自制了多单体接枝物PP g (St co MMA) ,并利用其增容PP/PVC共混体系。讨论了共混物组成、相容剂用量在不同温度、不同压力下对其流变行为的影响。实验结果表明 ,在所研究的温度和压力范围内 ,加入PP g (St co MMA)增容PP/PVC共混体系后 ...自制了多单体接枝物PP g (St co MMA) ,并利用其增容PP/PVC共混体系。讨论了共混物组成、相容剂用量在不同温度、不同压力下对其流变行为的影响。实验结果表明 ,在所研究的温度和压力范围内 ,加入PP g (St co MMA)增容PP/PVC共混体系后 ,共混物熔体呈典型的假塑性流体特性 ,粘流活化能增加 ,非牛顿性有增大的趋势。共混体系的力学性能提高 。展开更多
In order to improve mechanical properties of soft poly(vinyl chloride)(PVC) films,we used commercial multi-layer graphene(MLG) with large size and high structural integrity as reinforcing fillers,and prepared MLG/PVC ...In order to improve mechanical properties of soft poly(vinyl chloride)(PVC) films,we used commercial multi-layer graphene(MLG) with large size and high structural integrity as reinforcing fillers,and prepared MLG/PVC composite films by using conventional melt-mixing methods.Microstructures,static and dynamic mechanical properties of the MLG/PVC composite films were investigated.The results showed that a small amount of MLG loading could greatly increase the mechanical properties of the MLG/PVC composites.The tensile modulus of the 0.96 wt%MLG/PVC composites was up to 40 MPa,increasing by31.3%in comparison to the neat PVC.Such a significant mechanical reinforcement was mainly attributed to uniform dispersion of the large-size MLG,good compatibility and strong interactions among MLG and plasticizers and PVC.展开更多
文摘自制了多单体接枝物PP g (St co MMA) ,并利用其增容PP/PVC共混体系。讨论了共混物组成、相容剂用量在不同温度、不同压力下对其流变行为的影响。实验结果表明 ,在所研究的温度和压力范围内 ,加入PP g (St co MMA)增容PP/PVC共混体系后 ,共混物熔体呈典型的假塑性流体特性 ,粘流活化能增加 ,非牛顿性有增大的趋势。共混体系的力学性能提高 。
基金financial supports from the Ministry of Science and Technology of China(No.2012AA030303)the Hundred Talents Program of Chinese Academy of Sciences(No.CAS2012)the Fund for Creative Research Groups(No.51221264)
文摘In order to improve mechanical properties of soft poly(vinyl chloride)(PVC) films,we used commercial multi-layer graphene(MLG) with large size and high structural integrity as reinforcing fillers,and prepared MLG/PVC composite films by using conventional melt-mixing methods.Microstructures,static and dynamic mechanical properties of the MLG/PVC composite films were investigated.The results showed that a small amount of MLG loading could greatly increase the mechanical properties of the MLG/PVC composites.The tensile modulus of the 0.96 wt%MLG/PVC composites was up to 40 MPa,increasing by31.3%in comparison to the neat PVC.Such a significant mechanical reinforcement was mainly attributed to uniform dispersion of the large-size MLG,good compatibility and strong interactions among MLG and plasticizers and PVC.
