In this investigation, polymeric nanocomposite membranes（PNMs） were prepared via incorporating zinc oxide（ZnO） into poly（ether-block-amide）(PEBAX-1074) polymer matrix with different loadings. The neat membrane a...In this investigation, polymeric nanocomposite membranes（PNMs） were prepared via incorporating zinc oxide（ZnO） into poly（ether-block-amide）(PEBAX-1074) polymer matrix with different loadings. The neat membrane and nanocomposite membranes were prepared via solution casting and solution blending methods, respectively. The fabricated membranes were characterized by field emission scanning electron microscopy（FESEM） to survey cross-sectional morphologies and thermal gravimetric analysis（TGA）to study thermal stability. Fourier transform infrared（FT-IR） and X-ray diffraction（XRD） analyses were also employed to identify variations of the chemical bonds and crystal structure of the membranes, respectively. Permeation of pure gases, CO, CHand Nthrough the prepared neat and nanocomposite membranes was studied at pressures of 3–18 bar and temperature of 25 °C. The obtained results showed that the fabricated nanocomposite membranes exhibit better separation performance compared to the neat PEBAX membrane in terms of both permeability and selectivity. As an example, at temperature of 25 °C and pressure of 3 bar, COpermeability, ideal CO/CHand CO/Nselectivity values for the neat PEBAX membrane are 110.67 Barrer, 11.09 and 50.08, respectively, while those values are 152.27 Barrer,13.52 and 62.15 for PEBAX/ZnO nanocomposite membrane containing 8 wt% ZnO.展开更多
In this work, a series of Cu2O-Ag/ZnO, Cu2O/ZnO and Ag/ZnO nanocomposites with various compositions were prepared via a hydrothermal method followed by chemical modification, and their antibacterial performance was in...In this work, a series of Cu2O-Ag/ZnO, Cu2O/ZnO and Ag/ZnO nanocomposites with various compositions were prepared via a hydrothermal method followed by chemical modification, and their antibacterial performance was investigated in detail. X-ray powder diffraction, scanning electron microscopy and transmission electron microscopy results confirmed that 31 nm Cu20 and 30 nm Ag nanoparticles are well-dispersed on 202 nm ZnO grains to form a Cu2O/ZnO and Ag/ZnO heterojunction, respectively. The bi-heterojuction structure in the Cu20-Ag/ZnO provided a synergistic effect on antibacterial activity, and the(Cu2O)0.04Ag0.06ZnO0.9nanocomposites showed the highest antimicrobial activity of all samples with minimum inhibitory concentration and minimum bactericidal concentration against Escherichia coli and Staphylococcus aureus as low to 31.25 μg/mL, 250μg/mL, 125μg/mL and 500μg/mL, respectively. This is the first report of the antibacterial activities of Cu2O and Ag co-modified ZnO nanocomposites.展开更多
In order to achieve effective, economic, and easily achievable photocatalyst for the degradation of dye methyl orange（MeO）, ZnO, ZnO/ZnS and ZnO/ZnS/α-Fe2O3 nanocomposites were prepared by simple chemical synthetic...In order to achieve effective, economic, and easily achievable photocatalyst for the degradation of dye methyl orange（MeO）, ZnO, ZnO/ZnS and ZnO/ZnS/α-Fe2O3 nanocomposites were prepared by simple chemical synthetic route in the aqueous medium. Phase, crystallinity, surface structure and surface behavior of the synthesized materials were determined by X-ray diffraction（XRD） and Brunauer-Emmett-Teller analysis（BET） techniques. XRD study established formation of good crystalline ZnO, ZnO/ZnS and ZnO/ZnS/α-Fe2O3 nanomaterials. By using intensity of constituent peaks in the XRD pattern, the compositions of nanocomposites were determined. From the BET analysis, the prepared materials show mesoporous behavior, type Ⅳ curves along with H4 hysteresis. The ZnO/ZnS/α-Fe2O3 composite shows the largest surface area among three materials. From the UV-visible spectra, the band gap energy of the materials was determined. Photoluminescence spectra（PL） were used to determine the emission behavior and surface defects in the materials. In PL spectra, the intensity of UV peak of ZnO/ZnS is lowered than that of ZnO while in case of ZnO/ZnS/α-Fe2O3, the intensity further decreased. The visible emission spectra of ZnO/ZnS increased compared with ZnO while in ZnO/ZnS/α-Fe2O3 it is further increased compared with ZnO/ZnS. The as-synthesized materials were used as photocatalysts for the degradation of dye MeO. The photo-degradation data revealed that the ZnO/ZnS/α-Fe2O3 is the best photocatalyst among three specimens for the degradation of dye MeO. The decrease of intensity of UV emission peak and the increase of intensity of visible emission cause the decrease of recombination of electrons and holes which are ultimately responsible for the highest photocatalytic activity of ZnO/ZnS/α-Fe2O3.展开更多
A series of nanosized CeO2-Fe2O3 mixed-oxide nanocomposites with different Ce4+/Fe3+molar ratios were successfully prepared by a co-precipitation technique.The surface area increased with Fe2O3 content increasing up t...A series of nanosized CeO2-Fe2O3 mixed-oxide nanocomposites with different Ce4+/Fe3+molar ratios were successfully prepared by a co-precipitation technique.The surface area increased with Fe2O3 content increasing up to 60 wt%in the composite.However,with further increase in Fe2O3 content,the surface area began to decrease.The reduction processes of the CeO2-Fe2O3 nanocomposites were studied in a hydrogen atmosphere at 300-600℃.The reduction rates increased by increasing both the temperature and Fe2O3 content in the nanocomposites.The microstructure of the reduced composites at 500℃illustrated the presence of a considerable number of macro-and micro-pores.The activation energy values were calculated which were in the range of 3.56-5.37 kJ mol-1 at the initial stages(up to 35%reduction)and 5.21-10.2 kJ·mol-1 at the final stages(up to 80%reduction)of reduction.The rate-controlling mechanisms in both the initial and final reduction stages were determined,and the initial reaction stage was controlled by combined gaseous diffusion and interfacial chemical reaction mechanisms for all the composites except for pure CeO2,which was controlled by a chemical reaction mechanism.The final reaction stage was controlled by a gaseous diffusion mechanism for some composites,while for the others it was controlled by combined gaseous diffusion and interfacial chemical reaction mechanisms.The hydrogen sorption properties of the nanocomposites were studied by pressure composition isotherms using a volumetric method.Hydrogen storage in the nanocomposites increased by increasing the temperature because of the formation of oxygen vacancies which enhance atomic H adsorption and function as strong adsorption sites forming more metal hydride covalent bonds.展开更多
Zinc oxide/low-density polyethylene （LDPE） nanocomposites were prepared for intrauterine devices. The change of Zn^2＋ release rates of nanocomposites （ doped with various mass fractions of zinc oxide nanoparticles...Zinc oxide/low-density polyethylene （LDPE） nanocomposites were prepared for intrauterine devices. The change of Zn^2＋ release rates of nanocomposites （ doped with various mass fractions of zinc oxide nanoparticles between 5wt% and 65 wt% ） for 264 days in a simulated uterine solution were investigated. The resuits show that initial burst phases are followed by near zero-order release phases. SEM technique was employed to observe the surface morphology of the 45wt% ZnO/ LDPE composite. Elements and phases on the surface of the nanocomposite after incubation were also analyzed by EDX and XRD respectively. The experimental results show that incrustation formation does not occur after incubation.展开更多
Europium doped ZnO/SnO2 nanocomposite phosphors were synthesized via room temperature co-precipitation method. In this work structural changes, optical properties and the associated photoluminescence response were inv...Europium doped ZnO/SnO2 nanocomposite phosphors were synthesized via room temperature co-precipitation method. In this work structural changes, optical properties and the associated photoluminescence response were investigated for different compositions of ZnO and SnO2 activated with Eu3＋ ions. The prepared samples were systematically characterized by means of X-ray diffraction （XRD）, Fourier transform infrared spectroscopy （FTIR）, field emission scanning electron microscopy for obtaining the structural information about the prepared materials. Diffuse reflectance （DR） UV-Vis spectrometer and photoluminescence （PL） spectroscopy technique were employed for studying the optical properties of prepared materials. XRD results confirmed the presence of both phases, hexagonal ZnO as well as tetragonal SnO2 simultaneously and further using Debye Scherrer＇s and Hall-Williamson relations, crystallite size were estimated and it was found to be in the range of 8-14 nm. The FTIR studies revealed the presence of different stretching and bending modes of Zn-O and Sn-O with an additional stretching and bending vibration of absorbed water （O-H） molecules. FESEM images suggested that the particle size lied in the range of 50 to 70 nm, which were almost spherical in shapes. A long range multi colour emission from blue to red region was observed for the 320 nm excitation wavelength. The observed emission involved sharp emission due to 5D0→7F1 transition that corresponded to the magnetic dipole transition. The study showed that the Eu3＋ doped nanocomposite was more suitable material than singly Eu3＋ doped ZnO and Eu3＋ doped SnO2 with enhanced opto-eleetronic and luminescence properties and potential applications in display devices.展开更多
A simple, mild and green approach has been developed for the synthesis of asymmetrical heterobiaryls under the irradiation of visible light without any oxidants and promoting reagents through using Pd/Ce O2 nanocompos...A simple, mild and green approach has been developed for the synthesis of asymmetrical heterobiaryls under the irradiation of visible light without any oxidants and promoting reagents through using Pd/Ce O2 nanocomposite photocatalyst. This method can tolerate considerable functional groups such as electrondonating groups and electron-withdrawing groups through CààC cross-coupling. Moreover, we obtain the products with moderate yields in an efficient way. Finally, a plausible mechanism is proposed.展开更多
TiO_(2)-ZnO nanocomposites were synthesized by varying Ti:Zn molar ratio from 1:0.1(TZ-1:0.1)to 1:1(TZ-1:1).With increase in Zn content,from TZ-1:0.1 to TZ-1:0.2,anatase transformed to rutile phase.TZ-1:0.3,which cont...TiO_(2)-ZnO nanocomposites were synthesized by varying Ti:Zn molar ratio from 1:0.1(TZ-1:0.1)to 1:1(TZ-1:1).With increase in Zn content,from TZ-1:0.1 to TZ-1:0.2,anatase transformed to rutile phase.TZ-1:0.3,which contained a blend of phases,including rutile and anatase TiO_(2),ZnO,and zinc titanates,exhibited the narrowest bandgap(2.5±0.1 e V),and showed the highest photocatalytic activity.TZ-1:1 was predominated by zinc titanates.All the nanocomposites exhibited narrower bandgaps compared to pure TiO_(2)nanoparticles,facilitating visible light activity.This study was designed to explore whether a method targeting the removal of a specific crystalline phase(anatase)influenced the properties and photocatalytic activity of the nanocomposite.Selective dissolution not only removed anatase phase,but also led to significant loss of crystallinity,widened the bandgap,and adversely affected photocatalytic performance,in nanocomposites that contained>80%anatase phase(TZ-1:0.1 and TZ-1:0.2).However,in nanocomposites that contained less of anatase phase(TZ-1:0.3and TZ-1:1),the morphology,bandgap,crystallinity,and the extent of photocatalytic activity at the end of 240 min remained largely unaffected.Photocatalytic activity in TZ-1:0.3 and TZ-1:1 originated from a blend of phases comprising of less photocatalytically active phases,such as rutile TiO_(2),Zn TiO3,and Zn2TiO4,rather than from the anatase phase.The Ti:Zn molar ratio controlled the phases present in TiO_(2)-ZnO nanocomposites,which,in turn,controlled the physicochemical properties and visible light activity.Thus,in nanocomposites that contained a mix of several phases,the properties and photocatalytic activity were not dependent on anatase phase.展开更多
采用柠檬酸为络合剂,溶胶-凝胶法制备系列CeO_2-CuO/ZnO/Al_2O_3,在3.0 MPa压力和220~230℃反应条件下,甲苯二胺(TDA)和乙烯催化合成二乙基甲苯二胺(DETDA)为探针反应,考察其催化性能,其中CeO_2掺杂量为3%,催化活性最高。通过X射线衍射(...采用柠檬酸为络合剂,溶胶-凝胶法制备系列CeO_2-CuO/ZnO/Al_2O_3,在3.0 MPa压力和220~230℃反应条件下,甲苯二胺(TDA)和乙烯催化合成二乙基甲苯二胺(DETDA)为探针反应,考察其催化性能,其中CeO_2掺杂量为3%,催化活性最高。通过X射线衍射(XRD)、傅里叶红外光谱(FT-IR)、差热重量分析法(DTG-DTA)、核磁氢谱1 H NMR对CeO_2-CuO/ZnO/Al_2O_3、DETDA、TDA进行检测和表征,揭示了它们的微观结构和内在规律性。XRD检测发现CeO_2掺杂量增多,CeO_2-CuO/ZnO/Al_2O_3衍射峰强度增强,提高了晶化程度,金属原子存在协同效应,增多了活性中心。FT-IR揭示了DETDA内部化学键键型,拥有甲基、亚甲基的多取代芳胺。DTG-DTA检测出的质量变化与热效应两种信息,DETDA的DTG-DTA曲线在66.0、271.0℃存在二个吸热峰,分别为氨基脱离苯环、DETDA的分解产生。通过1 H NMR对DETDA、TDA检测,得到DETDA、TDA的氢原子的数目分别为18和10,分子中各个氢核对应所归属的吸收峰,分别和它们分子式中的氢原子数目吻合。CeO_2-CuO/ZnO/Al_2O_3催化合成DETDA,反应条件温和,工艺流程简单,容易实现高效率和连续化工业生产,因此具有广阔的发展前景。展开更多
文摘In this investigation, polymeric nanocomposite membranes（PNMs） were prepared via incorporating zinc oxide（ZnO） into poly（ether-block-amide）(PEBAX-1074) polymer matrix with different loadings. The neat membrane and nanocomposite membranes were prepared via solution casting and solution blending methods, respectively. The fabricated membranes were characterized by field emission scanning electron microscopy（FESEM） to survey cross-sectional morphologies and thermal gravimetric analysis（TGA）to study thermal stability. Fourier transform infrared（FT-IR） and X-ray diffraction（XRD） analyses were also employed to identify variations of the chemical bonds and crystal structure of the membranes, respectively. Permeation of pure gases, CO, CHand Nthrough the prepared neat and nanocomposite membranes was studied at pressures of 3–18 bar and temperature of 25 °C. The obtained results showed that the fabricated nanocomposite membranes exhibit better separation performance compared to the neat PEBAX membrane in terms of both permeability and selectivity. As an example, at temperature of 25 °C and pressure of 3 bar, COpermeability, ideal CO/CHand CO/Nselectivity values for the neat PEBAX membrane are 110.67 Barrer, 11.09 and 50.08, respectively, while those values are 152.27 Barrer,13.52 and 62.15 for PEBAX/ZnO nanocomposite membrane containing 8 wt% ZnO.
基金supported in part by the National Natural Science Foundation of China(Grant Nos.51677120 and 51207093)the Shenzhen Government Fund(Grant Nos.JCYJ20160422102919963)the Shenzhen Key Laboratory of Special Functional Materials(Grant Nos.T201502)
文摘In this work, a series of Cu2O-Ag/ZnO, Cu2O/ZnO and Ag/ZnO nanocomposites with various compositions were prepared via a hydrothermal method followed by chemical modification, and their antibacterial performance was investigated in detail. X-ray powder diffraction, scanning electron microscopy and transmission electron microscopy results confirmed that 31 nm Cu20 and 30 nm Ag nanoparticles are well-dispersed on 202 nm ZnO grains to form a Cu2O/ZnO and Ag/ZnO heterojunction, respectively. The bi-heterojuction structure in the Cu20-Ag/ZnO provided a synergistic effect on antibacterial activity, and the(Cu2O)0.04Ag0.06ZnO0.9nanocomposites showed the highest antimicrobial activity of all samples with minimum inhibitory concentration and minimum bactericidal concentration against Escherichia coli and Staphylococcus aureus as low to 31.25 μg/mL, 250μg/mL, 125μg/mL and 500μg/mL, respectively. This is the first report of the antibacterial activities of Cu2O and Ag co-modified ZnO nanocomposites.
文摘In order to achieve effective, economic, and easily achievable photocatalyst for the degradation of dye methyl orange（MeO）, ZnO, ZnO/ZnS and ZnO/ZnS/α-Fe2O3 nanocomposites were prepared by simple chemical synthetic route in the aqueous medium. Phase, crystallinity, surface structure and surface behavior of the synthesized materials were determined by X-ray diffraction（XRD） and Brunauer-Emmett-Teller analysis（BET） techniques. XRD study established formation of good crystalline ZnO, ZnO/ZnS and ZnO/ZnS/α-Fe2O3 nanomaterials. By using intensity of constituent peaks in the XRD pattern, the compositions of nanocomposites were determined. From the BET analysis, the prepared materials show mesoporous behavior, type Ⅳ curves along with H4 hysteresis. The ZnO/ZnS/α-Fe2O3 composite shows the largest surface area among three materials. From the UV-visible spectra, the band gap energy of the materials was determined. Photoluminescence spectra（PL） were used to determine the emission behavior and surface defects in the materials. In PL spectra, the intensity of UV peak of ZnO/ZnS is lowered than that of ZnO while in case of ZnO/ZnS/α-Fe2O3, the intensity further decreased. The visible emission spectra of ZnO/ZnS increased compared with ZnO while in ZnO/ZnS/α-Fe2O3 it is further increased compared with ZnO/ZnS. The as-synthesized materials were used as photocatalysts for the degradation of dye MeO. The photo-degradation data revealed that the ZnO/ZnS/α-Fe2O3 is the best photocatalyst among three specimens for the degradation of dye MeO. The decrease of intensity of UV emission peak and the increase of intensity of visible emission cause the decrease of recombination of electrons and holes which are ultimately responsible for the highest photocatalytic activity of ZnO/ZnS/α-Fe2O3.
文摘A series of nanosized CeO2-Fe2O3 mixed-oxide nanocomposites with different Ce4+/Fe3+molar ratios were successfully prepared by a co-precipitation technique.The surface area increased with Fe2O3 content increasing up to 60 wt%in the composite.However,with further increase in Fe2O3 content,the surface area began to decrease.The reduction processes of the CeO2-Fe2O3 nanocomposites were studied in a hydrogen atmosphere at 300-600℃.The reduction rates increased by increasing both the temperature and Fe2O3 content in the nanocomposites.The microstructure of the reduced composites at 500℃illustrated the presence of a considerable number of macro-and micro-pores.The activation energy values were calculated which were in the range of 3.56-5.37 kJ mol-1 at the initial stages(up to 35%reduction)and 5.21-10.2 kJ·mol-1 at the final stages(up to 80%reduction)of reduction.The rate-controlling mechanisms in both the initial and final reduction stages were determined,and the initial reaction stage was controlled by combined gaseous diffusion and interfacial chemical reaction mechanisms for all the composites except for pure CeO2,which was controlled by a chemical reaction mechanism.The final reaction stage was controlled by a gaseous diffusion mechanism for some composites,while for the others it was controlled by combined gaseous diffusion and interfacial chemical reaction mechanisms.The hydrogen sorption properties of the nanocomposites were studied by pressure composition isotherms using a volumetric method.Hydrogen storage in the nanocomposites increased by increasing the temperature because of the formation of oxygen vacancies which enhance atomic H adsorption and function as strong adsorption sites forming more metal hydride covalent bonds.
文摘Zinc oxide/low-density polyethylene （LDPE） nanocomposites were prepared for intrauterine devices. The change of Zn^2＋ release rates of nanocomposites （ doped with various mass fractions of zinc oxide nanoparticles between 5wt% and 65 wt% ） for 264 days in a simulated uterine solution were investigated. The resuits show that initial burst phases are followed by near zero-order release phases. SEM technique was employed to observe the surface morphology of the 45wt% ZnO/ LDPE composite. Elements and phases on the surface of the nanocomposite after incubation were also analyzed by EDX and XRD respectively. The experimental results show that incrustation formation does not occur after incubation.
基金supported by ISM research scholars funding by Government of India
文摘Europium doped ZnO/SnO2 nanocomposite phosphors were synthesized via room temperature co-precipitation method. In this work structural changes, optical properties and the associated photoluminescence response were investigated for different compositions of ZnO and SnO2 activated with Eu3＋ ions. The prepared samples were systematically characterized by means of X-ray diffraction （XRD）, Fourier transform infrared spectroscopy （FTIR）, field emission scanning electron microscopy for obtaining the structural information about the prepared materials. Diffuse reflectance （DR） UV-Vis spectrometer and photoluminescence （PL） spectroscopy technique were employed for studying the optical properties of prepared materials. XRD results confirmed the presence of both phases, hexagonal ZnO as well as tetragonal SnO2 simultaneously and further using Debye Scherrer＇s and Hall-Williamson relations, crystallite size were estimated and it was found to be in the range of 8-14 nm. The FTIR studies revealed the presence of different stretching and bending modes of Zn-O and Sn-O with an additional stretching and bending vibration of absorbed water （O-H） molecules. FESEM images suggested that the particle size lied in the range of 50 to 70 nm, which were almost spherical in shapes. A long range multi colour emission from blue to red region was observed for the 320 nm excitation wavelength. The observed emission involved sharp emission due to 5D0→7F1 transition that corresponded to the magnetic dipole transition. The study showed that the Eu3＋ doped nanocomposite was more suitable material than singly Eu3＋ doped ZnO and Eu3＋ doped SnO2 with enhanced opto-eleetronic and luminescence properties and potential applications in display devices.
文摘A simple, mild and green approach has been developed for the synthesis of asymmetrical heterobiaryls under the irradiation of visible light without any oxidants and promoting reagents through using Pd/Ce O2 nanocomposite photocatalyst. This method can tolerate considerable functional groups such as electrondonating groups and electron-withdrawing groups through CààC cross-coupling. Moreover, we obtain the products with moderate yields in an efficient way. Finally, a plausible mechanism is proposed.
基金provided by Department of Science and Technology,New Delhi,India,under the Water Technology Initiative(WTI)scheme(Project code:DST/TM/WTI/2K15/101(G)).
文摘TiO_(2)-ZnO nanocomposites were synthesized by varying Ti:Zn molar ratio from 1:0.1(TZ-1:0.1)to 1:1(TZ-1:1).With increase in Zn content,from TZ-1:0.1 to TZ-1:0.2,anatase transformed to rutile phase.TZ-1:0.3,which contained a blend of phases,including rutile and anatase TiO_(2),ZnO,and zinc titanates,exhibited the narrowest bandgap(2.5±0.1 e V),and showed the highest photocatalytic activity.TZ-1:1 was predominated by zinc titanates.All the nanocomposites exhibited narrower bandgaps compared to pure TiO_(2)nanoparticles,facilitating visible light activity.This study was designed to explore whether a method targeting the removal of a specific crystalline phase(anatase)influenced the properties and photocatalytic activity of the nanocomposite.Selective dissolution not only removed anatase phase,but also led to significant loss of crystallinity,widened the bandgap,and adversely affected photocatalytic performance,in nanocomposites that contained>80%anatase phase(TZ-1:0.1 and TZ-1:0.2).However,in nanocomposites that contained less of anatase phase(TZ-1:0.3and TZ-1:1),the morphology,bandgap,crystallinity,and the extent of photocatalytic activity at the end of 240 min remained largely unaffected.Photocatalytic activity in TZ-1:0.3 and TZ-1:1 originated from a blend of phases comprising of less photocatalytically active phases,such as rutile TiO_(2),Zn TiO3,and Zn2TiO4,rather than from the anatase phase.The Ti:Zn molar ratio controlled the phases present in TiO_(2)-ZnO nanocomposites,which,in turn,controlled the physicochemical properties and visible light activity.Thus,in nanocomposites that contained a mix of several phases,the properties and photocatalytic activity were not dependent on anatase phase.
基金National Natural Science Foundation of China(21076206)Natural Basic Research Program of China(973 Program,2010CB732302)National High Technology Research and Development Program(863 Program,2011AA050706)
文摘采用柠檬酸为络合剂,溶胶-凝胶法制备系列CeO_2-CuO/ZnO/Al_2O_3,在3.0 MPa压力和220~230℃反应条件下,甲苯二胺(TDA)和乙烯催化合成二乙基甲苯二胺(DETDA)为探针反应,考察其催化性能,其中CeO_2掺杂量为3%,催化活性最高。通过X射线衍射(XRD)、傅里叶红外光谱(FT-IR)、差热重量分析法(DTG-DTA)、核磁氢谱1 H NMR对CeO_2-CuO/ZnO/Al_2O_3、DETDA、TDA进行检测和表征,揭示了它们的微观结构和内在规律性。XRD检测发现CeO_2掺杂量增多,CeO_2-CuO/ZnO/Al_2O_3衍射峰强度增强,提高了晶化程度,金属原子存在协同效应,增多了活性中心。FT-IR揭示了DETDA内部化学键键型,拥有甲基、亚甲基的多取代芳胺。DTG-DTA检测出的质量变化与热效应两种信息,DETDA的DTG-DTA曲线在66.0、271.0℃存在二个吸热峰,分别为氨基脱离苯环、DETDA的分解产生。通过1 H NMR对DETDA、TDA检测,得到DETDA、TDA的氢原子的数目分别为18和10,分子中各个氢核对应所归属的吸收峰,分别和它们分子式中的氢原子数目吻合。CeO_2-CuO/ZnO/Al_2O_3催化合成DETDA,反应条件温和,工艺流程简单,容易实现高效率和连续化工业生产,因此具有广阔的发展前景。
