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A MIXED FINITE ELEMENT AND UPWIND MIXED FINITE ELEMENT MULTI-STEP METHOD FOR THE THREE-DIMENSIONAL POSITIVE SEMI-DEFINITE DARCY-FORCHHEIMER MISCIBLE DISPLACEMENT PROBLEM
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作者 Yirang YUAN Changfeng LI +1 位作者 Huailing SONG Tongjun SUN 《Acta Mathematica Scientia》 2025年第2期715-736,共22页
In this paper,a composite numerical scheme is proposed to solve the threedimensional Darcy-Forchheimer miscible displacement problem with positive semi-definite assumptions.A mixed finite element is used for the fow e... In this paper,a composite numerical scheme is proposed to solve the threedimensional Darcy-Forchheimer miscible displacement problem with positive semi-definite assumptions.A mixed finite element is used for the fow equation.The velocity and pressure are computed simultaneously.The accuracy of velocity is improved one order.The concentration equation is solved by using mixed finite element,multi-step difference and upwind approximation.A multi-step method is used to approximate time derivative for improving the accuracy.The upwind approximation and an expanded mixed finite element are adopted to solve the convection and diffusion,respectively.The composite method could compute the diffusion flux and its gradient.It possibly becomes an eficient tool for solving convection-dominated diffusion problems.Firstly,the conservation of mass holds.Secondly,the multi-step method has high accuracy.Thirdly,the upwind approximation could avoid numerical dispersion.Using numerical analysis of a priori estimates and special techniques of differential equations,we give an error estimates for a positive definite problem.Numerical experiments illustrate its computational efficiency and feasibility of application. 展开更多
关键词 Darcy-Forchheimer fow three-dimensional positive semi-definite problem upwind mixed finite element multi-step method conservation of mass convergence analysis
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Characterization of Calcined Kaolin/TiO_2 Composite Particle Material Prepared by Mechano-Chemical Method 被引量:4
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作者 王柏昆 丁浩 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2010年第5期765-769,共5页
Calcined kaolin/TiO2 composite particle material (CK/TCPM) was prepared with TiO2 coating on the surfaces of calcined kaolin particles by the mechano-chemical method. X-ray diffraction (XRD) and scanning electron ... Calcined kaolin/TiO2 composite particle material (CK/TCPM) was prepared with TiO2 coating on the surfaces of calcined kaolin particles by the mechano-chemical method. X-ray diffraction (XRD) and scanning electron microscope (SEM) were used to investigate the microstructures and morphologies, respectively. The mechanism of the mechano-chemical reaction between calcined kaolin and TiO2 was studied by infrared spectra (IR). The results show that TiO2 coats evenly on the surfaces of calcined kaolin particles by Si-O-Ti and Al-O-Ti bonds on their interfaces. The hiding power and whiteness of CK/TCPM are 17.12 g/m^2 and 95.7%, respectively, presenting its similarity to TiO2 in pigment properties. 展开更多
关键词 mechano-chemical method calcined kaolin TIO2 composite particles material pigment properties
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Effects of ultrasonic impregnation combined with calcination in N_2 atmosphere on the property of Co_3O_4/CeO_2 composites for catalytic methane combustion 被引量:1
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作者 Hong Lu Chengfa Jiang +3 位作者 Zhenwu Ding Wei Wang Wei Chu Yanyan Feng 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2016年第3期387-392,共6页
CoO/CeOcomposites with high surface areas and ultrafine crystalline sizes for catalytic combustion of methane were firstly prepared by a new sol-gel method which combined ultrasonic impregnation treatment and calcinat... CoO/CeOcomposites with high surface areas and ultrafine crystalline sizes for catalytic combustion of methane were firstly prepared by a new sol-gel method which combined ultrasonic impregnation treatment and calcination in Natmosphere. The samples were characterized by various means such as nitrogen adsorption/desorption, X-ray diffraction(XRD), Htemperature-programmed reduction(H-TPR),X-ray photoelectron spectroscopy(XPS) and transmission electron microscopy(TEM). Results showed that the modified catalyst had the mesoporous structure, comparatively higher amount of surface oxygen and larger oxygen vacancies than others. As a result of the structure and surface composition merits, a high methane combustion conversion(50%) could be obtained at a low temperature of 262 °C for the modified CoO/CeOcomposites catalysts. The experimental results demonstrated that ultrasonic impregnation treatment combined with the Nthermal treatment prior to calcination in air had a promising application for preparation of CoO/CeOcomposites catalysts for low-temperature catalytic combustion of methane. 展开更多
关键词 ULTRASONIC N_2 calcination Catalytic combustion Sol-gel method Co_3O_4/CeO_2
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Application of Multi-Step Differential Transform Method on Flow of a Second-Grade Fluid over a Stretching or Shrinking Sheet 被引量:6
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作者 M.M Rashidi Ali J. Chamkha M Keimanesh 《American Journal of Computational Mathematics》 2011年第2期119-128,共10页
In this study, a reliable algorithm to develop approximate solutions for the problem of fluid flow over a stretching or shrinking sheet is proposed. It is depicted that the differential transform method (DTM) solution... In this study, a reliable algorithm to develop approximate solutions for the problem of fluid flow over a stretching or shrinking sheet is proposed. It is depicted that the differential transform method (DTM) solutions are only valid for small values of the independent variable. The DTM solutions diverge for some differential equations that extremely have nonlinear behaviors or have boundary-conditions at infinity. For this reason the governing boundary-layer equations are solved by the Multi-step Differential Transform Method (MDTM). The main advantage of this method is that it can be applied directly to nonlinear differential equations without requiring linearization, discretization, or perturbation. It is a semi analytical-numerical technique that formulizes Taylor series in a very different manner. By applying the MDTM the interval of convergence for the series solution is increased. The MDTM is treated as an algorithm in a sequence of intervals for finding accurate approximate solutions for systems of differential equations. It is predicted that the MDTM can be applied to a wide range of engineering applications. 展开更多
关键词 Non-Newtonian Fluid STRETCHING Surface SHRINKING SHEET multi-step DIFFERENTIAL TRANSFORM method (MDTM)
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Adaptive multi-step piecewise interpolation reproducing kernel method for solving the nonlinear time-fractional partial differential equation arising from financial economics 被引量:1
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作者 杜明婧 孙宝军 凯歌 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第3期53-57,共5页
This paper is aimed at solving the nonlinear time-fractional partial differential equation with two small parameters arising from option pricing model in financial economics.The traditional reproducing kernel(RK)metho... This paper is aimed at solving the nonlinear time-fractional partial differential equation with two small parameters arising from option pricing model in financial economics.The traditional reproducing kernel(RK)method which deals with this problem is very troublesome.This paper proposes a new method by adaptive multi-step piecewise interpolation reproducing kernel(AMPIRK)method for the first time.This method has three obvious advantages which are as follows.Firstly,the piecewise number is reduced.Secondly,the calculation accuracy is improved.Finally,the waste time caused by too many fragments is avoided.Then four numerical examples show that this new method has a higher precision and it is a more timesaving numerical method than the others.The research in this paper provides a powerful mathematical tool for solving time-fractional option pricing model which will play an important role in financial economics. 展开更多
关键词 time-fractional partial differential equation adaptive multi-step reproducing kernel method method numerical solution
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Controllable synthesis of CuAlO_(2) via solid-phase method and its catalytic performance for methanol steam reforming to hydrogen 被引量:3
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作者 QING Shaojun SUN Xun +3 位作者 LI Xinglong WANG Lei WU Zhiwei WANG Jianguo 《燃料化学学报(中英文)》 EI CAS CSCD 北大核心 2024年第11期1641-1651,共11页
This study explores the controllable synthesis of CuAlO_(2) using copper hydroxide and pseudo-boehmite powders as raw materials via a simple solid-phase ball milling method,along with its catalytic performance investi... This study explores the controllable synthesis of CuAlO_(2) using copper hydroxide and pseudo-boehmite powders as raw materials via a simple solid-phase ball milling method,along with its catalytic performance investigation in methanol steam reforming(MSR).Various catalysts were prepared under different conditions,such as calcination temperature,calcination atmosphere,and heating rate.Characterization techniques including BET,XRD,XPS,SEM and H2-TPR were employed to analyze the samples.The results revealed significant effects of calcination temperature on the phase compositions,specific surface area,reduction performance,and surface properties of the CA-T catalysts.Based on the findings,a synthesis route of CuAlO_(2) via the solid-phase method was proposed,highlighting the importance of high calcination temperature,nitrogen atmosphere,and low heating rate for CuAlO_(2) formation.Catalytic evaluation data demonstrated that CuAlO_(2) could catalyze MSR without pre-reduction,with the catalytic performance of CA-T catalysts being notably influenced by calcination temperature.Among the prepared catalysts,the CA-1100 catalyst exhibited the highest catalytic activity and stability.The findings of this study might be useful for the further study of the catalytic material for sustained release catalysis,including the synthesis of catalytic materials and the regulation of sustained release catalytic performance. 展开更多
关键词 CuAlO_(2) solid-phase method methanol steam reforming sustained release catalysis calcination temperature
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Chaos control of gear system with elastomeric web based on multi-parameter multi-step method
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作者 刘海霞 江波 +1 位作者 王三民 郭家舜 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2012年第5期23-30,共8页
This paper employs a multi-parameter multi-step chaos control method, which is built up on the OGY method, to stabilize desirable UPOs of a gear system with elastomeric web as a high-dimensional and non-hyperbolic cha... This paper employs a multi-parameter multi-step chaos control method, which is built up on the OGY method, to stabilize desirable UPOs of a gear system with elastomeric web as a high-dimensional and non-hyperbolic chaotic system, and the analyses are carried out. Three types of relations between components of a certain control parameter combination are defined in a certain control process. Special emphasis is put on the comparison of control efficiencies of the multi-parameter multi-step method and single-parameter multi-step method. The numerical experiments show the ability to switch between different orbits and the method can be a good chaos control alternative since it provides a more effective UPOs stabilization of high-dimensional and non-hyperbolic chaotic systems than the single-parameter chaos control, and according to the relation between components of each parameter combination, the best combination for chaos control in a certain UPO stabilization process are obtained. 展开更多
关键词 chaos control a gear system with elastomeric web multi-parameter multi-step method high-dimensional and non-hyperbolic system
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纳米级煤矸石煅烧高岭土的制备工艺参数优化 被引量:1
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作者 张雨涵 赵雪淞 +2 位作者 王雪松 吴秀琳 李婷婷 《煤炭转化》 北大核心 2025年第1期114-123,共10页
煤矸石中富含高岭土资源,为解决目前煤矸石中高岭土资源纳米级制备工艺存在的工艺烦琐、成本过高、产出率低等问题,采用超重力法制备纳米级煤矸石煅烧高岭土,通过单因素实验探究了旋转床转速(A)、反应时间(B)、物料流量(C)对煅烧高岭土... 煤矸石中富含高岭土资源,为解决目前煤矸石中高岭土资源纳米级制备工艺存在的工艺烦琐、成本过高、产出率低等问题,采用超重力法制备纳米级煤矸石煅烧高岭土,通过单因素实验探究了旋转床转速(A)、反应时间(B)、物料流量(C)对煅烧高岭土粒径分布的影响,在此基础上以煅烧高岭土的D_(90)为指标,采用响应面法进一步优化了制备参数。结果表明:超重力法制备纳米级煅烧高岭土的的回归方程为:Y=90.60-48.50A+17.62B+3.87C-11.50AB-3.50AC+25.25BC+25.33A^(2)+29.58B^(2)+28.58C^(2)。方差分析结果表明二次项A^(2),B^(2),C^(2)的P值均小于0.0001,说明其对高岭土平均粒径影响极显著。影响煅烧高岭土D_(90)的三个因素按影响程度由高到低排序为A,B,C;影响煅烧高岭土D_(90)的各个交互项按影响程度由高到低排序为BC,AB,AC。最佳工艺参数为:旋转床转速为1900 r/min,反应时间为16 min,物料流量为1600 mL/min,在此条件下得到的煅烧高岭土(N-K)的D_(90)为78 nm;由扫描电子显微镜、透射电子显微镜分析可知最优条件下制得的煅烧高岭土呈现分散状态且片层厚度范围为2 nm~8 nm,符合二维纳米材料所具有的特征。 展开更多
关键词 煤矸石 纳米级煅烧高岭土 超重力 响应面法 参数优化
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具有高效析氧性能的CeO_(2)/Fe-NiO异质纳米催化剂的制备
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作者 孙豪杰 郭瑞华 +3 位作者 王瑞芬 王丽 张国芳 刘媛媛 《功能材料》 北大核心 2025年第10期10171-10181,共11页
电解水制氢因为在实际应用过程中无碳排放,可持续等优点而被重视。然而在阳极的析氧反应(OER)能垒高和反应动力学缓慢,限制了高效电解水制氢的发展。设计出具有低成本,高效率和稳定耐用的OER催化剂的重要性日益凸显。研究采用共沉淀法... 电解水制氢因为在实际应用过程中无碳排放,可持续等优点而被重视。然而在阳极的析氧反应(OER)能垒高和反应动力学缓慢,限制了高效电解水制氢的发展。设计出具有低成本,高效率和稳定耐用的OER催化剂的重要性日益凸显。研究采用共沉淀法和煅烧法制备出以Fe掺杂NiO固溶体为基底,CeO_(2)为第二相的异质纳米催化剂,即CeO_(2)/Fe-NiO。CeO_(2)与Fe-NiO之间具有良好的协同效应,能够优化活性中间体的吸附,降低了反应过程中电子转移需要的能量,在碱性条件下表现出优异的催化性能,OER的过电势η10、塔菲尔斜率和双层电容(C dl)分别为198.7 mV、63.48 mV/dec和2.76 mF/cm^(2)。研究所制备的催化剂具有成分多样、基体元素地球储量丰富和催化性能好等优势,为探索开发高效廉价且在碱性环境中稳定耐用的OER催化剂提供了理论支撑。 展开更多
关键词 析氧反应 共沉淀法和煅烧法 CeO_(2) 异质结构
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CoMoO_(4)@MnMoO_(4)复合电极材料的制备及电化学性能
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作者 刘欣宇 相珺 +1 位作者 马冬梅 李威 《稀有金属与硬质合金》 北大核心 2025年第4期140-147,共8页
本研究通过两次水热法以及退火煅烧处理,制备出以泡沫镍为基底的CoMoO_(4)@MnMoO_(4)自支撑复合电极材料。利用X射线衍射仪(XRD)、扫描电子显微镜(SEM)研究电极材料物相组成与微观形貌,并通过电化学工作站对电极材料的电化学性能进行研... 本研究通过两次水热法以及退火煅烧处理,制备出以泡沫镍为基底的CoMoO_(4)@MnMoO_(4)自支撑复合电极材料。利用X射线衍射仪(XRD)、扫描电子显微镜(SEM)研究电极材料物相组成与微观形貌,并通过电化学工作站对电极材料的电化学性能进行研究测试。结果显示,CoMoO_(4)@MnMoO_(4)电极材料具有致密的纳米片层结构,且表面附着大量纳米颗粒,丰富的纳米片层间孔隙显著促进了离子传输,提供了大量活性位点,从而促进活性物质与电解质之间的法拉第氧化还原反应;该电极充放电时间可持续1 500 s,比电容在1 A/g的电流密度下高达726.6 C/g;此外,相较于单体CoMoO_(4)和MnMoO_(4)电极,CoMoO_(4)@MnMoO_(4)复合电极材料具有更优异的倍率性能。CoMoO_(4)@MnMoO_(4)复合电极材料相比其单体材料具有更突出的电化学性能。 展开更多
关键词 CoMoO_(4)@MnMoO_(4) 复合电极材料 水热法 退火 煅烧 电化学性能 显微组织
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磷尾矿煅粉碳化法制备碱式碳酸镁工艺研究
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作者 樊昊宇 李智力 +4 位作者 杨晶晶 郑泽民 柳凌 何东升 包峻豪 《河南化工》 2025年第6期12-18,共7页
以浮选后的高镁磷尾矿煅烧后的高活性煅粉为原料,经消化和碳化反应得到碳酸氢镁溶液,固液分离后溶液进行热解反应制备出碱式碳酸镁产品,通过XRD和XRF检测对热解产物进行表征。实验结果表明,最佳消化反应条件为温度60℃、时间40 min、液... 以浮选后的高镁磷尾矿煅烧后的高活性煅粉为原料,经消化和碳化反应得到碳酸氢镁溶液,固液分离后溶液进行热解反应制备出碱式碳酸镁产品,通过XRD和XRF检测对热解产物进行表征。实验结果表明,最佳消化反应条件为温度60℃、时间40 min、液固比20∶1 mL/g、搅拌速度200 r/min、陈化时间30 min。最佳碳化反应条件为CO_(2)流速200 mL/min、液固比30∶1(mL/g)、温度25℃、搅拌速度600 r/min和时间40 min。碳酸氢镁溶液在温度90℃和搅拌速度400 r/min下热解120 min,得到的碱式碳酸镁Mg_(5)(CO_(3))_(4)(OH)_(2)·4(H_(2)O)产品质量符合标准,实现了镁资源的高效回收利用。 展开更多
关键词 活性煅粉 消化 碳化法 热解 碱式碳酸镁
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单晶NCM811正极材料的制备以及电化学性能的研究
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作者 吴允龙 江晓雪 +1 位作者 郭旗 李翠芹 《现代化工》 CAS 北大核心 2025年第1期149-155,共7页
富镍层状正极材料(LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2),NCM811)因具有极高的充放电比容量被广泛关注,但是其在循环过程中面临着严重的结构退化以及界面不稳定的问题。采用多步煅烧法协同球磨法成功制备了单晶NCM811正极材料(SC-NCM),并对... 富镍层状正极材料(LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2),NCM811)因具有极高的充放电比容量被广泛关注,但是其在循环过程中面临着严重的结构退化以及界面不稳定的问题。采用多步煅烧法协同球磨法成功制备了单晶NCM811正极材料(SC-NCM),并对其电化学性能进行了测试。结果表明,以SC-NCM为正极、锂片为负极组装的半电池首圈库伦效率为85.4%,在1 C循环200次后拥有86.2%的容量保持率;以石墨为负极、SC-NCM为正极组装的全电池在相同的测试条件下达到了94.1%的容量保持率。通过对比传统NCM811(PC-NCM)与SC-NCM在循环期间的差异,分析得出对高镍三元正极材料长循环稳定性最大的影响因素;同时提出了多步煅烧法协同球磨法合成SC-NCM正极材料的新策略,以加速NCM811商业化。 展开更多
关键词 单晶NCM811 循环稳定性 SC-NCM||石墨全电池 多步煅烧法
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磷酸钒锂正极材料在空气气氛中的锻烧行为研究 被引量:1
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作者 孙陆毅 邹玉浩 +2 位作者 李明娟 李媛 陈鑫智 《电源技术》 北大核心 2025年第5期933-939,共7页
磷酸钒锂[Li_(3)V_(2)(PO_(4))_(3),简称LVP]因其较高的氧化还原电压和优异的理论比容量,近年来成为锂离子电池正极材料研究的热点。采用溶胶-凝胶法成功合成了LVP粉体,并系统探讨了其在不同温度下空气气氛中热处理后的物理化学性质演... 磷酸钒锂[Li_(3)V_(2)(PO_(4))_(3),简称LVP]因其较高的氧化还原电压和优异的理论比容量,近年来成为锂离子电池正极材料研究的热点。采用溶胶-凝胶法成功合成了LVP粉体,并系统探讨了其在不同温度下空气气氛中热处理后的物理化学性质演变规律。结果表明,500℃时,灰色LVP粉体发生转变,生成绿色固体,X射线衍射(XRD)分析确认其主相为磷酸氧钒锂(LiVOPO_(4));800℃时,灰色LVP粉体转化为熔融的黑色固体,XRD图谱呈现无特征峰的近似平直线条,表明LVP已演变为玻璃态。这些发现不仅丰富了对LVP材料的理解,也为进一步优化LVP材料的性能提供了重要的结构信息和理论基础。 展开更多
关键词 磷酸钒锂 正极材料 溶胶凝胶法 煅烧行为
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高活性氧化镁的制备和表征
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作者 孙佳妮 杨佳妮 +3 位作者 郝春来 赫丽杰 张启君 孙云龙 《化工技术与开发》 2025年第9期23-26,60,共5页
活性氧化镁是一种新型功能无机材料,在日常生活中得到越来越多的应用。本文探究了不同的煅烧条件对轻烧氧化镁活性的影响。采用水合法对活性进行了表征,可为工业生产提供数据支持。实验结果表明,在一次煅烧温度为750℃且保温时长为0.5h... 活性氧化镁是一种新型功能无机材料,在日常生活中得到越来越多的应用。本文探究了不同的煅烧条件对轻烧氧化镁活性的影响。采用水合法对活性进行了表征,可为工业生产提供数据支持。实验结果表明,在一次煅烧温度为750℃且保温时长为0.5h的条件下,所制备的轻烧氧化镁的活性值最高达到了82.36%。在一次煅烧的最优工艺条件下,经水化除杂后,二次煅烧温度为550℃、保温1h得到的氧化镁,活性最高达到85.55%。 展开更多
关键词 菱镁矿 活性氧化镁 水合法 煅烧工艺
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A Robust Hybrid Solution for Pull-in Instability of FG Nano Electro-Mechanical Switches Based on Surface Elasticity Theory
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作者 Vafa Mirzaei Mohammad Bameri +1 位作者 Peyman Moradweysi Mohammad Mohammadi Aghdam 《Computer Modeling in Engineering & Sciences》 2025年第6期2811-2832,共22页
The precise computation of nanoelectromechanical switches’(NEMS)multi-physical interactions requires advanced numerical models and is a crucial part of the development of micro-and nano-systems.This paper presents a ... The precise computation of nanoelectromechanical switches’(NEMS)multi-physical interactions requires advanced numerical models and is a crucial part of the development of micro-and nano-systems.This paper presents a novel compound numerical method to study the instability of a functionally graded(FG)beam-type NEMS,considering surface elasticity effects as stated by Gurtin-Murdoch theory in an Euler-Bernoulli beam.The presented method is based on a combination of the Method of Adjoints(MoA)together with the Bézier-based multistep technique.By utilizing the MoA,a boundary value problem(BVP)is turned into an initial value problem(IVP).The resulting IVP is then solved by employing a cost-efficient multi-step process.It is demonstrated that the mentioned method can arrive at a high level of accuracy.Furthermore,it is revealed that the stability of the presented methodology is far better than that of other common multi-step methods,such as Adams-Bashforth,particularly at higher step sizes.Finally,the effects of axially functionally graded(FG)properties on the pull-in phenomenon and the main design parameters of NEMS,including the detachment length,are inspected.It was shown that the main parameter of design is the modulus of elasticity of the material,as Silver(Ag),which had better mechanical properties,showed almost a 6%improvement compared to aluminum(Al).However,by applying the correct amount of material with sturdier surface parameters,such as Aluminum(Al),at certain points,the nanobeams’functionality can be improved even further by around 1.5%. 展开更多
关键词 Nano electro-mechanical switches pull-in instability surface elasticity theory method of Adjoints Bezier multi-step method
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Preparation of Silicon Fertilizer Using Lithium Pyroxene Acid-leaching Residues as Starting Materials
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作者 CHEN Jianghua LUO Dawei +2 位作者 GAO Zijie RONG Ke DENG Jiabao 《Journal of Wuhan University of Technology(Materials Science)》 2025年第2期389-399,共11页
We focus on a novel and economical route for the synthesis of Si fertilizer via the calcination method using lithium pyroxene acid-leaching residues as the starting materials.The molar ratio of Si/K/Ca of 1:1.4:0.8,ca... We focus on a novel and economical route for the synthesis of Si fertilizer via the calcination method using lithium pyroxene acid-leaching residues as the starting materials.The molar ratio of Si/K/Ca of 1:1.4:0.8,calcination temperature of 900℃and calcination time of 120 min were identified as the optimal conditions to maximize the available Si content of the prepared Si fertilizer.The performance of the resulting product satisfies the Chinese agricultural standard for silica fertilizers,providing a new solution for the large-scale harmless and sustainable reuse of lithium pyroxene tailings.The X-ray diffraction(XRD)and Fourier transform infrared spectroscopy(FTIR)characterization elucidated the formation mechanism of silica fertilizers,and identified KAlSiO_(4)and K_(4)CaSi_(3)O_(9)as the primary silicates products.Observation of the surface morphology of the samples was conducted by scanning electron microscopy(SEM)and X-ray energy dispersive spectrometry(EDS),and compositional analysis of the micro-regions.The acceleration action of CaCO_(3)in the decomposition process of lithium pyroxene acid-leaching residues was demonstrated by the thermogravimetry-differential scanning calorimetry(TG-DSC)test.Determination of heavy metal elements in Si fertilizer was performed by ICP-OES.Potting experiments confirmed that the best growth of pakchoi was achieved when 5 g·kg^(-1)of Si fertilizer was applied.These evidence suggests that the Si fertilizer prepared in this study is a promising candidate for a silica-supplemented soil. 展开更多
关键词 lithium pyroxene acid-leaching residues available silicon calcination method Si fertilizer
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煅烧因素对煤矸石煅烧产品白度及活性的影响
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作者 徐培杰 朱毅菲 +2 位作者 曹永丹 曹钊 辛学铭 《工程科学学报》 北大核心 2025年第7期1473-1484,共12页
煤矸石的大量堆存带来了一系列的生产安全隐患和环境污染问题.煅烧活化技术为实现煤矸石中有用元素和矿物的高质高效利用开辟了新途径,但目前煅烧因素对煤矸石白度及火山灰活性的影响缺乏系统研究.通过考察煅烧因素对煅烧煤矸石白度及... 煤矸石的大量堆存带来了一系列的生产安全隐患和环境污染问题.煅烧活化技术为实现煤矸石中有用元素和矿物的高质高效利用开辟了新途径,但目前煅烧因素对煤矸石白度及火山灰活性的影响缺乏系统研究.通过考察煅烧因素对煅烧煤矸石白度及火山灰活性的影响,探明了煤矸石煅烧前后物相组成、微观形貌、孔径分布、白度及火山灰活性的变化.结果表明,动态煅烧产品的白度值及火山灰活性高于静态煅烧产品.在煅烧温度为600~900℃、煅烧时间为2 h时,静态煅烧产品的白度值增加幅度高于动态煅烧产品,随着煅烧时间的延长,白度值持续增加.相较于静态煅烧,动态煅烧的烧结现象不明显.所得动态煅烧产品的比表面积、孔结构特征均优于静态煅烧产品.所得最佳煤矸石煅烧产品的煅烧方式为动态煅烧,煅烧温度900℃,煅烧时间2 h. 展开更多
关键词 煤矸石 煅烧方式 白度值 火山灰活性 孔结构
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Cu/Al_(2)O_(3)催化臭氧氧化深度处理造纸废水
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作者 尹宝河 常淑斌 +3 位作者 战树岩 贾振睿 高涛 杜静轩 《中国造纸》 北大核心 2025年第7期131-139,共9页
本研究首先以Al_(2)O_(3)为载体,采用浸渍-焙烧法制备了非均相催化剂Cu/Al_(2)O_(3),并对其进行表征;以天津某造纸厂废水为原料,开展了实验室规模的臭氧通入量(4、6、8和10 mg/min)、Cu/Al_(2)O_(3)用量(30、40、50和60 g/L)及循环水流... 本研究首先以Al_(2)O_(3)为载体,采用浸渍-焙烧法制备了非均相催化剂Cu/Al_(2)O_(3),并对其进行表征;以天津某造纸厂废水为原料,开展了实验室规模的臭氧通入量(4、6、8和10 mg/min)、Cu/Al_(2)O_(3)用量(30、40、50和60 g/L)及循环水流速(0、40、80和120 mL/min)对出水化学需氧量(COD)影响的测试;最终将Cu/Al_(2)O_(3)催化臭氧氧化工艺作为废水深度处理工艺,开展中试试验。结果表明,Cu可以通过浸渍-焙烧法负载在载体表面。在实验室测试中,当臭氧通入量为8 mg/min、Cu/Al_(2)O_(3)用量为50 g/L、循环水流速为120 mL/min时,废水COD_(Cr)从64.0 mg/L降至21.8 mg/L,COD_(Cr)去除率为65.9%。在中试试验中,当中试试验进水的COD_(Cr)在50.0~65.0 mg/L范围波动时,出水的COD_(Cr)均低于30 mg/L,COD_(Cr)去除率稳定在63.1%左右,出水COD符合GB 3544—2008《制浆造纸工业水污染物排放标准》中的排放标准,表明制备的催化剂活性稳定,无二次污染。 展开更多
关键词 催化臭氧氧化 非均相催化剂 造纸废水 深度处理 浸渍-焙烧法
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Ag包覆对正极材料LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)性能的影响
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作者 王树新 郑舒 《电源技术》 北大核心 2025年第3期543-548,共6页
为了提高LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)的稳定性和倍率性能,采用湿法和高温煅烧法对其表面进行Ag包覆改性。利用X射线衍射、扫描电子显微镜和电化学充放电等测试,对材料结构进行表征和电化学性能测试,结果表明:单质Ag可以均匀包覆LiN... 为了提高LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)的稳定性和倍率性能,采用湿法和高温煅烧法对其表面进行Ag包覆改性。利用X射线衍射、扫描电子显微镜和电化学充放电等测试,对材料结构进行表征和电化学性能测试,结果表明:单质Ag可以均匀包覆LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)材料表面,且不影响材料的晶体结构,Ag包覆可提高材料在工作过程中的循环稳定性和倍率性能。实验所得材料常温1 C倍率下的放电比容量高达173.7 mAh/g,25℃下1 C循环2000次后容量保持率在89%以上。 展开更多
关键词 电化学性能 LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)正极材料 煅烧法
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SnS纳米花的制备及其在挥发性有机化合物气体传感中的应用
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作者 李子恒 张明雪 +1 位作者 张泽宇 闫爽 《大连工业大学学报》 2025年第4期307-312,共6页
二维硫族化合物作为气体传感器敏感材料具有高响应、低功耗的优势,但其较差的导电性制约了实际应用。制备了一种由超薄纳米片组装而成的花状SnS纳米结构,用于挥发性有机化合物(VOCs)气体检测。首先采用水热法合成纳米花状SnS_(2)纳米结... 二维硫族化合物作为气体传感器敏感材料具有高响应、低功耗的优势,但其较差的导电性制约了实际应用。制备了一种由超薄纳米片组装而成的花状SnS纳米结构,用于挥发性有机化合物(VOCs)气体检测。首先采用水热法合成纳米花状SnS_(2)纳米结构,再通过热氧化-氮气煅烧法制备花状SnS纳米片。该花状结构具有较大比表面积,可确保气敏过程中敏感材料与目标气体的有效接触;同时,材料优良的结晶度克服了敏感材料导电性差的问题。在200℃工作温度下,SnS传感器对体积分数为1.00×10^(-4)乙醇的响应值高达13.3,表现出稳定的响应性能和优异的恢复特性。 展开更多
关键词 气敏传感器 纳米花 水热法 热氧化-氮气煅烧法
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