Prediction of production decline and evaluation of the adsorbed/free gas ratio are critical for determining the lifespan and production status of shale gas wells.Traditional production prediction methods have some sho...Prediction of production decline and evaluation of the adsorbed/free gas ratio are critical for determining the lifespan and production status of shale gas wells.Traditional production prediction methods have some shortcomings because of the low permeability and tightness of shale,complex gas flow behavior of multi-scale gas transport regions and multiple gas transport mechanism superpositions,and complex and variable production regimes of shale gas wells.Recent research has demonstrated the existence of a multi-stage isotope fractionation phenomenon during shale gas production,with the fractionation characteristics of each stage associated with the pore structure,gas in place(GIP),adsorption/desorption,and gas production process.This study presents a new approach for estimating shale gas well production and evaluating the adsorbed/free gas ratio throughout production using isotope fractionation techniques.A reservoir-scale carbon isotope fractionation(CIF)model applicable to the production process of shale gas wells was developed for the first time in this research.In contrast to the traditional model,this model improves production prediction accuracy by simultaneously fitting the gas production rate and δ^(13)C_(1) data and provides a new evaluation method of the adsorbed/free gas ratio during shale gas production.The results indicate that the diffusion and adsorption/desorption properties of rock,bottom-hole flowing pressure(BHP)of gas well,and multi-scale gas transport regions of the reservoir all affect isotope fractionation,with the diffusion and adsorption/desorption parameters of rock having the greatest effect on isotope fractionation being D∗/D,PL,VL,α,and others in that order.We effectively tested the universality of the four-stage isotope fractionation feature and revealed a unique isotope fractionation mechanism caused by the superimposed coupling of multi-scale gas transport regions during shale gas well production.Finally,we applied the established CIF model to a shale gas well in the Sichuan Basin,China,and calculated the estimated ultimate recovery(EUR)of the well to be 3.33×10^(8) m^(3);the adsorbed gas ratio during shale gas production was 1.65%,10.03%,and 23.44%in the first,fifth,and tenth years,respectively.The findings are significant for understanding the isotope fractionation mechanism during natural gas transport in complex systems and for formulating and optimizing unconventional natural gas development strategies.展开更多
A unified mathematical model is established to simulate the nonlinear unsteady percolation of shale gas with the consideration of the nonlinear multi-scale effects such as slippage, diffusion, and desorption. The cont...A unified mathematical model is established to simulate the nonlinear unsteady percolation of shale gas with the consideration of the nonlinear multi-scale effects such as slippage, diffusion, and desorption. The continuous inhomogeneous models of equivalent porosity and permeability are proposed for the whole shale gas reservoir includ- ing the hydraulic fracture, the micro-fracture, and the matrix regions. The corresponding semi-analytical method is developed by transforming the nonlinear partial differential governing equation into the integral equation and the numerical discretization. The nonlinear multi-scale effects of slippage and diffusion and the pressure dependent effect of desorption on the shale gas production are investigated.展开更多
The application of ecosystem services(ES)theories in land consolidation is a confusing issue that has long plagued scholars and government officials.As the upgraded version of traditional land consolidation,comprehens...The application of ecosystem services(ES)theories in land consolidation is a confusing issue that has long plagued scholars and government officials.As the upgraded version of traditional land consolidation,comprehensive land consolidation(CLC)emphasizes ecological benefits,but it does not achieve the expected effect during the pilot phase.This study first proposed a theoretical analysis framework based on ES knowledge to answer the three key questions of why,where,and how to implement CLC better.Taking mountainous counties as the study area,we found that ES trade-offs/synergies,bundles,and drivers were significantly affected by scale effects.ES knowledge can play a crucial role in designing multi-scale CLC strategies regarding the objective,zoning,intensity,and mode.Specifically,mitigating the significant trade-offs between recreational opportunities,food production,and other ES is the top priority of CLC.Land consolidation zoning based on the ES bundles analysis is more rational and can provide the scientific premise for designing locally adapted CLC measures.Land consolidation can be classified into high-intensity direct intervention and low-intensity indirect intervention modes,based on the major drivers of ES.These findings help narrow the gap between ES and CLC practices.展开更多
Located in Eurasia inland,Tacheng Basin belongs to arid and semi-arid climate region in middle temperate zone,and the main crops include winter wheat,spring wheat,maize,seeding-watermelon,sugar beet and so on,while wi...Located in Eurasia inland,Tacheng Basin belongs to arid and semi-arid climate region in middle temperate zone,and the main crops include winter wheat,spring wheat,maize,seeding-watermelon,sugar beet and so on,while winter wheat is the main food crop.From November 2009 to March 2010,a snowstorm which occurred every 60 years appeared in Tacheng Basin,and there was more snowfall in five continuous months,while this snowfall broke through the extreme value in history and reached a historic high.Based on the comparison between practical monitoring data and history data of winter wheat,the effects of snowstorm on winter wheat production were analyzed.展开更多
Based on statistic data of agricultural production and meteorological disasters in Liaoning Province from 1971 to 2008,the effect weight,disaster rate and variance value of main agro-meteorological disasters including...Based on statistic data of agricultural production and meteorological disasters in Liaoning Province from 1971 to 2008,the effect weight,disaster rate and variance value of main agro-meteorological disasters including drought,flood,wind,hail and frozen injury were calculated,and the variation characteristic of time series of agro-meteorological disasters was further analyzed,while the grade division and comprehensive evaluation of agro-meteorological disasters were carried out in our paper.The results showed that there was a negative correlation between grain yield and the degree of agro-meteorological disasters,and agro-meteorological disasters were relatively serious in 1989,1997 and 2000,with the reduction of grain yield.Meanwhile,the occurrence frequency of light disasters was highest,accounting for 39% of total years,and the adverse effect of agro-meteorological disasters on agricultural production became more and more severe decade by decade;the effect weight of drought reached 63%,so drought was the main agro-meteorological disaster influencing agricultural production.展开更多
Chinese farmers are often accused of overusing pesticides that play a crucial role in enhancing crop yield by reducing losses to crop pests. Pesticide overuse has caused a series of negative health and environmental e...Chinese farmers are often accused of overusing pesticides that play a crucial role in enhancing crop yield by reducing losses to crop pests. Pesticide overuse has caused a series of negative health and environmental externalities. This paper quantiifes the productivity effect and the optimal amount of pesticides in rice, cotton and maize production in China from the economic perspective. Using survey data col ected in 2012 and 2013, both Cobb-Douglas and Weibul damage control speciifcations are used to estimate the production function. Results show that pesticides have statistical y signiifcant pro-ductivity effect on crop yield. On the condition of Weibul damage control speciifcations, the marginal products of 1 kg of the active ingredients of pesticides for rice, cotton and maize are 71.06, 22.73 and 98.45 kg, respectively. However, 57, 64 and 17%of the actual amount of pesticides are overused for rice, cotton and maize, respectively. Moreover, the productivity effect of pesticides would be overestimated using Cobb-Douglas speciifcation without incorporating a damage control agent.展开更多
Grazing is a main human activity in the grasslands of Xinjiang, China. It is vital to identify the effects of grazing on the sustainable utilization of local grasslands. However, the effects of grazing on net primary ...Grazing is a main human activity in the grasslands of Xinjiang, China. It is vital to identify the effects of grazing on the sustainable utilization of local grasslands. However, the effects of grazing on net primary productivity （NPP）, evapotranspiration （ET） and water use efficiency （WUE） in this region remain unclear. Using the spatial Biome-BGC grazing model, we explored the effects of grazing on NPP, ET and WUE across the different regions and grassland types in Xinjiang during 1979-2012. NPP, ET and WUE under the grazed scenario were generally lower than those under the ungrazed scenario, and the differences showed increasing trends over time. The decreases in NPP, ET and WUE varied significantly among the regions and grassland types. NPP decreased as follows： among the regions, Northern Xinjiang （16.60 g C/（m2·a））, Tianshan Mountains （15.94 g C/（m2·a）） and Southern Xinjiang （-3.54 g C/（m2·a））; and among the grassland types, typical grasslands （25.70 g C/（m2·a））, swamp meadows （25.26 g C/（m2·a））, mid-mountain meadows （23.39 g C/（m2·a））, alpine meadows （6.33 g C/（m2·a））, desert grasslands （5.82 g C/（m2·a）） and saline meadows （2.90 g C/（me.a））. ET decreased as follows： among the regions, Tianshan Mountains （28.95 mm/a）, Northern Xinjiang （8.11 mm/a） and Southern Xinjiang （7.57 mm/a）; and among the grassland types, mid-mountain meadows （29.30 mm/a）, swamp meadows （25.07 mm·a）, typical grasslands （24.56 mm/a）, alpine meadows （20.69 mm/a）, desert grasslands （11.06 mm/a） and saline meadows （3.44 mm/a）. WUE decreased as follows： among the regions, Northern Xinjiang （0.053 g C/kg H2O）, Tianshan Mountains （0.034 g C/kg H2O） and Southern Xinjiang （0.012 g C/kg H2O）; and among the grassland types, typical grasslands （0.0609 g C/kg H2O）, swamp meadows （0.0548 g C/kg H2O）, mid-mountain meadows （0.0501 g C/kg H2O）, desert grasslands （0.0172 g C/kg H2O）, alpine meadows （0.0121 g C/kg H2O） and saline meadows （0.0067 g C/kg H2O）. In general, the decreases in NPP and WUE were more significant in the regions with relatively high levels of vegetation growth because of the high grazing intensity in these regions. The decreases in ET were significant in mountainous areas due to the terrain and high grazing intensity.展开更多
The demand of high-end electromagnetic wave absorbing materials puts forward higher requirements on comprehensive performances of small thickness,lightweight,broadband,and strong absorption.Herein,a novel multi-layer ...The demand of high-end electromagnetic wave absorbing materials puts forward higher requirements on comprehensive performances of small thickness,lightweight,broadband,and strong absorption.Herein,a novel multi-layer stepped metamaterial absorber with gradient electromagnetic properties is proposed.The complex permittivity and permeability of each layer are tailored via the proportion of carbonyliron and carbon-fiber dispersing into the epoxy resin.The proposed metamaterial is further optimized via adjusting the electromagnetic parameters and geometric sizes of each layer.Comparing with the four-layer composite with gradient electromagnetic properties which could only realize reflection loss(RL)of less than−6 dB in 2.0-40 GHz,the optimized stepped metamaterial with the same thickness and electromagnetic properties realizes less than−10 dB in the relevant frequency range.Additionally,the RL of less than−15 dB is achieved in the frequency range of 11.2-21.4 GHz and 28.5-40 GHz.The multiple electromagnetic wave absorption mechanism is discussed based on the experimental and simulation results,which is believed to be attributed to the synergy effect induced by multi-scale structures of the metamaterial.Therefore,combining multi-layer structures and periodic stepped structures into a novel gradient absorbing metamaterial would give new insights into designing microwave absorption devices for broadband electromagnetic protections.展开更多
A large number of nanopores and complex fracture structures in shale reservoirs results in multi-scale flow of oil. With the development of shale oil reservoirs, the permeability of multi-scale media undergoes changes...A large number of nanopores and complex fracture structures in shale reservoirs results in multi-scale flow of oil. With the development of shale oil reservoirs, the permeability of multi-scale media undergoes changes due to stress sensitivity, which plays a crucial role in controlling pressure propagation and oil flow. This paper proposes a multi-scale coupled flow mathematical model of matrix nanopores, induced fractures, and hydraulic fractures. In this model, the micro-scale effects of shale oil flow in fractal nanopores, fractal induced fracture network, and stress sensitivity of multi-scale media are considered. We solved the model iteratively using Pedrosa transform, semi-analytic Segmented Bessel function, Laplace transform. The results of this model exhibit good agreement with the numerical solution and field production data, confirming the high accuracy of the model. As well, the influence of stress sensitivity on permeability, pressure and production is analyzed. It is shown that the permeability and production decrease significantly when induced fractures are weakly supported. Closed induced fractures can inhibit interporosity flow in the stimulated reservoir volume (SRV). It has been shown in sensitivity analysis that hydraulic fractures are beneficial to early production, and induced fractures in SRV are beneficial to middle production. The model can characterize multi-scale flow characteristics of shale oil, providing theoretical guidance for rapid productivity evaluation.展开更多
Twenty-one typical coupled large samples were chosen from areas within and surrounding nature reserves on the Tibetan Plateau using the large sample comparison method(LSCM).To evaluate the effectiveness of the nature ...Twenty-one typical coupled large samples were chosen from areas within and surrounding nature reserves on the Tibetan Plateau using the large sample comparison method(LSCM).To evaluate the effectiveness of the nature reserves in protecting the ecological environment,the alpine grassland net primary production(NPP) of these coupled samples were compared and the differences between them before and after their establishment as protected areas were analyzed.The results showed that:(1) With respect to the alpine grassland NPP,the ecological and environmental conditions of most nature reserves were more fragile than those of the surrounding areas and also lower than the average values for the Tibetan Plateau.(2) Of the 11 typical nature reserves selected,the positive trend in the NPP for Manzetang was the most significant,whereas there was no obvious trend in Taxkorgan.With the exception of Selincuo,the annual NPP growth rate in the nature reserves covered by alpine meadow and wetland was higher than that in nature reserves consisting of alpine steppe and alpine desert.(3) There were notable findings in 21 typical coupled samples:(a) After the establishment of the nature reserves,the annual rate of increase in the NPP in 76% of samples inside nature reserves and 82% of samples inside national nature reserves was higher than that of the corresponding samples outside nature reserves.(b) The effectiveness of ecological protection of the Mid-Kunlun,Changshagongma,Zoige and Selincuo(Selin Co) nature reserves was significant; the effectiveness of protection was relatively sig-nificant in most parts of the Sanjiangyuan and Qiangtang nature reserves,whereas in south-east Manzetang and north Taxkorgan the protection effectiveness was not obvious.(c) The ecological protection effectiveness was significant in nature reserves consisting of alpine meadow,but was weak in nature reserves covered by alpine steppe.This study also shows that the advantage of large sample comparison method in evaluating regional ecology change.Careful design of the samples used,to ensure comparability between the samples,is crucial to the success of this LSCM.展开更多
The frequency domain electromagnetic method has already been widely used for tomographic imaging or electromagnetic well logging. However, different from open hole logging, the metal casing existing in production well...The frequency domain electromagnetic method has already been widely used for tomographic imaging or electromagnetic well logging. However, different from open hole logging, the metal casing existing in production well logging has a strong shielding effect on the electromagnetic waves, thus bringing some difficulties to the application of the frequency domain electromagnetic method in production well logging. According to the relation of the field source geometry to the ring around the mandrel, the general expressions of frequency domain electromagnetic responses in axially symmetrical layered conductive medium are deduced. The propagation effects caused by the low-frequency electromagnetic waves in cased hole are also analyzed. The distribution curves of eddy current density and magnetic flux density along the radial direction in the mandrel indicate that the eddy loss within the mandrel is proportional to the transmission signal frequency and the mandrel conductivity. The secondary field responses of different casing materials show that the transmission frequency has an important effect on the ability of electromagnetic waves penetrating the metal casing. The transmission frequency should be ultra-low in order to enable the electromagnetic signal to penetrate the casing easily. The numerical results of frequency responses for different casing physical parameters show that the casing thickness has a significant impact on the choice of the transmission frequency. It is also found that the effect of the casing radius on the transmission frequency can be neglected.展开更多
The spatiotemporal characteristics of hydrothermal resources in southern rice production area of China have changed under the background of climate change,and this change would affect the effectiveness of hydrothermal...The spatiotemporal characteristics of hydrothermal resources in southern rice production area of China have changed under the background of climate change,and this change would affect the effectiveness of hydrothermal resources during local rice growing period.According to the cropping system subdivision in southern rice production area of China during 1980s,this study used climate data from 254 meteorological stations and phonological data from 168 agricultural observation stations in the south of China,and adopted 6 international evaluation indices about the effectiveness of hydrothermal resources to analyze the temporal and spatial characteristics of hydrothermal resources during the growing period of single cropping rice system and double cropping rice system for 16 planting zones in the whole study area.The results showed that：in southern rice production area of China,the effectiveness of thermal resources of single cropping rice area（SCRA） was less than that of double cropping rice area（DCRA）,whereas the effectiveness of thermal resources of both SARA and DCRA showed a decreasing trend.The index value of effective precipitation satisfaction of SCRA was higher than that of DCRA,nevertheless the index value of effective precipitation satisfaction of both SCRA and DCRA showed a decreasing trend.There was a significant linear relationship between effective thermal resource and water demand,likely water demand increased by 18 mm with every 100°C d increase of effective heat.Effective precipitation satisfaction index（EPSI） showed a negative correlation with effective heat,yet showed a positive correlation with effective precipitation.EPSI reduced by 1% when effective heat resource increased by 125°C d.This study could provide insights for policy makers,land managers or farmers to improve water and heat resource uses and rationally arrange rice production activities under global climate change condition.展开更多
Annulus fibrosus （AF） tissue engineering has recently received increasing attention as a treatment for intervertebral disc 0VD） degeneration; however, such engineering remains challenging because of the remarkable ...Annulus fibrosus （AF） tissue engineering has recently received increasing attention as a treatment for intervertebral disc 0VD） degeneration; however, such engineering remains challenging because of the remarkable complexity of AF tissue. In order to engineer a functional AF replacement, the fabrication of cell-scaffold constructs that mimic the cellular, biochemical and structural features of native AF tissue is critical. In this study, we fabricated aligned fibroua polyurethane scaffolds using an electrospinning technique and used them for culturing AF-derived-stem/progenitor cells （AFSCs）. Random fibrous scaffolds, also prepared via electrospinningy were used as a control. We compared the morphology, proliferation, gene expression and matrix production of AFSCs on aligned scaffolds and random scaffolds. There was no apparent difference in the attachment or proliferation of cells cultured on aligned scaffolds and random scaffolds. However, compared to cells on random scaffolds, the AFSCs on aligned scaffolds were more elongated and better aligned, and they exhibited higher gene expression and matrix production of coUagen-I and aggrecan. The gene expression and protein production of coUagen-II did not appear to differ between the two groups. Together, these findings indicate that aligned fibrous scaffolds may provide a favourable microenvironment for the differentiation of AFSCs into cells similar to outer AF cells, which predominantly produce collagen-I matrix.展开更多
The vibration problem of a fluid conveying cylindrical shell consisted of newly developed multi-scale hybrid nanocomposites is solved in the present manuscript within the framework of an analytical solution.The consis...The vibration problem of a fluid conveying cylindrical shell consisted of newly developed multi-scale hybrid nanocomposites is solved in the present manuscript within the framework of an analytical solution.The consistent material is considered to be made from an initial matrix strengthened via both macro-and nano-scale reinforcements.The influence of nanofillers’agglomeration,generated due to the high surface to volume ratio in nanostructures,is included by implementing Eshelby-Mori-Tanaka homogenization scheme.Afterwards,the equivalent material properties of the carbon nanotube reinforced(CNTR)nanocomposite are coupled with those of CFs within the framework of a modified rule of mixture.On the other hand,the influences of viscous flow are covered by extending the Navier-Stokes equation for cylinders.A cylindrical coordinate system is chosen and mixed with the infinitesimal strains of first-order shear deformation theory of shells to obtain the motion equations on the basis of the dynamic form of principle of virtual work.Next,the achieved governing equations will be solved by Galerkin’s method to reach the natural frequency of the structure for both simply supported and clamped boundary conditions.Presenting a set of illustrations,effects of each parameter on the dimensionless frequency of nanocomposite shells will be shown graphically.展开更多
Based on data of monthly sunshine duration in Shouguang City during 1961-2013,changing features of sunshine duration and effects on greenhouse production in Shouguang City were analyzed by using linear tendency method...Based on data of monthly sunshine duration in Shouguang City during 1961-2013,changing features of sunshine duration and effects on greenhouse production in Shouguang City were analyzed by using linear tendency method,M-K mutation test and Molet wavelet analysis. The results show that in Shouguang City,sunshine duration in a year and each season reduced obviously from 1961 to 2013,and sunshine duration in a year and autumn changed suddenly in the 1990s,while sunshine duration in winter and spring changed suddenly in the 1980s. There existed obvious periodic variations of sunshine duration in a year and various seasons from 1961 to 2013. The reduction of sunshine duration and the increase of cloudy days resulted in the decrease in the yield of crops in solar greenhouses,so some effective measures should be taken to enhance the light intensity and time in solar greenhouses to promote crop growth.展开更多
An optimization model is proposed to examine the choice of sharing or not sharing the product link for manufacturing firms with owned social media by considering the role of fan effects.The equilibrium marketing effor...An optimization model is proposed to examine the choice of sharing or not sharing the product link for manufacturing firms with owned social media by considering the role of fan effects.The equilibrium marketing effort level and firm profit in both cases are compared.The results show that the firm chooses to share(not share)the product link when the social platform commission rate is low(high).Moreover,the likelihood of sharing the product link increases as the fan effect weakens and the perceived conversion cost strengthens.Interestingly,the marketing effort level increases with the product price,but firm profit does not always follow.Additionally,as the fan effect and fan count grow,so does the firm s profit.Furthermore,when the firm shares the product link,the level of marketing effort and firm profit decrease with the commission rate.Conversely,when the firm does not share the product link,those aforementioned factors increase as the perceived conversion cost declines.These results thus suggest that firms should enhance the influence of owned social media to attract more high-quality fans,and social platforms should optimize the product link functionality.展开更多
Electrochemical ozone production(EOP) via water electrolysis represents an attractive method for the generation of high-purity O3. Herein, the X-PtZn/Zn-N-C electrocatalysts show a strong structural sensitive behavior...Electrochemical ozone production(EOP) via water electrolysis represents an attractive method for the generation of high-purity O3. Herein, the X-PtZn/Zn-N-C electrocatalysts show a strong structural sensitive behavior depends on the size of the PtZn nanoparticles and their EOP activity exhibits a volcano-type dependence for the O3 performance in neutral media. The 7.7-PtZn/Zn-N-C exhibits EOP current efficiency of 4.2%, and shows the prominent performance in the production of gaseous O3 with a value of 1647 ppb at 30 min, which is almost 4-fold compared to 2.2-Pt Zn/Zn-N-C. Based on the experiments and theoretical calculations, the performance of the EOP process was determined by the nanoparticle size-effect and the synergistic effect between the PtZn nanoparticles and atomically dispersed Zn-N-C. Furthermore, the fivemembered cyclic structure of O3 can be stabilized between the PtZn nanoparticle and the Zn-N-C support,indicating that O3 is produced at the interface.展开更多
Cadmium （Cd） is an elemental heavy metal with widely recognized toxicity. Its long-term use in industrial processes and daily activities has caused alarming levels of Cd contamination in the natural environment. Acc...Cadmium （Cd） is an elemental heavy metal with widely recognized toxicity. Its long-term use in industrial processes and daily activities has caused alarming levels of Cd contamination in the natural environment. According to the estimates by the Agency of Toxic Substances and Disease Registry in the US, 25 000 to 30 000 metric tons of Cd is annually released to the environment . Results of previous studies have demonstrated that several organs are targets of Cd, but the most important of these targeted organs may be the testes.展开更多
The pan-Arctic is confronted with air pollution transported from lower latitudes.Observations have shown that aerosols help increase plant photosynthesis through the diffuse radiation fertilization effects(DRFEs).Whil...The pan-Arctic is confronted with air pollution transported from lower latitudes.Observations have shown that aerosols help increase plant photosynthesis through the diffuse radiation fertilization effects(DRFEs).While such DRFEs have been explored at low to middle latitudes,the aerosol impacts on pan-Arctic ecosystems and the contributions by anthropogenic and natural emission sources remain less quantified.Here,we perform regional simulations at 0.2o×0.2ousing a well-validated vegetation model(Yale Interactive terrestrial Biosphere,YIBs)in combination with multi-source of observations to quantify the impacts of aerosol DRFEs on the net primary productivity(NPP)in the pan-Arctic during 2001-19.Results show that aerosol DRFEs increase pan-Arctic NPP by 2.19 Pg C(12.8%)yr^(-1)under clear-sky conditions,in which natural and anthropogenic sources contribute to 8.9% and 3.9%,respectively.Under all-sky conditions,such DRFEs are largely dampened by cloud to only 0.26 Pg C(1.24%)yr^(-1),with contributions of 0.65% by natural and 0.59% by anthropogenic species.Natural aerosols cause a positive NPP trend of 0.022% yr^(-1)following the increased fire activities in the pan-Arctic.In contrast,anthropogenic aerosols induce a negative trend of-0.01% yr^(-1)due to reduced emissions from the middle latitudes.Such trends in aerosol DRFEs show a turning point in the year of 2007 with more positive NPP trends by natural aerosols but negative NPP trends by anthropogenic aerosols thereafter.Though affected by modeling uncertainties,this study suggests a likely increasing impact of aerosols on terrestrial ecosystems in the pan-Arctic under global warming.展开更多
基金supported by the Natural Science Foundation of China(Grant No.42302170)National Postdoctoral Innovative Talent Support Program(Grant No.BX20220062)+3 种基金CNPC Innovation Found(Grant No.2022DQ02-0104)National Science Foundation of Heilongjiang Province of China(Grant No.YQ2023D001)Postdoctoral Science Foundation of Heilongjiang Province of China(Grant No.LBH-Z22091)the Natural Science Foundation of Shandong Province(Grant No.ZR2022YQ30).
文摘Prediction of production decline and evaluation of the adsorbed/free gas ratio are critical for determining the lifespan and production status of shale gas wells.Traditional production prediction methods have some shortcomings because of the low permeability and tightness of shale,complex gas flow behavior of multi-scale gas transport regions and multiple gas transport mechanism superpositions,and complex and variable production regimes of shale gas wells.Recent research has demonstrated the existence of a multi-stage isotope fractionation phenomenon during shale gas production,with the fractionation characteristics of each stage associated with the pore structure,gas in place(GIP),adsorption/desorption,and gas production process.This study presents a new approach for estimating shale gas well production and evaluating the adsorbed/free gas ratio throughout production using isotope fractionation techniques.A reservoir-scale carbon isotope fractionation(CIF)model applicable to the production process of shale gas wells was developed for the first time in this research.In contrast to the traditional model,this model improves production prediction accuracy by simultaneously fitting the gas production rate and δ^(13)C_(1) data and provides a new evaluation method of the adsorbed/free gas ratio during shale gas production.The results indicate that the diffusion and adsorption/desorption properties of rock,bottom-hole flowing pressure(BHP)of gas well,and multi-scale gas transport regions of the reservoir all affect isotope fractionation,with the diffusion and adsorption/desorption parameters of rock having the greatest effect on isotope fractionation being D∗/D,PL,VL,α,and others in that order.We effectively tested the universality of the four-stage isotope fractionation feature and revealed a unique isotope fractionation mechanism caused by the superimposed coupling of multi-scale gas transport regions during shale gas well production.Finally,we applied the established CIF model to a shale gas well in the Sichuan Basin,China,and calculated the estimated ultimate recovery(EUR)of the well to be 3.33×10^(8) m^(3);the adsorbed gas ratio during shale gas production was 1.65%,10.03%,and 23.44%in the first,fifth,and tenth years,respectively.The findings are significant for understanding the isotope fractionation mechanism during natural gas transport in complex systems and for formulating and optimizing unconventional natural gas development strategies.
基金supported by the National Basic Research Program of China(973 Program)(No.2013CB228002)
文摘A unified mathematical model is established to simulate the nonlinear unsteady percolation of shale gas with the consideration of the nonlinear multi-scale effects such as slippage, diffusion, and desorption. The continuous inhomogeneous models of equivalent porosity and permeability are proposed for the whole shale gas reservoir includ- ing the hydraulic fracture, the micro-fracture, and the matrix regions. The corresponding semi-analytical method is developed by transforming the nonlinear partial differential governing equation into the integral equation and the numerical discretization. The nonlinear multi-scale effects of slippage and diffusion and the pressure dependent effect of desorption on the shale gas production are investigated.
基金National Natural Science Foundation of China,No.42171255,No.41971216。
文摘The application of ecosystem services(ES)theories in land consolidation is a confusing issue that has long plagued scholars and government officials.As the upgraded version of traditional land consolidation,comprehensive land consolidation(CLC)emphasizes ecological benefits,but it does not achieve the expected effect during the pilot phase.This study first proposed a theoretical analysis framework based on ES knowledge to answer the three key questions of why,where,and how to implement CLC better.Taking mountainous counties as the study area,we found that ES trade-offs/synergies,bundles,and drivers were significantly affected by scale effects.ES knowledge can play a crucial role in designing multi-scale CLC strategies regarding the objective,zoning,intensity,and mode.Specifically,mitigating the significant trade-offs between recreational opportunities,food production,and other ES is the top priority of CLC.Land consolidation zoning based on the ES bundles analysis is more rational and can provide the scientific premise for designing locally adapted CLC measures.Land consolidation can be classified into high-intensity direct intervention and low-intensity indirect intervention modes,based on the major drivers of ES.These findings help narrow the gap between ES and CLC practices.
文摘Located in Eurasia inland,Tacheng Basin belongs to arid and semi-arid climate region in middle temperate zone,and the main crops include winter wheat,spring wheat,maize,seeding-watermelon,sugar beet and so on,while winter wheat is the main food crop.From November 2009 to March 2010,a snowstorm which occurred every 60 years appeared in Tacheng Basin,and there was more snowfall in five continuous months,while this snowfall broke through the extreme value in history and reached a historic high.Based on the comparison between practical monitoring data and history data of winter wheat,the effects of snowstorm on winter wheat production were analyzed.
基金Supported by Scientific and Technological Development Project of Shenyang Regional Climate Center(201015)~~
文摘Based on statistic data of agricultural production and meteorological disasters in Liaoning Province from 1971 to 2008,the effect weight,disaster rate and variance value of main agro-meteorological disasters including drought,flood,wind,hail and frozen injury were calculated,and the variation characteristic of time series of agro-meteorological disasters was further analyzed,while the grade division and comprehensive evaluation of agro-meteorological disasters were carried out in our paper.The results showed that there was a negative correlation between grain yield and the degree of agro-meteorological disasters,and agro-meteorological disasters were relatively serious in 1989,1997 and 2000,with the reduction of grain yield.Meanwhile,the occurrence frequency of light disasters was highest,accounting for 39% of total years,and the adverse effect of agro-meteorological disasters on agricultural production became more and more severe decade by decade;the effect weight of drought reached 63%,so drought was the main agro-meteorological disaster influencing agricultural production.
基金financial support from the National Natural Science Foundation of China (71173014 and 71210004)the China Scholarship Council (201306030053)
文摘Chinese farmers are often accused of overusing pesticides that play a crucial role in enhancing crop yield by reducing losses to crop pests. Pesticide overuse has caused a series of negative health and environmental externalities. This paper quantiifes the productivity effect and the optimal amount of pesticides in rice, cotton and maize production in China from the economic perspective. Using survey data col ected in 2012 and 2013, both Cobb-Douglas and Weibul damage control speciifcations are used to estimate the production function. Results show that pesticides have statistical y signiifcant pro-ductivity effect on crop yield. On the condition of Weibul damage control speciifcations, the marginal products of 1 kg of the active ingredients of pesticides for rice, cotton and maize are 71.06, 22.73 and 98.45 kg, respectively. However, 57, 64 and 17%of the actual amount of pesticides are overused for rice, cotton and maize, respectively. Moreover, the productivity effect of pesticides would be overestimated using Cobb-Douglas speciifcation without incorporating a damage control agent.
基金supported financially by the National Natural Science Foundation of China(41361140361,41271126)the Project of State Key Laboratory of Desert and Oasis Ecology(Y471163)
文摘Grazing is a main human activity in the grasslands of Xinjiang, China. It is vital to identify the effects of grazing on the sustainable utilization of local grasslands. However, the effects of grazing on net primary productivity （NPP）, evapotranspiration （ET） and water use efficiency （WUE） in this region remain unclear. Using the spatial Biome-BGC grazing model, we explored the effects of grazing on NPP, ET and WUE across the different regions and grassland types in Xinjiang during 1979-2012. NPP, ET and WUE under the grazed scenario were generally lower than those under the ungrazed scenario, and the differences showed increasing trends over time. The decreases in NPP, ET and WUE varied significantly among the regions and grassland types. NPP decreased as follows： among the regions, Northern Xinjiang （16.60 g C/（m2·a））, Tianshan Mountains （15.94 g C/（m2·a）） and Southern Xinjiang （-3.54 g C/（m2·a））; and among the grassland types, typical grasslands （25.70 g C/（m2·a））, swamp meadows （25.26 g C/（m2·a））, mid-mountain meadows （23.39 g C/（m2·a））, alpine meadows （6.33 g C/（m2·a））, desert grasslands （5.82 g C/（m2·a）） and saline meadows （2.90 g C/（me.a））. ET decreased as follows： among the regions, Tianshan Mountains （28.95 mm/a）, Northern Xinjiang （8.11 mm/a） and Southern Xinjiang （7.57 mm/a）; and among the grassland types, mid-mountain meadows （29.30 mm/a）, swamp meadows （25.07 mm·a）, typical grasslands （24.56 mm/a）, alpine meadows （20.69 mm/a）, desert grasslands （11.06 mm/a） and saline meadows （3.44 mm/a）. WUE decreased as follows： among the regions, Northern Xinjiang （0.053 g C/kg H2O）, Tianshan Mountains （0.034 g C/kg H2O） and Southern Xinjiang （0.012 g C/kg H2O）; and among the grassland types, typical grasslands （0.0609 g C/kg H2O）, swamp meadows （0.0548 g C/kg H2O）, mid-mountain meadows （0.0501 g C/kg H2O）, desert grasslands （0.0172 g C/kg H2O）, alpine meadows （0.0121 g C/kg H2O） and saline meadows （0.0067 g C/kg H2O）. In general, the decreases in NPP and WUE were more significant in the regions with relatively high levels of vegetation growth because of the high grazing intensity in these regions. The decreases in ET were significant in mountainous areas due to the terrain and high grazing intensity.
基金financially supported by the National Natural Science Foundation of China (No. 52102113)the Nature Science Foundation of Shaanxi in China (No. 2022JQ-323)+1 种基金the Creative Research Foundation of the Science and Technology on Thermostructural Composite Materials LaboratoryNatural Science Foundation and Department of Education of Shaanxi in China (No. 21JK0912)
文摘The demand of high-end electromagnetic wave absorbing materials puts forward higher requirements on comprehensive performances of small thickness,lightweight,broadband,and strong absorption.Herein,a novel multi-layer stepped metamaterial absorber with gradient electromagnetic properties is proposed.The complex permittivity and permeability of each layer are tailored via the proportion of carbonyliron and carbon-fiber dispersing into the epoxy resin.The proposed metamaterial is further optimized via adjusting the electromagnetic parameters and geometric sizes of each layer.Comparing with the four-layer composite with gradient electromagnetic properties which could only realize reflection loss(RL)of less than−6 dB in 2.0-40 GHz,the optimized stepped metamaterial with the same thickness and electromagnetic properties realizes less than−10 dB in the relevant frequency range.Additionally,the RL of less than−15 dB is achieved in the frequency range of 11.2-21.4 GHz and 28.5-40 GHz.The multiple electromagnetic wave absorption mechanism is discussed based on the experimental and simulation results,which is believed to be attributed to the synergy effect induced by multi-scale structures of the metamaterial.Therefore,combining multi-layer structures and periodic stepped structures into a novel gradient absorbing metamaterial would give new insights into designing microwave absorption devices for broadband electromagnetic protections.
基金This study was supported by the National Natural Science Foundation of China(U22B2075,52274056,51974356).
文摘A large number of nanopores and complex fracture structures in shale reservoirs results in multi-scale flow of oil. With the development of shale oil reservoirs, the permeability of multi-scale media undergoes changes due to stress sensitivity, which plays a crucial role in controlling pressure propagation and oil flow. This paper proposes a multi-scale coupled flow mathematical model of matrix nanopores, induced fractures, and hydraulic fractures. In this model, the micro-scale effects of shale oil flow in fractal nanopores, fractal induced fracture network, and stress sensitivity of multi-scale media are considered. We solved the model iteratively using Pedrosa transform, semi-analytic Segmented Bessel function, Laplace transform. The results of this model exhibit good agreement with the numerical solution and field production data, confirming the high accuracy of the model. As well, the influence of stress sensitivity on permeability, pressure and production is analyzed. It is shown that the permeability and production decrease significantly when induced fractures are weakly supported. Closed induced fractures can inhibit interporosity flow in the stimulated reservoir volume (SRV). It has been shown in sensitivity analysis that hydraulic fractures are beneficial to early production, and induced fractures in SRV are beneficial to middle production. The model can characterize multi-scale flow characteristics of shale oil, providing theoretical guidance for rapid productivity evaluation.
基金The Strategic Priority Research Program of the Chinese Academy of Sciences,No.XDB03030500National Key Technology Research and Development Program,No.2013BAC04B02+1 种基金Key Foundation Project of Basic Work of the Ministry of Science and Technology of China,No.2012FY111400National Natural Science Foundation of China,No.41171080,No.41201095
文摘Twenty-one typical coupled large samples were chosen from areas within and surrounding nature reserves on the Tibetan Plateau using the large sample comparison method(LSCM).To evaluate the effectiveness of the nature reserves in protecting the ecological environment,the alpine grassland net primary production(NPP) of these coupled samples were compared and the differences between them before and after their establishment as protected areas were analyzed.The results showed that:(1) With respect to the alpine grassland NPP,the ecological and environmental conditions of most nature reserves were more fragile than those of the surrounding areas and also lower than the average values for the Tibetan Plateau.(2) Of the 11 typical nature reserves selected,the positive trend in the NPP for Manzetang was the most significant,whereas there was no obvious trend in Taxkorgan.With the exception of Selincuo,the annual NPP growth rate in the nature reserves covered by alpine meadow and wetland was higher than that in nature reserves consisting of alpine steppe and alpine desert.(3) There were notable findings in 21 typical coupled samples:(a) After the establishment of the nature reserves,the annual rate of increase in the NPP in 76% of samples inside nature reserves and 82% of samples inside national nature reserves was higher than that of the corresponding samples outside nature reserves.(b) The effectiveness of ecological protection of the Mid-Kunlun,Changshagongma,Zoige and Selincuo(Selin Co) nature reserves was significant; the effectiveness of protection was relatively sig-nificant in most parts of the Sanjiangyuan and Qiangtang nature reserves,whereas in south-east Manzetang and north Taxkorgan the protection effectiveness was not obvious.(c) The ecological protection effectiveness was significant in nature reserves consisting of alpine meadow,but was weak in nature reserves covered by alpine steppe.This study also shows that the advantage of large sample comparison method in evaluating regional ecology change.Careful design of the samples used,to ensure comparability between the samples,is crucial to the success of this LSCM.
基金supported by the National Natural Science Foundation of China (No.50974103, No.61003196)the Specialized Research Plan of Shaanxi Province Education Department (No.2010JK787)
文摘The frequency domain electromagnetic method has already been widely used for tomographic imaging or electromagnetic well logging. However, different from open hole logging, the metal casing existing in production well logging has a strong shielding effect on the electromagnetic waves, thus bringing some difficulties to the application of the frequency domain electromagnetic method in production well logging. According to the relation of the field source geometry to the ring around the mandrel, the general expressions of frequency domain electromagnetic responses in axially symmetrical layered conductive medium are deduced. The propagation effects caused by the low-frequency electromagnetic waves in cased hole are also analyzed. The distribution curves of eddy current density and magnetic flux density along the radial direction in the mandrel indicate that the eddy loss within the mandrel is proportional to the transmission signal frequency and the mandrel conductivity. The secondary field responses of different casing materials show that the transmission frequency has an important effect on the ability of electromagnetic waves penetrating the metal casing. The transmission frequency should be ultra-low in order to enable the electromagnetic signal to penetrate the casing easily. The numerical results of frequency responses for different casing physical parameters show that the casing thickness has a significant impact on the choice of the transmission frequency. It is also found that the effect of the casing radius on the transmission frequency can be neglected.
基金supported by the Special Fund for Meteorology-Scientific Research in the Public Interest,China(GYHY201106020)the National 973 Program of China(2010CB951502)
文摘The spatiotemporal characteristics of hydrothermal resources in southern rice production area of China have changed under the background of climate change,and this change would affect the effectiveness of hydrothermal resources during local rice growing period.According to the cropping system subdivision in southern rice production area of China during 1980s,this study used climate data from 254 meteorological stations and phonological data from 168 agricultural observation stations in the south of China,and adopted 6 international evaluation indices about the effectiveness of hydrothermal resources to analyze the temporal and spatial characteristics of hydrothermal resources during the growing period of single cropping rice system and double cropping rice system for 16 planting zones in the whole study area.The results showed that：in southern rice production area of China,the effectiveness of thermal resources of single cropping rice area（SCRA） was less than that of double cropping rice area（DCRA）,whereas the effectiveness of thermal resources of both SARA and DCRA showed a decreasing trend.The index value of effective precipitation satisfaction of SCRA was higher than that of DCRA,nevertheless the index value of effective precipitation satisfaction of both SCRA and DCRA showed a decreasing trend.There was a significant linear relationship between effective thermal resource and water demand,likely water demand increased by 18 mm with every 100°C d increase of effective heat.Effective precipitation satisfaction index（EPSI） showed a negative correlation with effective heat,yet showed a positive correlation with effective precipitation.EPSI reduced by 1% when effective heat resource increased by 125°C d.This study could provide insights for policy makers,land managers or farmers to improve water and heat resource uses and rationally arrange rice production activities under global climate change condition.
基金supported by the National Natural Science Foundation of China (81171479, 51303120, 81471790)the China Postdoctoral Science Foundation (2012M521121)+2 种基金the Natural Science Foundation of Jiangsu Province (BK20130335)the Jiangsu Provincial Special Program of Medical Science (BL2012004)the Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘Annulus fibrosus （AF） tissue engineering has recently received increasing attention as a treatment for intervertebral disc 0VD） degeneration; however, such engineering remains challenging because of the remarkable complexity of AF tissue. In order to engineer a functional AF replacement, the fabrication of cell-scaffold constructs that mimic the cellular, biochemical and structural features of native AF tissue is critical. In this study, we fabricated aligned fibroua polyurethane scaffolds using an electrospinning technique and used them for culturing AF-derived-stem/progenitor cells （AFSCs）. Random fibrous scaffolds, also prepared via electrospinningy were used as a control. We compared the morphology, proliferation, gene expression and matrix production of AFSCs on aligned scaffolds and random scaffolds. There was no apparent difference in the attachment or proliferation of cells cultured on aligned scaffolds and random scaffolds. However, compared to cells on random scaffolds, the AFSCs on aligned scaffolds were more elongated and better aligned, and they exhibited higher gene expression and matrix production of coUagen-I and aggrecan. The gene expression and protein production of coUagen-II did not appear to differ between the two groups. Together, these findings indicate that aligned fibrous scaffolds may provide a favourable microenvironment for the differentiation of AFSCs into cells similar to outer AF cells, which predominantly produce collagen-I matrix.
文摘The vibration problem of a fluid conveying cylindrical shell consisted of newly developed multi-scale hybrid nanocomposites is solved in the present manuscript within the framework of an analytical solution.The consistent material is considered to be made from an initial matrix strengthened via both macro-and nano-scale reinforcements.The influence of nanofillers’agglomeration,generated due to the high surface to volume ratio in nanostructures,is included by implementing Eshelby-Mori-Tanaka homogenization scheme.Afterwards,the equivalent material properties of the carbon nanotube reinforced(CNTR)nanocomposite are coupled with those of CFs within the framework of a modified rule of mixture.On the other hand,the influences of viscous flow are covered by extending the Navier-Stokes equation for cylinders.A cylindrical coordinate system is chosen and mixed with the infinitesimal strains of first-order shear deformation theory of shells to obtain the motion equations on the basis of the dynamic form of principle of virtual work.Next,the achieved governing equations will be solved by Galerkin’s method to reach the natural frequency of the structure for both simply supported and clamped boundary conditions.Presenting a set of illustrations,effects of each parameter on the dimensionless frequency of nanocomposite shells will be shown graphically.
基金Supported by Project for Research on Meteorological Science and Technology of Weifang Meteorological Bureau(2016wfqxkt04)
文摘Based on data of monthly sunshine duration in Shouguang City during 1961-2013,changing features of sunshine duration and effects on greenhouse production in Shouguang City were analyzed by using linear tendency method,M-K mutation test and Molet wavelet analysis. The results show that in Shouguang City,sunshine duration in a year and each season reduced obviously from 1961 to 2013,and sunshine duration in a year and autumn changed suddenly in the 1990s,while sunshine duration in winter and spring changed suddenly in the 1980s. There existed obvious periodic variations of sunshine duration in a year and various seasons from 1961 to 2013. The reduction of sunshine duration and the increase of cloudy days resulted in the decrease in the yield of crops in solar greenhouses,so some effective measures should be taken to enhance the light intensity and time in solar greenhouses to promote crop growth.
基金The National Natural Science Foundation of China(No.71871054)。
文摘An optimization model is proposed to examine the choice of sharing or not sharing the product link for manufacturing firms with owned social media by considering the role of fan effects.The equilibrium marketing effort level and firm profit in both cases are compared.The results show that the firm chooses to share(not share)the product link when the social platform commission rate is low(high).Moreover,the likelihood of sharing the product link increases as the fan effect weakens and the perceived conversion cost strengthens.Interestingly,the marketing effort level increases with the product price,but firm profit does not always follow.Additionally,as the fan effect and fan count grow,so does the firm s profit.Furthermore,when the firm shares the product link,the level of marketing effort and firm profit decrease with the commission rate.Conversely,when the firm does not share the product link,those aforementioned factors increase as the perceived conversion cost declines.These results thus suggest that firms should enhance the influence of owned social media to attract more high-quality fans,and social platforms should optimize the product link functionality.
基金financial support from the National Natural Science Foundation of China (NSFC-21776251, 21625604, 21671172 and 91934302)。
文摘Electrochemical ozone production(EOP) via water electrolysis represents an attractive method for the generation of high-purity O3. Herein, the X-PtZn/Zn-N-C electrocatalysts show a strong structural sensitive behavior depends on the size of the PtZn nanoparticles and their EOP activity exhibits a volcano-type dependence for the O3 performance in neutral media. The 7.7-PtZn/Zn-N-C exhibits EOP current efficiency of 4.2%, and shows the prominent performance in the production of gaseous O3 with a value of 1647 ppb at 30 min, which is almost 4-fold compared to 2.2-Pt Zn/Zn-N-C. Based on the experiments and theoretical calculations, the performance of the EOP process was determined by the nanoparticle size-effect and the synergistic effect between the PtZn nanoparticles and atomically dispersed Zn-N-C. Furthermore, the fivemembered cyclic structure of O3 can be stabilized between the PtZn nanoparticle and the Zn-N-C support,indicating that O3 is produced at the interface.
基金supported by the Natural Science Foundation of the Higher Education Institutions of Jiangsu Province,China(No.08KJD230002)the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)
文摘Cadmium （Cd） is an elemental heavy metal with widely recognized toxicity. Its long-term use in industrial processes and daily activities has caused alarming levels of Cd contamination in the natural environment. According to the estimates by the Agency of Toxic Substances and Disease Registry in the US, 25 000 to 30 000 metric tons of Cd is annually released to the environment . Results of previous studies have demonstrated that several organs are targets of Cd, but the most important of these targeted organs may be the testes.
基金jointly supported by the National Key Research and Development Program of China(Grant No.2022YFE0106500)Jiangsu Science Fund for Distinguished Young Scholars(Grant No.BK20200040)。
文摘The pan-Arctic is confronted with air pollution transported from lower latitudes.Observations have shown that aerosols help increase plant photosynthesis through the diffuse radiation fertilization effects(DRFEs).While such DRFEs have been explored at low to middle latitudes,the aerosol impacts on pan-Arctic ecosystems and the contributions by anthropogenic and natural emission sources remain less quantified.Here,we perform regional simulations at 0.2o×0.2ousing a well-validated vegetation model(Yale Interactive terrestrial Biosphere,YIBs)in combination with multi-source of observations to quantify the impacts of aerosol DRFEs on the net primary productivity(NPP)in the pan-Arctic during 2001-19.Results show that aerosol DRFEs increase pan-Arctic NPP by 2.19 Pg C(12.8%)yr^(-1)under clear-sky conditions,in which natural and anthropogenic sources contribute to 8.9% and 3.9%,respectively.Under all-sky conditions,such DRFEs are largely dampened by cloud to only 0.26 Pg C(1.24%)yr^(-1),with contributions of 0.65% by natural and 0.59% by anthropogenic species.Natural aerosols cause a positive NPP trend of 0.022% yr^(-1)following the increased fire activities in the pan-Arctic.In contrast,anthropogenic aerosols induce a negative trend of-0.01% yr^(-1)due to reduced emissions from the middle latitudes.Such trends in aerosol DRFEs show a turning point in the year of 2007 with more positive NPP trends by natural aerosols but negative NPP trends by anthropogenic aerosols thereafter.Though affected by modeling uncertainties,this study suggests a likely increasing impact of aerosols on terrestrial ecosystems in the pan-Arctic under global warming.
