When a high energy nanosecond(ns)laser induces breakdown in the air,the plasma density generated in the rarefied atmosphere is much smaller than that at normal pressure.It is associated with a relatively lower absorpt...When a high energy nanosecond(ns)laser induces breakdown in the air,the plasma density generated in the rarefied atmosphere is much smaller than that at normal pressure.It is associated with a relatively lower absorption coefficient and reduces energy loss of the laser beam at low pressure.In this paper,the general transmission characterizations of a Joule level 10 ns 1064 nm focused laser beam are investigated both theoretically and experimentally under different pressures.The evolution of the electron density(n_(e)),the changes in electron temperature(T_(e))and the variation of laser intensity(I)are employed for numerical analyses in the simulation model.For experiments,four optical image transfer systems with focal length(f)of 200 mm are placed in a chamber and employed to focus the laser beam and produce plasmas at the focus.The results suggest that the transmittance increases obviously with the decreasing pressure and the plasma channels on the transmission path can be observed by the self-illumination.The simulation results agree well with the experimental data.The numerical model presents that the maximum n_e at the focus can reach 10^(19)cm^(-3),which is far below the critical density(n_(c)).As a result,the laser beam is not completely shielded by the plasmas.展开更多
In this paper,we investigated the emission spectra of plasmas produced from femtosecond and nanosecond laser ablations at different target temperatures in air.A brass was selected as ablated target of the experiment.T...In this paper,we investigated the emission spectra of plasmas produced from femtosecond and nanosecond laser ablations at different target temperatures in air.A brass was selected as ablated target of the experiment.The results indicated that spectral emission intensity and plasma temperature showed similar trend for femtosecond and nanosecond lasers,and the two parameters were improved by increasing the sample temperature in both cases.Moreover,the temperature of nanosecond laser-excited plasma was higher compared with that of femtosecond laser-excited plasma,and the increase of the plasma temperature in the case of nanosecond laser was more evident.In addition,there was a significant difference in electron density between femtosecond and nanosecond laser-induced plasmas.The electron density for femtosecond laser decreased with increasing the target temperature,while for nanosecond laser,the electron density was almost unchanged at different sample temperatures.展开更多
A study of a nanosecond laser irradiation on the titanium-layer-buried gold planar target is presented. The timeresolved x-ray emission spectra of titanium tracer are measured by a streaked crystal spectrometer. By co...A study of a nanosecond laser irradiation on the titanium-layer-buried gold planar target is presented. The timeresolved x-ray emission spectra of titanium tracer are measured by a streaked crystal spectrometer. By comparing the simulated spectra obtained by using the FLYCHK code with the measured titanium spectra, the temporal plasma states, i.e.,the electron temperatures and densities, are deduced. To evaluate the feasibility of using the method for the characterization of Au plasma states, the deduced plasma states from the measured titanium spectra are compared with the Multi-1D hydrodynamic simulations of laser-produced Au plasmas. By comparing the measured and simulated results, an overall agreement for the electron temperatures is found, whereas there are deviations in the electron densities. The experiment–theory discrepancy may suggest that the plasma state could not be well reproduced by the Multi-1D hydrodynamic simulation, in which the radial gradient is not taken into account. Further investigations on the spectral characterization and hydrodynamic simulations of the plasma states are needed. All the measured and FLYCHK simulated spectra are given in this paper as datasets. The datasets are openly available at http://www.doi.org/10.57760/sciencedb.j00113.00032.展开更多
The laser-induced damage threshold(LIDT)of optical elements is a critical limitation in advancing nextgeneration spaceborne laser technologies.Transient mechanisms in multiple-pulse damage dynamics have been recognize...The laser-induced damage threshold(LIDT)of optical elements is a critical limitation in advancing nextgeneration spaceborne laser technologies.Transient mechanisms in multiple-pulse damage dynamics have been recognized,but significant gaps remain in understanding these processes.In this study,we introduce a practice time interval(Δt_(p))-dependent damage metric.Using a double-pulse double-probe experimental configuration,we systematically examine the double-pulse damage dynamics and relaxation process.The first pulse induces localized modifications that initiate a relaxation process,accumulating material damage caused by the subsequent pulse.Our results show that this relaxation lasts~500 ns for surface damage and is on a several millisecond scale for bulk damage.The second pulse induces more pronounced modifications and damage whenΔt_(p)is less than100 ns,dominated by nonlinear phenomena like multiphoton absorption due to temporally overlapping pulses.Conversely,forΔt_(p)>100 ns,thermal accumulation via phonon relaxation predominates.Additionally,the critical energy density for damage correlates positively with LIDT asΔt_(p)increases,reflecting the reduced thermal and mechanical stress influence.These findings highlight the dynamic competition between nonlinear and thermal effects in multiple-pulse laser interactions,providing practical strategies for designing optical components with high damage thresholds and developing high-performance optical systems.展开更多
Precision drilling with picosecond laser has been advocated to significantly improve the quality of micro-holes with reduced recast layer thickness and almost no heat affected zone.However,a detailed comparison betwee...Precision drilling with picosecond laser has been advocated to significantly improve the quality of micro-holes with reduced recast layer thickness and almost no heat affected zone.However,a detailed comparison between nanosecond and picosecond laser drilling techniques has rarely been reported in previous research.In the present study,a series of micro-holes are manufactured on stainless steel 304 using a nanosecond and a picosecond laser drilling system,respectively.The quality of the micro-holes,e.g.,recast layer,micro-crack,circularity,and conicity,etc,is evaluated by employing an optical microscope,an optical interferometer,and a scanning electron microscope.Additionally,the micro-structure of the samples between the edges of the micro-holes and the parent material is compared following etching treatment.The researching results show that a great amount of spattering material accumulated at the entrance ends of the nanosecond laser drilled micro-holes.The formation of a recast layer with a thickness of;5μm is detected on the side walls,associated with initiation of micro-cracks.Tapering phenomenon is also observed and the circularity of the micro-holes is rather poor.With regard to the micro-holes drilled by picosecond laser,the entrance ends,the exit ends,and the side walls are quite smooth without accumulation of spattering material,formation of recast layer and micro-cracks.The circularity of the micro-holes is fairly good without observation of tapering phenomenon.Furthermore,there is no obvious difference as for the micro-structure between the edges of the micro-holes and the parent material.This study proposes a picosecond laser helical drilling technique which can be used for effective manufacturing of high quality micro-holes.展开更多
Aluminum samples have been analyzed by femtosecond polarization-resolved laser-induced breakdown spectroscopy （fs-PRLIBS）. We compare the obtained spectra with those obtained from nanosecond PRLIBS （ns-PRLIBS）. Th...Aluminum samples have been analyzed by femtosecond polarization-resolved laser-induced breakdown spectroscopy （fs-PRLIBS）. We compare the obtained spectra with those obtained from nanosecond PRLIBS （ns-PRLIBS）. The main specific features of fs-PRLIBS are that a lower plasma temperature leads to a low level of continuum and no species are detected from the ambient gas. Furthermore, signals obtained by fs-PRLIBS show a higher stability than those of ns-PRLIBS. However, more elements are detected in the ns-PRLIBS spectra.展开更多
Laser surface texturing(LST)is a non-contact manufacturing process for fabricating functional surfaces in a manner that improves the corresponding wettability,and is widely used in biomedicine and industry.Laser surfa...Laser surface texturing(LST)is a non-contact manufacturing process for fabricating functional surfaces in a manner that improves the corresponding wettability,and is widely used in biomedicine and industry.Laser surface texturing is a facile approach that is compatible with various materials,can result in a hierarchical texture,and enables a high degree of surface wetting(i.e.,extreme wetting).In addition to surface structures,surface chemical modification is a primary factor in producing extreme wetting surfaces.This review discusses the effects of various surface textures and surface chemistries on wettability.Optimal laser parameters for the desired surface texture are based on the fundamental wettability and laser mechanism.In particular,bumps in the morphology are conducive to obtaining extreme wetting.Diverse surface chemical strategies result in extreme wetting by different mechanisms.This paper makes a rigorous evaluation of the laser parameters and optimal surface chemical modifications by elucidating the relationships between the surface structure,surface chemical modification,and wettability,and in so doing,determines the final wettability.The unresolved problems of LST are presented in the conclusion.This review provides guidance,development directions,and an integrated framework for LST,which will be useful for fabricating extreme wetting surfaces on various metals.展开更多
Multilayer dielectric gratings(MLDGs)are crucial for pulse compression in picosecond-petawatt laser systems.Bulged nodular defects,embedded in coating stacks during multilayer deposition,influence the lithographic pro...Multilayer dielectric gratings(MLDGs)are crucial for pulse compression in picosecond-petawatt laser systems.Bulged nodular defects,embedded in coating stacks during multilayer deposition,influence the lithographic process and performance of the final MLDG products.In this study,the integration of nanosecond laser conditioning(NLC)into different manufacturing stages of MLDGs was proposed for the first time on multilayer dielectric films(MLDFs)and final grating products to improve laser-induced damage performance.The results suggest that the remaining nodular ejection pits introduced by the two protocols exhibit a high nanosecond laser damage resistance,which remains stable when the irradiated laser fluence is more than twice the nanosecond-laser-induced damage threshold(nanosecond-LIDT)of the unconditioned MLDGs.Furthermore,the picosecond-LIDT of the nodular ej ection pit conditioned on the MLDFs was approximately 40%higher than that of the nodular defects,and the loss of the grating structure surrounding the nodular defects was avoided.Therefore,NLC is an effective strategy for improving the laser damage resistance of MLDGs.展开更多
In this work,we comprehensively investigate the response of amorphous and crystalline Zr-based alloys under nanosecond pulse laser ablation.The in situ multiphysics processes and ablation morphologies of the two alloy...In this work,we comprehensively investigate the response of amorphous and crystalline Zr-based alloys under nanosecond pulse laser ablation.The in situ multiphysics processes and ablation morphologies of the two alloy targets are explored and compared.The results indicate that the dynamics of laser-induced plasma and shock waves obey the idea blast wave theory and are insensitive to the topological structures of targets.Both targets experience significant superheating and culminate in explosive boiling.This ablation process leads to the formation of a hierarchical structure in the resultant ablation crater:microdents covered by widespread nanovoids.The amorphous target shows shallower microdents and smaller nanovoids than their crystalline counterparts because the former has a smaller heat-affected zone and experiences a higher degree of superheating.The hierarchical structure can adjust the surface wettability of targets from initial hydrophilic to hydrophobic,showing an increase of the contact angle approximately 119% for amorphous alloy compared with the crystal approximately 64%.This work demonstrates that amorphous alloys have a better performance against nanosecond pulse laser ablation and provides a feasible and one-step method of wettability modification for either amorphous or crystalline alloys.展开更多
Metal surfaces play a crucial role in numerous applications,from self-cleaning and anti-icing to anti-fogging and oil-water separation.The regulation of their wettability is essential to enhance their performance in t...Metal surfaces play a crucial role in numerous applications,from self-cleaning and anti-icing to anti-fogging and oil-water separation.The regulation of their wettability is essential to enhance their performance in these areas.This paper proposes a multi-state regulation method for metal surface wettability,leveraging nanosecond laser ablation.By creating non-uniform microstructures on a metal surface,the contact area between the solid and liquid phases can be increased,resulting in the attainment of superhydrophilic properties(contact angle(CA),ranging from 4.6°to 8.5°).Conversely,the construction of uniform microstructures leads to a decreased solid-liquid contact area,thereby rendering the metal surface hydrophilic(CA=12.2°–53°).Furthermore,through heat treatment on a surface with uniform microstructures,organic matter adsorption can be promoted while simultaneously reducing surface energy.This process results in the metal surface acquiring hydrophobic properties(CA=92.1°–133.5°),facilitated by the“air cushion effect.”Building on the hydrophobic surface,stearic acid modification can further reduce surface energy,ultimately bestowing the metal surface with superhydrophobic properties(CA=150.1°–152.7°,and sliding angle=3.8°).Performance testing has validated the durability and self-cleaning effectiveness of the fabricated superhydrophobic surface while also highlighting the excellent anti-fog performance of the superhydrophilic surface.These findings strongly indicate the immense potential of these surfaces in various engineering applications.展开更多
pH dependent uorescence emission of a thioxanthone-based probe has been re-ported recently.The potential deter-minant factors of pH dependence may provide important clues to design novel thioxanthone-based probes in t...pH dependent uorescence emission of a thioxanthone-based probe has been re-ported recently.The potential deter-minant factors of pH dependence may provide important clues to design novel thioxanthone-based probes in the fu-ture.pH dependence of photochemical kinetics of thioxanthone itself was inves-tigated in this work using nanosecond time-resolved laser ash photolysis.The nanosecond time-resolved transient absorption spectra and kinetics of TX in aqueous acetonitrile were recorded,as well as for a model reaction system including TX with diphenylamine(DPA)as a co-initiator.Besides the well-known absorption peak of ^(3)TX*,other peaks at 417,518,673 and 780 nm,have been reliably attributed to major intermediates in the overall reaction between TX and DPA with photolysis,which has been con rmed to occur along a multistep process.In the strong acidic solution(pH≈3.0),TX and protonated TX ions(TXH^(+))coexist due to protonated equilibrium.Consequently,high proton concentration promotes the predominant decay pathway after photolysis from electron transfer to proton affnity.Subsequently,the di erent primary products,^(3)TXH^(+*)or TX^(·-),proceed di erent secondary reaction channels.In addition,within the wide pH range from weak acid(pH=5.0)to alkaline solution(pH=13.0),the overall reaction mechanism and rates do not show visible changes.展开更多
Gallium nitride(GaN)has widespread applications in the semiconductor industry because of its desirable optoelectronic properties.The fabrication of surface structures on GaN thin films can effectively modify their opt...Gallium nitride(GaN)has widespread applications in the semiconductor industry because of its desirable optoelectronic properties.The fabrication of surface structures on GaN thin films can effectively modify their optical and electrical properties,providing additional degrees of freedom for controlling GaN-based devices.Compared with lithography-based techniques,laser processing is maskless and much more efficient.This paper shows how surface micronano structures can be produced on GaN thin films using 355 nm nanosecond laser irradiation.The effects of the laser pulse energy,number of pulses,and polarization direction were studied.It was found that distinct micro-nano structures were formed under different irradiation conditions,and their geometries and elemental compositions were analyzed.The results indicate that different types of surface micro-nano structures can be produced on GaN thin films in a controllable manner using 355 nm nanosecond laser irradiation.The results of our study provide valuable guidance for the surface modification of GaN-based optoelectronic devices.展开更多
Shock compression driven by nanosecond-laser techniques generates extreme pressure and temperature conditions in materials,enabling the study of high-pressure phase transitions and the behavior of materials in extreme...Shock compression driven by nanosecond-laser techniques generates extreme pressure and temperature conditions in materials,enabling the study of high-pressure phase transitions and the behavior of materials in extreme environments.These dynamic high-pressure states are relevant to a wide range of phenomena,including planetary formation,asteroid impacts,spacecraft shielding,and inertial confinement fusion.The integration of advanced X-ray diffraction experimental techniques,from laser-induced X-ray sources and X-ray free-electron lasers,and theoretical simulations has provided unprecedented insights into material behavior under extreme conditions.This perspective reviews recent advances in dynamic high-pressure research and the insights that they can provide,concentrating on dynamical phase transitions,metastable and transient states,the influence of crystal orientation,microstructural changes,and the kinetic mechanism of phase transitions across a variety of interdisciplinary fields.展开更多
The flat plane of small surface roughness below 0.1μm average roughness was obtained for monocrystalline diamond by nanosecond pulsed laser irradiation of 1060 nm and post-process acid cleaning,at a laser fluence aro...The flat plane of small surface roughness below 0.1μm average roughness was obtained for monocrystalline diamond by nanosecond pulsed laser irradiation of 1060 nm and post-process acid cleaning,at a laser fluence around the material removal threshold value.The glossy and flat plane at the bottom of the micro-groove was parallel to the top surface of the specimen,although the round beam of Gaussian mode was irradiated in the direction perpendicular to the top surface of specimen.The square beam of top-hat mode produced a shallower micro-groove with a wider,flatter bottom compared with the round beam in Gaussian mode.The creation method of the flat plane with small surface roughness was discussed in the arrangement strategy of linear micro-grooving by the square beam of top-hat mode.Normal side-by-side repetition of linear micro-grooving did not create a flat plane with constant depth.Therefore,a two-step scanning method was proposed in order to overcome the problem in the normal side-by-side repetition of liner micro-grooving.Non-removal areas were partly retained between the processing lines in the first step,and the laser scanning was conducted on the retained area in the second step.The newly proposed two-step scanning method was practical and useful to create a widely flat plane with small surface roughness,and the two-step scanning method provided superior control over the micro-groove depth.This proposed method can reduce the surface roughness in addition to the shape creation of monocrystalline diamond,and it can be used as a high-quality micro-shape fabrication method of monocrystalline diamond.展开更多
Silver nanoparticles (AgNPs) were fabricated by repetitive irradiation of near ultraviolet (UV) nanosecond laser pulses (355 nm, 5 ns) in an aqueous solution of silver nitrate in the absence of stabilizing agents. A b...Silver nanoparticles (AgNPs) were fabricated by repetitive irradiation of near ultraviolet (UV) nanosecond laser pulses (355 nm, 5 ns) in an aqueous solution of silver nitrate in the absence of stabilizing agents. A broad absorption peak was observed in the visible region showing the formation of a variety of AgNPs in the solution. Among the variety of products, it was found that silver nanocubes (AgNCs) grew in size with longer laser irradiation time. The size of AgNCs also increased with higher laser intensity. The average size of AgNCs, investigated by a scanning electron microscope (SEM) was in the range of 75 - 200 nm. The number of reduced atoms in AgNCs as a function of laser intensity showed that the AgNCs are apparently produced by a four photon process, implying that the formation of dimer silver atoms is essential for the formation.展开更多
Nanosecond time-resolved transient absorption spectra of pyrene-triphenylamine, pyrenediphenylamine, pyrene-N, N-dibenzylaniline systems in various solvents have been investigated. In nonpolar solvent, pyrene-tripheny...Nanosecond time-resolved transient absorption spectra of pyrene-triphenylamine, pyrenediphenylamine, pyrene-N, N-dibenzylaniline systems in various solvents have been investigated. In nonpolar solvent, pyrene-triphenylamine exciplex and pyrene-N, N-dibenzylaniline exciplex were observed directly. In acetonitrile, the pyrene anion radical, triphenylamine and diphenylamine cation radicals were detected. On the basis of the present experimental facts, the mechanism of fluorescence quenching processes of pyrene in polar and nonpolar solvents has been established.展开更多
Purple membrane, molecular weight 26ku, is synthesized by Holobacterium halobium on some parts of its cell membrane under a special condition combined by 248 residues,and 7 times acrossing membrane. Only one kind of p...Purple membrane, molecular weight 26ku, is synthesized by Holobacterium halobium on some parts of its cell membrane under a special condition combined by 248 residues,and 7 times acrossing membrane. Only one kind of protein, bacteriorhodopsin (BR), is on the membrane. After light excitation, BR goes through a series of intermediate processes K, L, M, N, O and recovers to BR. Purple membrane is an ideal biomaterial for photo energy transfer, and becomes a new focus field of many branches of science. Because the photocycle of BR is related to light-driven proton pump and photoelectric response,展开更多
We demonstrated a 2-μm passively mode-locked nanosecond fiber laser based on a MoS2 saturable absorber（SA）.Owing to the effect of nonlinear absorption in the MoS2 SA, the pulse width decreased from 64.7 to 13.8 ns ...We demonstrated a 2-μm passively mode-locked nanosecond fiber laser based on a MoS2 saturable absorber（SA）.Owing to the effect of nonlinear absorption in the MoS2 SA, the pulse width decreased from 64.7 to 13.8 ns with increasing pump power from 1.10 to 1.45 W. The use of a narrow-bandwidth fiber Bragg grating resulted in a central wavelength and 3-dB spectral bandwidth of 2010.16 and 0.15 nm, respectively. Experimental results show that MoS2 is a promising material for a 2-μm mode-locked fiber laser.展开更多
基金Project supported by the Science and Technology Innovation Foundation of the Chinese Academy of Sciences(Grant No.CXJJ-20S020)。
文摘When a high energy nanosecond(ns)laser induces breakdown in the air,the plasma density generated in the rarefied atmosphere is much smaller than that at normal pressure.It is associated with a relatively lower absorption coefficient and reduces energy loss of the laser beam at low pressure.In this paper,the general transmission characterizations of a Joule level 10 ns 1064 nm focused laser beam are investigated both theoretically and experimentally under different pressures.The evolution of the electron density(n_(e)),the changes in electron temperature(T_(e))and the variation of laser intensity(I)are employed for numerical analyses in the simulation model.For experiments,four optical image transfer systems with focal length(f)of 200 mm are placed in a chamber and employed to focus the laser beam and produce plasmas at the focus.The results suggest that the transmittance increases obviously with the decreasing pressure and the plasma channels on the transmission path can be observed by the self-illumination.The simulation results agree well with the experimental data.The numerical model presents that the maximum n_e at the focus can reach 10^(19)cm^(-3),which is far below the critical density(n_(c)).As a result,the laser beam is not completely shielded by the plasmas.
基金the support by the Scientific and Technological Research Project of the Education Department of Jilin Province, China (No. JJKH20200937KJ)National Natural Science Foundation of China (Nos. 11674128, 11674124 and 11974138)
文摘In this paper,we investigated the emission spectra of plasmas produced from femtosecond and nanosecond laser ablations at different target temperatures in air.A brass was selected as ablated target of the experiment.The results indicated that spectral emission intensity and plasma temperature showed similar trend for femtosecond and nanosecond lasers,and the two parameters were improved by increasing the sample temperature in both cases.Moreover,the temperature of nanosecond laser-excited plasma was higher compared with that of femtosecond laser-excited plasma,and the increase of the plasma temperature in the case of nanosecond laser was more evident.In addition,there was a significant difference in electron density between femtosecond and nanosecond laser-induced plasmas.The electron density for femtosecond laser decreased with increasing the target temperature,while for nanosecond laser,the electron density was almost unchanged at different sample temperatures.
基金Project supported by the National Key Research and Development Program of China (Grant No.2017YFA0403300)the National Natural Science Foundation of China (Grant Nos.12074352 and 11675158)Fundamental Research Funds for the Central Universities in China (Grant No.YJ202144)。
文摘A study of a nanosecond laser irradiation on the titanium-layer-buried gold planar target is presented. The timeresolved x-ray emission spectra of titanium tracer are measured by a streaked crystal spectrometer. By comparing the simulated spectra obtained by using the FLYCHK code with the measured titanium spectra, the temporal plasma states, i.e.,the electron temperatures and densities, are deduced. To evaluate the feasibility of using the method for the characterization of Au plasma states, the deduced plasma states from the measured titanium spectra are compared with the Multi-1D hydrodynamic simulations of laser-produced Au plasmas. By comparing the measured and simulated results, an overall agreement for the electron temperatures is found, whereas there are deviations in the electron densities. The experiment–theory discrepancy may suggest that the plasma state could not be well reproduced by the Multi-1D hydrodynamic simulation, in which the radial gradient is not taken into account. Further investigations on the spectral characterization and hydrodynamic simulations of the plasma states are needed. All the measured and FLYCHK simulated spectra are given in this paper as datasets. The datasets are openly available at http://www.doi.org/10.57760/sciencedb.j00113.00032.
基金National Key Research and Development Program of China(2021YFB3601402)National Natural Science Foundation of China(61975153)。
文摘The laser-induced damage threshold(LIDT)of optical elements is a critical limitation in advancing nextgeneration spaceborne laser technologies.Transient mechanisms in multiple-pulse damage dynamics have been recognized,but significant gaps remain in understanding these processes.In this study,we introduce a practice time interval(Δt_(p))-dependent damage metric.Using a double-pulse double-probe experimental configuration,we systematically examine the double-pulse damage dynamics and relaxation process.The first pulse induces localized modifications that initiate a relaxation process,accumulating material damage caused by the subsequent pulse.Our results show that this relaxation lasts~500 ns for surface damage and is on a several millisecond scale for bulk damage.The second pulse induces more pronounced modifications and damage whenΔt_(p)is less than100 ns,dominated by nonlinear phenomena like multiphoton absorption due to temporally overlapping pulses.Conversely,forΔt_(p)>100 ns,thermal accumulation via phonon relaxation predominates.Additionally,the critical energy density for damage correlates positively with LIDT asΔt_(p)increases,reflecting the reduced thermal and mechanical stress influence.These findings highlight the dynamic competition between nonlinear and thermal effects in multiple-pulse laser interactions,providing practical strategies for designing optical components with high damage thresholds and developing high-performance optical systems.
基金Supported by National Basic Research Program of China(Grant No.2011CB013004)National Natural Science Foundation of China(Grant No.51005130)Research Fund of State Key Laboratory of Tribology,Tsinghua University(Grant no.SKLT12B06)
文摘Precision drilling with picosecond laser has been advocated to significantly improve the quality of micro-holes with reduced recast layer thickness and almost no heat affected zone.However,a detailed comparison between nanosecond and picosecond laser drilling techniques has rarely been reported in previous research.In the present study,a series of micro-holes are manufactured on stainless steel 304 using a nanosecond and a picosecond laser drilling system,respectively.The quality of the micro-holes,e.g.,recast layer,micro-crack,circularity,and conicity,etc,is evaluated by employing an optical microscope,an optical interferometer,and a scanning electron microscope.Additionally,the micro-structure of the samples between the edges of the micro-holes and the parent material is compared following etching treatment.The researching results show that a great amount of spattering material accumulated at the entrance ends of the nanosecond laser drilled micro-holes.The formation of a recast layer with a thickness of;5μm is detected on the side walls,associated with initiation of micro-cracks.Tapering phenomenon is also observed and the circularity of the micro-holes is rather poor.With regard to the micro-holes drilled by picosecond laser,the entrance ends,the exit ends,and the side walls are quite smooth without accumulation of spattering material,formation of recast layer and micro-cracks.The circularity of the micro-holes is fairly good without observation of tapering phenomenon.Furthermore,there is no obvious difference as for the micro-structure between the edges of the micro-holes and the parent material.This study proposes a picosecond laser helical drilling technique which can be used for effective manufacturing of high quality micro-holes.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 11211120156, 11274053, 11074027, 61178022, and 60978014)the Science and Technology Department of Jilin Province, China (Grant Nos. 20100521, 20100168, and 20111812)the SRF for ROCS, SEM
文摘Aluminum samples have been analyzed by femtosecond polarization-resolved laser-induced breakdown spectroscopy （fs-PRLIBS）. We compare the obtained spectra with those obtained from nanosecond PRLIBS （ns-PRLIBS）. The main specific features of fs-PRLIBS are that a lower plasma temperature leads to a low level of continuum and no species are detected from the ambient gas. Furthermore, signals obtained by fs-PRLIBS show a higher stability than those of ns-PRLIBS. However, more elements are detected in the ns-PRLIBS spectra.
基金supported by Natural Science Foundation of Chongqing,China(Grant No.cstc2019jcyj-msxmX0114).
文摘Laser surface texturing(LST)is a non-contact manufacturing process for fabricating functional surfaces in a manner that improves the corresponding wettability,and is widely used in biomedicine and industry.Laser surface texturing is a facile approach that is compatible with various materials,can result in a hierarchical texture,and enables a high degree of surface wetting(i.e.,extreme wetting).In addition to surface structures,surface chemical modification is a primary factor in producing extreme wetting surfaces.This review discusses the effects of various surface textures and surface chemistries on wettability.Optimal laser parameters for the desired surface texture are based on the fundamental wettability and laser mechanism.In particular,bumps in the morphology are conducive to obtaining extreme wetting.Diverse surface chemical strategies result in extreme wetting by different mechanisms.This paper makes a rigorous evaluation of the laser parameters and optimal surface chemical modifications by elucidating the relationships between the surface structure,surface chemical modification,and wettability,and in so doing,determines the final wettability.The unresolved problems of LST are presented in the conclusion.This review provides guidance,development directions,and an integrated framework for LST,which will be useful for fabricating extreme wetting surfaces on various metals.
基金supported by the National Key R&D Program of China(Grant No.2018YFE0115900)the Key Foreign Cooperation Projects of Bureau of the International Cooperation of Chinese Academy of Sciences(Grant No.181231KYSB20210001)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA25020314).
文摘Multilayer dielectric gratings(MLDGs)are crucial for pulse compression in picosecond-petawatt laser systems.Bulged nodular defects,embedded in coating stacks during multilayer deposition,influence the lithographic process and performance of the final MLDG products.In this study,the integration of nanosecond laser conditioning(NLC)into different manufacturing stages of MLDGs was proposed for the first time on multilayer dielectric films(MLDFs)and final grating products to improve laser-induced damage performance.The results suggest that the remaining nodular ejection pits introduced by the two protocols exhibit a high nanosecond laser damage resistance,which remains stable when the irradiated laser fluence is more than twice the nanosecond-laser-induced damage threshold(nanosecond-LIDT)of the unconditioned MLDGs.Furthermore,the picosecond-LIDT of the nodular ej ection pit conditioned on the MLDFs was approximately 40%higher than that of the nodular defects,and the loss of the grating structure surrounding the nodular defects was avoided.Therefore,NLC is an effective strategy for improving the laser damage resistance of MLDGs.
基金supported by the National Outstanding Youth Science Fund Project(Grant No.12125206)of the National Natural Science Foundation of China(NSFC)the NSFC Basic Science Center for"Multiscale Problems in Nonlinear Mechanics"(Grant No.11988102)the NSFC(Grant Nos.11972345 and 11790292).
文摘In this work,we comprehensively investigate the response of amorphous and crystalline Zr-based alloys under nanosecond pulse laser ablation.The in situ multiphysics processes and ablation morphologies of the two alloy targets are explored and compared.The results indicate that the dynamics of laser-induced plasma and shock waves obey the idea blast wave theory and are insensitive to the topological structures of targets.Both targets experience significant superheating and culminate in explosive boiling.This ablation process leads to the formation of a hierarchical structure in the resultant ablation crater:microdents covered by widespread nanovoids.The amorphous target shows shallower microdents and smaller nanovoids than their crystalline counterparts because the former has a smaller heat-affected zone and experiences a higher degree of superheating.The hierarchical structure can adjust the surface wettability of targets from initial hydrophilic to hydrophobic,showing an increase of the contact angle approximately 119% for amorphous alloy compared with the crystal approximately 64%.This work demonstrates that amorphous alloys have a better performance against nanosecond pulse laser ablation and provides a feasible and one-step method of wettability modification for either amorphous or crystalline alloys.
基金supported by the Natural Science Foundation of Hunan Province,China(Grant No.2023JJ30669)the Natural Science Foundation of Changsha City,China(Grant No.kq2208273)+3 种基金the Fundamental Research Funds for the Central Universities of Central South University(Grant No.2023ZZTS0967)the Fundamentals and Application Fundamentals Foundation of Guangdong Province,China(Grant No.2022A1515011226)the Project of State Key Laboratory of Precision Manufacturing for Extreme Service Performance,Central South University(Grant No.ZZYJKT2022-10)the Project of Guangdong Provincial Key Laboratory of Manufacturing Equipment Digitization(Grant No.2020B1212060014)。
文摘Metal surfaces play a crucial role in numerous applications,from self-cleaning and anti-icing to anti-fogging and oil-water separation.The regulation of their wettability is essential to enhance their performance in these areas.This paper proposes a multi-state regulation method for metal surface wettability,leveraging nanosecond laser ablation.By creating non-uniform microstructures on a metal surface,the contact area between the solid and liquid phases can be increased,resulting in the attainment of superhydrophilic properties(contact angle(CA),ranging from 4.6°to 8.5°).Conversely,the construction of uniform microstructures leads to a decreased solid-liquid contact area,thereby rendering the metal surface hydrophilic(CA=12.2°–53°).Furthermore,through heat treatment on a surface with uniform microstructures,organic matter adsorption can be promoted while simultaneously reducing surface energy.This process results in the metal surface acquiring hydrophobic properties(CA=92.1°–133.5°),facilitated by the“air cushion effect.”Building on the hydrophobic surface,stearic acid modification can further reduce surface energy,ultimately bestowing the metal surface with superhydrophobic properties(CA=150.1°–152.7°,and sliding angle=3.8°).Performance testing has validated the durability and self-cleaning effectiveness of the fabricated superhydrophobic surface while also highlighting the excellent anti-fog performance of the superhydrophilic surface.These findings strongly indicate the immense potential of these surfaces in various engineering applications.
基金This work was supported by the Educational Com-mission of Anhui Province of China(No.KJ2018A0491 and KJ2019A0736)the National Natural Science Foun-dation of China(No.21873089)the Natural Science Foundation of Anhui Province(No.1908085MB50).
文摘pH dependent uorescence emission of a thioxanthone-based probe has been re-ported recently.The potential deter-minant factors of pH dependence may provide important clues to design novel thioxanthone-based probes in the fu-ture.pH dependence of photochemical kinetics of thioxanthone itself was inves-tigated in this work using nanosecond time-resolved laser ash photolysis.The nanosecond time-resolved transient absorption spectra and kinetics of TX in aqueous acetonitrile were recorded,as well as for a model reaction system including TX with diphenylamine(DPA)as a co-initiator.Besides the well-known absorption peak of ^(3)TX*,other peaks at 417,518,673 and 780 nm,have been reliably attributed to major intermediates in the overall reaction between TX and DPA with photolysis,which has been con rmed to occur along a multistep process.In the strong acidic solution(pH≈3.0),TX and protonated TX ions(TXH^(+))coexist due to protonated equilibrium.Consequently,high proton concentration promotes the predominant decay pathway after photolysis from electron transfer to proton affnity.Subsequently,the di erent primary products,^(3)TXH^(+*)or TX^(·-),proceed di erent secondary reaction channels.In addition,within the wide pH range from weak acid(pH=5.0)to alkaline solution(pH=13.0),the overall reaction mechanism and rates do not show visible changes.
文摘Gallium nitride(GaN)has widespread applications in the semiconductor industry because of its desirable optoelectronic properties.The fabrication of surface structures on GaN thin films can effectively modify their optical and electrical properties,providing additional degrees of freedom for controlling GaN-based devices.Compared with lithography-based techniques,laser processing is maskless and much more efficient.This paper shows how surface micronano structures can be produced on GaN thin films using 355 nm nanosecond laser irradiation.The effects of the laser pulse energy,number of pulses,and polarization direction were studied.It was found that distinct micro-nano structures were formed under different irradiation conditions,and their geometries and elemental compositions were analyzed.The results indicate that different types of surface micro-nano structures can be produced on GaN thin films in a controllable manner using 355 nm nanosecond laser irradiation.The results of our study provide valuable guidance for the surface modification of GaN-based optoelectronic devices.
基金supported by the National Natural Science Foundation of China under Grant Nos.12534013,12035002,12047561,and 12104507as well as the Science and Technology Innovation Program of Hunan Province under Grant No.2021RC4026+1 种基金T.Sekine gratefully acknowledges financial support from the Shanghai Key Laboratory of Material Frontiers Research in Extreme Environments,China(Grant No.22dz2260800)from the Shanghai Science and Technology Committee,China(Grant No.22JC1410300).
文摘Shock compression driven by nanosecond-laser techniques generates extreme pressure and temperature conditions in materials,enabling the study of high-pressure phase transitions and the behavior of materials in extreme environments.These dynamic high-pressure states are relevant to a wide range of phenomena,including planetary formation,asteroid impacts,spacecraft shielding,and inertial confinement fusion.The integration of advanced X-ray diffraction experimental techniques,from laser-induced X-ray sources and X-ray free-electron lasers,and theoretical simulations has provided unprecedented insights into material behavior under extreme conditions.This perspective reviews recent advances in dynamic high-pressure research and the insights that they can provide,concentrating on dynamical phase transitions,metastable and transient states,the influence of crystal orientation,microstructural changes,and the kinetic mechanism of phase transitions across a variety of interdisciplinary fields.
基金partially supported by Osawa Scientific Studies Grants Foundation
文摘The flat plane of small surface roughness below 0.1μm average roughness was obtained for monocrystalline diamond by nanosecond pulsed laser irradiation of 1060 nm and post-process acid cleaning,at a laser fluence around the material removal threshold value.The glossy and flat plane at the bottom of the micro-groove was parallel to the top surface of the specimen,although the round beam of Gaussian mode was irradiated in the direction perpendicular to the top surface of specimen.The square beam of top-hat mode produced a shallower micro-groove with a wider,flatter bottom compared with the round beam in Gaussian mode.The creation method of the flat plane with small surface roughness was discussed in the arrangement strategy of linear micro-grooving by the square beam of top-hat mode.Normal side-by-side repetition of linear micro-grooving did not create a flat plane with constant depth.Therefore,a two-step scanning method was proposed in order to overcome the problem in the normal side-by-side repetition of liner micro-grooving.Non-removal areas were partly retained between the processing lines in the first step,and the laser scanning was conducted on the retained area in the second step.The newly proposed two-step scanning method was practical and useful to create a widely flat plane with small surface roughness,and the two-step scanning method provided superior control over the micro-groove depth.This proposed method can reduce the surface roughness in addition to the shape creation of monocrystalline diamond,and it can be used as a high-quality micro-shape fabrication method of monocrystalline diamond.
文摘Silver nanoparticles (AgNPs) were fabricated by repetitive irradiation of near ultraviolet (UV) nanosecond laser pulses (355 nm, 5 ns) in an aqueous solution of silver nitrate in the absence of stabilizing agents. A broad absorption peak was observed in the visible region showing the formation of a variety of AgNPs in the solution. Among the variety of products, it was found that silver nanocubes (AgNCs) grew in size with longer laser irradiation time. The size of AgNCs also increased with higher laser intensity. The average size of AgNCs, investigated by a scanning electron microscope (SEM) was in the range of 75 - 200 nm. The number of reduced atoms in AgNCs as a function of laser intensity showed that the AgNCs are apparently produced by a four photon process, implying that the formation of dimer silver atoms is essential for the formation.
基金Project supported by the National Natural Science Foundation of China.
文摘Nanosecond time-resolved transient absorption spectra of pyrene-triphenylamine, pyrenediphenylamine, pyrene-N, N-dibenzylaniline systems in various solvents have been investigated. In nonpolar solvent, pyrene-triphenylamine exciplex and pyrene-N, N-dibenzylaniline exciplex were observed directly. In acetonitrile, the pyrene anion radical, triphenylamine and diphenylamine cation radicals were detected. On the basis of the present experimental facts, the mechanism of fluorescence quenching processes of pyrene in polar and nonpolar solvents has been established.
文摘Purple membrane, molecular weight 26ku, is synthesized by Holobacterium halobium on some parts of its cell membrane under a special condition combined by 248 residues,and 7 times acrossing membrane. Only one kind of protein, bacteriorhodopsin (BR), is on the membrane. After light excitation, BR goes through a series of intermediate processes K, L, M, N, O and recovers to BR. Purple membrane is an ideal biomaterial for photo energy transfer, and becomes a new focus field of many branches of science. Because the photocycle of BR is related to light-driven proton pump and photoelectric response,
基金Project supported by the National Natural Science Foundation of China(Grant No.11304409)the Natural Science Foundation of Chongqing City,China(Grant No.CSTC2013jcyj A4004)+1 种基金the Scientific and Technological Research Program of Chongqing Municipal Education Commission,China(Grant No.KJ1500422)the Special Theme Projects on LCD Industrial Generic Technology Innovation of Chongqing City,China(Grant No.CSTC2015zdcyztzx40003)
文摘We demonstrated a 2-μm passively mode-locked nanosecond fiber laser based on a MoS2 saturable absorber（SA）.Owing to the effect of nonlinear absorption in the MoS2 SA, the pulse width decreased from 64.7 to 13.8 ns with increasing pump power from 1.10 to 1.45 W. The use of a narrow-bandwidth fiber Bragg grating resulted in a central wavelength and 3-dB spectral bandwidth of 2010.16 and 0.15 nm, respectively. Experimental results show that MoS2 is a promising material for a 2-μm mode-locked fiber laser.
