Succinonitrile(SN)-based polymer plastic crystal electrolytes(PPCEs)are regarded as promising candidates for lithium metal batteries but suffer from serious side reactions with Li metal.Herein,we propose a multi-dimen...Succinonitrile(SN)-based polymer plastic crystal electrolytes(PPCEs)are regarded as promising candidates for lithium metal batteries but suffer from serious side reactions with Li metal.Herein,we propose a multi-dimensional optimization strategy to alleviate the side reactions between SN and Li metal,and develop a highly stable poly-vinylethylene carbonate-based PPCE(PPCE-VEC).Moreover,we identify the intrinsic factors of multi-dimensional polymer structures on the electrolyte stability by three typical classes of polyesters.The PPCE-VEC constructed by in situ polymerization exhibits much better stability than poly-vinylene carbonate-based PPCE(PPCE-VCA)and poly-trifluoroethyl acrylate-based PPCE(PPCE-TFA),which is verified by its fewer SN-decomposition species in X-ray photoelectron spectroscopy(XPS)and outstanding full cell performance.The PPCE-VEC-enabled LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)full cell achieve 73.7%capacity retention after 1400 cycles,which outperforms PPCE-VCA-and PPCE-TFA-enabled full cells(61.9%and 46.9%).Spectral analysis and theoretical calculation reveal that the high solvation ability of the carbonyl site,flexible polymer chain,and homogeneous electrolyte phase of PPCE-VEC are favorable to maximizing competition coordination with Li^(+)to weaken the Li^(+)–SN binding and shape an anion-rich solvation structure.This optimized polymer-involved Li^(+)solvation enhances SN stability and facilitates the formation of B/F enriched solid-electrolyte interphase(SEI),thus significantly improving PPCE stability.展开更多
With the accelerating aging process of China’s population,the demand for community elderly care services has shown diversified and personalized characteristics.However,problems such as insufficient total care service...With the accelerating aging process of China’s population,the demand for community elderly care services has shown diversified and personalized characteristics.However,problems such as insufficient total care service resources,uneven distribution,and prominent supply-demand contradictions have seriously affected service quality.Big data technology,with core advantages including data collection,analysis and mining,and accurate prediction,provides a new solution for the allocation of community elderly care service resources.This paper systematically studies the application value of big data technology in the allocation of community elderly care service resources from three aspects:resource allocation efficiency,service accuracy,and management intelligence.Combined with practical needs,it proposes optimal allocation strategies such as building a big data analysis platform and accurately grasping the elderly’s care needs,striving to provide operable path references for the construction of community elderly care service systems,promoting the early realization of the elderly care service goal of“adequate support and proper care for the elderly”,and boosting the high-quality development of China’s elderly care service industry.展开更多
Coal serves not only as a crucial energy resource but also as a significant reservoir of critical metal elements,including Lithium(Li),Gallium(Ga),Germanium(Ge),and rare earth elements(REE).This paper provides a syste...Coal serves not only as a crucial energy resource but also as a significant reservoir of critical metal elements,including Lithium(Li),Gallium(Ga),Germanium(Ge),and rare earth elements(REE).This paper provides a systematic review of the enrichment characteristics,occurrence modes,and comprehensive utilization potential of these critical metals in coal.Globally,the distribution of these metal resources exhibits significant regional heterogeneity.While the concentration in most coals falls below industrial cut-off grades,anomalous enrichment in specific coal basins results in Li,Ga,Ge,and REE concentrations far exceeding global averages,highlighting their considerable potential as unconventional metal deposits.The occurrence modes of these metals are diverse:Li is primarily hosted in mineral phases;Ga exists in inorganic,organic,and complex forms;Ge shows a strong association with organic matter;and REE are mainly present in adsorbed/isomorphic forms within clay minerals,while also displaying organic affinity.Direct extraction of metals from raw coal is often cost-prohibitive;effective recovery is therefore more feasible when integrated with coal processing.Metals are further enriched in solid wastes such as coal gangue,fly ash,and bottom ash,from which recovery is more economically and technically viable.Current comprehensive utilization primarily employs integrated mineral processing-hydrometallurgy approaches.Future research should focus on elucidating the precise occurrence forms of metals in coal and solid wastes,optimizing pre-treatment methods,and selecting effective activators and leachants.Advancing the synergistic extraction and green recovery of multiple associated resources from coal and its by-products is essential for achieving high-value,comprehensive utilization of coal-based resources.展开更多
As a major source of freshwater in Central Asia,Tajikistan is endowed with abundant glaciers and water resources.However,the country faces multiple challenges,including accelerated glacier retreat,complex inter-govern...As a major source of freshwater in Central Asia,Tajikistan is endowed with abundant glaciers and water resources.However,the country faces multiple challenges,including accelerated glacier retreat,complex inter-government water resource management,and inefficient water use.Existing research has predominantly focused on individual hydrological processes,such as glacier retreat,snow cover change,or transboundary water issues,but it has yet to fully capture the overall complexity of water system.Tajikistan’s water system functions as an integrated whole from mountain runoff to downstream supply,but a comprehensive study of its water resource has yet to be conducted.To address this research gap,this study systematically examined the status,challenges,and sustainable management strategies of Tajikistan’s water resources based on a literature review,remote sensing data analysis,and case studies.Despite Tajikistan’s relative abundance of water resources,global warming is accelerating glacier melting and altering the hydrological cycles,which have resulted in unstable runoff patterns and heightened risks of extreme events.In Tajikistan,outdated infrastructure and poor management are primary causes of low water-use efficiency in the agricultural sector,which accounts for 85.00%of the total water withdrawals.At the governance level,Tajikistan faces challenges in balancing the water-energy-food nexus and transboundary water resource issues.To address these issues,this study proposes core paths for Tajikistan to achieve sustainable water resource management,such as accelerating technological innovation,promoting water-saving agricultural technologies,improving water resource utilization efficiency,and establishing a community participation-based comprehensive management framework.Additionally,strengthening cross-border cooperation and improving real-time monitoring systems have been identified as critical steps to advance sustainable water resource utilization and evidence-based decision-making in Tajikistan and across Central Asia.展开更多
The integration of Artificial Intelligence(AI)and Machine Learning(ML)into groundwater exploration and water resources management has emerged as a transformative approach to addressing global water challenges.This rev...The integration of Artificial Intelligence(AI)and Machine Learning(ML)into groundwater exploration and water resources management has emerged as a transformative approach to addressing global water challenges.This review explores key AI and ML concepts,methodologies,and their applications in hydrology,focusing on groundwater potential mapping,water quality prediction,and groundwater level forecasting.It discusses various data acquisition techniques,including remote sensing,geospatial analysis,and geophysical surveys,alongside preprocessing methods that are essential for enhancing model accuracy.The study highlights AI-driven solutions in water distribution,allocation optimization,and realtime resource management.Despite their advantages,the application of AI and ML in water sciences faces several challenges,including data scarcity,model reliability,and the integration of these tools with traditional water management systems.Ethical and regulatory concerns also demand careful consideration.The paper also outlines future research directions,emphasizing the need for improved data collection,interpretable models,real-time monitoring capabilities,and interdisciplinary collaboration.By leveraging AI and ML advancements,the water sector can enhance decision-making,optimize resource distribution,and support the development of sustainable water management strategies.展开更多
Owing to the emergence of drug resistance and high morbidity,the need for novel antiviral drugs with novel targets is highly sought after.Marine-derived compounds mostly possess potent antiviral activity and serve as ...Owing to the emergence of drug resistance and high morbidity,the need for novel antiviral drugs with novel targets is highly sought after.Marine-derived compounds mostly possess potent antiviral activity and serve as a primary source for developing novel antiviral drugs,making the rapid discovery and evaluation of marine antiviral agents particularly crucial.Thus,future research should place greater emphasis on the identification of novel antiviral targets through the combination of artificial intelligence(AI)and structural pharmacology,as well as expanding the marine resource and target databases.展开更多
Mineral resources in Asia continent and its mining industry play a significant role in the economic growth and industrialization of both Asia and the world.Asia continent boasts the most comprehensive kinds of mineral...Mineral resources in Asia continent and its mining industry play a significant role in the economic growth and industrialization of both Asia and the world.Asia continent boasts the most comprehensive kinds of minerals,with reserves of at least 38 of over 80 widely used minerals worldwide accounting for more than30%of the global total reserves.Asia continent experienced three main tectonic evolution and mineralization stages:The Precambrian,the Paleozoic,and the Mesozoic to Cenozoic.The abundant mineral resources in this continent can be divided into seven first-order metallogenic belts(metallogenic domains),18 second-order metallogenic belts(metallogenic provinces),61 third-order metallogenic belts(metallogenic zones),and nine main minerogenetic series.Asia continent exhibits the most significant metallogenic specialization among all continents.Specifically,granite belts of Asia continent manifest pronounced metallogenic specialization of tin,rare metals,and porphyry Cu-Au-Mo deposits.Its maficultramafic rock belts and ophiolite belts display notable metallogenic specialization of lateritic nickel deposits and magmatic type chromite deposits,while its Mesozoic to Cenozoic basalt belts show remarkable metallogenic specialization of lateritic bauxite deposits.Consequently,many giant metallogenic belts were formed,including the Southeast Asian tin belt,the Qinghai-Xizang Plateau rare metal metallogenic belt,the Tethyan porphyry Cu-Au-Mo metallogenic belt,the circum-Pacific porphyry Cu-Au-Mo metallogenic belt,the Southeast Asian lateritic bauxite metallogenic belt,the Deccan Plateau lateritic bauxite metallogenic belt in India,the Southeast Asian lateritic nickel metallogenic belt,and the Tethyan magmatic type chromite metallogenic belt—all of which are significant metallogenic belts in Asia continent.Future mineral exploration in Asia should focus primarily on the Precambrian mineralization of ancient cratons,the Paleozoic mineralization of the Central Asian-Mongolian orogenic belt,and the Mesozoic to Cenozoic mineralization of the Tethyan and circum-Pacific mobile belts.Asia's mining industry not only underpins its own economic growth but also propels global economic development and industrialization,contributing significantly to the world economy.Asia boasts the highest production value of minerals,the largest annual production of minerals,and the greatest trade value of mineral products among all the continents,having emerged as the trade center of global mineral products and the center of the mining industry economy.China is identified as one of the few countries that possess the most comprehensive kinds of minerals,and its mining industry has supported and driven the economic development and industrialization of Asia and even the world.Standing as the largest mineral producer worldwide,China ranked first in the production of 28 mineral commodities in the world in 2022.Besides,China exhibits the highest annual production value of minerals and the largest trade value of mineral products among all countries.Therefore,China's demand for global mineral products influences the global supply and demand patterns of minerals and the world economic situation.展开更多
The rich resources and unique environment of the Moon make it an ideal location for human expansion and the utilization of extraterrestrial resources.Oxygen,crucial for supporting human life on the Moon,can be extract...The rich resources and unique environment of the Moon make it an ideal location for human expansion and the utilization of extraterrestrial resources.Oxygen,crucial for supporting human life on the Moon,can be extracted from lunar regolith,which is highly rich in oxygen and contains polymetallic oxides.This oxygen and metal extraction can be achieved using existing metallurgical techniques.Furthermore,the ample reserves of water ice on the Moon offer another means for oxygen production.This paper offers a detailed overview of the leading technologies for achieving oxygen production on the Moon,drawing from an analysis of lunar resources and environmental conditions.It delves into the principles,processes,advantages,and drawbacks of water-ice electrolysis,two-step oxygen production from lunar regolith,and one-step oxygen production from lunar regolith.The two-step methods involve hydrogen reduction,carbothermal reduction,and hydrometallurgy,while the one-step methods encompass fluorination/chlorination,high-temperature decomposition,molten salt electrolysis,and molten regolith electrolysis(MOE).Following a thorough comparison of raw materials,equipment,technology,and economic viability,MOE is identified as the most promising approach for future in-situ oxygen production on the Moon.Considering the corrosion characteristics of molten lunar regolith at high temperatures,along with the Moon's low-gravity environment,the development of inexpensive and stable inert anodes and electrolysis devices that can easily collect oxygen is critical for promoting MOE technology on the Moon.This review significantly contributes to our understanding of in-situ oxygen production technologies on the Moon and supports upcoming lunar exploration initiatives.展开更多
[Objective]The channel straightening project of the Pinglu Canal has fragmented the river course,compromising the integrity of original river course and causing ecosystem patchiness.Understanding the current status of...[Objective]The channel straightening project of the Pinglu Canal has fragmented the river course,compromising the integrity of original river course and causing ecosystem patchiness.Understanding the current status of fish resources and the characteristics of their diversity is crucial for the ecological management of the Pinglu Canal.[Methods]During the spring and autumn in 2021 and 2022,a survey of fish resources and species diversity in the Pinglu Canal was conducted using multi-mesh gill nets.A total of 125 fish species were collected,belonging to 10 orders,34 families,and 89 genera.[Results]The result showed that the Pinglu Canal contained three nationally protected Class II species,two endemic species of the Qinjiang River,three anadromous/migratory species,and eight invasive species,accounting for 2.4%,1.6%,2.4%,and 6.4%of the total species,respectively.The fish community primarily consisted of mid-and bottom-dwelling,adhesive-egg-laying,and omnivorous species.The Shannon-Wiener,Simpson,Margalef,and Pielou indices of the fish community in the Pinglu Canal ranged from 2.347 to 2.757,0.081 to 0.151,3.493 to 4.382,and 0.812 to 0.892,respectively.These indices showed relatively uniform distribution across different river reaches.[Conclusion]The result indicate that the fish community structure in the Pinglu Canal is relatively uniform.The reach from the Yujiang River to the Shaping River shows higher stability,while other river reaches experience moderate or severe disturbances.This study provides supplementary baseline data on the fish community structure in the Pinglu Canal and explores the potential impact of inter-basin connectivity on fish resources,aiming to provide a scientific basis for habitat restoration assessments after the channel straightening project.展开更多
[Objective] This study aimed to establish the multi-dimensional evaluation index system of agricultural water resources in Liaoning Province. [Method] Delphi method in conjunction with AHP method was adopted to establ...[Objective] This study aimed to establish the multi-dimensional evaluation index system of agricultural water resources in Liaoning Province. [Method] Delphi method in conjunction with AHP method was adopted to establish the multi-dimensional evaluation index system of agricultural water resources in Liaoning Province, and all the indexes in each hierarchy were ranked overall according to their weights. [Result] There were three hierarchies in this index system, totally including 21 indexes, among which water resource exploitation and utilization rate, sewage treatment rate and utilization of available water resources were the three crucial factors influencing the sustainable development. [Conclusion] This evaluation index system can reflect the true sustainable situation of the agricultural water resources in Liaoning Province.展开更多
A composite anti-disturbance predictive control strategy employing a Multi-dimensional Taylor Network(MTN)is presented for unmanned systems subject to time-delay and multi-source disturbances.First,the multi-source di...A composite anti-disturbance predictive control strategy employing a Multi-dimensional Taylor Network(MTN)is presented for unmanned systems subject to time-delay and multi-source disturbances.First,the multi-source disturbances are addressed according to their specific characteristics as follows:(A)an MTN data-driven model,which is used for uncertainty description,is designed accompanied with the mechanism model to represent the unmanned systems;(B)an adaptive MTN filter is used to remove the influence of the internal disturbance;(C)an MTN disturbance observer is constructed to estimate and compensate for the influence of the external disturbance;(D)the Extended Kalman Filter(EKF)algorithm is utilized as the learning mechanism for MTNs.Second,to address the time-delay effect,a recursiveτstep-ahead MTN predictive model is designed utilizing recursive technology,aiming to mitigate the impact of time-delay,and the EKF algorithm is employed as its learning mechanism.Then,the MTN predictive control law is designed based on the quadratic performance index.By implementing the proposed composite controller to unmanned systems,simultaneous feedforward compensation and feedback suppression to the multi-source disturbances are conducted.Finally,the convergence of the MTN and the stability of the closed-loop system are established utilizing the Lyapunov theorem.Two exemplary applications of unmanned systems involving unmanned vehicle and rigid spacecraft are presented to validate the effectiveness of the proposed approach.展开更多
With the acceleration of global aging,the population aged 60 and above in China has exceeded 280 million,and the contradiction between the digital skills demands of the elderly and the supply of static and universal e...With the acceleration of global aging,the population aged 60 and above in China has exceeded 280 million,and the contradiction between the digital skills demands of the elderly and the supply of static and universal educational resources has become prominent.This article conducts an in-depth study on the“on-demand creation”model of elderly education resource services driven by generative AI.This study proposes an“on-demand creation”service paradigm based on generative AI,providing suitable resources for elderly intelligent life skills training through demand perception,content generation,and dynamic optimization mechanisms.From the perspective of technological philosophy and service science,deconstruct the core element logic of the paradigm to demonstrate its dual value in reconstructing the theoretical framework of elderly education and promoting practical transformation.This research indicates that this paradigm provides systematic theoretical support for the innovation of elderly education services through a balance between technological empowerment and humanistic care,helping the elderly master modern information technology and life skills,enhancing their self-care ability and social participation,and better adapting to life in the digital age.展开更多
Based on new understandings of the whole petroleum system theory for coal measures,and utilizing data from coal-rock gas wells and other oil and gas wells in numerous pilot test areas for key parameter validation,this...Based on new understandings of the whole petroleum system theory for coal measures,and utilizing data from coal-rock gas wells and other oil and gas wells in numerous pilot test areas for key parameter validation,this study conducted a national resource assessment of coal-rock gas widely developed in marine-continental transitional and continental strata in major petroliferous basins like Ordos,Sichuan and Junggar in China.The main achievements and understandings were obtained as follows.(1)A resource evaluation methodology for coal-rock gas was established,incorporating varying geological/data conditions.(2)Key parameter thresholds for deep coal-rock gas resource evaluation were defined,including the upper limits of critical depth(1500,2000,2500 m),lower limit of reservoir thickness(1 m),and lower limits of gas content in medium-low rank and medium-high rank coals(2,10 m^(3)/t),depending on varying geological conditions across basins.(3)Methods for determining key parameters such as gas content,porosity,and technical recovery factor were developed using the basic data from coal-rock gas experiments/tests and logging.(4)Evaluation results indicate that the geological resources of coal-rock gas in the 14 major basins of onshore China amount to 55.11×10^(12) m^(3).Resources at depths of 1500-3000,3000-5000,5000-6000 m account for 50.29%,43.11%,6.60%of the total,respectively.Resource classification shows that Class Ⅰ,Ⅱ,and Ⅲ resources constitute 21.80%,32.76%,45.44%,with the Class Ⅰ and Ⅱ technically recoverable resources of approximately 13.23×10^(12) m^(3).(5)The Ordos Basin remains the most favorable province,while the Sichuan,Junggar and Tarim basins are the promising targets,for future exploration and development of coal-rock gas in the country.Other basins including Bohai Bay,Qaidam,Tuha,Songliao and Hailar are considered as prospective options.Coal-rock gas production is expected to reach 500×10^(8) m^(3) annually within the next 10-15 years,positioning it as a major contributor to the natural gas production growth of China and a crucial alternative resource for ensuring the national gas supply.展开更多
The ancient tacit knowledge behind the logic system permeated the culture and promoted numerous impactful inventions throughout the history. Traditional Chinese medicine with its effectiveness should also have stemmed...The ancient tacit knowledge behind the logic system permeated the culture and promoted numerous impactful inventions throughout the history. Traditional Chinese medicine with its effectiveness should also have stemmed out from such logic system. This article aims to rearticulate the underlying lucid multi-dimensional logic system, which faded in obscurity only because of time-out loss of the mid-right concept. Retracing this past tacit but important concept could uncover a multi-dimensional system over a point relating to all matters while capturing the central core of the matter. The seemingly unmanageable multidimensional logic was strengthened by verification processes which affirmed its further extensions, and made up the language of the people, the concepts of yin-yang(阴阳), and the development of extensions of Ba Gua(八卦) derivatives, which furthered the interpretation of the space-time properties and Chinese medicine.展开更多
The pivotal role of complex numbers in quantum mechanics underpins the resource theory of imaginarity.We investigate imaginarity dynamics in a single-qubit open system coupled to a non-Markovian environment.Crucially,...The pivotal role of complex numbers in quantum mechanics underpins the resource theory of imaginarity.We investigate imaginarity dynamics in a single-qubit open system coupled to a non-Markovian environment.Crucially,cavity field detuning emerges as the dominant regulator,driving continuous conversion between the real and imaginary components of coherence.Nonzero detuning induces characteristic non-periodic oscillations of imaginarity between zero and maximal values,preventing complete decoherence at specific times.We establish that imaginarity resources stem from both intrinsic system evolution and environmental feedback.Significantly,detuning-driven imaginarity generation persists even in Markovian regimes,demonstrating its origin beyond environmental memory effects.These insights offer new perspectives for understanding and harnessing quantum coherence.展开更多
Stress accumulation is a key factor leading to sodium storage performance deterioration for NiSe_(2)-based anodes.Therefore,inhibiting the concentrated local stress during the sodiataion/desodiation process is crucial...Stress accumulation is a key factor leading to sodium storage performance deterioration for NiSe_(2)-based anodes.Therefore,inhibiting the concentrated local stress during the sodiataion/desodiation process is crucial for acquiring stable NiSe2-based materials for sodium-ion batteries(SIBs),Herein,a stress dissipation strategy driven by architecture engineering is proposed,which can achieve ultrafast and ultralong sodium storage properties.Different from the conventional sphere-like or rod-like architecture,the three-dimensional(3D)flower-like NiSe_(2)@C composite is delicately designed and assembled with onedimensional nanorods and carbon framework.More importantly,the fundamental mechanism of improved structure stability is unveiled by simulations and experimental results simultaneously.It demonstrates that this designed multidimensional flower-like architecture with dispersed nanorods can balance the structural mismatch,avoid concentrated local strain,and relax the internal stress,mainly induced by the unavoidable volume variation during the repeated conversion processes.Moreover,it can provide more Na^(+)-storage sites and multi-directional migration pathways,leading to a fast Na^(+)-migration channel with boosted reaction kinetic.As expected,it delivers superior rate performance(441 mA h g^(-1)at 5.0 A g^(-1))and long cycling stability(563 mA h g^(-1)at 1.0 A g^(-1)over 1000 cycles)for SIBs.This work provides useful insights for designing high-performance conversion-based anode materials for SIBs.展开更多
This paper explores whole-process engineering consulting,including its application models in public buildings and elderly-friendly projects,such as service integration and whole lifecycle management.It also addresses ...This paper explores whole-process engineering consulting,including its application models in public buildings and elderly-friendly projects,such as service integration and whole lifecycle management.It also addresses the construction of multi-dimensional collaborative theoretical models,public space streamline organization,and other aspects,emphasizing the importance of multi-dimensional collaboration.Additionally,it highlights the role of talent cultivation and digital transformation in enhancing project efficiency.展开更多
Accurate and effective assessment of hydrothermal resources is crucial in the geothermal industry,given that the global installed capacity for direct use(173303 MW)significantly exceeds that for geothermal power(16260...Accurate and effective assessment of hydrothermal resources is crucial in the geothermal industry,given that the global installed capacity for direct use(173303 MW)significantly exceeds that for geothermal power(16260 MW).Despite the widespread application of various geothermal resource assessment methods,including the volumetric method,Monte Carlo method,analogy,statistical analysis,and numerical methods,there are still limitations faced in terms of data precision and model uncertainty assessment,fracture heterogeneity,boundary conditions,renewable energy attributes,integration of geothermal compensation mechanisms under the“extraction-injection”balance,diversification of economic evaluation metrics,and the establishment of standardized assessment criteria.This review outlines the various methods suitable for different stages of the hydrothermal resource assessment process,and proposes future technical approaches for sustainable development,including improving the accuracy of assessments and establishing standards for geothermal resource evaluation methods,in order to enhance the efficiency of geothermal resource utilization.展开更多
The multi-dimensional interactive teaching model significantly enhances the effectiveness of college English instruction by emphasizing dynamic engagement between teachers and students,as well as among students themse...The multi-dimensional interactive teaching model significantly enhances the effectiveness of college English instruction by emphasizing dynamic engagement between teachers and students,as well as among students themselves.This paper explores practical strategies for implementing this model,focusing on four key aspects:deepening teachers’understanding of the model through continuous learning,innovating interactive methods such as questioning techniques and practical activities,leveraging modern technology to integrate resources and track learning progress,and establishing a communication platform that centers on student participation.By adopting these approaches,the model fosters a student-centered classroom environment,improves comprehensive English application skills,and optimizes overall teaching quality.展开更多
基金supported by the National Natural Science Foundation of China(22072048)the Guangdong Provincial Department of Science and Technology(2021A1515010128 and 2022A0505050013).
文摘Succinonitrile(SN)-based polymer plastic crystal electrolytes(PPCEs)are regarded as promising candidates for lithium metal batteries but suffer from serious side reactions with Li metal.Herein,we propose a multi-dimensional optimization strategy to alleviate the side reactions between SN and Li metal,and develop a highly stable poly-vinylethylene carbonate-based PPCE(PPCE-VEC).Moreover,we identify the intrinsic factors of multi-dimensional polymer structures on the electrolyte stability by three typical classes of polyesters.The PPCE-VEC constructed by in situ polymerization exhibits much better stability than poly-vinylene carbonate-based PPCE(PPCE-VCA)and poly-trifluoroethyl acrylate-based PPCE(PPCE-TFA),which is verified by its fewer SN-decomposition species in X-ray photoelectron spectroscopy(XPS)and outstanding full cell performance.The PPCE-VEC-enabled LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)full cell achieve 73.7%capacity retention after 1400 cycles,which outperforms PPCE-VCA-and PPCE-TFA-enabled full cells(61.9%and 46.9%).Spectral analysis and theoretical calculation reveal that the high solvation ability of the carbonyl site,flexible polymer chain,and homogeneous electrolyte phase of PPCE-VEC are favorable to maximizing competition coordination with Li^(+)to weaken the Li^(+)–SN binding and shape an anion-rich solvation structure.This optimized polymer-involved Li^(+)solvation enhances SN stability and facilitates the formation of B/F enriched solid-electrolyte interphase(SEI),thus significantly improving PPCE stability.
文摘With the accelerating aging process of China’s population,the demand for community elderly care services has shown diversified and personalized characteristics.However,problems such as insufficient total care service resources,uneven distribution,and prominent supply-demand contradictions have seriously affected service quality.Big data technology,with core advantages including data collection,analysis and mining,and accurate prediction,provides a new solution for the allocation of community elderly care service resources.This paper systematically studies the application value of big data technology in the allocation of community elderly care service resources from three aspects:resource allocation efficiency,service accuracy,and management intelligence.Combined with practical needs,it proposes optimal allocation strategies such as building a big data analysis platform and accurately grasping the elderly’s care needs,striving to provide operable path references for the construction of community elderly care service systems,promoting the early realization of the elderly care service goal of“adequate support and proper care for the elderly”,and boosting the high-quality development of China’s elderly care service industry.
基金supported by the Key Support Project of Regional Innovation and Development Joint Fund of the National Natural Science Foundation of China(No.U24A2095).
文摘Coal serves not only as a crucial energy resource but also as a significant reservoir of critical metal elements,including Lithium(Li),Gallium(Ga),Germanium(Ge),and rare earth elements(REE).This paper provides a systematic review of the enrichment characteristics,occurrence modes,and comprehensive utilization potential of these critical metals in coal.Globally,the distribution of these metal resources exhibits significant regional heterogeneity.While the concentration in most coals falls below industrial cut-off grades,anomalous enrichment in specific coal basins results in Li,Ga,Ge,and REE concentrations far exceeding global averages,highlighting their considerable potential as unconventional metal deposits.The occurrence modes of these metals are diverse:Li is primarily hosted in mineral phases;Ga exists in inorganic,organic,and complex forms;Ge shows a strong association with organic matter;and REE are mainly present in adsorbed/isomorphic forms within clay minerals,while also displaying organic affinity.Direct extraction of metals from raw coal is often cost-prohibitive;effective recovery is therefore more feasible when integrated with coal processing.Metals are further enriched in solid wastes such as coal gangue,fly ash,and bottom ash,from which recovery is more economically and technically viable.Current comprehensive utilization primarily employs integrated mineral processing-hydrometallurgy approaches.Future research should focus on elucidating the precise occurrence forms of metals in coal and solid wastes,optimizing pre-treatment methods,and selecting effective activators and leachants.Advancing the synergistic extraction and green recovery of multiple associated resources from coal and its by-products is essential for achieving high-value,comprehensive utilization of coal-based resources.
基金supported by the National Natural Science Foundation of China(W2412135)the Youth Innovation Promotion Association of the Chinese Academy of Sciences.
文摘As a major source of freshwater in Central Asia,Tajikistan is endowed with abundant glaciers and water resources.However,the country faces multiple challenges,including accelerated glacier retreat,complex inter-government water resource management,and inefficient water use.Existing research has predominantly focused on individual hydrological processes,such as glacier retreat,snow cover change,or transboundary water issues,but it has yet to fully capture the overall complexity of water system.Tajikistan’s water system functions as an integrated whole from mountain runoff to downstream supply,but a comprehensive study of its water resource has yet to be conducted.To address this research gap,this study systematically examined the status,challenges,and sustainable management strategies of Tajikistan’s water resources based on a literature review,remote sensing data analysis,and case studies.Despite Tajikistan’s relative abundance of water resources,global warming is accelerating glacier melting and altering the hydrological cycles,which have resulted in unstable runoff patterns and heightened risks of extreme events.In Tajikistan,outdated infrastructure and poor management are primary causes of low water-use efficiency in the agricultural sector,which accounts for 85.00%of the total water withdrawals.At the governance level,Tajikistan faces challenges in balancing the water-energy-food nexus and transboundary water resource issues.To address these issues,this study proposes core paths for Tajikistan to achieve sustainable water resource management,such as accelerating technological innovation,promoting water-saving agricultural technologies,improving water resource utilization efficiency,and establishing a community participation-based comprehensive management framework.Additionally,strengthening cross-border cooperation and improving real-time monitoring systems have been identified as critical steps to advance sustainable water resource utilization and evidence-based decision-making in Tajikistan and across Central Asia.
文摘The integration of Artificial Intelligence(AI)and Machine Learning(ML)into groundwater exploration and water resources management has emerged as a transformative approach to addressing global water challenges.This review explores key AI and ML concepts,methodologies,and their applications in hydrology,focusing on groundwater potential mapping,water quality prediction,and groundwater level forecasting.It discusses various data acquisition techniques,including remote sensing,geospatial analysis,and geophysical surveys,alongside preprocessing methods that are essential for enhancing model accuracy.The study highlights AI-driven solutions in water distribution,allocation optimization,and realtime resource management.Despite their advantages,the application of AI and ML in water sciences faces several challenges,including data scarcity,model reliability,and the integration of these tools with traditional water management systems.Ethical and regulatory concerns also demand careful consideration.The paper also outlines future research directions,emphasizing the need for improved data collection,interpretable models,real-time monitoring capabilities,and interdisciplinary collaboration.By leveraging AI and ML advancements,the water sector can enhance decision-making,optimize resource distribution,and support the development of sustainable water management strategies.
文摘Owing to the emergence of drug resistance and high morbidity,the need for novel antiviral drugs with novel targets is highly sought after.Marine-derived compounds mostly possess potent antiviral activity and serve as a primary source for developing novel antiviral drugs,making the rapid discovery and evaluation of marine antiviral agents particularly crucial.Thus,future research should place greater emphasis on the identification of novel antiviral targets through the combination of artificial intelligence(AI)and structural pharmacology,as well as expanding the marine resource and target databases.
基金funded by geological survey project of China Geological Survey(DD20211404)。
文摘Mineral resources in Asia continent and its mining industry play a significant role in the economic growth and industrialization of both Asia and the world.Asia continent boasts the most comprehensive kinds of minerals,with reserves of at least 38 of over 80 widely used minerals worldwide accounting for more than30%of the global total reserves.Asia continent experienced three main tectonic evolution and mineralization stages:The Precambrian,the Paleozoic,and the Mesozoic to Cenozoic.The abundant mineral resources in this continent can be divided into seven first-order metallogenic belts(metallogenic domains),18 second-order metallogenic belts(metallogenic provinces),61 third-order metallogenic belts(metallogenic zones),and nine main minerogenetic series.Asia continent exhibits the most significant metallogenic specialization among all continents.Specifically,granite belts of Asia continent manifest pronounced metallogenic specialization of tin,rare metals,and porphyry Cu-Au-Mo deposits.Its maficultramafic rock belts and ophiolite belts display notable metallogenic specialization of lateritic nickel deposits and magmatic type chromite deposits,while its Mesozoic to Cenozoic basalt belts show remarkable metallogenic specialization of lateritic bauxite deposits.Consequently,many giant metallogenic belts were formed,including the Southeast Asian tin belt,the Qinghai-Xizang Plateau rare metal metallogenic belt,the Tethyan porphyry Cu-Au-Mo metallogenic belt,the circum-Pacific porphyry Cu-Au-Mo metallogenic belt,the Southeast Asian lateritic bauxite metallogenic belt,the Deccan Plateau lateritic bauxite metallogenic belt in India,the Southeast Asian lateritic nickel metallogenic belt,and the Tethyan magmatic type chromite metallogenic belt—all of which are significant metallogenic belts in Asia continent.Future mineral exploration in Asia should focus primarily on the Precambrian mineralization of ancient cratons,the Paleozoic mineralization of the Central Asian-Mongolian orogenic belt,and the Mesozoic to Cenozoic mineralization of the Tethyan and circum-Pacific mobile belts.Asia's mining industry not only underpins its own economic growth but also propels global economic development and industrialization,contributing significantly to the world economy.Asia boasts the highest production value of minerals,the largest annual production of minerals,and the greatest trade value of mineral products among all the continents,having emerged as the trade center of global mineral products and the center of the mining industry economy.China is identified as one of the few countries that possess the most comprehensive kinds of minerals,and its mining industry has supported and driven the economic development and industrialization of Asia and even the world.Standing as the largest mineral producer worldwide,China ranked first in the production of 28 mineral commodities in the world in 2022.Besides,China exhibits the highest annual production value of minerals and the largest trade value of mineral products among all countries.Therefore,China's demand for global mineral products influences the global supply and demand patterns of minerals and the world economic situation.
基金financially supported by the National Natural Science Foundation of China(Nos.52404328,52274412,and 52374418)the China Postdoctoral Science Foundation(No.2024M753248)。
文摘The rich resources and unique environment of the Moon make it an ideal location for human expansion and the utilization of extraterrestrial resources.Oxygen,crucial for supporting human life on the Moon,can be extracted from lunar regolith,which is highly rich in oxygen and contains polymetallic oxides.This oxygen and metal extraction can be achieved using existing metallurgical techniques.Furthermore,the ample reserves of water ice on the Moon offer another means for oxygen production.This paper offers a detailed overview of the leading technologies for achieving oxygen production on the Moon,drawing from an analysis of lunar resources and environmental conditions.It delves into the principles,processes,advantages,and drawbacks of water-ice electrolysis,two-step oxygen production from lunar regolith,and one-step oxygen production from lunar regolith.The two-step methods involve hydrogen reduction,carbothermal reduction,and hydrometallurgy,while the one-step methods encompass fluorination/chlorination,high-temperature decomposition,molten salt electrolysis,and molten regolith electrolysis(MOE).Following a thorough comparison of raw materials,equipment,technology,and economic viability,MOE is identified as the most promising approach for future in-situ oxygen production on the Moon.Considering the corrosion characteristics of molten lunar regolith at high temperatures,along with the Moon's low-gravity environment,the development of inexpensive and stable inert anodes and electrolysis devices that can easily collect oxygen is critical for promoting MOE technology on the Moon.This review significantly contributes to our understanding of in-situ oxygen production technologies on the Moon and supports upcoming lunar exploration initiatives.
文摘[Objective]The channel straightening project of the Pinglu Canal has fragmented the river course,compromising the integrity of original river course and causing ecosystem patchiness.Understanding the current status of fish resources and the characteristics of their diversity is crucial for the ecological management of the Pinglu Canal.[Methods]During the spring and autumn in 2021 and 2022,a survey of fish resources and species diversity in the Pinglu Canal was conducted using multi-mesh gill nets.A total of 125 fish species were collected,belonging to 10 orders,34 families,and 89 genera.[Results]The result showed that the Pinglu Canal contained three nationally protected Class II species,two endemic species of the Qinjiang River,three anadromous/migratory species,and eight invasive species,accounting for 2.4%,1.6%,2.4%,and 6.4%of the total species,respectively.The fish community primarily consisted of mid-and bottom-dwelling,adhesive-egg-laying,and omnivorous species.The Shannon-Wiener,Simpson,Margalef,and Pielou indices of the fish community in the Pinglu Canal ranged from 2.347 to 2.757,0.081 to 0.151,3.493 to 4.382,and 0.812 to 0.892,respectively.These indices showed relatively uniform distribution across different river reaches.[Conclusion]The result indicate that the fish community structure in the Pinglu Canal is relatively uniform.The reach from the Yujiang River to the Shaping River shows higher stability,while other river reaches experience moderate or severe disturbances.This study provides supplementary baseline data on the fish community structure in the Pinglu Canal and explores the potential impact of inter-basin connectivity on fish resources,aiming to provide a scientific basis for habitat restoration assessments after the channel straightening project.
文摘[Objective] This study aimed to establish the multi-dimensional evaluation index system of agricultural water resources in Liaoning Province. [Method] Delphi method in conjunction with AHP method was adopted to establish the multi-dimensional evaluation index system of agricultural water resources in Liaoning Province, and all the indexes in each hierarchy were ranked overall according to their weights. [Result] There were three hierarchies in this index system, totally including 21 indexes, among which water resource exploitation and utilization rate, sewage treatment rate and utilization of available water resources were the three crucial factors influencing the sustainable development. [Conclusion] This evaluation index system can reflect the true sustainable situation of the agricultural water resources in Liaoning Province.
基金co-supported by the National Key R&D Program of China(No.2023YFB4704400)the Zhejiang Provincial Natural Science Foundation of China(No.LQ24F030012)the National Natural Science Foundation of China General Project(No.62373033)。
文摘A composite anti-disturbance predictive control strategy employing a Multi-dimensional Taylor Network(MTN)is presented for unmanned systems subject to time-delay and multi-source disturbances.First,the multi-source disturbances are addressed according to their specific characteristics as follows:(A)an MTN data-driven model,which is used for uncertainty description,is designed accompanied with the mechanism model to represent the unmanned systems;(B)an adaptive MTN filter is used to remove the influence of the internal disturbance;(C)an MTN disturbance observer is constructed to estimate and compensate for the influence of the external disturbance;(D)the Extended Kalman Filter(EKF)algorithm is utilized as the learning mechanism for MTNs.Second,to address the time-delay effect,a recursiveτstep-ahead MTN predictive model is designed utilizing recursive technology,aiming to mitigate the impact of time-delay,and the EKF algorithm is employed as its learning mechanism.Then,the MTN predictive control law is designed based on the quadratic performance index.By implementing the proposed composite controller to unmanned systems,simultaneous feedforward compensation and feedback suppression to the multi-source disturbances are conducted.Finally,the convergence of the MTN and the stability of the closed-loop system are established utilizing the Lyapunov theorem.Two exemplary applications of unmanned systems involving unmanned vehicle and rigid spacecraft are presented to validate the effectiveness of the proposed approach.
文摘With the acceleration of global aging,the population aged 60 and above in China has exceeded 280 million,and the contradiction between the digital skills demands of the elderly and the supply of static and universal educational resources has become prominent.This article conducts an in-depth study on the“on-demand creation”model of elderly education resource services driven by generative AI.This study proposes an“on-demand creation”service paradigm based on generative AI,providing suitable resources for elderly intelligent life skills training through demand perception,content generation,and dynamic optimization mechanisms.From the perspective of technological philosophy and service science,deconstruct the core element logic of the paradigm to demonstrate its dual value in reconstructing the theoretical framework of elderly education and promoting practical transformation.This research indicates that this paradigm provides systematic theoretical support for the innovation of elderly education services through a balance between technological empowerment and humanistic care,helping the elderly master modern information technology and life skills,enhancing their self-care ability and social participation,and better adapting to life in the digital age.
基金Supported by the National Science and Technology Major Project(2025ZD1404200)Research Project of PetroChina Company Limited(2024DJ23)Scientific Research and Technology Development Project of PetroChina Research Institute of Petroleum Exploration&Development(2024vzz).
文摘Based on new understandings of the whole petroleum system theory for coal measures,and utilizing data from coal-rock gas wells and other oil and gas wells in numerous pilot test areas for key parameter validation,this study conducted a national resource assessment of coal-rock gas widely developed in marine-continental transitional and continental strata in major petroliferous basins like Ordos,Sichuan and Junggar in China.The main achievements and understandings were obtained as follows.(1)A resource evaluation methodology for coal-rock gas was established,incorporating varying geological/data conditions.(2)Key parameter thresholds for deep coal-rock gas resource evaluation were defined,including the upper limits of critical depth(1500,2000,2500 m),lower limit of reservoir thickness(1 m),and lower limits of gas content in medium-low rank and medium-high rank coals(2,10 m^(3)/t),depending on varying geological conditions across basins.(3)Methods for determining key parameters such as gas content,porosity,and technical recovery factor were developed using the basic data from coal-rock gas experiments/tests and logging.(4)Evaluation results indicate that the geological resources of coal-rock gas in the 14 major basins of onshore China amount to 55.11×10^(12) m^(3).Resources at depths of 1500-3000,3000-5000,5000-6000 m account for 50.29%,43.11%,6.60%of the total,respectively.Resource classification shows that Class Ⅰ,Ⅱ,and Ⅲ resources constitute 21.80%,32.76%,45.44%,with the Class Ⅰ and Ⅱ technically recoverable resources of approximately 13.23×10^(12) m^(3).(5)The Ordos Basin remains the most favorable province,while the Sichuan,Junggar and Tarim basins are the promising targets,for future exploration and development of coal-rock gas in the country.Other basins including Bohai Bay,Qaidam,Tuha,Songliao and Hailar are considered as prospective options.Coal-rock gas production is expected to reach 500×10^(8) m^(3) annually within the next 10-15 years,positioning it as a major contributor to the natural gas production growth of China and a crucial alternative resource for ensuring the national gas supply.
文摘The ancient tacit knowledge behind the logic system permeated the culture and promoted numerous impactful inventions throughout the history. Traditional Chinese medicine with its effectiveness should also have stemmed out from such logic system. This article aims to rearticulate the underlying lucid multi-dimensional logic system, which faded in obscurity only because of time-out loss of the mid-right concept. Retracing this past tacit but important concept could uncover a multi-dimensional system over a point relating to all matters while capturing the central core of the matter. The seemingly unmanageable multidimensional logic was strengthened by verification processes which affirmed its further extensions, and made up the language of the people, the concepts of yin-yang(阴阳), and the development of extensions of Ba Gua(八卦) derivatives, which furthered the interpretation of the space-time properties and Chinese medicine.
基金support of the Tianchi Talented Young Doctoral Fund Project and Huyang Talent Research Startup Fund Project of Tarim University(Project Number:TDZKSS202511).
文摘The pivotal role of complex numbers in quantum mechanics underpins the resource theory of imaginarity.We investigate imaginarity dynamics in a single-qubit open system coupled to a non-Markovian environment.Crucially,cavity field detuning emerges as the dominant regulator,driving continuous conversion between the real and imaginary components of coherence.Nonzero detuning induces characteristic non-periodic oscillations of imaginarity between zero and maximal values,preventing complete decoherence at specific times.We establish that imaginarity resources stem from both intrinsic system evolution and environmental feedback.Significantly,detuning-driven imaginarity generation persists even in Markovian regimes,demonstrating its origin beyond environmental memory effects.These insights offer new perspectives for understanding and harnessing quantum coherence.
基金the financial support from the Guangxi Natural Science Foundation(grant no.2021GXNSFDA075012,2023GXNSFGA026002)National Natural Science Foundation of China(52104298,22075073,52362027,52462029)Fundamental Research Funds for the Central Universities(531107051077).
文摘Stress accumulation is a key factor leading to sodium storage performance deterioration for NiSe_(2)-based anodes.Therefore,inhibiting the concentrated local stress during the sodiataion/desodiation process is crucial for acquiring stable NiSe2-based materials for sodium-ion batteries(SIBs),Herein,a stress dissipation strategy driven by architecture engineering is proposed,which can achieve ultrafast and ultralong sodium storage properties.Different from the conventional sphere-like or rod-like architecture,the three-dimensional(3D)flower-like NiSe_(2)@C composite is delicately designed and assembled with onedimensional nanorods and carbon framework.More importantly,the fundamental mechanism of improved structure stability is unveiled by simulations and experimental results simultaneously.It demonstrates that this designed multidimensional flower-like architecture with dispersed nanorods can balance the structural mismatch,avoid concentrated local strain,and relax the internal stress,mainly induced by the unavoidable volume variation during the repeated conversion processes.Moreover,it can provide more Na^(+)-storage sites and multi-directional migration pathways,leading to a fast Na^(+)-migration channel with boosted reaction kinetic.As expected,it delivers superior rate performance(441 mA h g^(-1)at 5.0 A g^(-1))and long cycling stability(563 mA h g^(-1)at 1.0 A g^(-1)over 1000 cycles)for SIBs.This work provides useful insights for designing high-performance conversion-based anode materials for SIBs.
文摘This paper explores whole-process engineering consulting,including its application models in public buildings and elderly-friendly projects,such as service integration and whole lifecycle management.It also addresses the construction of multi-dimensional collaborative theoretical models,public space streamline organization,and other aspects,emphasizing the importance of multi-dimensional collaboration.Additionally,it highlights the role of talent cultivation and digital transformation in enhancing project efficiency.
基金funded by the National Natural Science Foundation of China(No.42130809)the Science and Technology Project of China Petroleum and Chemical Corporation Limited(No.KLJP23009)。
文摘Accurate and effective assessment of hydrothermal resources is crucial in the geothermal industry,given that the global installed capacity for direct use(173303 MW)significantly exceeds that for geothermal power(16260 MW).Despite the widespread application of various geothermal resource assessment methods,including the volumetric method,Monte Carlo method,analogy,statistical analysis,and numerical methods,there are still limitations faced in terms of data precision and model uncertainty assessment,fracture heterogeneity,boundary conditions,renewable energy attributes,integration of geothermal compensation mechanisms under the“extraction-injection”balance,diversification of economic evaluation metrics,and the establishment of standardized assessment criteria.This review outlines the various methods suitable for different stages of the hydrothermal resource assessment process,and proposes future technical approaches for sustainable development,including improving the accuracy of assessments and establishing standards for geothermal resource evaluation methods,in order to enhance the efficiency of geothermal resource utilization.
文摘The multi-dimensional interactive teaching model significantly enhances the effectiveness of college English instruction by emphasizing dynamic engagement between teachers and students,as well as among students themselves.This paper explores practical strategies for implementing this model,focusing on four key aspects:deepening teachers’understanding of the model through continuous learning,innovating interactive methods such as questioning techniques and practical activities,leveraging modern technology to integrate resources and track learning progress,and establishing a communication platform that centers on student participation.By adopting these approaches,the model fosters a student-centered classroom environment,improves comprehensive English application skills,and optimizes overall teaching quality.
