Gold and atomically precise polyoxometalates(POMs)are widely used materials with electron reservoir redox properties.The combination of optically excited gold nanoparticles,gold surface/tip electrodes,or molecular gol...Gold and atomically precise polyoxometalates(POMs)are widely used materials with electron reservoir redox properties.The combination of optically excited gold nanoparticles,gold surface/tip electrodes,or molecular gold(I)complexes with{V_(6)^(V)}Lindqvist-,{MnMo_(6)^(VI)}Anderson-Evans-,and{PW_(12)^(VI)}Keggin-type POM structures leads to interfacial multielectron transformations with far-reaching implications for electronics,photonics,biomedical diagnostics,and catalysis.展开更多
基金supported by the Deutsche Forschungsgemeinschaft(DFG)through the SPP 2262 program MemrisTec(Memristive Devices Toward Smart Technical Systems).Project number 536022773(2DPOMristor).
文摘Gold and atomically precise polyoxometalates(POMs)are widely used materials with electron reservoir redox properties.The combination of optically excited gold nanoparticles,gold surface/tip electrodes,or molecular gold(I)complexes with{V_(6)^(V)}Lindqvist-,{MnMo_(6)^(VI)}Anderson-Evans-,and{PW_(12)^(VI)}Keggin-type POM structures leads to interfacial multielectron transformations with far-reaching implications for electronics,photonics,biomedical diagnostics,and catalysis.
