Based on the rapid advancements in nanomaterials and nanotechnology,the Nanofluidic Reverse Electrodialysis(NRED)has attracted significant attention as an innovative and promising energy conversion strategy for extrac...Based on the rapid advancements in nanomaterials and nanotechnology,the Nanofluidic Reverse Electrodialysis(NRED)has attracted significant attention as an innovative and promising energy conversion strategy for extracting sustainable and clean energy fromthe salinity gradient energy.However,the scarcity of research investigating the intricate multi-factor coupling effects on the energy conversion performance,especially the trade-offs between ion selectivity and mass transfer in nanochannels,of NRED poses a great challenge to achieving breakthroughs in energy conversion processes.This numerical study innovatively investigates the multi-factor coupling effect of three critical operational factors,including the nanochannel configuration,the temperature field,and the concentration difference,on the energy conversion processes of NRED.In this work,a dimensionless amplitude parameter s is introduced to emulate the randomly varied wall configuration of nanochannels that inherently occur in practical applications,thereby enhancing the realism and applicability of our analysis.Numerical results reveal that the application of a temperature gradient,which is oriented in opposition to the concentration gradient,enhances the ion transportation and selectivity simultaneously,leading to an enhancement in both output power and energy conversion efficiency.Additionally,the increased fluctuation of the nanochannel wall from s=0 to s=0.08 improves ion selectivity yet raises ion transport resistance,resulting in an enhancement in output power and energy conversion efficiency but a slight reduction in current.Furthermore,with increasing the concentration ratio cH/cL from 10 to 1000,either within a fixed temperature field or at a constant dimensionless amplitude,the maximumpower consistently attains its optimal value at a concentration ratio of 100 but the cation transfer number experiences amonotonic decrease across this entire range of concentration ratios.Finally,uponmodifying the operational parameters fromthe baseline condition of s=0,c_(H)/c_(L)=10,andΔT=0 K to the targetedconditionof s=0.08,c_(H)/c_(L)=50,andΔT=25 K,there is a concerted improvement observed in the open-circuit potential,short-circuit current,andmaximumpower,with respective increments of 8.86%,204.97%,and 232.01%,but a reduction in cation transfer number with a notable decrease of 15.37%.展开更多
In order to accurately simulate the diffusion of chloride ion in the existing concrete bridge and acquire the precise chloride ion concentration at given time, a cellular automata （CA）-based model is proposed. The p...In order to accurately simulate the diffusion of chloride ion in the existing concrete bridge and acquire the precise chloride ion concentration at given time, a cellular automata （CA）-based model is proposed. The process of chloride ion diffusion is analyzed by the CA-based method and a nonlinear solution of the Fick＇s second law is obtained. Considering the impact of various factors such as stress states, temporal and spatial variability of diffusion parameters and water-cement ratio on the process of chloride ion diffusion, the model of chloride ion diffusion under multi-factor coupling actions is presented. A chloride ion penetrating experiment reported in the literature is used to prove the effectiveness and reasonability of the present method, and a T-type beam is taken as an illustrative example to analyze the process of chloride ion diffusion in practical application. The results indicate that CA-based method can simulate the diffusion of chloride ion in the concrete structures with acceptable precision.展开更多
Heavy-equipment airdrop is a highly risky procedure that has a complicated system due to the secluded and complex nature of factors＇ coupling. As a result, it is difficult to study the modeling and safety simulation ...Heavy-equipment airdrop is a highly risky procedure that has a complicated system due to the secluded and complex nature of factors＇ coupling. As a result, it is difficult to study the modeling and safety simulation of this system. The dynamic model of the heavy-equipment airdrop is based on the Lagrange analytical mechanics, which has all the degrees of freedom and can accurately pinpoint the real-time coordinates and attitude of the carrier with its cargo. Unfavorable conditions accounted in the factors＇ models, including aircraft malfunctions and adverse environments, are established from a man-machine-environment perspective. Subsequently, a virtual simulation system for the safety research of the multi-factor coupling heavy-equipment airdrop is developed through MATLAB/Simulink, C language and Flightgear software. To verify the veracity of the theory, the verification model is built based on dynamic software ADAMS. Finally, the emulation is put to the test with the input of realistic accident variables to ascertain its feasibility and validity of this method.展开更多
In order to solve the problem of strength instability of cemented tailings backfill(CTB)under low temperature environment(≤20℃),the strength optimization and prediction of CTB under the influence of multiple factors...In order to solve the problem of strength instability of cemented tailings backfill(CTB)under low temperature environment(≤20℃),the strength optimization and prediction of CTB under the influence of multiple factors were carried out.The response surface method(RSM)was used to design the experiment to analyze the development law of backfill strength under the coupling effect of curing temperature,sand-cement ratio and slurry mass fraction,and to optimize the mix proportion;the artificial neural network algorithm(ANN)and particle swarm optimization algorithm(PSO)were used to build the prediction model of backfill strength.According to the experimental results of RSM,the optimal mix proportion under different curing temperatures was obtained.When the curing temperature is 10-15℃,the best mix proportion of sand-cement ratio is 9,and the slurry mass fraction is 71%;when the curing temperature is 15-20℃,the best mix proportion of sand-cement ratio is 8,and the slurry mass fraction is 69%.The ANN-PSO intelligent model can accurately predict the strength of CTB,its mean relative estimation error value and correlation coefficient value are only 1.95%and 0.992,and the strength of CTB under different mix proportion can be predicted quickly and accurately by using this model.展开更多
Combined with the parameters of the production process of a steel factory, numerical simulations for a new ladle from preheating to turnover are conducted using the finite element analysis system software （ANSYS）. T...Combined with the parameters of the production process of a steel factory, numerical simulations for a new ladle from preheating to turnover are conducted using the finite element analysis system software （ANSYS）. The measured data proved that the simulated results are reliable. The effects of preheating time, thermal cycling times, and empty package time on steel temperature are calculated, an ideal preheating time is provided, besides, based on the analysis of a single factor and use the nonlinear analysis method, a steel temperature compensating model with di- versified coupling factors is proposed, with the largest error of the present coupling model at 1. 462 ~C, and the er- rors between actual and target steel temperature in tundish after the model is applied to practical production are basi- cally controlled within -4-6 ~C, which can meet the accuracy of the manufacturer and has a practical guiding significance for the production in steelmaking workshops.展开更多
The coupling reactions of methanol and long-chain alkanes(n-dodecane,n-tetradecane and n-hexadecane)over CHA-type molecular sieves were studied in a fixed bed reactor.Over SAPO-34 and SSZ-13,it was found that the indu...The coupling reactions of methanol and long-chain alkanes(n-dodecane,n-tetradecane and n-hexadecane)over CHA-type molecular sieves were studied in a fixed bed reactor.Over SAPO-34 and SSZ-13,it was found that the induction period of methanol conversion was shortened by the introduction of long-chain alkanes.However,the addition of long-chain alkanes had little influence on the product distribution.Polymethylbenzenes and the derivatives were the main retained species on spent SSZ-13 catalyst,while adamantanes were the main retained species on SAPO-34.This indicates that coking species formation was mainly related to the further transformation of long-chain alkane/methanol coupling products at acid sites of the molecular sieve.These findings provide valuable information of long chain alkanes conversion and methanol reaction behavior of induction period over small pore CHA molecular sieves.展开更多
Wire arc additive manufacturing(WAAM)has emerged as a promising approach for fabricating large-scale components.However,conventional WAAM still faces challenges in optimizing microstructural evolution,minimizing addit...Wire arc additive manufacturing(WAAM)has emerged as a promising approach for fabricating large-scale components.However,conventional WAAM still faces challenges in optimizing microstructural evolution,minimizing additive-induced defects,and alleviating residual stress and deformation,all of which are critical for enhancing the mechanical performance of the manufactured parts.Integrating interlayer friction stir processing(FSP)into WAAM significantly enhances the quality of deposited materials.However,numerical simulation research focusing on elucidating the associated thermomechanical coupling mechanisms remains insufficient.A comprehensive numerical model was developed to simulate the thermomechanical coupling behavior in friction stir-assisted WAAM.The influence of post-deposition FSP on the coupled thermomechanical response of the WAAM process was analyzed quantitatively.Moreover,the residual stress distribution and deformation behavior under both single-layer and multilayer deposition conditions were investigated.Thermal analysis of different deposition layers in WAAM and friction stir-assisted WAAM was conducted.Results show that subsequent layer deposition induces partial remelting of the previously solidified layer,whereas FSP does not cause such remelting.Furthermore,thermal stress and deformation analysis confirm that interlayer FSP effectively mitigates residual stresses and distortion in WAAM components,thereby improving their structural integrity and mechanical properties.展开更多
This study aims to promote the optimization and upgrading of the economic structure in rural areas of China by focusing on the coupling coordination mechanism between digital economy–agriculture integration and rural...This study aims to promote the optimization and upgrading of the economic structure in rural areas of China by focusing on the coupling coordination mechanism between digital economy–agriculture integration and rural revitalization.By examining panel data from 30 Chinese provinces,autonomous regions,and municipalities between 2011 and 2022,the research constructs a weight-based evaluation system that integrates subjective and objective methods and a coupling coordination model to reveal its dynamic evolution patterns.Key findings indicate that digital economy–agriculture integration and rural revitalization achieve cross-coupling through critical activities.The impact of digital-agriculture integration on advancing rural revitalization lags by 2–3 years.Although the coupling development degree between the two systems continues to improve,it remains at the stage of primary coordination.Regional disparities are significant,showing a gradient pattern of“high degree of coupling development in the east and low degree of coupling development in the west.”展开更多
Multilayer complex dynamical networks,characterized by the intricate topological connections and diverse hierarchical structures,present significant challenges in determining complete structural configurations due to ...Multilayer complex dynamical networks,characterized by the intricate topological connections and diverse hierarchical structures,present significant challenges in determining complete structural configurations due to the unique functional attributes and interaction patterns inherent to different layers.This paper addresses the critical question of whether structural information from a known layer can be used to reconstruct the unknown intralayer structure of a target layer within general weighted output-coupling multilayer networks.Building upon the generalized synchronization principle,we propose an innovative reconstruction method that incorporates two essential components in the design of structure observers,the cross-layer coupling modulator and the structural divergence term.A key advantage of the proposed reconstruction method lies in its flexibility to freely designate both the unknown target layer and the known reference layer from the general weighted output-coupling multilayer network.The reduced dependency on full-state observability enables more deployment in engineering applications with partial measurements.Numerical simulations are conducted to validate the effectiveness of the proposed structure reconstruction method.展开更多
The F_(1)-ATPase and V_(1)-ATPase are rotary biomotors.Alignment of their amino acid sequences,which originate from bovine heart mitochondria(1BMF)and Enterococcus hirae(3VR6),respectively,demonstrates that the segmen...The F_(1)-ATPase and V_(1)-ATPase are rotary biomotors.Alignment of their amino acid sequences,which originate from bovine heart mitochondria(1BMF)and Enterococcus hirae(3VR6),respectively,demonstrates that the segment forming the ATP catalytic pocket is highly conserved.Single-molecule experiments,however,have revealed subtle differences in efficiency between the F_(1) and V_(1) motors.Here,we perform both atomistic and coarse-grained molecular dynamics simulations to investigate the mechanochemical coupling and coordination in F_(1) and V_(1) ATPase.Our results show that the correlation between conformational changes in F_(1) is stronger than that in V_(1),indicating that the mechanochemical coupling in F_(1) is tighter than in V_(1).Moreover,the unidirectional rotation of F_(1) is more processive than that of V_(1),which accounts for the higher efficiency observed in F_(1) and explains the occasional backward steps detected in single-molecule experiments on V_(1).展开更多
The coupling effects among the flow field,temperature distribution and structural deformation in a turbine cannot be ignored,particularly during flight cycles when the turbine experiences varied operational states.Rel...The coupling effects among the flow field,temperature distribution and structural deformation in a turbine cannot be ignored,particularly during flight cycles when the turbine experiences varied operational states.Relying solely on steady-state solutions cannot predict the detrimental effects caused by hysteresis.Consequently,this paper employs a quasi-steady-state fluid-thermalstructure multidisciplinary coupling solution method,integrating transient solid heat conduction with steady-state flow field and static structural deformation solutions.After conducting a numerical simulation of a three-dimensional,five-stage,low-pressure turbine air system,the following conclusions are drawn:when boundary conditions attain high-power states through processes that are numerically identical but in opposite directions,slight variations in solid deformation significantly impact the flow field;when boundary conditions attain high-power states through processes that are directionally consistent but have different numerical values,the influence of the boundary condition change rate on the flow field surpasses that of solid deformation.In terms of turbine design parameters,a large difference in stage-reaction between adjacent stages at the lower radius of the turbine can lead to significant changes in the disc cavity flow field during flight cycles.The difference in the stage-reaction of 0.23 at 10%blade height in adjacent stages may induce severe gas ingress in the stator disc cavity.Thus,it is crucial to minimize this difference and to appropriately extend the duration of the deceleration phase to ensure the turbine's safe operation.展开更多
Based on the Smit-Suhl formula,we propose a universal approach for solving the magnon-magnon coupling problem in bilayer coupled systems(e.g.,antiferromagnets).This method requires only the energy expression,enabling ...Based on the Smit-Suhl formula,we propose a universal approach for solving the magnon-magnon coupling problem in bilayer coupled systems(e.g.,antiferromagnets).This method requires only the energy expression,enabling the automatic derivation of analytical expressions for the eigenmatrix elements via symbolic computation,eliminating the need for tedious manual calculations.Using this approach,we investigate the impact of magnetic hysteresis on magnon-magnon coupling in a system with interlayer Dzyaloshinskii-Moriya interaction(DMI).The magnetic hysteresis leads to an asymmetric magnetic field dependence of the resonance frequency and alters the number of degeneracy points between the pure optical and acoustic modes.Moreover,it can result in the coupling strength at the gap of the f–H phase diagram being nearly vanishing,contrary to the conventionally expected maximum.These results deepen the understanding of the effect of interlayer DMI on magnon–magnon coupling and the proposed universal method significantly streamlines the solving process of magnon–magnon coupling problems.展开更多
This study presents an implicit multiphysics coupling method integrating Computational Fluid Dynamics(CFD),the Multiphase Particle-in-Cell(MPPIC)model,and the Finite Element Method(FEM),implemented with OpenFOAM,Calcu...This study presents an implicit multiphysics coupling method integrating Computational Fluid Dynamics(CFD),the Multiphase Particle-in-Cell(MPPIC)model,and the Finite Element Method(FEM),implemented with OpenFOAM,CalculiX,and preCICE to simulate fluid-particle-structure interactions with large deformations.Mesh motion in the fluid field is handled using the radial basis function(RBF)method.The particle phase is modeled by MPPIC,where fluid-particle interaction is described through momentum exchange,and inter-particle collisions are characterized by collision stress.The structural field is solved by nonlinear FEM to capture large deformations induced by geometric nonlinearity.Coupling among fields is realized through a partitioned,parallel,and non-intrusive iterative strategy,ensuring stable transfer and convergence of interface forces and displacements.Notably,the influence of particles on the structure is not direct but mediated by the fluid,while structural motion directly affects particle dynamics.The results demonstrate that the proposed approach effectively captures multiphysics interaction processes and provides a valuable reference for numerical modeling of coupled fluid-particle-structure systems.展开更多
Hydraulic asphalt concrete(HAC)has been increasingly employed as an appropriate impervious structure in hydraulic and hydropower engineering.However,asphalt mortar,usually seen as the matrix of HAC composite,is partic...Hydraulic asphalt concrete(HAC)has been increasingly employed as an appropriate impervious structure in hydraulic and hydropower engineering.However,asphalt mortar,usually seen as the matrix of HAC composite,is particularly prone to damage under combined stress and seepage interactions,and the mesoscale investigations on the damage-seepage coupling behavior of HAC under complex stress states remain limited.This research develops a numerical three-dimensional mesoscale model composed of asphalt mortar and polyhedral aggregate to investigate the stress-damage-seepage coupling behavior in HAC.In this model,asphalt mortar yields the viscoelastic continuum damage law and aggregate obeys the Mazars’elastic-brittle damage law;simultaneously,the effective permeability coefficient of asphalt mortar is assumed to follow an exponential function of damage.The predicted deviatoric stress-strain and hydraulic gradient-seepage curves both are in good agreement with the reported experimental results,which shows the proposed model is valid and reasonable.The simulated results indicate that the damaged asphalt mortar can induce localized areas of high permeability,which in turn affects the overall impervious performance of HAC.展开更多
High rock temperature is a great challenge frequently encountered during subsurface resource recovery and deep underground space utilization,and it is still unclear how the granitic rock responds to realtime high temp...High rock temperature is a great challenge frequently encountered during subsurface resource recovery and deep underground space utilization,and it is still unclear how the granitic rock responds to realtime high temperature upon shear loading.To better understand the shear fracture behavior and underlying processes of intact granite exposed to thermal-mechanical coupling loading,direct shear tests were conducted utilizing a newly built testing apparatus at varied normal stresses and high temperatures.Influencesof different temperatures and different heating methods(real-time heating and thermal treatment)on the shear mechanical behavior were compared and discussed.Results indicate that shear stress fluctuationswith some small stress drops occur as shear stress is approaching the peak strength under real-time heating,accompanied by more and earlier AE signal uprushes.This suggests that greater cracking events occur earlier during real-time heating than after thermal treatment,resulting in a lower peak shear strength.Furthermore,the peak shear strength,post-peak stress drop,and cohesion rise from room temperature(RT)to 200℃(the peak strength increases by 8%,5.8%,and 9.9%under normal stress of 5 MPa,15 MPa,and 20 MPa,correspondingly),and subsequently decline from 200℃to 400℃.Temperature has a limited impact on shear stiffness from RT to 200℃,but significantlyreduces it from 200℃to 400℃,with drops of 15%,7.9%,and 10%under normal stress of 5 MPa,15 MPa,and 20 MPa,respectively.Moreover,the shear strength and stiffness under real-time heating are lower than those for the thermally treated specimens.The strengthening of intact granite below 200℃upon shear is associated with loss of water and a more compacted structure,while the weakening effect of temperature on shear strength from 200℃to 400℃is due to the new thermal cracks and less brittle and stiff of minerals.展开更多
To address the deficiencies in comprehensive surface contamination prevention strategies within China's nitrate-affected regions,this research innovatively proposes the DITAPH model-a systematic framework integrat...To address the deficiencies in comprehensive surface contamination prevention strategies within China's nitrate-affected regions,this research innovatively proposes the DITAPH model-a systematic framework integrating groundwater nitrate vulnerability assessment and Nitrate Vulnerable Zones(NVZs)delineation through optimization of hydrogeological parameters.Based on detailed hydrogeological and hydrochemical investigations,the DITAPH model was applied in the plain areas of Quanzhou to evaluate its applicability.The model selected hydrogeological parameters(depth of groundwater,lithology of the vadose zone,topographic slope,aquifer water yield property),one climatic parameter(precipitation),and two anthropogenic parameters(land use type and population density)as assessment indicators.The results of the groundwater nitrate vulnerability assessment showed that the low,relatively low,relatively high,and high groundwater nitrate vulnerability zones in the study area accounted for 5.96%,35.44%,53.74%and 4.86%of the total area,respectively.Groundwater nitrate vulnerability was most strongly influenced by human activities,followed by groundwater depth and topographic slope.The high vulnerability zone is mainly affected by domestic and industrial wastewater,whereas the relatively high groundwater nitrate vulnerability zone is primarily influenced by agricultural activities.Validation of the DITAPH model revealed a significant positive correlation between the DITAPH index(DI)and nitrate concentration(ρ(NO3−)).The results of the NVZs delineated by the DITAPH model are reliable and can serve as a tool for water resource management planning,guiding the development of targeted measures in the NVZs to prevent groundwater contamination.展开更多
Surface acoustic wave(SAW)resonators offer distinct advantages for coupling to semiconductor qubits,including low loss,high stability,and compatibility with magnetic fields.However,the integration of SAW resonators wi...Surface acoustic wave(SAW)resonators offer distinct advantages for coupling to semiconductor qubits,including low loss,high stability,and compatibility with magnetic fields.However,the integration of SAW resonators with double quantum dots(DQDs)that host charge and spin qubits remains largely unexplored.In this work,we propose a flip-chip architecture that enables three-dimensional integration of a semiconductor DQD with a SAW resonator.Taking experimental feasibility into account,we estimate the coupling strength between a DQD and a SAW resonator.The results suggest that the strong coupling regime can be reached in our design.This study provides theoretical insight and practical guidance for experimental exploration of phonon–electron coupling in hybrid SAW-DQD quantum systems.展开更多
[Objective]This study aims to investigate the multi-body hydrodynamic interaction mechanisms during offshore lifting operations of aquaculture net cages in wind-fishery integration systems.By integrating numerical sim...[Objective]This study aims to investigate the multi-body hydrodynamic interaction mechanisms during offshore lifting operations of aquaculture net cages in wind-fishery integration systems.By integrating numerical simulations and dynamic analysis methods,this study systematically investigates the coupled dynamic response characteristics during the cage-carrier vessel separation process to reveal its dynamic evolution patterns and key influence mechanisms.[Method]Based on potential flow theory,a fully coupled dynamic analysis model of crane vessel-net cage-semi-submersible barge was established for a marine ranch project in Guangdong.The complete lifting process was dynamically simulated using SESAM software.Five typical operating sea states were configured to investigate the influence of wave parameters on the system's motion response under combined wave-current-wind actions.[Result]The results demonstrate that wave period dominates the system stability.Under short-period conditions,the system maintains stable motion with relatively small horizontal relative displacements,while long-period conditions excite low-frequency resonance,leading to significant slow-drift motions.Vertical response analysis reveals that long-period waves cause severe relative displacement fluctuations between the cage and semi-submersible vessel,with actual displacement amplitudes doubling the preset safety target of 2.045 m.Quantitative analysis further indicates that when significant wave height increases from 1.0 m to 1.5 m,the actual displacement amplitude increases by approximately 20%relative to the target displacement of 2.045 m,demonstrating that its influence is significantly weaker than the displacement variations induced by wave period changes.The complete dynamic simulation successfully captures the continuous dynamic response characteristics during the lifting process.[Conclusion]This research clarifies the influence mechanisms of wave parameters on the cage lifting process,identifying wave period as the crucial factor for operational safety.An operation window assessment method incorporating multi-body coupling effects is established,proposing a safety criterion with peak period not exceeding six seconds as the core requirement.The findings provide theoretical foundation for safe installation of marine ranch net cages and offer valuable references for similar offshore lifting operations.展开更多
High geo-stress and high temperature in deep rock engineering increase the possibility of engineering and geological disasters in discontinuous rocks.However,the influence of thermomechanical coupling on the shear beh...High geo-stress and high temperature in deep rock engineering increase the possibility of engineering and geological disasters in discontinuous rocks.However,the influence of thermomechanical coupling on the shear behavior and damage evolution of prefractured granite remains immature.In this context,true triaxial laboratory tests and discrete element method simulations under different confining pressures(σ3=3 MPa,σ2=4 MPa,andσ3=80 MPa,σ2=100 MPa)and temperatures(25℃-500℃)were carried out on rough granite fractures with two different orientations.Results indicate that high temperature and high confining pressure increase the peak strength of the prefractured specimen,leading to more microcracks in the host rock and more gouges between the surfaces.Thermal strengthening at low temperatures(<300℃)and residual stick-slip only occur under a greater confining pressure for prefractured specimens.High confining pressure suppresses generation of the thermal microcracks in the heating stage.Cracks first initiate in the asperities on the fracture surfaces,and then propagate into the rock matrix during the mechanical loading stage.In addition,prefractured granite with a larger fracture angle is characterized by smaller peak and residual strength,faster residual slip,fewer new cracks on the specimen surface,and a more pronounced thermal strengthening effect on peak strength.The slip tendency analysis indicates that a higher maximum principal stress(s1)and a large fracture angle(45°-75°)generally result in a higher potential for fracture slip or activation.This study will contribute to a better understanding of the fracture shear mechanism under true triaxial thermomechanical coupling conditions and provides new insights into the stability evaluation of deep dynamic geological hazards.展开更多
Cuprous oxide(Cu_(2)O) is one of the most promising catalysts for electrochemical conversion of CO_(2) into value-added C_(2) products.The efficiency of CO_(2)-to-C_(2) conversion is highly dependent on the Cu_(2)O cr...Cuprous oxide(Cu_(2)O) is one of the most promising catalysts for electrochemical conversion of CO_(2) into value-added C_(2) products.The efficiency of CO_(2)-to-C_(2) conversion is highly dependent on the Cu_(2)O crystal plane orientation and the corresponding adsorbed ^(*)CO species.Herein,we constructed high-index crystal planes(311) in Cu_(2)O(CO-Cu_(2)O) via a facile self-selective CO-induced strategy under a CO atmosphere,which was verified by high-resolution transmission electron microscopy(HR-TEM) and atomic force microscopy(AFM) results.By exploiting the high surface energy of the high index crystal planes,^(*)CO species are stabilized in CO-Cu_(2)O during CO_(2)RR,resulting in exceptional catalytic performance for CO_(2)-to-C_(2)products.In situ infrared spectroscopy revealed that both atop-type(^(*)CO_(atop)) and hollow-type(^(*)CO_(hollow)) adsorption of ^(*)CO species occurred on the CO-Cu_(2)O.The asymmetric C-C coupling energy barrier between ^(*)CO_(atop) and ^(*)CO_(hollow) in(311) crystal plane decreases by 47.8 % compared to the symmetric coupling of ^(*)CO_(atop) in conventional(100) crystal planes.Consequently,the Faradaic efficiency of C_(2) products generated with CO-Cu_(2)O was increased by as high as 100 % compared to that with pristine Cu_(2)O.展开更多
基金funded by the National Natural Science Foundation of China[52106246]the Postgraduate Research&Practice innovation Program of Jiangsu Province[KYCX24_1641].
文摘Based on the rapid advancements in nanomaterials and nanotechnology,the Nanofluidic Reverse Electrodialysis(NRED)has attracted significant attention as an innovative and promising energy conversion strategy for extracting sustainable and clean energy fromthe salinity gradient energy.However,the scarcity of research investigating the intricate multi-factor coupling effects on the energy conversion performance,especially the trade-offs between ion selectivity and mass transfer in nanochannels,of NRED poses a great challenge to achieving breakthroughs in energy conversion processes.This numerical study innovatively investigates the multi-factor coupling effect of three critical operational factors,including the nanochannel configuration,the temperature field,and the concentration difference,on the energy conversion processes of NRED.In this work,a dimensionless amplitude parameter s is introduced to emulate the randomly varied wall configuration of nanochannels that inherently occur in practical applications,thereby enhancing the realism and applicability of our analysis.Numerical results reveal that the application of a temperature gradient,which is oriented in opposition to the concentration gradient,enhances the ion transportation and selectivity simultaneously,leading to an enhancement in both output power and energy conversion efficiency.Additionally,the increased fluctuation of the nanochannel wall from s=0 to s=0.08 improves ion selectivity yet raises ion transport resistance,resulting in an enhancement in output power and energy conversion efficiency but a slight reduction in current.Furthermore,with increasing the concentration ratio cH/cL from 10 to 1000,either within a fixed temperature field or at a constant dimensionless amplitude,the maximumpower consistently attains its optimal value at a concentration ratio of 100 but the cation transfer number experiences amonotonic decrease across this entire range of concentration ratios.Finally,uponmodifying the operational parameters fromthe baseline condition of s=0,c_(H)/c_(L)=10,andΔT=0 K to the targetedconditionof s=0.08,c_(H)/c_(L)=50,andΔT=25 K,there is a concerted improvement observed in the open-circuit potential,short-circuit current,andmaximumpower,with respective increments of 8.86%,204.97%,and 232.01%,but a reduction in cation transfer number with a notable decrease of 15.37%.
基金the National Natural Science Foundation of China (No.51178305)Key Projects in the Science & Technology Pillar Program of Tianjin (No.11ZCKFSF00300)
文摘In order to accurately simulate the diffusion of chloride ion in the existing concrete bridge and acquire the precise chloride ion concentration at given time, a cellular automata （CA）-based model is proposed. The process of chloride ion diffusion is analyzed by the CA-based method and a nonlinear solution of the Fick＇s second law is obtained. Considering the impact of various factors such as stress states, temporal and spatial variability of diffusion parameters and water-cement ratio on the process of chloride ion diffusion, the model of chloride ion diffusion under multi-factor coupling actions is presented. A chloride ion penetrating experiment reported in the literature is used to prove the effectiveness and reasonability of the present method, and a T-type beam is taken as an illustrative example to analyze the process of chloride ion diffusion in practical application. The results indicate that CA-based method can simulate the diffusion of chloride ion in the concrete structures with acceptable precision.
基金co-supported by the National Natural Science Foundation of China (Nos. 61374145 and U1333131)
文摘Heavy-equipment airdrop is a highly risky procedure that has a complicated system due to the secluded and complex nature of factors＇ coupling. As a result, it is difficult to study the modeling and safety simulation of this system. The dynamic model of the heavy-equipment airdrop is based on the Lagrange analytical mechanics, which has all the degrees of freedom and can accurately pinpoint the real-time coordinates and attitude of the carrier with its cargo. Unfavorable conditions accounted in the factors＇ models, including aircraft malfunctions and adverse environments, are established from a man-machine-environment perspective. Subsequently, a virtual simulation system for the safety research of the multi-factor coupling heavy-equipment airdrop is developed through MATLAB/Simulink, C language and Flightgear software. To verify the veracity of the theory, the verification model is built based on dynamic software ADAMS. Finally, the emulation is put to the test with the input of realistic accident variables to ascertain its feasibility and validity of this method.
基金the National Key Technology Research and Development Program of China(Nos.2018YFC1900603 and 2018YFC0604604)。
文摘In order to solve the problem of strength instability of cemented tailings backfill(CTB)under low temperature environment(≤20℃),the strength optimization and prediction of CTB under the influence of multiple factors were carried out.The response surface method(RSM)was used to design the experiment to analyze the development law of backfill strength under the coupling effect of curing temperature,sand-cement ratio and slurry mass fraction,and to optimize the mix proportion;the artificial neural network algorithm(ANN)and particle swarm optimization algorithm(PSO)were used to build the prediction model of backfill strength.According to the experimental results of RSM,the optimal mix proportion under different curing temperatures was obtained.When the curing temperature is 10-15℃,the best mix proportion of sand-cement ratio is 9,and the slurry mass fraction is 71%;when the curing temperature is 15-20℃,the best mix proportion of sand-cement ratio is 8,and the slurry mass fraction is 69%.The ANN-PSO intelligent model can accurately predict the strength of CTB,its mean relative estimation error value and correlation coefficient value are only 1.95%and 0.992,and the strength of CTB under different mix proportion can be predicted quickly and accurately by using this model.
基金Item Sponsored by Technology Supporting Program During the 11th Five-Year Plan Period(BAE03A07)
文摘Combined with the parameters of the production process of a steel factory, numerical simulations for a new ladle from preheating to turnover are conducted using the finite element analysis system software （ANSYS）. The measured data proved that the simulated results are reliable. The effects of preheating time, thermal cycling times, and empty package time on steel temperature are calculated, an ideal preheating time is provided, besides, based on the analysis of a single factor and use the nonlinear analysis method, a steel temperature compensating model with di- versified coupling factors is proposed, with the largest error of the present coupling model at 1. 462 ~C, and the er- rors between actual and target steel temperature in tundish after the model is applied to practical production are basi- cally controlled within -4-6 ~C, which can meet the accuracy of the manufacturer and has a practical guiding significance for the production in steelmaking workshops.
基金Supported by National Natural Science Foundation of China(21991093)。
文摘The coupling reactions of methanol and long-chain alkanes(n-dodecane,n-tetradecane and n-hexadecane)over CHA-type molecular sieves were studied in a fixed bed reactor.Over SAPO-34 and SSZ-13,it was found that the induction period of methanol conversion was shortened by the introduction of long-chain alkanes.However,the addition of long-chain alkanes had little influence on the product distribution.Polymethylbenzenes and the derivatives were the main retained species on spent SSZ-13 catalyst,while adamantanes were the main retained species on SAPO-34.This indicates that coking species formation was mainly related to the further transformation of long-chain alkane/methanol coupling products at acid sites of the molecular sieve.These findings provide valuable information of long chain alkanes conversion and methanol reaction behavior of induction period over small pore CHA molecular sieves.
基金National Key Research and Development Program of China(2022YFB4600902)Shandong Provincial Science Foundation for Outstanding Young Scholars(ZR2024YQ020)。
文摘Wire arc additive manufacturing(WAAM)has emerged as a promising approach for fabricating large-scale components.However,conventional WAAM still faces challenges in optimizing microstructural evolution,minimizing additive-induced defects,and alleviating residual stress and deformation,all of which are critical for enhancing the mechanical performance of the manufactured parts.Integrating interlayer friction stir processing(FSP)into WAAM significantly enhances the quality of deposited materials.However,numerical simulation research focusing on elucidating the associated thermomechanical coupling mechanisms remains insufficient.A comprehensive numerical model was developed to simulate the thermomechanical coupling behavior in friction stir-assisted WAAM.The influence of post-deposition FSP on the coupled thermomechanical response of the WAAM process was analyzed quantitatively.Moreover,the residual stress distribution and deformation behavior under both single-layer and multilayer deposition conditions were investigated.Thermal analysis of different deposition layers in WAAM and friction stir-assisted WAAM was conducted.Results show that subsequent layer deposition induces partial remelting of the previously solidified layer,whereas FSP does not cause such remelting.Furthermore,thermal stress and deformation analysis confirm that interlayer FSP effectively mitigates residual stresses and distortion in WAAM components,thereby improving their structural integrity and mechanical properties.
基金Youth project under the National Social Science Foundation of China(15CJY054)key project in Philosophy and Social Sciences funded by the Chongqing Municipal Education Commission(22SKGH091)。
文摘This study aims to promote the optimization and upgrading of the economic structure in rural areas of China by focusing on the coupling coordination mechanism between digital economy–agriculture integration and rural revitalization.By examining panel data from 30 Chinese provinces,autonomous regions,and municipalities between 2011 and 2022,the research constructs a weight-based evaluation system that integrates subjective and objective methods and a coupling coordination model to reveal its dynamic evolution patterns.Key findings indicate that digital economy–agriculture integration and rural revitalization achieve cross-coupling through critical activities.The impact of digital-agriculture integration on advancing rural revitalization lags by 2–3 years.Although the coupling development degree between the two systems continues to improve,it remains at the stage of primary coordination.Regional disparities are significant,showing a gradient pattern of“high degree of coupling development in the east and low degree of coupling development in the west.”
基金Project supported by the National Natural Science Foun-dation of China(Grant No.62373197)the Natural Science Foundation of the Higher Education Institutions of Jiangsu Province,China(Grant No.23KJB120010)+1 种基金the Industry-University-Research Cooperation Project of Jiangsu Province,China(Grant No.BY20251038)the Cultivation and In-cubation Project of the College of Automation,Nanjing Uni-versity of Posts and Telecommunications.
文摘Multilayer complex dynamical networks,characterized by the intricate topological connections and diverse hierarchical structures,present significant challenges in determining complete structural configurations due to the unique functional attributes and interaction patterns inherent to different layers.This paper addresses the critical question of whether structural information from a known layer can be used to reconstruct the unknown intralayer structure of a target layer within general weighted output-coupling multilayer networks.Building upon the generalized synchronization principle,we propose an innovative reconstruction method that incorporates two essential components in the design of structure observers,the cross-layer coupling modulator and the structural divergence term.A key advantage of the proposed reconstruction method lies in its flexibility to freely designate both the unknown target layer and the known reference layer from the general weighted output-coupling multilayer network.The reduced dependency on full-state observability enables more deployment in engineering applications with partial measurements.Numerical simulations are conducted to validate the effectiveness of the proposed structure reconstruction method.
基金supported by the National Natural Science Foundation of China(Grant Nos.22193032 and 32401033)the Research Fund of Wenzhou Institute,Chinese Academy of Sciences(Grant Nos.WIUCASQD2020009,WIUCASQD2023005,XSZD2024004,2021HZSY0061,and WIUCASICTP2022)。
文摘The F_(1)-ATPase and V_(1)-ATPase are rotary biomotors.Alignment of their amino acid sequences,which originate from bovine heart mitochondria(1BMF)and Enterococcus hirae(3VR6),respectively,demonstrates that the segment forming the ATP catalytic pocket is highly conserved.Single-molecule experiments,however,have revealed subtle differences in efficiency between the F_(1) and V_(1) motors.Here,we perform both atomistic and coarse-grained molecular dynamics simulations to investigate the mechanochemical coupling and coordination in F_(1) and V_(1) ATPase.Our results show that the correlation between conformational changes in F_(1) is stronger than that in V_(1),indicating that the mechanochemical coupling in F_(1) is tighter than in V_(1).Moreover,the unidirectional rotation of F_(1) is more processive than that of V_(1),which accounts for the higher efficiency observed in F_(1) and explains the occasional backward steps detected in single-molecule experiments on V_(1).
基金supported by the National Science and Tech-nology Major Project,China(No.J2019-II-0012-0032)。
文摘The coupling effects among the flow field,temperature distribution and structural deformation in a turbine cannot be ignored,particularly during flight cycles when the turbine experiences varied operational states.Relying solely on steady-state solutions cannot predict the detrimental effects caused by hysteresis.Consequently,this paper employs a quasi-steady-state fluid-thermalstructure multidisciplinary coupling solution method,integrating transient solid heat conduction with steady-state flow field and static structural deformation solutions.After conducting a numerical simulation of a three-dimensional,five-stage,low-pressure turbine air system,the following conclusions are drawn:when boundary conditions attain high-power states through processes that are numerically identical but in opposite directions,slight variations in solid deformation significantly impact the flow field;when boundary conditions attain high-power states through processes that are directionally consistent but have different numerical values,the influence of the boundary condition change rate on the flow field surpasses that of solid deformation.In terms of turbine design parameters,a large difference in stage-reaction between adjacent stages at the lower radius of the turbine can lead to significant changes in the disc cavity flow field during flight cycles.The difference in the stage-reaction of 0.23 at 10%blade height in adjacent stages may induce severe gas ingress in the stator disc cavity.Thus,it is crucial to minimize this difference and to appropriately extend the duration of the deceleration phase to ensure the turbine's safe operation.
基金supported by the National Key Research and Development Program of China (MOST)(Grant No.2022YFA1402800)the Chinese Academy of Sciences (CAS) Presidents International Fellowship Initiative (PIFI)(Grant No.2025PG0006)+3 种基金the National Natural Science Foundation of China (NSFC)(Grant Nos.51831012,12274437,and 52161160334)the CAS Project for Young Scientists in Basic Research (Grant No.YSBR-084)the CAS Youth Interdisciplinary Teamthe China Postdoctoral Science Foundation (Grant No.2025M773402)。
文摘Based on the Smit-Suhl formula,we propose a universal approach for solving the magnon-magnon coupling problem in bilayer coupled systems(e.g.,antiferromagnets).This method requires only the energy expression,enabling the automatic derivation of analytical expressions for the eigenmatrix elements via symbolic computation,eliminating the need for tedious manual calculations.Using this approach,we investigate the impact of magnetic hysteresis on magnon-magnon coupling in a system with interlayer Dzyaloshinskii-Moriya interaction(DMI).The magnetic hysteresis leads to an asymmetric magnetic field dependence of the resonance frequency and alters the number of degeneracy points between the pure optical and acoustic modes.Moreover,it can result in the coupling strength at the gap of the f–H phase diagram being nearly vanishing,contrary to the conventionally expected maximum.These results deepen the understanding of the effect of interlayer DMI on magnon–magnon coupling and the proposed universal method significantly streamlines the solving process of magnon–magnon coupling problems.
基金supported in part by the Mining Hydraulic Technology and Equipment Engineering Research Center,Liaoning Technical University,Fuxin,China(Grant No.MHTE23-R04)the Fundamental Research Funds for the Central Universities(ID N25BSS068).
文摘This study presents an implicit multiphysics coupling method integrating Computational Fluid Dynamics(CFD),the Multiphase Particle-in-Cell(MPPIC)model,and the Finite Element Method(FEM),implemented with OpenFOAM,CalculiX,and preCICE to simulate fluid-particle-structure interactions with large deformations.Mesh motion in the fluid field is handled using the radial basis function(RBF)method.The particle phase is modeled by MPPIC,where fluid-particle interaction is described through momentum exchange,and inter-particle collisions are characterized by collision stress.The structural field is solved by nonlinear FEM to capture large deformations induced by geometric nonlinearity.Coupling among fields is realized through a partitioned,parallel,and non-intrusive iterative strategy,ensuring stable transfer and convergence of interface forces and displacements.Notably,the influence of particles on the structure is not direct but mediated by the fluid,while structural motion directly affects particle dynamics.The results demonstrate that the proposed approach effectively captures multiphysics interaction processes and provides a valuable reference for numerical modeling of coupled fluid-particle-structure systems.
基金supported by the National Key Research and Development Program of China(Grant No.2022YFC3005603-01)the Natural Science Foundation Science of Anhui Province(Grant No.2308085US02).
文摘Hydraulic asphalt concrete(HAC)has been increasingly employed as an appropriate impervious structure in hydraulic and hydropower engineering.However,asphalt mortar,usually seen as the matrix of HAC composite,is particularly prone to damage under combined stress and seepage interactions,and the mesoscale investigations on the damage-seepage coupling behavior of HAC under complex stress states remain limited.This research develops a numerical three-dimensional mesoscale model composed of asphalt mortar and polyhedral aggregate to investigate the stress-damage-seepage coupling behavior in HAC.In this model,asphalt mortar yields the viscoelastic continuum damage law and aggregate obeys the Mazars’elastic-brittle damage law;simultaneously,the effective permeability coefficient of asphalt mortar is assumed to follow an exponential function of damage.The predicted deviatoric stress-strain and hydraulic gradient-seepage curves both are in good agreement with the reported experimental results,which shows the proposed model is valid and reasonable.The simulated results indicate that the damaged asphalt mortar can induce localized areas of high permeability,which in turn affects the overall impervious performance of HAC.
基金support from the Taishan Scholars Program,Key Research Program of Frontier Sciences,Chinese Academy of Sciences(CAS),Grant No.ZDBS-LY-DQC022Open Research Fund of State Key Laboratory of Geomechanics and Geotechnical Engineering Safety,Grant No.SKLGME023003.
文摘High rock temperature is a great challenge frequently encountered during subsurface resource recovery and deep underground space utilization,and it is still unclear how the granitic rock responds to realtime high temperature upon shear loading.To better understand the shear fracture behavior and underlying processes of intact granite exposed to thermal-mechanical coupling loading,direct shear tests were conducted utilizing a newly built testing apparatus at varied normal stresses and high temperatures.Influencesof different temperatures and different heating methods(real-time heating and thermal treatment)on the shear mechanical behavior were compared and discussed.Results indicate that shear stress fluctuationswith some small stress drops occur as shear stress is approaching the peak strength under real-time heating,accompanied by more and earlier AE signal uprushes.This suggests that greater cracking events occur earlier during real-time heating than after thermal treatment,resulting in a lower peak shear strength.Furthermore,the peak shear strength,post-peak stress drop,and cohesion rise from room temperature(RT)to 200℃(the peak strength increases by 8%,5.8%,and 9.9%under normal stress of 5 MPa,15 MPa,and 20 MPa,correspondingly),and subsequently decline from 200℃to 400℃.Temperature has a limited impact on shear stiffness from RT to 200℃,but significantlyreduces it from 200℃to 400℃,with drops of 15%,7.9%,and 10%under normal stress of 5 MPa,15 MPa,and 20 MPa,respectively.Moreover,the shear strength and stiffness under real-time heating are lower than those for the thermally treated specimens.The strengthening of intact granite below 200℃upon shear is associated with loss of water and a more compacted structure,while the weakening effect of temperature on shear strength from 200℃to 400℃is due to the new thermal cracks and less brittle and stiff of minerals.
基金supported by the National Key Research and Development Program of China(No.2022YFF1301301)the Natural Science Foundation of Xiamen Municipality(No.3502Z202472047)the Geological Survey Program of China Geological Survey(DD20190303).
文摘To address the deficiencies in comprehensive surface contamination prevention strategies within China's nitrate-affected regions,this research innovatively proposes the DITAPH model-a systematic framework integrating groundwater nitrate vulnerability assessment and Nitrate Vulnerable Zones(NVZs)delineation through optimization of hydrogeological parameters.Based on detailed hydrogeological and hydrochemical investigations,the DITAPH model was applied in the plain areas of Quanzhou to evaluate its applicability.The model selected hydrogeological parameters(depth of groundwater,lithology of the vadose zone,topographic slope,aquifer water yield property),one climatic parameter(precipitation),and two anthropogenic parameters(land use type and population density)as assessment indicators.The results of the groundwater nitrate vulnerability assessment showed that the low,relatively low,relatively high,and high groundwater nitrate vulnerability zones in the study area accounted for 5.96%,35.44%,53.74%and 4.86%of the total area,respectively.Groundwater nitrate vulnerability was most strongly influenced by human activities,followed by groundwater depth and topographic slope.The high vulnerability zone is mainly affected by domestic and industrial wastewater,whereas the relatively high groundwater nitrate vulnerability zone is primarily influenced by agricultural activities.Validation of the DITAPH model revealed a significant positive correlation between the DITAPH index(DI)and nitrate concentration(ρ(NO3−)).The results of the NVZs delineated by the DITAPH model are reliable and can serve as a tool for water resource management planning,guiding the development of targeted measures in the NVZs to prevent groundwater contamination.
基金supported by the National Natural Science Foundation of China(Grant Nos.12274401,12274397,12034018)the National Key Research and Development Program of China(Grant No.2022YFA1405900)the Natural Science Foundation of Jiangsu Province(Grant No.BK20240123)。
文摘Surface acoustic wave(SAW)resonators offer distinct advantages for coupling to semiconductor qubits,including low loss,high stability,and compatibility with magnetic fields.However,the integration of SAW resonators with double quantum dots(DQDs)that host charge and spin qubits remains largely unexplored.In this work,we propose a flip-chip architecture that enables three-dimensional integration of a semiconductor DQD with a SAW resonator.Taking experimental feasibility into account,we estimate the coupling strength between a DQD and a SAW resonator.The results suggest that the strong coupling regime can be reached in our design.This study provides theoretical insight and practical guidance for experimental exploration of phonon–electron coupling in hybrid SAW-DQD quantum systems.
文摘[Objective]This study aims to investigate the multi-body hydrodynamic interaction mechanisms during offshore lifting operations of aquaculture net cages in wind-fishery integration systems.By integrating numerical simulations and dynamic analysis methods,this study systematically investigates the coupled dynamic response characteristics during the cage-carrier vessel separation process to reveal its dynamic evolution patterns and key influence mechanisms.[Method]Based on potential flow theory,a fully coupled dynamic analysis model of crane vessel-net cage-semi-submersible barge was established for a marine ranch project in Guangdong.The complete lifting process was dynamically simulated using SESAM software.Five typical operating sea states were configured to investigate the influence of wave parameters on the system's motion response under combined wave-current-wind actions.[Result]The results demonstrate that wave period dominates the system stability.Under short-period conditions,the system maintains stable motion with relatively small horizontal relative displacements,while long-period conditions excite low-frequency resonance,leading to significant slow-drift motions.Vertical response analysis reveals that long-period waves cause severe relative displacement fluctuations between the cage and semi-submersible vessel,with actual displacement amplitudes doubling the preset safety target of 2.045 m.Quantitative analysis further indicates that when significant wave height increases from 1.0 m to 1.5 m,the actual displacement amplitude increases by approximately 20%relative to the target displacement of 2.045 m,demonstrating that its influence is significantly weaker than the displacement variations induced by wave period changes.The complete dynamic simulation successfully captures the continuous dynamic response characteristics during the lifting process.[Conclusion]This research clarifies the influence mechanisms of wave parameters on the cage lifting process,identifying wave period as the crucial factor for operational safety.An operation window assessment method incorporating multi-body coupling effects is established,proposing a safety criterion with peak period not exceeding six seconds as the core requirement.The findings provide theoretical foundation for safe installation of marine ranch net cages and offer valuable references for similar offshore lifting operations.
基金support from the National Key Research and Development Program of China(Grant No.2022YFE0137200)supported by the Taishan Scholars Program and Open Research Fund of State Key Laboratory of Geomechanics and Geotechnical Engineering Safety(Grant No.SKLGME023003).
文摘High geo-stress and high temperature in deep rock engineering increase the possibility of engineering and geological disasters in discontinuous rocks.However,the influence of thermomechanical coupling on the shear behavior and damage evolution of prefractured granite remains immature.In this context,true triaxial laboratory tests and discrete element method simulations under different confining pressures(σ3=3 MPa,σ2=4 MPa,andσ3=80 MPa,σ2=100 MPa)and temperatures(25℃-500℃)were carried out on rough granite fractures with two different orientations.Results indicate that high temperature and high confining pressure increase the peak strength of the prefractured specimen,leading to more microcracks in the host rock and more gouges between the surfaces.Thermal strengthening at low temperatures(<300℃)and residual stick-slip only occur under a greater confining pressure for prefractured specimens.High confining pressure suppresses generation of the thermal microcracks in the heating stage.Cracks first initiate in the asperities on the fracture surfaces,and then propagate into the rock matrix during the mechanical loading stage.In addition,prefractured granite with a larger fracture angle is characterized by smaller peak and residual strength,faster residual slip,fewer new cracks on the specimen surface,and a more pronounced thermal strengthening effect on peak strength.The slip tendency analysis indicates that a higher maximum principal stress(s1)and a large fracture angle(45°-75°)generally result in a higher potential for fracture slip or activation.This study will contribute to a better understanding of the fracture shear mechanism under true triaxial thermomechanical coupling conditions and provides new insights into the stability evaluation of deep dynamic geological hazards.
基金the financial support from the National Natural Science Foundation of China (Nos.U23A20677,22022610 and 52400137)"Pioneer" and "Leading Goose" R&D Program of Zhejiang (Nos.2022C03146 and 2023C03017)+2 种基金China Postdoctoral Science Foundation (No.2024T170805)Zhejiang Provincial Natural Science Foundation of China (No.LDT23E06015B06)the support of the Research Computing Center in College of Chemical and Biological Engineering at Zhejiang University for assistance with the calculations。
文摘Cuprous oxide(Cu_(2)O) is one of the most promising catalysts for electrochemical conversion of CO_(2) into value-added C_(2) products.The efficiency of CO_(2)-to-C_(2) conversion is highly dependent on the Cu_(2)O crystal plane orientation and the corresponding adsorbed ^(*)CO species.Herein,we constructed high-index crystal planes(311) in Cu_(2)O(CO-Cu_(2)O) via a facile self-selective CO-induced strategy under a CO atmosphere,which was verified by high-resolution transmission electron microscopy(HR-TEM) and atomic force microscopy(AFM) results.By exploiting the high surface energy of the high index crystal planes,^(*)CO species are stabilized in CO-Cu_(2)O during CO_(2)RR,resulting in exceptional catalytic performance for CO_(2)-to-C_(2)products.In situ infrared spectroscopy revealed that both atop-type(^(*)CO_(atop)) and hollow-type(^(*)CO_(hollow)) adsorption of ^(*)CO species occurred on the CO-Cu_(2)O.The asymmetric C-C coupling energy barrier between ^(*)CO_(atop) and ^(*)CO_(hollow) in(311) crystal plane decreases by 47.8 % compared to the symmetric coupling of ^(*)CO_(atop) in conventional(100) crystal planes.Consequently,the Faradaic efficiency of C_(2) products generated with CO-Cu_(2)O was increased by as high as 100 % compared to that with pristine Cu_(2)O.
