As the second most important solid waste produced by coal-fired power plants,the improper management of coal-fired slag has the potential to result in environmental pollution.It is therefore imperative that high-value...As the second most important solid waste produced by coal-fired power plants,the improper management of coal-fired slag has the potential to result in environmental pollution.It is therefore imperative that high-value utilization pathways for coal-fired slag should be developed.In this study,modified magnesium slag(MMS),produced by a magnesium smelter,was selected as the alkali activator.The activated silica-aluminum solid wastes,namely coal-fired slag(CFS)and mineral powder(MP),were employed as pozzolanic materials in the preparation of alkali-activated cementitious materials.The alkali-activated cementitious materials prepared with 50 wt%MMS,40 wt%CFS and 10 wt%MP exhibited favorable mechanical properties,with a compressive strength of 32.804 MPa in the paste sample cured for 28 d.Then,the activated silica-aluminum solid waste consisting of CFS-MP generated a significant amount of C-S(A)-H gels,AFt,and other products,which were observed to occupy the pore structure of the specimen.In addition,the secondary hydration reaction of CFS-MP occurs in high alkalinity environments,resulting in the formation of a mutually stimulated and promoted reaction system between CFS-MP and MMS,this will subsequently accelerate the hydrolysis reaction of MMS.It is important to emphasize that the amount of MMS in alkali-activated cementitious materials must be strictly regulated to avert the potential issue of incomplete depolymerization-repolymerization of active silica-aluminum solid waste containing CFS-MP.This in turn could have a deleterious impact on the late strength of the cementitious materials.The aim of this work is to improve the joint disposal of MMS,CFS and MP and thereby provide a scientific basis for the development of environmentally friendly and low-carbon modified magnesium slag alkali-activated coal-fired slag based cementitious materials for mine backfilling.展开更多
[Objective] The aim was to reduce fertilizer and water losses caused by surface runoffs in rainy season and provide scientific references for soil moisture in arid season. [Method] The application proportion of comple...[Objective] The aim was to reduce fertilizer and water losses caused by surface runoffs in rainy season and provide scientific references for soil moisture in arid season. [Method] The application proportion of complex water-holding organic materials was determined by multi-factor mixture experiment and the curve changes of soil moisture characters were tested to analyze water-holding capacity and water availability of soils. [Result] The initial moisture content of soil with different mixture proportions improved in varying degrees. For example, when water-retention agents reached 0.4% and 0.6% of soil weight, soil moisture contents were 69.0% and70.5%, respectively, which showed significant differences with the control（S0.0）. Soil dehydration terms in different treatments all extended, prolonging in the range of4.6-14 d. [Conclusion] The applications of water-retention agent and organic material would improve water-holding capacity of hills and low mountains, and initial moisture content and dehydration cycle tend to be volatile upon mixture proportion. Therefore,it is necessary to adjust soil fertility, crop species, and irrigation to meet crop demands on fertilizer and water.展开更多
Labile organic carbon （LC） and recalcitrant organic carbon （RC） are two major fractions of soil organic carbon （SOC） and play a critical role in organic carbon turnover and sequestration. The aims of this study ...Labile organic carbon （LC） and recalcitrant organic carbon （RC） are two major fractions of soil organic carbon （SOC） and play a critical role in organic carbon turnover and sequestration. The aims of this study were to evaluate the variations of LC and RC in a semi-arid soil （Inner Mongolia, China） under plastic mulch and drip irrigation after the application of organic materials （OMs）, and to explore the effects of OMs from various sources on LC and RC by probing the decomposition characteristics of OMs using in-situ nylon mesh bags burying method. The field experiment included seven treatments, i.e., chicken manure （CM）, sheep manure （SM）, mushroom residue （MR）, maize straw （MS）, fodder grass （FG）, tree leaves （TL） and no OMs as a control （CK）. Soil LC and RC were separated by Huygens D＇s method （particle size-density）, and the average soil mass recovery rate and carbon recovery rate were above 95%, which indicated this method was suitable for carbon pools size analysis. The LC and RC contents significantly （P〈0.01） increased after the application of OMs. Moreover, LC and RC contents were 3.2%-8.6% and 5.0%-9.4% higher in 2016 than in 2015. The applications of CM and SM significantly increased （P〈0,01） LC content and LC/SOC ratio, whereas they were the lowest after the application of TL. However, SOC and RC contents were significantly higher （P〈0.01） after the applications of TL and MS. The correlation analysis indicated the decomposition rate of OMs was positively related with LC content and LC/SOC ratio. In addition, lignin, polyphenol, WOM （total water-soluble organic matter）, WHA （water-soluble humic acid）, HSL （humicdike substance） and HAL （humic acid-like） contents in initial OMs played important roles in SOC and RC. In-situ nylon mesh bags burying experiment indicated the decomposition rates of CM, SM and MS were significantly higher than those of MR, FG, and TL. Furthermore, MS could result in more lignin derivatives, WHA, and HAL polymers in shorter time during the decomposition process. In conclusion, the application of MS in the semi-arid soil under a long-term plastic mulch and drip irrigation condition could not only improve soil fertility, but also enhance soil carbon sequestration.展开更多
The non-isothermal leaching kinetics of primary titanium-rich material by microwave heating was investigated,and the temperature-pressure curves of leaching system and microwave absorption characteristics of mixture s...The non-isothermal leaching kinetics of primary titanium-rich material by microwave heating was investigated,and the temperature-pressure curves of leaching system and microwave absorption characteristics of mixture solutions before and after leaching were measured.The research of non-isothermal kinetics was evaluated by the leaching rate of Fe and the total apparent velocity equation of the non-isothermal kinetics of leaching for primary titanium-rich material by microwave heating was obtained.It is shown from the temperature-pressure curves that the high temperature and high pressure of closed leaching system are favorable to the enhancement of the leaching rate of Fe.Microwave absorption characteristics of mixture solutions before and after leaching show that there are abrupt changes of microwave absorption characteristics for 15%HCl solution and the mixture solution after leaching by 20%HCl.展开更多
Cerium-aluminum(CeAl)alloy is promising reactive structural materials(RSMs)with significant potential for liner applications.To investigate the thermochemical characteristics of CeAl alloy and the perforation behavior...Cerium-aluminum(CeAl)alloy is promising reactive structural materials(RSMs)with significant potential for liner applications.To investigate the thermochemical characteristics of CeAl alloy and the perforation behavior of its liner impacting steel targets,a CeAl alloy liner with 5 wt%Al content was fabricated,with a cerium(Ce)liner and a copper(Cu)liner used as control.The microstructure and elemental distribution of the CeAl alloy were analyzed using SEM,EDS,and XRD.The thermochemical reaction mechanism of the CeAl alloy was examined through TG-DSC.Penetration experiments were conducted to explore the combined effects of invasion and implosion of CeAl alloy liner against steel target.The results indicate that the addition of Al leads to the formation of Ce_(3)Al intermetallic compounds in the alloy and reduces the apparent activation energy of the Ce-based alloy by around 53.17%,thereby facilitating energy release.The presence of 5 wt%Al increases the calorific value by approximately 24.5%,and this change allows the oxidation process to be divided into three distinct stages.Compared to an inert copper liner,the average penetration diameter of the CeAl_(5) reactive alloy liner increases by around 42.78%.Furthermore,when compared to the Ce liner,the penetration depth of the CeAl_(5) reactive alloy liner increases by approximately 82.64%.展开更多
This article investigates the characteristics of shock wave overpressure generated by multi-layer composite charge under different detonation modes.Combining dimensional analysis and the explosion mechanism of the cha...This article investigates the characteristics of shock wave overpressure generated by multi-layer composite charge under different detonation modes.Combining dimensional analysis and the explosion mechanism of the charge,a peak overpressure prediction model for the composite charge under singlepoint detonation and simultaneous detonation was established.The effects of the charge structure and initiation method on the overpressure field characteristics were investigated in AUTODYN simulation.The accuracy of the prediction model and the reliability of the numerical simulation method were subsequently verified in a series of static explosion experiments.The results reveal that the mass of the inner charge was the key factor determining the peak overpressure of the composite charge under single-point detonation.The peak overpressure in the radial direction improved apparently with an increase in the aspect ratio of the charge.The overpressure curves in the axial direction exhibited a multi-peak phenomenon,and the secondary peak overpressure even exceeded the primary peak at distances of 30D and 40D(where D is the charge diameter).The difference in peak overpressure among azimuth angles of 0-90°gradually decreased with an increase in the propagation distance of the shock wave.The coupled effect of the detonation energy of the inner and outer charge under simultaneous detonation improved the overpressure in both radial and axial directions.The difference in peak overpressure obtained from model prediction and experimental measurements was less than 16.4%.展开更多
Cholesteric liquid crystals（CLCs） have recently sparked an enormous amount of interest in the development of soft matter materials due to their unique ability to self-organize into a helical supra-molecular architec...Cholesteric liquid crystals（CLCs） have recently sparked an enormous amount of interest in the development of soft matter materials due to their unique ability to self-organize into a helical supra-molecular architecture and their excellent selective reflection of light based on the Bragg relationship.Nowadays,by the virtue of building the self-organized nanostructures with pitch gradient or non-uniform pitch distribution,extensive work has already been performed to obtain CLC films with a broad reflection band.Based on authors＇ many years＇ research experience,this critical review systematically summarizes the physical and optical background of the CLCs with broadband reflection characteristics,methods to obtain broadband reflection of CLCs,as well as the application in the field of intelligent optical modulation materials.Combined with the research status and the advantages in the field,the important basic and applied scientific problems in the research direction are also introduced.展开更多
One objective of developing machine learning(ML)-based material models is to integrate them with well-established numerical methods to solve boundary value problems(BVPs).In the family of ML models,recurrent neural ne...One objective of developing machine learning(ML)-based material models is to integrate them with well-established numerical methods to solve boundary value problems(BVPs).In the family of ML models,recurrent neural networks(RNNs)have been extensively applied to capture history-dependent constitutive responses of granular materials,but these multiple-step-based neural networks are neither sufficiently efficient nor aligned with the standard finite element method(FEM).Single-step-based neural networks like the multi-layer perceptron(MLP)are an alternative to bypass the above issues but have to introduce some internal variables to encode complex loading histories.In this work,one novel Frobenius norm-based internal variable,together with the Fourier layer and residual architectureenhanced MLP model,is crafted to replicate the history-dependent constitutive features of representative volume element(RVE)for granular materials.The obtained ML models are then seamlessly embedded into the FEM to solve the BVP of a biaxial compression case and a rigid strip footing case.The obtained solutions are comparable to results from the FEM-DEM multiscale modelling but achieve significantly improved efficiency.The results demonstrate the applicability of the proposed internal variable in enabling MLP to capture highly nonlinear constitutive responses of granular materials.展开更多
Cotton fabrics treated with phase change materials( PCMs)were used in multi-layered fabrics of the fire fighter protective clothing to study its effect on thermal protection. The thermal protective performance( TPP) o...Cotton fabrics treated with phase change materials( PCMs)were used in multi-layered fabrics of the fire fighter protective clothing to study its effect on thermal protection. The thermal protective performance( TPP) of the multi-layered fabrics was measured by a TPP tester under flash fire. Results showed that the utilization of the PCM fabrics improved the thermal protective performance of the multi-layered fabrics. The fabric with a PCM add on of 41. 9% increased the thermal protection by 50. 6% and reduced the time to reach a second degree burn by 8. 4 s compared with the reference fabrics( without PCMs). The employment of the PCM fabrics also reduced the blackened areas on the inner layers. The PCM fabrics with higher PCM melting temperature could bring higher thermal protective performance.展开更多
In order to investigate detonation propagation characteristics of different charge patterns,the detonation velocities of superposition strip shaped charges made up of a detonating cord and explosives were measured by...In order to investigate detonation propagation characteristics of different charge patterns,the detonation velocities of superposition strip shaped charges made up of a detonating cord and explosives were measured by a detonation velocity measuring instrument under conditions of different ignition.The experimental results and theoretical analysis show that the maximum detonation propagation velocity depends on the explosive materials with the maximum velocity among all the explosive materials.Using detonating cord in a superposition charge can shorten detonation propagation time and improve the efficiency of explosive energy.The measurement method of detonation propagation velocity and experimental results are presented and investigated.展开更多
In the present study, physico-chemical investigations have been carried out on the possibility of using Cameroonian volcanic or clay pozzolans as raw material for geopolymer or pozzolanic binder. The research had made...In the present study, physico-chemical investigations have been carried out on the possibility of using Cameroonian volcanic or clay pozzolans as raw material for geopolymer or pozzolanic binder. The research had made some suggestive results and conclusions. Powders of less than 100 μm of five sampled pozzolans from volcanic or clay origins have been subjected to chemical and mineralogical analysis, BET specific surface, absolute density, granulometry and pozzolanic activity in solution tests. The results obtained showed that, geopolymers or pozzolanic binders can be produced from samples studied. The samples contain significant amounts of glassy or amorphous phase ready to dissolve in an alkaline solution. The high alkali content of volcanic pozzolans makes them more appropriate for geopolymer application. Clay pozzolans are the easier to grind in order to obtain the appropriate fineness and can be used for both geo- polymers and pozzolanic binders.展开更多
Quantitative relationship between nanosecond pulsed laser parameters and the characteristics of laser-generated ultrasonic waves in polycrystalline materials was evaluated.The high energy of the pulsed laser with a la...Quantitative relationship between nanosecond pulsed laser parameters and the characteristics of laser-generated ultrasonic waves in polycrystalline materials was evaluated.The high energy of the pulsed laser with a large irradiation spot simultaneously generated ultrasonic longitudinal and shear waves at the epicenter under the slight ablation regime.An optimized denoising technique based on wavelet thresholding and variational mode decomposition was applied to reduce noise in shear waves with a low signal-to-noise ratio.An approach for characterizing grain size was proposed using spectral central frequency ratio(SCFR)based on time-frequency analysis.The results demonstrate that the generation regime of ultrasonic waves is not solely determined by the laser power density;even at high power densities,a high energy with a large spot can generate an ultrasonic waveform dominated by the thermoelastic effect.This is ascribed to the intensification of the thermoelastic effect with the proportional increase in laser irradiation spot area for a given laser power density.Furthermore,both longitudinal and shear wave SCFRs are linearly related to grain size in polycrystalline materials;however,the shear wave SCFR is more sensitive to finer-grained materials.This study holds great significance for evaluating metal material properties using laser ultrasound.展开更多
In a gas governor unit, gas pressure vibration often occurs in the tube that connects the diaphragm chamber of the pilot valve to the downstream pipeline. Generally, placing a restriction such as an orifice in the tub...In a gas governor unit, gas pressure vibration often occurs in the tube that connects the diaphragm chamber of the pilot valve to the downstream pipeline. Generally, placing a restriction such as an orifice in the tube can curb the vibration. However, because of the nonlinear flow rate characteristics of an orifice, the gain of the pressure response changes with changing amplitude of the pressure vibration. This paper proposes a method that employs porous materials for improving the characteristics of the gas pressure control system on account of their linear flow rate characteristics. A static flow rate characteristics experiment was performed and the linear flow rate characteristics of the porous materials were confirmed. Then, a series of dynamic pressure response experiments, in which an isothermal chamber replaced the diaphragm chamber, were performed to examine the dynamic characteristics of the porous materials and an orifice. The experimental results revealed that the gain of the pressure response in the isothermal chamber with the porous materials remained unchanged irrespective of changes in the pressure vibration amplitude, and they were in close agreement with the simulation results. They also indicated that the pressure gain of porous materials is smaller than that of an orifice when the amplitude of pressure vibration is small. These results demonstrate that porous materials can be employed instead of an orifice in the gas governor unit in order to improve the unit’s stability.展开更多
As a byproduct of water treatment,drinking water treatment aluminum sludge(DWTAS)has challenges related to imperfect treatment and disposal,which has caused potential harm to human health and the environment.In this p...As a byproduct of water treatment,drinking water treatment aluminum sludge(DWTAS)has challenges related to imperfect treatment and disposal,which has caused potential harm to human health and the environment.In this paper,heat treatment DWTAS as a supplement cementitious material was used to prepare a green cementing material.The results show that the 800℃ is considered as the optimum heat treatment temperature for DWTAS.DWTAS-800℃ is fully activated after thermal decomposition to form incompletely crystallized highly activeγ-Al_(2)O_(3) and active SiO_(2).The addition of DWTAS promoted the formation of ettringite and C-(A)-S-H gel,which could make up for the low early compressive strength of cementing materials to a certain extent.When cured for 90 days,the compressive strength of the mortar with 30% DWTAS-800℃ reached 44.86 MPa.The dynamic process was well simulated by Krstulovi′c-Dabi′c hydration kinetics model.This study provided a methodology for the fabrication of environmentally friendly and cost-effective compound cementitiousmaterials and proposed a“waste-to-resource”strategy for the sustainable management of typical solid wastes.展开更多
1 Introduction The Tudimiaogou-Yindongshan lead-zinc polymetallic orefield is located in the Tudimiaogou-Weimoshi lead and zinc silver polymetallic metallogenic belt.The belt is an important part of southwestern Henan...1 Introduction The Tudimiaogou-Yindongshan lead-zinc polymetallic orefield is located in the Tudimiaogou-Weimoshi lead and zinc silver polymetallic metallogenic belt.The belt is an important part of southwestern Henan lead and zinc展开更多
"Golden triangle"area bordered on Yunnan-Guizhou-Guangxi was one of the most important Carlin-type gold deposits concentration areas.Deep understanding of Carlin-type gold deposits in Guizhou and Guangxi Pro..."Golden triangle"area bordered on Yunnan-Guizhou-Guangxi was one of the most important Carlin-type gold deposits concentration areas.Deep understanding of Carlin-type gold deposits in Guizhou and Guangxi Province had reached through several decades studies,but geological environment was very complex in the southeastern Yunnan,and Carlin-type gold deposits produced in the southeastern Yunnan were different from that of America,few studies were taken there.Based on a large number of field work,studies on the geological characteristics combining with geochemistry characteristics were taken,and analysis the genesis of Laozhaiwan gold deposit.The types of alteration in Laozhaiwan gold deposit were mainly silicification and pyritization,and Gold grade was high when silicification and pyritization were both occurred.It could be caculated that fluid density(g/cm3)varied from 0.7 to 4.9,salinity varied from 0.76%to 0.95%and ore-forming pressure(Pa)varied from 1.81×105 to 49.96×105 according to fluid inclusion test results,showed that Laozhaiwan gold deposit was hypabyssal hydrothermal deposit in low temperature and low salinity.According to composition of fluid inclusion analysis,combining with H-O isotope,made theδD-δ18O figure,showed that the fluid of the deposit rooted in formation water and mixed with meteoric waters later.展开更多
The Sichuan Basin represents the earliest area where natural gas is explored,developed and comprehensively utilized in China.After over 50 years of oil and gas exploration,oil and gas reservoirs have been discovered i...The Sichuan Basin represents the earliest area where natural gas is explored,developed and comprehensively utilized in China.After over 50 years of oil and gas exploration,oil and gas reservoirs have been discovered in 24 gas-dominant layers in this basin.For the purpose of predicting natural gas exploration direction and target of each layer in the Sichuan Basin,the sedimentary characteristics of marine and continental strata in this basin were summarized and the forms of multi-cycled tectonic movement and their controlling effect on sedimentation,diagenesis and hydrocarbon accumulation were analyzed.Based on the analysis,the following characteristics were identified.First,the Sichuan Basin has experienced the transformation from marine sedimentation to continental sedimentation since the Sinian with the former being dominant.Second,multiple sourceereservoir assemblages are formed based on multi-rhythmed deposition,and multi-layered reservoir hydrocarbon accumulation characteristics are vertically presented.And third,multi-cycled tectonic movement appears in many forms and has a significant controlling effect on sedimentation,diagenesis and hydrocarbon accumulation.Then,oil and gas reservoir characteristics and enrichment laws were investigated.It is indicated that the Sichuan Basin is characterized by coexistence of conventional and unconventional oil and gas reservoirs,multi-layered reservoir hydrocarbon supply,multiple reservoir types,multiple trap types,multi-staged hydrocarbon accumulation and multiple hydrocarbon accumulation models.Besides,its natural gas enrichment is affected by hydrocarbon source intensity,large paleo-uplift,favorable sedimentary facies belt,sedimentaryestructural discontinuity plane and structural fracture development.Finally,the natural gas exploration and research targets of each layer in the Sichuan Basin were predicted according to the basic petroleum geologic conditions,enrichment laws and exploration status.展开更多
The growing trend,which includes extensive application of herbal materials and consumers’constantly increasing expectation for the use of natural ingredients,brings both opportunities and challenges to the applicatio...The growing trend,which includes extensive application of herbal materials and consumers’constantly increasing expectation for the use of natural ingredients,brings both opportunities and challenges to the application of herbal materials in cosmetic products.In this paper,the development and innovation of Chinese characteristic plant materials in cosmetics are discussed by referring to the relevant study done in inoherb,a Chinese skincare company.This paper also presents the key factors for the development of Chinese characteristic herbal materials.The paper points out that quality standard is the embodiment of the quality of natural raw materials,effectiveness is the goal of raw material development and the introduction of new technology is the source of raw material innovation.Additionally,this paper suggests that"prescription",a concept in Traditional Chinese Medicine,could be introduced into the study of herbal materials in cosmetics.In our study,prescriptions are put into 4 categories:classic prescription,empirical prescription,composition prescription and efficacious prescription.This idea creates a new direction for the future development of herbal cosmetic products.展开更多
In deep underground engineering,rock burst and other dynamic disasters are prone to occur due to stress concentration and energy accumulation in surrounding rock.The control of dynamic disasters requires bolts and cab...In deep underground engineering,rock burst and other dynamic disasters are prone to occur due to stress concentration and energy accumulation in surrounding rock.The control of dynamic disasters requires bolts and cables with high strength,high elongation,and high energy-absorbing capacity.Therefore,a constant resistance energy-absorbing(CREA)material is developed.In this study,the dynamic characteristics of the new material are obtained via the drop hammer tests and the Split Hopkinson Pressure Bar(SHPB)tests of the new material and two common bolt(CB)materials widely used in the field.The test results of drop hammer test and SHPB test show that the percentage elongation of CREA material is more than 2.64 and 3.22 times those of the CB material,and the total impact energy acting on CREA material is more than 18.50 and 21.84 times,respectively,indicating that the new material has high elongation and high energy-absorbing capacity.Subsequently,the CREA bolts and cables using the new material are developed,which are applied in roadways with high stress and strong dynamic disturbance.The field monitoring results show that CREA bolts and cables can effectively control the surrounding rock deformation and ensure engineering safety.展开更多
Reactive Materials(RMs),a new material with structural and energy release characteristics under shockinduced chemical reactions,are promising in extensive applications in national defense and military fields.They can ...Reactive Materials(RMs),a new material with structural and energy release characteristics under shockinduced chemical reactions,are promising in extensive applications in national defense and military fields.They can increase the lethality of warheads due to their dual functionality.This paper focuses on the energy release characteristics of RM casings prepared by alloy melting and casting process under explosive loading.Explosion experiments of RM and conventional 2A12 aluminum alloy casings were conducted in free field to capture the explosive fireballs,temperature distribution,peak overpressure of the air shock wave and the fracture morphology of fragments of reactive material(RM)warhead casings by using high-speed camera,infrared thermal imager temperature and peak overpressure testing and scanning electron microscope.Results showed that an increase of both the fireball temperature and air shock wave were observed in all RM casings compared to conventional 2A12 aluminum ally casings.The RM casings can improve the peak overpressure of the air shock wave under explosion loading,though the results are different with different charge ratios.According to the energy release characteristics of the RM,increasing the thickness of RM casings will increase the peak overpressure of the near-field air shock wave,while reducing the thickness will increase the peak overpressure of the far-field air shock wave.展开更多
基金Projects(52222404,52074212)supported by the National Natural Science Foundation of ChinaProject(2023-LL-QY-07)supported by the Two-chain Integration Key Projects in Shaanxi Province,China。
文摘As the second most important solid waste produced by coal-fired power plants,the improper management of coal-fired slag has the potential to result in environmental pollution.It is therefore imperative that high-value utilization pathways for coal-fired slag should be developed.In this study,modified magnesium slag(MMS),produced by a magnesium smelter,was selected as the alkali activator.The activated silica-aluminum solid wastes,namely coal-fired slag(CFS)and mineral powder(MP),were employed as pozzolanic materials in the preparation of alkali-activated cementitious materials.The alkali-activated cementitious materials prepared with 50 wt%MMS,40 wt%CFS and 10 wt%MP exhibited favorable mechanical properties,with a compressive strength of 32.804 MPa in the paste sample cured for 28 d.Then,the activated silica-aluminum solid waste consisting of CFS-MP generated a significant amount of C-S(A)-H gels,AFt,and other products,which were observed to occupy the pore structure of the specimen.In addition,the secondary hydration reaction of CFS-MP occurs in high alkalinity environments,resulting in the formation of a mutually stimulated and promoted reaction system between CFS-MP and MMS,this will subsequently accelerate the hydrolysis reaction of MMS.It is important to emphasize that the amount of MMS in alkali-activated cementitious materials must be strictly regulated to avert the potential issue of incomplete depolymerization-repolymerization of active silica-aluminum solid waste containing CFS-MP.This in turn could have a deleterious impact on the late strength of the cementitious materials.The aim of this work is to improve the joint disposal of MMS,CFS and MP and thereby provide a scientific basis for the development of environmentally friendly and low-carbon modified magnesium slag alkali-activated coal-fired slag based cementitious materials for mine backfilling.
基金Supported by Fund for Independent Innovation of Agricultural Sciences in Jiangsu Province(CX(14)2099)~~
文摘[Objective] The aim was to reduce fertilizer and water losses caused by surface runoffs in rainy season and provide scientific references for soil moisture in arid season. [Method] The application proportion of complex water-holding organic materials was determined by multi-factor mixture experiment and the curve changes of soil moisture characters were tested to analyze water-holding capacity and water availability of soils. [Result] The initial moisture content of soil with different mixture proportions improved in varying degrees. For example, when water-retention agents reached 0.4% and 0.6% of soil weight, soil moisture contents were 69.0% and70.5%, respectively, which showed significant differences with the control（S0.0）. Soil dehydration terms in different treatments all extended, prolonging in the range of4.6-14 d. [Conclusion] The applications of water-retention agent and organic material would improve water-holding capacity of hills and low mountains, and initial moisture content and dehydration cycle tend to be volatile upon mixture proportion. Therefore,it is necessary to adjust soil fertility, crop species, and irrigation to meet crop demands on fertilizer and water.
基金supported by the National Key R&D Program of China (2017YFD0201801)the Research Foundation of the Science & Technology Agency of Jilin Province, China (20150203004NY)
文摘Labile organic carbon （LC） and recalcitrant organic carbon （RC） are two major fractions of soil organic carbon （SOC） and play a critical role in organic carbon turnover and sequestration. The aims of this study were to evaluate the variations of LC and RC in a semi-arid soil （Inner Mongolia, China） under plastic mulch and drip irrigation after the application of organic materials （OMs）, and to explore the effects of OMs from various sources on LC and RC by probing the decomposition characteristics of OMs using in-situ nylon mesh bags burying method. The field experiment included seven treatments, i.e., chicken manure （CM）, sheep manure （SM）, mushroom residue （MR）, maize straw （MS）, fodder grass （FG）, tree leaves （TL） and no OMs as a control （CK）. Soil LC and RC were separated by Huygens D＇s method （particle size-density）, and the average soil mass recovery rate and carbon recovery rate were above 95%, which indicated this method was suitable for carbon pools size analysis. The LC and RC contents significantly （P〈0.01） increased after the application of OMs. Moreover, LC and RC contents were 3.2%-8.6% and 5.0%-9.4% higher in 2016 than in 2015. The applications of CM and SM significantly increased （P〈0,01） LC content and LC/SOC ratio, whereas they were the lowest after the application of TL. However, SOC and RC contents were significantly higher （P〈0.01） after the applications of TL and MS. The correlation analysis indicated the decomposition rate of OMs was positively related with LC content and LC/SOC ratio. In addition, lignin, polyphenol, WOM （total water-soluble organic matter）, WHA （water-soluble humic acid）, HSL （humicdike substance） and HAL （humic acid-like） contents in initial OMs played important roles in SOC and RC. In-situ nylon mesh bags burying experiment indicated the decomposition rates of CM, SM and MS were significantly higher than those of MR, FG, and TL. Furthermore, MS could result in more lignin derivatives, WHA, and HAL polymers in shorter time during the decomposition process. In conclusion, the application of MS in the semi-arid soil under a long-term plastic mulch and drip irrigation condition could not only improve soil fertility, but also enhance soil carbon sequestration.
基金Project(2007CB613606)supported by the National Basic Research Program of China
文摘The non-isothermal leaching kinetics of primary titanium-rich material by microwave heating was investigated,and the temperature-pressure curves of leaching system and microwave absorption characteristics of mixture solutions before and after leaching were measured.The research of non-isothermal kinetics was evaluated by the leaching rate of Fe and the total apparent velocity equation of the non-isothermal kinetics of leaching for primary titanium-rich material by microwave heating was obtained.It is shown from the temperature-pressure curves that the high temperature and high pressure of closed leaching system are favorable to the enhancement of the leaching rate of Fe.Microwave absorption characteristics of mixture solutions before and after leaching show that there are abrupt changes of microwave absorption characteristics for 15%HCl solution and the mixture solution after leaching by 20%HCl.
文摘Cerium-aluminum(CeAl)alloy is promising reactive structural materials(RSMs)with significant potential for liner applications.To investigate the thermochemical characteristics of CeAl alloy and the perforation behavior of its liner impacting steel targets,a CeAl alloy liner with 5 wt%Al content was fabricated,with a cerium(Ce)liner and a copper(Cu)liner used as control.The microstructure and elemental distribution of the CeAl alloy were analyzed using SEM,EDS,and XRD.The thermochemical reaction mechanism of the CeAl alloy was examined through TG-DSC.Penetration experiments were conducted to explore the combined effects of invasion and implosion of CeAl alloy liner against steel target.The results indicate that the addition of Al leads to the formation of Ce_(3)Al intermetallic compounds in the alloy and reduces the apparent activation energy of the Ce-based alloy by around 53.17%,thereby facilitating energy release.The presence of 5 wt%Al increases the calorific value by approximately 24.5%,and this change allows the oxidation process to be divided into three distinct stages.Compared to an inert copper liner,the average penetration diameter of the CeAl_(5) reactive alloy liner increases by around 42.78%.Furthermore,when compared to the Ce liner,the penetration depth of the CeAl_(5) reactive alloy liner increases by approximately 82.64%.
基金funded by the National Natural Science Foundation of China(Grant No.11972018,No.12002336)China Postdoctoral Science Foundation(Grant No.2021M701710)。
文摘This article investigates the characteristics of shock wave overpressure generated by multi-layer composite charge under different detonation modes.Combining dimensional analysis and the explosion mechanism of the charge,a peak overpressure prediction model for the composite charge under singlepoint detonation and simultaneous detonation was established.The effects of the charge structure and initiation method on the overpressure field characteristics were investigated in AUTODYN simulation.The accuracy of the prediction model and the reliability of the numerical simulation method were subsequently verified in a series of static explosion experiments.The results reveal that the mass of the inner charge was the key factor determining the peak overpressure of the composite charge under single-point detonation.The peak overpressure in the radial direction improved apparently with an increase in the aspect ratio of the charge.The overpressure curves in the axial direction exhibited a multi-peak phenomenon,and the secondary peak overpressure even exceeded the primary peak at distances of 30D and 40D(where D is the charge diameter).The difference in peak overpressure among azimuth angles of 0-90°gradually decreased with an increase in the propagation distance of the shock wave.The coupled effect of the detonation energy of the inner and outer charge under simultaneous detonation improved the overpressure in both radial and axial directions.The difference in peak overpressure obtained from model prediction and experimental measurements was less than 16.4%.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.51573006,51573003,51203003,51303008,51302006,51402006,51272026,and 51273022)the Major Project of Beijing Science and Technology Program,China(Grant Nos.Z151100003315023 and Z141100003814011)the Fok Ying Tung Education Foundation,China(Grant No.142009)
文摘Cholesteric liquid crystals（CLCs） have recently sparked an enormous amount of interest in the development of soft matter materials due to their unique ability to self-organize into a helical supra-molecular architecture and their excellent selective reflection of light based on the Bragg relationship.Nowadays,by the virtue of building the self-organized nanostructures with pitch gradient or non-uniform pitch distribution,extensive work has already been performed to obtain CLC films with a broad reflection band.Based on authors＇ many years＇ research experience,this critical review systematically summarizes the physical and optical background of the CLCs with broadband reflection characteristics,methods to obtain broadband reflection of CLCs,as well as the application in the field of intelligent optical modulation materials.Combined with the research status and the advantages in the field,the important basic and applied scientific problems in the research direction are also introduced.
基金supported by the National Natural Science Foundation of China(NSFC)(Grant No.12072217).
文摘One objective of developing machine learning(ML)-based material models is to integrate them with well-established numerical methods to solve boundary value problems(BVPs).In the family of ML models,recurrent neural networks(RNNs)have been extensively applied to capture history-dependent constitutive responses of granular materials,but these multiple-step-based neural networks are neither sufficiently efficient nor aligned with the standard finite element method(FEM).Single-step-based neural networks like the multi-layer perceptron(MLP)are an alternative to bypass the above issues but have to introduce some internal variables to encode complex loading histories.In this work,one novel Frobenius norm-based internal variable,together with the Fourier layer and residual architectureenhanced MLP model,is crafted to replicate the history-dependent constitutive features of representative volume element(RVE)for granular materials.The obtained ML models are then seamlessly embedded into the FEM to solve the BVP of a biaxial compression case and a rigid strip footing case.The obtained solutions are comparable to results from the FEM-DEM multiscale modelling but achieve significantly improved efficiency.The results demonstrate the applicability of the proposed internal variable in enabling MLP to capture highly nonlinear constitutive responses of granular materials.
基金Fundamental Research Funds for the Central Universities,China(No.14D110715/17/18)Start up Fund by Shanghai University of Engineering Science(No.2015-69)Young Teacher Training Program by Shanghai,China(No.ZZGCD15051))
文摘Cotton fabrics treated with phase change materials( PCMs)were used in multi-layered fabrics of the fire fighter protective clothing to study its effect on thermal protection. The thermal protective performance( TPP) of the multi-layered fabrics was measured by a TPP tester under flash fire. Results showed that the utilization of the PCM fabrics improved the thermal protective performance of the multi-layered fabrics. The fabric with a PCM add on of 41. 9% increased the thermal protection by 50. 6% and reduced the time to reach a second degree burn by 8. 4 s compared with the reference fabrics( without PCMs). The employment of the PCM fabrics also reduced the blackened areas on the inner layers. The PCM fabrics with higher PCM melting temperature could bring higher thermal protective performance.
文摘In order to investigate detonation propagation characteristics of different charge patterns,the detonation velocities of superposition strip shaped charges made up of a detonating cord and explosives were measured by a detonation velocity measuring instrument under conditions of different ignition.The experimental results and theoretical analysis show that the maximum detonation propagation velocity depends on the explosive materials with the maximum velocity among all the explosive materials.Using detonating cord in a superposition charge can shorten detonation propagation time and improve the efficiency of explosive energy.The measurement method of detonation propagation velocity and experimental results are presented and investigated.
文摘In the present study, physico-chemical investigations have been carried out on the possibility of using Cameroonian volcanic or clay pozzolans as raw material for geopolymer or pozzolanic binder. The research had made some suggestive results and conclusions. Powders of less than 100 μm of five sampled pozzolans from volcanic or clay origins have been subjected to chemical and mineralogical analysis, BET specific surface, absolute density, granulometry and pozzolanic activity in solution tests. The results obtained showed that, geopolymers or pozzolanic binders can be produced from samples studied. The samples contain significant amounts of glassy or amorphous phase ready to dissolve in an alkaline solution. The high alkali content of volcanic pozzolans makes them more appropriate for geopolymer application. Clay pozzolans are the easier to grind in order to obtain the appropriate fineness and can be used for both geo- polymers and pozzolanic binders.
基金supported in part by the Natural Science Foundation of Shandong Province,China (Grant No.ZR2023ME073)the National Natural Science Foundation of China (Grant No.51805304)+1 种基金the Education Department of Shandong Province,China (Grant No.2022KJ130)Qilu University of Technology (Shandong Academy of Sciences),China (Grant Nos.2023PY009,2021JC02008 and 2022GH005)。
文摘Quantitative relationship between nanosecond pulsed laser parameters and the characteristics of laser-generated ultrasonic waves in polycrystalline materials was evaluated.The high energy of the pulsed laser with a large irradiation spot simultaneously generated ultrasonic longitudinal and shear waves at the epicenter under the slight ablation regime.An optimized denoising technique based on wavelet thresholding and variational mode decomposition was applied to reduce noise in shear waves with a low signal-to-noise ratio.An approach for characterizing grain size was proposed using spectral central frequency ratio(SCFR)based on time-frequency analysis.The results demonstrate that the generation regime of ultrasonic waves is not solely determined by the laser power density;even at high power densities,a high energy with a large spot can generate an ultrasonic waveform dominated by the thermoelastic effect.This is ascribed to the intensification of the thermoelastic effect with the proportional increase in laser irradiation spot area for a given laser power density.Furthermore,both longitudinal and shear wave SCFRs are linearly related to grain size in polycrystalline materials;however,the shear wave SCFR is more sensitive to finer-grained materials.This study holds great significance for evaluating metal material properties using laser ultrasound.
文摘In a gas governor unit, gas pressure vibration often occurs in the tube that connects the diaphragm chamber of the pilot valve to the downstream pipeline. Generally, placing a restriction such as an orifice in the tube can curb the vibration. However, because of the nonlinear flow rate characteristics of an orifice, the gain of the pressure response changes with changing amplitude of the pressure vibration. This paper proposes a method that employs porous materials for improving the characteristics of the gas pressure control system on account of their linear flow rate characteristics. A static flow rate characteristics experiment was performed and the linear flow rate characteristics of the porous materials were confirmed. Then, a series of dynamic pressure response experiments, in which an isothermal chamber replaced the diaphragm chamber, were performed to examine the dynamic characteristics of the porous materials and an orifice. The experimental results revealed that the gain of the pressure response in the isothermal chamber with the porous materials remained unchanged irrespective of changes in the pressure vibration amplitude, and they were in close agreement with the simulation results. They also indicated that the pressure gain of porous materials is smaller than that of an orifice when the amplitude of pressure vibration is small. These results demonstrate that porous materials can be employed instead of an orifice in the gas governor unit in order to improve the unit’s stability.
基金This work is supported by the National Key Research and Development Program of China(No.2022YFC3203203)the Outstanding Youth Science Foundation of Shaanxi Province(No.2023-JC-JQ-36)the National Natural Science Foundation of China(No.52300121).
文摘As a byproduct of water treatment,drinking water treatment aluminum sludge(DWTAS)has challenges related to imperfect treatment and disposal,which has caused potential harm to human health and the environment.In this paper,heat treatment DWTAS as a supplement cementitious material was used to prepare a green cementing material.The results show that the 800℃ is considered as the optimum heat treatment temperature for DWTAS.DWTAS-800℃ is fully activated after thermal decomposition to form incompletely crystallized highly activeγ-Al_(2)O_(3) and active SiO_(2).The addition of DWTAS promoted the formation of ettringite and C-(A)-S-H gel,which could make up for the low early compressive strength of cementing materials to a certain extent.When cured for 90 days,the compressive strength of the mortar with 30% DWTAS-800℃ reached 44.86 MPa.The dynamic process was well simulated by Krstulovi′c-Dabi′c hydration kinetics model.This study provided a methodology for the fabrication of environmentally friendly and cost-effective compound cementitiousmaterials and proposed a“waste-to-resource”strategy for the sustainable management of typical solid wastes.
文摘1 Introduction The Tudimiaogou-Yindongshan lead-zinc polymetallic orefield is located in the Tudimiaogou-Weimoshi lead and zinc silver polymetallic metallogenic belt.The belt is an important part of southwestern Henan lead and zinc
基金financially supported by the Program of National Natural Science Foundation of China(No.41372093No.40930423+2 种基金No.41171302)the work item of China Geological Survey(No.12120113036200)higher education quality engineering project of chalcography excellent textbook Construction(No.XJC1105)
文摘"Golden triangle"area bordered on Yunnan-Guizhou-Guangxi was one of the most important Carlin-type gold deposits concentration areas.Deep understanding of Carlin-type gold deposits in Guizhou and Guangxi Province had reached through several decades studies,but geological environment was very complex in the southeastern Yunnan,and Carlin-type gold deposits produced in the southeastern Yunnan were different from that of America,few studies were taken there.Based on a large number of field work,studies on the geological characteristics combining with geochemistry characteristics were taken,and analysis the genesis of Laozhaiwan gold deposit.The types of alteration in Laozhaiwan gold deposit were mainly silicification and pyritization,and Gold grade was high when silicification and pyritization were both occurred.It could be caculated that fluid density(g/cm3)varied from 0.7 to 4.9,salinity varied from 0.76%to 0.95%and ore-forming pressure(Pa)varied from 1.81×105 to 49.96×105 according to fluid inclusion test results,showed that Laozhaiwan gold deposit was hypabyssal hydrothermal deposit in low temperature and low salinity.According to composition of fluid inclusion analysis,combining with H-O isotope,made theδD-δ18O figure,showed that the fluid of the deposit rooted in formation water and mixed with meteoric waters later.
文摘The Sichuan Basin represents the earliest area where natural gas is explored,developed and comprehensively utilized in China.After over 50 years of oil and gas exploration,oil and gas reservoirs have been discovered in 24 gas-dominant layers in this basin.For the purpose of predicting natural gas exploration direction and target of each layer in the Sichuan Basin,the sedimentary characteristics of marine and continental strata in this basin were summarized and the forms of multi-cycled tectonic movement and their controlling effect on sedimentation,diagenesis and hydrocarbon accumulation were analyzed.Based on the analysis,the following characteristics were identified.First,the Sichuan Basin has experienced the transformation from marine sedimentation to continental sedimentation since the Sinian with the former being dominant.Second,multiple sourceereservoir assemblages are formed based on multi-rhythmed deposition,and multi-layered reservoir hydrocarbon accumulation characteristics are vertically presented.And third,multi-cycled tectonic movement appears in many forms and has a significant controlling effect on sedimentation,diagenesis and hydrocarbon accumulation.Then,oil and gas reservoir characteristics and enrichment laws were investigated.It is indicated that the Sichuan Basin is characterized by coexistence of conventional and unconventional oil and gas reservoirs,multi-layered reservoir hydrocarbon supply,multiple reservoir types,multiple trap types,multi-staged hydrocarbon accumulation and multiple hydrocarbon accumulation models.Besides,its natural gas enrichment is affected by hydrocarbon source intensity,large paleo-uplift,favorable sedimentary facies belt,sedimentaryestructural discontinuity plane and structural fracture development.Finally,the natural gas exploration and research targets of each layer in the Sichuan Basin were predicted according to the basic petroleum geologic conditions,enrichment laws and exploration status.
文摘The growing trend,which includes extensive application of herbal materials and consumers’constantly increasing expectation for the use of natural ingredients,brings both opportunities and challenges to the application of herbal materials in cosmetic products.In this paper,the development and innovation of Chinese characteristic plant materials in cosmetics are discussed by referring to the relevant study done in inoherb,a Chinese skincare company.This paper also presents the key factors for the development of Chinese characteristic herbal materials.The paper points out that quality standard is the embodiment of the quality of natural raw materials,effectiveness is the goal of raw material development and the introduction of new technology is the source of raw material innovation.Additionally,this paper suggests that"prescription",a concept in Traditional Chinese Medicine,could be introduced into the study of herbal materials in cosmetics.In our study,prescriptions are put into 4 categories:classic prescription,empirical prescription,composition prescription and efficacious prescription.This idea creates a new direction for the future development of herbal cosmetic products.
基金This work was supported by the National Natural Science Foundation of China(Nos.41941018,52074164,and 42077267);the Natural Science Foundation of Shandong Province,China(Nos.2019SDZY04 and ZR2020JQ23)the Project of Shandong Province Higher Educational Youth Innovation Science and Technology Program,China(No.2019KJG013).
文摘In deep underground engineering,rock burst and other dynamic disasters are prone to occur due to stress concentration and energy accumulation in surrounding rock.The control of dynamic disasters requires bolts and cables with high strength,high elongation,and high energy-absorbing capacity.Therefore,a constant resistance energy-absorbing(CREA)material is developed.In this study,the dynamic characteristics of the new material are obtained via the drop hammer tests and the Split Hopkinson Pressure Bar(SHPB)tests of the new material and two common bolt(CB)materials widely used in the field.The test results of drop hammer test and SHPB test show that the percentage elongation of CREA material is more than 2.64 and 3.22 times those of the CB material,and the total impact energy acting on CREA material is more than 18.50 and 21.84 times,respectively,indicating that the new material has high elongation and high energy-absorbing capacity.Subsequently,the CREA bolts and cables using the new material are developed,which are applied in roadways with high stress and strong dynamic disturbance.The field monitoring results show that CREA bolts and cables can effectively control the surrounding rock deformation and ensure engineering safety.
基金the Fundamental Research Funds for the Central Universities(No.30920021108)Open Foundation of Hypervelocity Impact Research Center of CARDC(20200106).
文摘Reactive Materials(RMs),a new material with structural and energy release characteristics under shockinduced chemical reactions,are promising in extensive applications in national defense and military fields.They can increase the lethality of warheads due to their dual functionality.This paper focuses on the energy release characteristics of RM casings prepared by alloy melting and casting process under explosive loading.Explosion experiments of RM and conventional 2A12 aluminum alloy casings were conducted in free field to capture the explosive fireballs,temperature distribution,peak overpressure of the air shock wave and the fracture morphology of fragments of reactive material(RM)warhead casings by using high-speed camera,infrared thermal imager temperature and peak overpressure testing and scanning electron microscope.Results showed that an increase of both the fireball temperature and air shock wave were observed in all RM casings compared to conventional 2A12 aluminum ally casings.The RM casings can improve the peak overpressure of the air shock wave under explosion loading,though the results are different with different charge ratios.According to the energy release characteristics of the RM,increasing the thickness of RM casings will increase the peak overpressure of the near-field air shock wave,while reducing the thickness will increase the peak overpressure of the far-field air shock wave.
