Recently,multifunctional materials have received widespread attention from researchers.Cellulose nanofibers(CNF)is one of biomass materials with abundant hydroxyl groups,which shows great potential in manufacturing mu...Recently,multifunctional materials have received widespread attention from researchers.Cellulose nanofibers(CNF)is one of biomass materials with abundant hydroxyl groups,which shows great potential in manufacturing multifunctional composite material.In this paper,a kind of polyaniline@CNF/polyvinyl alcohol-H_(2)SO_(4) multifunctional composite material(PANI@CNF/PVA-H_(2)SO_(4))was successfully designed by in-situ chemical polymerization of conductive polyaniline(PANI)onto CNF aerogel with high aspect ratio,and then coated with PVA-H_(2)SO_(4) gel.The composite material has a specific capacitance of 502.2 F/g at a scan rate of 5 mV/s as supercapacitor electrode.Furthermore,when the composite was assembled into a symmetrical supercapacitor,it can still provide an energy density of 11.49 W·h/kg at a high power density of 413.55 W/kg.Besides,the as-obtained PANI@CNF/PVA-H_(2)SO_(4) composite has an excellent electromagnetic shielding performance of 34.75 dB in X-band.In addition,due to the excellent flexibility of CNF and PVA,the PANI@CNF/PVA-H2SO4 composites can be further applied to stress sensors to detect pressure and human motion signals.展开更多
基金supported by the fund of National Natural Science Foundation of China(22078184,22378249 and 22178208)Key R&D Plan of Shaanxi Province(2024GX-YBXM-335)+1 种基金China Postdoctoral Science Foundation(2019M653853XB)Natural science advance research foundation of Shaanxi University of Science and Technology(2018QNBJ-03).
文摘Recently,multifunctional materials have received widespread attention from researchers.Cellulose nanofibers(CNF)is one of biomass materials with abundant hydroxyl groups,which shows great potential in manufacturing multifunctional composite material.In this paper,a kind of polyaniline@CNF/polyvinyl alcohol-H_(2)SO_(4) multifunctional composite material(PANI@CNF/PVA-H_(2)SO_(4))was successfully designed by in-situ chemical polymerization of conductive polyaniline(PANI)onto CNF aerogel with high aspect ratio,and then coated with PVA-H_(2)SO_(4) gel.The composite material has a specific capacitance of 502.2 F/g at a scan rate of 5 mV/s as supercapacitor electrode.Furthermore,when the composite was assembled into a symmetrical supercapacitor,it can still provide an energy density of 11.49 W·h/kg at a high power density of 413.55 W/kg.Besides,the as-obtained PANI@CNF/PVA-H_(2)SO_(4) composite has an excellent electromagnetic shielding performance of 34.75 dB in X-band.In addition,due to the excellent flexibility of CNF and PVA,the PANI@CNF/PVA-H2SO4 composites can be further applied to stress sensors to detect pressure and human motion signals.
