Polyionic complex DHP-PDDA was prepared by reacting anionic surfactant dihexadecyl phosphate (DHP) with polycationic poly(diallyldimethyl ammonium) (PDDA). Thin films made from DHP-PDDA with incorporated hemoglobin (H...Polyionic complex DHP-PDDA was prepared by reacting anionic surfactant dihexadecyl phosphate (DHP) with polycationic poly(diallyldimethyl ammonium) (PDDA). Thin films made from DHP-PDDA with incorporated hemoglobin (Hb) on pyrolytic graphite (PG) electrodes were characterized by electrochemistry and other techniques.展开更多
Three rare-earth-containing heteropolyoxometalates with different sizes, Na9[Eu(W5 O18)2], K13[Eu(SiW11O39)2], and K17[Eu(P2W17O61)2], have been incorporated by self-assembly into the interlayer of synthetic multibila...Three rare-earth-containing heteropolyoxometalates with different sizes, Na9[Eu(W5 O18)2], K13[Eu(SiW11O39)2], and K17[Eu(P2W17O61)2], have been incorporated by self-assembly into the interlayer of synthetic multibilayer films of dimethyldioctadecylammonium chloride and exhibited different orientations.展开更多
The molecular interactions between Nd^(3+), Gd^(3+)and Yb^(3+) and DPPC in multibilayer have been studied by Fourier transform infrared spectroscopy. The results show that incorporations of the lanthanide ions conside...The molecular interactions between Nd^(3+), Gd^(3+)and Yb^(3+) and DPPC in multibilayer have been studied by Fourier transform infrared spectroscopy. The results show that incorporations of the lanthanide ions considerably shift the gel to liquid-crystal phase transition to higher temperatures. The incorporations of Gd^(3+) and Yb^(3+) obviously reduce the cooperations of the transition. The phosphate region of the spectra indicates that the Ln^(3+) binding to DPPC forms DPPC-Ln^(3+)complex and the Lna^(3+)binding is not dependent on the phase state of DPPC. The C-H stretching region of the spectra suggests that the incorporation of Ln^(3+)increases the conformational order of DPPC both in gel and in liquid-crystal phase as a result of the reduction of gauche rotamers.展开更多
基金the financial support from the National Natural Science Foundation of China (29975003).
文摘Polyionic complex DHP-PDDA was prepared by reacting anionic surfactant dihexadecyl phosphate (DHP) with polycationic poly(diallyldimethyl ammonium) (PDDA). Thin films made from DHP-PDDA with incorporated hemoglobin (Hb) on pyrolytic graphite (PG) electrodes were characterized by electrochemistry and other techniques.
基金supported by the National Nature Science Foundation of China(20071007)the Foundation for University Key Teacher by the Ministry of Education of China
文摘Three rare-earth-containing heteropolyoxometalates with different sizes, Na9[Eu(W5 O18)2], K13[Eu(SiW11O39)2], and K17[Eu(P2W17O61)2], have been incorporated by self-assembly into the interlayer of synthetic multibilayer films of dimethyldioctadecylammonium chloride and exhibited different orientations.
文摘The molecular interactions between Nd^(3+), Gd^(3+)and Yb^(3+) and DPPC in multibilayer have been studied by Fourier transform infrared spectroscopy. The results show that incorporations of the lanthanide ions considerably shift the gel to liquid-crystal phase transition to higher temperatures. The incorporations of Gd^(3+) and Yb^(3+) obviously reduce the cooperations of the transition. The phosphate region of the spectra indicates that the Ln^(3+) binding to DPPC forms DPPC-Ln^(3+)complex and the Lna^(3+)binding is not dependent on the phase state of DPPC. The C-H stretching region of the spectra suggests that the incorporation of Ln^(3+)increases the conformational order of DPPC both in gel and in liquid-crystal phase as a result of the reduction of gauche rotamers.
