The principle, imaging condition and experimental method for obtaining high resolution composition contrast in secondary electron image were described. A new technique of specimen preparation for secondary electron co...The principle, imaging condition and experimental method for obtaining high resolution composition contrast in secondary electron image were described. A new technique of specimen preparation for secondary electron composition contrast observation was introduced and discussed. By using multilayer P+Si1-xGex/pSi heterojunction internal photoemission infrared detector as an example, the applications of secondary electron composition contrast imaging in microstructure studies on heterojunction semiconducting materials and devices were stated. The characteristics of the image were compared with the ordinary transmission electron diffraction contrast image. The prospects of applications of the imaging method in heterojunction semiconductor devices and multilayer materials are also discussed.展开更多
A mathematical model for describing the relationship betweenelectrical conductivity and the thickness of bilayer, ratio of sublayer thickness of a nano-scale multilayer material (MLM) is presented. Fe/Cu MLM was synth...A mathematical model for describing the relationship betweenelectrical conductivity and the thickness of bilayer, ratio of sublayer thickness of a nano-scale multilayer material (MLM) is presented. Fe/Cu MLM was synthesized by electron beam physical vapor deposition (EB-PVD) technique, and the dependence of electrical conductivity of Fe/Cu MLM on the bilayer thickness and ratio of sublayer thickness were investigated. It is shown that the electrical conductivity of Fe/Cu MLM with fixed ratio of sublayer thickness decreases sharply when the thickness of bilayer becomes thinner than 30 nm. When the bilayer thickness is kept constant, the electrical conductivity linearly decreases with the increasing ratio of sublayer thickness. The values of parameters in the model were obtained by fitting the measured results of electrical conductivity of Fe/Cu MLM with fixed ratio of sublayer thickness. It is found that the calculated values agree well with measured ones.展开更多
Functionally graded material(FGM)can tailor properties of components such as wear resistance,corrosion resistance,and functionality to enhance the overall performance.The selective laser melting(SLM)additive manufactu...Functionally graded material(FGM)can tailor properties of components such as wear resistance,corrosion resistance,and functionality to enhance the overall performance.The selective laser melting(SLM)additive manufacturing highlights the capability in manufacturing FGMs with a high geometrical complexity and manufacture flexibility.In this work,the 316L/CuSn10/18Ni300/CoCr four-type materials FGMs were fabricated using SLM.The microstructure and properties of the FGMs were investigated to reveal the effects of SLM processing parameters on the defects.A large number of microcracks were found at the 316L/CuSn10 interface,which initiated from the fusion boundary of 316L region and extended along the building direction.The elastic modulus and nano-hardness in the 18Ni300/CoCr fusion zone decreased significantly,less than those in the 18Ni300 region or the CoCr region.The iron and copper elements were well diffused in the 316L/CuSn10 fusion zone,while elements in the CuSn10/18Ni300 and the 18Ni300/CoCr fusion zones showed significantly gradient transitions.Compared with other regions,the width of the CuSn10/18Ni300 interface and the CuSn10 region expand significantly.The mechanisms of materials fusion and crack generation at the 316L/CuSn10 interface were discussed.In addition,FGM structures without macro-crack were built by only altering the deposition subsequence of 316L and CuSn10,which provides a guide for the additive manufacturing of FGM structures.展开更多
Electrolyte electroreflectance (EER) has been widely employed to investigate the electronic energy band structure and related physical properties of semiconductors. The electrolyte electroreflectance (EER) method comb...Electrolyte electroreflectance (EER) has been widely employed to investigate the electronic energy band structure and related physical properties of semiconductors. The electrolyte electroreflectance (EER) method combined with electrochemical anodic dissolution was used to study GaAs/GaAlAs multilayer structural materials. According to variation of the EER spectra during anodic dissolution the characteristics of GaAs/GaAlAs multilayer structural materials such as properties of the interface, p-n junction positions and Al content profiles were obtained.展开更多
The multilayer impedance composite sound absorption structure of the new muffler is proposed by combining the microporous plate structure with the resonant sound absorption structure of the porous material.Firstly,the...The multilayer impedance composite sound absorption structure of the new muffler is proposed by combining the microporous plate structure with the resonant sound absorption structure of the porous material.Firstly,the acoustic impedance and acoustic absorption coefficient of the new muffler structure are calculated by acoustic electric analogy method,and then the noise attenuation is calculated.When the new muffler structure parameters change,the relationship among the noise frequency,the sound absorption coefficient and the noise attenuation is calculated by using MATLAB.Finally,the calculated results are compared with the experimental data to verify the correctness of the theoretical calculation.The variation of resonance peak,resonance frequency and attenuation band width of each structural parameter is analyzed by the relation curve.The conclusion shows that it is feasible to use multilayer sound absorbing materials as the body structure of the new muffler.And the influence relationship between the change of various parameters of the sound absorption structure with the sound absorption coefficient and noise attenuation is obtained.展开更多
In this study,the nonlocal strain gradient theory is adopted to investigate the static bending deformation of a functionally graded(FG)multilayered nanoplate made of onedimensional hexagonal piezoelectric quasicrystal...In this study,the nonlocal strain gradient theory is adopted to investigate the static bending deformation of a functionally graded(FG)multilayered nanoplate made of onedimensional hexagonal piezoelectric quasicrystal(PQC)materials subjected to mechanical and electrical surface loadings.The FG materials are assumed to be exponential distribution along the thickness direction.Exact closed-form solutions of an FG PQC nanoplate including nonlocality and strain gradient micro-size dependency are derived by utilizing the pseudo-Stroh formalism.The propagator matrix method is further used to solve the multilayered case by assuming that the layer interfaces are perfectly contacted.Numerical examples for two FG sandwich nanoplates made of piezoelectric crystals and PQC are provided to show the influences of nonlocal parameter,strain gradient parameter,exponential factor,length-to-width ratio,loading form,and stacking sequence on the static deformation of two FG sandwich nanoplates,which play an important role in designing new smart composite structures in engineering.展开更多
Ordered Ni/Au multilayer nanowire arrays are successfully fabricated inside the nanochannels of anodic aluminum oxide template by pulse electrodeposition method. The thickness of the alternating layers is controlled t...Ordered Ni/Au multilayer nanowire arrays are successfully fabricated inside the nanochannels of anodic aluminum oxide template by pulse electrodeposition method. The thickness of the alternating layers is controlled to examine the magnetostatic interaction in Ni/Au multilayer nanowires. The magnetic easy axis parallel to the nanowires indicates that here the magnetostatic coupling along the wire axis dominates over the interactions perpendicular to the nanowires. However,the magnetostatic interaction between adjacent nanowires with larger magnetic layers is enhanced, leading to the existence of an optimum coercivity value.展开更多
The present paper develops an analytical model for multi-electrodes in multi-layered piezoelectric actuators, in which the electrodes are vertical to and terminated at the edges of the medium and electroelastic field ...The present paper develops an analytical model for multi-electrodes in multi-layered piezoelectric actuators, in which the electrodes are vertical to and terminated at the edges of the medium and electroelastic field concentrations ahead of the electrodes in the multilayer piezoelectric actuators are examined. By considering a representative unit in realistic multilayers, the problem is formulated in terms of electric potential between the electrode tips and results in a system of singular integral equations in which the electric potential is taken as unknown function. Effects are investigated of electrode spacing and piezoelectric coupling on the singular electroelastic fields at the electrode tips, and closed-form expressions are given for the electromechanical field near the electrode tips. Exact solution for un-coupled dielectrics is provided, where no piezoelectric coupling is present.展开更多
Multiferroic tunnel junctions(MFTJs),which combine tunneling magnetoresistance(TMR)and electroresistance(TER)efects,have emerged as key candidates for data storage.Two-dimensional van der Waals(vdW)MFTJs,in particular...Multiferroic tunnel junctions(MFTJs),which combine tunneling magnetoresistance(TMR)and electroresistance(TER)efects,have emerged as key candidates for data storage.Two-dimensional van der Waals(vdW)MFTJs,in particular,are promising spintronic devices for the post-Moore era.However,these vdW MFTJs are typically based on multiferroics composed of ferromagnetic and ferroelectric materials or multilayer magnetic materials with sliding ferroelectricity,which increases device fabrication complexity.In this work,we design a vdW MFTJ using bilayer MoPtGe_(2)S_(6),a material with homologous multiferroicity in each monolayer,combined with symmetric PtTe_(2)electrodes.Using frst-principles calculations based on density functional theory and nonequilibrium Green's functions,we theoretically explore the spin-polarized electronic transport properties of this MFTJ.By controlling the ferroelectric and ferromagnetic polarization directions of bilayer MoPtGe_(2)S_(6),the MFTJ can exhibit six distinct non-volatile resistance states,with maximum TMR(137%)and TER(1943%)ratios.Under biaxial strain,TMR and TER can increase to 265%and 4210%,respectively.The TER ratio also increases to 2186%under a 0.1 V bias voltage.Remarkably,the MFTJ exhibits a pronounced spin-fltering and a signifcant negative diferential resistance efect.These fndings not only highlight the potential of monolayer multiferroic MoPtGe_(2)S_(6)for MFTJs but also ofer valuable theoretical insights for future experimental investigations.展开更多
LiNi_(x)Co_(y)Al_(z)O_(2)(NCA)cathode materials are drawing widespread attention,but the huge gap between the ideal and present cyclic stability still hinders their further commercial application,especially for the Ni...LiNi_(x)Co_(y)Al_(z)O_(2)(NCA)cathode materials are drawing widespread attention,but the huge gap between the ideal and present cyclic stability still hinders their further commercial application,especially for the Ni-rich LiNi_(x)Co_(y)Al_(z)O_(2)(x>0.8,x+y+z=1)cathode material,which is owing to the structural degradation and particles'intrinsic fracture.To tackle the problems,Li_(0.5)La_(2)Al_(0.5)O_(4)in situ coated and Mn compensating doped multilayer LiNi_(0.82)Co_(0.14)Al_(0.04)O_(2)was prepared.XRD refinement indicates that La-Mn co-modifying could realize appropriate Li/Ni disorder degree.Calculated results and in situ XRD patterns reveal that the LLAO coating layer could effectively restrain crack in secondary particles benefited from the suppressed internal strain.AFM further improves as NCA-LM2 has superior mechanical property.The SEM,TEM,XPS tests indicate that the cycled cathode with LLAO-Mn modification displays a more complete morphology and less side reaction with electrolyte.DEMS was used to further investigate cathode-electrolyte interface which was reflected by gas evolution.NCA-LM2 releases less CO_(2)than NCA-P indexing on a more stable surface.The modified material presents outstanding capacity retention of 96.2%after 100 cycles in the voltage range of 3.0-4.4 V at 1C,13%higher than that of the pristine and 80.8%at 1 C after 300 cycles.This excellent electrochemical performance could be attributed to the fact that the high chemically stable coating layer of Li_(0.5)La_(2)Al_(0.5)O_(4)(LLAO)could enhance the interface and the Mn doping layer could suppress the influence of the lattice mismatch and distortion.We believe that it can be a useful strategy for the modification of Ni-rich cathode material and other advanced functional material.展开更多
文摘The principle, imaging condition and experimental method for obtaining high resolution composition contrast in secondary electron image were described. A new technique of specimen preparation for secondary electron composition contrast observation was introduced and discussed. By using multilayer P+Si1-xGex/pSi heterojunction internal photoemission infrared detector as an example, the applications of secondary electron composition contrast imaging in microstructure studies on heterojunction semiconducting materials and devices were stated. The characteristics of the image were compared with the ordinary transmission electron diffraction contrast image. The prospects of applications of the imaging method in heterojunction semiconductor devices and multilayer materials are also discussed.
基金This work was supported by the National Natural Science Foundation of China (Grant No. 59425001).
文摘A mathematical model for describing the relationship betweenelectrical conductivity and the thickness of bilayer, ratio of sublayer thickness of a nano-scale multilayer material (MLM) is presented. Fe/Cu MLM was synthesized by electron beam physical vapor deposition (EB-PVD) technique, and the dependence of electrical conductivity of Fe/Cu MLM on the bilayer thickness and ratio of sublayer thickness were investigated. It is shown that the electrical conductivity of Fe/Cu MLM with fixed ratio of sublayer thickness decreases sharply when the thickness of bilayer becomes thinner than 30 nm. When the bilayer thickness is kept constant, the electrical conductivity linearly decreases with the increasing ratio of sublayer thickness. The values of parameters in the model were obtained by fitting the measured results of electrical conductivity of Fe/Cu MLM with fixed ratio of sublayer thickness. It is found that the calculated values agree well with measured ones.
基金Project(2020B090922002)supported by Guangdong Provincial Key Field Research and Development Program,ChinaProjects(51875215,52005189)supported by the National Natural Science Foundation of ChinaProject(2019B1515120094)supported by Guangdong Provincial Basic and Applied Basic Research Fund,China。
文摘Functionally graded material(FGM)can tailor properties of components such as wear resistance,corrosion resistance,and functionality to enhance the overall performance.The selective laser melting(SLM)additive manufacturing highlights the capability in manufacturing FGMs with a high geometrical complexity and manufacture flexibility.In this work,the 316L/CuSn10/18Ni300/CoCr four-type materials FGMs were fabricated using SLM.The microstructure and properties of the FGMs were investigated to reveal the effects of SLM processing parameters on the defects.A large number of microcracks were found at the 316L/CuSn10 interface,which initiated from the fusion boundary of 316L region and extended along the building direction.The elastic modulus and nano-hardness in the 18Ni300/CoCr fusion zone decreased significantly,less than those in the 18Ni300 region or the CoCr region.The iron and copper elements were well diffused in the 316L/CuSn10 fusion zone,while elements in the CuSn10/18Ni300 and the 18Ni300/CoCr fusion zones showed significantly gradient transitions.Compared with other regions,the width of the CuSn10/18Ni300 interface and the CuSn10 region expand significantly.The mechanisms of materials fusion and crack generation at the 316L/CuSn10 interface were discussed.In addition,FGM structures without macro-crack were built by only altering the deposition subsequence of 316L and CuSn10,which provides a guide for the additive manufacturing of FGM structures.
文摘Electrolyte electroreflectance (EER) has been widely employed to investigate the electronic energy band structure and related physical properties of semiconductors. The electrolyte electroreflectance (EER) method combined with electrochemical anodic dissolution was used to study GaAs/GaAlAs multilayer structural materials. According to variation of the EER spectra during anodic dissolution the characteristics of GaAs/GaAlAs multilayer structural materials such as properties of the interface, p-n junction positions and Al content profiles were obtained.
基金National Natural Science Foundation of China(Nos.51705545 and 15A460041)。
文摘The multilayer impedance composite sound absorption structure of the new muffler is proposed by combining the microporous plate structure with the resonant sound absorption structure of the porous material.Firstly,the acoustic impedance and acoustic absorption coefficient of the new muffler structure are calculated by acoustic electric analogy method,and then the noise attenuation is calculated.When the new muffler structure parameters change,the relationship among the noise frequency,the sound absorption coefficient and the noise attenuation is calculated by using MATLAB.Finally,the calculated results are compared with the experimental data to verify the correctness of the theoretical calculation.The variation of resonance peak,resonance frequency and attenuation band width of each structural parameter is analyzed by the relation curve.The conclusion shows that it is feasible to use multilayer sound absorbing materials as the body structure of the new muffler.And the influence relationship between the change of various parameters of the sound absorption structure with the sound absorption coefficient and noise attenuation is obtained.
基金supported by the National Natural Science Foundation of China(Grant Nos.11862021,12072166)the Program for Young Talents of Science and Technology in Universities of Inner Mongolia Autonomous Region(Grant No.NJYT-19-A06)the Natural Science Foundation of Inner Mongolia Autonomous Region of China(Grant Nos.2020MS01006,2019MS01015,2019MS01017).
文摘In this study,the nonlocal strain gradient theory is adopted to investigate the static bending deformation of a functionally graded(FG)multilayered nanoplate made of onedimensional hexagonal piezoelectric quasicrystal(PQC)materials subjected to mechanical and electrical surface loadings.The FG materials are assumed to be exponential distribution along the thickness direction.Exact closed-form solutions of an FG PQC nanoplate including nonlocality and strain gradient micro-size dependency are derived by utilizing the pseudo-Stroh formalism.The propagator matrix method is further used to solve the multilayered case by assuming that the layer interfaces are perfectly contacted.Numerical examples for two FG sandwich nanoplates made of piezoelectric crystals and PQC are provided to show the influences of nonlocal parameter,strain gradient parameter,exponential factor,length-to-width ratio,loading form,and stacking sequence on the static deformation of two FG sandwich nanoplates,which play an important role in designing new smart composite structures in engineering.
基金supported by the National Natural Science Foundation of China(Grant No.11204246)the Natural Science Foundation of CQCSTC(Grant No.cstc2014jcyjA50027)
文摘Ordered Ni/Au multilayer nanowire arrays are successfully fabricated inside the nanochannels of anodic aluminum oxide template by pulse electrodeposition method. The thickness of the alternating layers is controlled to examine the magnetostatic interaction in Ni/Au multilayer nanowires. The magnetic easy axis parallel to the nanowires indicates that here the magnetostatic coupling along the wire axis dominates over the interactions perpendicular to the nanowires. However,the magnetostatic interaction between adjacent nanowires with larger magnetic layers is enhanced, leading to the existence of an optimum coercivity value.
文摘The present paper develops an analytical model for multi-electrodes in multi-layered piezoelectric actuators, in which the electrodes are vertical to and terminated at the edges of the medium and electroelastic field concentrations ahead of the electrodes in the multilayer piezoelectric actuators are examined. By considering a representative unit in realistic multilayers, the problem is formulated in terms of electric potential between the electrode tips and results in a system of singular integral equations in which the electric potential is taken as unknown function. Effects are investigated of electrode spacing and piezoelectric coupling on the singular electroelastic fields at the electrode tips, and closed-form expressions are given for the electromechanical field near the electrode tips. Exact solution for un-coupled dielectrics is provided, where no piezoelectric coupling is present.
基金supported by the National Key R&D Program of China(Grant No.2022YFB3505301)the National Key R&D Program of Shanxi Province(Grant No.202302050201014)+1 种基金the National Natural Science Foundation of China(Grant No.12304148)the Natural Science Basic Research Program of Shanxi Province(Grant No.202203021222219)。
文摘Multiferroic tunnel junctions(MFTJs),which combine tunneling magnetoresistance(TMR)and electroresistance(TER)efects,have emerged as key candidates for data storage.Two-dimensional van der Waals(vdW)MFTJs,in particular,are promising spintronic devices for the post-Moore era.However,these vdW MFTJs are typically based on multiferroics composed of ferromagnetic and ferroelectric materials or multilayer magnetic materials with sliding ferroelectricity,which increases device fabrication complexity.In this work,we design a vdW MFTJ using bilayer MoPtGe_(2)S_(6),a material with homologous multiferroicity in each monolayer,combined with symmetric PtTe_(2)electrodes.Using frst-principles calculations based on density functional theory and nonequilibrium Green's functions,we theoretically explore the spin-polarized electronic transport properties of this MFTJ.By controlling the ferroelectric and ferromagnetic polarization directions of bilayer MoPtGe_(2)S_(6),the MFTJ can exhibit six distinct non-volatile resistance states,with maximum TMR(137%)and TER(1943%)ratios.Under biaxial strain,TMR and TER can increase to 265%and 4210%,respectively.The TER ratio also increases to 2186%under a 0.1 V bias voltage.Remarkably,the MFTJ exhibits a pronounced spin-fltering and a signifcant negative diferential resistance efect.These fndings not only highlight the potential of monolayer multiferroic MoPtGe_(2)S_(6)for MFTJs but also ofer valuable theoretical insights for future experimental investigations.
基金supported in part by the High Performance Computing Center of Central South Universitythe financial support from the Government of Chongzuo,Guangxi Zhuang Autonomous Region(Fund No.FA2020011FA20210713)
文摘LiNi_(x)Co_(y)Al_(z)O_(2)(NCA)cathode materials are drawing widespread attention,but the huge gap between the ideal and present cyclic stability still hinders their further commercial application,especially for the Ni-rich LiNi_(x)Co_(y)Al_(z)O_(2)(x>0.8,x+y+z=1)cathode material,which is owing to the structural degradation and particles'intrinsic fracture.To tackle the problems,Li_(0.5)La_(2)Al_(0.5)O_(4)in situ coated and Mn compensating doped multilayer LiNi_(0.82)Co_(0.14)Al_(0.04)O_(2)was prepared.XRD refinement indicates that La-Mn co-modifying could realize appropriate Li/Ni disorder degree.Calculated results and in situ XRD patterns reveal that the LLAO coating layer could effectively restrain crack in secondary particles benefited from the suppressed internal strain.AFM further improves as NCA-LM2 has superior mechanical property.The SEM,TEM,XPS tests indicate that the cycled cathode with LLAO-Mn modification displays a more complete morphology and less side reaction with electrolyte.DEMS was used to further investigate cathode-electrolyte interface which was reflected by gas evolution.NCA-LM2 releases less CO_(2)than NCA-P indexing on a more stable surface.The modified material presents outstanding capacity retention of 96.2%after 100 cycles in the voltage range of 3.0-4.4 V at 1C,13%higher than that of the pristine and 80.8%at 1 C after 300 cycles.This excellent electrochemical performance could be attributed to the fact that the high chemically stable coating layer of Li_(0.5)La_(2)Al_(0.5)O_(4)(LLAO)could enhance the interface and the Mn doping layer could suppress the influence of the lattice mismatch and distortion.We believe that it can be a useful strategy for the modification of Ni-rich cathode material and other advanced functional material.
