yield had significantly increased. At the nitrogen level of 375 kg/hm2, however, the effects of increasing lint yield were significantly less than that at the nitrogen level of 300 kg/hm2. Compared with the nitrogen levels of 225 and 375, 300 kg/hm2 of nitrogen was the optimum application amount to improve the plant height, daily increment of plant height, number of fruit branches, number ratio of nodes to fruit branches, boll volume and seed cotton weight per boll. [Conclusion] The rational management of nitrogen is the most effective way to promote the growth and development of cotton plants, ensure high yielding ability and minimize the environmental pollution caused by the overuse of nitrogen. This study had provided a sound nitrogen application strategy for the cultivation of this high-quality cotton line in the field plantation.
基金Supported by Construction Project of National Rapeseed Modern Industrial Technology System (nycytx-00563)Guizhou Academy of Agricultural Sciences "Research of High Yield and High Quality Cultivation Technology for High Grade Hybrid Rapeseed with High Oil" [C ZX(2007)015]+2 种基金Department of Agriculture of Guizhou Province "Research, Promotion and Application of High Yield Cultivation Technology for Hybridized Rapeseed of New Variety Youyan 599" [QNYZZ (2009) 007]Guizhou Academy of Agricultural Sciences "Large Area Intermediate Experiment, Promotion and Application of Hybridized Rapeseed Youyan 599" [QNKZX (2009) 030]Department of Agriculture of Guizhou Province "Integrated Innovation of Seed Production Techniques and Large Area Demonstration for New High Oil Rapeseed Hybrid Variety Sanbei 98 [QKH NY (2010) 3087]~~
文摘[Objective] The paper was to study the nitrogen application amount and nitrogen application model for high grade hybrid rapeseed （Brassica napus L.） to get high yield. [Method] With ＂Youyan 599＂ and ＂Sanbei 98＂ as materials, using quadratic regression orthogonal gyration combination design, the impact of nitrogen application amount during various periods on rapeseed yield was studied. [Result] The combinations of factors to obtain the highest yield index （2 898.211 kg / hm 2 ） of ＂Youyan 599＂ were as follows： living rape fertilizer 89.27 kg / hm 2 , opening fertilizer 120 kg / hm 2 , 12 th lunar month fertilizer 101.12 kg / hm 2 , total nitrogen application amount 310.39 kg / hm 2 . The proportions of living rape fertilizer, opening fertilizer and 12th lunar month fertilizer were 28.76%, 38.66% and 32.58%, respectively. The combinations of factors to obtain the highest yield index （2 870.14 kg/hm 2 ） of ＂Sanbei 98＂ were as follows： living rape fertilizer 120 kg / hm 2 , opening fertilizer 120 kg / hm 2 , 12 th lunar month fertilizer 37.55kg / hm 2 , total nitrogen application amount 277.55 kg / hm 2 . The proportions of living rape fertilizer, opening fertilizer and 12 th lunar month fertilizer were 43.24%, 43.24% and 13.53%, respectively. The combinations of factors to obtain the highest yield index of two combined varieties （2 813.82 kg/hm 2 ）were as follows： living rape fertilizer 120 kg/hm 2 , opening fertilizer 120 kg/hm 2 , 12 th lunar month fertilizer 76.23 kg/hm 2 , total nitrogen application amount 316.23 kg/hm 2 . The proportions of living rape fertilizer, opening fertilizer and 12 th lunar month fertilizer were 37.95% , 37.95% and 24.11% , respectively. [Conclusion] The paper provided theoretical basis for high yield cultivation of high grade hybridized rapeseed.
文摘[Objective] This study aimed to provide certain scientific basis for reasonable application of nitrogen fertilizer in the pollution-free cultivation of Phaseolus vulgaris. [Method] A field experiment was conducted to investigate the effects of different nitrogen fertilization amounts on the prophase yield and economic efficiency of P. vulgaris and available nitrogen content of soil. [Result] With the increased application amount of nitrogen fertilizer, the prophase yield and economic efficiency of P. vulgaris reached the peaks in the Treatment 3 （8 690.48 kg/ hm^2 and 32 222 yuan/hm^2）, and significant differences were found among different treatment groups. With the increased nitrogen fertilization amount, the soil available nitrogen content increased, showing a positive correlation with correlation coefficient of 0.856 5. Excess nitrogen fertilizer reduced the prophase yield and economic efficiency of P. vulgaris. For the open field cultivation of P. vulgaris, the optimum application amount of nitrogen fertilizer was 178 kg/hm^2. [Conclusion] Application of nitrogen fertilizer could effectively increase the soil available nitrogen content.
基金Supported by the Water-and Fertilizer-saving Technology Demonstration for Wheat and Maize in Central Henan Province(2013BAD07B07-2)National Key Technology Research and Development Program during the 12th Five-year Plan Period(2012BAD04B07-2)~~
文摘[Objective] This study aimed to determine the effects of supplemental irrigation on yield and nitrogen uptake in winter wheat. [Method] Three supplemental irrigation levels were set based on the target soil contents of 60%, 70% and 80%） at jointing stage of wheat. Moreover, three nitrogen levels （0, 195 and 255 kg/hm^2） were designed. The experimental plots were arranged fol owing a split-plot design. Zhoumai 18 was selected as the experimental material. [Result] Supplemental irrigation and nitrogen application in combination had significant or extremely significant effects on yield, yield components and nitrogen uptake in winter wheat. The interaction between irrigation and nitrogen fertilization had significant or extremely significant influence on the number of ears, number of grains per ear, 1 000-grain weight, grain yield and nitrogen accumulation in winter wheat. Under different combinations of supplemental irrigation and nitrogen application, the maximum yield of winter wheat was obtained at W2 N195, while the minimum at W1 N255. [Conclusion] With the increase of irrigation, negative effect of nitrogen on number of ears, number of grains per ear, 1 000-grain weight, grain yield and nitrogen accumulation decrease under lower nitrogen application rate.
文摘[Objective] This study was conducted to optimize the suitable application amounts of nitrogen fertilizer and phosphate fertilizer for winter wheat.[Method] A field experiment was carried out to investigate the effects of the application amounts of nitrogen fertilizer and phosphate fertilizer on the yield of winter wheat.[Result]The quadratic simulation function between the application of nitrogen fertilizer and wheat yield was y =-0.6611x^2＋20.091 x ＋234.85,with a correlation coefficient of0.970 8,and the yield of winter wheat was the highest at the application amount of nitrogen fertilizer of 228.0 kg/hm^2.The quadratic simulation function between the application of phosphate fertilizer and wheat yield was y =-0.572 6x^2＋13.168 x ＋340.4,with a correlation coefficient of 0.921 95,and the yield of winter wheat was the highest at the application amount of phosphate fertilizer of 172.5 kg/hm^2.[Conclusion] This study provides a scientific basis for the rational application of nitrogen fertilizer and phosphate fertilizer on winter wheat.
基金funded by the National Key Research and Development Program of China(2016YFD0300105 and 2016YFD0300401)the National Natural Science Foundation of China(31871563)the earmarked fund for China Agriculture Research System(CARS-3)。
文摘Available irrigation resources are becoming increasingly scarce in the North China Plain (NCP),and nitrogen-use efficiency of crop production is also relatively low.Thus,it is imperative to improve the water-use efficiency (WUE) and nitrogen fertilizer productivity on the NCP.Here,we conducted a two-year field experiment to explore the effects of different irrigation amounts (S60,60 mm;S90,90 mm;S120,120 mm;S150,150 mm) and nitrogen application rates (150,195 and 240 kg ha^(–1);denoted as N1,N2 and N3,respectively) under micro-sprinkling with water and nitrogen combined on the grain yield(GY),yield components,leaf area index (LAI),flag leaf chlorophyll content,dry matter accumulation (DM),WUE,and nitrogen partial factor productivity (NPFP).The results indicated that the GY and NPFP increased significantly with increasing irrigation amount,but there was no significant difference between S120 and S150;WUE significantly increased first but then decreased with increasing irrigation and S120 achieved the highest WUE.The increase in nitrogen was beneficial to improving the GY and WUE in S60 and S90,while the excessive nitrogen application (N3) significantly reduced the GY and WUE in S120 and S150 compared with those in the N2 treatment.The NPFP significantly decreased with increasing nitrogen rate under the same irrigation treatments.The synchronous increase in spike number (SN) and 1 000-grain weight (TWG)was the main reason for the large increase in GY by micro-sprinkling with increasing irrigation,and the differences in SN and TGW between S120 and S150 were small.Under S60 and S90,the TGW increased with increasing nitrogen application,which enhanced the GY,while N2 achieved the highest TWG in S120 and S150.At the filling stage,the LAI increased with increasing irrigation,and greater amounts of irrigation significantly increased the chlorophyll content in the flag leaf,which was instrumental in increasing DM after anthesis and increasing the TGW.Micro-sprinkling with increased amounts of irrigation or excessive nitrogen application decreased the WUE mainly due to the increase in total water consumption (ET)and the small increase or decrease in GY.Moreover,the increase in irrigation increased the total nitrogen accumulation or contents (TNC) of plants at maturity and reduced the residual nitrate-nitrogen in the soil (SNC),which was conducive to the increase in NPFP,but there was no significant difference in TNC between S120 and S150.Under the same irrigation treatments,an increase in nitrogen application significantly increased the residual SNC and decreased the NPFP.Overall,micro-sprinkling with 120 mm of irrigation and a total nitrogen application of 195 kg ha^(–1) can lead to increases in GY,WUE and NPFP on the NCP.
基金Supported by State Key Research and Development Program of Ministry of Science and Technology(2016YFD0101603)Fundamental Research Funds for the Central Universities in 2016(XDJK2016A020)
文摘In order to screen suitable high hybrid wheat seed production technology,the split-plot experiment design was adopted and study was carried out about the effects of the different row ratios of male and female parents and application amount of nitrogen fertilizer on hybrid wheat seed production and its component factors. The results showed that the seed production increased with the increase in the number of female parent row. When the row ratio of male and female parents was 2 ∶ 6,the seed production was 3 683. 8 kg/ha; when the application amount of nitrogen fertilization was 50 kg/ha,the seed production was 3 649. 4 kg/ha; the interaction between the row ratio of male and female parents and the application amount of nitrogen fertilizer indicated that when the row ratio of male and female parents was 2∶ 6 and the application amount of nitrogen fertilizer was 300 kg/ha,the seed production reached the highest( 4160. 6 kg/ha). The row ratio of male and female parents and application amount of nitrogen fertilizer had significant effect on the component factors of seed production,including the number of grains per spike,spike weight and setting percentage. When the row ratio of male and female parents was 2∶ 5,the number of grains per spike,spike weight and setting percentage were the highest at 26. 7 grains,1. 12 g,and 62. 6% respectively; when application amount of nitrogen fertilizer was 450 kg/ha,the number of grains per spike,spike weight and setting percentage were the highest at 26. 0 grains,1. 08 g,and59. 2% respectively; the interaction of row ratio of male and female parents and application amount of nitrogen fertilizer had significant effect on the number of grains per spike,spike weight and setting percentage; when the row ratio of male and female parents was 2∶ 5 and the application amount of nitrogen fertilizer was 300 kg/ha,the number of grains per spike,spike weight and setting percentage were the highest at 29. 6grains,1. 24 g,and 71. 6% respectively. The number of grains per spike is the largest component factor for seed production. Increasing the number of grains per spike can increase the seed production. According to the effects of row ratio of male and female parents and application amount of nitrogen fertilizer on the component factors of seed production,the optimal condition was 2∶ 5-2∶ 6 for row ratio of male and female parents and 300-450 kg/ha for application amount of nitrogen fertilizer.
文摘Corn, with C4 photosynthetic metabolism, often has no photosynthetic or yield response to elevated carbon dioxide concentrations. In C3 species, the yield stimulation at elevated carbon dioxide concentrations often decreases with nitrogen limitation. I tested whether such a nitrogen interaction occurred in corn, by growing sweet corn in field plots in open top chambers at ambient and elevated (ambient + 180 mmol·mol-1) carbon dioxide concentrations for four seasons, with six nitrogen application rates, ranging from half to twice the locally recommended rate. At the recommended rate of nitrogen application, no carbon dioxide effect on production occurred. However, both ear and leaf plus stem biomass were lower for the elevated carbon dioxide treatment than for the ambient treatment at less than the recommended rate of nitrogen application, and higher at the highest rates of nitrogen application. There were no significant responses of mid-day leaf gas exchange rates to nitrogen application rate for either carbon dioxide treatment, and elevated carbon dioxide did not significantly increase leaf carbon dioxide assimilation rates at any nitrogen level. Leaf area index during vegetative growth increased more with nitrogen application rate at elevated than at ambient carbon dioxide. It is concluded that elevated carbon dioxide increased the responsiveness of corn growth to nitrogen application by increasing the response of leaf area to nitrogen application rate, and that elevated carbon dioxide increased the amount of nitrogen required to achieve maximum yields.
文摘WNxfilms are deposited by reactive chemical vapor deposition at different amounts of nitrogen in gas mixtures.Experimental data demonstrate that nitrogen amount has a strong effect on microstructure, phase formation,texture morphology, mechanical and optical properties of the WNxfilms. With increasing nitrogen a phase transition from a single WNxphase with low crystallinity structure to a well-mixed crystallized hexagonal WNxand face-centered-cubic W2N phases appears. Relatively smooth morphology at lower N2concentration changes to a really smooth morphology and then granular with coarse surface at higher N2concentration. The SEM observation clearly shows a columnar structure at lower N2concentration and a dense nanoplates one for higher nitrogen content. The hardness of WNxthin films mainly depends on the film microstructure. The absorbance peak position shifts to shorter wavelength continuously with increasing nitrogen amount and decreasing particle size.
基金supported by the Natural Science Fund of China(31771724)the Key Research and Development Project of Shaanxi Province(2024NC-ZDCYL-01-10).
文摘The increase in soil temperature associated with climate change has introduced considerable challenges to crop production.Split nitrogen application(SN)represents a potential strategy for improving crop nitrogen use efficiency and enhancing crop stress resistance.Nevertheless,the precise interaction between soil warming(SW)and SN remains unclear.In order to ascertain the impact of SW on maize growth and whether SN can improve the tolerance of maize to SW,a two-year field experiment was conducted(2022-2023).The aim was to examine the influence of two SW ranges(MT,warming 1.40℃;HT,warming 2.75℃)and two nitrogen application methods(N1,one-time basal application of nitrogen fertilizer;N2,one third of base nitrogen fertilizer+two thirds of jointing stage supplemental nitrogen fertilizer)on maize root growth,photosynthetic characteristics,nitrogen use efficiency,and yield.The results demonstrated that SW impeded root growth and precipitated the premature aging of maize leaves following anthesis,particularly in the HT,which led to a notable reduction in maize yield.In comparison to N1,SN has been shown to increase root length density by 8.54%,root bleeding rate by 8.57%,and enhance root distribution ratio in the middle soil layers(20-60 cm).The interaction between SW and SN had a notable impact on maize growth and yield.The SN improved the absorption and utilization efficiency of nitrogen by promoting root development and downward canopy growth,thus improving the tolerance of maize to SW at the later stage of growth.In particular,the N2HT resulted in a 14.51%increase in the photosynthetic rate,a 18.58%increase in nitrogen absorption efficiency,and a 18.32%increase in maize yield compared with N1HT.It can be posited that the SN represents a viable nitrogen management measure with the potential to enhance maize tolerance to soil high-temperature stress.
基金supported by the National Natural Science Foundation of China(51609247)the Henan Provincial Natural Science Foundation,China(222300420589,202300410553)+4 种基金the Central Public-interest Scientific Institution Basal Research Fund,China(FIRI2022-22)the Science&Technology Fundamental Resources Investigation Program,China(2022FY101601)the Science and Technology Project of Xinxiang City,Henan Province,China(GG2021024)the Major Special Science and Technology Project of Henan Province,China(221100110700)the Joint Fund of Science and Technology Research and Development Plan of Henan Province,China(Superior Discipline Cultivation)(222301420104)。
文摘Nitrogen(N)uptake is regulated by water availability,and a water deficit can limit crop N responses by reducing N uptake and utilization.The complex and multifaceted interplay between water availability and the crop N response makes it difficult to predict and quantify the effect of water deficit on crop N status.The nitrogen nutrition index(NNI)has been widely used to accurately diagnose crop N status and to evaluate the effectiveness of N application.The decline of NNI under water-limiting conditions has been documented,although the underlying mechanism governing this decline is not fully understood.This study aimed to elucidate the reason for the decline of NNI under waterlimiting conditions and to provide insights into the accurate utilization of NNI for assessing crop N status under different water-N interaction treatments.Rainout shelter experiments were conducted over three growing seasons from 2018 to 2021 under different N(75 and 225 kg N ha^(-1),low N and high N)and water(120 to 510 mm,W0 to W3)co-limitation treatments.Plant N accumulation,shoot biomass(SB),plant N concentration(%N),soil nitrate-N content,actual evapotranspiration(ET_a),and yield were recorded at the stem elongation,booting,anthesis and grain filling stages.Compared to W0,W1 to W3 treatments exhibited NNI values that were greater by 10.2 to 20.5%,12.6to 24.8%,14 to 24.8%,and 16.8 to 24.8%at stem elongation,booting,anthesis,and grain filling,respectively,across the 2018-2021 seasons.This decline in NNI under water-limiting conditions stemmed from two main factors.First,reduced ET_(a) and SB led to a greater critical N concentration(%N_(c))under water-limiting conditions,which contributed to the decline in NNI primarily under high N conditions.Second,changes in plant%N played a more significant role under low N conditions.Plant N accumulation exhibited a positive allometric relationship with SB and a negative relationship with soil nitrate-N content under water-limiting conditions,indicating co-regulation by SB and the soil nitrate-N content.However,this regulation was influenced by water availability.Plant N accumulation sourced from the soil nitrate-N content reflects soil N availability.Greater soil water availability facilitated greater absorption of soil nitrate-N into the plants,leading to a positive correlation between plant N accumulation and ET_(a)across the different water-N interaction treatments.Therefore,considering the impact of soil water availability is crucial when assessing soil N availability under water-limiting conditions.The findings of this study provide valuable insights into the factors contributing to the decline in NNI among different water-N interaction treatments and can contribute to the more accurate utilization of NNI for assessing winter wheat N status.
基金supported by the Key Research and Development Program of Shaanxi,China(2021NY-083)the National Natural Science Foundation of China(31871567)。
文摘The trade-off between yield and environmental effects caused by nitrogen fertilizer application is an important issue in wheat production.A reduction in fertile florets is one of the main reasons for the lower yields under low nitrogen application rates.Brassinosteroids(BRs)have been found to play a role in nitrogen-induced rice spikelet degeneration.However,whether BRs play a role in wheat floret development and the mechanisms involved are not clear.Therefore,a nitrogen gradient experiment and exogenous spraying experiment were conducted to investigate the role and mechanism of BRs in wheat floret development under low nitrogen stress.The results showed that as the nitrogen application decreased,the endogenous BRs content of the spikes decreased,photosynthesis weakened,and total carbon,soluble sugar and starch in the spikes decreased,leading to a reduction in the number of fertile florets.Under low nitrogen stress,exogenous spraying of 24-epibrassinolide promoted photosynthesis,and stimulated stem fructan hydrolysis and the utilization and storage of sucrose in spikes,which directed more carbohydrates to the spikes and increased the number of fertile florets.In conclusion,BRs mediate the effects of nitrogen fertilizer on wheat floret development,and under low nitrogen stress,foliar spraying of 24-epibrassinolide promotes the flow of carbohydrates from the stem to the spikes,alleviating wheat floret degeneration.
基金supported by the Key-Area Research and Development Program of Guangdong Province(Grant No.2021B0909060004)the National Natural Science Foundation of China(Grant Nos.12072355 and 92271117)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB0620202).
文摘The thermochemical non-equilibrium phenomena encountered by hypersonic vehicles present significant challenges in their design.To investigate the thermochemical reaction flow behind shock waves,the non-equilibrium radiation in the visible range using a shock tube was studied.Experiments were conducted with a shock velocity of 4.7 km/s,using nitrogen at a pressure of 20 Pa.To address measurement difficulties associated with weak radiation,a special square section shock tube with a side length of 380 mm was utilized.A high-speed camera characterized the shock wave’s morphology,and a spectrograph and a monochromator captured the radiation.The spectra were analyzed,and the numerical spectra were compared with experimental results,showing a close match.Temperature changes behind the shock wave were obtained and compared with numerical predictions.The findings indicate that the vibrational temperatures are overestimated,while the vibrational relaxation time is likely underestimated,due to the oversimplified portrayals of the non-equilibrium relaxation process in the models.Additionally,both experimental and simulated time-resolved profiles of radiation intensity at specific wavelengths were analyzed.The gathered data aims to enhance computational fluid dynamics codes and radiation models,improving their predictive accuracy.
基金financially supported by the National Natural Science Foundation of China(No.21675131)the Volkswagen Foundation(Freigeist Fellowship No.89592)+1 种基金the Natural Science Foundation of Chongqing(No.2020jcyj-zdxmX0003,CSTB2023NSCQ-MSX0924)the National Research Foundation,Singapore,and A*STAR(Agency for Science Technology and Research)under its LCER Phase 2 Programme Hydrogen&Emerging Technologies FI,Directed Hydrogen Programme(Award No.U2305D4003).
文摘Ammonia and nitric acid,versatile industrial feedstocks,and burgeoning clean energy vectors hold immense promise for sustainable development.However,Haber–Bosch and Ostwald processes,which generates carbon dioxide as massive by-product,contribute to greenhouse effects and pose environmental challenges.Thus,the pursuit of nitrogen fixation through carbon–neutral pathways under benign conditions is a frontier of scientific topics,with the harnessing of solar energy emerging as an enticing and viable option.This review delves into the refinement strategies for scale-up mild photocatalytic nitrogen fixation,fields ripe with potential for innovation.The narrative is centered on enhancing the intrinsic capabilities of catalysts to surmount current efficiency barriers.Key focus areas include the in-depth exploration of fundamental mechanisms underpinning photocatalytic procedures,rational element selection,and functional planning,state-of-the-art experimental protocols for understanding photo-fixation processes,valid photocatalytic activity evaluation,and the rational design of catalysts.Furthermore,the review offers a suite of forward-looking recommendations aimed at propelling the advancement of mild nitrogen photo-fixation.It scrutinizes the existing challenges and prospects within this burgeoning domain,aspiring to equip researchers with insightful perspectives that can catalyze the evolution of cutting-edge nitrogen fixation methodologies and steer the development of next-generation photocatalytic systems.
基金supported by Natural Science Foundation of Shandong Province(Nos.ZR2022YQ42,ZR2021JQ15,ZR2021QE011,ZR2021ZD20,2022GJJLJRC-01)Innovative Team Project of Jinan(No.2021GXRC019)the National Natural Science Foundation of China(Nos.52022037,52202366).
文摘In contrast to research on active sites in nanomaterials,lithium tantalate single crystals,known for their exceptional optical properties and long-range ordered lattice structure,present a promising avenue for in-depth exploration of photocatalytic reaction systems with fewer constraints imposed by surface chemistry.Typically,the isotropy of a specific facet provides a perfect support for studying heteroatom doping.Herein,this work delves into the intrinsic catalytic sites for photocatalytic nitrogen fixation in iron-doped lithium tantalate single crystals.The presence of iron not only modifies the electronic structure of lithium tantalate,improving its light absorption capacity,but also functions as an active site for the nitrogen adsorption and activation.The photocatalytic ammonia production rate of the iron-doped lithium tantalate in pure water is maximum 26.95μg cm^(−2)h^(−1),which is three times higher than that of undoped lithium tantalate.The combination of first-principles simulations with in situ characterizations confirms that iron doping promotes the rate-determining step and changes the pathway of hydrogenation to associative alternating.This study provides a new perspective on in-depth investigation of intrinsic catalytic active sites in photocatalysis and other catalytic processes.
基金financially supported by the National Natural Science Foundation of China(Nos.51874236 and 52174207)Shaanxi Science and Technology Innovation Team(No.2022TD02)Henan University of Science and Technology PhD Funded Projects(No.B2025-9)。
文摘To more accurately describe the coal damage and fracture evolution law during liquid nitrogen(LN_(2))fracturing under true triaxial stress,a thermal-hydraulic-mechanical-damage(THMD)coupling model for LN_(2) fracturing coal was developed,considering the coal heterogeneity and thermophysical parameters of nitrogen.The accuracy and applicability of model were verified by comparing with LN_(2) injection pre-cooling and fracturing experimental data.The effects of different pre-cooling times and horizontal stress ratios on coal damage evolution,permeability,temperature distribution,and fracture characteristics were analyzed.The results show that the permeability and damage of the coal increase exponentially,while the temperature decreases exponentially during the fracturing process.As the pre-cooling time increases,the damage range of the coal expands,and the fracture propagation becomes more pronounced.The initiation pressure and rupture pressure decrease and tend to stabilize with longer precooling times.As the horizontal stress ratio increases,fractures preferentially extend along the direction of maximum horizontal principal stress,leading to a significant decrease in both initiation and rupture pressures.At a horizontal stress ratio of 3,the initiation pressure drops by 48.07%,and the rupture pressure decreases by 41.36%.The results provide a theoretical basis for optimizing LN_(2) fracturing techniques and improving coal seam modification.
