针对超(超)临界电站锅炉高温受热面材料蒸汽侧氧化问题,该文开展国产镍基合金C-HRA-1在620~650℃/25 MPa以及C-HRA-2在650℃/25 MPa超临界水环境的氧化实验研究。利用精密电子天平、扫描电子显微镜(scanning electron microscope,SEM)、...针对超(超)临界电站锅炉高温受热面材料蒸汽侧氧化问题,该文开展国产镍基合金C-HRA-1在620~650℃/25 MPa以及C-HRA-2在650℃/25 MPa超临界水环境的氧化实验研究。利用精密电子天平、扫描电子显微镜(scanning electron microscope,SEM)、X射线衍射(X-ray diffraction,XRD)、X射线光电子能谱(X-ray photoelectron spectroscopy,XPS)以及原子力显微镜(atomic force microscope,AFM)等对材料氧化动力学、氧化膜微观形貌以及氧化膜物相组成进行分析。同时,开展600℃/25 MPa超临界水环境氧同位素标记实验,探究镍基合金C-HRA-1在超临界水中的氧化机理。结果可知,C-HRA-1与C-HRA-2氧化后的主要物相为Cr_(2)O_(3)和NiCr_(2)O_(4),NiO、CoO、MoO_(3)以及NiFe_(2)O_(4)也被检测到;合金中阳离子向外扩散导致了氧化膜的生长。国产镍基合金C-HRA-1在超临界水中表现出较高的抗氧化性能。展开更多
The recrystallization behavior of a single crystal nickel-base superalloy was investigated by shot peening and subsequent annealing. Two kinds of recrystallization microstructures, which are intensively dependent on t...The recrystallization behavior of a single crystal nickel-base superalloy was investigated by shot peening and subsequent annealing. Two kinds of recrystallization microstructures, which are intensively dependent on the annealing temperature, are shown in the nickel-base superalloy after shot peening and subsequent annealing. Surface recrystallized grains are obtained when the superalloy is annealed at solution treatment temperature. The nucleation of recrystallization originates from the dendritic core, where rapid dissolution of γ＇ particles occurs. Cellular recrystallization is observed after annealing at lower temperatures. Cellular structures induced by high diffusivity of the moving boundary and more γ＇ particles dissolution led by residual stress are developed from the surface region. Recrystallized kinetics of the shot-peened alloy annealed at 1050°C accords with the Johnson-Mehl-Avrami-Kolmogorov equation. The low Avrami exponent is caused by the inhomogeneous distribution of stored energy, the decreasing of stored energy during recovery, and the strong resistance of boundary migration by γ＇ particles.展开更多
基金supported by the Major State Basic Research and Development Program of China (No.2010CB631206)the National Natural Science Foundation of China (No.50931004)the Foundation of State Key Lab for Advanced Metals and Materials (No.2008zd-07)
文摘The recrystallization behavior of a single crystal nickel-base superalloy was investigated by shot peening and subsequent annealing. Two kinds of recrystallization microstructures, which are intensively dependent on the annealing temperature, are shown in the nickel-base superalloy after shot peening and subsequent annealing. Surface recrystallized grains are obtained when the superalloy is annealed at solution treatment temperature. The nucleation of recrystallization originates from the dendritic core, where rapid dissolution of γ＇ particles occurs. Cellular recrystallization is observed after annealing at lower temperatures. Cellular structures induced by high diffusivity of the moving boundary and more γ＇ particles dissolution led by residual stress are developed from the surface region. Recrystallized kinetics of the shot-peened alloy annealed at 1050°C accords with the Johnson-Mehl-Avrami-Kolmogorov equation. The low Avrami exponent is caused by the inhomogeneous distribution of stored energy, the decreasing of stored energy during recovery, and the strong resistance of boundary migration by γ＇ particles.
