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Syntheses and fluorescent sensing properties of two coordination polymers based on 9,9′‑dihexyl‑2,7‑di(pyridin‑4‑yl)fluorene
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作者 WANG Gaofeng SUN Shuwen +1 位作者 Meng Lixin PENG Dequn 《无机化学学报》 北大核心 2026年第2期331-339,共9页
Under solvothermal conditions,1,4‑naphthalenedicarboxylic acid(H_(2)ndc)and 9,9′‑dihexyl‑2,7‑di(pyridin‑4‑yl)fluorene(hfdp)reacted with Co^(2+)ions and Cd^(2+)ions to form two coordination polymers,[Co(hfdp)(ndc)(H2O... Under solvothermal conditions,1,4‑naphthalenedicarboxylic acid(H_(2)ndc)and 9,9′‑dihexyl‑2,7‑di(pyridin‑4‑yl)fluorene(hfdp)reacted with Co^(2+)ions and Cd^(2+)ions to form two coordination polymers,[Co(hfdp)(ndc)(H2O)]·DMA}n(1)and{[Cd(hfdp)(ndc)(H_(2)O)]·DMA}_(n)(2),respectively(DMA=N,N‑dimethylacetamide).Single‑crystal X‑ray diffraction analyses showed that both complexes 1 and 2 contain similar structures.Topological analysis indicates that complexes 1 and 2 have a{44·62}planar structure.In addition,both complexes reveal good thermal stability and fluorescence sensing performance.They exhibited good sensitivity and selectivity towards 2,4,6‑trinitrophenol(TNP)by fluorescent quenching.The limits of detection of 1 and 2 for TNP were 0.107 and 0.327μmol·L^(-1),respectively.CCDC:2475515,1;2475516,2. 展开更多
关键词 coordination polymers cadmium(Ⅱ) TOPOLOGY FLUORESCENCE FLUORENE
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Synthesis and crystal structures of Co(Ⅱ)/Cu(Ⅱ)coordination polymers based on solvent and ligand concentration regulation strategy
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作者 SUN Yinxia LIU Liping +7 位作者 BAI Xue SUN Yu SUN Wanhong DENG Zhepeng CHEN Jianghai WANG Jianjun XU Li ZHANG Shuzhen 《无机化学学报》 北大核心 2026年第2期340-354,共15页
Four distinct coordination polymers(CPs)were successfully synthesized by altering solvent types and adjusting ligand concentrations,and their crystal structures were investigated.[Co(L)(FDCA)(H_(2)O)_(2)]·0.5H_(2... Four distinct coordination polymers(CPs)were successfully synthesized by altering solvent types and adjusting ligand concentrations,and their crystal structures were investigated.[Co(L)(FDCA)(H_(2)O)_(2)]·0.5H_(2)O(1)was synthesized as a 2D structure using Coas the metal source,methanol‑water(4∶6,V/V)as the solvent,and specific concentrations of 2,5‑furandicarboxylic acid(H_(2)FDCA)and 1,3,5‑triimidazole benzene(L).Adjusting to pure water and lowering the concentration of L yielded the 1D chain structure of[Co(HL)2(H_(2)O)_(2)](FDCA)_(2)·6H_(2)O(2).Using Cu(Ⅱ)as the metal source,methanol/water(9∶1,V/V)as the solvent,and specific concentrations of L and H2FDCA,the 1D chain structure of[Cu(L)(FDCA)(H_(2)O)]·2H_(2)O(3)was synthesized.Upon increasing the concentrations of L and H2FDCA,and switching the solvent to pure water,the 1D chain structure of[Cu(HL)_(2)(H_(2)O)_(2)](FDCA)_(2)·6H_(2)O(4)was obtained.This shows that changing the solvent and ligand concentrations can affect the structural changes of CPs.In addition,the solid‑state photoluminescence of CPs 1‑4 at room temperature was studied,and their morphological changes were observed via scanning electron microscopy.Density functional theory calculations revealed that the negative charge concentrates on the O and N atoms of the ligand,facilitating ligand‑metal ion coordination.CCDC:2403934,1;2403935,2;2403936,3;2403938,4. 展开更多
关键词 Co(Ⅱ)/Cu(Ⅱ)coordination polymer crystal structure solvent system ligand concentration regulation strategy
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Coordination-driven in-situ reduction and extraction of neptunium
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作者 Huaixin Hao Shuyun Zhang +7 位作者 Xue Dong Qilong Tang Yuxiao Guo Yaoyang Liu Jing Chen Jing Su Zhipeng Wang Chao Xu 《Science China Chemistry》 2026年第2期777-783,共7页
The recycling of neptunium(Np)from nuclear wastes is crucial for the sustainable development of nuclear energy,yet it is still a challenging task owing to the complexity of Np chemistry.Precise control of oxidation st... The recycling of neptunium(Np)from nuclear wastes is crucial for the sustainable development of nuclear energy,yet it is still a challenging task owing to the complexity of Np chemistry.Precise control of oxidation state is highly desirable for the effective recovery of Np.In this study,we report an innovative strategy for Np recovery through in-situ coordination and reduction of Np(Ⅴ)in a biphasic extraction system.By leveraging the synergistic effects of coordination by a P=O donating ligand(trialkyl phosphine oxide,TRPO)and reduction by hydroquinone(HQ)in the organic phase,efficient Np(Ⅴ)-to-Np(Ⅳ)conversion and high distribution ratio(D)of Np were achieved in a single extraction contact.The reduction mechanism of Np was elucidated through spectroscopic and theoretical analyses.This work enriches the redox chemistry of Np and provides a novel pathway for Np recovery in advanced nuclear fuel cycles. 展开更多
关键词 NEPTUNIUM coordination REDUCTION EXTRACTION
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MDGET-MER:Multi-Level Dynamic Gating and Emotion Transfer for Multi-Modal Emotion Recognition
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作者 Musheng Chen Qiang Wen +2 位作者 Xiaohong Qiu Junhua Wu Wenqing Fu 《Computers, Materials & Continua》 2026年第3期872-893,共22页
In multi-modal emotion recognition,excessive reliance on historical context often impedes the detection of emotional shifts,while modality heterogeneity and unimodal noise limit recognition performance.Existing method... In multi-modal emotion recognition,excessive reliance on historical context often impedes the detection of emotional shifts,while modality heterogeneity and unimodal noise limit recognition performance.Existing methods struggle to dynamically adjust cross-modal complementary strength to optimize fusion quality and lack effective mechanisms to model the dynamic evolution of emotions.To address these issues,we propose a multi-level dynamic gating and emotion transfer framework for multi-modal emotion recognition.A dynamic gating mechanism is applied across unimodal encoding,cross-modal alignment,and emotion transfer modeling,substantially improving noise robustness and feature alignment.First,we construct a unimodal encoder based on gated recurrent units and feature-selection gating to suppress intra-modal noise and enhance contextual representation.Second,we design a gated-attention crossmodal encoder that dynamically calibrates the complementary contributions of visual and audio modalities to the dominant textual features and eliminates redundant information.Finally,we introduce a gated enhanced emotion transfer module that explicitly models the temporal dependence of emotional evolution in dialogues via transfer gating and optimizes continuity modeling with a comparative learning loss.Experimental results demonstrate that the proposed method outperforms state-of-the-art models on the public MELD and IEMOCAP datasets. 展开更多
关键词 multi-modal emotion recognition dynamic gating emotion transfer module cross-modal dynamic alignment noise robustness
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Cu^(+)optimizes the FeHCF coordination environment to enhance high-voltage energy storage
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作者 Zu-Tao Pan Yao Xu Ling-Bin Kong 《Journal of Energy Chemistry》 2026年第1期752-759,I0017,共9页
Prussian blue analogs(PBAs)are considered one of the excellent cathode materials for sodium-ion batteries due to their low cost and high theoretical specific capacity,especially sodium-rich iron-based PBAs(FeHCF)can p... Prussian blue analogs(PBAs)are considered one of the excellent cathode materials for sodium-ion batteries due to their low cost and high theoretical specific capacity,especially sodium-rich iron-based PBAs(FeHCF)can provide higher energy density.FeHCF has a poor charge/discharge platform stability at high voltages(FeC_(6)moiety),which is mainly affected by its coordination environment.In this research,Cu^(+)(six-coordinated),which is close to the ionic radius of Fe^(2+),was used for substitution,the FeC_(6)vacancies of FeHCF were reduced,and the coordination environment was optimized.The low Cu^(+)-substituted FeHCF(Cu^(+)0.625)has an optimal electrochemical performance at 8.5 mA/g with a reversible specific capacity of 142 mA h/g and FeC_(6)moiety contribution of more than 68 mA h/g,which is superior to that of unmodified and other Cu^(2+)-substituted FeHCFs.In situ tests demonstrate the reversible structural stability of the Cu^(+)0.625,supporting the stability of their high-voltage platform capacity.This Cu^(+)substitution strategy further enriches the approach to optimize the coordination environment of sodium-rich FeHCF. 展开更多
关键词 Prussian blue analogues Sodium-ion batteries Cathode materials coordination environment Structural stability
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An Optimal Right-Turn Coordination System for Connected and Automated Vehicles at Urban Intersections
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作者 Mahmudul Hasan Shuji Doman +2 位作者 A.S.M.Bakibillah Md Abdus Samad Kamal Kou Yamada 《Computers, Materials & Continua》 2026年第1期430-446,共17页
Traffic at urban intersections frequently encounters unexpected obstructions,resulting in congestion due to uncooperative and priority-based driving behavior.This paper presents an optimal right-turn coordination syst... Traffic at urban intersections frequently encounters unexpected obstructions,resulting in congestion due to uncooperative and priority-based driving behavior.This paper presents an optimal right-turn coordination system for Connected and Automated Vehicles(CAVs)at single-lane intersections,particularly in the context of left-hand side driving on roads.The goal is to facilitate smooth right turns for certain vehicles without creating bottlenecks.We consider that all approaching vehicles share relevant information through vehicular communications.The Intersection Coordination Unit(ICU)processes this information and communicates the optimal crossing or turning times to the vehicles.The primary objective of this coordination is to minimize overall traffic delays,which also helps improve the fuel consumption of vehicles.By considering information from upcoming vehicles at the intersection,the coordination system solves an optimization problem to determine the best timing for executing right turns,ultimately minimizing the total delay for all vehicles.The proposed coordination system is evaluated at a typical urban intersection,and its performance is compared to traditional traffic systems.Numerical simulation results indicate that the proposed coordination system significantly enhances the average traffic speed and fuel consumption compared to the traditional traffic system in various scenarios. 展开更多
关键词 Right-turn coordination connected and automated vehicles vehicular communication edge processing urban intersection
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Construction of effective and recyclable non-noble metal coordination polymers and their multiple applications in water
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作者 Jiahao Li Bin Pan +2 位作者 Anruo Mao Likui Wang Dawei Wang 《Chinese Chemical Letters》 2026年第1期266-275,共10页
Acceptorless dehydrogenative coupling of pyridinemethanol with ketones is one of the most reliable methodologies to access functionalized 1,8-naphthyridine derivatives.However,it is challenging to develop environmenta... Acceptorless dehydrogenative coupling of pyridinemethanol with ketones is one of the most reliable methodologies to access functionalized 1,8-naphthyridine derivatives.However,it is challenging to develop environmentally friendly catalytic systems,especially in constructing efficient and recyclable catalysts under water or solvent-free conditions.Here,we designed two novel coordination polymers Cd-CPs and Fe-CPs to investigate their catalytic performance in water.Gratifyingly,it was observed that Cd-CPs as a multifunctional catalyst was successfully applied to establish a universal pathway for direct fabrication of 1,8-naphthyridine derivatives under water conditions,while it was effective for the synthesis of1,3,5-triazines through acceptorless dehydrogenative coupling strategies.The features of broad substrate,high atom efficiency,and good catalyst reusability highlight the feasibility of this transformation.In additional,we demonstrated the spindle-like structures Fe-P,derived from the Fe-CPs via phosphorylation,which can be used as an efficient electrocatalyst for oxygen evolution reaction with good stability.This work provides two highly efficient non-noble metal catalysts for functionalized 1,8-naphthyridine derivatives production and oxygen evolution reaction,and opens a new avenue to further fabricate diverse metal catalysts with high catalytic performance in water. 展开更多
关键词 Acceptorless dehydrogenative coupling 1 8-Naphthyridine derivatives coordination polymers Non-noble metal catalyst
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Design of dual-network structure based on coordination bonds and hydrogen bonds for high-performance multifunctional flexible gel absorbers
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作者 Xinyue Xie Zijing Li +3 位作者 Shusheng Wang Geng Chen Limin Zhang Hongjing Wu 《International Journal of Minerals,Metallurgy and Materials》 2026年第2期693-703,共11页
The emergence of precision electronic devices and wearable electronic products urgently requires high-performance multifunctional electromagnetic wave(EMW)absorbers to meet the applicability and versatility in various... The emergence of precision electronic devices and wearable electronic products urgently requires high-performance multifunctional electromagnetic wave(EMW)absorbers to meet the applicability and versatility in various applications.Herein,a dual-network(DN)gel was successfully prepared using acrylamide and sodium lignosulphonate as the basic units by simple chemical cross-linking and physical cross-linking methods.Specifically,the hydrogel forms two types of cross-linking networks through metal coordination and hydrogen bonding.Benefiting from the combined effects of dipole polarization and conductivity loss,the gel achieves an effective absorption bandwidth(EAB)of 6.74 GHz at a thickness of only 1.89 mm,demonstrating excellent EMW absorption performance.In addition,this unique structural configuration endows the EMW absorber with multifunctional features,such as remarkable tensile strength,good environmental compatibility,ultraviolet(UV)resistance,and excellent adhesion.Integrating multiple functional features into the EMW gels displays a broad application prospect in a variety of application scenarios.This research reveals the significance of DN structure design in the electromagnetic wave absorption(EWA)performance of gel-based materials,providing a substantial foundation for the multifunctional design of gel-based absorbers. 展开更多
关键词 electromagnetic wave absorbers dual-network structure polarization loss hydrogen bonds coordination bonds multifunc-tional characteristics
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Intelligent Human Interaction Recognition with Multi-Modal Feature Extraction and Bidirectional LSTM
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作者 Muhammad Hamdan Azhar Yanfeng Wu +4 位作者 Nouf Abdullah Almujally Shuaa S.Alharbi Asaad Algarni Ahmad Jalal Hui Liu 《Computers, Materials & Continua》 2026年第4期1632-1649,共18页
Recognizing human interactions in RGB videos is a critical task in computer vision,with applications in video surveillance.Existing deep learning-based architectures have achieved strong results,but are computationall... Recognizing human interactions in RGB videos is a critical task in computer vision,with applications in video surveillance.Existing deep learning-based architectures have achieved strong results,but are computationally intensive,sensitive to video resolution changes and often fail in crowded scenes.We propose a novel hybrid system that is computationally efficient,robust to degraded video quality and able to filter out irrelevant individuals,making it suitable for real-life use.The system leverages multi-modal handcrafted features for interaction representation and a deep learning classifier for capturing complex dependencies.Using Mask R-CNN and YOLO11-Pose,we extract grayscale silhouettes and keypoint coordinates of interacting individuals,while filtering out irrelevant individuals using a proposed algorithm.From these,we extract silhouette-based features(local ternary pattern and histogram of optical flow)and keypoint-based features(distances,angles and velocities)that capture distinct spatial and temporal information.A Bidirectional Long Short-Term Memory network(BiLSTM)then classifies the interactions.Extensive experiments on the UT Interaction,SBU Kinect Interaction and the ISR-UOL 3D social activity datasets demonstrate that our system achieves competitive accuracy.They also validate the effectiveness of the chosen features and classifier,along with the proposed system’s computational efficiency and robustness to occlusion. 展开更多
关键词 Human interaction recognition keypoint coordinates grayscale silhouettes bidirectional long shortterm memory network
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Coordination Thermodynamic Control of Magnetic Domain Configuration Evolution toward Low‑Frequency Electromagnetic Attenuation
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作者 Tong Huang Dan Wang +9 位作者 Xue He Zhaobo Feng Zhiqiang Xiong Yuqi Luo Yuhui Peng Guangsheng Luo Xuliang Nie Mingyue Yuan Chongbo Liu Renchao Che 《Nano-Micro Letters》 2026年第3期860-875,共16页
The precise tuning of magnetic nanoparticle size and magnetic domains,thereby shaping magnetic properties.However,the dynamic evolution mechanisms of magnetic domain configurations in relation to electromagnetic(EM)at... The precise tuning of magnetic nanoparticle size and magnetic domains,thereby shaping magnetic properties.However,the dynamic evolution mechanisms of magnetic domain configurations in relation to electromagnetic(EM)attenuation behavior remain poorly understood.To address this gap,a thermodynamically controlled periodic coordination strategy is proposed to achieve precise modulation of magnetic nanoparticle spacing.This approach unveils the evolution of magnetic domain configurations,progressing from individual to coupled and ultimately to crosslinked domain configurations.A unique magnetic coupling phenomenon surpasses the Snoek limit in low-frequency range,which is observed through micromagnetic simulation.The crosslinked magnetic configuration achieves effective low-frequency EM wave absorption at 3.68 GHz,encompassing nearly the entire C-band.This exceptional magnetic interaction significantly enhances radar camouflage and thermal insulation properties.Additionally,a robust gradient metamaterial design extends coverage across the full band(2–40 GHz),effectively mitigating the impact of EM pollution on human health and environment.This comprehensive study elucidates the evolution mechanisms of magnetic domain configurations,addresses gaps in dynamic magnetic modulation,and provides novel insights for the development of high-performance,low-frequency EM wave absorption materials. 展开更多
关键词 Thermodynamically controlled coordination strategy Magnetic domain configuration Low-frequency electromagnetic wave absorption Electrical/magnetic coupling MULTIFUNCTION
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Telomere-to-telomere genome assembly reveals the genomic architecture of disease resistance and yield coordination in elite wheat YM33
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作者 Guofeng Lv Yating Wang +15 位作者 Heping Zhang Yuning Shen Wenjing Hu Datong Liu Mengmeng Liu Wenna Wang Yuwen Gao Caixia Lan Tongde Bie Hongya Wu Wei Chen Yong Zhang Jianwei Zhang Chao He Wenhao Yan Derong Gao 《Molecular Plant》 2026年第2期213-216,共4页
Wheat(Triticum aestivum)faces significant threats from diseases such as powdery mildew(Blumeria graminis)and Fusarium head blight(FHB;caused by Fusarium graminearum),which cause severe yield losses.Moreover,the antago... Wheat(Triticum aestivum)faces significant threats from diseases such as powdery mildew(Blumeria graminis)and Fusarium head blight(FHB;caused by Fusarium graminearum),which cause severe yield losses.Moreover,the antagonism between yield-related traits and disease resistance makes yield resistance coordination a major challenge in wheat breeding.The lack of genetic resources combining both disease resistance and high yield constrains the elucidation of underlying resistance-yield trade-off mechanisms,thereby hindering the development of high-yield and disease-resistant wheat cultivars.Remarkably,Yangmai 33(YM33),a notable wheat cultivar with resistance to both powdery mildew and FHB as well as high-yield performance,was recently developed.It offers a unique opportunity to dissect the genomic architecture underlying the coordination between disease resistance and yield. 展开更多
关键词 fusarium head blight fhbcaused powdery mildew blumeria yield resistance coordination telomere telomere genome assembly disease resistance elite wheat genetic resources genomic architecture
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A cadmium(Ⅱ)coordination polymer based on a semirigid tetracarboxylate ligand for highly selective detection of Fe^(3+)and 4-nitrophenol 被引量:2
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作者 BAI Yu WANG Jijiang +4 位作者 TANG Long YUE Erlin BAI Chao WANG Xiao ZHANG Yuqi 《无机化学学报》 北大核心 2025年第6期1217-1226,共10页
A novel coordination polymer(CP){[Cd_(2)(L)(1,4-bimb)_(1.5)(DMF)_(2)]·DMF}n(1)(H_(4)L=5,5'-[1,1'-biphenyl-4,4'-diylbis(oxy)]diisophthalic acid,1,4-bimb=1,4-bis(imidazole-1-ylmethyl)-benzene)has been d... A novel coordination polymer(CP){[Cd_(2)(L)(1,4-bimb)_(1.5)(DMF)_(2)]·DMF}n(1)(H_(4)L=5,5'-[1,1'-biphenyl-4,4'-diylbis(oxy)]diisophthalic acid,1,4-bimb=1,4-bis(imidazole-1-ylmethyl)-benzene)has been designed and synthesized through solvothermal reaction.Structural analysis shows that Cd(Ⅱ)is connected by H4L and 1,4-bimb to form a 2D network,and 1,4-bimb further expands the 2D network into a 3D framework.CP 1 can be used as an excellent fluorescence sensor for Fe^(3+)and 4-nitrophenol(4-NP),with low detection limits and good anti-interference.The detection limits of Fe^(3+)and 4-NP were 0.034 and 0.031μmol·L^(-1),respectively.In addition,the fluorescence quenching mechanism was studied.1 was successfully applied to determine Fe^(3+)and 4-NP content in the Yanhe River water sample.CCDC:2351092. 展开更多
关键词 coordination polymer Fe^(3+) 4-NITROPHENOL fluorescence sensing
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Coordination equilibrium between cyclometalated Pt(Ⅱ)complexs[Pt(κ^(3)-N^C^N′)(CNXyl)]Cl and[Pt(κ^(2)-N^C^N′)(CNXyl)Cl] 被引量:1
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作者 ZHANG Huahong ZHAO Yang +2 位作者 NING Rui WU Shuixing ZHANG Xiaopeng 《无机化学学报》 北大核心 2025年第9期1840-1850,共11页
Reaction of the non-substituted/substituted unsymmetric pinene-derived complex[Pt(N^C^N')Cl]with the aryl isocyanide 2,6-dimethylphenyl isocyanide(CNXyl)afforded a mixture of two isomeric species:the ionic complex... Reaction of the non-substituted/substituted unsymmetric pinene-derived complex[Pt(N^C^N')Cl]with the aryl isocyanide 2,6-dimethylphenyl isocyanide(CNXyl)afforded a mixture of two isomeric species:the ionic complex[Pt(κ^(3)-N^C^N')(CNXyl)]Cl([A]Cl)and the molecular complex[Pt(κ^(2)-N^C^N')(CNXyl)Cl](B).Isomer B was almost the dominating product.The structures of the isomer B derivatives bearing-CF_(3)and-Cl substituents on the pyridine ring of the pinene moiety(5B and 7B,respectively)have been confirmed by single-crystal X-ray diffraction,revealing a slightly distorted square planar geometry with trans-N_(N^C^N'),CNR configuration(The terminal N atom of theκ^(2)-N^C^N'ligand is trans to the isocyanide ligand CNXyl.).Isomer B is thermodynamically more stable,as confirmed by theoretical calculations.CCDC:2416415,5B;2416414,7B. 展开更多
关键词 coordination equilibrium cyclometalated Pt(Ⅱ)complex isocyanide pinene group
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Construction and evaluation of a predictive model for the degree of coronary artery occlusion based on adaptive weighted multi-modal fusion of traditional Chinese and western medicine data 被引量:2
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作者 Jiyu ZHANG Jiatuo XU +1 位作者 Liping TU Hongyuan FU 《Digital Chinese Medicine》 2025年第2期163-173,共11页
Objective To develop a non-invasive predictive model for coronary artery stenosis severity based on adaptive multi-modal integration of traditional Chinese and western medicine data.Methods Clinical indicators,echocar... Objective To develop a non-invasive predictive model for coronary artery stenosis severity based on adaptive multi-modal integration of traditional Chinese and western medicine data.Methods Clinical indicators,echocardiographic data,traditional Chinese medicine(TCM)tongue manifestations,and facial features were collected from patients who underwent coro-nary computed tomography angiography(CTA)in the Cardiac Care Unit(CCU)of Shanghai Tenth People's Hospital between May 1,2023 and May 1,2024.An adaptive weighted multi-modal data fusion(AWMDF)model based on deep learning was constructed to predict the severity of coronary artery stenosis.The model was evaluated using metrics including accura-cy,precision,recall,F1 score,and the area under the receiver operating characteristic(ROC)curve(AUC).Further performance assessment was conducted through comparisons with six ensemble machine learning methods,data ablation,model component ablation,and various decision-level fusion strategies.Results A total of 158 patients were included in the study.The AWMDF model achieved ex-cellent predictive performance(AUC=0.973,accuracy=0.937,precision=0.937,recall=0.929,and F1 score=0.933).Compared with model ablation,data ablation experiments,and various traditional machine learning models,the AWMDF model demonstrated superior per-formance.Moreover,the adaptive weighting strategy outperformed alternative approaches,including simple weighting,averaging,voting,and fixed-weight schemes.Conclusion The AWMDF model demonstrates potential clinical value in the non-invasive prediction of coronary artery disease and could serve as a tool for clinical decision support. 展开更多
关键词 Coronary artery disease Deep learning multi-modal Clinical prediction Traditional Chinese medicine diagnosis
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Coupling Coordination Development and Driving Factors of New Energy Vehicles and Ecological Environment in China 被引量:5
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作者 XU Zonghuang 《Wuhan University Journal of Natural Sciences》 2025年第1期79-90,共12页
Studying the coupling coordination development of new energy vehicles(NEVs)and the ecological environment in China is helpful in promoting the development of NEVs in the country and is of great significance in promoti... Studying the coupling coordination development of new energy vehicles(NEVs)and the ecological environment in China is helpful in promoting the development of NEVs in the country and is of great significance in promoting high-quality development of new energy in China.This paper constructs an evaluation index system for the development of NEVs and the ecological environment.It uses game theory combining weighting model,particle swarm optimized projection tracking evaluation model,coupling coordination degree model,and machine learning algorithms to calculate and analyze the level of coupling coordination development of NEVs and the ecological environment in China from 2010 to 2021,and identifies the driving factors.The research results show that:(i)From 2010 to 2021,the development index of NEVs in China has steadily increased from 0.085 to 0.634,while the ecological environment level index significantly rose from 0.170 to 0.884,reflecting the continuous development of China in both NEVs and the ecological environment.(ii)From 2010 to 2012,the two systems—new energy vehicle(NEV)development and the ecological environment—were in a period of imbalance and decline.From 2013 to 2016,they underwent a transition period,and from 2017 to 2021,they entered a period of coordinated development showing a trend of benign and continuous improvement.By 2021,they reached a good level of coordination.(iii)Indicators such as the number of patents granted for NEVs,water consumption per unit of GDP,and energy consumption per unit of GDP are the main driving factors affecting the coupling coordination development of NEVs and the ecological environment in China. 展开更多
关键词 new energy vehicles(NEVs) ecological environment coupling coordination development machine learning driving factors
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TCM network pharmacology:new perspective integrating network target with artificial intelligence and multi-modal multi-omics technologies 被引量:1
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作者 Ziyi Wang Tingyu Zhang +1 位作者 Boyang Wang Shao Li 《Chinese Journal of Natural Medicines》 2025年第11期1425-1434,共10页
Traditional Chinese medicine(TCM)demonstrates distinctive advantages in disease prevention and treatment.However,analyzing its biological mechanisms through the modern medical research paradigm of“single drug,single ... Traditional Chinese medicine(TCM)demonstrates distinctive advantages in disease prevention and treatment.However,analyzing its biological mechanisms through the modern medical research paradigm of“single drug,single target”presents significant challenges due to its holistic approach.Network pharmacology and its core theory of network targets connect drugs and diseases from a holistic and systematic perspective based on biological networks,overcoming the limitations of reductionist research models and showing considerable value in TCM research.Recent integration of network target computational and experimental methods with artificial intelligence(AI)and multi-modal multi-omics technologies has substantially enhanced network pharmacology methodology.The advancement in computational and experimental techniques provides complementary support for network target theory in decoding TCM principles.This review,centered on network targets,examines the progress of network target methods combined with AI in predicting disease molecular mechanisms and drug-target relationships,alongside the application of multi-modal multi-omics technologies in analyzing TCM formulae,syndromes,and toxicity.Looking forward,network target theory is expected to incorporate emerging technologies while developing novel approaches aligned with its unique characteristics,potentially leading to significant breakthroughs in TCM research and advancing scientific understanding and innovation in TCM. 展开更多
关键词 Network pharmacology Traditional Chinese medicine Network target Artificial intelligence multi-modal Multi-omics
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MMGC-Net: Deep neural network for classification of mineral grains using multi-modal polarization images 被引量:1
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作者 Jun Shu Xiaohai He +3 位作者 Qizhi Teng Pengcheng Yan Haibo He Honggang Chen 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第6期3894-3909,共16页
The multi-modal characteristics of mineral particles play a pivotal role in enhancing the classification accuracy,which is critical for obtaining a profound understanding of the Earth's composition and ensuring ef... The multi-modal characteristics of mineral particles play a pivotal role in enhancing the classification accuracy,which is critical for obtaining a profound understanding of the Earth's composition and ensuring effective exploitation utilization of its resources.However,the existing methods for classifying mineral particles do not fully utilize these multi-modal features,thereby limiting the classification accuracy.Furthermore,when conventional multi-modal image classification methods are applied to planepolarized and cross-polarized sequence images of mineral particles,they encounter issues such as information loss,misaligned features,and challenges in spatiotemporal feature extraction.To address these challenges,we propose a multi-modal mineral particle polarization image classification network(MMGC-Net)for precise mineral particle classification.Initially,MMGC-Net employs a two-dimensional(2D)backbone network with shared parameters to extract features from two types of polarized images to ensure feature alignment.Subsequently,a cross-polarized intra-modal feature fusion module is designed to refine the spatiotemporal features from the extracted features of the cross-polarized sequence images.Ultimately,the inter-modal feature fusion module integrates the two types of modal features to enhance the classification precision.Quantitative and qualitative experimental results indicate that when compared with the current state-of-the-art multi-modal image classification methods,MMGC-Net demonstrates marked superiority in terms of mineral particle multi-modal feature learning and four classification evaluation metrics.It also demonstrates better stability than the existing models. 展开更多
关键词 Mineral particles multi-modal image classification Shared parameters Feature fusion Spatiotemporal feature
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Multi-modal intelligent situation awareness in real-time air traffic control: Control intent understanding and flight trajectory prediction 被引量:1
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作者 Dongyue GUO Jianwei ZHANG +1 位作者 Bo YANG Yi LIN 《Chinese Journal of Aeronautics》 2025年第6期41-57,共17页
With the advent of the next-generation Air Traffic Control(ATC)system,there is growing interest in using Artificial Intelligence(AI)techniques to enhance Situation Awareness(SA)for ATC Controllers(ATCOs),i.e.,Intellig... With the advent of the next-generation Air Traffic Control(ATC)system,there is growing interest in using Artificial Intelligence(AI)techniques to enhance Situation Awareness(SA)for ATC Controllers(ATCOs),i.e.,Intelligent SA(ISA).However,the existing AI-based SA approaches often rely on unimodal data and lack a comprehensive description and benchmark of the ISA tasks utilizing multi-modal data for real-time ATC environments.To address this gap,by analyzing the situation awareness procedure of the ATCOs,the ISA task is refined to the processing of the two primary elements,i.e.,spoken instructions and flight trajectories.Subsequently,the ISA is further formulated into Controlling Intent Understanding(CIU)and Flight Trajectory Prediction(FTP)tasks.For the CIU task,an innovative automatic speech recognition and understanding framework is designed to extract the controlling intent from unstructured and continuous ATC communications.For the FTP task,the single-and multi-horizon FTP approaches are investigated to support the high-precision prediction of the situation evolution.A total of 32 unimodal/multi-modal advanced methods with extensive evaluation metrics are introduced to conduct the benchmarks on the real-world multi-modal ATC situation dataset.Experimental results demonstrate the effectiveness of AI-based techniques in enhancing ISA for the ATC environment. 展开更多
关键词 Airtraffic control Automatic speechrecognition and understanding Flight trajectory prediction multi-modal Situationawareness
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Personal Style Guided Outfit Recommendation with Multi-Modal Fashion Compatibility Modeling 被引量:1
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作者 WANG Kexin ZHANG Jie +3 位作者 ZHANG Peng SUN Kexin ZHAN Jiamei WEI Meng 《Journal of Donghua University(English Edition)》 2025年第2期156-167,共12页
A personalized outfit recommendation has emerged as a hot research topic in the fashion domain.However,existing recommendations do not fully exploit user style preferences.Typically,users prefer particular styles such... A personalized outfit recommendation has emerged as a hot research topic in the fashion domain.However,existing recommendations do not fully exploit user style preferences.Typically,users prefer particular styles such as casual and athletic styles,and consider attributes like color and texture when selecting outfits.To achieve personalized outfit recommendations in line with user style preferences,this paper proposes a personal style guided outfit recommendation with multi-modal fashion compatibility modeling,termed as PSGNet.Firstly,a style classifier is designed to categorize fashion images of various clothing types and attributes into distinct style categories.Secondly,a personal style prediction module extracts user style preferences by analyzing historical data.Then,to address the limitations of single-modal representations and enhance fashion compatibility,both fashion images and text data are leveraged to extract multi-modal features.Finally,PSGNet integrates these components through Bayesian personalized ranking(BPR)to unify the personal style and fashion compatibility,where the former is used as personal style features and guides the output of the personalized outfit recommendation tailored to the target user.Extensive experiments on large-scale datasets demonstrate that the proposed model is efficient on the personalized outfit recommendation. 展开更多
关键词 personalized outfit recommendation fashion compatibility modeling style preference multi-modal representation Bayesian personalized ranking(BPR) style classifier
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Learning Based Interference Coordination for Maritime Communications 被引量:1
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作者 Liu Chuhuan Xiao Liang +3 位作者 Chen Yifan Li Siyao Yang Helin Lyu Zefang 《China Communications》 2025年第4期356-374,共19页
With the boom in maritime activities,the need for highly reliable maritime communication is becoming urgent,which is an important component of 5G/6G communication networks.However,the bandwidth reuse characteristic of... With the boom in maritime activities,the need for highly reliable maritime communication is becoming urgent,which is an important component of 5G/6G communication networks.However,the bandwidth reuse characteristic of 5G/6G networks will inevitably lead to severe interference,resulting in degradation in the communication performance of maritime users.In this paper,we propose a safe deep reinforcement learning based interference coordination scheme to jointly optimize the power control and bandwidth allocation in maritime communication systems,and exploit the quality-of-service requirements of users as the risk value references to evaluate the communication policies.In particular,this scheme designs a deep neural network to select the communication policies through the evaluation network and update the parameters using the target network,which improves the communication performance and speeds up the convergence rate.Moreover,the Nash equilibrium of the interference coordination game and the computational complexity of the proposed scheme are analyzed.Simulation and experimental results verify the performance gain of the proposed scheme compared with benchmarks. 展开更多
关键词 bandwidth allocation interference coordination maritime communication power control rein-forcement learning
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