Soil structure and nutrient ingredient before and after shattering and returning sugarcane leaf as well as its technologies and methods were comparatively analyzed in this study to discuss the main reasons primarily,w...Soil structure and nutrient ingredient before and after shattering and returning sugarcane leaf as well as its technologies and methods were comparatively analyzed in this study to discuss the main reasons primarily,while the controlling technologies were proposed by combining cultivation,management and technical measures.展开更多
Four mineral admixture concrete specimens werefabricated to study the negative effect improvements ofaccelerated curing on the chloride penetration resistance ofordinary concrete. After reaching different initial stre...Four mineral admixture concrete specimens werefabricated to study the negative effect improvements ofaccelerated curing on the chloride penetration resistance ofordinary concrete. After reaching different initial strengths, the specimens were placed in 40, 60, or 80 t water tanks foraccelerated curing. The Coulomb values of the specimens weemeasured with ASTM C1202 experiment at 28, 100, 200, ad300 d. Partial specimens were also selected for rapid chlorideion migration coefficient and mercury intrusion porosimetryexperiments. The experimental results show that theaccelerated curing for ordinary concrete linealy deterioratesthe chloride penetration resistance, whereas the incorporationof mineral admixtures improves the concrete microscopic pore-structures and negative effects. An upper temperature limit of60 t of the accelerated curing is suitable for obtainingsuperior chloride penetration resistance for the mineraladmixture concrete. Pre-curing at a normal temperature of 20t is beneficial for improving the negative effect, which isalso aieviated with increasing testing age as a result of thesuccessive hydration of binder materials in concrete.展开更多
This paper summarizes the negative effects on geological environment caused by groundwater exploitation and its distribution. There are seven main types of the geological environment negative effects, which are genera...This paper summarizes the negative effects on geological environment caused by groundwater exploitation and its distribution. There are seven main types of the geological environment negative effects, which are generally as follows:(1) Constant decrease of groundwater level is mainly distributed in China(East Asia), India(South Asia), Tajikistan(Central Asia) and Saudi Arabia(West Asia);(2) land subsidence occurs mainly in eastern plains of East Asia and west Siberian Plain of North Asia;(3) seawater intrusion occurs mainly in China, Japan and South Korea in East Asia, Philippines and Indonesia in Southeast Asia, the Indian coastal areas in South Asia;(4) groundwater level decline caused by groundwater exploitation in oil fields;(5) mining collapse is mainly in 50° to 70° north latitude band;(6) the total area of karst collapse in China of East Asia is as much as 197.05 km^2; and(7) ground fracture is mainly distributed in the North China Plain, Fenwei Plain and the Yangtze River Delta. Asia can be divided into 6 zones in terms of the geological environment negative effect caused by groundwater exploitation. According to analysis, with the increasing intensity of human activities, geological environment issues become more and more serious, therefore it is vital to control the human activities within the scope of 5× 10~5 people/km^2 to 9.9× 10~5 people/km^2 for the effective control of the size of the affected area by geological environment problems.展开更多
Artificial nest boxes are placed to attract birds to nest and breed in a specific location,and they are widely used in avian ecology research and in the attraction of insectivorous birds.There is evidence that artific...Artificial nest boxes are placed to attract birds to nest and breed in a specific location,and they are widely used in avian ecology research and in the attraction of insectivorous birds.There is evidence that artificial nest boxes can adversely affect breeding fitness but no great focus has been placed on this issue by researchers.Therefore,we retrieved 321 research papers regarding artificial nest boxes published from 2003 to 2022 and used the'Biblioshiny'program to extract and integrate keywords;we then summarized the adverse effects of artificial nest boxes on avian breeding success.The studies highlighted many drawbacks and misuses in the designing and placement of nest boxes;furthermore,bird attraction was decreased by their inappropriate selection,thus reducing breeding success.Regarding nest box production,there were shortcomings in the construction material,color,smell,and structural design of the boxes used.Nest boxes were also placed at inappropriate densities,locations,orientations,heights,and managed incorrectly.Finally,we propose suggestions for more efficient and safer artificial nest boxes for future use in avian ecology research and bird conservation.展开更多
This paper attempts to investigate the negative effects of the spread of COVID-19 on low-income families in Egypt.Coronavirus spread is measured by"Coronavirus cases"and"Coronavirus deaths"on a dai...This paper attempts to investigate the negative effects of the spread of COVID-19 on low-income families in Egypt.Coronavirus spread is measured by"Coronavirus cases"and"Coronavirus deaths"on a daily basis.Besides,it is measured by both"new Coronavirus cases"and"new deaths from Coronavirus",in relation to the population of Egypt.The Egyptian government is taking some measures to reduce the negative effects of COVID-19,including increasing personal exemptions by amending some provisions of the Egyptian Income Tax Law promulgated by Law No.91 of 2005 to protect low-income families.Of the negative effects of COVID-19,it is one of the most important tax policies to achieve social justice in distributing the tax burden,according to income levels,in a manner that achieves justice and equality.We find that Personal exemptions did not succeed in achieving tax justice by easing the tax burden on the low-income people in society.展开更多
The present paper discusses three major sources of negative effect of classroom instruction on L2 learners'pragmatic development:inadequate or inappropriate metapragmatic input,non-authentic classroom discourse an...The present paper discusses three major sources of negative effect of classroom instruction on L2 learners'pragmatic development:inadequate or inappropriate metapragmatic input,non-authentic classroom discourse and grammar-oriented pedagogy,then proposes some pedagogical suggestions on developing pragmatic competence.展开更多
With the development of computer and network technologies, computer--assisted language teaching and learning have been changing from the presentation of single text materials and response model to the integration of o...With the development of computer and network technologies, computer--assisted language teaching and learning have been changing from the presentation of single text materials and response model to the integration of outside classroom education media combining text, graphics, images, sound, animation and network communication （CMC） technology. As an auxiliary tool of foreign language teaching, the computer plays its huge potential and promotes the completion of all kinds of language learning tasks. However, high cost and lack of technical support bringing the negative effects to the foreign language teaching is also cannot be ignored. Therefore, in the study of the historical evolvement of the CALL, to fully understand the positive and negative effects from the foreign language teaching will help make the positive effect of foreign language teaching maximized, and avoid misuse and abuse of the CALL.展开更多
In such an information age, multimedia teaching has changed into one of the most important educational ways in middle and primary schools. In contrast to traditional education, multimedia teaching owns numerous advant...In such an information age, multimedia teaching has changed into one of the most important educational ways in middle and primary schools. In contrast to traditional education, multimedia teaching owns numerous advantages. However, there are also a great number of shortcomings in it. In this paper, considering the current situation of education in middle and primary schools, the author carries out an analysis on the negative effects of multimedia teaching on education in middle and primary schools, and also proposes some personal suggestions, hopefully providing a reference for teaching personnel in middle and primary schools.展开更多
The electronic and transport characteristics of protonated derivatives of naphthalocyanine(Nc)were investigated using density functional theory and non-equilibrium Green's functions.The results indicate that the p...The electronic and transport characteristics of protonated derivatives of naphthalocyanine(Nc)were investigated using density functional theory and non-equilibrium Green's functions.The results indicate that the protonation of external meso-N atoms of Nc preserves its planar structure and is energetically more favorable than the protonation of internal isoindole-N atoms.The protonation shifts the energy levels of system's frontier molecular orbitals closer to the Fermi level,thus creating channels for electron transport.In contrast with the semiconductor transport properties of H2Nc,its protonation products respond more sensitively to bias and exhibit negative differential resistance phenomena at specific bias.展开更多
deployment of the THAAD system in South Korea imposed by the United States is superficially and nominally to target at the DPRK's nuclear and missile threats,but essentially to respond to the rising China and Russ...deployment of the THAAD system in South Korea imposed by the United States is superficially and nominally to target at the DPRK's nuclear and missile threats,but essentially to respond to the rising China and Russia,is further tied South Korea to the U.S.war chariot and is a dose of poison undermining the Northeast Asian environment for the mutual benefit,mutual trust and win-win cooperation as well as development and stability.展开更多
The so-called 'negative difference effect'(NDE) was often defined by the increasing rate of hydrogen evolution from magnesium(Mg) surface under anodic polarization.In this work,a series of electrochemical test...The so-called 'negative difference effect'(NDE) was often defined by the increasing rate of hydrogen evolution from magnesium(Mg) surface under anodic polarization.In this work,a series of electrochemical tests and microstructure observations were performed to provide an evidence that the NDE of Mg-Li alloys can be retarded by increasing lithium content.Potentiostatic,galvanostatic and potentiodynamic polarization experiments using Mg-xLi(x=4,7.5 and 14 wt%) alloys electrodes indicated that Mg-4 Li alloy maintained the enhancing NDE prior to anodic dissolution as that of conventional Mg alloys.However,the emergence of β-Li phase weakened the NDE of duplex Mg-7.5 Li alloy at a low anodic current density,but it was still enhanced apparently after a high applied anodic value(more than 2 mA/cm^2).The surface observations,including the plane and cross-sectional morphologies,confirmed that the cracked surface film derived from the anodic dissolution resulted in the catalytic activity of NDE for Mg-4 Li and Mg-7.5 Li alloys.Furthermore,the NDE of Mg-14 Li alloy was suppressed obviously after a prior applied anodic polarization,which was attributed to the persistent and integrated surface film which endured a higher level of applied anodic potential and current.展开更多
Efficient photogenerated carrier migration/separation plays a critical role in increasing the photocatalytic performance of g-C_(3)N_(4).Herein,sulfonic acid group-functionalized g-C_(3)N_(4)(SACN)was synthesized and ...Efficient photogenerated carrier migration/separation plays a critical role in increasing the photocatalytic performance of g-C_(3)N_(4).Herein,sulfonic acid group-functionalized g-C_(3)N_(4)(SACN)was synthesized and then synchronously strengthened by a facile-solid-state thermal reaction of g-C_(3)N_(4)and sulfamic acid.As a solid strong acid,sulfamic acid can be used to achieve acid etching on the surface of g-C_(3)N_(4)with the assistance of thermal treatment,leading to an enlarged specific surface area and increased surface catalytic reaction sites.More importantly,our experiments and density functional theory calculations indicate that the driving force generated by the negative inductive effect of sulfonic acid groups significantly improves the charge transfer dynamics and effectively inhibits their recombination.Moreover,the negative inductive effect can induce charge redistribution,which reduces the conduction band potential of g-C_(3)N_(4)to enhance the reduction ability of photo-induced electrons.As a result,the SACN-400 sample showed excellent photocatalytic performance in H2 generation with an apparent quantum efficiency of 11.03%at 420±15 nm,as well as an efficient photodegradation rate for organic pollutants.展开更多
The anti-resonant phenomenon of effective electromagnetic parameters of metamaterials has aroused controversy due to negative imaginary permittivity or permeability. It is experimentally found that the negative imagin...The anti-resonant phenomenon of effective electromagnetic parameters of metamaterials has aroused controversy due to negative imaginary permittivity or permeability. It is experimentally found that the negative imaginary permittivity can occur for the natural passive materials near the Fabry Perot resonances. We reveal the nature of negative imaginary permittivity, which is correlated with the magnetoelectric coupling. The anti-resonance of permittivity is a non-inherent feature for passive materials, while it can be inherent for devices or metamaterials. Our finding validates that the negative imaginary part of effective permittivity does not contradict the second law of thermodynamics for metamaterials owing to the magnetoelectric coupling.展开更多
抓挠“痒痒包”到底是好是坏?这个看似简单的动作背后竟有科学奥秘!Don’t scratch that mosquito(蚊子)bite!Maybe you’ve heard this advice before-and found it hard to follow.So you may already know that scratching can feel ...抓挠“痒痒包”到底是好是坏?这个看似简单的动作背后竟有科学奥秘!Don’t scratch that mosquito(蚊子)bite!Maybe you’ve heard this advice before-and found it hard to follow.So you may already know that scratching can feel good at the time,but may not help in the long run.A study in mice finds that scratching can have both positive and negative effects.展开更多
As one of the most distinguished features of Chinese Culture,collective oriented culture is the deep structure of Chinese cultural psychology which has shaped Chinese character and influenced their behavior.As a resul...As one of the most distinguished features of Chinese Culture,collective oriented culture is the deep structure of Chinese cultural psychology which has shaped Chinese character and influenced their behavior.As a result of it,Chinese students suffer this negative effect from collective orientated culture when acquiring English,especially in oral English acquisition.TEFL teachers should be aware of cultural psychology and try their best to minimize its negative effect instead of neglecting or even enlarging it during oral English teaching.展开更多
Adsorption behaviors of phenol from aqueous solutions have been investigated in batch systems at 303 K and 318 K respectively, using hypercrosslinked polymeric adsorbent （CHA111）, aminated hypercrosslinked polymeric...Adsorption behaviors of phenol from aqueous solutions have been investigated in batch systems at 303 K and 318 K respectively, using hypercrosslinked polymeric adsorbent （CHA111）, aminated hypercrosslinked polymeric adsorbents （NDA101, NDA103, NDA105） and weakly basic polymeric adsorbent （D301） with a view to studying the effect of hydrogen bonding and Van der Waals interactions between adsorbate and the adsorbent. All adsorption isotherms can be well fitted by Langmuir and Freundlich equations. Compared with D301 driven by hydrogen bonding interaction only and CHA111 driven by Van der Waals interaction only, phenol adsorption on aminated adsorbents driven by both hydrogen bonding and Van der Waals interactions were apparently different, i.e., negative effect for NDA105, positive effect for NDA101 and synergistic effect for NDA103. In this synergistic action, some weak interactions would contribute more or less to the adsorption than they work individually.展开更多
The oxidation of p-xylene to terephthalic acid with molecular oxygen in acetic acids modified carbon dioxide over Co/Mn/Br catalyst was studied in a batch reactor. The results showed that the oxidation of p-xylene to ...The oxidation of p-xylene to terephthalic acid with molecular oxygen in acetic acids modified carbon dioxide over Co/Mn/Br catalyst was studied in a batch reactor. The results showed that the oxidation of p-xylene to terephthalic acid was severely inhibited when carbon dioxide exceeded a certain amount, the conversion of p-xylene decreased rapidly from 100.0% to 3.3% and the yield of terephthalic acid dropped from 42.6% to trace. Whereas the oxidation processes of p-Tolualdchyde to p-Toluic acid and 4-Carboxybenzaldehyde to tcrcphthalic acid were improved when a relative small amount of CO2 v/as added, Further investigation found that this negative effect may be caused by multiphase reactions emerging.展开更多
Tunneling field effect transistors（TFETs） based on two-dimensional materials are promising contenders to the traditional metal oxide semiconductor field effect transistor, mainly due to potential applications in low...Tunneling field effect transistors（TFETs） based on two-dimensional materials are promising contenders to the traditional metal oxide semiconductor field effect transistor, mainly due to potential applications in low power devices. Here,we investigate the TFETs based on two different integration types： in-plane and vertical heterostructures composed of two kinds of layered phosphorous（β-P and δ-P） by ab initio quantum transport simulations. NDR effects have been observed in both in-plane and vertical heterostructures, and the effects become significant with the highest peak-to-valley ratio（PVR）when the intrinsic region length is near zero. Compared with the in-plane TFET based on β-P and δ-P, better performance with a higher on/off current ratio of - 10-6 and a steeper subthreshold swing（SS） of - 23 mV/dec is achieved in the vertical TFET. Such differences in the NDR effects, on/off current ratio and SS are attributed to the distinct interaction nature of theβ-P and δ-P layers in the in-plane and vertical heterostructures.展开更多
基金Supported by Agricultural Science and Technology Stride Plan(2009-16)Natural Science Fund in Hainan(808202)Scienceand Technology Project from Chinese Academy of Tropical Agricultural Sciences(Rky09)~~
文摘Soil structure and nutrient ingredient before and after shattering and returning sugarcane leaf as well as its technologies and methods were comparatively analyzed in this study to discuss the main reasons primarily,while the controlling technologies were proposed by combining cultivation,management and technical measures.
基金The National Natural Science Foundation of China(No.51178455)the Transformation Program of Science and Technology Achievements of Jiangsu Province(No.BA2015133)
文摘Four mineral admixture concrete specimens werefabricated to study the negative effect improvements ofaccelerated curing on the chloride penetration resistance ofordinary concrete. After reaching different initial strengths, the specimens were placed in 40, 60, or 80 t water tanks foraccelerated curing. The Coulomb values of the specimens weemeasured with ASTM C1202 experiment at 28, 100, 200, ad300 d. Partial specimens were also selected for rapid chlorideion migration coefficient and mercury intrusion porosimetryexperiments. The experimental results show that theaccelerated curing for ordinary concrete linealy deterioratesthe chloride penetration resistance, whereas the incorporationof mineral admixtures improves the concrete microscopic pore-structures and negative effects. An upper temperature limit of60 t of the accelerated curing is suitable for obtainingsuperior chloride penetration resistance for the mineraladmixture concrete. Pre-curing at a normal temperature of 20t is beneficial for improving the negative effect, which isalso aieviated with increasing testing age as a result of thesuccessive hydration of binder materials in concrete.
基金supported by Geological Map of Groundwater Resources and Environment of China and Surrounding Areas(12120113014200)Series Maps of Karst Environment Geology of China and South East Asia(12120114006401,12120114006301)
文摘This paper summarizes the negative effects on geological environment caused by groundwater exploitation and its distribution. There are seven main types of the geological environment negative effects, which are generally as follows:(1) Constant decrease of groundwater level is mainly distributed in China(East Asia), India(South Asia), Tajikistan(Central Asia) and Saudi Arabia(West Asia);(2) land subsidence occurs mainly in eastern plains of East Asia and west Siberian Plain of North Asia;(3) seawater intrusion occurs mainly in China, Japan and South Korea in East Asia, Philippines and Indonesia in Southeast Asia, the Indian coastal areas in South Asia;(4) groundwater level decline caused by groundwater exploitation in oil fields;(5) mining collapse is mainly in 50° to 70° north latitude band;(6) the total area of karst collapse in China of East Asia is as much as 197.05 km^2; and(7) ground fracture is mainly distributed in the North China Plain, Fenwei Plain and the Yangtze River Delta. Asia can be divided into 6 zones in terms of the geological environment negative effect caused by groundwater exploitation. According to analysis, with the increasing intensity of human activities, geological environment issues become more and more serious, therefore it is vital to control the human activities within the scope of 5× 10~5 people/km^2 to 9.9× 10~5 people/km^2 for the effective control of the size of the affected area by geological environment problems.
基金supported by the National Natural Science Foundation of China(Grant No.32170485,31501867)the Fundamental Research Funds for the Central Universities(Grant No.2572022BE02)。
文摘Artificial nest boxes are placed to attract birds to nest and breed in a specific location,and they are widely used in avian ecology research and in the attraction of insectivorous birds.There is evidence that artificial nest boxes can adversely affect breeding fitness but no great focus has been placed on this issue by researchers.Therefore,we retrieved 321 research papers regarding artificial nest boxes published from 2003 to 2022 and used the'Biblioshiny'program to extract and integrate keywords;we then summarized the adverse effects of artificial nest boxes on avian breeding success.The studies highlighted many drawbacks and misuses in the designing and placement of nest boxes;furthermore,bird attraction was decreased by their inappropriate selection,thus reducing breeding success.Regarding nest box production,there were shortcomings in the construction material,color,smell,and structural design of the boxes used.Nest boxes were also placed at inappropriate densities,locations,orientations,heights,and managed incorrectly.Finally,we propose suggestions for more efficient and safer artificial nest boxes for future use in avian ecology research and bird conservation.
文摘This paper attempts to investigate the negative effects of the spread of COVID-19 on low-income families in Egypt.Coronavirus spread is measured by"Coronavirus cases"and"Coronavirus deaths"on a daily basis.Besides,it is measured by both"new Coronavirus cases"and"new deaths from Coronavirus",in relation to the population of Egypt.The Egyptian government is taking some measures to reduce the negative effects of COVID-19,including increasing personal exemptions by amending some provisions of the Egyptian Income Tax Law promulgated by Law No.91 of 2005 to protect low-income families.Of the negative effects of COVID-19,it is one of the most important tax policies to achieve social justice in distributing the tax burden,according to income levels,in a manner that achieves justice and equality.We find that Personal exemptions did not succeed in achieving tax justice by easing the tax burden on the low-income people in society.
文摘The present paper discusses three major sources of negative effect of classroom instruction on L2 learners'pragmatic development:inadequate or inappropriate metapragmatic input,non-authentic classroom discourse and grammar-oriented pedagogy,then proposes some pedagogical suggestions on developing pragmatic competence.
文摘With the development of computer and network technologies, computer--assisted language teaching and learning have been changing from the presentation of single text materials and response model to the integration of outside classroom education media combining text, graphics, images, sound, animation and network communication （CMC） technology. As an auxiliary tool of foreign language teaching, the computer plays its huge potential and promotes the completion of all kinds of language learning tasks. However, high cost and lack of technical support bringing the negative effects to the foreign language teaching is also cannot be ignored. Therefore, in the study of the historical evolvement of the CALL, to fully understand the positive and negative effects from the foreign language teaching will help make the positive effect of foreign language teaching maximized, and avoid misuse and abuse of the CALL.
文摘In such an information age, multimedia teaching has changed into one of the most important educational ways in middle and primary schools. In contrast to traditional education, multimedia teaching owns numerous advantages. However, there are also a great number of shortcomings in it. In this paper, considering the current situation of education in middle and primary schools, the author carries out an analysis on the negative effects of multimedia teaching on education in middle and primary schools, and also proposes some personal suggestions, hopefully providing a reference for teaching personnel in middle and primary schools.
基金supported by the Postgraduate Inovation Programme of Changchun Wormal University(YJSCX202424)the Science and Technology Project of Jilin Provincial Education Department(JJKH20220828KJ)the Natural Science Foundation of Changchun Normal University(2020-005).
文摘The electronic and transport characteristics of protonated derivatives of naphthalocyanine(Nc)were investigated using density functional theory and non-equilibrium Green's functions.The results indicate that the protonation of external meso-N atoms of Nc preserves its planar structure and is energetically more favorable than the protonation of internal isoindole-N atoms.The protonation shifts the energy levels of system's frontier molecular orbitals closer to the Fermi level,thus creating channels for electron transport.In contrast with the semiconductor transport properties of H2Nc,its protonation products respond more sensitively to bias and exhibit negative differential resistance phenomena at specific bias.
文摘deployment of the THAAD system in South Korea imposed by the United States is superficially and nominally to target at the DPRK's nuclear and missile threats,but essentially to respond to the rising China and Russia,is further tied South Korea to the U.S.war chariot and is a dose of poison undermining the Northeast Asian environment for the mutual benefit,mutual trust and win-win cooperation as well as development and stability.
基金supported financially by the National Key Research and Development Program of China (Nos. 2017YFB0702001 and 2016YFB0301105)the National Natural Science Foundation of China Projects (Nos. 51901047,51871211 and51701129)+5 种基金the Doctor Startup Fund of Natural Science Foundation Program of Liaoning Province (No. 2019-BS-200)the Strategic New Industry Development Special Foundation of Shenzhen (No. JCYJ20170306141749970)the Funds of International Joint Laboratory for Light Alloys, the Liaoning Bai Qian Wan Talents Programthe Domain Foundation of Equipment Advance Research of 13th Five-year Plan (No. 61409220118)the Innovation Fund of Institute of Metal Research (IMR), Chinese Academy of Sciences (CAS)the National Basic Research Program of China (No. 2013CB632205)。
文摘The so-called 'negative difference effect'(NDE) was often defined by the increasing rate of hydrogen evolution from magnesium(Mg) surface under anodic polarization.In this work,a series of electrochemical tests and microstructure observations were performed to provide an evidence that the NDE of Mg-Li alloys can be retarded by increasing lithium content.Potentiostatic,galvanostatic and potentiodynamic polarization experiments using Mg-xLi(x=4,7.5 and 14 wt%) alloys electrodes indicated that Mg-4 Li alloy maintained the enhancing NDE prior to anodic dissolution as that of conventional Mg alloys.However,the emergence of β-Li phase weakened the NDE of duplex Mg-7.5 Li alloy at a low anodic current density,but it was still enhanced apparently after a high applied anodic value(more than 2 mA/cm^2).The surface observations,including the plane and cross-sectional morphologies,confirmed that the cracked surface film derived from the anodic dissolution resulted in the catalytic activity of NDE for Mg-4 Li and Mg-7.5 Li alloys.Furthermore,the NDE of Mg-14 Li alloy was suppressed obviously after a prior applied anodic polarization,which was attributed to the persistent and integrated surface film which endured a higher level of applied anodic potential and current.
文摘Efficient photogenerated carrier migration/separation plays a critical role in increasing the photocatalytic performance of g-C_(3)N_(4).Herein,sulfonic acid group-functionalized g-C_(3)N_(4)(SACN)was synthesized and then synchronously strengthened by a facile-solid-state thermal reaction of g-C_(3)N_(4)and sulfamic acid.As a solid strong acid,sulfamic acid can be used to achieve acid etching on the surface of g-C_(3)N_(4)with the assistance of thermal treatment,leading to an enlarged specific surface area and increased surface catalytic reaction sites.More importantly,our experiments and density functional theory calculations indicate that the driving force generated by the negative inductive effect of sulfonic acid groups significantly improves the charge transfer dynamics and effectively inhibits their recombination.Moreover,the negative inductive effect can induce charge redistribution,which reduces the conduction band potential of g-C_(3)N_(4)to enhance the reduction ability of photo-induced electrons.As a result,the SACN-400 sample showed excellent photocatalytic performance in H2 generation with an apparent quantum efficiency of 11.03%at 420±15 nm,as well as an efficient photodegradation rate for organic pollutants.
基金Supported by the National Natural Science Foundation of China under Grant No 51102007the Fund for Discipline Construction of Beijing University of Chemical Technology under Grant No XK1702
文摘The anti-resonant phenomenon of effective electromagnetic parameters of metamaterials has aroused controversy due to negative imaginary permittivity or permeability. It is experimentally found that the negative imaginary permittivity can occur for the natural passive materials near the Fabry Perot resonances. We reveal the nature of negative imaginary permittivity, which is correlated with the magnetoelectric coupling. The anti-resonance of permittivity is a non-inherent feature for passive materials, while it can be inherent for devices or metamaterials. Our finding validates that the negative imaginary part of effective permittivity does not contradict the second law of thermodynamics for metamaterials owing to the magnetoelectric coupling.
文摘抓挠“痒痒包”到底是好是坏?这个看似简单的动作背后竟有科学奥秘!Don’t scratch that mosquito(蚊子)bite!Maybe you’ve heard this advice before-and found it hard to follow.So you may already know that scratching can feel good at the time,but may not help in the long run.A study in mice finds that scratching can have both positive and negative effects.
文摘As one of the most distinguished features of Chinese Culture,collective oriented culture is the deep structure of Chinese cultural psychology which has shaped Chinese character and influenced their behavior.As a result of it,Chinese students suffer this negative effect from collective orientated culture when acquiring English,especially in oral English acquisition.TEFL teachers should be aware of cultural psychology and try their best to minimize its negative effect instead of neglecting or even enlarging it during oral English teaching.
基金This study was funded by the National Natural Science Foundation of China(No.20274017)the Natural Science Foundation of Jiangsu Province(No.BK2004415).
文摘Adsorption behaviors of phenol from aqueous solutions have been investigated in batch systems at 303 K and 318 K respectively, using hypercrosslinked polymeric adsorbent （CHA111）, aminated hypercrosslinked polymeric adsorbents （NDA101, NDA103, NDA105） and weakly basic polymeric adsorbent （D301） with a view to studying the effect of hydrogen bonding and Van der Waals interactions between adsorbate and the adsorbent. All adsorption isotherms can be well fitted by Langmuir and Freundlich equations. Compared with D301 driven by hydrogen bonding interaction only and CHA111 driven by Van der Waals interaction only, phenol adsorption on aminated adsorbents driven by both hydrogen bonding and Van der Waals interactions were apparently different, i.e., negative effect for NDA105, positive effect for NDA101 and synergistic effect for NDA103. In this synergistic action, some weak interactions would contribute more or less to the adsorption than they work individually.
文摘The oxidation of p-xylene to terephthalic acid with molecular oxygen in acetic acids modified carbon dioxide over Co/Mn/Br catalyst was studied in a batch reactor. The results showed that the oxidation of p-xylene to terephthalic acid was severely inhibited when carbon dioxide exceeded a certain amount, the conversion of p-xylene decreased rapidly from 100.0% to 3.3% and the yield of terephthalic acid dropped from 42.6% to trace. Whereas the oxidation processes of p-Tolualdchyde to p-Toluic acid and 4-Carboxybenzaldehyde to tcrcphthalic acid were improved when a relative small amount of CO2 v/as added, Further investigation found that this negative effect may be caused by multiphase reactions emerging.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11604019,61574020,and 61376018)the Ministry of Science and Technology of China(Grant No.2016YFA0301300)+1 种基金the Fund of State Key Laboratory of Information Photonics and Optical Communications(Beijing University of Posts and Telecommunications),Chinathe Fundamental Research Funds for the Central Universities,China(Grant No.2016RCGD22)
文摘Tunneling field effect transistors（TFETs） based on two-dimensional materials are promising contenders to the traditional metal oxide semiconductor field effect transistor, mainly due to potential applications in low power devices. Here,we investigate the TFETs based on two different integration types： in-plane and vertical heterostructures composed of two kinds of layered phosphorous（β-P and δ-P） by ab initio quantum transport simulations. NDR effects have been observed in both in-plane and vertical heterostructures, and the effects become significant with the highest peak-to-valley ratio（PVR）when the intrinsic region length is near zero. Compared with the in-plane TFET based on β-P and δ-P, better performance with a higher on/off current ratio of - 10-6 and a steeper subthreshold swing（SS） of - 23 mV/dec is achieved in the vertical TFET. Such differences in the NDR effects, on/off current ratio and SS are attributed to the distinct interaction nature of theβ-P and δ-P layers in the in-plane and vertical heterostructures.
