Spontaneous vesicles from the mixed aqueous solution of poly-tailed cationic surfactant PTA and anionic surfactant AOT are firstly obtained. Vesicle formation and characterizations are demonstrated by negative-staini...Spontaneous vesicles from the mixed aqueous solution of poly-tailed cationic surfactant PTA and anionic surfactant AOT are firstly obtained. Vesicle formation and characterizations are demonstrated by negative-staining TEM and dynamic light scattering. A monodisperse vesicle system is obtained with a polydispersity of 0.082. Ultrasonication can promote the vesicle formation. Mechanism of vesicle formation is discussed from the viewpoint of molecular interaction.展开更多
The spontaneous formation of vesicles in the aqueous of cationic surfactant phosphate (PTA) and anionic surfactant sodium dodecyl sulfate (SDS) at certain mixing ratios have obtained1. The addition of urea or NaI will...The spontaneous formation of vesicles in the aqueous of cationic surfactant phosphate (PTA) and anionic surfactant sodium dodecyl sulfate (SDS) at certain mixing ratios have obtained1. The addition of urea or NaI will expand the range of spontaneous vesicle formation. The fact is demonstrated by negative-staining transmission electron microscope(TEM) and dynamic light scattering(DLS) methods. The phenomenon especially in the part of urea is reported by us at first. Mechanism of urea/NaI–induced vesicles formation is discussed from the viewpoint of the molecular geometry packing parameter f, conformation and interaction.展开更多
基金The work was supported by the Natural Science Foundation of China (No. 29903006 29973023).
文摘Spontaneous vesicles from the mixed aqueous solution of poly-tailed cationic surfactant PTA and anionic surfactant AOT are firstly obtained. Vesicle formation and characterizations are demonstrated by negative-staining TEM and dynamic light scattering. A monodisperse vesicle system is obtained with a polydispersity of 0.082. Ultrasonication can promote the vesicle formation. Mechanism of vesicle formation is discussed from the viewpoint of molecular interaction.
基金This work supported by the National Natural Science Foundation of China(No.30370945)Ministry of Science and Technology(G 2000078104,2003CCA02900)+2 种基金Guizhou Provincial Govemor Foundation(No.6,2001)Guizhou Education Department(No.206,2003)Guizhou Normal University Young Teachers Development Scientific Research Found.
文摘The spontaneous formation of vesicles in the aqueous of cationic surfactant phosphate (PTA) and anionic surfactant sodium dodecyl sulfate (SDS) at certain mixing ratios have obtained1. The addition of urea or NaI will expand the range of spontaneous vesicle formation. The fact is demonstrated by negative-staining transmission electron microscope(TEM) and dynamic light scattering(DLS) methods. The phenomenon especially in the part of urea is reported by us at first. Mechanism of urea/NaI–induced vesicles formation is discussed from the viewpoint of the molecular geometry packing parameter f, conformation and interaction.
