Objective: To investigate the efficacy of multidimensional protective nursing interventions in reducing occupational exposure risks to hydrofluoric acid in dental departments. Methods: The study was conducted between ...Objective: To investigate the efficacy of multidimensional protective nursing interventions in reducing occupational exposure risks to hydrofluoric acid in dental departments. Methods: The study was conducted between January 2024 and January 2025, involving 60 healthcare workers who were randomly assigned to groups. The control group (n = 30) received conventional occupational protective nursing care, while the observation group underwent multidimensional protective nursing interventions. Results: Following intervention, the observation group demonstrated significantly higher scores than the control group in knowledge of hydrofluoric acid occupational exposure, occupational exposure risk perception, and protective skill operation (p < 0.05). Emergency response capability scores and protective behavior implementation scores were also higher in the observation group (p < 0.05). Compared to the control group, the observation group exhibited higher occupational health satisfaction rates and lower occupational exposure incidence rates (p < 0.05). Conclusion: Multidimensional protective nursing interventions effectively enhance dental healthcare personnel’s awareness and protective capabilities regarding hydrofluoric acid occupational exposure, improve compliance with protective measures, and significantly reduce occupational exposure risks. This approach warrants promotion and application in occupational protective nursing interventions within dental departments.展开更多
Succinonitrile(SN)-based polymer plastic crystal electrolytes(PPCEs)are regarded as promising candidates for lithium metal batteries but suffer from serious side reactions with Li metal.Herein,we propose a multi-dimen...Succinonitrile(SN)-based polymer plastic crystal electrolytes(PPCEs)are regarded as promising candidates for lithium metal batteries but suffer from serious side reactions with Li metal.Herein,we propose a multi-dimensional optimization strategy to alleviate the side reactions between SN and Li metal,and develop a highly stable poly-vinylethylene carbonate-based PPCE(PPCE-VEC).Moreover,we identify the intrinsic factors of multi-dimensional polymer structures on the electrolyte stability by three typical classes of polyesters.The PPCE-VEC constructed by in situ polymerization exhibits much better stability than poly-vinylene carbonate-based PPCE(PPCE-VCA)and poly-trifluoroethyl acrylate-based PPCE(PPCE-TFA),which is verified by its fewer SN-decomposition species in X-ray photoelectron spectroscopy(XPS)and outstanding full cell performance.The PPCE-VEC-enabled LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)full cell achieve 73.7%capacity retention after 1400 cycles,which outperforms PPCE-VCA-and PPCE-TFA-enabled full cells(61.9%and 46.9%).Spectral analysis and theoretical calculation reveal that the high solvation ability of the carbonyl site,flexible polymer chain,and homogeneous electrolyte phase of PPCE-VEC are favorable to maximizing competition coordination with Li^(+)to weaken the Li^(+)–SN binding and shape an anion-rich solvation structure.This optimized polymer-involved Li^(+)solvation enhances SN stability and facilitates the formation of B/F enriched solid-electrolyte interphase(SEI),thus significantly improving PPCE stability.展开更多
The newly formulated non-Newtonian rivulet flows streaming down an inclined planar surface,with additional periodic perturbations arising from the application of the 2nd Stokes problem to the investigation of rivulet ...The newly formulated non-Newtonian rivulet flows streaming down an inclined planar surface,with additional periodic perturbations arising from the application of the 2nd Stokes problem to the investigation of rivulet dynamics,are demonstrated in the current research.Hereby,the 2nd Stokes problem assumes that the surface,with a thin shared layer of the fluid on it,oscillates in a harmonic manner along the x-axis of the rivulet flow,which coincides with the main flow direction streaming down the underlying surface.We obtain the exact extension of the rivulet flow family,clarifying the structure of the pressure field,which fully absorbs the arising perturbation.The profile of the velocity field is assumed to be Gaussian-type with a non-zero level of plasticity.Hence,the absolutely non-Newtonian case of the viscoplastic flow solution,which satisfies the motion and continuity equations,is considered(with particular cases of exact solutions for pressure).The perturbed governing equations of motion for rivulet flows then result in the Riccati-type ordinary differential equation(ODE),describing the dynamics of the coordinate x(t).The approximated schematic dynamics are presented in graphical plots.展开更多
Particle-and droplet-laden flows are central to many problems in mechanics and transport.They occur in sedimentladen boundary layers,gas-solid and gas-liquid dispersions,and surface-water films driven by external forc...Particle-and droplet-laden flows are central to many problems in mechanics and transport.They occur in sedimentladen boundary layers,gas-solid and gas-liquid dispersions,and surface-water films driven by external forcing.They also underpin practical applications ranging from environmental transport to high-speed and aerothermal systems.Despite decades of progress,prediction remains difficult.The physics spans a wide range of scales and often couples turbulence,interphase momentum exchange,collisions,and interfacial transport.Reliable computation therefore requires both robust numerical methodology and careful physical interpretation.展开更多
Forests are experiencing more frequent and intense wildfires in Canada,which pose considerable threats to water quantity and quality,particularly during the summer low-flow period when water demand is high.While the i...Forests are experiencing more frequent and intense wildfires in Canada,which pose considerable threats to water quantity and quality,particularly during the summer low-flow period when water demand is high.While the impacts of wildfire on hydrology have been widely assessed at the watershed scale,the underlying mechanisms of the responses of summer low flows remain poorly understood.In this study,we employed an integrated research framework that combines hydrometric monitoring with geochemical tracing to evaluate how the 2021 White Rock Lake Wildfire affected summer low flows,and to identify the underlying mechanisms governing these responses in the Okanagan Valley,British Columbia(BC),Canada.We found that(1)summer low flows,represented by Q90(flows exceeded at 90%of the time in summer)significantly increased following the wildfire(p<0.05);(2)summer low flows were primarily regulated by snow water in early summer(July),while dominated by groundwater in late summer(August and September);and(3)enhanced snow water contribution and reduced evapotranspiration(ET)were two primary contributors to the increased summer low flows.Our results provide insights for developing sustainable water management strategies for the region in the context of climate change and increasing forest disturbance.This study also demonstrates that the combination of hydrometric monitoring and geochemical tracing is an effective approach towards uncovering mechanisms that drive low-flow responses.展开更多
Based on reanalysis data and CMIP6 simulations,this study investigates the distinct responses of the cross-equatorial flows(CEFs)over the Maritime Continent(MC)under the simultaneous summer condition of two types of E...Based on reanalysis data and CMIP6 simulations,this study investigates the distinct responses of the cross-equatorial flows(CEFs)over the Maritime Continent(MC)under the simultaneous summer condition of two types of ENSO:central Pacific(CP)and eastern Pacific(EP).Results indicate that CP ENSO tends to exert stronger impacts on CEF.In CP ENSO years,significant lower-level southerly anomalies can be observed across all CEF branches adjacent to MC,accompanied by broader and deeper upper-level northerly anomalies,indicating a well-organized strengthening of both upper-and lowerlevel CEFs.In contrast,CEF anomalies in EP ENSO years tend to be weaker,with significant meridional wind anomalies confined to the east of MC.The disparities in the CEF responses can be elucidated from the perspective of convection over MC,a crucial factor in triggering CEF.In CP ENSO years,westward-leaning sea surface temperature(SST)anomalies result in a distinct cooling in MC and suppressed convection above,driving pronounced CEF anomalies.Conversely,the absence of such organized SST cooling during EP ENSO results in weaker convective forcing and subdued CEF responses.Furthermore,historical simulations from 48 CMIP6 models are utilized to validate the observational findings.Results show that model simulations can successfully reproduce the stronger impacts of CP ENSO,with a remarkable intermodel consistency.This research contributes toward a comprehensive understanding of the diversity in the relationship between CEF and ENSO types,and has implications for seasonal forecasting of CEF variability.展开更多
A comprehensive assessment of grain supply,demand,and ecosystem service flows is essential for identifying grain movement pathways,ensuring regional grain security,and guiding sustainable management strategies.However...A comprehensive assessment of grain supply,demand,and ecosystem service flows is essential for identifying grain movement pathways,ensuring regional grain security,and guiding sustainable management strategies.However,current studies primarily focus on short-term grain provision services while neglecting the spatiotemporal variations in grain flows across different scales.This gap limits the identification of dynamic matching relationships and the formulation of optimization strategies for balancing grain flows.This study examined the spatiotemporal evolution of grain supply and demand in the Beijing-Tianjin-Hebei(BTH)region from 1980 to 2020.Using the Enhanced TwoStep Floating Catchment Area method,the grain provision ecosystem service flows were quantified,the changes in supply–demand matching under different grain flow scenarios were analyzed and the optimal distance threshold for grain flows was investigated.The results revealed that grain production follows a spatial distribution pattern characterized by high levels in the southeast and low levels in the northwest.A significant mismatch exists between supply and demand,and it shows a scale effect.Deficit areas are mainly concentrated in the northwest,while surplus areas are mainly located in the central and southern regions.As the spatial scale increases,the ecosystem service supply–demand ratio(SDR)classification becomes more clustered,while it exhibits greater spatial SDR heterogeneity at smaller scales.This study examined two distinct scenarios of grain provision ecosystem service flow dynamics based on 100 and 200 km distance thresholds.The flow increased significantly,from 2.17 to 11.81million tons in the first scenario and from 2.41 to 12.37 million tons in the second scenario over nearly 40 years,forming a spatial movement pattern from the central and southern regions to the surrounding areas.Large flows were mainly concentrated in the interior of urban centers,with significant outflows between cities such as Baoding,Shijiazhuang,Xingtai,and Hengshui.At the county scale,supply–demand matching patterns remained consistent between the grain flows in the two scenarios.Notably,incorporating grain flow dynamics significantly reduced the number of grain-deficit areas compared to scenarios without grain flow.In 2020,grain-deficit counties decreased by28.79 and 37.88%,and cities by 12.50 and 25.0%under the two scenarios,respectively.Furthermore,the distance threshold for achieving optimal supply and demand matching at the county scale was longer than at the city scale in both grain flow scenarios.This study provides valuable insights into the dynamic relationships and heterogeneous patterns of grain matching,and expands the research perspective on grain and ecosystem service flows across various spatiotemporal scales.展开更多
Developing advanced acoustic treatments,such as the Multi-Degree-of-Freedom(MDOF)septum liner,to realize the broadband noise reduction is critical for silent aeroengines.This study investigates experimentally the MDOF...Developing advanced acoustic treatments,such as the Multi-Degree-of-Freedom(MDOF)septum liner,to realize the broadband noise reduction is critical for silent aeroengines.This study investigates experimentally the MDOF septum liner and its impedance model on the Beihang Grazing Flow Duct(BGFD)setup,over a wide frequency range under grazing flows up to 0.5 Mach number and Sound Pressure Level(SPL)up to 150 dB,typically encountered in aeroengine nacelles.Several specimens varying in the numbers,types,and depths of septa among units are designed,fabricated,and measured.Their impedances and Transmission Losses(TL)are obtained using the mirror-based multimodal straightforward method and the mode decomposition technique,respectively.Generally,the model predictions show good agreement with the educed impedances in all cases,and such liners with a large-porosity facesheet exhibit low acoustic nonlinearities in the presence of high SPL,especially under high-velocity grazing flows.Moreover,a MDOF liner we delicately designed,compared with a conventional broadband three-layer perforated liner as the reference,is close to the resonant state at more frequencies and thus has higher and wider measured TL spectra almost from 1 kHz up to 10 kHz at studied Mach numbers,under the premise of saving 22.7 mm in the thickness.These show that,the MDOF septum liner,if well designed,can achieve an ultra-broadband efficient sound attenuation using more limited spaces in complex aeroacoustic environments.展开更多
Circumferentially non-uniform tip clearances induced by rotor eccentricity significantly affect the overall performance of axial compressors,particularly the stability margin.Currently,Computational Fluid Dynamics(CFD...Circumferentially non-uniform tip clearances induced by rotor eccentricity significantly affect the overall performance of axial compressors,particularly the stability margin.Currently,Computational Fluid Dynamics(CFD)plays a crucial role in the aerodynamic analysis of eccentric compressors.However,conventional full-annulus Unsteady Reynolds-Averaged Navier-Stokes(URANS)simulations are prohibitively expensive for routine design and analysis purposes.To address this issue,the paper presents a novel Fourier-based method,called the Time-Space Collocation(TSC)method,for efficient simulations of eccentric compressors.This method coherently treats temporal and spatial harmonics,making it well-suited to tackle the rotor eccentricity problem,as the perturbation waves induced by eccentricity are time-periodic with respect to the rotor and space-periodic with respect to the stator.Three numerical cases,including NASA Rotor 67,original Stage 67,and Stage 67 with a reduced rotor-stator axial gap,were conducted to verify the effectiveness of the TSC method.The results indicate that,for the rotor eccentricity levels studied in this paper,the influence of weak rotor-stator interactions can be disregarded in the original Stage 67.In this situation,applying three harmonics can accurately capture both the performance variations and the non-uniformly distributed flowfields of eccentric compressors,while achieving a reduction in run time by two orders of magnitude compared to full-annulus URANS simulations.However,in Stage 67 with a reduced rotor-stator axial gap,the results that include rotor-stator interactions align much more closely with the URANS results.Nevertheless,the TSC simulations can still achieve speed-ups of several dozen times.Overall,the TSC method shows promising potential for application within the engineering community.展开更多
Stony debris flows,characterized by coarse boulders embedded in a sediment-laden matrix,greatly amplify destructive potential by altering flow dynamics and impact forces.Conventional single-phase particle-fluidmixture...Stony debris flows,characterized by coarse boulders embedded in a sediment-laden matrix,greatly amplify destructive potential by altering flow dynamics and impact forces.Conventional single-phase particle-fluidmixture models often struggle to capture the complexities introduced by coarse boulders and multi-phase interactions,while strong-coupling methods can be computationally prohibitive for practical hazard assessments.In this study,we propose a semi-hybrid,fully resolved coupling numerical framework for modeling boulder-laden debris flows.This framework conceptualizes debris flows as a composite system comprising a continuous viscous fluidphase(including finesediments)and a discrete phase of arbitrarily shaped coarse particles.The continuous phase is treated as a generalized nonlinear Coulomb-viscoplastic fluidusing the smoothed particle hydrodynamics(SPH)method,while coarse particles are modeled via the distributed contact discrete element method(DCDEM).These two phases are coupled through an efficienttwo-way resolved scheme,ensuring accurate simulation of flow-boulder interactions within a unifiedtimeframe.We validate the proposed method against two physical experiments:(1)gravity-driven concrete flows and(2)debris flowinteracting with slit-type barriers.Results confirmthe method's robustness in accurately capturing fluid-solid-structureinteractions and deposition processes.Its capabilities are further showcased through the simulation of a stony debris-flowevent inWenchuan County,China,highlighting its promise for real-world engineering applications and validating the effectiveness of the existing cascade dam system in mitigating debrisflowimpact and energy dissipation.展开更多
This paper deals with the numerical solution of inviscid compressible flows.The threedimensional Euler equations describing the mentioned problem are presented and solved numerically with the finite volume method.The ...This paper deals with the numerical solution of inviscid compressible flows.The threedimensional Euler equations describing the mentioned problem are presented and solved numerically with the finite volume method.The evaluation of the numerical flux at the interfaces is performed by using the Toro Vazquez-Harten Lax Leer(TV-HLL)scheme.An essential feature of the proposed scheme is to associate two systems of differential equations,called the advection system and the pressure system.It can be implemented with a very simple manner in the standard finite volume Euler and Navier–Stokes codes as extremely simple task.The scheme is applied to some test problems covering a wide spectrum of Mach numbers,including hypersonic,low speed flow and three-dimensional aerodynamics applications.展开更多
In this paper, a compensated compactness framework is established for sonicsubsonic approximate solutions to the n-dimensional （n ≥ 2） Euler equations for steady irrotational flow that may contain stagnation points...In this paper, a compensated compactness framework is established for sonicsubsonic approximate solutions to the n-dimensional （n ≥ 2） Euler equations for steady irrotational flow that may contain stagnation points. This compactness framework holds provided that the approximate solutions are uniformly bounded and satisfy Hloc^-1（Ω） compactness conditions. As illustration, we show the existence of sonic-subsonic weak solution to n-dimensional （n ≥ 2） Euler equations for steady irrotational flow past obstacles or through an infinitely long nozzle. This is the first result concerning the sonic-subsonic limit for n-dimension （n ≥ 3）.展开更多
A composite anti-disturbance predictive control strategy employing a Multi-dimensional Taylor Network(MTN)is presented for unmanned systems subject to time-delay and multi-source disturbances.First,the multi-source di...A composite anti-disturbance predictive control strategy employing a Multi-dimensional Taylor Network(MTN)is presented for unmanned systems subject to time-delay and multi-source disturbances.First,the multi-source disturbances are addressed according to their specific characteristics as follows:(A)an MTN data-driven model,which is used for uncertainty description,is designed accompanied with the mechanism model to represent the unmanned systems;(B)an adaptive MTN filter is used to remove the influence of the internal disturbance;(C)an MTN disturbance observer is constructed to estimate and compensate for the influence of the external disturbance;(D)the Extended Kalman Filter(EKF)algorithm is utilized as the learning mechanism for MTNs.Second,to address the time-delay effect,a recursiveτstep-ahead MTN predictive model is designed utilizing recursive technology,aiming to mitigate the impact of time-delay,and the EKF algorithm is employed as its learning mechanism.Then,the MTN predictive control law is designed based on the quadratic performance index.By implementing the proposed composite controller to unmanned systems,simultaneous feedforward compensation and feedback suppression to the multi-source disturbances are conducted.Finally,the convergence of the MTN and the stability of the closed-loop system are established utilizing the Lyapunov theorem.Two exemplary applications of unmanned systems involving unmanned vehicle and rigid spacecraft are presented to validate the effectiveness of the proposed approach.展开更多
This paper aims to numerically explore the characteristics of unsteady cavitating flow around a NACA0015 hydrofoil,with a focus on vorticity attributes.The simulation utilizes a homogeneous mixture model coupled with ...This paper aims to numerically explore the characteristics of unsteady cavitating flow around a NACA0015 hydrofoil,with a focus on vorticity attributes.The simulation utilizes a homogeneous mixture model coupled with a filter-based density correction turbulence model and a modified Zwart cavitation model.The study investigates the dynamic cavitation features of the thermal fluid around the hydrofoil at various incoming flow velocities.It systematically elucidates the evolution of cavitation and vortex dynamics corresponding to each velocity condition.The results indicate that with increasing incoming flow velocity,distinct cavitation processes take place in the flow field.展开更多
The stability of supersonic inlets faces challenges due to various changes in flight conditions,and flow control methods that address shock wave/boundary layer interactions under only one set of conditions cannot meet...The stability of supersonic inlets faces challenges due to various changes in flight conditions,and flow control methods that address shock wave/boundary layer interactions under only one set of conditions cannot meet developmental requirements.This paper proposes an adaptive bump control scheme and employs dynamic mesh technology for numerical simulation to investigate the unsteady control effects of adaptive bumps.The obtained results indicate that the use of moving bumps to control shock wave/boundary layer interactions is feasible.The adaptive control effects of five different bump speeds are evaluated.Within the range of bump speeds studied,the analysis of the flow field structure reveals the patterns of change in the separation zone area during the control process,as well as the relationship between the bump motion speed and the control effect on the separation zone.It is concluded that the moving bump endows the boundary layer with additional energy.展开更多
Large size titanium alloy parts are widely used in aerospace.However,they are difficult to manufacture using mechanical cutting technology because of severe tool wear.Electrochemical jet machining is a promising techn...Large size titanium alloy parts are widely used in aerospace.However,they are difficult to manufacture using mechanical cutting technology because of severe tool wear.Electrochemical jet machining is a promising technology to achieve high efficiency,because it has high machining flexibility and no machining tool wear.However,reports on the macro electrochemical jet machining of large size titanium alloy parts are very scarce,because it is difficult to achieve effective constraint of the flow field in macro electrochemical jet machining.In addition,titanium alloy is very sensitive to fluctuation of the flow field,and a turbulent flow field would lead to serious stray corrosion.This paper reports a series of investigations of the electrochemical jet machining of titanium alloy parts.Based on the flow analysis and experiments,the machining flow field was effectively constrained.TB6 titanium alloy part with a perimeter of one meter was machined.The machined surface was smooth with no obvious machining defects.The machining process was particularly stable with no obvious spark discharge.The research provides a reference for the application of electrochemical jet machining technology to achieve large allowance material removal in the machining of large titanium alloy parts.展开更多
The ancient tacit knowledge behind the logic system permeated the culture and promoted numerous impactful inventions throughout the history. Traditional Chinese medicine with its effectiveness should also have stemmed...The ancient tacit knowledge behind the logic system permeated the culture and promoted numerous impactful inventions throughout the history. Traditional Chinese medicine with its effectiveness should also have stemmed out from such logic system. This article aims to rearticulate the underlying lucid multi-dimensional logic system, which faded in obscurity only because of time-out loss of the mid-right concept. Retracing this past tacit but important concept could uncover a multi-dimensional system over a point relating to all matters while capturing the central core of the matter. The seemingly unmanageable multidimensional logic was strengthened by verification processes which affirmed its further extensions, and made up the language of the people, the concepts of yin-yang(阴阳), and the development of extensions of Ba Gua(八卦) derivatives, which furthered the interpretation of the space-time properties and Chinese medicine.展开更多
Stress accumulation is a key factor leading to sodium storage performance deterioration for NiSe_(2)-based anodes.Therefore,inhibiting the concentrated local stress during the sodiataion/desodiation process is crucial...Stress accumulation is a key factor leading to sodium storage performance deterioration for NiSe_(2)-based anodes.Therefore,inhibiting the concentrated local stress during the sodiataion/desodiation process is crucial for acquiring stable NiSe2-based materials for sodium-ion batteries(SIBs),Herein,a stress dissipation strategy driven by architecture engineering is proposed,which can achieve ultrafast and ultralong sodium storage properties.Different from the conventional sphere-like or rod-like architecture,the three-dimensional(3D)flower-like NiSe_(2)@C composite is delicately designed and assembled with onedimensional nanorods and carbon framework.More importantly,the fundamental mechanism of improved structure stability is unveiled by simulations and experimental results simultaneously.It demonstrates that this designed multidimensional flower-like architecture with dispersed nanorods can balance the structural mismatch,avoid concentrated local strain,and relax the internal stress,mainly induced by the unavoidable volume variation during the repeated conversion processes.Moreover,it can provide more Na^(+)-storage sites and multi-directional migration pathways,leading to a fast Na^(+)-migration channel with boosted reaction kinetic.As expected,it delivers superior rate performance(441 mA h g^(-1)at 5.0 A g^(-1))and long cycling stability(563 mA h g^(-1)at 1.0 A g^(-1)over 1000 cycles)for SIBs.This work provides useful insights for designing high-performance conversion-based anode materials for SIBs.展开更多
基金Construction of Standardized Protective Nursing Plan for Hydrofluoric Acid Operations in Dentistry and Research on Injury Prevention Effects(Project No.:FZ2025101)。
文摘Objective: To investigate the efficacy of multidimensional protective nursing interventions in reducing occupational exposure risks to hydrofluoric acid in dental departments. Methods: The study was conducted between January 2024 and January 2025, involving 60 healthcare workers who were randomly assigned to groups. The control group (n = 30) received conventional occupational protective nursing care, while the observation group underwent multidimensional protective nursing interventions. Results: Following intervention, the observation group demonstrated significantly higher scores than the control group in knowledge of hydrofluoric acid occupational exposure, occupational exposure risk perception, and protective skill operation (p < 0.05). Emergency response capability scores and protective behavior implementation scores were also higher in the observation group (p < 0.05). Compared to the control group, the observation group exhibited higher occupational health satisfaction rates and lower occupational exposure incidence rates (p < 0.05). Conclusion: Multidimensional protective nursing interventions effectively enhance dental healthcare personnel’s awareness and protective capabilities regarding hydrofluoric acid occupational exposure, improve compliance with protective measures, and significantly reduce occupational exposure risks. This approach warrants promotion and application in occupational protective nursing interventions within dental departments.
基金supported by the National Natural Science Foundation of China(22072048)the Guangdong Provincial Department of Science and Technology(2021A1515010128 and 2022A0505050013).
文摘Succinonitrile(SN)-based polymer plastic crystal electrolytes(PPCEs)are regarded as promising candidates for lithium metal batteries but suffer from serious side reactions with Li metal.Herein,we propose a multi-dimensional optimization strategy to alleviate the side reactions between SN and Li metal,and develop a highly stable poly-vinylethylene carbonate-based PPCE(PPCE-VEC).Moreover,we identify the intrinsic factors of multi-dimensional polymer structures on the electrolyte stability by three typical classes of polyesters.The PPCE-VEC constructed by in situ polymerization exhibits much better stability than poly-vinylene carbonate-based PPCE(PPCE-VCA)and poly-trifluoroethyl acrylate-based PPCE(PPCE-TFA),which is verified by its fewer SN-decomposition species in X-ray photoelectron spectroscopy(XPS)and outstanding full cell performance.The PPCE-VEC-enabled LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)full cell achieve 73.7%capacity retention after 1400 cycles,which outperforms PPCE-VCA-and PPCE-TFA-enabled full cells(61.9%and 46.9%).Spectral analysis and theoretical calculation reveal that the high solvation ability of the carbonyl site,flexible polymer chain,and homogeneous electrolyte phase of PPCE-VEC are favorable to maximizing competition coordination with Li^(+)to weaken the Li^(+)–SN binding and shape an anion-rich solvation structure.This optimized polymer-involved Li^(+)solvation enhances SN stability and facilitates the formation of B/F enriched solid-electrolyte interphase(SEI),thus significantly improving PPCE stability.
文摘The newly formulated non-Newtonian rivulet flows streaming down an inclined planar surface,with additional periodic perturbations arising from the application of the 2nd Stokes problem to the investigation of rivulet dynamics,are demonstrated in the current research.Hereby,the 2nd Stokes problem assumes that the surface,with a thin shared layer of the fluid on it,oscillates in a harmonic manner along the x-axis of the rivulet flow,which coincides with the main flow direction streaming down the underlying surface.We obtain the exact extension of the rivulet flow family,clarifying the structure of the pressure field,which fully absorbs the arising perturbation.The profile of the velocity field is assumed to be Gaussian-type with a non-zero level of plasticity.Hence,the absolutely non-Newtonian case of the viscoplastic flow solution,which satisfies the motion and continuity equations,is considered(with particular cases of exact solutions for pressure).The perturbed governing equations of motion for rivulet flows then result in the Riccati-type ordinary differential equation(ODE),describing the dynamics of the coordinate x(t).The approximated schematic dynamics are presented in graphical plots.
文摘Particle-and droplet-laden flows are central to many problems in mechanics and transport.They occur in sedimentladen boundary layers,gas-solid and gas-liquid dispersions,and surface-water films driven by external forcing.They also underpin practical applications ranging from environmental transport to high-speed and aerothermal systems.Despite decades of progress,prediction remains difficult.The physics spans a wide range of scales and often couples turbulence,interphase momentum exchange,collisions,and interfacial transport.Reliable computation therefore requires both robust numerical methodology and careful physical interpretation.
基金the China Scholarship Council(CSC)the Uplifting Reciprocal Research Scholarship Program for sponsoring Shixuan Lyu+1 种基金supported by MITACS Accelerate(No.IT39116)the Okanagan Basin Water Board water conservation and quality improvement grant program。
文摘Forests are experiencing more frequent and intense wildfires in Canada,which pose considerable threats to water quantity and quality,particularly during the summer low-flow period when water demand is high.While the impacts of wildfire on hydrology have been widely assessed at the watershed scale,the underlying mechanisms of the responses of summer low flows remain poorly understood.In this study,we employed an integrated research framework that combines hydrometric monitoring with geochemical tracing to evaluate how the 2021 White Rock Lake Wildfire affected summer low flows,and to identify the underlying mechanisms governing these responses in the Okanagan Valley,British Columbia(BC),Canada.We found that(1)summer low flows,represented by Q90(flows exceeded at 90%of the time in summer)significantly increased following the wildfire(p<0.05);(2)summer low flows were primarily regulated by snow water in early summer(July),while dominated by groundwater in late summer(August and September);and(3)enhanced snow water contribution and reduced evapotranspiration(ET)were two primary contributors to the increased summer low flows.Our results provide insights for developing sustainable water management strategies for the region in the context of climate change and increasing forest disturbance.This study also demonstrates that the combination of hydrometric monitoring and geochemical tracing is an effective approach towards uncovering mechanisms that drive low-flow responses.
基金supported by the National Natural Science Foundation of China(Grant No.42405029).
文摘Based on reanalysis data and CMIP6 simulations,this study investigates the distinct responses of the cross-equatorial flows(CEFs)over the Maritime Continent(MC)under the simultaneous summer condition of two types of ENSO:central Pacific(CP)and eastern Pacific(EP).Results indicate that CP ENSO tends to exert stronger impacts on CEF.In CP ENSO years,significant lower-level southerly anomalies can be observed across all CEF branches adjacent to MC,accompanied by broader and deeper upper-level northerly anomalies,indicating a well-organized strengthening of both upper-and lowerlevel CEFs.In contrast,CEF anomalies in EP ENSO years tend to be weaker,with significant meridional wind anomalies confined to the east of MC.The disparities in the CEF responses can be elucidated from the perspective of convection over MC,a crucial factor in triggering CEF.In CP ENSO years,westward-leaning sea surface temperature(SST)anomalies result in a distinct cooling in MC and suppressed convection above,driving pronounced CEF anomalies.Conversely,the absence of such organized SST cooling during EP ENSO results in weaker convective forcing and subdued CEF responses.Furthermore,historical simulations from 48 CMIP6 models are utilized to validate the observational findings.Results show that model simulations can successfully reproduce the stronger impacts of CP ENSO,with a remarkable intermodel consistency.This research contributes toward a comprehensive understanding of the diversity in the relationship between CEF and ENSO types,and has implications for seasonal forecasting of CEF variability.
基金supported by the National Natural Science Foundation of China(42471336,52379021 and 42201278)the Hebei Province Backbone Talent Program,China(Returnee Platform for Overseas Study)(A20240028)+2 种基金the Hebei Province Statistical Science Research Project,China(2024HZ04)the Hebei Province Graduate Education and Teaching Reform Research Project,China(YJG2024046)the Innovation Ability Training Program for Postgraduate Students of Hebei Provincial Department of Education,China(CXZZSS2025048)。
文摘A comprehensive assessment of grain supply,demand,and ecosystem service flows is essential for identifying grain movement pathways,ensuring regional grain security,and guiding sustainable management strategies.However,current studies primarily focus on short-term grain provision services while neglecting the spatiotemporal variations in grain flows across different scales.This gap limits the identification of dynamic matching relationships and the formulation of optimization strategies for balancing grain flows.This study examined the spatiotemporal evolution of grain supply and demand in the Beijing-Tianjin-Hebei(BTH)region from 1980 to 2020.Using the Enhanced TwoStep Floating Catchment Area method,the grain provision ecosystem service flows were quantified,the changes in supply–demand matching under different grain flow scenarios were analyzed and the optimal distance threshold for grain flows was investigated.The results revealed that grain production follows a spatial distribution pattern characterized by high levels in the southeast and low levels in the northwest.A significant mismatch exists between supply and demand,and it shows a scale effect.Deficit areas are mainly concentrated in the northwest,while surplus areas are mainly located in the central and southern regions.As the spatial scale increases,the ecosystem service supply–demand ratio(SDR)classification becomes more clustered,while it exhibits greater spatial SDR heterogeneity at smaller scales.This study examined two distinct scenarios of grain provision ecosystem service flow dynamics based on 100 and 200 km distance thresholds.The flow increased significantly,from 2.17 to 11.81million tons in the first scenario and from 2.41 to 12.37 million tons in the second scenario over nearly 40 years,forming a spatial movement pattern from the central and southern regions to the surrounding areas.Large flows were mainly concentrated in the interior of urban centers,with significant outflows between cities such as Baoding,Shijiazhuang,Xingtai,and Hengshui.At the county scale,supply–demand matching patterns remained consistent between the grain flows in the two scenarios.Notably,incorporating grain flow dynamics significantly reduced the number of grain-deficit areas compared to scenarios without grain flow.In 2020,grain-deficit counties decreased by28.79 and 37.88%,and cities by 12.50 and 25.0%under the two scenarios,respectively.Furthermore,the distance threshold for achieving optimal supply and demand matching at the county scale was longer than at the city scale in both grain flow scenarios.This study provides valuable insights into the dynamic relationships and heterogeneous patterns of grain matching,and expands the research perspective on grain and ecosystem service flows across various spatiotemporal scales.
基金co-supported by the National Natural Science Foundation of China(No.52206039)the Taihang Laboratory of China(No.A2053)+1 种基金the Aeronautical Science Foundation of China(No.20240011051001)the National Key R&D Program of China(No.2021YFB3703900)。
文摘Developing advanced acoustic treatments,such as the Multi-Degree-of-Freedom(MDOF)septum liner,to realize the broadband noise reduction is critical for silent aeroengines.This study investigates experimentally the MDOF septum liner and its impedance model on the Beihang Grazing Flow Duct(BGFD)setup,over a wide frequency range under grazing flows up to 0.5 Mach number and Sound Pressure Level(SPL)up to 150 dB,typically encountered in aeroengine nacelles.Several specimens varying in the numbers,types,and depths of septa among units are designed,fabricated,and measured.Their impedances and Transmission Losses(TL)are obtained using the mirror-based multimodal straightforward method and the mode decomposition technique,respectively.Generally,the model predictions show good agreement with the educed impedances in all cases,and such liners with a large-porosity facesheet exhibit low acoustic nonlinearities in the presence of high SPL,especially under high-velocity grazing flows.Moreover,a MDOF liner we delicately designed,compared with a conventional broadband three-layer perforated liner as the reference,is close to the resonant state at more frequencies and thus has higher and wider measured TL spectra almost from 1 kHz up to 10 kHz at studied Mach numbers,under the premise of saving 22.7 mm in the thickness.These show that,the MDOF septum liner,if well designed,can achieve an ultra-broadband efficient sound attenuation using more limited spaces in complex aeroacoustic environments.
文摘Circumferentially non-uniform tip clearances induced by rotor eccentricity significantly affect the overall performance of axial compressors,particularly the stability margin.Currently,Computational Fluid Dynamics(CFD)plays a crucial role in the aerodynamic analysis of eccentric compressors.However,conventional full-annulus Unsteady Reynolds-Averaged Navier-Stokes(URANS)simulations are prohibitively expensive for routine design and analysis purposes.To address this issue,the paper presents a novel Fourier-based method,called the Time-Space Collocation(TSC)method,for efficient simulations of eccentric compressors.This method coherently treats temporal and spatial harmonics,making it well-suited to tackle the rotor eccentricity problem,as the perturbation waves induced by eccentricity are time-periodic with respect to the rotor and space-periodic with respect to the stator.Three numerical cases,including NASA Rotor 67,original Stage 67,and Stage 67 with a reduced rotor-stator axial gap,were conducted to verify the effectiveness of the TSC method.The results indicate that,for the rotor eccentricity levels studied in this paper,the influence of weak rotor-stator interactions can be disregarded in the original Stage 67.In this situation,applying three harmonics can accurately capture both the performance variations and the non-uniformly distributed flowfields of eccentric compressors,while achieving a reduction in run time by two orders of magnitude compared to full-annulus URANS simulations.However,in Stage 67 with a reduced rotor-stator axial gap,the results that include rotor-stator interactions align much more closely with the URANS results.Nevertheless,the TSC simulations can still achieve speed-ups of several dozen times.Overall,the TSC method shows promising potential for application within the engineering community.
基金supported by the Japan Society for the Promotion of Science(JSPS)KAKENHI(Grant Nos.JP23KK0182,JP23K26356,and JP24K00971).
文摘Stony debris flows,characterized by coarse boulders embedded in a sediment-laden matrix,greatly amplify destructive potential by altering flow dynamics and impact forces.Conventional single-phase particle-fluidmixture models often struggle to capture the complexities introduced by coarse boulders and multi-phase interactions,while strong-coupling methods can be computationally prohibitive for practical hazard assessments.In this study,we propose a semi-hybrid,fully resolved coupling numerical framework for modeling boulder-laden debris flows.This framework conceptualizes debris flows as a composite system comprising a continuous viscous fluidphase(including finesediments)and a discrete phase of arbitrarily shaped coarse particles.The continuous phase is treated as a generalized nonlinear Coulomb-viscoplastic fluidusing the smoothed particle hydrodynamics(SPH)method,while coarse particles are modeled via the distributed contact discrete element method(DCDEM).These two phases are coupled through an efficienttwo-way resolved scheme,ensuring accurate simulation of flow-boulder interactions within a unifiedtimeframe.We validate the proposed method against two physical experiments:(1)gravity-driven concrete flows and(2)debris flowinteracting with slit-type barriers.Results confirmthe method's robustness in accurately capturing fluid-solid-structureinteractions and deposition processes.Its capabilities are further showcased through the simulation of a stony debris-flowevent inWenchuan County,China,highlighting its promise for real-world engineering applications and validating the effectiveness of the existing cascade dam system in mitigating debrisflowimpact and energy dissipation.
文摘This paper deals with the numerical solution of inviscid compressible flows.The threedimensional Euler equations describing the mentioned problem are presented and solved numerically with the finite volume method.The evaluation of the numerical flux at the interfaces is performed by using the Toro Vazquez-Harten Lax Leer(TV-HLL)scheme.An essential feature of the proposed scheme is to associate two systems of differential equations,called the advection system and the pressure system.It can be implemented with a very simple manner in the standard finite volume Euler and Navier–Stokes codes as extremely simple task.The scheme is applied to some test problems covering a wide spectrum of Mach numbers,including hypersonic,low speed flow and three-dimensional aerodynamics applications.
基金supported in part by NSFC (10825102) for distinguished youth scholarNational Basic Research Program of China (973 Program) under Grant No.2011CB808002
文摘In this paper, a compensated compactness framework is established for sonicsubsonic approximate solutions to the n-dimensional （n ≥ 2） Euler equations for steady irrotational flow that may contain stagnation points. This compactness framework holds provided that the approximate solutions are uniformly bounded and satisfy Hloc^-1（Ω） compactness conditions. As illustration, we show the existence of sonic-subsonic weak solution to n-dimensional （n ≥ 2） Euler equations for steady irrotational flow past obstacles or through an infinitely long nozzle. This is the first result concerning the sonic-subsonic limit for n-dimension （n ≥ 3）.
基金co-supported by the National Key R&D Program of China(No.2023YFB4704400)the Zhejiang Provincial Natural Science Foundation of China(No.LQ24F030012)the National Natural Science Foundation of China General Project(No.62373033)。
文摘A composite anti-disturbance predictive control strategy employing a Multi-dimensional Taylor Network(MTN)is presented for unmanned systems subject to time-delay and multi-source disturbances.First,the multi-source disturbances are addressed according to their specific characteristics as follows:(A)an MTN data-driven model,which is used for uncertainty description,is designed accompanied with the mechanism model to represent the unmanned systems;(B)an adaptive MTN filter is used to remove the influence of the internal disturbance;(C)an MTN disturbance observer is constructed to estimate and compensate for the influence of the external disturbance;(D)the Extended Kalman Filter(EKF)algorithm is utilized as the learning mechanism for MTNs.Second,to address the time-delay effect,a recursiveτstep-ahead MTN predictive model is designed utilizing recursive technology,aiming to mitigate the impact of time-delay,and the EKF algorithm is employed as its learning mechanism.Then,the MTN predictive control law is designed based on the quadratic performance index.By implementing the proposed composite controller to unmanned systems,simultaneous feedforward compensation and feedback suppression to the multi-source disturbances are conducted.Finally,the convergence of the MTN and the stability of the closed-loop system are established utilizing the Lyapunov theorem.Two exemplary applications of unmanned systems involving unmanned vehicle and rigid spacecraft are presented to validate the effectiveness of the proposed approach.
文摘This paper aims to numerically explore the characteristics of unsteady cavitating flow around a NACA0015 hydrofoil,with a focus on vorticity attributes.The simulation utilizes a homogeneous mixture model coupled with a filter-based density correction turbulence model and a modified Zwart cavitation model.The study investigates the dynamic cavitation features of the thermal fluid around the hydrofoil at various incoming flow velocities.It systematically elucidates the evolution of cavitation and vortex dynamics corresponding to each velocity condition.The results indicate that with increasing incoming flow velocity,distinct cavitation processes take place in the flow field.
基金supported by the National Key R&D Program of China(Grant No.2019YFA0405300)the National Natural Science Foundation of China(Grant No.11972368)the Natural Science Foundation of Hunan Province(Grant No.2021JJ10045).
文摘The stability of supersonic inlets faces challenges due to various changes in flight conditions,and flow control methods that address shock wave/boundary layer interactions under only one set of conditions cannot meet developmental requirements.This paper proposes an adaptive bump control scheme and employs dynamic mesh technology for numerical simulation to investigate the unsteady control effects of adaptive bumps.The obtained results indicate that the use of moving bumps to control shock wave/boundary layer interactions is feasible.The adaptive control effects of five different bump speeds are evaluated.Within the range of bump speeds studied,the analysis of the flow field structure reveals the patterns of change in the separation zone area during the control process,as well as the relationship between the bump motion speed and the control effect on the separation zone.It is concluded that the moving bump endows the boundary layer with additional energy.
基金the National Natural Science Foundation of China(No.52205468)China Postdoctoral Science Foundation(No.2022M710061 and No.2023T160277)Natural Science Foundation of Jiangsu Province(No.BK20210755)。
文摘Large size titanium alloy parts are widely used in aerospace.However,they are difficult to manufacture using mechanical cutting technology because of severe tool wear.Electrochemical jet machining is a promising technology to achieve high efficiency,because it has high machining flexibility and no machining tool wear.However,reports on the macro electrochemical jet machining of large size titanium alloy parts are very scarce,because it is difficult to achieve effective constraint of the flow field in macro electrochemical jet machining.In addition,titanium alloy is very sensitive to fluctuation of the flow field,and a turbulent flow field would lead to serious stray corrosion.This paper reports a series of investigations of the electrochemical jet machining of titanium alloy parts.Based on the flow analysis and experiments,the machining flow field was effectively constrained.TB6 titanium alloy part with a perimeter of one meter was machined.The machined surface was smooth with no obvious machining defects.The machining process was particularly stable with no obvious spark discharge.The research provides a reference for the application of electrochemical jet machining technology to achieve large allowance material removal in the machining of large titanium alloy parts.
文摘The ancient tacit knowledge behind the logic system permeated the culture and promoted numerous impactful inventions throughout the history. Traditional Chinese medicine with its effectiveness should also have stemmed out from such logic system. This article aims to rearticulate the underlying lucid multi-dimensional logic system, which faded in obscurity only because of time-out loss of the mid-right concept. Retracing this past tacit but important concept could uncover a multi-dimensional system over a point relating to all matters while capturing the central core of the matter. The seemingly unmanageable multidimensional logic was strengthened by verification processes which affirmed its further extensions, and made up the language of the people, the concepts of yin-yang(阴阳), and the development of extensions of Ba Gua(八卦) derivatives, which furthered the interpretation of the space-time properties and Chinese medicine.
基金the financial support from the Guangxi Natural Science Foundation(grant no.2021GXNSFDA075012,2023GXNSFGA026002)National Natural Science Foundation of China(52104298,22075073,52362027,52462029)Fundamental Research Funds for the Central Universities(531107051077).
文摘Stress accumulation is a key factor leading to sodium storage performance deterioration for NiSe_(2)-based anodes.Therefore,inhibiting the concentrated local stress during the sodiataion/desodiation process is crucial for acquiring stable NiSe2-based materials for sodium-ion batteries(SIBs),Herein,a stress dissipation strategy driven by architecture engineering is proposed,which can achieve ultrafast and ultralong sodium storage properties.Different from the conventional sphere-like or rod-like architecture,the three-dimensional(3D)flower-like NiSe_(2)@C composite is delicately designed and assembled with onedimensional nanorods and carbon framework.More importantly,the fundamental mechanism of improved structure stability is unveiled by simulations and experimental results simultaneously.It demonstrates that this designed multidimensional flower-like architecture with dispersed nanorods can balance the structural mismatch,avoid concentrated local strain,and relax the internal stress,mainly induced by the unavoidable volume variation during the repeated conversion processes.Moreover,it can provide more Na^(+)-storage sites and multi-directional migration pathways,leading to a fast Na^(+)-migration channel with boosted reaction kinetic.As expected,it delivers superior rate performance(441 mA h g^(-1)at 5.0 A g^(-1))and long cycling stability(563 mA h g^(-1)at 1.0 A g^(-1)over 1000 cycles)for SIBs.This work provides useful insights for designing high-performance conversion-based anode materials for SIBs.
