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Multi-level Flocculation Structures of Fresh Cement Paste by Confocal Laser Scanning Microscope
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作者 张力冉 王栋民 ZHANG Weili 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2014年第2期302-308,共7页
Under saturation dosage of all kinds of SP, the free water amount was examined by centrifuge. The distribution of solution and flocculation microstructures in fresh cement paste was observed in three- dimensional spac... Under saturation dosage of all kinds of SP, the free water amount was examined by centrifuge. The distribution of solution and flocculation microstructures in fresh cement paste was observed in three- dimensional space by confocal laser scanning microscope(CLSM). Results indicate that SP can increase the free water amount by destroying the flocculated cement particle structure and different free water amount is released by different kinds of SP. The changes of the size of flocculation structures and the dispersion of solution were obviously detected with confocal laser scanning microscope: the size of flocculation structures was smaller and more dispersed in fresh cement paste with polycarboxylate superplasticizer, but the size of flocculation structures was bigger and cannot be dispersed uniformly in fresh cement paste with others SP. The multi- level flocculation structures theoretical model of fresh cement paste was then set up. The theory indicates that different kinds of SP with different dispersion strength will open the flocculation structures at different levels, which in turn present different water reducing rate. 展开更多
关键词 multi-level flocculation structure CLSM SP free water amount
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A Multi-level Approach for Complex Fault Isolation Based on Structured Residuals 被引量:3
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作者 叶鲁彬 石向荣 梁军 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2011年第3期462-472,共11页
In industrial processes,there exist faults that have complex effect on process variables.Complex and simple faults are defined according to their effect dimensions.The conventional approaches based on structured resid... In industrial processes,there exist faults that have complex effect on process variables.Complex and simple faults are defined according to their effect dimensions.The conventional approaches based on structured residuals cannot isolate complex faults.This paper presents a multi-level strategy for complex fault isolation.An extraction procedure is employed to reduce the complex faults to simple ones and assign them to several levels.On each level,faults are isolated by their different responses in the structured residuals.Each residual is obtained insensitive to one fault but more sensitive to others.The faults on different levels are verified to have different residual responses and will not be confused.An entire incidence matrix containing residual response characteristics of all faults is obtained,based on which faults can be isolated.The proposed method is applied in the Tennessee Eastman process example,and the effectiveness and advantage are demonstrated. 展开更多
关键词 multi-level structured residuals principal component analysis complex fault isolation Tennessee Eastman process
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Quantitatively characterizing sandy soil structure altered by MICP using multi-level thresholding segmentation algorithm 被引量:1
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作者 Jianjun Zi Tao Liu +3 位作者 Wei Zhang Xiaohua Pan Hu Ji Honghu Zhu 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第10期4285-4299,共15页
The influences of biological,chemical,and flow processes on soil structure through microbially induced carbonate precipitation(MICP)are not yet fully understood.In this study,we use a multi-level thresholding segmenta... The influences of biological,chemical,and flow processes on soil structure through microbially induced carbonate precipitation(MICP)are not yet fully understood.In this study,we use a multi-level thresholding segmentation algorithm,genetic algorithm(GA)enhanced Kapur entropy(KE)(GAE-KE),to accomplish quantitative characterization of sandy soil structure altered by MICP cementation.A sandy soil sample was treated using MICP method and scanned by the synchrotron radiation(SR)micro-CT with a resolution of 6.5 mm.After validation,tri-level thresholding segmentation using GAE-KE successfully separated the precipitated calcium carbonate crystals from sand particles and pores.The spatial distributions of porosity,pore structure parameters,and flow characteristics were calculated for quantitative characterization.The results offer pore-scale insights into the MICP treatment effect,and the quantitative understanding confirms the feasibility of the GAE-KE multi-level thresholding segmentation algorithm. 展开更多
关键词 Soil structure MICRO-CT multi-level thresholding MICP Genetic algorithm(GA)
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Improved Fibroblast Adhesion and Proliferation by Controlling Multi-level Structure of Polycaprolactone Microfiber 被引量:1
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作者 JIAO Yongjie LI Chaojing +3 位作者 LI Qiwei LIU Laijun WANG Fujun WANG Lu 《Journal of Donghua University(English Edition)》 EI CAS 2020年第4期280-285,共6页
Improving wound healing efficiency is a key issue for high performance dressings.The surface topology of fibers in wound dressings plays an important role in regulating cell behaviors during the regeneration.Herein,a ... Improving wound healing efficiency is a key issue for high performance dressings.The surface topology of fibers in wound dressings plays an important role in regulating cell behaviors during the regeneration.Herein,a polycaprolactone(PCL)scaffold with a shish-kebab structure was prepared by electrospinning and solution-induced crystallization.L929 cells were used to investigate the behavior of fibroblasts on the multi-level microfiber.The results showed that the shish-kebab fiber-based scaffold enhanced the cell proliferation when compared with the normal fiber and the fiber with a porous structure.Protein absorption,cell adhesive force,and cell modulus also increased by the shish-kebab fiber.The shish-kebab fiber-based scaffold with improved fibroblast-regulation ability can be applied in rapid wound healing. 展开更多
关键词 cell-regulation multi-level microfiber shish-kebab structure electrospinning surface
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Influence of coarse tailings on flocculation settlement 被引量:14
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作者 Shi Wang Xue-peng Song +3 位作者 Xiao-jun Wang Qiu-song Chen Jian-chun Qin Yu-xian Ke 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2020年第8期1065-1074,共10页
The composition of tailings particles in mines plays a key role in the flocculation settlement of slurries.To study the influence of coarse particle tailings(CPTs)on the flocculation settlement of tailings slurries(TS... The composition of tailings particles in mines plays a key role in the flocculation settlement of slurries.To study the influence of coarse particle tailings(CPTs)on the flocculation settlement of tailings slurries(TSs),static flocculent settling tests,scanning electron microscopy observations,and laser particle size analyses were conducted using the tailings obtained from a copper mine.The results demonstrate that(i)in the accelerated and free settling process,CPTs did not directly settle at the bottom of graduated cylinders;instead,they were netted by the flocculent structures(FSs)and settled together more quickly.The CPTs accelerate the rapid settlement of TSs;the acceleration effect is more obvious when the CPTs content is greater than 50 wt%.(ii)The most appropriate flocculant unit consumption(FUC)is 20 g·t-1,and no substantial increase is observed in the flocculant settling velocity with an increase in the flocculant because the effective FSs did not substantially change and thus did not lead to a notable increase in the settling velocity of the solid–liquid interface(SLI).(iii)In the effective settling space of the thickening facility,free water quickly flowed from the pores of FSs,which is reflected in the period from 0 to 1 min. 展开更多
关键词 tailings slurry particle size distribution flocculent structures flocculating sedimentation solid–liquid interface
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Distribution of aluminum species and the characteristics of structure of poly-aluminum-chloride-sulfate(PACS) 被引量:5
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作者 GAO Bao\|yu, YUE Qin\|yan, YU Hui, WANG Yan (Department of Environmental Engineering, Shandong University, Jinan\ 250100, China. E\|mail:bygao@sdu.edu.cn) 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2001年第1期108-114,共7页
A series of poly-aluminum-chloride-sulfate (PACS), which has different basicities (gamma) and Al3+/SO42- molar ratio, has been prepared and dried at 105degreesC and 65degreesC, respectively. The distribution of alumin... A series of poly-aluminum-chloride-sulfate (PACS), which has different basicities (gamma) and Al3+/SO42- molar ratio, has been prepared and dried at 105degreesC and 65degreesC, respectively. The distribution of aluminum species of PACS was examined, and the effect of 7 value, Al3+/SO42- molar ratio, dilution on the distribution of aluminum species of PACS was also investigated by using Al-ferron timed complex colorimetric method. The IR spectroscopy and X-ray diffraction were used to study the effect of gamma value, Al3+ / SO42- molar ratio and the drying temperature on the structure of PACS. The experimental results show that Al3+/SO42- molar ratio has a great effect on the distribution of aluminum species, but the dilution has a little effect on the distribution of aluminum species. The lower the Al3+/SO42- molar ratio, the higher the proportions of the polymer and colloidal species in PACS, The polymeric degree of PACS was related to gamma value and Al3+/SO(4)(2-)molar ratio. Drying temperature has an influence on the structure and the solubility of solid PACS products. 展开更多
关键词 flocculant PACS SPECIES structure Al-ferron timed complex colorimetric method IR spectroscopy X-ray diffraction
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Structural Optimization of Hatch Cover Based on Bi-directional Evolutionary Structure Optimization and Surrogate Model Method 被引量:3
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作者 LI Kai YU Yanyun +2 位作者 HE Jingyi ZHAO Decai LIN Yan 《Journal of Shanghai Jiaotong university(Science)》 EI 2018年第4期538-549,共12页
Weight reduction has attracted much attention among ship designers and ship owners.In the present work,based on an improved bi-directional evolutionary structural optimization(BESO) method and surrogate model method,w... Weight reduction has attracted much attention among ship designers and ship owners.In the present work,based on an improved bi-directional evolutionary structural optimization(BESO) method and surrogate model method,we propose a hybrid optimization method for the structural design optimization of beam-plate structures,which covers three optimization levels:dimension optimization,topology optimization and section optimization.The objective of the proposed optimization method is to minimize the weight of design object under a group of constraints.The kernel optimization procedure(KOP) uses BESO to obtain the optimal topology from a ground structure.To deal with beam-plate structures,the traditional BESO method is improved by using cubic box as the unit cell instead of solid unit to construct periodic lattice structure.In the first optimization level,a series of ground structures are generated based on different dimensional parameter combinations,the KOP is performed to all the ground structures,the response surface model of optimal objective values and dimension parameters is created,and then the optimal dimension parameters can be obtained.In the second optimization level,the optimal topology is obtained by using the KOP according to the optimal dimension parameters.In the third optimization level,response surface method(RSM) is used to determine the section parameters.The proposed method is applied to a hatch cover structure design.The locations and shapes of all the structural members are determined from an oversized ground structure.The results show that the proposed method leads to a greater weight saving,compared with the original design and genetic algorithm(GA) based optimization results. 展开更多
关键词 hatch cover structure optimization multi-level optimization hi-directional evolutionary structural optimization response surface method
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Structural analysis of multi-level detachments and identification of deep-seated anticline 被引量:1
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作者 CHEN Zhuxin LEI Yongliang +2 位作者 HU Ying WANG Lining YANG Geng 《Petroleum Exploration and Development》 2018年第2期281-289,共9页
Based on forward modeling of detachment fold, this study presents a method to analyze multi-level detachment structures and identify the authenticity of deep-seated anticlines using time-domain seismic section. The st... Based on forward modeling of detachment fold, this study presents a method to analyze multi-level detachment structures and identify the authenticity of deep-seated anticlines using time-domain seismic section. The steps include the conversion of the time-migrated seismic image into depth domain image using a constant velocity field, structural interpretation of the depth seismic image, measurement of each structural relief area and each height above reference level, plotting of area-height relationship chart with piecewise fitting etc. The area-depth correlation can help the division of structural sequences, the definition of detachment levels, the calculation of the tectonic shortening, and the identification of deep-seated structure. The segment area-height relationship is a feature of multi-level detachment structures, while little or no linear correlation between area and height is an indicator of non-deformation or pseudo-anticline. Regardless of the uncertainty of area-height relationship, the segment slopes will correspond to the differential shortenings of multi-level detachments, the intersection between adjacent segments will give the height of detachment surface above reference level and then help define the detachment level in original time-domain seismic section. This method can make use of time-domain seismic data to determine the geologic structure of complicated structure areas and assess risks of deep exploration targets. It has achieved good results in southern Junggar and eastern Sichuan areas. 展开更多
关键词 multi-level detachments ANTICLINE time-domain seismic section area-height relationship COMPLICATED structure southern JUNGGAR Basin eastern SICHUAN FOLD belt
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Structural geology and favorable exploration prospect belts in northwestern Sichuan Basin, SW China 被引量:5
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作者 CHEN Zhuxin LI Wei +5 位作者 WANG Lining LEI Yongliang YANG Guang ZHANG Benjian YIN Hong YUAN Baoguo 《Petroleum Exploration and Development》 2019年第2期413-425,共13页
The northwestern Sichuan region has experienced multi-stage tectonic evolution including marine cratonic basin from the Sinian to the Middle Triassic and intra-continental basin from the Late Triassic to the Cenozoic.... The northwestern Sichuan region has experienced multi-stage tectonic evolution including marine cratonic basin from the Sinian to the Middle Triassic and intra-continental basin from the Late Triassic to the Cenozoic. Several regional tectonic activities caused complicated stratigraphic distribution and structural deformations in the deep-buried layers. During the key tectonic periods, some characteristic sedimentary and deformation structures were formed, including the step-shaped marginal carbonate platform of Dengying Formation, the western paleo-high at the end of Silurian, and the passive continental margin of the Late Paleozoic–Middle Triassic. The Meso-Cenozoic intra-continental compressional tectonic processes since the Late Triassic controlled the formation of complex thrusting structures surrounding and inside the northwestern basin. The northern Longmenshan fold-thrust belt has a footwall in-situ thrust structure,which is controlled by two sets of detachments in the Lower Triassic and Lower Cambrian and presents as a multi-level deformation structure with the shallow folds, the middle thin-skin thrusts and the deeper basement-involved folds. The thrust belt in front of the Micangshan Mountain shows a double-layer deformation controlled by the Lower Triassic salt detachment, which is composed by the upper monocline and deep-buried imbricate thrust structures. The interior of the basin is characterized by several rows of large-scale basement-involved folds with NEE strike direction. From the perspective of structural geology, the favorable exploration reservoirs and belts in northwestern Sichuan have obvious zoning characteristics. The favorable exploration layers of Dengying Formation of Upper Sinian are mainly distributed in the eastern and northern areas of the northwestern Sichuan Basin, in which the Jiulongshan structural belt, Zitong syncline and Yanting slope are the most favorable. The Lower Paleozoic was transformed by Caledonian paleo-uplift and late Cenozoic folding, and the midwest area such as the Zitong syncline is a potential area for hydrocarbon exploration. The favorable part of the Upper Paleozoic is mainly distributed in the northern Longmenshan belt and its frontal area, where the deep-buried thin-skin thrust structures in the footwall are the key exploration targets. 展开更多
关键词 NORTHWESTERN Sichuan Basin fold-thrust belt multi-level DETACHMENT SINIAN PALEOZOIC platform margin paleohigh structural deformation tectonic evolution hydrocarbon exploration
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超支化絮凝剂对废弃油基钻井液的处理效果研究
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作者 金辉 蒋官澄 +3 位作者 许万利 全晓虎 冯奇 杨俊 《石油科学通报》 2025年第6期1361-1373,共13页
南海油田某钻井平台产生的废弃油基钻井液(8#、10#和20#))固相含量高、粘度高、密度大,并且存在回收、转运困难和难以循环使用的问题。现场采用高速离心和热脱附的方法均不能降低废弃钻井液中固相含量,且使用常规的絮凝剂也不能有效去... 南海油田某钻井平台产生的废弃油基钻井液(8#、10#和20#))固相含量高、粘度高、密度大,并且存在回收、转运困难和难以循环使用的问题。现场采用高速离心和热脱附的方法均不能降低废弃钻井液中固相含量,且使用常规的絮凝剂也不能有效去除废弃钻井液中有害固相颗粒。本文以硅酸四乙酯、纳米Fe_(3)O_(4)为原料,丙烯酸甲酯为接枝单体,制备磁性纳米核,再分别与1,3-丙二胺、三乙烯四胺进行迈克尔加成反应,成功制备出2种带有磁核和超支化结构的絮凝剂(以1,3-丙二胺为封端剂(絮凝剂-1),以三乙烯四胺为封端剂(絮凝剂-2)),并通过红外光谱、元素分析的方法测定絮凝剂分子的结构。然后采用絮凝离心的方法,探究2种超支化絮凝剂对废弃油基钻井液的固相含量、密度和粘度的影响。结果表明:絮凝剂加量2.5%时,絮凝剂-1对8#、10#和20#钻井液的有害固相去除率为82.75%、62.30%和70.56%,处理后8#、10#和20#钻井液的固相含量为5.21%、15.34%和14.43%;絮凝剂-2对8#、10#和20#钻井液的有害固相去除率为81.06%、59.13%和69.48%,处理后8#、10#和20#钻井液的固相含量为5.72%、16.63%和14.96%;处理后3种钻井液的密度为0.86~1.16 g·cm-3;表观粘度和塑性粘度为52~90 mPa·s。其絮凝机理除了电荷中和、吸附架桥作用外,还与其超支化分子结构的吸附性能有关。经过处理的钻井液,满足钻井平台对海上废弃钻井液的要求:8#钻井液(已经过热脱附处理)固相指标5%~7%、10#和20#钻井液(未经处理)固相指标10%~18%,并为其它废弃钻井液的处理提供可借鉴的技术方法。 展开更多
关键词 废弃油基钻井液 絮凝剂 有害固相 阳离子多胺类 超支化结构
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混凝/絮凝技术在油田污水处理中的应用
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作者 王洪勃 张娟 +4 位作者 杨子浩 张风帆 徐昆誉 林梅钦 董朝霞 《山东大学学报(理学版)》 北大核心 2025年第10期42-58,共17页
石油是当今世界上不可替代的能源之一。在其开采、加工和运输过程中,不可避免地产生大量含油污水。含油污水具有成分复杂、处理量大等特点,若处理不当将会对生态环境和人类健康产生严重的威胁,因此,如何高效处理含油污水已成为石油行业... 石油是当今世界上不可替代的能源之一。在其开采、加工和运输过程中,不可避免地产生大量含油污水。含油污水具有成分复杂、处理量大等特点,若处理不当将会对生态环境和人类健康产生严重的威胁,因此,如何高效处理含油污水已成为石油行业亟待解决的难题。目前,混凝/絮凝技术作为一种油田污水处理技术,因其相对成熟、高效、经济且环保等优点而受到研究者们的广泛关注。本文综述了混凝/絮凝技术在油田污水处理方面的应用。首先考虑到含油污水组成复杂和处理难度,比较了含油污水处理中的各类混凝剂/絮凝剂,包括无机混凝剂、有机絮凝剂以及复合混凝剂/絮凝剂,强调了其分子结构对除油性能的影响。此外,还详细介绍影响其除油性能的各种因素,如投加量、pH和温度等。总结不同混凝剂/絮凝剂在含油污水处理中的不同混凝/絮凝机理。本综述旨在为含油污水处理中混凝剂/絮凝剂的选择提供理论基础,为现场应用提供理论指导,并对未来的研究提出可行的方向。 展开更多
关键词 油田含油污水 分子结构 混凝/絮凝机理
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盐温耦合作用下深海软黏土动态流变特性研究
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作者 王亚 常留成 +1 位作者 王红雨 王勇 《海洋学报》 北大核心 2025年第10期90-98,共9页
为保障海洋动荷载(波浪、洋流、地震)长期作用下海底结构物的稳定性,需明确海床表层深海软黏土的流变特性。本研究以深海软黏土为对象,采用应变控制模式流变仪,开展不同盐温条件下的动态剪切试验,分析储能模量(G')、损耗模量(G'... 为保障海洋动荷载(波浪、洋流、地震)长期作用下海底结构物的稳定性,需明确海床表层深海软黏土的流变特性。本研究以深海软黏土为对象,采用应变控制模式流变仪,开展不同盐温条件下的动态剪切试验,分析储能模量(G')、损耗模量(G'')和交叉应变的变化规律,结合液塑限试验和自由沉降试验,揭示盐温条件对深海软黏土流变行为的影响机制。试验结果表明,随NaCl溶液浓度(CNaCl)升高与温度降低,深海软黏土的液限、塑限、沉降体积、G'、G''及交叉应变均呈增大趋势,该现象与黏土颗粒絮凝结构发育及双电层厚度减小直接相关;随剪切应变增加,深海软黏土呈现典型两步屈服特征:第一屈服发生于模量首次下降阶段(对应絮凝网络破坏),第二屈服出现于模量二次下降阶段(对应剪切诱导形成的中空圆柱形结构破碎),两屈服阶段间的平台期由中空圆柱形结构的抗剪切作用所致。本研究成果可为超深海工程基础设计与稳定性评估提供理论依据。 展开更多
关键词 深海软黏土 动态振荡剪切 流变行为 双电层 絮凝结构
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Application of biochar-based materials in environmental remediation:from multi-level structures to specific devices 被引量:17
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作者 Lun Lu Wentao Yu +7 位作者 Yaofeng Wang Kun Zhang Xiaomin Zhu Yuecan Zhang Yajing Wu Habib Ullah Xin Xiao Baoliang Chen 《Biochar》 2020年第1期1-31,共31页
The development of biochar has triggered a hot-spot in various research fields including agriculture,energy,environment,and materials.Biochar-based materials provide a novel approach against environmental challenging ... The development of biochar has triggered a hot-spot in various research fields including agriculture,energy,environment,and materials.Biochar-based materials provide a novel approach against environmental challenging issues.Considering the rapid development of biochar materials,this review serves as a valuable platform to summarize the recent progress on the theoretical investigation and engineering applications of biochar materials in environmental remediation.For a better understanding of the structure-application relationships,the structural properties of biochar from macroscopic and microscopic aspects are summarized.The multilevel structures including elements,phases,surface chemistry,and molecular are highlighted to elucidate the multi-functional properties of biochars.Sorption,catalysis,redox reaction,and biological activity of biochar are briefly illustrated,which influence the transport,transformation,and removal of organic and inorganic pollutants in the environments.According to the multi-level structures and structure-application relationships of biochar,specific biochar-based materials and devices have been designed for practical environmental application.The important progress on the functionalization and device of biochar-based materials,including magnetic biochars,2D and 3D biochar-based macrostructures,immobilized microorganism on biochar,and biochar-amended biofilters are highlighted.The environmental friendliness and sustainability of biochar-based materials,considering the whole cycle from synthesis to application,are evaluated. 展开更多
关键词 Biochar-based materials Environmental remediation multi-level structure Reactivity Macrostructures BIOFILTERS
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壳聚糖类絮凝剂及其在水处理中的应用研究
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作者 刘倩 《工程建设与设计》 2025年第11期6-8,共3页
基于结构-活性关系来选择和确定高性能材料是一项重要的工作。论文通过探讨不同的絮凝机理及其在含有不同污染物的各种废水处理中的应用,重点分析研究了壳聚糖类絮凝剂的结构元素对其絮凝特性的影响,其作为絮凝剂在水处理中具有巨大的... 基于结构-活性关系来选择和确定高性能材料是一项重要的工作。论文通过探讨不同的絮凝机理及其在含有不同污染物的各种废水处理中的应用,重点分析研究了壳聚糖类絮凝剂的结构元素对其絮凝特性的影响,其作为絮凝剂在水处理中具有巨大的应用潜力。 展开更多
关键词 壳聚糖絮凝剂 结构-活性关系 絮凝机理 化学改性 水处理
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矿物掺合料对低水胶比铝酸钙水泥浆体流变性能的影响
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作者 刘方宁 刘健 吕梁胜 《硅酸盐通报》 北大核心 2025年第11期4080-4091,共12页
铝酸钙水泥具有早期强度高、耐火性能优异的优点,被广泛应用于应急抢险和高温环境中,在现场施工时,铝酸钙水泥的流变特性至关重要。本研究在铝酸钙水泥中加入粒化高炉矿渣粉和硅灰,制备了铝酸钙水泥复合浆体(以下简称浆体),并测定了其... 铝酸钙水泥具有早期强度高、耐火性能优异的优点,被广泛应用于应急抢险和高温环境中,在现场施工时,铝酸钙水泥的流变特性至关重要。本研究在铝酸钙水泥中加入粒化高炉矿渣粉和硅灰,制备了铝酸钙水泥复合浆体(以下简称浆体),并测定了其流变性能。通过测定Zeta电位、水化热、低场核磁共振弛豫信号、水膜厚度和絮凝结构,研究了粒化高炉矿渣粉和硅灰对浆体流变性能的影响机理。结果表明,粒化高炉矿渣粉在10%(质量分数)掺量内对浆体屈服应力影响较为明显,而硅灰对浆体屈服应力影响不明显。随着粒化高炉矿渣粉含量的增加,浆体塑性黏度值显著增加,而随着硅灰含量的增加,浆体塑性黏度值逐渐减小。粒化高炉矿渣粉可以加速水化,凝胶孔隙峰信号增强。加入硅灰后,弛豫信号强度明显增强,总孔隙度降低,孔隙结构得到优化。粒化高炉矿渣粉和硅灰的存在显著降低了浆体Zeta电位值和电导率。硅灰可以减少絮凝结构的生成数量,改善浆体堆积状态,从而释放体系中更多的过剩水,增大水膜层厚度,而粒化高炉矿渣粉则相反。 展开更多
关键词 铝酸钙水泥 粒化高炉矿渣粉 硅灰 流变性能 水膜层厚度 絮凝结构
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微生物絮凝剂MBFGA1的结构鉴定及絮凝机理研究 被引量:18
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作者 张媛媛 杨朝晖 +4 位作者 曾光明 汪理科 黄兢 魏淑梅 冯婧 《中国环境科学》 EI CAS CSCD 北大核心 2013年第2期278-285,共8页
以对高岭土的絮凝率为指标对GA1发酵液中各组分的絮凝活性进行预分析,确定MBFGA1精产品为该絮凝剂的核心有效成分.通过丙酮沉淀法提取MBFGA1粗产品,经Sevage试剂纯化后得到MBFGA1精产品,采用全波长扫描、苯酚-硫酸法及考马斯亮蓝法鉴定... 以对高岭土的絮凝率为指标对GA1发酵液中各组分的絮凝活性进行预分析,确定MBFGA1精产品为该絮凝剂的核心有效成分.通过丙酮沉淀法提取MBFGA1粗产品,经Sevage试剂纯化后得到MBFGA1精产品,采用全波长扫描、苯酚-硫酸法及考马斯亮蓝法鉴定精产品为多糖类物质,并经2次凝胶过滤层析分离获得MBFGA1-1和MBFGA1-2两组分;分别使用电镜(ESEM)、红外光谱(FTIR)、高效液相色谱(HPLC)以及气相色谱(GC)对MBFGA1、MBFGA1-1和MBFGA1-2进行检测分析.结果显示MBFGA1为线性长链状分子结构,多糖主链上单糖间的连接主要为α-型糖苷键,含有羟基,羧基,甲氧基等有利于絮凝的基团;高效液相色谱和气相色谱测定MBFGA1-1分子量为1.18 106D,单糖组成为0.3木糖:1甘露糖:1.09葡萄糖,另含有少量鼠李糖;MBFGA1-2分子量为3.08 103D,单糖组成为0.68鼠李糖:0.28木糖:1.82甘露糖:1半乳糖:3.73葡萄糖.根据分析结果推测絮凝机理主要为吸附架桥,其中MBFGA1的大分子量以及所含的极性基团使得絮凝剂长链结构分子能够充分伸展,较好地发挥吸附架桥作用. 展开更多
关键词 微生物絮凝剂 多糖 分子结构 絮凝 絮凝活性 絮凝机理
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絮凝条件对絮体分形结构的影响 被引量:38
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作者 李冬梅 施周 +2 位作者 梅胜 谭万春 金同轨 《环境科学》 EI CAS CSCD 北大核心 2006年第3期488-492,共5页
在85kg/m3的含沙高浊水中投加阳离子高分子聚合物,借助图像分析技术与沉降技术分析探讨了不同絮凝条件下泥沙絮凝形态学参数:絮体粒径、絮体有效质量密度、絮体自由沉速、浑液面沉速与上清液余浊等的变化规律.利用表征参数“分维”定量... 在85kg/m3的含沙高浊水中投加阳离子高分子聚合物,借助图像分析技术与沉降技术分析探讨了不同絮凝条件下泥沙絮凝形态学参数:絮体粒径、絮体有效质量密度、絮体自由沉速、浑液面沉速与上清液余浊等的变化规律.利用表征参数“分维”定量控制不同絮凝条件(如搅拌速率、搅拌时间、高分子浓度等)对含沙高浊水絮体结构分形特性的影响.实验证明,不合适的絮凝条件将导致絮体分形构造疏松脆弱,分维值低.絮凝条件合适时(快速絮凝强度为:r1=300r/min,t1=10s;慢速絮凝强度:r2=120r/min,t2=180s;CP浓度:0.1%),絮体分形结构处于最佳状态.该状态下的絮体具有粒径较大、沉速快、有效质量密度高、粒度分布均匀,分维值最高(D3=2.16)的特点.而且,由静沉实验测得浑液面沉速高,上清液余浊也低.泥沙絮体分形结构达最佳时的混凝性能、沉降性能与结构密实性均较理想. 展开更多
关键词 含沙高浊水 架桥絮体 絮凝条件 絮凝形态学 分形结构 分形维数
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聚硅酸锌絮凝剂的电镜特征和絮凝效果 被引量:48
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作者 刘和清 汪凤珍 +2 位作者 袁天佑 谭承德 韦万兴 《环境化学》 CAS CSCD 北大核心 2001年第2期179-184,共6页
利用透射电子显微镜(TEM)和扫描电子显微镜(SEM)观察了聚硅酸锌(PSAZ)絮凝剂的凝胶颗粒结构,考察了不同浓度的锌离子与二氧化硅含量以及不同阴离子组成对聚硅酸锌絮凝剂凝胶结构的影响.对比了锌离子和铝离子形成聚硅酸盐絮... 利用透射电子显微镜(TEM)和扫描电子显微镜(SEM)观察了聚硅酸锌(PSAZ)絮凝剂的凝胶颗粒结构,考察了不同浓度的锌离子与二氧化硅含量以及不同阴离子组成对聚硅酸锌絮凝剂凝胶结构的影响.对比了锌离子和铝离子形成聚硅酸盐絮凝剂的结构特征.同时比较了聚硅酸锌絮凝剂和铝系列絮凝剂的絮凝效果. 展开更多
关键词 聚硅酸锌 聚硅酸铝 凝胶结构 电镜特征 絮凝效果 絮凝剂
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结构流充填料浆管道输送阻力特性 被引量:48
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作者 吴爱祥 刘晓辉 +3 位作者 王洪江 王贻明 焦华喆 刘斯忠 《中南大学学报(自然科学版)》 EI CAS CSCD 北大核心 2014年第12期4325-4330,共6页
基于结构动力学理论,结合宾汉流体模型,探讨膏体充填料浆管道输送阻力特性的变化规律,并通过某铅锌矿充填膏体的泵送环管试验数据对结论进行验证。研究结果表明:随着流速v增加,管道摩阻损失im呈先减小再增大的趋势,存在一最佳流速vx,... 基于结构动力学理论,结合宾汉流体模型,探讨膏体充填料浆管道输送阻力特性的变化规律,并通过某铅锌矿充填膏体的泵送环管试验数据对结论进行验证。研究结果表明:随着流速v增加,管道摩阻损失im呈先减小再增大的趋势,存在一最佳流速vx,在此条件下管阻损失im(vx)有最小值;vx受浆体流变性质及管径影响,管径越大,vx越大。当采用全尾砂+水淬渣物料配比,管径178 mm,输送流速0.7-0.8 m/s时,系统能耗较低且满足充填要求,为合理输送参数。 展开更多
关键词 全尾砂 结构流 絮网结构 剪切速率 管阻损失
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利用FBRM研究阳离子聚丙烯酰胺对高岭土的动态絮凝过程 被引量:11
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作者 张方东 李国栋 +3 位作者 裴继诚 王长建 王海洋 王嵌嵌 《中国造纸》 CAS 北大核心 2013年第10期15-20,共6页
利用聚焦光束反射测量仪(FBRM)研究了阳离子聚丙烯酰胺(CPAM)对高岭土颗粒体系的动态絮凝过程,结合浊度仪、激光衍射粒度仪、显微摄像等表征手段,探讨了絮凝剂用量对絮凝性能和絮体结构的影响。同时基于分形理论对絮凝过程中絮体分形维... 利用聚焦光束反射测量仪(FBRM)研究了阳离子聚丙烯酰胺(CPAM)对高岭土颗粒体系的动态絮凝过程,结合浊度仪、激光衍射粒度仪、显微摄像等表征手段,探讨了絮凝剂用量对絮凝性能和絮体结构的影响。同时基于分形理论对絮凝过程中絮体分形维数的变化进行了考察,基于Smoluchowski模型研究了CPAM作用下高岭土粒子的絮凝动力学。结果表明,随着药品用量的增加,体系中粒子的平均弦长和粒径逐渐增大,体系达到稳定的时间延长,浊度不断下降。在絮凝过程中,随着作用时间的延长,絮体结构发生变化,分形维数增加,形成相对致密的絮体。增加絮凝剂的用量,絮凝作用增强,絮体尺寸变大,絮凝速率较快,需较长的絮凝反应时间才能达到平衡。 展开更多
关键词 絮凝剂 FBRM 絮体结构 分形维数 絮凝动力学
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