Electrocatalytic reduction of CO_(2) converts intermittent renewable electricity into value-added liquid products with an enticing prospect,but its practical application is hampered due to the lack of high-performance...Electrocatalytic reduction of CO_(2) converts intermittent renewable electricity into value-added liquid products with an enticing prospect,but its practical application is hampered due to the lack of high-performance electrocatalysts.Herein,we elaborately design and develop strongly coupled nanosheets composed of Ag nanoparticles and Sn-SnO_(2) grains,designated as Ag/Sn-SnO_(2) nanosheets(NSs),which possess optimized electronic structure,high electrical conductivity,and more accessible sites.As a result,such a catalyst exhibits unprecedented catalytic performance toward CO_(2)-to-formate conversion with near-unity faradaic efficiency(≥90%),ultrahigh partial current density(2,000 mA cm^(−2)),and superior long-term stability(200 mA cm^(−2),200 h),surpassing the reported catalysts of CO_(2) electroreduction to formate.Additionally,in situ attenuated total reflection-infrared spectra combined with theoretical calculations revealed that electron-enriched Sn sites on Ag/Sn-SnO_(2)NSs not only promote the formation of*OCHO and alleviate the energy barriers of*OCHO to*HCOOH,but also impede the desorption of H*.Notably,the Ag/Sn-SnO_(2)NSs as the cathode in a membrane electrode assembly with porous solid electrolyte layer reactor can continuously produce~0.12 M pure HCOOH solution at 100 mA cm^(−2)over 200 h.This work may inspire further development of advanced electrocatalysts and innovative device systems for promoting practical application of producing liquid fuels from CO_(2).展开更多
Based on the rapid advancements in nanomaterials and nanotechnology,the Nanofluidic Reverse Electrodialysis(NRED)has attracted significant attention as an innovative and promising energy conversion strategy for extrac...Based on the rapid advancements in nanomaterials and nanotechnology,the Nanofluidic Reverse Electrodialysis(NRED)has attracted significant attention as an innovative and promising energy conversion strategy for extracting sustainable and clean energy fromthe salinity gradient energy.However,the scarcity of research investigating the intricate multi-factor coupling effects on the energy conversion performance,especially the trade-offs between ion selectivity and mass transfer in nanochannels,of NRED poses a great challenge to achieving breakthroughs in energy conversion processes.This numerical study innovatively investigates the multi-factor coupling effect of three critical operational factors,including the nanochannel configuration,the temperature field,and the concentration difference,on the energy conversion processes of NRED.In this work,a dimensionless amplitude parameter s is introduced to emulate the randomly varied wall configuration of nanochannels that inherently occur in practical applications,thereby enhancing the realism and applicability of our analysis.Numerical results reveal that the application of a temperature gradient,which is oriented in opposition to the concentration gradient,enhances the ion transportation and selectivity simultaneously,leading to an enhancement in both output power and energy conversion efficiency.Additionally,the increased fluctuation of the nanochannel wall from s=0 to s=0.08 improves ion selectivity yet raises ion transport resistance,resulting in an enhancement in output power and energy conversion efficiency but a slight reduction in current.Furthermore,with increasing the concentration ratio cH/cL from 10 to 1000,either within a fixed temperature field or at a constant dimensionless amplitude,the maximumpower consistently attains its optimal value at a concentration ratio of 100 but the cation transfer number experiences amonotonic decrease across this entire range of concentration ratios.Finally,uponmodifying the operational parameters fromthe baseline condition of s=0,c_(H)/c_(L)=10,andΔT=0 K to the targetedconditionof s=0.08,c_(H)/c_(L)=50,andΔT=25 K,there is a concerted improvement observed in the open-circuit potential,short-circuit current,andmaximumpower,with respective increments of 8.86%,204.97%,and 232.01%,but a reduction in cation transfer number with a notable decrease of 15.37%.展开更多
The aging characteristics of lithium-ion battery(LIB)under fast charging is investigated based on an electrochemical-thermal-mechanical(ETM)coupling model.Firstly,the ETM coupling model is established by COMSOL Multip...The aging characteristics of lithium-ion battery(LIB)under fast charging is investigated based on an electrochemical-thermal-mechanical(ETM)coupling model.Firstly,the ETM coupling model is established by COMSOL Multiphysics.Subsequently,a long cycle test was conducted to explore the aging characteristics of LIB.Specifically,the effects of charging(C)rate and cycle number on battery aging are analyzed in terms of nonuniform distribution of solid electrolyte interface(SEI),SEI formation,thermal stability and stress characteristics.The results indicate that the increases in C rate and cycling led to an increase in the degree of nonuniform distribution of SEI,and thus a consequent increase in the capacity loss due to the SEI formation.Meanwhile,the increases in C rate and cycle number also led to an increase in the heat generation and a decrease in the heat dissipation rate of the battery,respectively,which result in a decrease in the thermal stability of the electrode materials.In addition,the von Mises stress of the positive electrode material is higher than that of the negative electrode material as the cycling proceeds,with the positive electrode material exhibiting tensile deformation and the negative electrode material exhibiting compressive deformation.The available lithium ion concentration of the positive electrode is lower than that of the negative electrode,proving that the tensile-type fracture occurring in the positive material under long cycling dominated the capacity loss process.The aforementioned studies are helpful for researchers to further explore the aging behavior of LIB under fast charging and take corresponding preventive measures.展开更多
In order to accurately simulate the diffusion of chloride ion in the existing concrete bridge and acquire the precise chloride ion concentration at given time, a cellular automata （CA）-based model is proposed. The p...In order to accurately simulate the diffusion of chloride ion in the existing concrete bridge and acquire the precise chloride ion concentration at given time, a cellular automata （CA）-based model is proposed. The process of chloride ion diffusion is analyzed by the CA-based method and a nonlinear solution of the Fick＇s second law is obtained. Considering the impact of various factors such as stress states, temporal and spatial variability of diffusion parameters and water-cement ratio on the process of chloride ion diffusion, the model of chloride ion diffusion under multi-factor coupling actions is presented. A chloride ion penetrating experiment reported in the literature is used to prove the effectiveness and reasonability of the present method, and a T-type beam is taken as an illustrative example to analyze the process of chloride ion diffusion in practical application. The results indicate that CA-based method can simulate the diffusion of chloride ion in the concrete structures with acceptable precision.展开更多
Heavy-equipment airdrop is a highly risky procedure that has a complicated system due to the secluded and complex nature of factors＇ coupling. As a result, it is difficult to study the modeling and safety simulation ...Heavy-equipment airdrop is a highly risky procedure that has a complicated system due to the secluded and complex nature of factors＇ coupling. As a result, it is difficult to study the modeling and safety simulation of this system. The dynamic model of the heavy-equipment airdrop is based on the Lagrange analytical mechanics, which has all the degrees of freedom and can accurately pinpoint the real-time coordinates and attitude of the carrier with its cargo. Unfavorable conditions accounted in the factors＇ models, including aircraft malfunctions and adverse environments, are established from a man-machine-environment perspective. Subsequently, a virtual simulation system for the safety research of the multi-factor coupling heavy-equipment airdrop is developed through MATLAB/Simulink, C language and Flightgear software. To verify the veracity of the theory, the verification model is built based on dynamic software ADAMS. Finally, the emulation is put to the test with the input of realistic accident variables to ascertain its feasibility and validity of this method.展开更多
We evaluated the potential use of amino silane coupling agent （SiNH） to improve physical and mechanical properties of UF-bonded wheat straw （Triticurn aestivum L.） poplar wood particleboard. We examined the effect...We evaluated the potential use of amino silane coupling agent （SiNH） to improve physical and mechanical properties of UF-bonded wheat straw （Triticurn aestivum L.） poplar wood particleboard. We examined the effects of varied content of silane coupling agent content and ratios of straw to poplar wood particles on particleboard prop- erties. The ratios of straw to poplar wood particles were 100：0, 85：15, 70：30 and 55：45. Silane coupling agent content was tested at three levels, 0, 5 and 10 %. The experimental panels were tested for their mechanical strength, including modulus of elasticity （MOE）, modulus of rupture （MOR）, intemal bonding （IB） and physical properties according to procedures specified in DIN 68763 （Chipboard for special purposes in building construction： concepts, requirements, testing, 1982-03, 1982）. All board properties were improved by the addition of silane cou- pling agent. The use of poplar wood particles had a positive effect on the mechanical properties of wheat straw parti- cleboard but had a negative effect on physical properties （thickness swelling and water absorption）.展开更多
The TiO_(2)nano-materials could only exert its bactericide effects under illumination.In order to develop new disinfectants which could also kill germs in the dark circumstances,e.g.,in the rooms and in the pipeline s...The TiO_(2)nano-materials could only exert its bactericide effects under illumination.In order to develop new disinfectants which could also kill germs in the dark circumstances,e.g.,in the rooms and in the pipeline systems,we coupled both Ag and TiO2 nano-particles and covered them on SiO2 bases.Three kinds of bacterials,i.e.,Colibacillus,Staphylococus Aureous and Pseudomonas Aeruginosa,were choosen as our target badteria.Then,they were interacted with different nano-materials and their survival rates were determined.It was found that the Ag coupled TiO2 nano-material could exert strong bactericide effects under both illumination and dark environment.By ESR mearsurement,the mechanism of sterilization was discuussed.展开更多
Fresh Pd/CeO/AlOclose coupled catalyst was prepared by the stepwise impregnation method and calcined at 550 °C for 3 h, which was then pretreated at 700, 800, and 900 °C for 3 h, respectively. Finally, these...Fresh Pd/CeO/AlOclose coupled catalyst was prepared by the stepwise impregnation method and calcined at 550 °C for 3 h, which was then pretreated at 700, 800, and 900 °C for 3 h, respectively. Finally, these pretreated catalysts were aged at 1000 °C for 3 h to study their anti-aging properties. The catalytic activities of the catalysts were investigated detailedly, and the results showed that the catalyst pretreated at 800 °C before aging treatment possessed the best anti-aging performance for CHoxidation. XRD and XPS results indicated that well-crystallized CeOparticles were formed during calcinations at 800 °C, which made CeOan effective promoter. HRTEM revealed that Pd particles found on the edge of CeOover the aged catalyst pretreated at 800 °C were relatively smaller than those over the catalysts without pretreatment. H-TPR and XPS results also implied that the interaction between well-crystallized CeOand Pd suppressed the deactivation of PdO sites and further enhanced the catalytic performance.展开更多
In order to solve the problem of strength instability of cemented tailings backfill(CTB)under low temperature environment(≤20℃),the strength optimization and prediction of CTB under the influence of multiple factors...In order to solve the problem of strength instability of cemented tailings backfill(CTB)under low temperature environment(≤20℃),the strength optimization and prediction of CTB under the influence of multiple factors were carried out.The response surface method(RSM)was used to design the experiment to analyze the development law of backfill strength under the coupling effect of curing temperature,sand-cement ratio and slurry mass fraction,and to optimize the mix proportion;the artificial neural network algorithm(ANN)and particle swarm optimization algorithm(PSO)were used to build the prediction model of backfill strength.According to the experimental results of RSM,the optimal mix proportion under different curing temperatures was obtained.When the curing temperature is 10-15℃,the best mix proportion of sand-cement ratio is 9,and the slurry mass fraction is 71%;when the curing temperature is 15-20℃,the best mix proportion of sand-cement ratio is 8,and the slurry mass fraction is 69%.The ANN-PSO intelligent model can accurately predict the strength of CTB,its mean relative estimation error value and correlation coefficient value are only 1.95%and 0.992,and the strength of CTB under different mix proportion can be predicted quickly and accurately by using this model.展开更多
We perform a scanning tunneling microscopy and spectroscopy study on the electronic structures of √3×√3- silicene on Ag（111）. It is found that the coupling strength of √3×√3-silicene with the Ag-（111...We perform a scanning tunneling microscopy and spectroscopy study on the electronic structures of √3×√3- silicene on Ag（111）. It is found that the coupling strength of √3×√3-silicene with the Ag-（111） substrate is variable in different regions, giving rise to notable effects in experiments. This evidence of decoupling or variable interaction of silicene with the substrate is helpful to in-depth understanding of the structure and clectronic properties of silieene.展开更多
Carbon capture,utilization,and storage(CCUS)represents a critical technological pathway for global car-bon emission reduction.CCUS-enhanced oil recovery(EOR)technology is the most feasible CCUS technol-ogy demonstrati...Carbon capture,utilization,and storage(CCUS)represents a critical technological pathway for global car-bon emission reduction.CCUS-enhanced oil recovery(EOR)technology is the most feasible CCUS technol-ogy demonstrating dual benefits of enhanced energy production and carbon reduction.This study comprehensively described the key influencing factors governing CO_(2)-EOR and geological storage and systematically analyzed reservoir properties,fluid characteristics,and operational parameters.The mech-anisms of these parameters on EOR versus CO_(2) storage performance were investigated throughout CCUS-EOR processes.This paper proposes a coupled two-stage CCUS-EOR process:CO_(2)-EOR storage stage and long-term CO_(2) storage stage after the CO_(2) injection phase is completed.In each stage,the main control factors impacting the CO_(2)-EOR and storage stages are screened and coupled with rigorous technical anal-ysis.The key factors here are reservoir properties,fluid characteristics,and operational parameter.A novel CCUS-EOR synergistic method was proposed to optimize the lifecycle performance of dual objective of EOR and storage.Furthermore,based on multi-objective optimization,considering the lifecycle,a multi-scale techno-economic evaluation method was proposed to fully assess the CCUS-EOR project per-formance.Finally,a set of recommendations for advancing CCUS-EOR technologies by deploying multi-factor/multi-field coupling methodologies,novel green intelligent injection materials,and artificial intel-ligence/machine learning technologies were visited.展开更多
Steam turbine generators frequently experience deep peak shaving conditions,in which the performance of insulation is significantlyimpacted by extreme fluctuationsin operating temperature.The degradation of water-inte...Steam turbine generators frequently experience deep peak shaving conditions,in which the performance of insulation is significantlyimpacted by extreme fluctuationsin operating temperature.The degradation of water-internally cooled stator bar insulation under repeated temperature variations is investigated in this study.This study examines the progression of winding insulation characteristics by Frequency Domain Spectroscopy(FDS)test and electro-thermal-hydraulic coupled simulations throughout various thermal ageing cycles.Accelerated thermal ageing experiments are conducted on stator bar specimens.Dielectric parameters are captured by FDS across various thermal ageing cycles to assess the effect of thermal ageing on the electrical properties of primary insulation materials.A stator bar model rated at 22 kV is constructed.Electro-thermal-fluidmultiphysics simulations based on the Finite Element Method are performed to compare and analyze electric fieldstrength and temperature distribution under different thermal ageing cycles.Experimental results demonstrate that dielectric properties of the main insulation material deteriorate as thermal ageing progresses,leading to gradual insulation performance degradation.Simulation analysis indicates that the resulting insulation decline increases surface electric fieldsand temperatures on the stator bar,accelerating thermal aging and establishing a positive feedback mechanism.These findingssupport optimised design of the stator bar's anti-corona structure to delay insulation aging,offering a theoretical basis for insulation design optimization and equipment lifespan extension in steam turbine generators.展开更多
基金the National Science Fund for Distinguished Young Scholars(Grant No.52125103)the National Natural Science Foundation of China(Grant Nos.52301232,52071041,12074048,and 12147102)China Postdoctoral Science Foundation(Grant No.2022M720552).
文摘Electrocatalytic reduction of CO_(2) converts intermittent renewable electricity into value-added liquid products with an enticing prospect,but its practical application is hampered due to the lack of high-performance electrocatalysts.Herein,we elaborately design and develop strongly coupled nanosheets composed of Ag nanoparticles and Sn-SnO_(2) grains,designated as Ag/Sn-SnO_(2) nanosheets(NSs),which possess optimized electronic structure,high electrical conductivity,and more accessible sites.As a result,such a catalyst exhibits unprecedented catalytic performance toward CO_(2)-to-formate conversion with near-unity faradaic efficiency(≥90%),ultrahigh partial current density(2,000 mA cm^(−2)),and superior long-term stability(200 mA cm^(−2),200 h),surpassing the reported catalysts of CO_(2) electroreduction to formate.Additionally,in situ attenuated total reflection-infrared spectra combined with theoretical calculations revealed that electron-enriched Sn sites on Ag/Sn-SnO_(2)NSs not only promote the formation of*OCHO and alleviate the energy barriers of*OCHO to*HCOOH,but also impede the desorption of H*.Notably,the Ag/Sn-SnO_(2)NSs as the cathode in a membrane electrode assembly with porous solid electrolyte layer reactor can continuously produce~0.12 M pure HCOOH solution at 100 mA cm^(−2)over 200 h.This work may inspire further development of advanced electrocatalysts and innovative device systems for promoting practical application of producing liquid fuels from CO_(2).
基金funded by the National Natural Science Foundation of China[52106246]the Postgraduate Research&Practice innovation Program of Jiangsu Province[KYCX24_1641].
文摘Based on the rapid advancements in nanomaterials and nanotechnology,the Nanofluidic Reverse Electrodialysis(NRED)has attracted significant attention as an innovative and promising energy conversion strategy for extracting sustainable and clean energy fromthe salinity gradient energy.However,the scarcity of research investigating the intricate multi-factor coupling effects on the energy conversion performance,especially the trade-offs between ion selectivity and mass transfer in nanochannels,of NRED poses a great challenge to achieving breakthroughs in energy conversion processes.This numerical study innovatively investigates the multi-factor coupling effect of three critical operational factors,including the nanochannel configuration,the temperature field,and the concentration difference,on the energy conversion processes of NRED.In this work,a dimensionless amplitude parameter s is introduced to emulate the randomly varied wall configuration of nanochannels that inherently occur in practical applications,thereby enhancing the realism and applicability of our analysis.Numerical results reveal that the application of a temperature gradient,which is oriented in opposition to the concentration gradient,enhances the ion transportation and selectivity simultaneously,leading to an enhancement in both output power and energy conversion efficiency.Additionally,the increased fluctuation of the nanochannel wall from s=0 to s=0.08 improves ion selectivity yet raises ion transport resistance,resulting in an enhancement in output power and energy conversion efficiency but a slight reduction in current.Furthermore,with increasing the concentration ratio cH/cL from 10 to 1000,either within a fixed temperature field or at a constant dimensionless amplitude,the maximumpower consistently attains its optimal value at a concentration ratio of 100 but the cation transfer number experiences amonotonic decrease across this entire range of concentration ratios.Finally,uponmodifying the operational parameters fromthe baseline condition of s=0,c_(H)/c_(L)=10,andΔT=0 K to the targetedconditionof s=0.08,c_(H)/c_(L)=50,andΔT=25 K,there is a concerted improvement observed in the open-circuit potential,short-circuit current,andmaximumpower,with respective increments of 8.86%,204.97%,and 232.01%,but a reduction in cation transfer number with a notable decrease of 15.37%.
基金funded by the National Natural Science Foundation of China(Grant No.12272217)。
文摘The aging characteristics of lithium-ion battery(LIB)under fast charging is investigated based on an electrochemical-thermal-mechanical(ETM)coupling model.Firstly,the ETM coupling model is established by COMSOL Multiphysics.Subsequently,a long cycle test was conducted to explore the aging characteristics of LIB.Specifically,the effects of charging(C)rate and cycle number on battery aging are analyzed in terms of nonuniform distribution of solid electrolyte interface(SEI),SEI formation,thermal stability and stress characteristics.The results indicate that the increases in C rate and cycling led to an increase in the degree of nonuniform distribution of SEI,and thus a consequent increase in the capacity loss due to the SEI formation.Meanwhile,the increases in C rate and cycle number also led to an increase in the heat generation and a decrease in the heat dissipation rate of the battery,respectively,which result in a decrease in the thermal stability of the electrode materials.In addition,the von Mises stress of the positive electrode material is higher than that of the negative electrode material as the cycling proceeds,with the positive electrode material exhibiting tensile deformation and the negative electrode material exhibiting compressive deformation.The available lithium ion concentration of the positive electrode is lower than that of the negative electrode,proving that the tensile-type fracture occurring in the positive material under long cycling dominated the capacity loss process.The aforementioned studies are helpful for researchers to further explore the aging behavior of LIB under fast charging and take corresponding preventive measures.
基金the National Natural Science Foundation of China (No.51178305)Key Projects in the Science & Technology Pillar Program of Tianjin (No.11ZCKFSF00300)
文摘In order to accurately simulate the diffusion of chloride ion in the existing concrete bridge and acquire the precise chloride ion concentration at given time, a cellular automata （CA）-based model is proposed. The process of chloride ion diffusion is analyzed by the CA-based method and a nonlinear solution of the Fick＇s second law is obtained. Considering the impact of various factors such as stress states, temporal and spatial variability of diffusion parameters and water-cement ratio on the process of chloride ion diffusion, the model of chloride ion diffusion under multi-factor coupling actions is presented. A chloride ion penetrating experiment reported in the literature is used to prove the effectiveness and reasonability of the present method, and a T-type beam is taken as an illustrative example to analyze the process of chloride ion diffusion in practical application. The results indicate that CA-based method can simulate the diffusion of chloride ion in the concrete structures with acceptable precision.
基金co-supported by the National Natural Science Foundation of China (Nos. 61374145 and U1333131)
文摘Heavy-equipment airdrop is a highly risky procedure that has a complicated system due to the secluded and complex nature of factors＇ coupling. As a result, it is difficult to study the modeling and safety simulation of this system. The dynamic model of the heavy-equipment airdrop is based on the Lagrange analytical mechanics, which has all the degrees of freedom and can accurately pinpoint the real-time coordinates and attitude of the carrier with its cargo. Unfavorable conditions accounted in the factors＇ models, including aircraft malfunctions and adverse environments, are established from a man-machine-environment perspective. Subsequently, a virtual simulation system for the safety research of the multi-factor coupling heavy-equipment airdrop is developed through MATLAB/Simulink, C language and Flightgear software. To verify the veracity of the theory, the verification model is built based on dynamic software ADAMS. Finally, the emulation is put to the test with the input of realistic accident variables to ascertain its feasibility and validity of this method.
文摘We evaluated the potential use of amino silane coupling agent （SiNH） to improve physical and mechanical properties of UF-bonded wheat straw （Triticurn aestivum L.） poplar wood particleboard. We examined the effects of varied content of silane coupling agent content and ratios of straw to poplar wood particles on particleboard prop- erties. The ratios of straw to poplar wood particles were 100：0, 85：15, 70：30 and 55：45. Silane coupling agent content was tested at three levels, 0, 5 and 10 %. The experimental panels were tested for their mechanical strength, including modulus of elasticity （MOE）, modulus of rupture （MOR）, intemal bonding （IB） and physical properties according to procedures specified in DIN 68763 （Chipboard for special purposes in building construction： concepts, requirements, testing, 1982-03, 1982）. All board properties were improved by the addition of silane cou- pling agent. The use of poplar wood particles had a positive effect on the mechanical properties of wheat straw parti- cleboard but had a negative effect on physical properties （thickness swelling and water absorption）.
文摘The TiO_(2)nano-materials could only exert its bactericide effects under illumination.In order to develop new disinfectants which could also kill germs in the dark circumstances,e.g.,in the rooms and in the pipeline systems,we coupled both Ag and TiO2 nano-particles and covered them on SiO2 bases.Three kinds of bacterials,i.e.,Colibacillus,Staphylococus Aureous and Pseudomonas Aeruginosa,were choosen as our target badteria.Then,they were interacted with different nano-materials and their survival rates were determined.It was found that the Ag coupled TiO2 nano-material could exert strong bactericide effects under both illumination and dark environment.By ESR mearsurement,the mechanism of sterilization was discuussed.
基金Project supported by the National Natural Science Foundation of China(21173153)the National Hi-tech Research Development Program of China(863 Program,2013AA065304)the Sichuan Science and Technology Agency Supported Project(2012FZ0008)
文摘Fresh Pd/CeO/AlOclose coupled catalyst was prepared by the stepwise impregnation method and calcined at 550 °C for 3 h, which was then pretreated at 700, 800, and 900 °C for 3 h, respectively. Finally, these pretreated catalysts were aged at 1000 °C for 3 h to study their anti-aging properties. The catalytic activities of the catalysts were investigated detailedly, and the results showed that the catalyst pretreated at 800 °C before aging treatment possessed the best anti-aging performance for CHoxidation. XRD and XPS results indicated that well-crystallized CeOparticles were formed during calcinations at 800 °C, which made CeOan effective promoter. HRTEM revealed that Pd particles found on the edge of CeOover the aged catalyst pretreated at 800 °C were relatively smaller than those over the catalysts without pretreatment. H-TPR and XPS results also implied that the interaction between well-crystallized CeOand Pd suppressed the deactivation of PdO sites and further enhanced the catalytic performance.
基金the National Key Technology Research and Development Program of China(Nos.2018YFC1900603 and 2018YFC0604604)。
文摘In order to solve the problem of strength instability of cemented tailings backfill(CTB)under low temperature environment(≤20℃),the strength optimization and prediction of CTB under the influence of multiple factors were carried out.The response surface method(RSM)was used to design the experiment to analyze the development law of backfill strength under the coupling effect of curing temperature,sand-cement ratio and slurry mass fraction,and to optimize the mix proportion;the artificial neural network algorithm(ANN)and particle swarm optimization algorithm(PSO)were used to build the prediction model of backfill strength.According to the experimental results of RSM,the optimal mix proportion under different curing temperatures was obtained.When the curing temperature is 10-15℃,the best mix proportion of sand-cement ratio is 9,and the slurry mass fraction is 71%;when the curing temperature is 15-20℃,the best mix proportion of sand-cement ratio is 8,and the slurry mass fraction is 69%.The ANN-PSO intelligent model can accurately predict the strength of CTB,its mean relative estimation error value and correlation coefficient value are only 1.95%and 0.992,and the strength of CTB under different mix proportion can be predicted quickly and accurately by using this model.
基金Supported by the National Basic Research Program of China under Grant Nos 2012CB921703 and 2013CB921702the National Natural Science Foundation of China under Grant Nos 11334011 and 91121003the Strategic Priority Research Program of the Chinese Academy of Sciences under Grant No XDB07000000
文摘We perform a scanning tunneling microscopy and spectroscopy study on the electronic structures of √3×√3- silicene on Ag（111）. It is found that the coupling strength of √3×√3-silicene with the Ag-（111） substrate is variable in different regions, giving rise to notable effects in experiments. This evidence of decoupling or variable interaction of silicene with the substrate is helpful to in-depth understanding of the structure and clectronic properties of silieene.
基金the financial support from the National Key Research and Development Program of China(2022YFE0206700)the Science Foundation of China University of Petroleum,Beijing(2462021YJRC012).
文摘Carbon capture,utilization,and storage(CCUS)represents a critical technological pathway for global car-bon emission reduction.CCUS-enhanced oil recovery(EOR)technology is the most feasible CCUS technol-ogy demonstrating dual benefits of enhanced energy production and carbon reduction.This study comprehensively described the key influencing factors governing CO_(2)-EOR and geological storage and systematically analyzed reservoir properties,fluid characteristics,and operational parameters.The mech-anisms of these parameters on EOR versus CO_(2) storage performance were investigated throughout CCUS-EOR processes.This paper proposes a coupled two-stage CCUS-EOR process:CO_(2)-EOR storage stage and long-term CO_(2) storage stage after the CO_(2) injection phase is completed.In each stage,the main control factors impacting the CO_(2)-EOR and storage stages are screened and coupled with rigorous technical anal-ysis.The key factors here are reservoir properties,fluid characteristics,and operational parameter.A novel CCUS-EOR synergistic method was proposed to optimize the lifecycle performance of dual objective of EOR and storage.Furthermore,based on multi-objective optimization,considering the lifecycle,a multi-scale techno-economic evaluation method was proposed to fully assess the CCUS-EOR project per-formance.Finally,a set of recommendations for advancing CCUS-EOR technologies by deploying multi-factor/multi-field coupling methodologies,novel green intelligent injection materials,and artificial intel-ligence/machine learning technologies were visited.
基金supported in part by the National Natural Science Foundation of China(No.51977173).
文摘Steam turbine generators frequently experience deep peak shaving conditions,in which the performance of insulation is significantlyimpacted by extreme fluctuationsin operating temperature.The degradation of water-internally cooled stator bar insulation under repeated temperature variations is investigated in this study.This study examines the progression of winding insulation characteristics by Frequency Domain Spectroscopy(FDS)test and electro-thermal-hydraulic coupled simulations throughout various thermal ageing cycles.Accelerated thermal ageing experiments are conducted on stator bar specimens.Dielectric parameters are captured by FDS across various thermal ageing cycles to assess the effect of thermal ageing on the electrical properties of primary insulation materials.A stator bar model rated at 22 kV is constructed.Electro-thermal-fluidmultiphysics simulations based on the Finite Element Method are performed to compare and analyze electric fieldstrength and temperature distribution under different thermal ageing cycles.Experimental results demonstrate that dielectric properties of the main insulation material deteriorate as thermal ageing progresses,leading to gradual insulation performance degradation.Simulation analysis indicates that the resulting insulation decline increases surface electric fieldsand temperatures on the stator bar,accelerating thermal aging and establishing a positive feedback mechanism.These findingssupport optimised design of the stator bar's anti-corona structure to delay insulation aging,offering a theoretical basis for insulation design optimization and equipment lifespan extension in steam turbine generators.
