Herein,3‑aminopropyltriethoxysilane(APTES)was used to modify F‑containing silica slag(SS)by simple grafting and served as a multifunctional barrier layer.The amino group(—NH2)in the amino‑modified SS(NH2‑SS)forms lig...Herein,3‑aminopropyltriethoxysilane(APTES)was used to modify F‑containing silica slag(SS)by simple grafting and served as a multifunctional barrier layer.The amino group(—NH2)in the amino‑modified SS(NH2‑SS)forms ligand bonds or hydrogen bonds with sulfur ions in lithium polysulfides(LiPSs),thus inhibiting the shuttle effect.Electrochemical analyses demonstrated that lithium‑sulfur(Li‑S)batteries employing the NH2‑SS interlayer exhibited discharge specific capacities of 1048 and 789 mAh·g^(-1) at 0.2C and 2C,respectively,and even at 4C,the initial discharge specific capacity remained at 590 mAh·g^(-1),outperforming the Li‑S battery with unmodified SS as the interlayer.展开更多
The key parameters that characterize the morphological quality of multi-layer and multi-pass metal laser deposited parts are the surface roughness and the error between the actual printing height and the theoretical m...The key parameters that characterize the morphological quality of multi-layer and multi-pass metal laser deposited parts are the surface roughness and the error between the actual printing height and the theoretical model height.The Taguchi method was employed to establish the correlations between process parameter combinations and multi-objective characterization of metal deposition morphology(height error and roughness).Results show that using the signal-to-noise ratio and grey relational analysis,the optimal parameter combination for multi-layer and multi-pass deposition is determined as follows:laser power of 800 W,powder feeding rate of 0.3 r/min,step distance of 1.6 mm,and scanning speed of 20 mm/s.Subsequently,a Genetic Bayesian-back propagation(GB-BP)network is constructed to predict multi-objective responses.Compared with the traditional back propagation network,the GB-back propagation network improves the prediction accuracy of height error and surface roughness by 43.14%and 71.43%,respectively.This network can accurately predict the multi-objective characterization of morphological quality of multi-layer and multi-pass metal deposited parts.展开更多
NaCu_(0.2)Fe_(0.3)Mn_(0.5)O_(2) (NCFM) cathode material was synthesized using a simple solid-state reaction, and the effect of calcination temperature on its interlayer spacing and oxygen vacancies concentration was i...NaCu_(0.2)Fe_(0.3)Mn_(0.5)O_(2) (NCFM) cathode material was synthesized using a simple solid-state reaction, and the effect of calcination temperature on its interlayer spacing and oxygen vacancies concentration was investigated. Through electrochemical testing and material characterizations, higher calcination temperatures increase the electrostatic repulsion between oxygen atoms in adjacent layers, resulting in an expansion of Na layer spacing. This structural change enhances the diffusion kinetics of Na^(+), thereby significantly improving the rate performance of NCFM. Furthermore, elevated calcination temperatures facilitate the reduction of oxygen vacancies, leading to improved crystallinity. This enhancement in crystallinity mitigates structural strain during phase transitions, contributing to improved cyclic stability. Consequently, the optimized NCFM shows an initial discharge specific capacity of 143.3 mA·h/g at 0.1C, with a capacity retention rate of 79.28% after 100 cycles at 1C.展开更多
Based on the Smit-Suhl formula,we propose a universal approach for solving the magnon-magnon coupling problem in bilayer coupled systems(e.g.,antiferromagnets).This method requires only the energy expression,enabling ...Based on the Smit-Suhl formula,we propose a universal approach for solving the magnon-magnon coupling problem in bilayer coupled systems(e.g.,antiferromagnets).This method requires only the energy expression,enabling the automatic derivation of analytical expressions for the eigenmatrix elements via symbolic computation,eliminating the need for tedious manual calculations.Using this approach,we investigate the impact of magnetic hysteresis on magnon-magnon coupling in a system with interlayer Dzyaloshinskii-Moriya interaction(DMI).The magnetic hysteresis leads to an asymmetric magnetic field dependence of the resonance frequency and alters the number of degeneracy points between the pure optical and acoustic modes.Moreover,it can result in the coupling strength at the gap of the f–H phase diagram being nearly vanishing,contrary to the conventionally expected maximum.These results deepen the understanding of the effect of interlayer DMI on magnon–magnon coupling and the proposed universal method significantly streamlines the solving process of magnon–magnon coupling problems.展开更多
X oilfield is a typical layered reservoir with a large vertical span and many oil-bearing formations. There are significant differences in reservoir types and fluid properties among various formations. The interlayer ...X oilfield is a typical layered reservoir with a large vertical span and many oil-bearing formations. There are significant differences in reservoir types and fluid properties among various formations. The interlayer interference is severe in the development process. At present, the interlayer interference research based on dynamic monitoring data cannot meet development adjustment needs. Combined with the field test results, through the indoor physical simulation experiment method, dynamic inversion method, and reservoir engineering method, this paper analyzes the main control factors and interference mechanism of interlayer interference, studies the variation law of interference coefficient, improves and forms the quantitative characteristic Theory of interlayer interference in multi-layer commingled production, and provides theoretical guidance for the total adjustment of the middle strata division in the oilfield.展开更多
X oilfield is a typical multi-layer sandstone reservoir in offshore China. In the early stage, in order to obtain economic oil production, directional well was used to adopt a set of multi-layer combined production, w...X oilfield is a typical multi-layer sandstone reservoir in offshore China. In the early stage, in order to obtain economic oil production, directional well was used to adopt a set of multi-layer combined production, which resulted in serious interlayer interference, water injection inrush and low reserve utilization. Based on the theory of single-phase unstable seepage flow and the theory of oil-water two-phase non-piston displacement, the author innovatively established a mathematical model of interlayer dynamic interference in multilayer sandstone reservoirs, revealed the influence law of main controlling factors such as permeability, viscosity, starting pressure gradient and reservoir type on interlayer interference, and innovatively formed a quantitative characterization theory of interlayer interference in multilayer combined oil production. The technical demarcation of offshore multi-zone combined oil production reservoir system is formulated and the recombination of oil field development system is guided.展开更多
At present,the emerging solid-phase friction-based additive manufacturing technology,including friction rolling additive man-ufacturing(FRAM),can only manufacture simple single-pass components.In this study,multi-laye...At present,the emerging solid-phase friction-based additive manufacturing technology,including friction rolling additive man-ufacturing(FRAM),can only manufacture simple single-pass components.In this study,multi-layer multi-pass FRAM-deposited alumin-um alloy samples were successfully prepared using a non-shoulder tool head.The material flow behavior and microstructure of the over-lapped zone between adjacent layers and passes during multi-layer multi-pass FRAM deposition were studied using the hybrid 6061 and 5052 aluminum alloys.The results showed that a mechanical interlocking structure was formed between the adjacent layers and the adja-cent passes in the overlapped center area.Repeated friction and rolling of the tool head led to different degrees of lateral flow and plastic deformation of the materials in the overlapped zone,which made the recrystallization degree in the left and right edge zones of the over-lapped zone the highest,followed by the overlapped center zone and the non-overlapped zone.The tensile strength of the overlapped zone exceeded 90%of that of the single-pass deposition sample.It is proved that although there are uneven grooves on the surface of the over-lapping area during multi-layer and multi-pass deposition,they can be filled by the flow of materials during the deposition of the next lay-er,thus ensuring the dense microstructure and excellent mechanical properties of the overlapping area.The multi-layer multi-pass FRAM deposition overcomes the limitation of deposition width and lays the foundation for the future deposition of large-scale high-performance components.展开更多
Protonic solid oxide electrolysis cells(P-SOECs)are a promising technology for water electrolysis to produce green hydrogen.However,there are still challenges related key materials and anode/electrolyte interface.P-SO...Protonic solid oxide electrolysis cells(P-SOECs)are a promising technology for water electrolysis to produce green hydrogen.However,there are still challenges related key materials and anode/electrolyte interface.P-SOECs with Zr-rich electrolyte,called Zr-rich side P-SOECs,possess high thermodynamically stability under high steam concentrations but the large reaction resistances and the current leakage,thus the inferior performances.In this study,an efficient functional interlayer Ba_(0.95)La_(0.05)Fe_(0.8)Zn_(0.2)O_(3-δ)(BLFZ)in-between the anode and the electrolyte is developed.The electrochemical performances of P-SOECs are greatly enhanced because the BLFZ can greatly increase the interface contact,boost anode reaction kinetics,and increase proton injection into electrolyte.As a result,the P-SOEC yields high current density of 0.83 A cm^(-2) at 600℃ in 1.3 Vamong all the reported Zr-rich side cells.This work not only offers an efficient functional interlayer for P-SOECs but also holds the potential to achieve P-SOECs with high performances and long-term stability.展开更多
Regulating lithium(Li)plating/stripping behavior in three-dimensional(3D)conductive scaffolds is critical to stabilizing Li metal batteries(LMBs).Surface protrusions and roughness in these scaffolds can induce uneven ...Regulating lithium(Li)plating/stripping behavior in three-dimensional(3D)conductive scaffolds is critical to stabilizing Li metal batteries(LMBs).Surface protrusions and roughness in these scaffolds can induce uneven distributions of the electric fields and ionic concentrations,forming“hot spots.”Hot spots may cause uncontrollable Li dendrites growth,presenting significant challenges to the cycle stability and safety of LMBs.To address these issues,we construct a Li ionic conductive-dielectric gradient bifunctional interlayer(ICDL)onto a 3D Li-injected graphene/carbon nanotube scaffold(LGCF)via in situ reaction of exfoliated hexagonal boron nitride(fhBN)and molten Li.Microscopic and spectroscopic analyses reveal that ICDL consists of fhBN-rich outer layer and inner layer enriched with Li_(3)N and Li-boron composites(Li-B).The outer layer utilizes dielectric properties to effectively homogenize the electric field,while the inner layer ensures high Li ion conductivity.Moreover,DFT calculations indicate that ICDL can effectively adsorb Li and decrease the Li diffusion barrier,promoting enhanced Li ion transport.The modulation of Li kinetics by ICDL increases the critical length of the Li nucleus,enabling suppression of Li dendrite growth.Attributing to these advantages,the ICDL-coated LGCF(ICDL@LGCF)demonstrates impressive long-term cycle performances in both symmetric cells and full cells.展开更多
As artificial intelligence and big data become increasingly prevalent, resistive random-access memory (RRAM) has become one of the most promising alternatives for storing massive amounts of data. In this study, we emp...As artificial intelligence and big data become increasingly prevalent, resistive random-access memory (RRAM) has become one of the most promising alternatives for storing massive amounts of data. In this study, we employed high-quality crystalline TiN/Al_(2)O_(3)/BaTiO_(3)/Pt RRAM with an optimized thin Al_(2)O_(3) interlayer around 12 nm thick prepared using atomic layer deposition since the thickness of the interlayer affects the memory window size. After insertion of the Al_(2)O_(3) interlayer, the novel RRAM exhibited outstanding uniform resistive switching voltage and the ON/OFF memory window drastically increased from 10 to 103 without any discernible decline in performance. Moreover, the low-resistance state and high-resistance state operating current values decreased by almost one order and three orders of magnitude, respectively, thereby decreasing the power consumption for the RESET and SET processes by more than three and almost one order of magnitude, respectively. The device also exhibits multilevel resistive switching behavior when varying the applied voltage. Finally, we also developed a 6 6 crossbar array which demonstrated consistent and reliable resistive switching behavior with minimal variation. Hence, our approach holds great promise for producing state-of-the-art non-volatile resistive switching devices.展开更多
A functional interlayer based on two-dimensional(2D)porous modified vermiculite nanosheets(PVS)was obtained by acid-etching vermiculite nanosheets.The as-obtained 2D porous nanosheets exhibited a high specific surface...A functional interlayer based on two-dimensional(2D)porous modified vermiculite nanosheets(PVS)was obtained by acid-etching vermiculite nanosheets.The as-obtained 2D porous nanosheets exhibited a high specific surface area of 427 m^(2)·g^(-1)and rich surface active sites,which help restrain polysulfides(LiPSs)through good physi-cal and chemical adsorption,while simultaneously accelerating the nucleation and dissolution kinetics of Li_(2)S,effec-tively suppressing the shuttle effect.The assembled lithium-sulfur batteries(LSBs)employing the PVS-based inter-layer delivered a high initial discharge capacity of 1386 mAh·g^(-1)at 0.1C(167.5 mAh·g^(-1)),long-term cycling stabil-ity,and good rate property.展开更多
Due to its unique layered structure and excellent electrochemical properties,molybdenum disulfide(MoS_(2))demonstrates significant potential for applications in the energy storage field,particularly in supercapacitors...Due to its unique layered structure and excellent electrochemical properties,molybdenum disulfide(MoS_(2))demonstrates significant potential for applications in the energy storage field,particularly in supercapacitors.It is widely regarded as one of the most representative transition metal dichalcogenides.MoS_(2)possesses a high theoretical specific capacitance,abundant edge active sites,and favorable tunability and structural diversity,which provide it with a distinct advantage in the construction of advanced electrode structures.Additionally,the anisotropic characteristics of MoS_(2)concerning electron and ion transport offer more dimensions for regulating its electrochemical behavior.This work will systematically review various synthesis strategies for MoS_(2)and its recent advancements in energy storage,with a particular focus on the mechanisms by which interlayer spacing modulation affects energy storage behavior in supercapacitor configurations.The discussion will encompass a comprehensive logical framework that spans material structure modifications,electronic configuration evolution,and enhancements in macroscopic device performance.This review aims to provide theoretical support and practical guidance for the application of MoS_(2)in the next generation of highperformance energy storage devices.展开更多
The transient liquid-phase(TLP)diffusion bonding of GH5188 with a BNi-5 interlayer was focused on.Parameters were chosen and optimized for GH5188 alloy according to the TLP joining mechanism.The microstructure evoluti...The transient liquid-phase(TLP)diffusion bonding of GH5188 with a BNi-5 interlayer was focused on.Parameters were chosen and optimized for GH5188 alloy according to the TLP joining mechanism.The microstructure evolution and mechanical properties of the joints were studied.Results show that the relatively complete isothermal solidification zone(ISZ)ensures a reliable connection of the base metal(BM).Within the temperature range of 1110–1190°C,higher bonding temperatures can widen ISZ and promote joint composition homogenization,thus improving mechanical properties.However,the increase in precipitated phase has an adverse effect on the mechanical properties of the joint.The maximum shear strength,reaching 482 MPa,is achieved at 1130°C,representing 84.6%of BM strength.Within the pressure range of 5–15 MPa,both precipitated phases in adiabatic solidification zone(ASZ)and voids generated by partial melting increase.On the contrary,their sizes decrease significantly under higher bonding pressure,resulting in an upward trend in alloy mechanical properties.The maximum shear strength of 490 MPa is attained at a bonding pressure of 15 MPa.The joint exhibits a typical mixed fracture pattern,with the small brittle M_(23)C_(6) phase and voids significantly impacting mechanical properties.Nano-indentation tests indicate that ASZ is a potential source of cracks.展开更多
Interlayer exchange coupling(IEC)plays a critical role in spin-orbit torque(SOT)switching in synthetic magnets.This work establishes a fundamental correlation between IEC and SOT dynamics within Co/Pt-based synthetic ...Interlayer exchange coupling(IEC)plays a critical role in spin-orbit torque(SOT)switching in synthetic magnets.This work establishes a fundamental correlation between IEC and SOT dynamics within Co/Pt-based synthetic antiferromagnets and synthetic ferromagnets.The antiferromagnetic and ferromagnetic coupling states are precisely engineered through Ruderman-Kittel-Kasuya-Yosida(RKKY)interactions by modulating the Ir spacer thickness.Experimental results reveal that the critical switching current density exhibits a strong positive correlation with the IEC strength,regardless of the coupling type.A comprehensive theoretical framework based on the Landau-Lifshitz-Gilbert equation elucidates how IEC contributes to the effective energy barrier that must be overcome during SOT-induced magnetization switching.Significantly,the antiferromagnetically coupled samples demonstrate enhanced SOT efficiency,with the spin Hall angle being directly proportional to the antiferromagnetic exchange coupling field.These insights establish a coherent physical paradigm for understanding IEC-dependent SOT dynamics and provide strategic design principles for the development of energy-efficient next-generation spintronic devices.展开更多
Surface adsorption plays a crucial role in various natural and industrial processes,particularly in the field of energy storage.The adsorption of sodium atoms on 2D layered materials can significantly impact their per...Surface adsorption plays a crucial role in various natural and industrial processes,particularly in the field of energy storage.The adsorption of sodium atoms on 2D layered materials can significantly impact their performance as carriers and electrodes in ion batteries.While it is commonly acknowledged that pristine graphene is not favorable for sodium ion adsorption,the suitability of other 2D materials with similar honeycomb symmetry remains unclear.In this study,we employ systematic first-principles calculations to explore interlayer interactions and electron transfer effects on sodium adsorption on 2D van der Waals(vdW)heterostructures(HTSs)surfaces.Our results demonstrate that sodium adsorption is energetically favorable on these substrates.Moreover,we find that the adsorption strength can be effectively tuned by manipulation of the electron accumulation or depletion of the layer directly interacting with the sodium atom.By stacking these layered materials with different electron abundancy to form vd W HTSs,the charge density of the substrate becomes tunable through interlayer charge transfer.In these vdW HTSs,the adsorption behavior of sodium is primarily controlled by the absorption layer and exhibits a linear correlation with its pz-band center.Additionally,we identify linear correlations between the sodium adsorption energies,the electron loss of the sodium atom,the interlayer charge transfer,and the heights of the adsorbed sodium atom.These discoveries underscore the impact of interlayer electron transfer and interactions on sodium ion adsorption on 2D vd W HTSs and providing new insights into material design for alkali atom adsorption.展开更多
The diversity of interlayers in shale oil reservoir leads to a low degree of vertical reconstruction.This paper aims to propose a method to guide the synchronous initiation of hydraulic fractures in different layers b...The diversity of interlayers in shale oil reservoir leads to a low degree of vertical reconstruction.This paper aims to propose a method to guide the synchronous initiation of hydraulic fractures in different layers by drilling multi-layer radial wells in spatial positions,and to form a fracture network that satisfies the vertical propagation range and complexity.In this paper,a 3D(three-dimensional)multi-layer radial well fracturing model considering fluid-mechanics coupling is established and the properties of shale oil reservoir are characterized according to the field geological profile.The influences of radial well spacing,fracturing fluid injection rate,and fracturing fluid viscosity on vertical fracture communication in multilayer radial wells are investigated.The results show that the radial well has the characteristics of guiding fracture penetrating interlayers.Reducing radial well spacing and appropriately increasing injection rate and viscosity are beneficial to improving vertical fracture propagation ability.However,high fracture fluid viscosity under the same displacement will lead to a significant increase in fracture aperture and weaken the total fracture area.In addition,if the stress interference around the radial wells is low,the radial well can be located in the middle of each layer to minimize the fracture height limitation.This study can provide a solution idea for vertical propagation limitation of hydraulic fractures in shale oil reservoir.展开更多
The potential of the vertical-horizontal well hybrid SAGD technique for developing shallow heavy oil reservoirs is gradually being realized.However,challenges remain in terms of low thermal efficiency and high carbon ...The potential of the vertical-horizontal well hybrid SAGD technique for developing shallow heavy oil reservoirs is gradually being realized.However,challenges remain in terms of low thermal efficiency and high carbon emissions in reservoirs with interlayers.Currently,there is limited research on the low-carbon strategy of coupling exhaust gas from steam boilers with the VH-SAGD technique.Herein,considering heterogeneity,a series of flue gas-assisted VH-SAGD experiments were conducted employing a high-performance 2D visualization model.The mechanism of enhanced recovery of flue gas in VH-SAGD and the effect of its injection methods were studied,with a focus on steam chamber development and oil saturation distribution.Crucially,the interlayer length was optimized to enhance oil recovery,providing a new perspective for well location design in heavy oil reservoirs with interlayers.The results showed that flue gas,as an additive,could fully exploit the well-type advantage of VH-SAGD.By supplementing energy at the reservoir top,flue gas effectively promoted steam chamber development,expanded the oil drainage area of VH-SAGD,and increased the oil recovery from 58.9%to 71.7%.The flow channels formed by pre-injection flue gas accelerated the early-stage expansion of the steam chamber while also inducing lateral migration of steam,slowing steam rise,and consequently increasing the heating range within the low-permeability layer.When the distance between the vertical and horizontal wells was set to twice the interlayer length,the negative effects of the interlayer were more effectively turned into advantages.Because when the lateral development distance of the steam chamber in the low-permeability layer slightly exceeds the interlayer,enhanced heating of the lower part of the reservoir occurred through vertical convection of rising steam and returning condensate.The research results contribute to reducing carbon emissions from steam-based heavy oil extraction while advancing the maturity of VH-SAGD.展开更多
The huge impact kinetic energy cannot be quickly dissipated by the energy-absorbing structure and transferred to the other vehicle through the car body structure,which will cause structural damage and threaten the liv...The huge impact kinetic energy cannot be quickly dissipated by the energy-absorbing structure and transferred to the other vehicle through the car body structure,which will cause structural damage and threaten the lives of the occupants.Therefore,it is necessary to understand the laws of energy conversion,dissipation and transfer during train collisions.This study proposes a multi-layer progressive analysis method of energy flow during train collisions,considering the characteristics of the train.In this method,the train collision system is divided into conversion,dissipation,and transfer layers from the perspective of the train,collision interface,and car body structure to analyze the energy conversion,dissipation and transfer characteristics.Taking the collision process of a rail train as an example,a train collision energy transfer path analysis model was established based on power flow theory.The results show that when the maximum mean acceleration of the vehicle meets the standard requirements,the jerk may exceed the allowable limit of the human body,and there is a risk of injury to the occupants of a secondary collision.The decay rate of the collision energy along the direction of train operation reaches 79%.As the collision progresses,the collision energy gradually converges in the structure with holes,and the structure deforms when the gathered energy is greater than the maximum energy the structure can withstand.The proposed method helps to understand the train collision energy flow law and provides theoretical support for the train crashworthiness design in the future.展开更多
The growing incidence of cyberattacks necessitates a robust and effective Intrusion Detection Systems(IDS)for enhanced network security.While conventional IDSs can be unsuitable for detecting different and emerging at...The growing incidence of cyberattacks necessitates a robust and effective Intrusion Detection Systems(IDS)for enhanced network security.While conventional IDSs can be unsuitable for detecting different and emerging attacks,there is a demand for better techniques to improve detection reliability.This study introduces a new method,the Deep Adaptive Multi-Layer Attention Network(DAMLAN),to boost the result of intrusion detection on network data.Due to its multi-scale attention mechanisms and graph features,DAMLAN aims to address both known and unknown intrusions.The real-world NSL-KDD dataset,a popular choice among IDS researchers,is used to assess the proposed model.There are 67,343 normal samples and 58,630 intrusion attacks in the training set,12,833 normal samples,and 9711 intrusion attacks in the test set.Thus,the proposed DAMLAN method is more effective than the standard models due to the consideration of patterns by the attention layers.The experimental performance of the proposed model demonstrates that it achieves 99.26%training accuracy and 90.68%testing accuracy,with precision reaching 98.54%on the training set and 96.64%on the testing set.The recall and F1 scores again support the model with training set values of 99.90%and 99.21%and testing set values of 86.65%and 91.37%.These results provide a strong basis for the claims made regarding the model’s potential to identify intrusion attacks and affirm its relatively strong overall performance,irrespective of type.Future work would employ more attempts to extend the scalability and applicability of DAMLAN for real-time use in intrusion detection systems.展开更多
文摘Herein,3‑aminopropyltriethoxysilane(APTES)was used to modify F‑containing silica slag(SS)by simple grafting and served as a multifunctional barrier layer.The amino group(—NH2)in the amino‑modified SS(NH2‑SS)forms ligand bonds or hydrogen bonds with sulfur ions in lithium polysulfides(LiPSs),thus inhibiting the shuttle effect.Electrochemical analyses demonstrated that lithium‑sulfur(Li‑S)batteries employing the NH2‑SS interlayer exhibited discharge specific capacities of 1048 and 789 mAh·g^(-1) at 0.2C and 2C,respectively,and even at 4C,the initial discharge specific capacity remained at 590 mAh·g^(-1),outperforming the Li‑S battery with unmodified SS as the interlayer.
基金National Natural Science Foundation of China(52175237)。
文摘The key parameters that characterize the morphological quality of multi-layer and multi-pass metal laser deposited parts are the surface roughness and the error between the actual printing height and the theoretical model height.The Taguchi method was employed to establish the correlations between process parameter combinations and multi-objective characterization of metal deposition morphology(height error and roughness).Results show that using the signal-to-noise ratio and grey relational analysis,the optimal parameter combination for multi-layer and multi-pass deposition is determined as follows:laser power of 800 W,powder feeding rate of 0.3 r/min,step distance of 1.6 mm,and scanning speed of 20 mm/s.Subsequently,a Genetic Bayesian-back propagation(GB-BP)network is constructed to predict multi-objective responses.Compared with the traditional back propagation network,the GB-back propagation network improves the prediction accuracy of height error and surface roughness by 43.14%and 71.43%,respectively.This network can accurately predict the multi-objective characterization of morphological quality of multi-layer and multi-pass metal deposited parts.
基金supported by the National Natural Science Foundation of China(No.12175089)the Key Research and Development Program of Yunnan Province,China(No.202103AF140006)+2 种基金Basic Research Programs of Yunnan Provincial Science and Technology Department,China(Nos.202001AW070004,202301AS070051,202401AV070008)Yunnan Industrial Innovative Talents Program for“Xingdian Talent Support Plan”,China(No.KKXY202252001)Yunnan Major Scientific and Technological Projects,China(No.202202AG050003)。
文摘NaCu_(0.2)Fe_(0.3)Mn_(0.5)O_(2) (NCFM) cathode material was synthesized using a simple solid-state reaction, and the effect of calcination temperature on its interlayer spacing and oxygen vacancies concentration was investigated. Through electrochemical testing and material characterizations, higher calcination temperatures increase the electrostatic repulsion between oxygen atoms in adjacent layers, resulting in an expansion of Na layer spacing. This structural change enhances the diffusion kinetics of Na^(+), thereby significantly improving the rate performance of NCFM. Furthermore, elevated calcination temperatures facilitate the reduction of oxygen vacancies, leading to improved crystallinity. This enhancement in crystallinity mitigates structural strain during phase transitions, contributing to improved cyclic stability. Consequently, the optimized NCFM shows an initial discharge specific capacity of 143.3 mA·h/g at 0.1C, with a capacity retention rate of 79.28% after 100 cycles at 1C.
基金supported by the National Key Research and Development Program of China (MOST)(Grant No.2022YFA1402800)the Chinese Academy of Sciences (CAS) Presidents International Fellowship Initiative (PIFI)(Grant No.2025PG0006)+3 种基金the National Natural Science Foundation of China (NSFC)(Grant Nos.51831012,12274437,and 52161160334)the CAS Project for Young Scientists in Basic Research (Grant No.YSBR-084)the CAS Youth Interdisciplinary Teamthe China Postdoctoral Science Foundation (Grant No.2025M773402)。
文摘Based on the Smit-Suhl formula,we propose a universal approach for solving the magnon-magnon coupling problem in bilayer coupled systems(e.g.,antiferromagnets).This method requires only the energy expression,enabling the automatic derivation of analytical expressions for the eigenmatrix elements via symbolic computation,eliminating the need for tedious manual calculations.Using this approach,we investigate the impact of magnetic hysteresis on magnon-magnon coupling in a system with interlayer Dzyaloshinskii-Moriya interaction(DMI).The magnetic hysteresis leads to an asymmetric magnetic field dependence of the resonance frequency and alters the number of degeneracy points between the pure optical and acoustic modes.Moreover,it can result in the coupling strength at the gap of the f–H phase diagram being nearly vanishing,contrary to the conventionally expected maximum.These results deepen the understanding of the effect of interlayer DMI on magnon–magnon coupling and the proposed universal method significantly streamlines the solving process of magnon–magnon coupling problems.
文摘X oilfield is a typical layered reservoir with a large vertical span and many oil-bearing formations. There are significant differences in reservoir types and fluid properties among various formations. The interlayer interference is severe in the development process. At present, the interlayer interference research based on dynamic monitoring data cannot meet development adjustment needs. Combined with the field test results, through the indoor physical simulation experiment method, dynamic inversion method, and reservoir engineering method, this paper analyzes the main control factors and interference mechanism of interlayer interference, studies the variation law of interference coefficient, improves and forms the quantitative characteristic Theory of interlayer interference in multi-layer commingled production, and provides theoretical guidance for the total adjustment of the middle strata division in the oilfield.
文摘X oilfield is a typical multi-layer sandstone reservoir in offshore China. In the early stage, in order to obtain economic oil production, directional well was used to adopt a set of multi-layer combined production, which resulted in serious interlayer interference, water injection inrush and low reserve utilization. Based on the theory of single-phase unstable seepage flow and the theory of oil-water two-phase non-piston displacement, the author innovatively established a mathematical model of interlayer dynamic interference in multilayer sandstone reservoirs, revealed the influence law of main controlling factors such as permeability, viscosity, starting pressure gradient and reservoir type on interlayer interference, and innovatively formed a quantitative characterization theory of interlayer interference in multilayer combined oil production. The technical demarcation of offshore multi-zone combined oil production reservoir system is formulated and the recombination of oil field development system is guided.
基金supported by the National Key Research and Development Program of China(No.2022YFB3404700)the National Natural Science Foundation of China(Nos.52105313 and 52275299)+2 种基金the Research and Development Program of Beijing Municipal Education Commission,China(No.KM202210005036)the Natural Science Foundation of Chongqing,China(No.CSTB2023NSCQ-MSX0701)the National Defense Basic Research Projects of China(No.JCKY2022405C002).
文摘At present,the emerging solid-phase friction-based additive manufacturing technology,including friction rolling additive man-ufacturing(FRAM),can only manufacture simple single-pass components.In this study,multi-layer multi-pass FRAM-deposited alumin-um alloy samples were successfully prepared using a non-shoulder tool head.The material flow behavior and microstructure of the over-lapped zone between adjacent layers and passes during multi-layer multi-pass FRAM deposition were studied using the hybrid 6061 and 5052 aluminum alloys.The results showed that a mechanical interlocking structure was formed between the adjacent layers and the adja-cent passes in the overlapped center area.Repeated friction and rolling of the tool head led to different degrees of lateral flow and plastic deformation of the materials in the overlapped zone,which made the recrystallization degree in the left and right edge zones of the over-lapped zone the highest,followed by the overlapped center zone and the non-overlapped zone.The tensile strength of the overlapped zone exceeded 90%of that of the single-pass deposition sample.It is proved that although there are uneven grooves on the surface of the over-lapping area during multi-layer and multi-pass deposition,they can be filled by the flow of materials during the deposition of the next lay-er,thus ensuring the dense microstructure and excellent mechanical properties of the overlapping area.The multi-layer multi-pass FRAM deposition overcomes the limitation of deposition width and lays the foundation for the future deposition of large-scale high-performance components.
基金financial support from the JSPS KAKENHI Grant-in-Aid for Scientific Research(B),No.21H02035KAKENHI Grant-in-Aid for Challenging Research(Exploratory),No.21K19017+2 种基金KAKENHI Grant-in-Aid for Transformative Research Areas(B),No.21H05100National Natural Science Foundation of China,No.22409033 and No.22409035Basic and Applied Basic Research Foundation of Guangdong Province,No.2022A1515110470.
文摘Protonic solid oxide electrolysis cells(P-SOECs)are a promising technology for water electrolysis to produce green hydrogen.However,there are still challenges related key materials and anode/electrolyte interface.P-SOECs with Zr-rich electrolyte,called Zr-rich side P-SOECs,possess high thermodynamically stability under high steam concentrations but the large reaction resistances and the current leakage,thus the inferior performances.In this study,an efficient functional interlayer Ba_(0.95)La_(0.05)Fe_(0.8)Zn_(0.2)O_(3-δ)(BLFZ)in-between the anode and the electrolyte is developed.The electrochemical performances of P-SOECs are greatly enhanced because the BLFZ can greatly increase the interface contact,boost anode reaction kinetics,and increase proton injection into electrolyte.As a result,the P-SOEC yields high current density of 0.83 A cm^(-2) at 600℃ in 1.3 Vamong all the reported Zr-rich side cells.This work not only offers an efficient functional interlayer for P-SOECs but also holds the potential to achieve P-SOECs with high performances and long-term stability.
基金the financial support from the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (NRF-2023R1A2C2007699 and 2022R1A6A1A0306303912)the Nano Material Technology Development Program through the NRF funded by the Ministry of Science and ICT (NRF-2015M3A7B6027970)the Technology Innovation Program by the Ministry of Trade, Industry & Energy (RS-202300236794)
文摘Regulating lithium(Li)plating/stripping behavior in three-dimensional(3D)conductive scaffolds is critical to stabilizing Li metal batteries(LMBs).Surface protrusions and roughness in these scaffolds can induce uneven distributions of the electric fields and ionic concentrations,forming“hot spots.”Hot spots may cause uncontrollable Li dendrites growth,presenting significant challenges to the cycle stability and safety of LMBs.To address these issues,we construct a Li ionic conductive-dielectric gradient bifunctional interlayer(ICDL)onto a 3D Li-injected graphene/carbon nanotube scaffold(LGCF)via in situ reaction of exfoliated hexagonal boron nitride(fhBN)and molten Li.Microscopic and spectroscopic analyses reveal that ICDL consists of fhBN-rich outer layer and inner layer enriched with Li_(3)N and Li-boron composites(Li-B).The outer layer utilizes dielectric properties to effectively homogenize the electric field,while the inner layer ensures high Li ion conductivity.Moreover,DFT calculations indicate that ICDL can effectively adsorb Li and decrease the Li diffusion barrier,promoting enhanced Li ion transport.The modulation of Li kinetics by ICDL increases the critical length of the Li nucleus,enabling suppression of Li dendrite growth.Attributing to these advantages,the ICDL-coated LGCF(ICDL@LGCF)demonstrates impressive long-term cycle performances in both symmetric cells and full cells.
基金supported by the National Research Foundation of Korea funded by the Korean Government(grant No.RS-2023-00208801).
文摘As artificial intelligence and big data become increasingly prevalent, resistive random-access memory (RRAM) has become one of the most promising alternatives for storing massive amounts of data. In this study, we employed high-quality crystalline TiN/Al_(2)O_(3)/BaTiO_(3)/Pt RRAM with an optimized thin Al_(2)O_(3) interlayer around 12 nm thick prepared using atomic layer deposition since the thickness of the interlayer affects the memory window size. After insertion of the Al_(2)O_(3) interlayer, the novel RRAM exhibited outstanding uniform resistive switching voltage and the ON/OFF memory window drastically increased from 10 to 103 without any discernible decline in performance. Moreover, the low-resistance state and high-resistance state operating current values decreased by almost one order and three orders of magnitude, respectively, thereby decreasing the power consumption for the RESET and SET processes by more than three and almost one order of magnitude, respectively. The device also exhibits multilevel resistive switching behavior when varying the applied voltage. Finally, we also developed a 6 6 crossbar array which demonstrated consistent and reliable resistive switching behavior with minimal variation. Hence, our approach holds great promise for producing state-of-the-art non-volatile resistive switching devices.
文摘A functional interlayer based on two-dimensional(2D)porous modified vermiculite nanosheets(PVS)was obtained by acid-etching vermiculite nanosheets.The as-obtained 2D porous nanosheets exhibited a high specific surface area of 427 m^(2)·g^(-1)and rich surface active sites,which help restrain polysulfides(LiPSs)through good physi-cal and chemical adsorption,while simultaneously accelerating the nucleation and dissolution kinetics of Li_(2)S,effec-tively suppressing the shuttle effect.The assembled lithium-sulfur batteries(LSBs)employing the PVS-based inter-layer delivered a high initial discharge capacity of 1386 mAh·g^(-1)at 0.1C(167.5 mAh·g^(-1)),long-term cycling stabil-ity,and good rate property.
文摘Due to its unique layered structure and excellent electrochemical properties,molybdenum disulfide(MoS_(2))demonstrates significant potential for applications in the energy storage field,particularly in supercapacitors.It is widely regarded as one of the most representative transition metal dichalcogenides.MoS_(2)possesses a high theoretical specific capacitance,abundant edge active sites,and favorable tunability and structural diversity,which provide it with a distinct advantage in the construction of advanced electrode structures.Additionally,the anisotropic characteristics of MoS_(2)concerning electron and ion transport offer more dimensions for regulating its electrochemical behavior.This work will systematically review various synthesis strategies for MoS_(2)and its recent advancements in energy storage,with a particular focus on the mechanisms by which interlayer spacing modulation affects energy storage behavior in supercapacitor configurations.The discussion will encompass a comprehensive logical framework that spans material structure modifications,electronic configuration evolution,and enhancements in macroscopic device performance.This review aims to provide theoretical support and practical guidance for the application of MoS_(2)in the next generation of highperformance energy storage devices.
基金National Natural Science Foundation of China(52075449,5197052086)。
文摘The transient liquid-phase(TLP)diffusion bonding of GH5188 with a BNi-5 interlayer was focused on.Parameters were chosen and optimized for GH5188 alloy according to the TLP joining mechanism.The microstructure evolution and mechanical properties of the joints were studied.Results show that the relatively complete isothermal solidification zone(ISZ)ensures a reliable connection of the base metal(BM).Within the temperature range of 1110–1190°C,higher bonding temperatures can widen ISZ and promote joint composition homogenization,thus improving mechanical properties.However,the increase in precipitated phase has an adverse effect on the mechanical properties of the joint.The maximum shear strength,reaching 482 MPa,is achieved at 1130°C,representing 84.6%of BM strength.Within the pressure range of 5–15 MPa,both precipitated phases in adiabatic solidification zone(ASZ)and voids generated by partial melting increase.On the contrary,their sizes decrease significantly under higher bonding pressure,resulting in an upward trend in alloy mechanical properties.The maximum shear strength of 490 MPa is attained at a bonding pressure of 15 MPa.The joint exhibits a typical mixed fracture pattern,with the small brittle M_(23)C_(6) phase and voids significantly impacting mechanical properties.Nano-indentation tests indicate that ASZ is a potential source of cracks.
基金Project supported by the“Pioneer”and“Leading Goose”R&D Program of Zhejiang Province(Grant No.2022C01053)the Key Research and Development Program of Zhejiang Province(Grant No.2021C01039)+1 种基金the National Natural Science Foundation of China(Grant No.62293493)the Natural Science Foundation of Zhejiang Province,China(Grant No.LQ21A050001)。
文摘Interlayer exchange coupling(IEC)plays a critical role in spin-orbit torque(SOT)switching in synthetic magnets.This work establishes a fundamental correlation between IEC and SOT dynamics within Co/Pt-based synthetic antiferromagnets and synthetic ferromagnets.The antiferromagnetic and ferromagnetic coupling states are precisely engineered through Ruderman-Kittel-Kasuya-Yosida(RKKY)interactions by modulating the Ir spacer thickness.Experimental results reveal that the critical switching current density exhibits a strong positive correlation with the IEC strength,regardless of the coupling type.A comprehensive theoretical framework based on the Landau-Lifshitz-Gilbert equation elucidates how IEC contributes to the effective energy barrier that must be overcome during SOT-induced magnetization switching.Significantly,the antiferromagnetically coupled samples demonstrate enhanced SOT efficiency,with the spin Hall angle being directly proportional to the antiferromagnetic exchange coupling field.These insights establish a coherent physical paradigm for understanding IEC-dependent SOT dynamics and provide strategic design principles for the development of energy-efficient next-generation spintronic devices.
基金the financial support by the National Key Research and Development Program of China(No.2019YFA0708700)the National Natural Science Foundation of China(Nos.62305196,U23B2087 and 62375158)+4 种基金the China Postdoctoral Science Foundation(No.GZC20231498)the Qingdao Postdoctoral Innovation Project(No.QDBSH20240102078)the Postdoctoral Innovation Program of Shandong Province(No.SDCX-ZG-202400318)Science and Technology Research Project of Hubei Provincial Department of Education(No.D20212603)Hubei University of Arts and Science(No.2020kypytd002)。
文摘Surface adsorption plays a crucial role in various natural and industrial processes,particularly in the field of energy storage.The adsorption of sodium atoms on 2D layered materials can significantly impact their performance as carriers and electrodes in ion batteries.While it is commonly acknowledged that pristine graphene is not favorable for sodium ion adsorption,the suitability of other 2D materials with similar honeycomb symmetry remains unclear.In this study,we employ systematic first-principles calculations to explore interlayer interactions and electron transfer effects on sodium adsorption on 2D van der Waals(vdW)heterostructures(HTSs)surfaces.Our results demonstrate that sodium adsorption is energetically favorable on these substrates.Moreover,we find that the adsorption strength can be effectively tuned by manipulation of the electron accumulation or depletion of the layer directly interacting with the sodium atom.By stacking these layered materials with different electron abundancy to form vd W HTSs,the charge density of the substrate becomes tunable through interlayer charge transfer.In these vdW HTSs,the adsorption behavior of sodium is primarily controlled by the absorption layer and exhibits a linear correlation with its pz-band center.Additionally,we identify linear correlations between the sodium adsorption energies,the electron loss of the sodium atom,the interlayer charge transfer,and the heights of the adsorbed sodium atom.These discoveries underscore the impact of interlayer electron transfer and interactions on sodium ion adsorption on 2D vd W HTSs and providing new insights into material design for alkali atom adsorption.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.52074315 and 52122401)Moreover,the authors also thank the financial support from China Scholarship Council(Grant No.202306440033).
文摘The diversity of interlayers in shale oil reservoir leads to a low degree of vertical reconstruction.This paper aims to propose a method to guide the synchronous initiation of hydraulic fractures in different layers by drilling multi-layer radial wells in spatial positions,and to form a fracture network that satisfies the vertical propagation range and complexity.In this paper,a 3D(three-dimensional)multi-layer radial well fracturing model considering fluid-mechanics coupling is established and the properties of shale oil reservoir are characterized according to the field geological profile.The influences of radial well spacing,fracturing fluid injection rate,and fracturing fluid viscosity on vertical fracture communication in multilayer radial wells are investigated.The results show that the radial well has the characteristics of guiding fracture penetrating interlayers.Reducing radial well spacing and appropriately increasing injection rate and viscosity are beneficial to improving vertical fracture propagation ability.However,high fracture fluid viscosity under the same displacement will lead to a significant increase in fracture aperture and weaken the total fracture area.In addition,if the stress interference around the radial wells is low,the radial well can be located in the middle of each layer to minimize the fracture height limitation.This study can provide a solution idea for vertical propagation limitation of hydraulic fractures in shale oil reservoir.
基金support for this work is received from the National Natural Science Foundation of China(Grant No.U22B20144).
文摘The potential of the vertical-horizontal well hybrid SAGD technique for developing shallow heavy oil reservoirs is gradually being realized.However,challenges remain in terms of low thermal efficiency and high carbon emissions in reservoirs with interlayers.Currently,there is limited research on the low-carbon strategy of coupling exhaust gas from steam boilers with the VH-SAGD technique.Herein,considering heterogeneity,a series of flue gas-assisted VH-SAGD experiments were conducted employing a high-performance 2D visualization model.The mechanism of enhanced recovery of flue gas in VH-SAGD and the effect of its injection methods were studied,with a focus on steam chamber development and oil saturation distribution.Crucially,the interlayer length was optimized to enhance oil recovery,providing a new perspective for well location design in heavy oil reservoirs with interlayers.The results showed that flue gas,as an additive,could fully exploit the well-type advantage of VH-SAGD.By supplementing energy at the reservoir top,flue gas effectively promoted steam chamber development,expanded the oil drainage area of VH-SAGD,and increased the oil recovery from 58.9%to 71.7%.The flow channels formed by pre-injection flue gas accelerated the early-stage expansion of the steam chamber while also inducing lateral migration of steam,slowing steam rise,and consequently increasing the heating range within the low-permeability layer.When the distance between the vertical and horizontal wells was set to twice the interlayer length,the negative effects of the interlayer were more effectively turned into advantages.Because when the lateral development distance of the steam chamber in the low-permeability layer slightly exceeds the interlayer,enhanced heating of the lower part of the reservoir occurred through vertical convection of rising steam and returning condensate.The research results contribute to reducing carbon emissions from steam-based heavy oil extraction while advancing the maturity of VH-SAGD.
基金Supported by the National Natural Science Foundation of China(Grant No.52172409)Postdoctoral Innovation Talents Support Program(Grant No.BX20240298)+1 种基金the Fundamental Research Funds for the Central Universities(Grant No.2682024GF023)Heilongjiang Province Postdoctoral Foundation Project(Grant No.LBH-Z23041).
文摘The huge impact kinetic energy cannot be quickly dissipated by the energy-absorbing structure and transferred to the other vehicle through the car body structure,which will cause structural damage and threaten the lives of the occupants.Therefore,it is necessary to understand the laws of energy conversion,dissipation and transfer during train collisions.This study proposes a multi-layer progressive analysis method of energy flow during train collisions,considering the characteristics of the train.In this method,the train collision system is divided into conversion,dissipation,and transfer layers from the perspective of the train,collision interface,and car body structure to analyze the energy conversion,dissipation and transfer characteristics.Taking the collision process of a rail train as an example,a train collision energy transfer path analysis model was established based on power flow theory.The results show that when the maximum mean acceleration of the vehicle meets the standard requirements,the jerk may exceed the allowable limit of the human body,and there is a risk of injury to the occupants of a secondary collision.The decay rate of the collision energy along the direction of train operation reaches 79%.As the collision progresses,the collision energy gradually converges in the structure with holes,and the structure deforms when the gathered energy is greater than the maximum energy the structure can withstand.The proposed method helps to understand the train collision energy flow law and provides theoretical support for the train crashworthiness design in the future.
基金Nourah bint Abdulrahman University for funding this project through the Researchers Supporting Project(PNURSP2025R319)Riyadh,Saudi Arabia and Prince Sultan University for covering the article processing charges(APC)associated with this publication.Special acknowledgement to Automated Systems&Soft Computing Lab(ASSCL),Prince Sultan University,Riyadh,Saudi Arabia.
文摘The growing incidence of cyberattacks necessitates a robust and effective Intrusion Detection Systems(IDS)for enhanced network security.While conventional IDSs can be unsuitable for detecting different and emerging attacks,there is a demand for better techniques to improve detection reliability.This study introduces a new method,the Deep Adaptive Multi-Layer Attention Network(DAMLAN),to boost the result of intrusion detection on network data.Due to its multi-scale attention mechanisms and graph features,DAMLAN aims to address both known and unknown intrusions.The real-world NSL-KDD dataset,a popular choice among IDS researchers,is used to assess the proposed model.There are 67,343 normal samples and 58,630 intrusion attacks in the training set,12,833 normal samples,and 9711 intrusion attacks in the test set.Thus,the proposed DAMLAN method is more effective than the standard models due to the consideration of patterns by the attention layers.The experimental performance of the proposed model demonstrates that it achieves 99.26%training accuracy and 90.68%testing accuracy,with precision reaching 98.54%on the training set and 96.64%on the testing set.The recall and F1 scores again support the model with training set values of 99.90%and 99.21%and testing set values of 86.65%and 91.37%.These results provide a strong basis for the claims made regarding the model’s potential to identify intrusion attacks and affirm its relatively strong overall performance,irrespective of type.Future work would employ more attempts to extend the scalability and applicability of DAMLAN for real-time use in intrusion detection systems.
