We present a four-state model for calculating the two-photon absorption of multi-branched molecules by using the time-depended function method, The numerical results indicate that the two-photon absorption cross secti...We present a four-state model for calculating the two-photon absorption of multi-branched molecules by using the time-depended function method, The numerical results indicate that the two-photon absorption cross section has a strong enhancement for three-branch molecules compared to two-branch structures, The maximal two-photon-absorption cross section is 2.358 × 10^-47 cm^4s/photon, At the same time, the charge-transfer process for the charge-transfer states is visualized in order to explain mechanism about the maximal TPA cross section.展开更多
Developing chemical systems capable of executing multipath nonequilibrium processes provides valuable insights into the study of multistage dissipative structures in living systems.Here,we report a nonequilibrium mult...Developing chemical systems capable of executing multipath nonequilibrium processes provides valuable insights into the study of multistage dissipative structures in living systems.Here,we report a nonequilibrium multipath evolution in a three-state supramolecular system,which is clarified by associating it with a multibranch selection structure.This system is constructed by synergistically combining an assembly-induced sol-gel transition with the color change of an acid-base indicator.Depending on the initial condition and chemical fuel composition,this system can execute five distinct nonequilibrium processes.In addition,the set of structured programming can be replayed by repeatedly introducing the chemical fuel.It is further utilized to explore the applications of information encryption and establish its universality.These findings offer novel avenues for future transient material design and may make significant contributions to systems chemistry.展开更多
基金Supported by the National Natural Science Foundation of China under Grant No 60471042.
文摘We present a four-state model for calculating the two-photon absorption of multi-branched molecules by using the time-depended function method, The numerical results indicate that the two-photon absorption cross section has a strong enhancement for three-branch molecules compared to two-branch structures, The maximal two-photon-absorption cross section is 2.358 × 10^-47 cm^4s/photon, At the same time, the charge-transfer process for the charge-transfer states is visualized in order to explain mechanism about the maximal TPA cross section.
基金supported by the National Natural Science Foundation of China(grant no.21975145)the Natural Science Foundation of Shandong Province(grant no.ZR2023JQ008).
文摘Developing chemical systems capable of executing multipath nonequilibrium processes provides valuable insights into the study of multistage dissipative structures in living systems.Here,we report a nonequilibrium multipath evolution in a three-state supramolecular system,which is clarified by associating it with a multibranch selection structure.This system is constructed by synergistically combining an assembly-induced sol-gel transition with the color change of an acid-base indicator.Depending on the initial condition and chemical fuel composition,this system can execute five distinct nonequilibrium processes.In addition,the set of structured programming can be replayed by repeatedly introducing the chemical fuel.It is further utilized to explore the applications of information encryption and establish its universality.These findings offer novel avenues for future transient material design and may make significant contributions to systems chemistry.
