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Multi-scale characterizations of colon polyps via computed tomographic colonography
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作者 Weiguo Cao Marc J.Pomeroy +4 位作者 Yongfeng Gao Matthew A.Barish Almas F.Abbasi Perry J.Pickhardt Zhengrong Liang 《Visual Computing for Industry,Biomedicine,and Art》 2019年第1期245-256,共12页
Texture features have played an essential role in the field of medical imaging for computer-aided diagnosis.The gray-level co-occurrence matrix(GLCM)-based texture descriptor has emerged to become one of the most succ... Texture features have played an essential role in the field of medical imaging for computer-aided diagnosis.The gray-level co-occurrence matrix(GLCM)-based texture descriptor has emerged to become one of the most successful feature sets for these applications.This study aims to increase the potential of these features by introducing multi-scale analysis into the construction of GLCM texture descriptor.In this study,we first introduce a new parameter-stride,to explore the definition of GLCM.Then we propose three multi-scaling GLCM models according to its three parameters,(1)learning model by multiple displacements,(2)learning model by multiple strides(LMS),and(3)learning model by multiple angles.These models increase the texture information by introducing more texture patterns and mitigate direction sparsity and dense sampling problems presented in the traditional Haralick model.To further analyze the three parameters,we test the three models by performing classification on a dataset of 63 large polyp masses obtained from computed tomography colonoscopy consisting of 32 adenocarcinomas and 31 benign adenomas.Finally,the proposed methods are compared to several typical GLCM-texture descriptors and one deep learning model.LMS obtains the highest performance and enhances the prediction power to 0.9450 with standard deviation 0.0285 by area under the curve of receiver operating characteristics score which is a significant improvement. 展开更多
关键词 Colon cancer Computed tomographic colonography Polyp characterization Texture feature
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Microstructure Analysis of TC4/Al 6063/Al 7075 Explosive Welded Composite Plate via Multi-scale Simulation and Experiment 被引量:1
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作者 Zhou Jianan Luo Ning +3 位作者 Liang Hanliang Chen Jinhua Liu Zhibing Zhou Xiaohong 《稀有金属材料与工程》 北大核心 2025年第1期27-38,共12页
Because of the challenge of compounding lightweight,high-strength Ti/Al alloys due to their considerable disparity in properties,Al 6063 as intermediate layer was proposed to fabricate TC4/Al 6063/Al 7075 three-layer ... Because of the challenge of compounding lightweight,high-strength Ti/Al alloys due to their considerable disparity in properties,Al 6063 as intermediate layer was proposed to fabricate TC4/Al 6063/Al 7075 three-layer composite plate by explosive welding.The microscopic properties of each bonding interface were elucidated through field emission scanning electron microscope and electron backscattered diffraction(EBSD).A methodology combining finite element method-smoothed particle hydrodynamics(FEM-SPH)and molecular dynamics(MD)was proposed for the analysis of the forming and evolution characteristics of explosive welding interfaces at multi-scale.The results demonstrate that the bonding interface morphologies of TC4/Al 6063 and Al 6063/Al 7075 exhibit a flat and wavy configuration,without discernible defects or cracks.The phenomenon of grain refinement is observed in the vicinity of the two bonding interfaces.Furthermore,the degree of plastic deformation of TC4 and Al 7075 is more pronounced than that of Al 6063 in the intermediate layer.The interface morphology characteristics obtained by FEM-SPH simulation exhibit a high degree of similarity to the experimental results.MD simulations reveal that the diffusion of interfacial elements predominantly occurs during the unloading phase,and the simulated thickness of interfacial diffusion aligns well with experimental outcomes.The introduction of intermediate layer in the explosive welding process can effectively produce high-quality titanium/aluminum alloy composite plates.Furthermore,this approach offers a multi-scale simulation strategy for the study of explosive welding bonding interfaces. 展开更多
关键词 TC4/Al 6063/Al 7075 composite plate explosive welding microstructure analysis multi-scale simulation
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A semi-analytical model for coupled flow in stress-sensitive multi-scale shale reservoirs with fractal characteristics 被引量:3
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作者 Qian Zhang Wen-Dong Wang +4 位作者 Yu-Liang Su Wei Chen Zheng-Dong Lei Lei Li Yong-Mao Hao 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期327-342,共16页
A large number of nanopores and complex fracture structures in shale reservoirs results in multi-scale flow of oil. With the development of shale oil reservoirs, the permeability of multi-scale media undergoes changes... A large number of nanopores and complex fracture structures in shale reservoirs results in multi-scale flow of oil. With the development of shale oil reservoirs, the permeability of multi-scale media undergoes changes due to stress sensitivity, which plays a crucial role in controlling pressure propagation and oil flow. This paper proposes a multi-scale coupled flow mathematical model of matrix nanopores, induced fractures, and hydraulic fractures. In this model, the micro-scale effects of shale oil flow in fractal nanopores, fractal induced fracture network, and stress sensitivity of multi-scale media are considered. We solved the model iteratively using Pedrosa transform, semi-analytic Segmented Bessel function, Laplace transform. The results of this model exhibit good agreement with the numerical solution and field production data, confirming the high accuracy of the model. As well, the influence of stress sensitivity on permeability, pressure and production is analyzed. It is shown that the permeability and production decrease significantly when induced fractures are weakly supported. Closed induced fractures can inhibit interporosity flow in the stimulated reservoir volume (SRV). It has been shown in sensitivity analysis that hydraulic fractures are beneficial to early production, and induced fractures in SRV are beneficial to middle production. The model can characterize multi-scale flow characteristics of shale oil, providing theoretical guidance for rapid productivity evaluation. 展开更多
关键词 multi-scale coupled flow Stress sensitivity Shale oil Micro-scale effect Fractal theory
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A multi-scale and multi-mechanism coupled model for carbon isotope fractionation of methane during shale gas production 被引量:1
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作者 Jun Wang Fang-Wen Chen +4 位作者 Wen-Biao Li Shuang-Fang Lu Sheng-Xian Zhao Yong-Yang Liu Zi-Yi Wang 《Petroleum Science》 2025年第7期2719-2746,共28页
Prediction of production decline and evaluation of the adsorbed/free gas ratio are critical for determining the lifespan and production status of shale gas wells.Traditional production prediction methods have some sho... Prediction of production decline and evaluation of the adsorbed/free gas ratio are critical for determining the lifespan and production status of shale gas wells.Traditional production prediction methods have some shortcomings because of the low permeability and tightness of shale,complex gas flow behavior of multi-scale gas transport regions and multiple gas transport mechanism superpositions,and complex and variable production regimes of shale gas wells.Recent research has demonstrated the existence of a multi-stage isotope fractionation phenomenon during shale gas production,with the fractionation characteristics of each stage associated with the pore structure,gas in place(GIP),adsorption/desorption,and gas production process.This study presents a new approach for estimating shale gas well production and evaluating the adsorbed/free gas ratio throughout production using isotope fractionation techniques.A reservoir-scale carbon isotope fractionation(CIF)model applicable to the production process of shale gas wells was developed for the first time in this research.In contrast to the traditional model,this model improves production prediction accuracy by simultaneously fitting the gas production rate and δ^(13)C_(1) data and provides a new evaluation method of the adsorbed/free gas ratio during shale gas production.The results indicate that the diffusion and adsorption/desorption properties of rock,bottom-hole flowing pressure(BHP)of gas well,and multi-scale gas transport regions of the reservoir all affect isotope fractionation,with the diffusion and adsorption/desorption parameters of rock having the greatest effect on isotope fractionation being D∗/D,PL,VL,α,and others in that order.We effectively tested the universality of the four-stage isotope fractionation feature and revealed a unique isotope fractionation mechanism caused by the superimposed coupling of multi-scale gas transport regions during shale gas well production.Finally,we applied the established CIF model to a shale gas well in the Sichuan Basin,China,and calculated the estimated ultimate recovery(EUR)of the well to be 3.33×10^(8) m^(3);the adsorbed gas ratio during shale gas production was 1.65%,10.03%,and 23.44%in the first,fifth,and tenth years,respectively.The findings are significant for understanding the isotope fractionation mechanism during natural gas transport in complex systems and for formulating and optimizing unconventional natural gas development strategies. 展开更多
关键词 Shale gas Isotope fractionation multi-scale Production prediction Adsorbed/free gas ratio
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Recent advances of metal vacancies in energy and environmental catalysis:Synthesis,characterization,and roles
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作者 Long Sun Shunzheng Zhao +4 位作者 Sirui Gao Ronghui Zhu Yiran Tan Xiaolong Tang Honghong Yi 《Green Energy & Environment》 SCIE EI CAS 2025年第1期84-108,共25页
With the ongoing depletion of fossil fuels,energy and environmental issues have become increasingly critical,necessitating the search for effective solutions.Catalysis,being one of the hallmarks of modern industry,off... With the ongoing depletion of fossil fuels,energy and environmental issues have become increasingly critical,necessitating the search for effective solutions.Catalysis,being one of the hallmarks of modern industry,offers a promising avenue for researchers.However,the question of how to significantly enhance the performance of catalysts has gradually drawn the attention of scholars.Defect engineering,a commonly employed and effective approach to improve catalyst activity,has become a significant research focus in the catalysis field in recent years.Nonmetal vacancies have received extensive attention due to their simple form.Consequently,exploration of metal vacancies has remained stagnant for a considerable period,resulting in a scarcity of comprehensive reviews on this topic.Therefore,based on the latest research findings,this paper summarizes and consolidates the construction strategies for metal vacancies,characterization techniques,and their roles in typical energy and environmental catalytic reactions.Additionally,it outlines potential challenges in the future,aiming to provide valuable references for researchers interested in investigating metal vacancies. 展开更多
关键词 Metal vacancies CATALYSIS Construction strategies characterization techniques ROLES
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Laboratory Diagnosis and Molecular Epidemiological Characterization of the First Imported Case of Lassa Fever in China 被引量:1
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作者 Yuliang Feng Wei Li +11 位作者 Mingfeng Jiang Hongrong Zhong Wei Wu Lyubo Tian Guo Chen Zhenhua Chen Can Luo Rongmei Yuan Xingyu Zhou Jiandong Li Xiaorong Yang Ming Pan 《Biomedical and Environmental Sciences》 2025年第3期279-289,共11页
Objective This study reports the first imported case of Lassa fever(LF)in China.Laboratory detection and molecular epidemiological analysis of the Lassa virus(LASV)from this case offer valuable insights for the preven... Objective This study reports the first imported case of Lassa fever(LF)in China.Laboratory detection and molecular epidemiological analysis of the Lassa virus(LASV)from this case offer valuable insights for the prevention and control of LF.Methods Samples of cerebrospinal fluid(CSF),blood,urine,saliva,and environmental materials were collected from the patient and their close contacts for LASV nucleotide detection.Whole-genome sequencing was performed on positive samples to analyze the genetic characteristics of the virus.Results LASV was detected in the patient’s CSF,blood,and urine,while all samples from close contacts and the environment tested negative.The virus belongs to the lineage IV strain and shares the highest homology with strains from Sierra Leone.The variability in the glycoprotein complex(GPC)among different strains ranged from 3.9%to 15.1%,higher than previously reported for the seven known lineages.Amino acid mutation analysis revealed multiple mutations within the GPC immunogenic epitopes,increasing strain diversity and potentially impacting immune response.Conclusion The case was confirmed through nucleotide detection,with no evidence of secondary transmission or viral spread.The LASV strain identified belongs to lineage IV,with broader GPC variability than previously reported.Mutations in the immune-related sites of GPC may affect immune responses,necessitating heightened vigilance regarding the virus. 展开更多
关键词 Lassa fever The first imported case Laboratory diagnosis Epidemiological characterization
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Occluded Gait Emotion Recognition Based on Multi-Scale Suppression Graph Convolutional Network
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作者 Yuxiang Zou Ning He +2 位作者 Jiwu Sun Xunrui Huang Wenhua Wang 《Computers, Materials & Continua》 SCIE EI 2025年第1期1255-1276,共22页
In recent years,gait-based emotion recognition has been widely applied in the field of computer vision.However,existing gait emotion recognition methods typically rely on complete human skeleton data,and their accurac... In recent years,gait-based emotion recognition has been widely applied in the field of computer vision.However,existing gait emotion recognition methods typically rely on complete human skeleton data,and their accuracy significantly declines when the data is occluded.To enhance the accuracy of gait emotion recognition under occlusion,this paper proposes a Multi-scale Suppression Graph ConvolutionalNetwork(MS-GCN).TheMS-GCN consists of three main components:Joint Interpolation Module(JI Moudle),Multi-scale Temporal Convolution Network(MS-TCN),and Suppression Graph Convolutional Network(SGCN).The JI Module completes the spatially occluded skeletal joints using the(K-Nearest Neighbors)KNN interpolation method.The MS-TCN employs convolutional kernels of various sizes to comprehensively capture the emotional information embedded in the gait,compensating for the temporal occlusion of gait information.The SGCN extracts more non-prominent human gait features by suppressing the extraction of key body part features,thereby reducing the negative impact of occlusion on emotion recognition results.The proposed method is evaluated on two comprehensive datasets:Emotion-Gait,containing 4227 real gaits from sources like BML,ICT-Pollick,and ELMD,and 1000 synthetic gaits generated using STEP-Gen technology,and ELMB,consisting of 3924 gaits,with 1835 labeled with emotions such as“Happy,”“Sad,”“Angry,”and“Neutral.”On the standard datasets Emotion-Gait and ELMB,the proposed method achieved accuracies of 0.900 and 0.896,respectively,attaining performance comparable to other state-ofthe-artmethods.Furthermore,on occlusion datasets,the proposedmethod significantly mitigates the performance degradation caused by occlusion compared to other methods,the accuracy is significantly higher than that of other methods. 展开更多
关键词 KNN interpolation multi-scale temporal convolution suppression graph convolutional network gait emotion recognition human skeleton
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BDMFuse:Multi-scale network fusion for infrared and visible images based on base and detail features
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作者 SI Hai-Ping ZHAO Wen-Rui +4 位作者 LI Ting-Ting LI Fei-Tao Fernando Bacao SUN Chang-Xia LI Yan-Ling 《红外与毫米波学报》 北大核心 2025年第2期289-298,共10页
The fusion of infrared and visible images should emphasize the salient targets in the infrared image while preserving the textural details of the visible images.To meet these requirements,an autoencoder-based method f... The fusion of infrared and visible images should emphasize the salient targets in the infrared image while preserving the textural details of the visible images.To meet these requirements,an autoencoder-based method for infrared and visible image fusion is proposed.The encoder designed according to the optimization objective consists of a base encoder and a detail encoder,which is used to extract low-frequency and high-frequency information from the image.This extraction may lead to some information not being captured,so a compensation encoder is proposed to supplement the missing information.Multi-scale decomposition is also employed to extract image features more comprehensively.The decoder combines low-frequency,high-frequency and supplementary information to obtain multi-scale features.Subsequently,the attention strategy and fusion module are introduced to perform multi-scale fusion for image reconstruction.Experimental results on three datasets show that the fused images generated by this network effectively retain salient targets while being more consistent with human visual perception. 展开更多
关键词 infrared image visible image image fusion encoder-decoder multi-scale features
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Synthesis and crystal structure characterization of yttrium imido complex:The reactivity of 2-substituted-1-amino-o-carborane with yttrium dialkyl complex
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作者 GUO Liping 《无机化学学报》 北大核心 2025年第7期1409-1415,共7页
2-substituted-1-amino-o-carboranes 2-R-1-NH_(2)-o-C_(2)B_(10)H_(10)(R=CH_(3),1a;R=Ph,1b)were synthesized and the reactions of these compounds with the yttrium dialkyl complex[Y(L)(CH_(2)SiMe3)_(2)](L=[2-(2,5-Me_(2)C_(... 2-substituted-1-amino-o-carboranes 2-R-1-NH_(2)-o-C_(2)B_(10)H_(10)(R=CH_(3),1a;R=Ph,1b)were synthesized and the reactions of these compounds with the yttrium dialkyl complex[Y(L)(CH_(2)SiMe3)_(2)](L=[2-(2,5-Me_(2)C_(4)H_(2)N)C_(6)H4NC(Ph)=NDipp]-,Dipp=2,6-iPr_(2)C_(6)H_(3))were investigated.The 1H NMR spectroscopy indicate that the reaction of ytrrium dialkyl complex with one equivalent of 2-R-1-NH_(2)-o-C_(2)B_(10)H_(10) produce the mixture of ytrrium alkyl-amido complex[Y(L)(2-R-1-NH-o-C_(2)B_(10)H_(10))(CH_(2)SiMe3)](R=CH_(3),2a;R=Ph,2b)and bis(amido)complex[Y(L)(2-R-1-NH-o-C_(2)B_(10)H_(10))_(2)](R=CH_(3),3a;R=Ph,3b).The yttrium bridging imido complex[Y(L)(2-CH_(3)-1-N-o-C_(2)B_(10)H_(10))]_(2)(4a)was obtained by heating the mixture at 55℃for 12 h.Complex 3a was isolated and characterized by treating the yttrium dialkyl complex with two equivalents of 1a.The structures of complexes 3a and 4a were verified by single-crystal Xray diffraction.CCDC:2424136,3a;2424137,4a. 展开更多
关键词 yttrium imide O-CARBORANE synthesis structure characterization
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A Nonlinear Multi-Scale Interaction Model for Atmospheric Blocking:A Tool for Exploring the Impact of Changing Climate on Mid-to-High Latitude Weather Extremes 被引量:1
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作者 Dehai LUO Wenqi ZHANG Binhe LUO 《Advances in Atmospheric Sciences》 2025年第10期2018-2035,共18页
A nonlinear multi-scale interaction(NMI)model was proposed and developed by the first author for nearly 30 years to represent the evolution of atmospheric blocking.In this review paper,we first review the creation and... A nonlinear multi-scale interaction(NMI)model was proposed and developed by the first author for nearly 30 years to represent the evolution of atmospheric blocking.In this review paper,we first review the creation and development of the NMI model and then emphasize that the NMI model represents a new tool for identifying the basic physics of how climate change influences mid-to-high latitude weather extremes.The building of the NMI model took place over three main periods.In the 1990s,a nonlinear Schr?dinger(NLS)equation model was presented to describe atmospheric blocking as a wave packet;however,it could not depict the lifetime(10-20 days)of atmospheric blocking.In the 2000s,we proposed an NMI model of atmospheric blocking in a uniform basic flow by making a scale-separation assumption and deriving an eddyforced NLS equation.This model succeeded in describing the life cycle of atmospheric blocking.In the 2020s,the NMI model was extended to include the impact of a changing climate mainly by altering the basic zonal winds and the magnitude of the meridional background potential vorticity gradient(PVy).Model results show that when PVy is smaller,blocking has a weaker dispersion and a stronger nonlinearity,so blocking can be more persistent and have a larger zonal scale and weaker eastward movement,thus favoring stronger weather extremes.However,when PVy is much smaller and below a critical threshold under much stronger winter Arctic warming of global warming,atmospheric blocking becomes locally less persistent and shows a much stronger westward movement,which acts to inhibit local cold extremes.Such a case does not happen in summer under global warming because PVy fails to fall below the critical threshold.Thus,our theory indicates that global warming can render summer-blocking anticyclones and mid-to-high latitude heatwaves more persistent,intense,and widespread. 展开更多
关键词 nonlinear Schrödinger equation nonlinear multi-scale interaction model of atmospheric blocking meridional background potential vorticity gradient climate change mid-to-high latitude weather extremes
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Characterization of Clay Raw Materials from Three Kankan Clay Deposits with a View to Their Use as Building Materials
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作者 Thierno Abdoulaye Barry Abdou Mbaye +5 位作者 Insa Badiane Albert Manga Badiane Stéphane Freslon Bérenger Aranda Laurent Molez Magatte Camara 《Journal of Materials Science and Chemical Engineering》 2025年第2期31-52,共22页
Clays are a constituent of the earth. As a result, the discovery and traditional use of clays in construction and pottery worldwide dates back to antiquity. Guinea has several deposits of clay minerals whose chemical ... Clays are a constituent of the earth. As a result, the discovery and traditional use of clays in construction and pottery worldwide dates back to antiquity. Guinea has several deposits of clay minerals whose chemical and mineralogical compositions have been little studied. Despite lacking of scientific data on these clay minerals, they are used today in pottery and habitat construction. As a step towards promoting the use of clay materials in Guinea, we conducted a study of the physicochemical and mineralogical properties of three natural clays from Kakan in the Republic of Guinea (AKKB, AKKE, AKKO) used in habitat construction. The aims of this work were to better understand their properties, but above all to be able to act on them to improve and broaden their applications, which until now have been limited to construction. These clays were studied by X-ray diffraction (XRD), X-ray fluorescence spectrometry (XRF), moisture content (%W), laser granulometry, Atterberg limits, specific surface area, infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), thermogravimetric analysis and differential thermal analysis (TGA/DTA). These analyses revealed that the main clay minerals present in our samples are kaolinite, illite and, montmorillonite, with the addition of impurities, the most abundant of which is quartz. 展开更多
关键词 characterization Clay Minerals Kankan Habitat Construction
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Heterologous Expression,Purification and Enzymatic Characterization of Xylitol Dehydrogenase from the Thermophilic Fungus Talaromyces emersonii
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作者 MENG Er QU Cong +8 位作者 YI Ke LI Hui-Min DUAN Xin-Yi ZHANG Zhe-Yuan HE Shao-Long LUO Yu-Tao WU Lei ZHANG Dong-Yi LIU Chang-Jun 《中国生物化学与分子生物学报》 北大核心 2025年第7期1007-1018,共12页
The xylitol dehydrogenase(XDH)is a crucial enzyme involved in the xylose utilization in pentose⁃catabolizing yeasts and fungi.In addition to producing xylulose,XDH can also be employed to develop a biosensor for monit... The xylitol dehydrogenase(XDH)is a crucial enzyme involved in the xylose utilization in pentose⁃catabolizing yeasts and fungi.In addition to producing xylulose,XDH can also be employed to develop a biosensor for monitoring xylitol concentration.In this study,the gene encoding the thermophilic fungus Talaromyces emersonii XDH(TeXDH)was heterologously expressed in Escherichia coli BL21(DE3)at 16℃in the soluble form.Recombinant TeXDH with high purity was purified by using a Ni⁃NTA affinity column.Size⁃exclusion chromatography and SDS⁃PAGE analysis demonstrated that the puri⁃fied recombinant TeXDH exists as a native trimer with a molecular mass of approximately 116 kD,and is composed of three identical subunits,each with a molecular weight of around 39 kD.The TeXDH strictly preferred NAD^(+)as a coenzyme to NADP^(+).The optimal temperature and pH of the TeXDH were 40℃and 10.0,respectively.After EDTA treatment,the enzyme activity of TeXDH decreased to 43.26%of the initial enzyme activity,while the divalent metal ions Mg^(2+)or Ca^(2+)could recover the enzyme activity of TeXDH,reaching 103.32%and 110.69%of the initial enzyme activity,respectively,making them the optimal divalent metal ion cofactors for TeXDH enzyme.However,the divalent metal ions of Mn^(2+),Ni^(2+),Cu^(2+),Zn^(2+),Co^(2+),and Cd^(2+)significantly inhibited the activity of TeXDH.ICP⁃MS and molecular doc⁃king studies revealed that 1 mol/L of TeXDH bound 2 mol/L Zn^(2+)ions and 1 mol/L Mg^(2+)ion.Further⁃more,TeXDH exhibited a high specificity for xylitol,laying the foundation for the development of future xylitol biosensors. 展开更多
关键词 xylitol dehydrogenase(XDH) Talaromyces emersonii heterologous expression enzymatic characterization
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In situ synthesis,crystal structure,and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold
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作者 WANG Zhaodong 《无机化学学报》 北大核心 2025年第3期597-604,共8页
A trinuclear copper complex [Cu_(3)(L2)_(2)(SO_(4))_(2)(H_(2)O)_(7)]·8H_(2)O(1)(HL2=1-hydroxy-3-(pyrazin-2-yl)-N-(pyrazin-2-ylmethyl)imidazo[1,5-a]pyrazine-8-carboxamide) with a multi-substituted imidazo[1,5-a]py... A trinuclear copper complex [Cu_(3)(L2)_(2)(SO_(4))_(2)(H_(2)O)_(7)]·8H_(2)O(1)(HL2=1-hydroxy-3-(pyrazin-2-yl)-N-(pyrazin-2-ylmethyl)imidazo[1,5-a]pyrazine-8-carboxamide) with a multi-substituted imidazo[1,5-a]pyrazine scaffold was serendipitously prepared from the reaction of the pro-ligand of H_(2)L1(N,N'-bis(pyrazin-2-ylmethyl)pyrazine-2,3-dicarboxamide) with CuSO_(4)·5H_(2O) in aqueous solution at room temperature.Complex 1 was characterized by IR,single-crystal X-ray analysis,and magnetic susceptibility measurements.Single-crystal X-ray analysis reveals that the complex consists of three Cu(Ⅱ) ions,two in situ transformed L2~-ligands,two coordinated sulfates,seven coordinated water molecules,and eight uncoordinated water molecules.Magnetic susceptibility measurement indicates that there are obvious ferromagnetic coupling interactions between the adjacent Cu(Ⅱ) ions in 1.CCDC:1852713. 展开更多
关键词 amide ligand copper complex single crystal structure C-N coupling magnetic characterization
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Clinical and Biological Characterization of Type 2 Diabetic Patients Followed at the National Center for Diabetology and Arterial Hypertension of the Central Hospital of Yaoundé, Cameroon
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作者 Etame Honoré Lucien Sone Nyemb Nyunaï +5 位作者 Bibi Thérèse Stella Souga Tsague Ginette Dzefouo Cédric Gueguim Christine Anne Ndzana Nteppe Leonel Mbah Mba Fabrice Medou 《Open Journal of Epidemiology》 2025年第1期19-35,共17页
Introduction: Diabetes remains a real public health problem today, due to its associated morbidity and mortality. It induces numerous metabolic, biochemical, hematological, and immunological changes, responsible for m... Introduction: Diabetes remains a real public health problem today, due to its associated morbidity and mortality. It induces numerous metabolic, biochemical, hematological, and immunological changes, responsible for multiple complications. The objective of this study was to characterize clinically and biologically type 2 diabetic patients followed at the National Center for Diabetology and Arterial Hypertension of the Central Hospital of Yaoundé. Method: This prospective, cross-sectional, and analytical study took place from April 5 to July 31, 2023 (4 months) on 100 diabetic patients of both sexes (61 women and 39 men), aged from 31 to 88 years. Body Mass Index, systolic and diastolic blood pressure, and cardiac frequency were measured on each of the patients. Subsequently, blood was collected from the patients for the determination of the complete blood count, HBA1c, lipid profile, serum albumin, TNF-α, and IL-6 levels. The data were analyzed using SPSS 17.0 software. Results: The age average of our population was 56.99 ± 11.51 years, the population was primarily female (61%) and primarily between the ages of 55 and 88. 67% of respondents were married. 59% went to secondary school. 73% of them lived in urban areas. 30% were obese and 40% were overweight, with an average BMI of 28.75 kg/m2. 76% of patients took oral antidiabetic medications. HbA1c level average was 8.65%, with 60% having readings above 6.5%. Low hemoglobin and hypochromia were among the abnormalities of red blood cells observed. Lipid profiles revealed low HDL-cholesterol and high triglycerides and cholesterol. Elevated levels of TNF-α and IL-6 indicated inflammation and cardiovascular risk. Conclusion: These results indicate the necessity of focused diabetic care and management on diabetic patients attending the central hospital of Yaoundé, Cameroon. 展开更多
关键词 CLINICAL BIOLOGICAL characterization Type 2 Diabetic Patients Central Hospital of Yaoundé
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Sensory Characterizations and Optimization of Cashew Apple Jam Formulations Using Baobab Powder as a Source of Pectin
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作者 Marie Bianoun Louise Dégni Doudjo Soro +3 位作者 Essan Bla Zita N’Goran-Aw Djedjro Clément Akmel Nogbou Emmanuel Assidjo Kouassi Benjamin Yao 《Food and Nutrition Sciences》 2025年第1期120-136,共17页
Cashew processing in Côte d’Ivoire focuses only on the cashew nut, to the detriment of the apple. Only a very small proportion of the apple is processed into juice. The aim of this work is to enhance the value o... Cashew processing in Côte d’Ivoire focuses only on the cashew nut, to the detriment of the apple. Only a very small proportion of the apple is processed into juice. The aim of this work is to enhance the value of cashew apples by transforming them into jam. Specifically, the aim was first to characterize the sensory properties of cashew apple jam formulations using baobab powder as a source of pectin and then to optimise the formulations. A Box-Behken design with pH, Sugar, and Baobab as factors was used to model and characterize the jam sensory descriptors, and a multivariate analysis with SensomineR was used to characterize the jam formulations. The desirability function was used to optimise the formulations. The results show globally significant regressions at the 0.05 threshold for the sensory descriptors Gelling, Brilliance, Smell, Sweetness, and (-)Astringency, with the exception of (-)Salinity. The R2 coefficients are greater than 80%. The factors studied could have effects on the sensory descriptors of cashew jam formulations. The Baobab had the main effect on the gelling, smell, and astringency of the jams. Brilliance depended on the added sugar. A product effect (p < 0.001) was observed for the descriptors Smell, Gelling, Brilliance, and Sweetness, as these allowed the panelists to find differences between the formulations. Optimum jam formulation can be achieved with 51.56% sugar and 2.12% Baobab at a pH of 3.15. Cashew apple jam using Baobab offers opportunities to add value to apples that have long been abandoned in the field. It would be important to find conditions for prolonged storage of this jam. 展开更多
关键词 Cashew Apple Sensory characterization Jam Formulation Area Design Product Effect Overall Desirability
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Progress and Prospect of Cryogenic Micro-and Nanomechanical In-Situ Characterization Techniques Based on Electron Microscopy
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作者 Langlang Feng Keqiang Li Guangjian Peng 《Acta Mechanica Solida Sinica》 2025年第2期229-239,共11页
The advancement of electron microscopy technology has driven the development of electron microscopes that can apply mechanical loading while observing samples,providing a valuable tool for In-Situ mechanical character... The advancement of electron microscopy technology has driven the development of electron microscopes that can apply mechanical loading while observing samples,providing a valuable tool for In-Situ mechanical characterization of materials.In response to the need to characterize the evolution of the mechanical behavior of structural materials,such as aerospace materials,in real cryogenic service environments,and to provide an experimental basis for improving their macroscopic cryogenic mechanical properties,the advancement of In-Situ characterization techniques capable of offering both cryogenic environments and mechanical loading has become imperative.There have been scholars using this technique to carry out cryogenic mechanical In-Situ studies of related materials,with experimental studies dominating in general,and a few reviews of mechanical characterization techniques mentioning cryogenic temperatures.In order to make it easier to conduct research using such characterization techniques and to further promote the development of related characterization techniques,this review compiles the previous work and summarizes the electron microscope-based In-Situ characterization techniques for cryogenic micro-and nanomechanics.These techniques primarily include transmission electron microscopy-based cryogenic tensile and indentation methods,as well as scanning electron microscopy-based cryogenic tensile,indentation,compression,and bending methods.Furthermore,the review outlines the prospective future development of In-Situ characterization techniques for cryogenic micro-and nanomechanics. 展开更多
关键词 Electron microscopy Micro-and nanomechanics Cryomechanical characterization In-Situ characterization
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Experimental Characterization of the Thermal Properties of Thin Polypropylene Plates Reinforced with Residues and Fibers from the Borassus Wood (Rônier) of Chad
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作者 Abakar Malgnan Kimtangar Ngargueudedjim +2 位作者 Bruno Bassa Hinpere Wedjou Bianpambe Guy Edgar Ntamack 《Open Journal of Applied Sciences》 2025年第2期517-529,共13页
This study focuses on the thermophysical characterizations of composite materials made from polypropylene reinforced with residues and fibers from Borassus wood from Chad. These properties are experimentally determine... This study focuses on the thermophysical characterizations of composite materials made from polypropylene reinforced with residues and fibers from Borassus wood from Chad. These properties are experimentally determined at different temperatures using the hot wire method of the “FP2C” machine, where the hot wire probe is inserted between two specimens. The values of the thermal conductivity in powdered Borassus wood range from 0.170 W/mK to 0.182 W/mK for female wood (FNTF) and from 0.169 W/mK to 0.173 W/mK for male wood. For the female and male fibers, the thermal conductivity values range from 0.137 W/mK to 0.157 W/mK for the female and from 0.138 W/mK to 0.168 W/mK for the male. The thermal effusivity of the residues and fibers of Borassus wood varies from: 509.6 Ws1/2/m2K to 543 Ws1/2/m2K for the powder of female wood and from 524.6 Ws1/2/m2K to 547 Ws1/2/m2K for the powder of male wood. For the fibers of Borassus wood, the values range from 410.6 Ws1/2/m2K to 523.6 Ws1/2/m2K for the female wood fibers and from 420.3 Ws1/2/m2K to 480.3 Ws1/2/m2K for the male wood fibers. These results are important for the applications of Borassus wood residues and fibers in construction works regarding the thermal insulation of habitats. 展开更多
关键词 Composite Materials Residues and Fibers of Rônier Wood from Chad Thin Sheets Thermal Properties characterization
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The Role of Multi-scale Integrated Hierarchical Intervention in Preventing Psychological Crises among College Students
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作者 XIONG Jun ZHAO Xiaoqing +3 位作者 SHUAI Yixin FENG Yuqi ZHUGE Junzhe LUO Jiaming 《贵州大学学报(自然科学版)》 2025年第4期18-25,共8页
Mental health problems and potential psychological crises affect the healthy growth and learning performance of college students.Effective and suitable prevention of psychological crises among college students is a co... Mental health problems and potential psychological crises affect the healthy growth and learning performance of college students.Effective and suitable prevention of psychological crises among college students is a continuous challenge university managers face.To explore a method of preventing psychological crises among college students,we measured 38661 students by using SCL-90(symptom check list-90)and screened out 5790 students with positive results.Then,we measured 33188 students by using PHQ-9(patient health questionnaire-9)and screened out 603 students with suicidal ideation or behavior;we interviewed 392 students by using GAQ(growth adversity questionnaire).The number of students who had positive results at both phases is 155.As a result,we obtained a data set(N=76)by integrating the students who tested positive on the PHQ-9(i.e.total score≥20)with those who completed the PHQ-9 and GAQ.In addition,we obtained a data set(N=50)by excluding the cases in which the GAQ score is 0.With regard to QCA(qualitative comparative analysis)results,the data set(N=76)exhibits 5 constellations of solutions with a coverage rate greater than 0.7,and the first eight indicators of the PHQ-9 constitute the explanatory variables in the combined solutions.About the data set(N=50),the combined solutions are extremely complicated and the explanatory variables encompass indicators from both the PHQ-9 and GAQ.All these mean that the multi-scale could more comprehensively reflect mental health states of college students,thus enhance the accuracy and effectiveness of the corresponding hierarchical intervention,and finally provide support for preventing psychological crises in universities. 展开更多
关键词 multi-scale hierarchical intervention preventing psychological crises
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Multi-scale modeling of the multi-phase flow in water electrolyzers for green hydrogen production
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作者 Lizhen Wu Qing Wang +2 位作者 Wenzhi Li Mingcong Tang Liang An 《Materials Reports(Energy)》 2025年第3期40-49,共10页
Water electrolyzers play a crucial role in green hydrogen production.However,their efficiency and scalability are often compromised by bubble dynamics across various scales,from nanoscale to macroscale components.This... Water electrolyzers play a crucial role in green hydrogen production.However,their efficiency and scalability are often compromised by bubble dynamics across various scales,from nanoscale to macroscale components.This review explores multi-scale modeling as a tool to visualize multi-phase flow and improve mass transport in water electrolyzers.At the nanoscale,molecular dynamics(MD)simulations reveal how electrode surface features and wettability influence nanobubble nucleation and stability.Moving to the mesoscale,models such as volume of fluid(VOF)and lattice Boltzmann method(LBM)shed light on bubble transport in porous transport layers(PTLs).These insights inform innovative designs,including gradient porosity and hydrophilic-hydrophobic patterning,aimed at minimizing gas saturation.At the macroscale,VOF simulations elucidate two-phase flow regimes within channels,showing how flow field geometry and wettability affect bubble discharging.Moreover,artificial intelligence(AI)-driven surrogate models expedite the optimization process,allowing for rapid exploration of structural parameters in channel-rib flow fields and porous flow field designs.By integrating these approaches,we can bridge theoretical insights with experimental validation,ultimately enhancing water electrolyzer performance,reducing costs,and advancing affordable,high-efficiency hydrogen production. 展开更多
关键词 Water electrolyzers Bubble dynamics multi-scale MULTI-PHASE MODELING
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Erratum to:Hydrochemical characterization of surface waters in Northen Tehran:Integrating cluster-based techniques with Self-Organizing Maps
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作者 Maryam SALIMI Hamid Reza NASSERY +2 位作者 Meysam VADIATI Prosun BHATTACHARYA Akram RAHBAR 《Journal of Mountain Science》 2025年第9期3527-3527,共1页
The title of the online version of the original article was revised.The title of the original article has been revised to:Hydrochemical characterization of surface waters in Northern Tehran:Integrating cluster-based t... The title of the online version of the original article was revised.The title of the original article has been revised to:Hydrochemical characterization of surface waters in Northern Tehran:Integrating cluster-based techniques with Self-Organizing Maps. 展开更多
关键词 northern tehran cluster based techniques characterization surface waters hydrochemical characterization surface waters self organizing maps
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