Metamaterials,owing to their exceptional physical characteristics that are absent in natural materials,have emerged as a crucial constituent of intelligent devices and systems.However,there are still significant chall...Metamaterials,owing to their exceptional physical characteristics that are absent in natural materials,have emerged as a crucial constituent of intelligent devices and systems.However,there are still significant challenges that necessitate immediate attention,as they have considerably constrained the applicability of metamaterials,including fixed mechanical properties post-fabrication and restricted design freedom.Here,thermo-responsive,photo-responsive,electro-responsive,and magneto-responsive shape memory polymer nano-composites were developed,and shape memory gradient metamaterials were fabricated using multi-material 4D printing technology.The correlation mechanism between the design parameters and the mechanical properties of multi-responsive gradient metamaterials was systematically analyzed,and the highly designable and programmable configuration and mechanical properties of the gradient metamaterials were realized.More importantly,4D printed multi-responsive shape memory polymer gradient metamaterials can be programmed in situ without additional infrastructure for multi-functional mechanical functions,paving the way for the realization of multiple functions of a single structure.Based on the multi-responsive gradient metamaterials,4D printed digital pixel metamaterial intelligent information carriers were fabricated,featuring customizable encryption and decryption protocols,exceptional scalability,and reusability.Additionally,4D printed gradient metamaterial logic gate electronic devices were developed,which were anticipated to contribute to the development of smart,adaptable robotic systems that combine sensing,actuation,and decision-making capabilities.展开更多
Four-dimensional(4D)printing represents a groundbreaking advancement in manufacturing,yet a persistent challenge is the limited number of stable configurations achievable through spontaneous shape reconstruction.Herei...Four-dimensional(4D)printing represents a groundbreaking advancement in manufacturing,yet a persistent challenge is the limited number of stable configurations achievable through spontaneous shape reconstruction.Herein,we present a novel 4D printing mechanism that utilizes self-adjustable gas pressure to facilitate a wide range of spontaneous and stable multi-shape transformations.The gas is precisely released at designated spatial locations through strategic temperature-controlled degradation of a solid material,which is printed and distributed as needed at the voxel level within a specially designed multi-material structure,consisting of a low degradation temperature material(LDTM),a high degradation temperature soft material(HDTSM),and a high degradation temperature hard material(HDTHM).Each shape configuration is determined and locked in by the maximum temperature experienced during its thermal history.Notably,this shape retains its form robustly,independently of subsequent temperature changes,until a higher temperature threshold is reached,at which point a new shape configuration is triggered.These shapes exhibit a remarkable temperature memory effect,permanently recording the peak temperature reached in their thermal history.Our study comprehensively investigates the underlying principles and key parameters that influence deformation.We present a series of examples demonstrating complex multi-shape transformations modulated by temperature,supported by finite element simulations.This advance in 4D printing has the potential to significantly enhance its functional capabilities,performance,and applicability,opening up new horizons in additive manufacturing and design.展开更多
In this paper, we consider the problem of irregular shapes tracking for multiple extended targets by introducing the Gaussian surface matrix（GSM） into the framework of the random finite set（RFS） theory. The Gaussi...In this paper, we consider the problem of irregular shapes tracking for multiple extended targets by introducing the Gaussian surface matrix（GSM） into the framework of the random finite set（RFS） theory. The Gaussian surface function is constructed first by the measurements, and it is used to define the GSM via a mapping function. We then integrate the GSM with the probability hypothesis density（PHD） filter, the Bayesian recursion formulas of GSM-PHD are derived and the Gaussian mixture implementation is employed to obtain the closed-form solutions. Moreover, the estimated shapes are designed to guide the measurement set sub-partition, which can cope with the problem of the spatially close target tracking. Simulation results show that the proposed algorithm can effectively estimate irregular target shapes and exhibit good robustness in cross extended target tracking.展开更多
Multi-wall carbon nanotube filled shape memory polymer composite(MWCNT/SMC)possessed enhanced modulus,strength,and electric conductivity,as well as excellent electrothermal shape memory properties,showing wide design ...Multi-wall carbon nanotube filled shape memory polymer composite(MWCNT/SMC)possessed enhanced modulus,strength,and electric conductivity,as well as excellent electrothermal shape memory properties,showing wide design scenarios and engineering application prospects.The thermoelectrically triggered shape memory process contains complex multi-physical mechanisms,especially when coupled with finite deformation rooted on micro-mechanisms.A multi-physical finite deformation model is necessary to get a deep understanding on the coupled electro-thermomechanical properties of electrothermal shape memory composites(ESMCs),beneficial to its design and wide application.Taking into consideration of micro-physical mechanisms of the MWCNTs interacting with double-chain networks,a finite deformation theoretical model is developed in this work based on two superimposed network chains of physically crosslinked network formed among MWCNTs and the chemically crosslinked network.An intact crosslinked chemical network is considered featuring with entropic-hyperelastic properties,superimposed with a physically crosslinked network where percolation theory is based on electric conductivity and electric-heating mechanisms.The model is calibrated by experiments and used for shape recoveries triggered by heating and electric fields.It captures the coupled electro-thermomechanical behavior of ESMCs and provides design guidelines for MWCNTs filled shape memory polymers.展开更多
The plasma screening of fast-electron-impact-ionization by excited state（3p） of Hydrogen-like ions was investigated in the first Born approximation with a plasma screening length δ varying from 1000a0 to 10a0. The ...The plasma screening of fast-electron-impact-ionization by excited state（3p） of Hydrogen-like ions was investigated in the first Born approximation with a plasma screening length δ varying from 1000a0 to 10a0. The generalized oscillator strength densities showed dramatic changes： some accessional minima occurred along with a remarkable enhancement in certain continuum-energy domains. The double-differential cross sections exhibit not only the same structures as the Bethe surface for moderate and large momentum transfers, but also a broadened enhancement for small momentum transfers.The single-differential cross sections exhibit a near-zero-energy-enhancement and prodigious multiple-shape resonances,depending on the continuum energy and the plasma screening length. These features are analogous to those of the photoionization cross section. These findings, for both types of cross section, can be explained by processes associated with continuum electrons, as long as the potential has a short-range character.展开更多
We propose and simulate a method for generating a three-dimensional （3D） optical cage in the vicinity of focus by focusing a double-ring shaped radially and azimuthally polarized beam. Our study shows that the combi...We propose and simulate a method for generating a three-dimensional （3D） optical cage in the vicinity of focus by focusing a double-ring shaped radially and azimuthally polarized beam. Our study shows that the combination of an inner ring with an azimuthally polarized field and an outer ring with a radially polarized field and a phase factor can produce an optical cage with a dark region enclosed by higher intensity. The shape of the cage can be tailored by appropriately adjusting the parameters of double-mode beams. Furthermore, multiple 3D optical cages can be realized by applying the shift theorem of the Fourier transform and macro-pixel sampling algorithm to a double-ring shaped radially and azimuthally polarized beam.展开更多
To change the situation of shape memory polymers(SMPs)that can only remember very few shapes and enable discretional morphing for practical application,the authors report a reversible stepless multiple SMP derived fro...To change the situation of shape memory polymers(SMPs)that can only remember very few shapes and enable discretional morphing for practical application,the authors report a reversible stepless multiple SMP derived from ultrahigh molecular weight polyethylene(UHMWPE).As the crystals of semicrystalline polymers are assembled by those with slightly different melting temperatures,and each type of crystal can remember a single shape,the crystalline region of UHMWPE is allowed to remember plenty of temporary shapes after programming.Changing the temperature of the programmed polymer within the melting/crystallization temperature ranges would lead to releasing/recovery of the memorized temporary shapes.Accordingly,multiple shape memory effects can be easily realized without an elaborate design of material structure and training process in advance as before.The temperaturedependent adjustability of the analog capacitor and soft lens with embedded programmed UHMWPE as actuators,characterized by the continuous/random/proportional responsivity,further reveals the utilization prospects of the controllable reversible stepless discretionary morphing effect.Moreover,the maximum work density of the programmed UHMWPE is found to be 210 kJ/m_(3),which is more than 10 times of piezoelectric ceramics,so that it can serve as a proof-of-concept mechanical driver for reversibly pumping of ethanediol-droplet upon heating/cooling.展开更多
基金supported by the National Key R&D Program of China(2022YFB3805700)the National Natural Science Foundation of China(Grant No.12302198)+2 种基金China Postdoctoral Science Foundation(2022M720042)Heilongjiang Postdoctoral Science Foundation(LBH-Z22016)Key Project of Heilongjiang Provincial Department of Science and Technology(2022ZX02C25).
文摘Metamaterials,owing to their exceptional physical characteristics that are absent in natural materials,have emerged as a crucial constituent of intelligent devices and systems.However,there are still significant challenges that necessitate immediate attention,as they have considerably constrained the applicability of metamaterials,including fixed mechanical properties post-fabrication and restricted design freedom.Here,thermo-responsive,photo-responsive,electro-responsive,and magneto-responsive shape memory polymer nano-composites were developed,and shape memory gradient metamaterials were fabricated using multi-material 4D printing technology.The correlation mechanism between the design parameters and the mechanical properties of multi-responsive gradient metamaterials was systematically analyzed,and the highly designable and programmable configuration and mechanical properties of the gradient metamaterials were realized.More importantly,4D printed multi-responsive shape memory polymer gradient metamaterials can be programmed in situ without additional infrastructure for multi-functional mechanical functions,paving the way for the realization of multiple functions of a single structure.Based on the multi-responsive gradient metamaterials,4D printed digital pixel metamaterial intelligent information carriers were fabricated,featuring customizable encryption and decryption protocols,exceptional scalability,and reusability.Additionally,4D printed gradient metamaterial logic gate electronic devices were developed,which were anticipated to contribute to the development of smart,adaptable robotic systems that combine sensing,actuation,and decision-making capabilities.
基金support from the Shenzhen Science and Technology Innovation Commission(Grant No.JCYJ20200109115439775 and JCYJ20230807140459034)Guangdong Basic and Applied Basic Research Foundation(Grant No.2022A1515012645)National Natural Science Foundation of China(Grant No.11872369).
文摘Four-dimensional(4D)printing represents a groundbreaking advancement in manufacturing,yet a persistent challenge is the limited number of stable configurations achievable through spontaneous shape reconstruction.Herein,we present a novel 4D printing mechanism that utilizes self-adjustable gas pressure to facilitate a wide range of spontaneous and stable multi-shape transformations.The gas is precisely released at designated spatial locations through strategic temperature-controlled degradation of a solid material,which is printed and distributed as needed at the voxel level within a specially designed multi-material structure,consisting of a low degradation temperature material(LDTM),a high degradation temperature soft material(HDTSM),and a high degradation temperature hard material(HDTHM).Each shape configuration is determined and locked in by the maximum temperature experienced during its thermal history.Notably,this shape retains its form robustly,independently of subsequent temperature changes,until a higher temperature threshold is reached,at which point a new shape configuration is triggered.These shapes exhibit a remarkable temperature memory effect,permanently recording the peak temperature reached in their thermal history.Our study comprehensively investigates the underlying principles and key parameters that influence deformation.We present a series of examples demonstrating complex multi-shape transformations modulated by temperature,supported by finite element simulations.This advance in 4D printing has the potential to significantly enhance its functional capabilities,performance,and applicability,opening up new horizons in additive manufacturing and design.
基金supported by the National Natural Science Foundation of China(6130501761304264+1 种基金61402203)the Natural Science Foundation of Jiangsu Province(BK20130154)
文摘In this paper, we consider the problem of irregular shapes tracking for multiple extended targets by introducing the Gaussian surface matrix（GSM） into the framework of the random finite set（RFS） theory. The Gaussian surface function is constructed first by the measurements, and it is used to define the GSM via a mapping function. We then integrate the GSM with the probability hypothesis density（PHD） filter, the Bayesian recursion formulas of GSM-PHD are derived and the Gaussian mixture implementation is employed to obtain the closed-form solutions. Moreover, the estimated shapes are designed to guide the measurement set sub-partition, which can cope with the problem of the spatially close target tracking. Simulation results show that the proposed algorithm can effectively estimate irregular target shapes and exhibit good robustness in cross extended target tracking.
基金supported by the National Natural Science Foundation of China(Grant No.12172125)the Science Foundation of Hunan Province(Grant No.2022JJ30119).
文摘Multi-wall carbon nanotube filled shape memory polymer composite(MWCNT/SMC)possessed enhanced modulus,strength,and electric conductivity,as well as excellent electrothermal shape memory properties,showing wide design scenarios and engineering application prospects.The thermoelectrically triggered shape memory process contains complex multi-physical mechanisms,especially when coupled with finite deformation rooted on micro-mechanisms.A multi-physical finite deformation model is necessary to get a deep understanding on the coupled electro-thermomechanical properties of electrothermal shape memory composites(ESMCs),beneficial to its design and wide application.Taking into consideration of micro-physical mechanisms of the MWCNTs interacting with double-chain networks,a finite deformation theoretical model is developed in this work based on two superimposed network chains of physically crosslinked network formed among MWCNTs and the chemically crosslinked network.An intact crosslinked chemical network is considered featuring with entropic-hyperelastic properties,superimposed with a physically crosslinked network where percolation theory is based on electric conductivity and electric-heating mechanisms.The model is calibrated by experiments and used for shape recoveries triggered by heating and electric fields.It captures the coupled electro-thermomechanical behavior of ESMCs and provides design guidelines for MWCNTs filled shape memory polymers.
基金supported by the National Basic Research Program of China(Grant No.2013CB922200)the National Natural Science Foundation of China(Grant Nos.11005049,11025417,and 10974021)
文摘The plasma screening of fast-electron-impact-ionization by excited state（3p） of Hydrogen-like ions was investigated in the first Born approximation with a plasma screening length δ varying from 1000a0 to 10a0. The generalized oscillator strength densities showed dramatic changes： some accessional minima occurred along with a remarkable enhancement in certain continuum-energy domains. The double-differential cross sections exhibit not only the same structures as the Bethe surface for moderate and large momentum transfers, but also a broadened enhancement for small momentum transfers.The single-differential cross sections exhibit a near-zero-energy-enhancement and prodigious multiple-shape resonances,depending on the continuum energy and the plasma screening length. These features are analogous to those of the photoionization cross section. These findings, for both types of cross section, can be explained by processes associated with continuum electrons, as long as the potential has a short-range character.
基金supported in part by the National Natural Science Foundation of China(Nos.91750202,11530046,and 11474156)the National Key R&D Program of China(No.2017YFA0303700)+1 种基金the Collaborative Innovation Center of Advanced Microstructures of Chinathe Collaborative Innovation Center of Solid-State Lighting and Energy-Saving Electronics of China
文摘We propose and simulate a method for generating a three-dimensional （3D） optical cage in the vicinity of focus by focusing a double-ring shaped radially and azimuthally polarized beam. Our study shows that the combination of an inner ring with an azimuthally polarized field and an outer ring with a radially polarized field and a phase factor can produce an optical cage with a dark region enclosed by higher intensity. The shape of the cage can be tailored by appropriately adjusting the parameters of double-mode beams. Furthermore, multiple 3D optical cages can be realized by applying the shift theorem of the Fourier transform and macro-pixel sampling algorithm to a double-ring shaped radially and azimuthally polarized beam.
基金Guangdong Basic and Applied Basic Research Foundation,Grant/Award Number:2019A1515110327Science Foundation for Young Teachers of Wuyi University,Grant/Award Number:2018AL017+4 种基金Innovation and Entrepreneurship Foundation of Students of Wuyi University,Grant/Award Number:2020CX16National Natural Science Foundation of China,Grant/Award Numbers:52003201,52033011Guangdong Science and Technology Major Special Fund,Grant/Award Number:2019-252Science Foundation for Young Research Group of Wuyi University,Grant/Award Number:2019td08Joint Research Fund for Wuyi University,Hong Kong and Macao Young Scholars,Grant/Award Number:2019WGALH05。
文摘To change the situation of shape memory polymers(SMPs)that can only remember very few shapes and enable discretional morphing for practical application,the authors report a reversible stepless multiple SMP derived from ultrahigh molecular weight polyethylene(UHMWPE).As the crystals of semicrystalline polymers are assembled by those with slightly different melting temperatures,and each type of crystal can remember a single shape,the crystalline region of UHMWPE is allowed to remember plenty of temporary shapes after programming.Changing the temperature of the programmed polymer within the melting/crystallization temperature ranges would lead to releasing/recovery of the memorized temporary shapes.Accordingly,multiple shape memory effects can be easily realized without an elaborate design of material structure and training process in advance as before.The temperaturedependent adjustability of the analog capacitor and soft lens with embedded programmed UHMWPE as actuators,characterized by the continuous/random/proportional responsivity,further reveals the utilization prospects of the controllable reversible stepless discretionary morphing effect.Moreover,the maximum work density of the programmed UHMWPE is found to be 210 kJ/m_(3),which is more than 10 times of piezoelectric ceramics,so that it can serve as a proof-of-concept mechanical driver for reversibly pumping of ethanediol-droplet upon heating/cooling.
