Based on the rapid advancements in nanomaterials and nanotechnology,the Nanofluidic Reverse Electrodialysis(NRED)has attracted significant attention as an innovative and promising energy conversion strategy for extrac...Based on the rapid advancements in nanomaterials and nanotechnology,the Nanofluidic Reverse Electrodialysis(NRED)has attracted significant attention as an innovative and promising energy conversion strategy for extracting sustainable and clean energy fromthe salinity gradient energy.However,the scarcity of research investigating the intricate multi-factor coupling effects on the energy conversion performance,especially the trade-offs between ion selectivity and mass transfer in nanochannels,of NRED poses a great challenge to achieving breakthroughs in energy conversion processes.This numerical study innovatively investigates the multi-factor coupling effect of three critical operational factors,including the nanochannel configuration,the temperature field,and the concentration difference,on the energy conversion processes of NRED.In this work,a dimensionless amplitude parameter s is introduced to emulate the randomly varied wall configuration of nanochannels that inherently occur in practical applications,thereby enhancing the realism and applicability of our analysis.Numerical results reveal that the application of a temperature gradient,which is oriented in opposition to the concentration gradient,enhances the ion transportation and selectivity simultaneously,leading to an enhancement in both output power and energy conversion efficiency.Additionally,the increased fluctuation of the nanochannel wall from s=0 to s=0.08 improves ion selectivity yet raises ion transport resistance,resulting in an enhancement in output power and energy conversion efficiency but a slight reduction in current.Furthermore,with increasing the concentration ratio cH/cL from 10 to 1000,either within a fixed temperature field or at a constant dimensionless amplitude,the maximumpower consistently attains its optimal value at a concentration ratio of 100 but the cation transfer number experiences amonotonic decrease across this entire range of concentration ratios.Finally,uponmodifying the operational parameters fromthe baseline condition of s=0,c_(H)/c_(L)=10,andΔT=0 K to the targetedconditionof s=0.08,c_(H)/c_(L)=50,andΔT=25 K,there is a concerted improvement observed in the open-circuit potential,short-circuit current,andmaximumpower,with respective increments of 8.86%,204.97%,and 232.01%,but a reduction in cation transfer number with a notable decrease of 15.37%.展开更多
In order to solve the problem of strength instability of cemented tailings backfill(CTB)under low temperature environment(≤20℃),the strength optimization and prediction of CTB under the influence of multiple factors...In order to solve the problem of strength instability of cemented tailings backfill(CTB)under low temperature environment(≤20℃),the strength optimization and prediction of CTB under the influence of multiple factors were carried out.The response surface method(RSM)was used to design the experiment to analyze the development law of backfill strength under the coupling effect of curing temperature,sand-cement ratio and slurry mass fraction,and to optimize the mix proportion;the artificial neural network algorithm(ANN)and particle swarm optimization algorithm(PSO)were used to build the prediction model of backfill strength.According to the experimental results of RSM,the optimal mix proportion under different curing temperatures was obtained.When the curing temperature is 10-15℃,the best mix proportion of sand-cement ratio is 9,and the slurry mass fraction is 71%;when the curing temperature is 15-20℃,the best mix proportion of sand-cement ratio is 8,and the slurry mass fraction is 69%.The ANN-PSO intelligent model can accurately predict the strength of CTB,its mean relative estimation error value and correlation coefficient value are only 1.95%and 0.992,and the strength of CTB under different mix proportion can be predicted quickly and accurately by using this model.展开更多
In order to accurately simulate the diffusion of chloride ion in the existing concrete bridge and acquire the precise chloride ion concentration at given time, a cellular automata （CA）-based model is proposed. The p...In order to accurately simulate the diffusion of chloride ion in the existing concrete bridge and acquire the precise chloride ion concentration at given time, a cellular automata （CA）-based model is proposed. The process of chloride ion diffusion is analyzed by the CA-based method and a nonlinear solution of the Fick＇s second law is obtained. Considering the impact of various factors such as stress states, temporal and spatial variability of diffusion parameters and water-cement ratio on the process of chloride ion diffusion, the model of chloride ion diffusion under multi-factor coupling actions is presented. A chloride ion penetrating experiment reported in the literature is used to prove the effectiveness and reasonability of the present method, and a T-type beam is taken as an illustrative example to analyze the process of chloride ion diffusion in practical application. The results indicate that CA-based method can simulate the diffusion of chloride ion in the concrete structures with acceptable precision.展开更多
Heavy-equipment airdrop is a highly risky procedure that has a complicated system due to the secluded and complex nature of factors＇ coupling. As a result, it is difficult to study the modeling and safety simulation ...Heavy-equipment airdrop is a highly risky procedure that has a complicated system due to the secluded and complex nature of factors＇ coupling. As a result, it is difficult to study the modeling and safety simulation of this system. The dynamic model of the heavy-equipment airdrop is based on the Lagrange analytical mechanics, which has all the degrees of freedom and can accurately pinpoint the real-time coordinates and attitude of the carrier with its cargo. Unfavorable conditions accounted in the factors＇ models, including aircraft malfunctions and adverse environments, are established from a man-machine-environment perspective. Subsequently, a virtual simulation system for the safety research of the multi-factor coupling heavy-equipment airdrop is developed through MATLAB/Simulink, C language and Flightgear software. To verify the veracity of the theory, the verification model is built based on dynamic software ADAMS. Finally, the emulation is put to the test with the input of realistic accident variables to ascertain its feasibility and validity of this method.展开更多
Combined with the parameters of the production process of a steel factory, numerical simulations for a new ladle from preheating to turnover are conducted using the finite element analysis system software （ANSYS）. T...Combined with the parameters of the production process of a steel factory, numerical simulations for a new ladle from preheating to turnover are conducted using the finite element analysis system software （ANSYS）. The measured data proved that the simulated results are reliable. The effects of preheating time, thermal cycling times, and empty package time on steel temperature are calculated, an ideal preheating time is provided, besides, based on the analysis of a single factor and use the nonlinear analysis method, a steel temperature compensating model with di- versified coupling factors is proposed, with the largest error of the present coupling model at 1. 462 ~C, and the er- rors between actual and target steel temperature in tundish after the model is applied to practical production are basi- cally controlled within -4-6 ~C, which can meet the accuracy of the manufacturer and has a practical guiding significance for the production in steelmaking workshops.展开更多
For space-borne gravitational wave detection missions based on the heterodyne interferometry principle,tilt-to-length(TTL)coupling noise is an important optical noise source,significantly influencing the accuracy of t...For space-borne gravitational wave detection missions based on the heterodyne interferometry principle,tilt-to-length(TTL)coupling noise is an important optical noise source,significantly influencing the accuracy of the measurement system.We present a method for analyzing TTL coupling noise under the joint influence of multiple factors.An equivalent simulated optical bench for the test mass interferometer was designed,and Gaussian beam tracing was adopted to simulate beam propagation.By simulating the interference signal,it can analyze the impact of various factors on the TTL coupling noise,including positional,beam parameters,detector parameters,and signal definition factors.On this basis,a random parameter space composed of multiple influential factors was constructed within a range satisfying the analysis requirement,and the corresponding simulation results from random sampling were evaluated via variance-based global sensitivity analysis.The calculated results of the main and total effect indexes show that the test mass rotation angle and the piston effect(lateral)significantly influence the TTL coupling noise in the test mass interferometer.The analysis provides a qualitative reference for designing and optimizing space-borne laser interferometry systems.展开更多
Defects-rich heterointerfaces integrated with adjustable crystalline phases and atom vacancies,as well as veiled dielectric-responsive character,are instrumental in electromagnetic dissipation.Conventional methods,how...Defects-rich heterointerfaces integrated with adjustable crystalline phases and atom vacancies,as well as veiled dielectric-responsive character,are instrumental in electromagnetic dissipation.Conventional methods,however,constrain their delicate constructions.Herein,an innovative alternative is proposed:carrageenan-assistant cations-regulated(CACR)strategy,which induces a series of sulfides nanoparticles rooted in situ on the surface of carbon matrix.This unique configuration originates from strategic vacancy formation energy of sulfides and strong sulfides-carbon support interaction,benefiting the delicate construction of defects-rich heterostructures in M_(x)S_(y)/carbon composites(M-CAs).Impressively,these generated sulfur vacancies are firstly found to strengthen electron accumulation/consumption ability at heterointerfaces and,simultaneously,induct local asymmetry of electronic structure to evoke large dipole moment,ultimately leading to polarization coupling,i.e.,defect-type interfacial polarization.Such“Janus effect”(Janus effect means versatility,as in the Greek two-headed Janus)of interfacial sulfur vacancies is intuitively confirmed by both theoretical and experimental investigations for the first time.Consequently,the sulfur vacancies-rich heterostructured Co/Ni-CAs displays broad absorption bandwidth of 6.76 GHz at only 1.8 mm,compared to sulfur vacancies-free CAs without any dielectric response.Harnessing defects-rich heterostructures,this one-pot CACR strategy may steer the design and development of advanced nanomaterials,boosting functionality across diverse application domains beyond electromagnetic response.展开更多
The occurrence of top-down(TD)cracking has gradually become a prevalent issue in semi-rigid base asphalt pavements after prolonged service.A coupled simulation model integrating the finite difference method(FDM)and di...The occurrence of top-down(TD)cracking has gradually become a prevalent issue in semi-rigid base asphalt pavements after prolonged service.A coupled simulation model integrating the finite difference method(FDM)and discrete element method(DEM)was employed to investigate the mechanical behavior of asphalt pavement containing a pre-existing TD crack.The mesoscopic parameters of the model were calibrated based on the mixture modulus and the static mechanical response on the MLS66 test road.Finally,an analysis was performed to assess how variations in TD crack depth and longitudinal length affect the distribution patterns of transverse tensile stress,vertical shear stress,and vertical compressive stress.The results indicate that the vertical propagation of TD crack significantly increases both the tensile stress value and range on the middle surface,while the longitudinal development of TD crack has minimal impact.This phenomenon may result in more severe fatigue failure on the middle surface.With the vertical and longitudinal development of TD crack,the vertical shear stress and compressive stress show obvious"two-stage"characteristics.When the crack's vertical length reaches 40 mm,there is a sharp increase in stress on the upper surface.As the crack continues to propagate vertically,the growth of stress on the upper surface becomes negligible,while the stress in the middle and lower layers increased significantly.Conversely,for longitudinal development of TD crack,any changes in stress are insignificant when their length is less than 180 mm;however,as they continue to develop longitudinally beyond this threshold,there is a sharp increase in stress levels.These findings hold great significance for understanding pavement structure deterioration and maintenance behavior associated with TD crack.展开更多
Electrochemical conversion of lignin for the production of high-value heterocyclic aromatic compounds has great potential.We demonstrate the targeted synthesis and cation modulation of NiCo_(2)O_(4)spinel nanoboxes,sy...Electrochemical conversion of lignin for the production of high-value heterocyclic aromatic compounds has great potential.We demonstrate the targeted synthesis and cation modulation of NiCo_(2)O_(4)spinel nanoboxes,synthesized via cation exchange and calcination oxidation.These catalysts exhibit excellent efficacy in the electrocatalytic conversion of lignin model compounds,specifically 2-phenoxy-1-phenylethanol,into nitrogen-containing aromatics,achieving high conversion rates and selectivities.These catalysts were synthesized via a cation exchange and calcination oxidation process,using Prussian blue nanocubes as precursors.The porous architecture and polymetallic composition of the NiCo_(2)O_(4)spinel demonstrated superior performance in electrocatalytic oxidative coupling,achieving a 99.2 wt%conversion rate of the 2-phenoxy-1-phenylethanol with selectivities of 37.5 wt%for quinoline derivatives and 31.5 wt%for phenol.Key innovations include the development of a sustainable one-pot synthesis method for quinoline derivatives,the elucidation of a multistage reaction pathway involving CAO bond cleavage,hydroxyaldol condensation,and CAN bond formation,and a deeper mechanistic understanding derived from DFT simulations.This work establishes a new strategy for lignin valorization,offering a sustainable route to produce high-value nitrogen-containing aromatics from renewable biomass under mild conditions,without the need for additional reagents.展开更多
Deep tight reservoirs exhibit complex stress and seepage fields due to varying pore structures,thus the seepage characteristics are significant for enhancing oil production.This study conducted triaxial compression an...Deep tight reservoirs exhibit complex stress and seepage fields due to varying pore structures,thus the seepage characteristics are significant for enhancing oil production.This study conducted triaxial compression and permeability tests to investigate the mechanical and seepage properties of tight sandstone.A digital core of tight sandstone was built using Computed Tomography(CT)scanning,which was divided into matrix and pore phases by a pore equivalent diameter threshold.A fluid-solid coupling model was established to investigate the seepage characteristics at micro-scale.The results showed that increasing the confining pressure decreased porosity,permeability,and flow velocity,with the pore phase becoming the dominant seepage channel.Cracks and large pores closed first under increasing pressure,resulted in a steep drop in permeability.However,permeability slightly decreased under high confining pressure,which followed a first-order exponential function.Flow velocity increased with seepage pressure.And the damage mainly occurred in stress-concentration regions under low seepage pressure.Seepage behavior followed linear Darcy flow,the damage emerged at seepage entrances under high pressure,which decreased rock elastic modulus and significantly increased permeability.展开更多
This study investigates the coordination between regional economic growth and ecological sustainability within the context of high-quality town economy development.To address the challenges of balancing economic expan...This study investigates the coordination between regional economic growth and ecological sustainability within the context of high-quality town economy development.To address the challenges of balancing economic expansion with environmental protection,a comprehensive evaluation index system is constructed,encompassing two key dimensions:regional economy and ecological environment.Using panel data from 2013 to 2022,the coupling coordination degree model is employed to quantify the interactions and synergy between these dimensions.Additionally,spatial econometric methods are applied to calculate both global and local Moran’s Index,revealing spatial clustering patterns,regional disparities,and heterogeneity.The relative development model further identifies critical factors influencing regional coordination,with a focus on the lagging development of basic infrastructure and public services.The findings demonstrate a positive temporal trend toward improved regional coordination and reduced development gaps,with a spatial pattern characterized by higher coupling degrees in eastern and central regions compared to western areas.Based on these results,this study proposes actionable strategies to enhance coordinated development,emphasizing ecological conservation,the establishment of green production and consumption systems,ecological restoration,and strengthened municipal collaboration.This revised abstract emphasizes the study’s purpose,methods,and key findings more clearly while maintaining a professional and concise tone.Finally,based on the above analysis results,the corresponding coordinated development suggestions of regional economy and ecological environment are given from the aspects of ecological environment protection measures,green production and consumption system construction,ecological environment restoration and municipal coordination.展开更多
Dislocations and disclinations are fundamental topological defects within crystals,which determine the mechanical properties of metals and alloys.Despite their important roles in multiple physical mechanisms,e.g.,dyna...Dislocations and disclinations are fundamental topological defects within crystals,which determine the mechanical properties of metals and alloys.Despite their important roles in multiple physical mechanisms,e.g.,dynamic recovery and grain boundary mediated plasticity,the intrinsic coupling and correlation between disclinations and dislocations,and their impacts on the deformation behavior of metallic materials still remain obscure,partially due to the lack of a theoretical tool to capture the rotational nature of disclinations.By using a Lie-algebra-based theoretical framework,we obtain a general equation to quantify the intrinsic coupling of disclinations and dislocations.Through quasi in-situ electron backscatter diffraction characterizations and disclination/dislocation density analyses in Mg alloys,the generation,coevolution and reactions of disclinations and dislocations during dynamic recovery and superplastic deformation have been quantitatively analyzed.It has been demonstrated that the obtained governing equation can capture multiple physical processes associated with mechanical deformation of metals,e.g.,grain rotation and grain boundary migration,at both room temperature and high temperature.By establishing the disclination-dislocation coupling equation within a Lie algebra description,our work provides new insights for exploring the coevolution and reaction of disclinations/dislocations,with profound implications for elucidating the microstructure-property relationship and underlying deformation mechanisms in metallic materials.展开更多
Self-trapping excitons(STEs) emission in metal halides has been a matter of interest, correlating with the strength of electron-phonon coupling in the lattice, which are usually caused by ions with ns~2 electronic str...Self-trapping excitons(STEs) emission in metal halides has been a matter of interest, correlating with the strength of electron-phonon coupling in the lattice, which are usually caused by ions with ns~2 electronic structure. In this work, Sb^(3+)/Te^(4+)ions doped Zn-based halide single crystals(SCs) with two STEs emissions have been synthesized and the possibility of its anti-counterfeiting application was explored.Further, the relationship between the strength of electron-phonon coupling and photoluminescence quantum yields(PLQYs) for STEs in a series of metal halides has been studied. And the semi-empirical range of the Huang-Rhys factors(S) for metal halides with excellent photoluminescence(PL) property has been summarized. This work provides ideas for further research into the relationship between luminescence performance and electron-phonon coupling of metal halides, and also provides a reference for designing the metal halides with high PLQYs.展开更多
Granite residual soil (GRS) is a type of weathering soil that can decompose upon contact with water, potentially causing geological hazards. In this study, cement, an alkaline solution, and glass fiber were used to re...Granite residual soil (GRS) is a type of weathering soil that can decompose upon contact with water, potentially causing geological hazards. In this study, cement, an alkaline solution, and glass fiber were used to reinforce GRS. The effects of cement content and SiO_(2)/Na2O ratio of the alkaline solution on the static and dynamic strengths of GRS were discussed. Microscopically, the reinforcement mechanism and coupling effect were examined using X-ray diffraction (XRD), micro-computed tomography (micro-CT), and scanning electron microscopy (SEM). The results indicated that the addition of 2% cement and an alkaline solution with an SiO_(2)/Na2O ratio of 0.5 led to the densest matrix, lowest porosity, and highest static compressive strength, which was 4994 kPa with a dynamic impact resistance of 75.4 kN after adding glass fiber. The compressive strength and dynamic impact resistance were a result of the coupling effect of cement hydration, a pozzolanic reaction of clay minerals in the GRS, and the alkali activation of clay minerals. Excessive cement addition or an excessively high SiO_(2)/Na2O ratio in the alkaline solution can have negative effects, such as the destruction of C-(A)-S-H gels by the alkaline solution and hindering the production of N-A-S-H gels. This can result in damage to the matrix of reinforced GRS, leading to a decrease in both static and dynamic strengths. This study suggests that further research is required to gain a more precise understanding of the effects of this mixture in terms of reducing our carbon footprint and optimizing its properties. The findings indicate that cement and alkaline solution are appropriate for GRS and that the reinforced GRS can be used for high-strength foundation and embankment construction. The study provides an analysis of strategies for mitigating and managing GRS slope failures, as well as enhancing roadbed performance.展开更多
The Electro–Hydrostatic Actuator(EHA)is applied to drive the control surface in flightcontrol system of more electric aircraft.In EHA,the Oil-Immersed Motor Pump(OMP)serves asthe core as a power assembly.However,the ...The Electro–Hydrostatic Actuator(EHA)is applied to drive the control surface in flightcontrol system of more electric aircraft.In EHA,the Oil-Immersed Motor Pump(OMP)serves asthe core as a power assembly.However,the compact integration of the OMP presents challenges inefficiently dissipating internal heat,leading to a performance degradation of the EHA due to ele-vated temperatures.Therefore,accurately modeling and predicting the internal thermal dynamicsof the OMP hold considerable significance for monitoring the operational condition of the EHA.In view of this,a modeling method considering cumulative thermal coupling was hereby proposed.Based on the proposed method,the thermal models of the motor and the pump were established,taking into account heat accumulation and transfer.Taking the leakage oil as the heat couplingpoint between the motor and the pump,the dynamic thermal coupling model of the OMP wasdeveloped,with the thermal characteristics of the oil considered.Additionally,the comparativeexperiments were conducted to illustrate the efficiency of the proposed model.The experimentalresults demonstrate that the proposed dynamic thermal coupling model accurately captured thethermal behavior of OMP,outperforming the static thermal parameter model.Overall,thisadvancement is crucial for effectively monitoring the health of EHA and ensuring flight safety.展开更多
Ground source heat pump systems demonstrate significant potential for northern rural heating applications;however,the effectiveness of these systems is often limited by challenging geological conditions.For instance,i...Ground source heat pump systems demonstrate significant potential for northern rural heating applications;however,the effectiveness of these systems is often limited by challenging geological conditions.For instance,in certain regions,the installation of buried pipes for heat exchangers may be complicated,and these pipes may not always serve as efficient low-temperature heat sources for the heat pumps of the system.To address this issue,the current study explored the use of solar-energy-collecting equipment to supplement buried pipes.In this design,both solar energy and geothermal energy provide low-temperature heat to the heat pump.First,a simulation model of a solar‒ground source heat pump coupling system was established using TRNSYS.The accuracy of this model was validated through experiments and simulations on various system configurations,including varying numbers of buried pipes,different areas of solar collectors,and varying volumes of water tanks.The simulations examined the coupling characteristics of these components and their influence on system performance.The results revealed that the operating parameters of the system remained consistent across the following configurations:three buried pipes,burial depth of 20 m,collector area of 6 m^(2),and water tank volume of 0.5 m^(3);four buried pipes,burial depth of 20 m,collector area of 3 m^(2),and water tank volume of 0.5 m^(3);and five buried pipes with a burial depth of 20 m.Furthermore,the heat collection capacity of the solar collectors spanning an area of 3 m^(2)was found to be equivalent to that of one buried pipe.Moreover,the findings revealed that the solar‒ground source heat pump coupling system demonstrated a lower annual cumulative energy consumption compared to the ground source heat pump system,presenting a reduction of 5.31%compared to the energy consumption of the latter.展开更多
Studying the coupling coordination development of new energy vehicles(NEVs)and the ecological environment in China is helpful in promoting the development of NEVs in the country and is of great significance in promoti...Studying the coupling coordination development of new energy vehicles(NEVs)and the ecological environment in China is helpful in promoting the development of NEVs in the country and is of great significance in promoting high-quality development of new energy in China.This paper constructs an evaluation index system for the development of NEVs and the ecological environment.It uses game theory combining weighting model,particle swarm optimized projection tracking evaluation model,coupling coordination degree model,and machine learning algorithms to calculate and analyze the level of coupling coordination development of NEVs and the ecological environment in China from 2010 to 2021,and identifies the driving factors.The research results show that:(i)From 2010 to 2021,the development index of NEVs in China has steadily increased from 0.085 to 0.634,while the ecological environment level index significantly rose from 0.170 to 0.884,reflecting the continuous development of China in both NEVs and the ecological environment.(ii)From 2010 to 2012,the two systems—new energy vehicle(NEV)development and the ecological environment—were in a period of imbalance and decline.From 2013 to 2016,they underwent a transition period,and from 2017 to 2021,they entered a period of coordinated development showing a trend of benign and continuous improvement.By 2021,they reached a good level of coordination.(iii)Indicators such as the number of patents granted for NEVs,water consumption per unit of GDP,and energy consumption per unit of GDP are the main driving factors affecting the coupling coordination development of NEVs and the ecological environment in China.展开更多
By using a newly developed 4-hydroxy picolinohydrazide as the ligand,Cu-catalyzed coupling of(hetero)aryl chlorides with sodium aryl sulfonates proceeded smoothly at 130℃to give a series of biarylsulfones in 53%~96%y...By using a newly developed 4-hydroxy picolinohydrazide as the ligand,Cu-catalyzed coupling of(hetero)aryl chlorides with sodium aryl sulfonates proceeded smoothly at 130℃to give a series of biarylsulfones in 53%~96%yields.This represents the first metal-catalyzed coupling reaction of(hetero)aryl chlorides with sodium aryl sulfonates.Aryl and heteroaryl chlorides bearing either electron-donating or electron-withdrawing groups were applicable for this coupling reaction.展开更多
Ferroelectric film materials have attracted significant interest due to their potential for harvesting various forms ofclean energy from natural environmental sources.However,the photoelectric performance of these mat...Ferroelectric film materials have attracted significant interest due to their potential for harvesting various forms ofclean energy from natural environmental sources.However,the photoelectric performance of these materials isfrequently constrained by heat generation during light absorption,resulting in significant thermal losses.Most offerroelectric films produce photocurrent and thermocurrent with opposite polarity,thus weakening the coupledphoto-thermoelectric output of the devices.Here we report on a LaNiO_(3)/BiMn_(2)O_(5)(BMO)/ITO ferroelectric film toproduce photocurrent and thermocurrent with the same polarity.The polarity of the photocurrent generated bythe BMO film is shown to be determined solely by the direction of spontaneous polarization,overcoming thedetrimental effect of Schottky barrier for energy harvesting in device.We propose a new strategy to enhance thecoupling factor,thereby offering valuable new insights for optimizing the utilization of ferroelectric materials inboth light and heat energy applications.展开更多
We report a theoretical analysis of magnon–magnon coupling in a noncollinear magnetic sandwiched structure with interlayer exchange interaction,which consists of two ferromagnetic layers with perpendicular and in-pla...We report a theoretical analysis of magnon–magnon coupling in a noncollinear magnetic sandwiched structure with interlayer exchange interaction,which consists of two ferromagnetic layers with perpendicular and in-plane magnetic anisotropy,respectively.Based on the Landau–Lifshitz equation,the spin wave dispersion is derived,and then the frequency gap is observed due to the magnon–magnon coupling effect induced by symmetry breaking.The influence of saturation magnetization,exchange coupling interaction,perpendicular magnetic anisotropy,and wave vector on the coupling strength is studied in detail.We find that the coupling strength is strongly dependent on the saturation magnetization and a small saturation magnetization can lead to strong coupling strength.By selecting the appropriate magnetic materials,the ultra-strong coupling regime can be achieved.The precession information in time domain is solved and the alternating change of the precession components in two ferromagnetic layers implies the exchange of energy and information.展开更多
基金funded by the National Natural Science Foundation of China[52106246]the Postgraduate Research&Practice innovation Program of Jiangsu Province[KYCX24_1641].
文摘Based on the rapid advancements in nanomaterials and nanotechnology,the Nanofluidic Reverse Electrodialysis(NRED)has attracted significant attention as an innovative and promising energy conversion strategy for extracting sustainable and clean energy fromthe salinity gradient energy.However,the scarcity of research investigating the intricate multi-factor coupling effects on the energy conversion performance,especially the trade-offs between ion selectivity and mass transfer in nanochannels,of NRED poses a great challenge to achieving breakthroughs in energy conversion processes.This numerical study innovatively investigates the multi-factor coupling effect of three critical operational factors,including the nanochannel configuration,the temperature field,and the concentration difference,on the energy conversion processes of NRED.In this work,a dimensionless amplitude parameter s is introduced to emulate the randomly varied wall configuration of nanochannels that inherently occur in practical applications,thereby enhancing the realism and applicability of our analysis.Numerical results reveal that the application of a temperature gradient,which is oriented in opposition to the concentration gradient,enhances the ion transportation and selectivity simultaneously,leading to an enhancement in both output power and energy conversion efficiency.Additionally,the increased fluctuation of the nanochannel wall from s=0 to s=0.08 improves ion selectivity yet raises ion transport resistance,resulting in an enhancement in output power and energy conversion efficiency but a slight reduction in current.Furthermore,with increasing the concentration ratio cH/cL from 10 to 1000,either within a fixed temperature field or at a constant dimensionless amplitude,the maximumpower consistently attains its optimal value at a concentration ratio of 100 but the cation transfer number experiences amonotonic decrease across this entire range of concentration ratios.Finally,uponmodifying the operational parameters fromthe baseline condition of s=0,c_(H)/c_(L)=10,andΔT=0 K to the targetedconditionof s=0.08,c_(H)/c_(L)=50,andΔT=25 K,there is a concerted improvement observed in the open-circuit potential,short-circuit current,andmaximumpower,with respective increments of 8.86%,204.97%,and 232.01%,but a reduction in cation transfer number with a notable decrease of 15.37%.
基金the National Key Technology Research and Development Program of China(Nos.2018YFC1900603 and 2018YFC0604604)。
文摘In order to solve the problem of strength instability of cemented tailings backfill(CTB)under low temperature environment(≤20℃),the strength optimization and prediction of CTB under the influence of multiple factors were carried out.The response surface method(RSM)was used to design the experiment to analyze the development law of backfill strength under the coupling effect of curing temperature,sand-cement ratio and slurry mass fraction,and to optimize the mix proportion;the artificial neural network algorithm(ANN)and particle swarm optimization algorithm(PSO)were used to build the prediction model of backfill strength.According to the experimental results of RSM,the optimal mix proportion under different curing temperatures was obtained.When the curing temperature is 10-15℃,the best mix proportion of sand-cement ratio is 9,and the slurry mass fraction is 71%;when the curing temperature is 15-20℃,the best mix proportion of sand-cement ratio is 8,and the slurry mass fraction is 69%.The ANN-PSO intelligent model can accurately predict the strength of CTB,its mean relative estimation error value and correlation coefficient value are only 1.95%and 0.992,and the strength of CTB under different mix proportion can be predicted quickly and accurately by using this model.
基金the National Natural Science Foundation of China (No.51178305)Key Projects in the Science & Technology Pillar Program of Tianjin (No.11ZCKFSF00300)
文摘In order to accurately simulate the diffusion of chloride ion in the existing concrete bridge and acquire the precise chloride ion concentration at given time, a cellular automata （CA）-based model is proposed. The process of chloride ion diffusion is analyzed by the CA-based method and a nonlinear solution of the Fick＇s second law is obtained. Considering the impact of various factors such as stress states, temporal and spatial variability of diffusion parameters and water-cement ratio on the process of chloride ion diffusion, the model of chloride ion diffusion under multi-factor coupling actions is presented. A chloride ion penetrating experiment reported in the literature is used to prove the effectiveness and reasonability of the present method, and a T-type beam is taken as an illustrative example to analyze the process of chloride ion diffusion in practical application. The results indicate that CA-based method can simulate the diffusion of chloride ion in the concrete structures with acceptable precision.
基金co-supported by the National Natural Science Foundation of China (Nos. 61374145 and U1333131)
文摘Heavy-equipment airdrop is a highly risky procedure that has a complicated system due to the secluded and complex nature of factors＇ coupling. As a result, it is difficult to study the modeling and safety simulation of this system. The dynamic model of the heavy-equipment airdrop is based on the Lagrange analytical mechanics, which has all the degrees of freedom and can accurately pinpoint the real-time coordinates and attitude of the carrier with its cargo. Unfavorable conditions accounted in the factors＇ models, including aircraft malfunctions and adverse environments, are established from a man-machine-environment perspective. Subsequently, a virtual simulation system for the safety research of the multi-factor coupling heavy-equipment airdrop is developed through MATLAB/Simulink, C language and Flightgear software. To verify the veracity of the theory, the verification model is built based on dynamic software ADAMS. Finally, the emulation is put to the test with the input of realistic accident variables to ascertain its feasibility and validity of this method.
基金Item Sponsored by Technology Supporting Program During the 11th Five-Year Plan Period(BAE03A07)
文摘Combined with the parameters of the production process of a steel factory, numerical simulations for a new ladle from preheating to turnover are conducted using the finite element analysis system software （ANSYS）. The measured data proved that the simulated results are reliable. The effects of preheating time, thermal cycling times, and empty package time on steel temperature are calculated, an ideal preheating time is provided, besides, based on the analysis of a single factor and use the nonlinear analysis method, a steel temperature compensating model with di- versified coupling factors is proposed, with the largest error of the present coupling model at 1. 462 ~C, and the er- rors between actual and target steel temperature in tundish after the model is applied to practical production are basi- cally controlled within -4-6 ~C, which can meet the accuracy of the manufacturer and has a practical guiding significance for the production in steelmaking workshops.
文摘For space-borne gravitational wave detection missions based on the heterodyne interferometry principle,tilt-to-length(TTL)coupling noise is an important optical noise source,significantly influencing the accuracy of the measurement system.We present a method for analyzing TTL coupling noise under the joint influence of multiple factors.An equivalent simulated optical bench for the test mass interferometer was designed,and Gaussian beam tracing was adopted to simulate beam propagation.By simulating the interference signal,it can analyze the impact of various factors on the TTL coupling noise,including positional,beam parameters,detector parameters,and signal definition factors.On this basis,a random parameter space composed of multiple influential factors was constructed within a range satisfying the analysis requirement,and the corresponding simulation results from random sampling were evaluated via variance-based global sensitivity analysis.The calculated results of the main and total effect indexes show that the test mass rotation angle and the piston effect(lateral)significantly influence the TTL coupling noise in the test mass interferometer.The analysis provides a qualitative reference for designing and optimizing space-borne laser interferometry systems.
基金financially supported by the National Natural Science Foundation of China(Grants nos.62201411,62371378,22205168,52302150 and 62304171)the China Postdoctoral Science Foundation(2022M722500)+1 种基金the Fundamental Research Funds for the Central Universities(Grants nos.ZYTS2308 and 20103237929)Startup Foundation of Xidian University(10251220001).
文摘Defects-rich heterointerfaces integrated with adjustable crystalline phases and atom vacancies,as well as veiled dielectric-responsive character,are instrumental in electromagnetic dissipation.Conventional methods,however,constrain their delicate constructions.Herein,an innovative alternative is proposed:carrageenan-assistant cations-regulated(CACR)strategy,which induces a series of sulfides nanoparticles rooted in situ on the surface of carbon matrix.This unique configuration originates from strategic vacancy formation energy of sulfides and strong sulfides-carbon support interaction,benefiting the delicate construction of defects-rich heterostructures in M_(x)S_(y)/carbon composites(M-CAs).Impressively,these generated sulfur vacancies are firstly found to strengthen electron accumulation/consumption ability at heterointerfaces and,simultaneously,induct local asymmetry of electronic structure to evoke large dipole moment,ultimately leading to polarization coupling,i.e.,defect-type interfacial polarization.Such“Janus effect”(Janus effect means versatility,as in the Greek two-headed Janus)of interfacial sulfur vacancies is intuitively confirmed by both theoretical and experimental investigations for the first time.Consequently,the sulfur vacancies-rich heterostructured Co/Ni-CAs displays broad absorption bandwidth of 6.76 GHz at only 1.8 mm,compared to sulfur vacancies-free CAs without any dielectric response.Harnessing defects-rich heterostructures,this one-pot CACR strategy may steer the design and development of advanced nanomaterials,boosting functionality across diverse application domains beyond electromagnetic response.
基金supported by National Key R&D Program of China(Grant No.2021YFB2601200)Open Fund of National Engineering Research Center of Highway Maintenance Technology(Changsha University of Science&Technology)(No.kfj230207).
文摘The occurrence of top-down(TD)cracking has gradually become a prevalent issue in semi-rigid base asphalt pavements after prolonged service.A coupled simulation model integrating the finite difference method(FDM)and discrete element method(DEM)was employed to investigate the mechanical behavior of asphalt pavement containing a pre-existing TD crack.The mesoscopic parameters of the model were calibrated based on the mixture modulus and the static mechanical response on the MLS66 test road.Finally,an analysis was performed to assess how variations in TD crack depth and longitudinal length affect the distribution patterns of transverse tensile stress,vertical shear stress,and vertical compressive stress.The results indicate that the vertical propagation of TD crack significantly increases both the tensile stress value and range on the middle surface,while the longitudinal development of TD crack has minimal impact.This phenomenon may result in more severe fatigue failure on the middle surface.With the vertical and longitudinal development of TD crack,the vertical shear stress and compressive stress show obvious"two-stage"characteristics.When the crack's vertical length reaches 40 mm,there is a sharp increase in stress on the upper surface.As the crack continues to propagate vertically,the growth of stress on the upper surface becomes negligible,while the stress in the middle and lower layers increased significantly.Conversely,for longitudinal development of TD crack,any changes in stress are insignificant when their length is less than 180 mm;however,as they continue to develop longitudinally beyond this threshold,there is a sharp increase in stress levels.These findings hold great significance for understanding pavement structure deterioration and maintenance behavior associated with TD crack.
基金National Natural Science Foundation of China (U23A6005 and 22078069)Project funded by China Postdoctoral Science Foundation (GZB20230172 and 2023M740748)。
文摘Electrochemical conversion of lignin for the production of high-value heterocyclic aromatic compounds has great potential.We demonstrate the targeted synthesis and cation modulation of NiCo_(2)O_(4)spinel nanoboxes,synthesized via cation exchange and calcination oxidation.These catalysts exhibit excellent efficacy in the electrocatalytic conversion of lignin model compounds,specifically 2-phenoxy-1-phenylethanol,into nitrogen-containing aromatics,achieving high conversion rates and selectivities.These catalysts were synthesized via a cation exchange and calcination oxidation process,using Prussian blue nanocubes as precursors.The porous architecture and polymetallic composition of the NiCo_(2)O_(4)spinel demonstrated superior performance in electrocatalytic oxidative coupling,achieving a 99.2 wt%conversion rate of the 2-phenoxy-1-phenylethanol with selectivities of 37.5 wt%for quinoline derivatives and 31.5 wt%for phenol.Key innovations include the development of a sustainable one-pot synthesis method for quinoline derivatives,the elucidation of a multistage reaction pathway involving CAO bond cleavage,hydroxyaldol condensation,and CAN bond formation,and a deeper mechanistic understanding derived from DFT simulations.This work establishes a new strategy for lignin valorization,offering a sustainable route to produce high-value nitrogen-containing aromatics from renewable biomass under mild conditions,without the need for additional reagents.
基金financially supported by the National Natural Science Foundation of China(Nos.42272153 and 42472195)the Research Fund of PetroChina Tarim Oilfield Company(No.671023060003)the Research Fund of China National Petroleum Corporation Limited(No.2023ZZ16YJ04).
文摘Deep tight reservoirs exhibit complex stress and seepage fields due to varying pore structures,thus the seepage characteristics are significant for enhancing oil production.This study conducted triaxial compression and permeability tests to investigate the mechanical and seepage properties of tight sandstone.A digital core of tight sandstone was built using Computed Tomography(CT)scanning,which was divided into matrix and pore phases by a pore equivalent diameter threshold.A fluid-solid coupling model was established to investigate the seepage characteristics at micro-scale.The results showed that increasing the confining pressure decreased porosity,permeability,and flow velocity,with the pore phase becoming the dominant seepage channel.Cracks and large pores closed first under increasing pressure,resulted in a steep drop in permeability.However,permeability slightly decreased under high confining pressure,which followed a first-order exponential function.Flow velocity increased with seepage pressure.And the damage mainly occurred in stress-concentration regions under low seepage pressure.Seepage behavior followed linear Darcy flow,the damage emerged at seepage entrances under high pressure,which decreased rock elastic modulus and significantly increased permeability.
基金support from Guangdong Science and Technology(20230505)Guangdong Provincial Philosophy and Social Science Planning Project(GD20SQ25)Guangdong Provincial Special Fund for Science and Technology Innovation Strategy in 2024(Cultivation of College Students’Science and Technology Innovation)(pdjh2024a391)during preparation of this manuscript.
文摘This study investigates the coordination between regional economic growth and ecological sustainability within the context of high-quality town economy development.To address the challenges of balancing economic expansion with environmental protection,a comprehensive evaluation index system is constructed,encompassing two key dimensions:regional economy and ecological environment.Using panel data from 2013 to 2022,the coupling coordination degree model is employed to quantify the interactions and synergy between these dimensions.Additionally,spatial econometric methods are applied to calculate both global and local Moran’s Index,revealing spatial clustering patterns,regional disparities,and heterogeneity.The relative development model further identifies critical factors influencing regional coordination,with a focus on the lagging development of basic infrastructure and public services.The findings demonstrate a positive temporal trend toward improved regional coordination and reduced development gaps,with a spatial pattern characterized by higher coupling degrees in eastern and central regions compared to western areas.Based on these results,this study proposes actionable strategies to enhance coordinated development,emphasizing ecological conservation,the establishment of green production and consumption systems,ecological restoration,and strengthened municipal collaboration.This revised abstract emphasizes the study’s purpose,methods,and key findings more clearly while maintaining a professional and concise tone.Finally,based on the above analysis results,the corresponding coordinated development suggestions of regional economy and ecological environment are given from the aspects of ecological environment protection measures,green production and consumption system construction,ecological environment restoration and municipal coordination.
基金Financial supports from the National Natural Science Foundation of China(Nos.52171116,U22A20109,52334010 and T2325013)are greatly acknowledgedPartial financial support came from The Program for the Central University Youth Innovation Team,and the Fundamental Research Funds for the Central Universities,JLU.
文摘Dislocations and disclinations are fundamental topological defects within crystals,which determine the mechanical properties of metals and alloys.Despite their important roles in multiple physical mechanisms,e.g.,dynamic recovery and grain boundary mediated plasticity,the intrinsic coupling and correlation between disclinations and dislocations,and their impacts on the deformation behavior of metallic materials still remain obscure,partially due to the lack of a theoretical tool to capture the rotational nature of disclinations.By using a Lie-algebra-based theoretical framework,we obtain a general equation to quantify the intrinsic coupling of disclinations and dislocations.Through quasi in-situ electron backscatter diffraction characterizations and disclination/dislocation density analyses in Mg alloys,the generation,coevolution and reactions of disclinations and dislocations during dynamic recovery and superplastic deformation have been quantitatively analyzed.It has been demonstrated that the obtained governing equation can capture multiple physical processes associated with mechanical deformation of metals,e.g.,grain rotation and grain boundary migration,at both room temperature and high temperature.By establishing the disclination-dislocation coupling equation within a Lie algebra description,our work provides new insights for exploring the coevolution and reaction of disclinations/dislocations,with profound implications for elucidating the microstructure-property relationship and underlying deformation mechanisms in metallic materials.
基金supported by the financial aid from the National Natural Science Foundation of China (No. 22271273)International Partnership Program of Chinese Academy of Sciences (No. 121522KYSB20190022)。
文摘Self-trapping excitons(STEs) emission in metal halides has been a matter of interest, correlating with the strength of electron-phonon coupling in the lattice, which are usually caused by ions with ns~2 electronic structure. In this work, Sb^(3+)/Te^(4+)ions doped Zn-based halide single crystals(SCs) with two STEs emissions have been synthesized and the possibility of its anti-counterfeiting application was explored.Further, the relationship between the strength of electron-phonon coupling and photoluminescence quantum yields(PLQYs) for STEs in a series of metal halides has been studied. And the semi-empirical range of the Huang-Rhys factors(S) for metal halides with excellent photoluminescence(PL) property has been summarized. This work provides ideas for further research into the relationship between luminescence performance and electron-phonon coupling of metal halides, and also provides a reference for designing the metal halides with high PLQYs.
基金the support provided by the National Natural Science Foundation of China(Grant Nos.52278336 and 42302032)Guangdong Basic and Applied Research Foundation(Grant Nos.2023B1515020061).
文摘Granite residual soil (GRS) is a type of weathering soil that can decompose upon contact with water, potentially causing geological hazards. In this study, cement, an alkaline solution, and glass fiber were used to reinforce GRS. The effects of cement content and SiO_(2)/Na2O ratio of the alkaline solution on the static and dynamic strengths of GRS were discussed. Microscopically, the reinforcement mechanism and coupling effect were examined using X-ray diffraction (XRD), micro-computed tomography (micro-CT), and scanning electron microscopy (SEM). The results indicated that the addition of 2% cement and an alkaline solution with an SiO_(2)/Na2O ratio of 0.5 led to the densest matrix, lowest porosity, and highest static compressive strength, which was 4994 kPa with a dynamic impact resistance of 75.4 kN after adding glass fiber. The compressive strength and dynamic impact resistance were a result of the coupling effect of cement hydration, a pozzolanic reaction of clay minerals in the GRS, and the alkali activation of clay minerals. Excessive cement addition or an excessively high SiO_(2)/Na2O ratio in the alkaline solution can have negative effects, such as the destruction of C-(A)-S-H gels by the alkaline solution and hindering the production of N-A-S-H gels. This can result in damage to the matrix of reinforced GRS, leading to a decrease in both static and dynamic strengths. This study suggests that further research is required to gain a more precise understanding of the effects of this mixture in terms of reducing our carbon footprint and optimizing its properties. The findings indicate that cement and alkaline solution are appropriate for GRS and that the reinforced GRS can be used for high-strength foundation and embankment construction. The study provides an analysis of strategies for mitigating and managing GRS slope failures, as well as enhancing roadbed performance.
基金supported by the National Key R&D Program of China(No.2021YFB2011300)the National Natural Science Foundation of China(Nos.52275044,U2233212)。
文摘The Electro–Hydrostatic Actuator(EHA)is applied to drive the control surface in flightcontrol system of more electric aircraft.In EHA,the Oil-Immersed Motor Pump(OMP)serves asthe core as a power assembly.However,the compact integration of the OMP presents challenges inefficiently dissipating internal heat,leading to a performance degradation of the EHA due to ele-vated temperatures.Therefore,accurately modeling and predicting the internal thermal dynamicsof the OMP hold considerable significance for monitoring the operational condition of the EHA.In view of this,a modeling method considering cumulative thermal coupling was hereby proposed.Based on the proposed method,the thermal models of the motor and the pump were established,taking into account heat accumulation and transfer.Taking the leakage oil as the heat couplingpoint between the motor and the pump,the dynamic thermal coupling model of the OMP wasdeveloped,with the thermal characteristics of the oil considered.Additionally,the comparativeexperiments were conducted to illustrate the efficiency of the proposed model.The experimentalresults demonstrate that the proposed dynamic thermal coupling model accurately captured thethermal behavior of OMP,outperforming the static thermal parameter model.Overall,thisadvancement is crucial for effectively monitoring the health of EHA and ensuring flight safety.
基金supported by 2024 Central Guidance Local Science and Technology Development Fund Project"Study on the mechanism and evaluation method of thermal pollution in water bodies,as well as research on thermal carrying capacity".(Grant 246Z4506G)Key Research and Development Project in Hebei Province:"Key Technologies and Equipment Research and Demonstration of Multiple Energy Complementary(Electricity,Heat,Cold System)for Solar Energy,Geothermal Energy,Phase Change Energy"(Grant 236Z4310G)the Hebei Academy of Sciences Key Research and Development Program"Research on Heat Transfer Mechanisms and Efficient Applications of Intermediate and Deep Geothermal Energy"(22702)。
文摘Ground source heat pump systems demonstrate significant potential for northern rural heating applications;however,the effectiveness of these systems is often limited by challenging geological conditions.For instance,in certain regions,the installation of buried pipes for heat exchangers may be complicated,and these pipes may not always serve as efficient low-temperature heat sources for the heat pumps of the system.To address this issue,the current study explored the use of solar-energy-collecting equipment to supplement buried pipes.In this design,both solar energy and geothermal energy provide low-temperature heat to the heat pump.First,a simulation model of a solar‒ground source heat pump coupling system was established using TRNSYS.The accuracy of this model was validated through experiments and simulations on various system configurations,including varying numbers of buried pipes,different areas of solar collectors,and varying volumes of water tanks.The simulations examined the coupling characteristics of these components and their influence on system performance.The results revealed that the operating parameters of the system remained consistent across the following configurations:three buried pipes,burial depth of 20 m,collector area of 6 m^(2),and water tank volume of 0.5 m^(3);four buried pipes,burial depth of 20 m,collector area of 3 m^(2),and water tank volume of 0.5 m^(3);and five buried pipes with a burial depth of 20 m.Furthermore,the heat collection capacity of the solar collectors spanning an area of 3 m^(2)was found to be equivalent to that of one buried pipe.Moreover,the findings revealed that the solar‒ground source heat pump coupling system demonstrated a lower annual cumulative energy consumption compared to the ground source heat pump system,presenting a reduction of 5.31%compared to the energy consumption of the latter.
基金Supported by the Postgraduate Research&Practice Innovation Program of Jiangsu Province(KYCX24_0102)the China Scholarship Council Program(202406190114)。
文摘Studying the coupling coordination development of new energy vehicles(NEVs)and the ecological environment in China is helpful in promoting the development of NEVs in the country and is of great significance in promoting high-quality development of new energy in China.This paper constructs an evaluation index system for the development of NEVs and the ecological environment.It uses game theory combining weighting model,particle swarm optimized projection tracking evaluation model,coupling coordination degree model,and machine learning algorithms to calculate and analyze the level of coupling coordination development of NEVs and the ecological environment in China from 2010 to 2021,and identifies the driving factors.The research results show that:(i)From 2010 to 2021,the development index of NEVs in China has steadily increased from 0.085 to 0.634,while the ecological environment level index significantly rose from 0.170 to 0.884,reflecting the continuous development of China in both NEVs and the ecological environment.(ii)From 2010 to 2012,the two systems—new energy vehicle(NEV)development and the ecological environment—were in a period of imbalance and decline.From 2013 to 2016,they underwent a transition period,and from 2017 to 2021,they entered a period of coordinated development showing a trend of benign and continuous improvement.By 2021,they reached a good level of coordination.(iii)Indicators such as the number of patents granted for NEVs,water consumption per unit of GDP,and energy consumption per unit of GDP are the main driving factors affecting the coupling coordination development of NEVs and the ecological environment in China.
文摘By using a newly developed 4-hydroxy picolinohydrazide as the ligand,Cu-catalyzed coupling of(hetero)aryl chlorides with sodium aryl sulfonates proceeded smoothly at 130℃to give a series of biarylsulfones in 53%~96%yields.This represents the first metal-catalyzed coupling reaction of(hetero)aryl chlorides with sodium aryl sulfonates.Aryl and heteroaryl chlorides bearing either electron-donating or electron-withdrawing groups were applicable for this coupling reaction.
基金supported by the National Natural Science Foundation of China(grant no.52072041)the Beijing Natural Science Foundation(grant no.JQ21007).
文摘Ferroelectric film materials have attracted significant interest due to their potential for harvesting various forms ofclean energy from natural environmental sources.However,the photoelectric performance of these materials isfrequently constrained by heat generation during light absorption,resulting in significant thermal losses.Most offerroelectric films produce photocurrent and thermocurrent with opposite polarity,thus weakening the coupledphoto-thermoelectric output of the devices.Here we report on a LaNiO_(3)/BiMn_(2)O_(5)(BMO)/ITO ferroelectric film toproduce photocurrent and thermocurrent with the same polarity.The polarity of the photocurrent generated bythe BMO film is shown to be determined solely by the direction of spontaneous polarization,overcoming thedetrimental effect of Schottky barrier for energy harvesting in device.We propose a new strategy to enhance thecoupling factor,thereby offering valuable new insights for optimizing the utilization of ferroelectric materials inboth light and heat energy applications.
基金supported by the National Natural Science Foundation of China(Grant No.52201290)the Natural Science Foundation of Gansu Province(Grant No.24JRRA402)the 9th Research Institute of China Electronics Technology Group Corporation’s open projects(Grant No.2024SK-001-4).
文摘We report a theoretical analysis of magnon–magnon coupling in a noncollinear magnetic sandwiched structure with interlayer exchange interaction,which consists of two ferromagnetic layers with perpendicular and in-plane magnetic anisotropy,respectively.Based on the Landau–Lifshitz equation,the spin wave dispersion is derived,and then the frequency gap is observed due to the magnon–magnon coupling effect induced by symmetry breaking.The influence of saturation magnetization,exchange coupling interaction,perpendicular magnetic anisotropy,and wave vector on the coupling strength is studied in detail.We find that the coupling strength is strongly dependent on the saturation magnetization and a small saturation magnetization can lead to strong coupling strength.By selecting the appropriate magnetic materials,the ultra-strong coupling regime can be achieved.The precession information in time domain is solved and the alternating change of the precession components in two ferromagnetic layers implies the exchange of energy and information.
