The UV absorption spectra of o-naphthol,α-naphthylamine,2,7-dihydroxy naphthalene,2,4-dimethoxy ben- zaldehyde and methyl salicylate,overlap severely;therefore it is impossible to determine them in mixtures by tradit...The UV absorption spectra of o-naphthol,α-naphthylamine,2,7-dihydroxy naphthalene,2,4-dimethoxy ben- zaldehyde and methyl salicylate,overlap severely;therefore it is impossible to determine them in mixtures by traditional spectrophotometric methods.In this paper,the partial least-squares(PLS)regression is applied to the simultaneous determination of these compounds in mixtures by UV spectrophtometry without any pretreatment of the samples.Ten synthetic mixture samples are analyzed by the proposed method.The mean recoveries are 99.4%,996%,100.2%,99.3% and 99.1%,and the relative standard deviations(RSD) are 1.87%,1.98%,1.94%,0.960% and 0.672%,respectively.展开更多
Based on simplex algorithm of optimal design, the multicomponent mixture regression model was used to investigate physical properties of submerged arc welding flux. The effect of complex interaction of seven component...Based on simplex algorithm of optimal design, the multicomponent mixture regression model was used to investigate physical properties of submerged arc welding flux. The effect of complex interaction of seven components in agglomerated flux on softening temperature was analyzed. The results indicate that the interaction of MgO-TiO2-CaCOa-AI20a increases the softening temperature of flux, but the additions of CaF2 and ZrO2 can decrease the softening temperature.展开更多
文摘The UV absorption spectra of o-naphthol,α-naphthylamine,2,7-dihydroxy naphthalene,2,4-dimethoxy ben- zaldehyde and methyl salicylate,overlap severely;therefore it is impossible to determine them in mixtures by traditional spectrophotometric methods.In this paper,the partial least-squares(PLS)regression is applied to the simultaneous determination of these compounds in mixtures by UV spectrophtometry without any pretreatment of the samples.Ten synthetic mixture samples are analyzed by the proposed method.The mean recoveries are 99.4%,996%,100.2%,99.3% and 99.1%,and the relative standard deviations(RSD) are 1.87%,1.98%,1.94%,0.960% and 0.672%,respectively.
文摘Based on simplex algorithm of optimal design, the multicomponent mixture regression model was used to investigate physical properties of submerged arc welding flux. The effect of complex interaction of seven components in agglomerated flux on softening temperature was analyzed. The results indicate that the interaction of MgO-TiO2-CaCOa-AI20a increases the softening temperature of flux, but the additions of CaF2 and ZrO2 can decrease the softening temperature.
