Constructing multi-dimensional hydrogen bond(H-bond)regulated single-molecule systems with multiemission remains a challenge.Herein,we report the design of a new excited-state intramolecular proton transfer(ESIPT)feat...Constructing multi-dimensional hydrogen bond(H-bond)regulated single-molecule systems with multiemission remains a challenge.Herein,we report the design of a new excited-state intramolecular proton transfer(ESIPT)featured chromophore(HBT-DPI)that shows flexible emission tunability via the multidimensional regulation of intra-and intermolecular H-bonds.The feature of switchable intramolecular Hbonds is induced via incorporating several hydrogen bond acceptors and donors into one single HBT-DPI molecule,allowing the“turn on/off”of ESIPT process by forming isomers with distinct intramolecular Hbonds configurations.In response to different external H-bonding environments,the obtained four types of crystal/cocrystals vary in the contents of isomers and the molecular packing modes,which are mainly guided by the intermolecular H-bonds,exhibiting non-emissive features or emissions ranging from green to orange.Utilizing the feature of intermolecular H-bond guided molecular packing,we demonstrate the utility of this fluorescent material for visualizing hydrophobic/hydrophilic areas on large-scale heterogeneous surfaces of modified poly(1,1-difluoroethylene)(PVDF)membranes and quantitatively estimating the surface hydrophobicity,providing a new approach for hydrophobicity/hydrophilicity monitoring and measurement.Overall,this study represents a new design strategy for constructing multi-dimensional hydrogen bond regulated ESIPT-based fluorescent materials that enable multiple emissions and unique applications.展开更多
Environmental covariates are the basis of predictive soil mapping.Their selection determines the performance of soil mapping to a great extent,especially in cases where the number of soil samples is limited but soil s...Environmental covariates are the basis of predictive soil mapping.Their selection determines the performance of soil mapping to a great extent,especially in cases where the number of soil samples is limited but soil spatial heterogeneity is high.In this study,we proposed an integrated method to select environmental covariates for predictive soil depth mapping.First,candidate variables that may influence the development of soil depth were selected based on pedogenetic knowledge.Second,three conventional methods(Pearson correlation analysis(PsCA),generalized additive models(GAMs),and Random Forest(RF))were used to generate optimal combinations of environmental covariates.Finally,three optimal combinations were integrated to produce a final combination based on the importance and occurrence frequency of each environmental covariate.We tested this method for soil depth mapping in the upper reaches of the Heihe River Basin in Northwest China.A total of 129 soil sampling sites were collected using a representative sampling strategy,and RF and support vector machine(SVM)models were used to map soil depth.The results showed that compared to the set of environmental covariates selected by the three conventional selection methods,the set of environmental covariates selected by the proposed method achieved higher mapping accuracy.The combination from the proposed method obtained a root mean square error(RMSE)of 11.88 cm,which was 2.25–7.64 cm lower than the other methods,and an R^2 value of 0.76,which was 0.08–0.26 higher than the other methods.The results suggest that our method can be used as an alternative to the conventional methods for soil depth mapping and may also be effective for mapping other soil properties.展开更多
A model integrating geo-information and self-organizing map(SOM) for exploring the database of soil environmental surveys was established. The dataset of 5 heavy metals(As, Cd, Cr, Hg, and Pb) was built by the regular...A model integrating geo-information and self-organizing map(SOM) for exploring the database of soil environmental surveys was established. The dataset of 5 heavy metals(As, Cd, Cr, Hg, and Pb) was built by the regular grid sampling in Hechi, Guangxi Zhuang Autonomous Region in southern China. Auxiliary datasets were collected throughout the study area to help interpret the potential causes of pollution. The main findings are as follows:(1) Soil samples of 5 elements exhibited strong variation and high skewness. High pollution risk existed in the case study area, especially Hg and Cd.(2) As and Pb had a similar topological distribution pattern, meaning they behaved similarly in the soil environment. Cr had behaviours in soil different from those of the other 4 elements.(3) From the U-matrix of SOM networks, 3 levels of SEQ were identified, and 11 high risk areas of soil heavy metal-contaminated were found throughout the study area, which were basically near rivers,factories, and ore zones.(4) The variations of contamination index(CI) followed the trend of construction land(1.353)> forestland(1.267)> cropland(1.175)> grassland(1.056), which suggest that decision makers should focus more on the problem of soil pollution surrounding industrial and mining enterprises and farmland.展开更多
With the research of the upcoming sixth generation(6 G) systems, new technologies will require wider bandwidth, larger scale antenna arrays and more diverse wireless communication scenarios on the future channel model...With the research of the upcoming sixth generation(6 G) systems, new technologies will require wider bandwidth, larger scale antenna arrays and more diverse wireless communication scenarios on the future channel modeling. Considering channel model is prerequisite for system design and performance evaluation of 6 G technologies, we face a challenging task: how to accurately and efficiently model 6 G channel for various scenarios? This paper tries to answer it. Firstly, the features of cluster-nuclei(CN) and principle of cluster-nuclei based channel model(CNCM) are introduced. Then, a novel modeling framework is proposed to implement CNCM,which consists four steps: propagation environment reconstruction, cluster-nuclei identification, multipath parameters generation, and channel coefficients generation. Three-dimensional environment with material information is utilized to map CN with scatterers in the propagation pathway. CN are identified by geometrical and electric field calculation based on environmental mapping, and multipath components within CN are calculated by statistical characteristics of angle, power and delay domains. Finally, we present a three-level verification structure to investigate the accuracy and complexity of channel modeling comprehensively. Simulation results reveal that CNCM can perform higher accuracy than geometrybased stochastic model while lower complexity compared with ray-tracing model for practical propagation environment.展开更多
The present study performed on the Angovia, Kokumbo, Hire and Agbaou sites consisted of mapping the environmental risks linked to artisanal gold mining activities in C?te d’Ivoire. An inventory was done by observing ...The present study performed on the Angovia, Kokumbo, Hire and Agbaou sites consisted of mapping the environmental risks linked to artisanal gold mining activities in C?te d’Ivoire. An inventory was done by observing the different phases of gold extraction and identifying the risks associated with these phases. Using a Geographic Information System (GIS), the representation of the spatial distribution of the pollution risks has been realized from indicator descriptives of the environmental sensitivity (i.e. slope, proximity to the watercourse, soil cover) and the transfer indicator (i.e. rainfall). The analysis of this map showed low sensitivity of mercury (Hg), arsenic (As), copper (Cu) and zinc (Zn) measured in the waters of the Hire and Agbaou localities, while moderate sensitivity in Kokumbo surface waters and high sensitivity for those of Angovia locality were observed. Moreover, analysis of Hg, As, Cu and Zn content spatial distribution maps in surface waters revealed that Hg and As come mainly from the artisanal mining activities for most localities. Among these metallic trace elements observed, only the Hg content was above the WHO Limit Values, 1994 (>0.001 mg·L-1). The continuous spread of metallic trace elements in surface water can pose serious health problems for people living around artisanal gold mining sites, hence the need to put in place a protection plan against contamination.展开更多
Noise pollution is one of the common physical harmful factors in many work environments.The current study aimed to assess personal and environmental sound pressure level and project the sound-Isosonic map in one of th...Noise pollution is one of the common physical harmful factors in many work environments.The current study aimed to assess personal and environmental sound pressure level and project the sound-Isosonic map in one of the Razavi Khorasan Paste manufacture using Surfer V.14 and Noise at work V.5.0.This cross-sectional,descrip-tive study is analytical that was conducted in 2018 in the Paste factory that contains Canister,production and Brewing unit.Following ISO 9612:2009,Casella Cel-320 was used to measure personal sound pressure level,while CEL-450 sound level meter(manufactured by Casella-Cel,the UK)was employed to assess environmental sound pressure level.Statistical analyzes was done using SPSS V.18 and Linear Regression test.The sound-isosonic maps were projected using Surfer V.14 and Noise at work V.5.0.The results of assessing personal sound pressure level indicated that the highest received dose(172.21%)and personal equivalent sound level(87.36 dBA)were recorded for workers in the Canister unit.According to results of measuring of the environmental sound pressure level,out of 16 measurement stations in this unit,overall 87.5%were regarded as danger and caution areas.The lowest and highest sound pressure levels in this units were 61 dBA and 92 dBA that belong to Brewing and Canister units respectively.Results indicate Over 75%of the Canister and production units had a sound pressure level greater than 85 dBA and these two units were regarded as the most dangerous area in terms of noise pollution.It is there-fore necessary to implement noise control measures,apply hearing protection program and auditory tests among workers in these units.展开更多
Artificial intelligence(AI)technology,with its powerful capabilities in data analysis,intelligent interaction,and personalized learning support,is creating new opportunities for the reform of education and teaching.Th...Artificial intelligence(AI)technology,with its powerful capabilities in data analysis,intelligent interaction,and personalized learning support,is creating new opportunities for the reform of education and teaching.Through the integration of online and offline blended teaching methods,this study utilizes a learning platform to analyze multi-source student learning data,assess knowledge mastery,and dynamically generate personalized learning paths.Abstract concepts are visualized via 3D modeling and dynamic simulation to enhance students'comprehension of microbiological knowledge.Knowledge mapping is employed to systematically organize course concepts and establish dynamic connections,aiding students in navigating complex and abstract knowledge structures.By leveraging an interactive learning platform,a multi-evaluation system incorporating dynamic assessment,teacher feedback,and student self-evaluation is established.This system evaluates learning outcomes through automated grading and intelligent analysis,while also delivering adaptive teaching resources tailored to individual student differences,so as to meet personalized learning need and stimulate students'interest and motivation.This study offers innovative insights for the curriculum reform of Environmental Engineering Microbiology in the context of emerging engineering education.展开更多
Connection methods are essential for integrating environmental factors with machine learning models for landslide susceptibility assessments.However,current research does not consider the different characteristics of ...Connection methods are essential for integrating environmental factors with machine learning models for landslide susceptibility assessments.However,current research does not consider the different characteristics of continuity and discreteness within environmental factors and therefore does not analyze the suitability of various connection methods for different factor types.Moreover,the applicability of connection methods remains unclear when slope units are used as the basic assessment units.This study employed slope units as mapping units.The original data of 15 environmental factors,including 12 continuous and three discrete factors,and two connection methods,i.e.,frequency ratio(FR)and modified FR(MFR),were separately used to construct the input datasets for landslide susceptibility modeling.The performance of four widely used machine learning models,random forest(RF),support vector machine(SVM),logistic regression(LR),and multilayer perceptron(MLP),was analyzed to evaluate the suitability of the connection methods for landslide susceptibility mapping.The results show that,in contrast to the decision tree-based RF model,the use of different connection methods for different factor types significantly influences the results of nontree models,including SVM,MLP,and LR.SVM model is the most sensitive to factor types and connection methods.When the MFR is used as the connection method,it improves the mapping results,especially for the SVM model.This shows that it is essential to consider the different characteristics of the data and select an appropriate environmental factor connection strategy to increase the effectiveness of landslide susceptibility evaluation.Furthermore,this study explored the role of connective methods from a sample distribution perspective,providing a theoretical foundation for the more rational and effective integration of environmental factors.展开更多
Giant Hogweed is a poisonous invasive weed in Latvia that poses significant threat to biodiversity and human health. Local residents are afraid and have very special concerns about the safety of their children because...Giant Hogweed is a poisonous invasive weed in Latvia that poses significant threat to biodiversity and human health. Local residents are afraid and have very special concerns about the safety of their children because the plant causes phytophotodermatitis (severe burns), painful blistering, permanent scarring and blindness when the sap of the plant comes in contact with the human body and is exposed to sunlight. This study utilizes public participation GIS (PPGIS) involving Latvian high school students as data collectors to monitor the geographic distribution of Giant Hogweed in Northeast Latvia. This paper also explores challenges with implementing such a public program, how to maximize participation, and how participation impacts environmental awareness of participants. In this study we also assessed the accuracy of PPGIS-collected data and how the utilization of such data impacts mapping and monitoring of Giant Hogweed in the study area. Results indicate that this PPGIS program is effective in facilitating data collection for monitoring Giant Hogweed in Latvia. Tested methods of increasing participation have proven largely unsuccessful to date. Statistical analyses of survey responses indicate participation had a marked effect on sensitivity towards environmental issues. Accuracy assessments indicate that quality of point data collected by participants is sufficient for mapping and for use as ground verification.展开更多
The field of environmental sciences is abundant with various interfaces and is the right place for the application of new fundamental approaches leading towards a better understanding of environmental phenomena. Follo...The field of environmental sciences is abundant with various interfaces and is the right place for the application of new fundamental approaches leading towards a better understanding of environmental phenomena. Following the definition of environmental interface by Mihailovic and Bala? [1], such interface can be, for example, placed between: human or animal bodies and surrounding air, aquatic species and water and air around them, and natural or artificially built surfaces (vegetation, ice, snow, barren soil, water, urban communities) and the atmosphere, cells and surrounding environment, etc. Complex environmental interface systems are (i) open and hierarchically organised (ii) interactions between their constituent parts are nonlinear, and (iii) their interaction with the surrounding environment is noisy. These systems are therefore very sensitive to initial conditions, deterministic external perturbations and random fluctuations always present in nature. The study of noisy non-equilibrium processes is fundamental for modelling the dynamics of environmental interface regarded as biophysical complex system and for understanding the mechanisms of spatio-temporal pattern formation in contemporary environmental sciences. In this paper we will investigate an aspect of dynamics of energy flow based on the energy balance equation. The energy exchange between interacting environmen- tal interfaces regarded as biophysical complex systems can be represented by coupled maps. Therefore, we will numerically investigate coupled maps representing that exchange. In ana- lysis of behaviour of these maps we applied Lyapunov exponent and cross sample entropy.展开更多
We have defined the environmental interface through the exchange processes between media forming this interface. Considering the environmental interface as a complex system we elaborated the advanced mathematical tool...We have defined the environmental interface through the exchange processes between media forming this interface. Considering the environmental interface as a complex system we elaborated the advanced mathematical tools for its modelling. We have suggested two coupled maps serving the exchange processes on the environmental interfaces spatially ranged from cellular to planetary level, i.e. 1) the map with diffusive coupling for energy exchange simulation and 2) the map with affinity, which is suitable for matter exchange processes at the cellular level. We have performed the dynamical analysis of the coupled maps using the Lyapunov exponent, cross sample as well as the permutation entropy in dependence on different map parameters. Finally, we discussed the map with affinity, which shows some features making it a promising toll in simulation of exchange processes on the environmental interface at the cellular level.展开更多
The development of modern cities has brought about tremendous changes in the climate environment.Faced with complex climate conditions,research on multi-scale climate change in cities is of great significance.The urba...The development of modern cities has brought about tremendous changes in the climate environment.Faced with complex climate conditions,research on multi-scale climate change in cities is of great significance.The urban environmental climate maps and the application of climate atlas tool in Stuttgart,Germany were studied,and the multi-scale application of urban environmental climate maps in Stuttgart,Germany was summarized through the analysis of the pre-planning,current construction situation,and landscape reconstruction of the German"Stuttgart 21"plan case.Besides,other important measures to cope with climate change in German were proposed,and finally multi-scale practical strategies to cope with urban climate and environment were summarized to provide ideas and methods for improving China’s future urban climate environment.展开更多
China’s public participation in environmental governance PPP projects has become a hot research issue.Based on the CiteSpace software,taking 1592 literatures collected by CNKI from 2000 to 2021 as samples,the paper v...China’s public participation in environmental governance PPP projects has become a hot research issue.Based on the CiteSpace software,taking 1592 literatures collected by CNKI from 2000 to 2021 as samples,the paper visually analyzes the literature timing,author distribution,institutional distribution,hot topics and evolution trends of Chinese public participation in environmental governance PPP project.After 20 years of development,the research focus of China’s public participation in environmental governance PPP project involves rural environmental governance,environmental diversification governance,regional environmental governance and environmental governance value-driven,and shows endogenous implicit drive and endogenous explicit drive.The multi-spiral characteristics of China’s public participation in environmental governance PPP coexist with endogenous implicit obstacles and exogenous implicit obstacles.展开更多
During emergency response to oil spills incident accurate information is required in order to reduce the risk associated with oil spill disasters. This study focuses on Environmental Sensitivity mapping for sustainabl...During emergency response to oil spills incident accurate information is required in order to reduce the risk associated with oil spill disasters. This study focuses on Environmental Sensitivity mapping for sustainable environmental clean-up and contingency planning along the 3.0 km of AGIP pipeline at Asemoku in Delta State, Nigeria. Geographic information systems (GIS) techniques were used to create an Environmental Sensitivity Index (ESI) map in the study area. A 2018 Google Earth Satellite imagery of the study area was downloaded, and landuse/cover classification scheme comprising of Vegetation, Farmland, Water Body, Wetland, built up area and Bare Surface was adopted. Existing categorization, ranking and classification of the inland habitat were adopted and used to create a Landuse/cover Environmental Sensitivity Index (ESI) map, while the buffer zones of 100 m, 200 m, 300 m and 400 m were adopted. In the ArcGIS 10.8 environment, the landuse/cover map was generated and buffer distances of 100 m, 200 m, 300 m and 400 m were created on the landuse/cover map to ascertain the features that are vulnerable and could be at risk in the event of oil spill. This study established that the Natural Vegetation areas are the most vulnerable and sensitive feature as a result of their size along the created buffer zones. Findings from this study thus provide insight into the most sensitive land-use/land-cover, in the event of a spill or emergency oil spill clean-up response.展开更多
Using newly developed methods and software, association mapping was conducted for chromium content and total sugar in tobacco leaf, based on four-omics datasets. Our objective was to collect data on genotype and pheno...Using newly developed methods and software, association mapping was conducted for chromium content and total sugar in tobacco leaf, based on four-omics datasets. Our objective was to collect data on genotype and phenotype for 60 leaf samples at four developmental stages, from three plant architectural positions and for three cultivars that were grown in two locations. Association mapping was conducted to detect genetic variants at quantitative trait SNP(QTS) loci, quantitative trait transcript(QTT) differences,quantitative trait protein(QTP) variability, and quantitative trait metabolite(QTM) changes,which can be summarized as QTX locus variation. The total heritabilities of the four-omics loci for both traits tested were 23.60% for epistasis and 15.26% for treatment interaction.Epistasis and environment × treatment interaction had important impacts on complex traits at all-omics levels. For decreasing chromium content and increasing total sugar in tobacco leaf, six methylated loci can be directly used for marker-assisted selection, and expression of ten QTTs, seven QTPs and six QTMs can be modified by selection or cultivation.展开更多
Conventional soil maps contain valuable knowledge on soil–environment relationships.Such knowledge can be extracted for use when updating conventional soil maps with improved environmental data.Existing methods take ...Conventional soil maps contain valuable knowledge on soil–environment relationships.Such knowledge can be extracted for use when updating conventional soil maps with improved environmental data.Existing methods take all polygons of the same map unit on a map as a whole to extract the soil–environment relationship.Such approach ignores the difference in the environmental conditions represented by individual soil polygons of the same map unit.This paper proposes a method of mining soil–environment relationships from individual soil polygons to update conventional soil maps.The proposed method consists of three major steps.Firstly,the soil–environment relationships represented by each individual polygon on a conventional soil map are extracted in the form of frequency distribution curves for the involved environmental covariates.Secondly,for each environmental covariate,these frequency distribution curves from individual polygons of the same soil map unit are synthesized to form the overall soil–environment relationship for that soil map unit across the mapped area.And lastly,the extracted soil–environment relationships are applied to updating the conventional soil map with new,improved environmental data by adopting a soil land inference model(SoLIM)framework.This study applied the proposed method to updating a conventional soil map of the Raffelson watershed in La Crosse County,Wisconsin,United States.The result from the proposed method was compared with that from the previous method of taking all polygons within the same soil map unit on a map as a whole.Evaluation results with independent soil samples showed that the proposed method exhibited better performance and produced higher accuracy.展开更多
Measuring the amount of vegetation in a given area on a large scale has long been accomplished using satellite and aerial imaging systems.These methods have been very reliable in measuring vegetation coverage accurate...Measuring the amount of vegetation in a given area on a large scale has long been accomplished using satellite and aerial imaging systems.These methods have been very reliable in measuring vegetation coverage accurately at the top of the canopy,but their capabilities are limited when it comes to identifying green vegetation located beneath the canopy cover.Measuring the amount of urban and suburban vegetation along a street network that is partially beneath the canopy has recently been introduced with the use of Google Street View(GSV)images,made accessible by the Google Street View Image API.Analyzing green vegetation through the use of GSV images can provide a comprehensive representation of the amount of green vegetation found within geographical regions of higher population density,and it facilitates an analysis performed at the street-level.In this paper we propose a fine-tuned color based image filtering and segmentation technique and we use it to define and map an urban green environment index.We deployed this image processing method and,using GSV images as a high-resolution GIS data source,we computed and mapped the green index of Milwaukee County,a 3,082 km^(2) urban/suburban county in Wisconsin.This approach generates a high-resolution street-level vegetation estimate that may prove valuable in urban planning and management,as well as for researchers investigating the correlation between environmental factors and human health outcomes.展开更多
Based on the mapping of groundwater resources and environmental geology in China and its surrounding regions, Groundwater Ecological Environment Map of Asia is drawn to broadly reflect the ecological situation of Asia...Based on the mapping of groundwater resources and environmental geology in China and its surrounding regions, Groundwater Ecological Environment Map of Asia is drawn to broadly reflect the ecological situation of Asian groundwater, categorize its ecological environment into three basic types and elaborate the research categories. This paper analyzes and summarizes the major characteristics and distribution regularities of the groundwater ecological environment of Asia to reveal the key related problem so as to provide a necessary reference for the construction and planning of One Belt and One Road.展开更多
To make clear the wear conditions of ATM (Automatic Teller Machine) tribosystem when servicing in Chi- nese sand dust environment, abrasive wear of two kinds of polymer tapes specified for ATM, PI (Polyimide) and PEN ...To make clear the wear conditions of ATM (Automatic Teller Machine) tribosystem when servicing in Chi- nese sand dust environment, abrasive wear of two kinds of polymer tapes specified for ATM, PI (Polyimide) and PEN (Polyethylene-2, 6-naphthalenedicarboxylate), was investigated in simulated sand dust environment with ATM tape-scraper tribosystem under various conditions of loads and sliding distances. The surface profiles of worn tape were measured with a surface profiler in order to calculating the wear cross-section areas and the wear volumes. The specific wear rates of polymer tapes were calculated under load conditions of 0.6, 1 and 1.5 N, and wear mechanisms were in- vestigated with optical topography photos. As main results, the specific wear rates show stage variations in the wear process and the wear resistance of polymer tape shows good relationship with the mechanical deformation factors. In consideration of the service life, four wear models are generalized according to the magnitude of specific wear rates, which include no wear, mild wear, normal wear and severe wear model and the corresponding wear mechanisms for the four wear models are discussed with typical worn topographies. Based on the wear models and corresponding wear mechanisms, the abrasive wear maps of two polymer tapes servicing in sand dust environments are concluded for its industrial applications.展开更多
The study of multi-dimensional expansion of urban space(MEUS) addresses the laws of urban spatial expansion from all directions and angles. Using Nanjing as an example,this paper constructs multi-temporal, urban three...The study of multi-dimensional expansion of urban space(MEUS) addresses the laws of urban spatial expansion from all directions and angles. Using Nanjing as an example,this paper constructs multi-temporal, urban three-dimensional models based on RS and GIS technology and then conducts qualitative and quantitative analysis of MEUS using plot ratio change maps and MEUS quantitative index for built-up areas. Based especially on the concept of volume growth contribution rate, this paper analyzes the characteristics of MEUS in different stages. The results show that in 2000–2004, planar expansion played the main role,the internal potential development(IPD) intensity of the urban built-up areas was relatively large, and the volume growth contribution rate was low; in 2004–2008, planar expansion accelerated, and IPD slowed down; in 2008–2012, planar expansion slowed while IPD intensity increased; the contribution rates of volume growth of urban IPD for the three periods were 22.21%, 24.51% and 73.38%, respectively. This study expands the research perspective of urban spatial expansion, and the adopted methods are instructive and meaningful for MEUS research. In addition, the results of this study will deepen the understanding of MEUS laws and help improve scientific decision-making for urban planning and urban land use management.展开更多
基金supported by the National Key R&D Program of China(No.2021YFC2103600)the National Natural Science Foundation of China(Nos.21878156,21978131,22275085,and 22278224)+2 种基金the Natural Science Foundation of Jiangsu Province(Nos.BK20200089 and BK20200691)the Project of Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)the State Key Laboratory of Materials-Oriented Chemical Engineering(No.KL21-08).
文摘Constructing multi-dimensional hydrogen bond(H-bond)regulated single-molecule systems with multiemission remains a challenge.Herein,we report the design of a new excited-state intramolecular proton transfer(ESIPT)featured chromophore(HBT-DPI)that shows flexible emission tunability via the multidimensional regulation of intra-and intermolecular H-bonds.The feature of switchable intramolecular Hbonds is induced via incorporating several hydrogen bond acceptors and donors into one single HBT-DPI molecule,allowing the“turn on/off”of ESIPT process by forming isomers with distinct intramolecular Hbonds configurations.In response to different external H-bonding environments,the obtained four types of crystal/cocrystals vary in the contents of isomers and the molecular packing modes,which are mainly guided by the intermolecular H-bonds,exhibiting non-emissive features or emissions ranging from green to orange.Utilizing the feature of intermolecular H-bond guided molecular packing,we demonstrate the utility of this fluorescent material for visualizing hydrophobic/hydrophilic areas on large-scale heterogeneous surfaces of modified poly(1,1-difluoroethylene)(PVDF)membranes and quantitatively estimating the surface hydrophobicity,providing a new approach for hydrophobicity/hydrophilicity monitoring and measurement.Overall,this study represents a new design strategy for constructing multi-dimensional hydrogen bond regulated ESIPT-based fluorescent materials that enable multiple emissions and unique applications.
基金supported financially by the National Natural Science Foundation of China (91325301, 41571212 and 41137224)the Project of "One-Three-Five" Strategic Planning & Frontier Sciences of the Institute of Soil Science, Chinese Academy of Sciences (ISSASIP1622)the National Key Basic Research Special Foundation of China (2012FY112100)
文摘Environmental covariates are the basis of predictive soil mapping.Their selection determines the performance of soil mapping to a great extent,especially in cases where the number of soil samples is limited but soil spatial heterogeneity is high.In this study,we proposed an integrated method to select environmental covariates for predictive soil depth mapping.First,candidate variables that may influence the development of soil depth were selected based on pedogenetic knowledge.Second,three conventional methods(Pearson correlation analysis(PsCA),generalized additive models(GAMs),and Random Forest(RF))were used to generate optimal combinations of environmental covariates.Finally,three optimal combinations were integrated to produce a final combination based on the importance and occurrence frequency of each environmental covariate.We tested this method for soil depth mapping in the upper reaches of the Heihe River Basin in Northwest China.A total of 129 soil sampling sites were collected using a representative sampling strategy,and RF and support vector machine(SVM)models were used to map soil depth.The results showed that compared to the set of environmental covariates selected by the three conventional selection methods,the set of environmental covariates selected by the proposed method achieved higher mapping accuracy.The combination from the proposed method obtained a root mean square error(RMSE)of 11.88 cm,which was 2.25–7.64 cm lower than the other methods,and an R^2 value of 0.76,which was 0.08–0.26 higher than the other methods.The results suggest that our method can be used as an alternative to the conventional methods for soil depth mapping and may also be effective for mapping other soil properties.
基金Strategic Priority Research Program of the Chinese Academy of Sciences,No.XDA19040302The Key Research Program of the Chinese Academy of Sciences,No.KFZD-SW-111
文摘A model integrating geo-information and self-organizing map(SOM) for exploring the database of soil environmental surveys was established. The dataset of 5 heavy metals(As, Cd, Cr, Hg, and Pb) was built by the regular grid sampling in Hechi, Guangxi Zhuang Autonomous Region in southern China. Auxiliary datasets were collected throughout the study area to help interpret the potential causes of pollution. The main findings are as follows:(1) Soil samples of 5 elements exhibited strong variation and high skewness. High pollution risk existed in the case study area, especially Hg and Cd.(2) As and Pb had a similar topological distribution pattern, meaning they behaved similarly in the soil environment. Cr had behaviours in soil different from those of the other 4 elements.(3) From the U-matrix of SOM networks, 3 levels of SEQ were identified, and 11 high risk areas of soil heavy metal-contaminated were found throughout the study area, which were basically near rivers,factories, and ore zones.(4) The variations of contamination index(CI) followed the trend of construction land(1.353)> forestland(1.267)> cropland(1.175)> grassland(1.056), which suggest that decision makers should focus more on the problem of soil pollution surrounding industrial and mining enterprises and farmland.
基金supported by National Science Fund for Distinguished Young Scholars (No.61925102)Beijing University of Posts and TelecommunicationsChina Mobile Research Institute Joint Innovation Center。
文摘With the research of the upcoming sixth generation(6 G) systems, new technologies will require wider bandwidth, larger scale antenna arrays and more diverse wireless communication scenarios on the future channel modeling. Considering channel model is prerequisite for system design and performance evaluation of 6 G technologies, we face a challenging task: how to accurately and efficiently model 6 G channel for various scenarios? This paper tries to answer it. Firstly, the features of cluster-nuclei(CN) and principle of cluster-nuclei based channel model(CNCM) are introduced. Then, a novel modeling framework is proposed to implement CNCM,which consists four steps: propagation environment reconstruction, cluster-nuclei identification, multipath parameters generation, and channel coefficients generation. Three-dimensional environment with material information is utilized to map CN with scatterers in the propagation pathway. CN are identified by geometrical and electric field calculation based on environmental mapping, and multipath components within CN are calculated by statistical characteristics of angle, power and delay domains. Finally, we present a three-level verification structure to investigate the accuracy and complexity of channel modeling comprehensively. Simulation results reveal that CNCM can perform higher accuracy than geometrybased stochastic model while lower complexity compared with ray-tracing model for practical propagation environment.
文摘The present study performed on the Angovia, Kokumbo, Hire and Agbaou sites consisted of mapping the environmental risks linked to artisanal gold mining activities in C?te d’Ivoire. An inventory was done by observing the different phases of gold extraction and identifying the risks associated with these phases. Using a Geographic Information System (GIS), the representation of the spatial distribution of the pollution risks has been realized from indicator descriptives of the environmental sensitivity (i.e. slope, proximity to the watercourse, soil cover) and the transfer indicator (i.e. rainfall). The analysis of this map showed low sensitivity of mercury (Hg), arsenic (As), copper (Cu) and zinc (Zn) measured in the waters of the Hire and Agbaou localities, while moderate sensitivity in Kokumbo surface waters and high sensitivity for those of Angovia locality were observed. Moreover, analysis of Hg, As, Cu and Zn content spatial distribution maps in surface waters revealed that Hg and As come mainly from the artisanal mining activities for most localities. Among these metallic trace elements observed, only the Hg content was above the WHO Limit Values, 1994 (>0.001 mg·L-1). The continuous spread of metallic trace elements in surface water can pose serious health problems for people living around artisanal gold mining sites, hence the need to put in place a protection plan against contamination.
文摘Noise pollution is one of the common physical harmful factors in many work environments.The current study aimed to assess personal and environmental sound pressure level and project the sound-Isosonic map in one of the Razavi Khorasan Paste manufacture using Surfer V.14 and Noise at work V.5.0.This cross-sectional,descrip-tive study is analytical that was conducted in 2018 in the Paste factory that contains Canister,production and Brewing unit.Following ISO 9612:2009,Casella Cel-320 was used to measure personal sound pressure level,while CEL-450 sound level meter(manufactured by Casella-Cel,the UK)was employed to assess environmental sound pressure level.Statistical analyzes was done using SPSS V.18 and Linear Regression test.The sound-isosonic maps were projected using Surfer V.14 and Noise at work V.5.0.The results of assessing personal sound pressure level indicated that the highest received dose(172.21%)and personal equivalent sound level(87.36 dBA)were recorded for workers in the Canister unit.According to results of measuring of the environmental sound pressure level,out of 16 measurement stations in this unit,overall 87.5%were regarded as danger and caution areas.The lowest and highest sound pressure levels in this units were 61 dBA and 92 dBA that belong to Brewing and Canister units respectively.Results indicate Over 75%of the Canister and production units had a sound pressure level greater than 85 dBA and these two units were regarded as the most dangerous area in terms of noise pollution.It is there-fore necessary to implement noise control measures,apply hearing protection program and auditory tests among workers in these units.
基金Supported by Higher Education Teaching Reform Project of Zhaoqing University(zlgc2024058).
文摘Artificial intelligence(AI)technology,with its powerful capabilities in data analysis,intelligent interaction,and personalized learning support,is creating new opportunities for the reform of education and teaching.Through the integration of online and offline blended teaching methods,this study utilizes a learning platform to analyze multi-source student learning data,assess knowledge mastery,and dynamically generate personalized learning paths.Abstract concepts are visualized via 3D modeling and dynamic simulation to enhance students'comprehension of microbiological knowledge.Knowledge mapping is employed to systematically organize course concepts and establish dynamic connections,aiding students in navigating complex and abstract knowledge structures.By leveraging an interactive learning platform,a multi-evaluation system incorporating dynamic assessment,teacher feedback,and student self-evaluation is established.This system evaluates learning outcomes through automated grading and intelligent analysis,while also delivering adaptive teaching resources tailored to individual student differences,so as to meet personalized learning need and stimulate students'interest and motivation.This study offers innovative insights for the curriculum reform of Environmental Engineering Microbiology in the context of emerging engineering education.
基金supported by the National Key Research and Development Program of China(No.2023YFC3007202)Joint Research Project on Meteorological Capacity Enhancement of the China Meteorological Administration(No.23NLTSZ009)Project of the Department of Science and Technology of Sichuan Province(No.2024YFHZ0098)。
文摘Connection methods are essential for integrating environmental factors with machine learning models for landslide susceptibility assessments.However,current research does not consider the different characteristics of continuity and discreteness within environmental factors and therefore does not analyze the suitability of various connection methods for different factor types.Moreover,the applicability of connection methods remains unclear when slope units are used as the basic assessment units.This study employed slope units as mapping units.The original data of 15 environmental factors,including 12 continuous and three discrete factors,and two connection methods,i.e.,frequency ratio(FR)and modified FR(MFR),were separately used to construct the input datasets for landslide susceptibility modeling.The performance of four widely used machine learning models,random forest(RF),support vector machine(SVM),logistic regression(LR),and multilayer perceptron(MLP),was analyzed to evaluate the suitability of the connection methods for landslide susceptibility mapping.The results show that,in contrast to the decision tree-based RF model,the use of different connection methods for different factor types significantly influences the results of nontree models,including SVM,MLP,and LR.SVM model is the most sensitive to factor types and connection methods.When the MFR is used as the connection method,it improves the mapping results,especially for the SVM model.This shows that it is essential to consider the different characteristics of the data and select an appropriate environmental factor connection strategy to increase the effectiveness of landslide susceptibility evaluation.Furthermore,this study explored the role of connective methods from a sample distribution perspective,providing a theoretical foundation for the more rational and effective integration of environmental factors.
文摘Giant Hogweed is a poisonous invasive weed in Latvia that poses significant threat to biodiversity and human health. Local residents are afraid and have very special concerns about the safety of their children because the plant causes phytophotodermatitis (severe burns), painful blistering, permanent scarring and blindness when the sap of the plant comes in contact with the human body and is exposed to sunlight. This study utilizes public participation GIS (PPGIS) involving Latvian high school students as data collectors to monitor the geographic distribution of Giant Hogweed in Northeast Latvia. This paper also explores challenges with implementing such a public program, how to maximize participation, and how participation impacts environmental awareness of participants. In this study we also assessed the accuracy of PPGIS-collected data and how the utilization of such data impacts mapping and monitoring of Giant Hogweed in the study area. Results indicate that this PPGIS program is effective in facilitating data collection for monitoring Giant Hogweed in Latvia. Tested methods of increasing participation have proven largely unsuccessful to date. Statistical analyses of survey responses indicate participation had a marked effect on sensitivity towards environmental issues. Accuracy assessments indicate that quality of point data collected by participants is sufficient for mapping and for use as ground verification.
基金funded by the Serbian Ministry of Science and Technology under the project No.III 43007“Research of climate changes and their impact on environment.Monitoring of the impact,adaptation and moderation”for 2011-2014.
文摘The field of environmental sciences is abundant with various interfaces and is the right place for the application of new fundamental approaches leading towards a better understanding of environmental phenomena. Following the definition of environmental interface by Mihailovic and Bala? [1], such interface can be, for example, placed between: human or animal bodies and surrounding air, aquatic species and water and air around them, and natural or artificially built surfaces (vegetation, ice, snow, barren soil, water, urban communities) and the atmosphere, cells and surrounding environment, etc. Complex environmental interface systems are (i) open and hierarchically organised (ii) interactions between their constituent parts are nonlinear, and (iii) their interaction with the surrounding environment is noisy. These systems are therefore very sensitive to initial conditions, deterministic external perturbations and random fluctuations always present in nature. The study of noisy non-equilibrium processes is fundamental for modelling the dynamics of environmental interface regarded as biophysical complex system and for understanding the mechanisms of spatio-temporal pattern formation in contemporary environmental sciences. In this paper we will investigate an aspect of dynamics of energy flow based on the energy balance equation. The energy exchange between interacting environmen- tal interfaces regarded as biophysical complex systems can be represented by coupled maps. Therefore, we will numerically investigate coupled maps representing that exchange. In ana- lysis of behaviour of these maps we applied Lyapunov exponent and cross sample entropy.
文摘We have defined the environmental interface through the exchange processes between media forming this interface. Considering the environmental interface as a complex system we elaborated the advanced mathematical tools for its modelling. We have suggested two coupled maps serving the exchange processes on the environmental interfaces spatially ranged from cellular to planetary level, i.e. 1) the map with diffusive coupling for energy exchange simulation and 2) the map with affinity, which is suitable for matter exchange processes at the cellular level. We have performed the dynamical analysis of the coupled maps using the Lyapunov exponent, cross sample as well as the permutation entropy in dependence on different map parameters. Finally, we discussed the map with affinity, which shows some features making it a promising toll in simulation of exchange processes on the environmental interface at the cellular level.
基金Sponsored by General Project of Natural Science Foundation of Beijing City(8202017)。
文摘The development of modern cities has brought about tremendous changes in the climate environment.Faced with complex climate conditions,research on multi-scale climate change in cities is of great significance.The urban environmental climate maps and the application of climate atlas tool in Stuttgart,Germany were studied,and the multi-scale application of urban environmental climate maps in Stuttgart,Germany was summarized through the analysis of the pre-planning,current construction situation,and landscape reconstruction of the German"Stuttgart 21"plan case.Besides,other important measures to cope with climate change in German were proposed,and finally multi-scale practical strategies to cope with urban climate and environment were summarized to provide ideas and methods for improving China’s future urban climate environment.
文摘China’s public participation in environmental governance PPP projects has become a hot research issue.Based on the CiteSpace software,taking 1592 literatures collected by CNKI from 2000 to 2021 as samples,the paper visually analyzes the literature timing,author distribution,institutional distribution,hot topics and evolution trends of Chinese public participation in environmental governance PPP project.After 20 years of development,the research focus of China’s public participation in environmental governance PPP project involves rural environmental governance,environmental diversification governance,regional environmental governance and environmental governance value-driven,and shows endogenous implicit drive and endogenous explicit drive.The multi-spiral characteristics of China’s public participation in environmental governance PPP coexist with endogenous implicit obstacles and exogenous implicit obstacles.
文摘During emergency response to oil spills incident accurate information is required in order to reduce the risk associated with oil spill disasters. This study focuses on Environmental Sensitivity mapping for sustainable environmental clean-up and contingency planning along the 3.0 km of AGIP pipeline at Asemoku in Delta State, Nigeria. Geographic information systems (GIS) techniques were used to create an Environmental Sensitivity Index (ESI) map in the study area. A 2018 Google Earth Satellite imagery of the study area was downloaded, and landuse/cover classification scheme comprising of Vegetation, Farmland, Water Body, Wetland, built up area and Bare Surface was adopted. Existing categorization, ranking and classification of the inland habitat were adopted and used to create a Landuse/cover Environmental Sensitivity Index (ESI) map, while the buffer zones of 100 m, 200 m, 300 m and 400 m were adopted. In the ArcGIS 10.8 environment, the landuse/cover map was generated and buffer distances of 100 m, 200 m, 300 m and 400 m were created on the landuse/cover map to ascertain the features that are vulnerable and could be at risk in the event of oil spill. This study established that the Natural Vegetation areas are the most vulnerable and sensitive feature as a result of their size along the created buffer zones. Findings from this study thus provide insight into the most sensitive land-use/land-cover, in the event of a spill or emergency oil spill clean-up response.
基金supported by the National Basic Research Program of China (2011CB109306 and 2009CB118404)the Program of Introducing Talents of Discipline to Universities of China ("111" Project, B06014)Research Programs (CNTC-D2011100, CNTC-[2012]146, NY-[2011]3047, QKHRZ [2013] 02)
文摘Using newly developed methods and software, association mapping was conducted for chromium content and total sugar in tobacco leaf, based on four-omics datasets. Our objective was to collect data on genotype and phenotype for 60 leaf samples at four developmental stages, from three plant architectural positions and for three cultivars that were grown in two locations. Association mapping was conducted to detect genetic variants at quantitative trait SNP(QTS) loci, quantitative trait transcript(QTT) differences,quantitative trait protein(QTP) variability, and quantitative trait metabolite(QTM) changes,which can be summarized as QTX locus variation. The total heritabilities of the four-omics loci for both traits tested were 23.60% for epistasis and 15.26% for treatment interaction.Epistasis and environment × treatment interaction had important impacts on complex traits at all-omics levels. For decreasing chromium content and increasing total sugar in tobacco leaf, six methylated loci can be directly used for marker-assisted selection, and expression of ten QTTs, seven QTPs and six QTMs can be modified by selection or cultivation.
基金supported by the National Natural Science Foundation of China (41431177 and 41422109)the Innovation Project of State Key Laboratory of Resources and Environmental Information System of China (O88RA20CYA)the Outstanding Innovation Team in Colleges and Universities in Jiangsu Province, China
文摘Conventional soil maps contain valuable knowledge on soil–environment relationships.Such knowledge can be extracted for use when updating conventional soil maps with improved environmental data.Existing methods take all polygons of the same map unit on a map as a whole to extract the soil–environment relationship.Such approach ignores the difference in the environmental conditions represented by individual soil polygons of the same map unit.This paper proposes a method of mining soil–environment relationships from individual soil polygons to update conventional soil maps.The proposed method consists of three major steps.Firstly,the soil–environment relationships represented by each individual polygon on a conventional soil map are extracted in the form of frequency distribution curves for the involved environmental covariates.Secondly,for each environmental covariate,these frequency distribution curves from individual polygons of the same soil map unit are synthesized to form the overall soil–environment relationship for that soil map unit across the mapped area.And lastly,the extracted soil–environment relationships are applied to updating the conventional soil map with new,improved environmental data by adopting a soil land inference model(SoLIM)framework.This study applied the proposed method to updating a conventional soil map of the Raffelson watershed in La Crosse County,Wisconsin,United States.The result from the proposed method was compared with that from the previous method of taking all polygons within the same soil map unit on a map as a whole.Evaluation results with independent soil samples showed that the proposed method exhibited better performance and produced higher accuracy.
基金This work was supported by the National Science Foundation [DUE-1129056]This research was completed under the University of Wisconsin-Milwaukee’s Undergraduate Research in Biology and Mathematics(UBM)Program and was supported by a grant from the National Science Foundation DUE-1129056.Additional support was provided from the University of Wisconsin-Milwaukee’s Support For Undergraduate Research Fellowship(SURF),issued by UW-Milwaukee’s Office of Undergraduate Research.The authors of this paper would like to thank Prof.Gabriella Pinter,Prof.Erica Young and Prof.John Berges for their invaluable support.Finally,the authors would like recognize Google LLC for its publicly available image resource and street view API,without which this investigation would not have been possible.
文摘Measuring the amount of vegetation in a given area on a large scale has long been accomplished using satellite and aerial imaging systems.These methods have been very reliable in measuring vegetation coverage accurately at the top of the canopy,but their capabilities are limited when it comes to identifying green vegetation located beneath the canopy cover.Measuring the amount of urban and suburban vegetation along a street network that is partially beneath the canopy has recently been introduced with the use of Google Street View(GSV)images,made accessible by the Google Street View Image API.Analyzing green vegetation through the use of GSV images can provide a comprehensive representation of the amount of green vegetation found within geographical regions of higher population density,and it facilitates an analysis performed at the street-level.In this paper we propose a fine-tuned color based image filtering and segmentation technique and we use it to define and map an urban green environment index.We deployed this image processing method and,using GSV images as a high-resolution GIS data source,we computed and mapped the green index of Milwaukee County,a 3,082 km^(2) urban/suburban county in Wisconsin.This approach generates a high-resolution street-level vegetation estimate that may prove valuable in urban planning and management,as well as for researchers investigating the correlation between environmental factors and human health outcomes.
基金supported by Geological Map of Groundwater Resources and Environments of China and Surrounding Areas(12120113014200)Series Maps of Karst environment geology of China and South East Asia(12120114006401,12120114006301)
文摘Based on the mapping of groundwater resources and environmental geology in China and its surrounding regions, Groundwater Ecological Environment Map of Asia is drawn to broadly reflect the ecological situation of Asian groundwater, categorize its ecological environment into three basic types and elaborate the research categories. This paper analyzes and summarizes the major characteristics and distribution regularities of the groundwater ecological environment of Asia to reveal the key related problem so as to provide a necessary reference for the construction and planning of One Belt and One Road.
基金Project 59974030 supported by National Natural Science Foundation of China and by Mechanical Engineering Research Laboratory, Hitachi Ltd of Japan
文摘To make clear the wear conditions of ATM (Automatic Teller Machine) tribosystem when servicing in Chi- nese sand dust environment, abrasive wear of two kinds of polymer tapes specified for ATM, PI (Polyimide) and PEN (Polyethylene-2, 6-naphthalenedicarboxylate), was investigated in simulated sand dust environment with ATM tape-scraper tribosystem under various conditions of loads and sliding distances. The surface profiles of worn tape were measured with a surface profiler in order to calculating the wear cross-section areas and the wear volumes. The specific wear rates of polymer tapes were calculated under load conditions of 0.6, 1 and 1.5 N, and wear mechanisms were in- vestigated with optical topography photos. As main results, the specific wear rates show stage variations in the wear process and the wear resistance of polymer tape shows good relationship with the mechanical deformation factors. In consideration of the service life, four wear models are generalized according to the magnitude of specific wear rates, which include no wear, mild wear, normal wear and severe wear model and the corresponding wear mechanisms for the four wear models are discussed with typical worn topographies. Based on the wear models and corresponding wear mechanisms, the abrasive wear maps of two polymer tapes servicing in sand dust environments are concluded for its industrial applications.
基金National Natural Science Foundation of China,No.41871178,No.41671385,No.41371172
文摘The study of multi-dimensional expansion of urban space(MEUS) addresses the laws of urban spatial expansion from all directions and angles. Using Nanjing as an example,this paper constructs multi-temporal, urban three-dimensional models based on RS and GIS technology and then conducts qualitative and quantitative analysis of MEUS using plot ratio change maps and MEUS quantitative index for built-up areas. Based especially on the concept of volume growth contribution rate, this paper analyzes the characteristics of MEUS in different stages. The results show that in 2000–2004, planar expansion played the main role,the internal potential development(IPD) intensity of the urban built-up areas was relatively large, and the volume growth contribution rate was low; in 2004–2008, planar expansion accelerated, and IPD slowed down; in 2008–2012, planar expansion slowed while IPD intensity increased; the contribution rates of volume growth of urban IPD for the three periods were 22.21%, 24.51% and 73.38%, respectively. This study expands the research perspective of urban spatial expansion, and the adopted methods are instructive and meaningful for MEUS research. In addition, the results of this study will deepen the understanding of MEUS laws and help improve scientific decision-making for urban planning and urban land use management.
