A novel Eu^(3+)-doped fluorapatite red phosphor Ca_(2)Y_(8)(BO_(4))_(2)(SiO_(4))_(4)F_(2)Eu^(3+)with pure phase was synthesized in this study.Density functional theory(DFT)calculation and diffuse reflection spectrum a...A novel Eu^(3+)-doped fluorapatite red phosphor Ca_(2)Y_(8)(BO_(4))_(2)(SiO_(4))_(4)F_(2)Eu^(3+)with pure phase was synthesized in this study.Density functional theory(DFT)calculation and diffuse reflection spectrum analysis reveal its potential as a matrix for phosphors excited by ultraviolet light.Eu^(3+)has a^(7)F_(0)→^(5)L_(6)transition at 394 nm,and the prepared phosphor exhibits a high emission intensity at 614 nm,which may be attributed to the^(5)D_(0)-^(7)F_(2)energy transition at the lower symmetry site of Eu^(3+).The optimal doping concentration of the phosphor is determined to be 11 mol%,with concentration quenching attributed to the exchange interaction mechanism.The overall color purity of the phosphor is up to 99.88%,with an internal quantum efficiency as high as 91.15%.Notably,Ca_(2)Y_(8)(BO_(4))_(2)(SiO_(4))_(4)F_(2):11 mol%Eu^(3+)(CYBSF:11 mol%Eu^(3+))phosphors exhibit good thermal stability,with a thermal quenching temperature(T1/2)of 552 K and the intensity of emission at 423 K still at 88.89%of that at 298 K.The activation energy of the phosphor is up to 0.30287 eV.Its comprehensive luminescence performance surpasses that of commercial red phosphor,making it suitable for near ultraviolet excited warm white light emitting diode(NUV-WLED)with a high color rendering index(Ra=82)and a correlated color temperature(CCT)of 4339 K.Moreover,the phosphor achieves latent fingerprint visualization and anti-counterfeiting ink on different material surfaces:glass,aluminum foil,plastic and paper.Overall,the fluorapatite CYBSF:11 mol%Eu^(3+)phosphor holds great potential for multimodal applications due to its high quantum efficiency and good thermal stability.展开更多
Human skin perceives external environmental stimulus by the synergies between the subcutaneous tactile corpuscles.Soft electronics with multiple sensing capabilities by mimicking the function of human skin are of sign...Human skin perceives external environmental stimulus by the synergies between the subcutaneous tactile corpuscles.Soft electronics with multiple sensing capabilities by mimicking the function of human skin are of significance in health monitoring and artificial sensation.The last decade has witnessed unprecedented development and convergence between multimodal tactile sensing devices and soft bioelectronics.Despite these advances,traditional flexible electronics achieve multimodal tactile sensing for pressure,strain,temperature,and humidity by integrating monomodal sensing devices together.This strategy results in high energy consumption,limited integration,and complex manufacturing process.Various multimodal sensors and crosstalk-free sensing mechanisms have been proposed to bridge the gap between natural sensory system and artificial perceptual system.In this review,we provide a comprehensive summary of tactile sensing mechanism,integration design principles,signal-decoupling strategies,and current applications for multimodal tactile perception.Finally,we highlight the current challenges and present the future perspectives to promote the development of multimodal tactile perception.展开更多
基金supported by the National Natural Science Foundation of China(52372013)Natural Science Foundation of Shanghai(22ZR1460600)。
文摘A novel Eu^(3+)-doped fluorapatite red phosphor Ca_(2)Y_(8)(BO_(4))_(2)(SiO_(4))_(4)F_(2)Eu^(3+)with pure phase was synthesized in this study.Density functional theory(DFT)calculation and diffuse reflection spectrum analysis reveal its potential as a matrix for phosphors excited by ultraviolet light.Eu^(3+)has a^(7)F_(0)→^(5)L_(6)transition at 394 nm,and the prepared phosphor exhibits a high emission intensity at 614 nm,which may be attributed to the^(5)D_(0)-^(7)F_(2)energy transition at the lower symmetry site of Eu^(3+).The optimal doping concentration of the phosphor is determined to be 11 mol%,with concentration quenching attributed to the exchange interaction mechanism.The overall color purity of the phosphor is up to 99.88%,with an internal quantum efficiency as high as 91.15%.Notably,Ca_(2)Y_(8)(BO_(4))_(2)(SiO_(4))_(4)F_(2):11 mol%Eu^(3+)(CYBSF:11 mol%Eu^(3+))phosphors exhibit good thermal stability,with a thermal quenching temperature(T1/2)of 552 K and the intensity of emission at 423 K still at 88.89%of that at 298 K.The activation energy of the phosphor is up to 0.30287 eV.Its comprehensive luminescence performance surpasses that of commercial red phosphor,making it suitable for near ultraviolet excited warm white light emitting diode(NUV-WLED)with a high color rendering index(Ra=82)and a correlated color temperature(CCT)of 4339 K.Moreover,the phosphor achieves latent fingerprint visualization and anti-counterfeiting ink on different material surfaces:glass,aluminum foil,plastic and paper.Overall,the fluorapatite CYBSF:11 mol%Eu^(3+)phosphor holds great potential for multimodal applications due to its high quantum efficiency and good thermal stability.
基金the Taishan Young Scholar Program of Shandong Province(No.tsqnz20231235)National Natural Science Foundation of China(Grant Nos.22104021,52303075,22227804)+1 种基金Natural Science Foundation of Shandong Province(ZR2023QB227)Department of Science and Technology of Guangdong Province(2022A1515110014).
文摘Human skin perceives external environmental stimulus by the synergies between the subcutaneous tactile corpuscles.Soft electronics with multiple sensing capabilities by mimicking the function of human skin are of significance in health monitoring and artificial sensation.The last decade has witnessed unprecedented development and convergence between multimodal tactile sensing devices and soft bioelectronics.Despite these advances,traditional flexible electronics achieve multimodal tactile sensing for pressure,strain,temperature,and humidity by integrating monomodal sensing devices together.This strategy results in high energy consumption,limited integration,and complex manufacturing process.Various multimodal sensors and crosstalk-free sensing mechanisms have been proposed to bridge the gap between natural sensory system and artificial perceptual system.In this review,we provide a comprehensive summary of tactile sensing mechanism,integration design principles,signal-decoupling strategies,and current applications for multimodal tactile perception.Finally,we highlight the current challenges and present the future perspectives to promote the development of multimodal tactile perception.
