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Primordial hydrogen partitioning at Earth’s core-mantle boundary:Multicomponent effects revealed by machine learning-augmented first-principles simulations 被引量:1
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作者 ZePing Jiang YuYang He ZhiGang Zhang 《Earth and Planetary Physics》 2025年第5期1001-1009,共9页
Hydrogen partitioning between liquid iron alloys and silicate melts governs its distribution and cycling in Earth’s deep interior.Existing models based on simplified Fe-H systems predict strong hydrogen sequestration... Hydrogen partitioning between liquid iron alloys and silicate melts governs its distribution and cycling in Earth’s deep interior.Existing models based on simplified Fe-H systems predict strong hydrogen sequestration into the core.However,these models do not account for the modulating effects of major light elements such as oxygen and silicon in the core during Earth’s primordial differentiation.In this study,we use first-principles molecular dynamics simulations,augmented by machine learning techniques,to quantify hydrogen chemical potentials in quaternary Fe-O-Si-H systems under early core-mantle boundary conditions(135 GPa,5000 K).Our results demonstrate that the presence of 5.2 wt%oxygen and 4.8 wt%silicon reduces the siderophile affinity of hydrogen by 35%,decreasing its alloy-silicate partition coefficient from 18.2(in the case of Fe-H)to 11.8(in the case of Fe-O-Si-H).These findings suggest that previous estimates of the core hydrogen content derived from binary system models require downward revision.Our study underscores the critical role of multicomponent interactions in core formation models and provides first-principles-derived constraints to reconcile Earth’s present-day hydrogen reservoirs with its accretionary history. 展开更多
关键词 partition coefficient HYDROGEN core-mantle differentiation light elements machine learning density functional theory
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INEQUALITIES FOR THE CUBIC PARTITIONS AND CUBIC PARTITION PAIRS
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作者 Chong LI Yi PENG Helen W.J.ZHANG 《Acta Mathematica Scientia》 2025年第2期737-754,共18页
In this paper,we examine the functions a(n)and b(n),which respectively represent the number of cubic partitions and cubic partition pairs.Our work leads to the derivation of asymptotic formulas for both a(n)and b(n).A... In this paper,we examine the functions a(n)and b(n),which respectively represent the number of cubic partitions and cubic partition pairs.Our work leads to the derivation of asymptotic formulas for both a(n)and b(n).Additionally,we establish the upper and lower bounds of these functions,factoring in the explicit error terms involved.Crucially,our findings reveal that a(n)and b(n)both satisfy several inequalities such as log-concavity,third-order Turan inequalities,and strict log-subadditivity. 展开更多
关键词 asymptotic formula LOG-CONCAVITY third-order Turan inequalities cubic partition cubic partition pair
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Highly selective acetylene capture by a pacs‑type metal‑organic framework constructed using metal‑formate complexes as pore partition units
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作者 GUO Hongzhe WANG Sen +3 位作者 YANG Lu LIU Fucheng ZHAO Jiongpeng YAO Zhaoquan 《无机化学学报》 北大核心 2025年第10期2157-2164,共8页
To obtain materials capable of efficiently separating acetylene(C_(2)H_(2))from carbon dioxide(CO_(2))and eth-ylene(C_(2)H_(4)),In this work,based on the pore space partition strategy,a pacs-metal-organic framework(MO... To obtain materials capable of efficiently separating acetylene(C_(2)H_(2))from carbon dioxide(CO_(2))and eth-ylene(C_(2)H_(4)),In this work,based on the pore space partition strategy,a pacs-metal-organic framework(MOF):(NH_(2)Me_(2))_(2)[Fe_(3)(μ_(3)-O)(bdc)_(3)][In(FA)_(3)Cl_(3)](Fe‑FAIn‑bdc)was synthesized successfully by using the metal-formate com-plex[In(FA)_(3)Cl_(3)]^(3-)as the pore partition units,where bdc^(2-)=terephthalate,FA-=formate.Owing to the pore partition effect of this metal-organic building block,fruitful confined spaces are formed in the network of Fe‑FAIn‑bdc,endowing this MOF with superior separation performance of acetylene and carbon dioxide.According to the adsorp-tion test,this MOF exhibited a high adsorption capacity for C_(2)H_(2)(50.79 cm^(3)·g^(-1))at 298 K and 100 kPa,which was much higher than that for CO_(2)(29.99 cm^(3)·g^(-1))and C_(2)H_(4)(30.94 cm^(3)·g^(-1))under the same conditions.Ideal adsorbed solution theory(IAST)calculations demonstrate that the adsorption selectivity of Fe‑FAIn‑bdc for the mixture of C_(2)H_(2)/CO_(2)and C_(2)H_(2)/C_(2)H_(4)in a volume ratio of 50∶50 was 3.08 and 3.65,respectively,which was higher than some reported MOFs such as NUM-11 and SNNU-18.CCDC:_(2)453954. 展开更多
关键词 pore space partition strategy metal-organic framework pore-partition ligands separation of C_(2)H_(2)/CO_(2)
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Efficient prediction of gaseous n-hexane removal in two-phase partitioning bioreactors with silicone oil based on the mechanism and kinetic models
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作者 Lichao Lu Tuo Ju +6 位作者 Yangdan Fang Jingtao Hu Zhuqiu Sun Zhuowei Cheng Qian Li Jianmeng Chen Dong-zhi Chen 《Journal of Environmental Sciences》 2025年第8期729-740,共12页
Two-phase partitioning bioreactors(TPPBs)have been widely used because they overcome the mass-transfer limitation of hydrophobic volatile organic compounds(VOCs)in waste gas biological treatments.Understanding the mec... Two-phase partitioning bioreactors(TPPBs)have been widely used because they overcome the mass-transfer limitation of hydrophobic volatile organic compounds(VOCs)in waste gas biological treatments.Understanding the mechanisms of mass-transfer enhancement in TPPBs would enable efficient predictions for further industrial applications.In this study,influences of gradually increasing silicone oil ratio on the TPPB was explored,and a 94.35%reduction of the n-hexane partition coefficient was observed with 0.1 vol.%silicone,which increased to 80.7%along with a 40-fold removal efficiency enhancement in the stabilised removal period.The elimination capacity increased from 1.47 to 148.35 g/(m^(3)·h),i.e.a 101-fold increase compared with that of the single-phase reactors,when 10 vol.%(3 Critical Micelle Concentration)silicone oil was added.The significantly promoted partition coefficient was the main reason for the mass transfer enhancement,which covered the negative influences of the decreased total mass-transfer coefficient with increasing silicone oil volume ratio.The gradually rising stirring rate was benefit to the n-hexane removal,which became negative when the dominant resistance shifted from mass transfer to biodegradation.Moreover,a mass-transfer-reaction kinetic model of the TPPB was constructed based on the balance of n-hexane concentration,dissolved oxygen and biomass.Similar to the mechanism,the partition factor was predicted sensitive to the removal performance,and another five sensitive parameters were found simultaneously.This forecasting method enables the optimisation of TPPB performance and provides theoretical support for hydrophobic VOCs degradation. 展开更多
关键词 Mass transfer N-HEXANE Two-phase partitioning bioreactors Silicone oil
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LRP:learned robust data partitioning for efficient processing of large dynamic queries
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作者 Pengju LIU Pan CAI +2 位作者 Kai ZHONG Cuiping LI Hong CHEN 《Frontiers of Computer Science》 2025年第9期43-60,共18页
The interconnection between query processing and data partitioning is pivotal for the acceleration of massive data processing during query execution,primarily by minimizing the number of scanned block files.Existing p... The interconnection between query processing and data partitioning is pivotal for the acceleration of massive data processing during query execution,primarily by minimizing the number of scanned block files.Existing partitioning techniques predominantly focus on query accesses on numeric columns for constructing partitions,often overlooking non-numeric columns and thus limiting optimization potential.Additionally,these techniques,despite creating fine-grained partitions from representative queries to enhance system performance,experience from notable performance declines due to unpredictable fluctuations in future queries.To tackle these issues,we introduce LRP,a learned robust partitioning system for dynamic query processing.LRP first proposes a method for data and query encoding that captures comprehensive column access patterns from historical queries.It then employs Multi-Layer Perceptron and Long Short-Term Memory networks to predict shifts in the distribution of historical queries.To create high-quality,robust partitions based on these predictions,LRP adopts a greedy beam search algorithm for optimal partition division and implements a data redundancy mechanism to share frequently accessed data across partitions.Experimental evaluations reveal that LRP yields partitions with more stable performance under incoming queries and significantly surpasses state-of-the-art partitioning methods. 展开更多
关键词 data partitioning data encoding query prediction beam search data redundancy
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Energy partition between entangled fission fragments
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作者 Hao-Yu Shang Yu Qiang Jun-Chen Pei 《Nuclear Science and Techniques》 2025年第11期257-263,共7页
We studied the energy partition between two well-separated fission fragments associated with the partition of nucleons owing to quantum entanglement.This is different from most fission models that invoke an explicit s... We studied the energy partition between two well-separated fission fragments associated with the partition of nucleons owing to quantum entanglement.This is different from most fission models that invoke an explicit statistical partition of excitation energies.The dynamical fission evolution is described within the time-dependent Hartree-Fock+BCS framework.Excitation energies of isotopic fission fragments were obtained using the particle number projection method after the dynamical splitting of^(238)U.The resulting excitation energies of the light and heavy fragments are consistent with the appearance of sawtooth structures.We found that the pairing correlation strengths have a significant influence on the partition of the excitation energies.Furthermore,the excitation energies of isotopic fragments increase with increasing neutron number,implying the suppression of the production of neutron-rich beams in rare-isotope beam facilities. 展开更多
关键词 Nuclear fission Energy partition Time-dependent density functional theory
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A Partitioned Yaw Control Algorithm for Wind Farms Using Dynamic Wake Modeling
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作者 Yinguo Yang Lifu Ding +3 位作者 Yang Liu Bingchen Wang Weihua Wang Ying Chen 《Energy Engineering》 2025年第7期2571-2587,共17页
This paper addresses the complexity of wake control in large-scale wind farms by proposing a partitioning control algorithm utilizing the FLORIDyn(FLOW Redirection and Induction Dynamics)dynamic wake model.First,the i... This paper addresses the complexity of wake control in large-scale wind farms by proposing a partitioning control algorithm utilizing the FLORIDyn(FLOW Redirection and Induction Dynamics)dynamic wake model.First,the impact of wakes on turbine effective wind speed is analyzed,leading to a quantitative method for assessing wake interactions.Based on these interactions,a partitioning method divides the wind farm into smaller,computationally manageable zones.Subsequently,a heuristic control algorithm is developed for yaw optimization within each partition,reducing the overall computational burden associated with multi-turbine optimization.The algorithm’s effectiveness is evaluated through case studies on 11-turbine and 28-turbine wind farms,demonstrating power generation increases of 9.78%and 1.78%,respectively,compared to baseline operation.The primary innovation lies in coupling the higher-fidelity dynamic FLORIDyn wake model with a graph-based partitioning strategy and a computationally efficient heuristic optimization,enabling scalable and accurate yaw control for large wind farms,overcoming limitations associated with simplified models or centralized optimization approaches. 展开更多
关键词 Wind farm wind turbine yaw control wind farm partition distributed optimization
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Novel non-equilibrium partitioning model and a developed strong and ductile Al–7.5Mg–0.5Sc–0.3Zr–0.6Si alloy for selective laser melting
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作者 Jianzhou Long Chi Zhou +7 位作者 Gang Wang Shuai Zhang Mengmeng Wang Yuanpei Duan Qingsong Pan Zesheng You Liang Song Zhourong Feng 《International Journal of Minerals,Metallurgy and Materials》 2025年第7期1669-1680,共12页
Strong and ductile Al alloys and their suitable design strategy have long been desired in selective laser melting(SLM).This work reports a non-equilibrium partitioning model and a correspondingly designed Al–7.5Mg–0... Strong and ductile Al alloys and their suitable design strategy have long been desired in selective laser melting(SLM).This work reports a non-equilibrium partitioning model and a correspondingly designed Al–7.5Mg–0.5Sc–0.3Zr–0.6Si alloy.This model effectively quantifies the influence of Mg and Si on hot cracking in aluminum alloy by considering the non-equilibrium partitioning under high cooling rates in SLM.The designed Al–7.5Mg–0.5Sc–0.3Zr–0.6Si alloy exhibits no hot cracks and achieves a remarkably enhanced strength–ductility synergy(a yield strength of(412±8)MPa and a uniform elongation of(15.6±0.6)%),superior to previously reported Al–Mg–Sc–Zr and Al–Mn alloys.A tensile cracking model is proposed to explore the origin of the improved ductility.Both the non-equilibrium partitioning model and the novel Al–7.5Mg–0.5Sc–0.3Zr–0.6Si alloy offers a promising opportunity for producing highly reliable aluminum parts through SLM. 展开更多
关键词 aluminum alloy mechanical property selective laser melting non-equilibrium partitioning
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An Energy Optimization Algorithm for WRSN Nodes Based on Regional Partitioning and Inter-Layer Routing
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作者 Cui Zhang Lieping Zhang +2 位作者 Huaquan Gan Hongyuan Chen Zhihao Li 《Computers, Materials & Continua》 2025年第8期3125-3148,共24页
In large-scaleWireless Rechargeable SensorNetworks(WRSN),traditional forward routingmechanisms often lead to reduced energy efficiency.To address this issue,this paper proposes a WRSN node energy optimization algorith... In large-scaleWireless Rechargeable SensorNetworks(WRSN),traditional forward routingmechanisms often lead to reduced energy efficiency.To address this issue,this paper proposes a WRSN node energy optimization algorithm based on regional partitioning and inter-layer routing.The algorithm employs a dynamic clustering radius method and the K-means clustering algorithm to dynamically partition the WRSN area.Then,the cluster head nodes in the outermost layer select an appropriate layer from the next relay routing region and designate it as the relay layer for data transmission.Relay nodes are selected layer by layer,starting from the outermost cluster heads.Finally,the inter-layer routing mechanism is integrated with regional partitioning and clustering methods to develop the WRSN energy optimization algorithm.To further optimize the algorithm’s performance,we conduct parameter optimization experiments on the relay routing selection function,cluster head rotation energy threshold,and inter-layer relay structure selection,ensuring the best configurations for energy efficiency and network lifespan.Based on these optimizations,simulation results demonstrate that the proposed algorithm outperforms traditional forward routing,K-CHRA,and K-CLP algorithms in terms of node mortality rate and energy consumption,extending the number of rounds to 50%node death by 11.9%,19.3%,and 8.3%in a 500-node network,respectively. 展开更多
关键词 Wireless rechargeable sensor network regional partitioning inter-layer routing energy optimization
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Microstructure-property correlation and strain partitioning behavior in medium-carbon carbide-free bainitic steel
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作者 Ru Su Xiong-wei Zheng +5 位作者 Jie Kang Da-yong Wu Hai-kun Ma Fu-cheng Zhang Zhi-nan Yang Qing Li 《Journal of Iron and Steel Research International》 2025年第7期2039-2053,共15页
The correlation between the microstructure,properties,and strain partitioning behavior in a medium-carbon carbide-free bainitic steel was investigated through a combination of experiments and representative volume ele... The correlation between the microstructure,properties,and strain partitioning behavior in a medium-carbon carbide-free bainitic steel was investigated through a combination of experiments and representative volume element simulations.The results reveal that as the austempering temperature increases from low to intermediate,the optimal balance of properties shifts from strength-toughness to plasticity-toughness.The formation of fine bainitic ferrite plates and bainite sheaves under low austempering temperature(270℃)enhances both strength and toughness.Conversely,the wide size and shape distribution of the retained austenite(RA)obtained through austempering at intermediate temperature(350℃)contribute to increased work-hardening capacity,resulting in enhanced plasticity.The volume fraction of the ductile film-like RA plays a crucial role in enhancing impact toughness under relatively higher austempering temperatures.In the simulations of tensile deformation,the concentration of equivalent plastic strain predominantly manifests in the bainitic ferrite neighboring the martensite,whereas the equivalent plastic strain evenly spreads between the thin film-like retained austenite and bainitic ferrite.It is predicted that the cracks will occur at the interface between martensite and bainitic ferrite where the strain is concentrated,and eventually propagate along the strain failure zone. 展开更多
关键词 Carbide-free bainitic steel STRENGTH Retained austenite Representative volume element Strain partitioning
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Distributed quantum circuit partitioning and optimization based on combined spectral clustering and search tree strategies
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作者 Zilu Chen Zhijin Guan +1 位作者 Shuxian Zhao Xueyun Cheng 《Chinese Physics B》 2025年第5期237-248,共12页
In the current noisy intermediate-scale quantum(NISQ)era,a single quantum processing unit(QPU)is insufficient to implement large-scale quantum algorithms;this has driven extensive research into distributed quantum com... In the current noisy intermediate-scale quantum(NISQ)era,a single quantum processing unit(QPU)is insufficient to implement large-scale quantum algorithms;this has driven extensive research into distributed quantum computing(DQC).DQC involves the cooperative operation of multiple QPUs but is concurrently challenged by excessive communication complexity.To address this issue,this paper proposes a quantum circuit partitioning method based on spectral clustering.The approach transforms quantum circuits into weighted graphs and,through computation of the Laplacian matrix and clustering techniques,identifies candidate partition schemes that minimize the total weight of the cut.Additionally,a global gate search tree strategy is introduced to meticulously explore opportunities for merged transfer of global gates,thereby minimizing the transmission cost of distributed quantum circuits and selecting the optimal partition scheme from the candidates.Finally,the proposed method is evaluated through various comparative experiments.The experimental results demonstrate that spectral clustering-based partitioning exhibits robust stability and efficiency in runtime in quantum circuits of different scales.In experiments involving the quantum Fourier transform algorithm and Revlib quantum circuits,the transmission cost achieved by the global gate search tree strategy is significantly optimized. 展开更多
关键词 NISQ era distributed quantum computing quantum circuit partitioning transmission cost
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A semi-implicit partition algorithm for fluid-structure coupling problems based on modal force prediction-correction
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作者 Kangdi LI Zili XU +2 位作者 Shizhi ZHAO Lu CHENG Yu FANG 《Chinese Journal of Aeronautics》 2025年第5期275-286,共12页
The implicit partition algorithm used to solve fluid–structure coupling problems has high accuracy,but it requires a long computation time.In this paper,a semi-implicit fluid–structure coupling algorithm based on mo... The implicit partition algorithm used to solve fluid–structure coupling problems has high accuracy,but it requires a long computation time.In this paper,a semi-implicit fluid–structure coupling algorithm based on modal force prediction-correction is proposed to improve the computational efficiency.In the pre-processing stage,the fluid domain is assumed to be a pseudo-elastic solid and merged with the solid domain to form a holistic system,and the normalized modal information of the holistic system is calculated and stored.During the sub-step cycle,the modal superposition method is used to obtain the response of the holistic system with the predicted modal force as the load,so that the deformation of the structure and the updating of the fluid mesh can be achieved simultaneously.After solving the Reynolds-averaged Navier-Stokes equations in the fluid domain,the predicted modal force is corrected and a new sub-step cycle is started until the converged result is obtained.In this method,the computation of the fluid equations and the updating of the dynamic mesh are done implicitly,while the deformation of the structure is done explicitly.Two numerical cases,vortex induced oscillation of an elastic beam and fluid–structure interaction of a final stage blade,are used to verify the efficiency and accuracy of the proposed algorithm.The results show that the proposed method achieves the same accuracy as the implicit method while the computational time is reduced.In the case of the vortex-induced oscillation problem,the computational time can be reduced to 18.6%.In the case of the final stage blade vibration,the computational time can be reduced to 53.8%. 展开更多
关键词 Fluid-structure interaction Fast mesh deformation Semi-implicit partition algorithm Prediction-correction method FLUTTER
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Dynamic partition of urban network considering congestion evolution based on random walk
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作者 Zhen-Tong Feng Lele Zhang +1 位作者 Yong-Hong Wu Mao-Bin Hu 《Chinese Physics B》 2025年第1期530-534,共5页
The successful application of perimeter control of urban traffic system strongly depends on the macroscopic fundamental diagram of the targeted region.Despite intensive studies on the partitioning of urban road networ... The successful application of perimeter control of urban traffic system strongly depends on the macroscopic fundamental diagram of the targeted region.Despite intensive studies on the partitioning of urban road networks,the dynamic partitioning of urban regions reflecting the propagation of congestion remains an open question.This paper proposes to partition the network into homogeneous sub-regions based on random walk algorithm.Starting from selected random walkers,the road network is partitioned from the early morning when congestion emerges.A modified Akaike information criterion is defined to find the optimal number of partitions.Region boundary adjustment algorithms are adopted to optimize the partitioning results to further ensure the correlation of partitions.The traffic data of Melbourne city are used to verify the effectiveness of the proposed partitioning method. 展开更多
关键词 urban road networks dynamic partitioning random walk Akaike information criterion perimeter control
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Dwell scheduling for MFIS with aperture partition and JRC waveform
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作者 CHENG Ting LIU Luqing HENG Siyu 《Journal of Systems Engineering and Electronics》 2025年第4期951-961,共11页
The multifunctional integration system(MFIS)is based on a common hardware platform that controls and regulates the system’s configurable parameters through software to meet dif-ferent operational requirements.Dwell s... The multifunctional integration system(MFIS)is based on a common hardware platform that controls and regulates the system’s configurable parameters through software to meet dif-ferent operational requirements.Dwell scheduling is a key for the system to realize multifunction and maximize the resource uti-lization.In this paper,an adaptive dwell scheduling optimization model for MFIS which considers the aperture partition and joint radar communication(JRC)waveform is established.To solve the formulated optimization problem,JRC scheduling condi-tions are proposed,including time overlapping condition,beam direction condition and aperture condition.Meanwhile,an effec-tive mechanism to dynamically occupy and release the aperture resource is introduced,where the time-pointer will slide to the earliest ending time of all currently scheduled tasks so that the occupied aperture resource can be released timely.Based on them,an adaptive dwell scheduling algorithm for MFIS with aperture partition and JRC waveform is put forward.Simulation results demonstrate that the proposed algorithm has better com-prehensive scheduling performance than up-to-date algorithms in all considered metrics. 展开更多
关键词 multifunctional integration system(MFIS) dwell scheduling aperture partition joint radar communication(JRC).
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Titanium partitioning between pyroxenes and lunar basaltic melts:An experimental perspective
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作者 Huan Gong Jing Yang Wei Du 《Acta Geochimica》 2025年第5期931-944,共14页
The size of basalt fragments in Chang’E-5(CE-5)regolith are small(<6 mm^(2)),resulting in large variation on the estimated bulk composition of CE-5 basalt.For example,the estimated TiO_(2) content of CE-5 basalt r... The size of basalt fragments in Chang’E-5(CE-5)regolith are small(<6 mm^(2)),resulting in large variation on the estimated bulk composition of CE-5 basalt.For example,the estimated TiO_(2) content of CE-5 basalt ranges from 3.7 wt% to 12.7 wt% and the Mg#(molar percentage of Mg/[Mg+Fe])also shows a wide range(26.2-42.4).Preliminary experimental studies have shown that these geochemical characteristics of CE-5 basalt are critical for investigating the crystallization sequence and formation mechanism of its parent magma.This study presents new experimental data on the distribution coefficient of titanium between pyroxene and lunar basaltic magma(D_(Ti)^(Px/melt)).Combining with available literature data,we confirm that D_(Ti)Px/melt is affected by crystallization conditions such as pressure and temperature,but it is mainly controlled by the CaO content of pyroxene.Comparing with previous experimental results under similar conditions,we parameterized the effect as D_(Ti)^(Px/Melt)=D_(Ti)^(Px/Melt)=-0.0005X_(Cao)^(2)+0.0218X_(CaO)+0.0425(R^(2)=0.82),where X_(CaO) is the CaO content in pyroxene in weight percentage.The new experimental results suggest that pyroxene with high TiO_(2) content(>2.5 wt%)in CE-5 basalt is not a product of equilibrium crystallization,and the CaO content in pyroxene is also affected by cooling rate of its parent magma.The TiO_(2) content in the CE-5 parent magma is estimated to be about 5 wt% based on the Mg# of pyroxene and its calculated CaO content,which is consistent with those estimated from olivine grains. 展开更多
关键词 Lunar basalt Chang’E-5 High pressure and high temperature experiments partitioning coefficient
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Laparoscopic associating liver partition and portal vein ligation for staged hepatectomy for colorectal liver metastases:A single-center experience
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作者 Zhe-Yu Zheng Lei Zhang +5 位作者 Wen-Li Li Shu-Yi Dong Jing-Lin Song Da-Wei Zhang Xiao-Ming Huang Wei-Dong Pan 《World Journal of Gastroenterology》 2025年第18期19-31,共13页
BACKGROUND Associating liver partition and portal vein ligation for staged hepatectomy(ALPPS)is a procedure used for patients with initially unresectable colorectal liver metastases(CRLM).However,the procedure has bee... BACKGROUND Associating liver partition and portal vein ligation for staged hepatectomy(ALPPS)is a procedure used for patients with initially unresectable colorectal liver metastases(CRLM).However,the procedure has been reported to be associated with high morbidity and mortality.Laparoscopic ALPPS has recently been reported as a minimally invasive technique that reduces perioperative risks.AIM To assess the safety and feasibility of full laparoscopic ALPPS in patients with CRLM.METHODS A retrospective analysis was conducted on all consecutive patients with CRLM who underwent full laparoscopic ALPPS at the Sixth Affiliated Hospital of Sun Yat-sen University between March 2021 and July 2024.RESULTS Fifteen patients were included,13 with synchronous liver metastases.Nine patients had more than five liver tumors,with the highest count being 22.The median diameter of the largest lesion was 2.8 cm on preoperative imaging.No extrahepatic metastases were observed.RAS mutations were detected in nine patients,and 14 underwent preoperative chemotherapy.The median increase in future liver remnant volume during the interstage interval was 47.0%.All patients underwent R0 resection.Overall complication rates were 13.3%(stage 1)and 53.3%(stage 2),while major complication rates(Clavien-Dindo≥IIIa)were 13.3%(stage 1)and 33.3%(stage 2).No mortality occurred in either stage.The median hospital stay after stage 2 was 10 days.CONCLUSION Full laparoscopic ALPPS for CRLM is safe and feasible,with the potential for reduced morbidity and mortality,offering radical resection opportunities for patients with initially unresectable CRLM. 展开更多
关键词 Minimally invasive surgery Laparoscopic surgery Associating liver partition and portal vein ligation for staged hepatectomy Colorectal liver metastases Future liver remnant
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Enhanced C_(2)H_(2)/CO_(2) separation in tetranuclear Cu(Ⅱ)cluster-based metal-organic frameworks by adjusting divider length of pore space partition
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作者 Fahui Xiang Lu Li +9 位作者 Zhen Yuan Wuji Wei Xiaoqing Zheng Shimin Chen Yisi Yang Liangji Chen Zizhu Yao Jianwei Fu Zhangjing Zhang Shengchang Xiang 《Chinese Chemical Letters》 2025年第3期550-554,共5页
Achieving efficient adsorption and separation of C_(2)H_(2)/CO_(2)mixtures is a goal that people have always pursued to improve the situation of high energy consumption brought by traditional separation technologies i... Achieving efficient adsorption and separation of C_(2)H_(2)/CO_(2)mixtures is a goal that people have always pursued to improve the situation of high energy consumption brought by traditional separation technologies in industry today.High-nuclearity metal cluster-based MOFs with different functionalities are promising for this separation,but it is a complicated and difficult task to precisely control their structures.The strategy of pore-space partition(PSP)is a powerful way to construct this type MOFs,which has the characteristic of isostructural relationship,and can be resulted in a similar performance for them.Therefore,it is an interesting work to explore the effect of MOFs property by adjusting the size of PSP dividers.Herein,three tetranuclear Cu(Ⅱ)cluster-based MOFs(FJU-112/113/114)with dual functionalities has been successfully obtained by PSP strategy with various lengths of divider units.With the highest microporosity and unique functional site,FJU-114 realized a good improvement in the adsorption and separation performance of C_(2)H_(2)/CO_(2).The gas adsorption and lab-scale C_(2)H_(2)/CO_(2)breakthrough experiments demonstrated that FJU-114 exhibits the highest adsorption uptake of 77 cm^(3)/g for C_(2)H_(2),and shows the best separation factor of 4.2 among three MOFs.The GCMC simulation reveals that a stronger adsorption binding site of C_(2)H_(2)in FJU-114a located in the cage II near the unchanged tetranuclear copper node,combined with its high microporosity to achieve the effect of dual functionalities for the improvement performance of C_(2)H_(2)adsorption and separation. 展开更多
关键词 Metal-organic frameworks Dual functionalities Pore space partition C_(2)H_(2)/CO_(2) separation Divider length adjustment
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Symplectic partitioned Runge-Kutta method based onthe eighth-order nearly analytic discrete operator and its wavefield simulations 被引量:3
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作者 张朝元 马啸 +1 位作者 杨磊 宋国杰 《Applied Geophysics》 SCIE CSCD 2014年第1期89-106,117,118,共20页
We propose a symplectic partitioned Runge-Kutta (SPRK) method with eighth-order spatial accuracy based on the extended Hamiltonian system of the acoustic waveequation. Known as the eighth-order NSPRK method, this te... We propose a symplectic partitioned Runge-Kutta (SPRK) method with eighth-order spatial accuracy based on the extended Hamiltonian system of the acoustic waveequation. Known as the eighth-order NSPRK method, this technique uses an eighth-orderaccurate nearly analytic discrete (NAD) operator to discretize high-order spatial differentialoperators and employs a second-order SPRK method to discretize temporal derivatives.The stability criteria and numerical dispersion relations of the eighth-order NSPRK methodare given by a semi-analytical method and are tested by numerical experiments. We alsoshow the differences of the numerical dispersions between the eighth-order NSPRK methodand conventional numerical methods such as the fourth-order NSPRK method, the eighth-order Lax-Wendroff correction (LWC) method and the eighth-order staggered-grid (SG)method. The result shows that the ability of the eighth-order NSPRK method to suppress thenumerical dispersion is obviously superior to that of the conventional numerical methods. Inthe same computational environment, to eliminate visible numerical dispersions, the eighth-order NSPRK is approximately 2.5 times faster than the fourth-order NSPRK and 3.4 timesfaster than the fourth-order SPRK, and the memory requirement is only approximately47.17% of the fourth-order NSPRK method and 49.41% of the fourth-order SPRK method,which indicates the highest computational efficiency. Modeling examples for the two-layermodels such as the heterogeneous and Marmousi models show that the wavefields generatedby the eighth-order NSPRK method are very clear with no visible numerical dispersion.These numerical experiments illustrate that the eighth-order NSPRK method can effectivelysuppress numerical dispersion when coarse grids are adopted. Therefore, this methodcan greatly decrease computer memory requirement and accelerate the forward modelingproductivity. In general, the eighth-order NSPRK method has tremendous potential value forseismic exploration and seismology research. 展开更多
关键词 SYMPLECTIC partitioned RUNGE-KUTTA method NEARLY ANALYTIC DISCRETE OPERATOR Numerical dispersion Wavefield simulation
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Fruit Photosynthesis and Assimilate Translocation and Partitioning: Their Characteristics and Role in Sugar Accumulation in Developing Citrus unshiu Fruit 被引量:12
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作者 陈俊伟 张上隆 +2 位作者 张良诚 赵智中 徐建国 《Acta Botanica Sinica》 CSCD 2002年第2期158-163,共6页
Dynamics of dry- or fresh-weight of fruit, peel photosynthetic rate and chlorophyll content, and the characteristics of translocation and distribution of radiolabelled assimilates from leaf or fruit were examined in d... Dynamics of dry- or fresh-weight of fruit, peel photosynthetic rate and chlorophyll content, and the characteristics of translocation and distribution of radiolabelled assimilates from leaf or fruit were examined in developing satsuma mandarin (Citrus unshiu Marc. cv. Miyagawa wase) fruit from primary stage of fruit enlargement up to fruit full ripe. Change in fruit photosynthetic rate was some what related to the change in the chlorophyll content of peel. Fruit photosynthetic rate markedly declined as chlorophyll degradation occurred in the peel. Before full ripe stage of the fruit, photosynthates produced by a 14C-fed leaf were mainly distributed to juice sacs even during periods when dry matter accumulation in peel was more rapid than that in juice sacs. At the full ripe stage, peel photosynthetic rate approached zero and peel became the major sink of leaf photosynthates. Most of the peel assimilates, however, remained in situ for up to 48 h after feeding 14CO 2 to the fruit, only a small portion being transported to other parts of fruit. The percentage of fruit photosynthates exported decreased with fruit development and ripening, but the peak rate of export to juice sacs amount to as high as 12%. The sugar content and dry weights of peel and juice sacs in shaded fruit were lower than that in the control fruit. These results show that peel assimilate was mainly consumed in peel respiration and growth and thus the dependence on leaf photosynthates decreased. Part of this assimiate was used in sugar accumulation in juice sacs of fruit. 展开更多
关键词 satsuma mandarin fruit photosynthesis PHOTOSYNTHATE TRANSLOCATION partitioning sugar accumulation
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A Reduced-Order Modeling of Multi-Port RC Networks by Means of Graph Partitioning 被引量:1
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作者 杨华中 冒小建 +1 位作者 燕昭然 汪蕙 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2002年第10期1037-1040,共4页
A modified reduced-order method for RC networks which takes a division-and-conquest strategy is presented.The whole network is partitioned into a set of sub-networks at first,then each of them is reduced by Krylov sub... A modified reduced-order method for RC networks which takes a division-and-conquest strategy is presented.The whole network is partitioned into a set of sub-networks at first,then each of them is reduced by Krylov subspace techniques,and finally all the reduced sub-networks are incorporated together.With some accuracy,this method can reduce the number of both nodes and components of the circuit comparing to the traditional methods which usually only offer a reduced net with less nodes.This can markedly accelerate the sparse-matrix-based simulators whose performance is dominated by the entity of the matrix or the number of components of the circuits. 展开更多
关键词 INTERCONNECT reduced-order modeling graph partitioning Krylov subspace
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