The dynamics of inviscid multi-component relativistic fluids may be modeled by the relativistic Euler equations, augmented by one (or more) additional species equation(s). We use the high-resolution staggered central ...The dynamics of inviscid multi-component relativistic fluids may be modeled by the relativistic Euler equations, augmented by one (or more) additional species equation(s). We use the high-resolution staggered central schemes to solve these equations. The equilibrium states for each component are coupled in space and time to have a common temperature and velocity. The current schemes can handle strong shocks and the oscillations near the interfaces are negligible, which usually happens in the multi-component flows. The schemes also guarantee the exact mass conservation for each component, the exact conservation of total momentum, and energy in the whole particle system. The central schemes are robust, reliable, compact and easy to implement. Several one- and two-dimensional numerical test cases are included in this paper, which validate the application of these schemes to relativistic multi-component flows.展开更多
Carbenes as one of the most important class of intermediates have been widely utilized in various organic synthetic transformations.Carbene insertion-initiated ring-opening reactions of cyclic ethers offer a valuable ...Carbenes as one of the most important class of intermediates have been widely utilized in various organic synthetic transformations.Carbene insertion-initiated ring-opening reactions of cyclic ethers offer a valuable strategy for constructing new carbon-oxygen bonds.In comparison with traditional thermal or metal-mediated carbene transfer reactions,visible-light-promoted multi-component reaction strategy provides a mild and eco-friendly approach to access densely functionalized molecules.Recently,visible-light-induced multi-component carbene transfer reactions of diazo compounds have been rapidly developed and attracted a great deal of research interest of chemists owing to their advantages of simple operation,mild condition,high atom economy and rich structural diversity.This paper summarizes the recent research progress on the visible-light-promoted multi-component carbene transfer reactions of diazo compounds via ring-opening of cyclic ethers with various nucleophiles.The reaction patterns of different nucleophiles and their corresponding mechanism are described in this review.The future research direction and challenges in this area are also discussed.展开更多
We extend the traditional kinetic scheme for ideal gases to the Euler equations with the equation of state for a multi-component stiffened gas. Based on a careful analysis of the oscillation mechanism of the tradition...We extend the traditional kinetic scheme for ideal gases to the Euler equations with the equation of state for a multi-component stiffened gas. Based on a careful analysis of the oscillation mechanism of the traditional kinetic scheme across contact discontinuities, we propose a new non-oscillatory kinetic （NOK） scheme for multi-component stiffened gases. The basic idea in the construction is to use a flux splitting technique to construct numerical fluxes which do not depend on the concrete form of the equilibrium state. The new scheme can not only can avoid spurious oscillations of the pressure and velocity near a material interface which are observed in the traditional kinetic schemes such as the kinetic flux vector splitting （KFVS） and BGK schemes, but also can deal with the stiffened gas equation of state. Moreover, we also carry out a careful analysis on the consistency condition, truncation error and positivity of the NOK scheme. A number of 1D and 2D numerical tests are presented which demonstrate the accuracy and robustness of the new scheme in the simulation of problems with smooth, weak and strong shock wave regions.展开更多
In the realm of nonlinear integrable systems,the presence of decompositions facilitates the establishment of linear superposition solutions and the derivation of novel coupled systems exhibiting nonlinear integrabilit...In the realm of nonlinear integrable systems,the presence of decompositions facilitates the establishment of linear superposition solutions and the derivation of novel coupled systems exhibiting nonlinear integrability.By focusing on single-component decompositions within the potential BKP hierarchy,it has been observed that specific linear superpositions of decomposition solutions remain consistent with the underlying equations.Moreover,through the implementation of multi-component decompositions within the potential BKP hierarchy,successful endeavors have been undertaken to formulate linear superposition solutions and novel coupled Kd V-type systems that resist decoupling via alterations in dependent variables.展开更多
Multi-component transition group metal borides(MMB_(2))have become a research hotspot due to their new composition design concepts and superior properties compared with conventional ceramics.Most of the current method...Multi-component transition group metal borides(MMB_(2))have become a research hotspot due to their new composition design concepts and superior properties compared with conventional ceramics.Most of the current methods,however,are complicated and time-consuming,the mass production remains a chal-lenge.Herein,we proposed a new high-efficiency strategy for synthesis of MMB_(2)using molten aluminum as the medium for the first time.The prepared Al-containing multi-component borides(TiZrHfNbTa)B_(2)microcrystals had a homogeneous composition with a hexagonal AlB_(2)structure and ultra-high hardness value of∼35.3 GPa,which was much higher than data reported in the literature and the rule of mix-ture estimations.Furthermore,combined with the First-principles calculation results,we found that the Poisson’s ratio(v)values exhibit a clearly ascending trend from 0.17 at VEC=3.5 to 0.18 at VEC=3.4,then to 0.201 at VEC=3.2 with the increasing of Al content.This indicates that the intrinsic toughness of multi-component boride microcrystals is obviously enhanced by the trace-doped Al elements.Besides,the fabricated Al-containing multi-component boride microcrystals have superior oxidation activation en-ergy and structural stability.The enhanced oxidation resistance is mainly attributed to the formation of a protective Al2 O3 oxide layer and the lattice distortion,both of which lead to sluggish diffusion of O_(2).These findings propose a new unexplored avenue for the fabrication of MMB_(2)materials with supe-rior comprehensive performance including ultra-hardness and intrinsically improved thermo-mechanical properties.展开更多
The hardening mechanism of multi-component carbide ceramic has been investigated in detail through a combination of experiments,first-principles calculations,and ab initio molecular dynamics(AIMD).Eight dense carbide ...The hardening mechanism of multi-component carbide ceramic has been investigated in detail through a combination of experiments,first-principles calculations,and ab initio molecular dynamics(AIMD).Eight dense carbide ceramics were prepared by spark plasma sintering.Compulsorily,all the multi-component carbide samples have similar carbon content,grain size,and uniform compositional distribution by optimizing the sintering process and adjusting the initial raw materials.Hence the interference of other factors on the hardness of multi-component carbide ceramics is minimized.The effects of changes in the elemental species on the lattice distortion,bond strength,bonding properties,and electronic structure of multi-component carbide ceramics were thoroughly analyzed.These results show that the hardening of multi-component carbide ceramic can be attributed to the coupling of solid solution strengthening caused by lattice distortion and covalent bond strengthening.Besides,the“host lattice”of multi-component carbide ceramics is defined based on the concept of supporting lattice.The present work is of great significance for a deeper understanding of the hardening mechanism of multi-component carbide ceramics and the design of superhard multi-component carbides.展开更多
A convenient photocatalytic multi-component reaction of alkenes,quinoxalin-2(1H)-ones,and diazo compounds has been developed in the presence of water.A number of ester-containing quinoxalin-2(1H)-ones could be efficie...A convenient photocatalytic multi-component reaction of alkenes,quinoxalin-2(1H)-ones,and diazo compounds has been developed in the presence of water.A number of ester-containing quinoxalin-2(1H)-ones could be efficiently obtained in moderate to good yields at room temperature.This metal-free visiblelight-driven tandem reaction was conducted through proton-coupled electron transfer(PCET)process using water as the hydrogen donor and 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene(4CzIPN)as the photocatalyst.展开更多
The construction of a borehole correction library for the multi-component array induction tool in deviated boreholes involves extensive 3D forward modeling and typically requires significant computational resources.To...The construction of a borehole correction library for the multi-component array induction tool in deviated boreholes involves extensive 3D forward modeling and typically requires significant computational resources.To address this challenge,this paper proposes an efficient algorithm for the library construction based on the 3D finite volume method(FVM)and contraction high-order Born approximation(CHBA).First,the electromagnetic(EM)field solution region is divided into two symmetric subregions based on the symmetry of the correction library model and the EM field.Numerical solution on a single subregion,combined with the symmetry boundary extension technique,enhances the efficiency of the 3D numerical simulation.Second,three reference mud conductivities are selected based on the mud conductivity range,and the CHBA is applied to calculate the EM responses at all mud conductivity nodes rapidly.Third,the number of forward simulation operations is further reduced by exploiting the principle that models with different frequencies and different formation conductivities have equivalent EM responses.Numerical experiments demonstrate the correctness and feasibility of the proposed algorithm.Compared to conventional 3D modeling,the proposed algorithm achieves approximately a 20-fold speedup in library construction,effectively reducing computational resources and time consumption.展开更多
To investigate the influence of Al-Zn-Mg-Cu alloy with as-homogenized and as-rolled initial microstructures on the tensile flow behavior,isothermal tensile tests were conducted on a GLEEBLE-3500 isothermal simulator a...To investigate the influence of Al-Zn-Mg-Cu alloy with as-homogenized and as-rolled initial microstructures on the tensile flow behavior,isothermal tensile tests were conducted on a GLEEBLE-3500 isothermal simulator at temperatures of 380-440℃and strain rates of 0.05-1 s^(−1).The Johnson-Cook model,Hensel-Spittel model,strain-compensated Arrhenius model,and critical fracture strain model were established.Results show that through the evaluation of the models using the correlation coefficient(R)and the average absolute relative error,the strain-compensated Arrhenius model can represent the flow behavior of the alloy more accurately.Shear bands are more pronounced in the as-homogenized specimens,whereas dynamic recrystallization is predominantly observed in as-rolled specimens.Fracture morphology analysis reveals that a mixed fracture mechanism is prevalent in the as-homogenized specimen,whereas a ductile fracture mechanism is predominant in the as-rolled specimen.The processing maps indicate that the unstable region is reduced in the as-rolled specimens compared with that in the as-homogenized specimens.The optimal hot working windows for the as-homogenized and as-rolled specimens are determined as 410-440℃/0.14-1 s^(−1)and 380-400℃/0.05-0.29 s^(−1),respectively.展开更多
Vanadium redox flow batteries(VRFBs)are a means of large-scale energy storage due to their excellent scalability,safety,long cycling life,and decoupled power and energy capacities.However,the slow redox kinetics of va...Vanadium redox flow batteries(VRFBs)are a means of large-scale energy storage due to their excellent scalability,safety,long cycling life,and decoupled power and energy capacities.However,the slow redox kinetics of vanadium species on conventional carbon electrodes remains a major limitation to their performance.We investigated the deposition of carbon black,carbon nanotubes,and electrochemically exfoliated graphene(Exf-Gr)onto thermally-activated carbon paper(ACP)by spray coating to increase the electrode electrocatalytic activity.The modified electrodes were characterized using scanning electron microscopy,X-ray diffraction,Raman spectroscopy,X-ray photoelectron microscopy,and surface area analysis,while their electrochemical properties were evaluated by cyclic voltammetry,electrochemical impedance spectroscopy,and singlecell VRFB testing.Among the modified electrodes,Exf-Gr/ACP had the best performance,achieving a 2.9-fold reduction in charge transfer resistance compared to pristine ACP and delivering 2.5 times the discharge capacity in single-cell tests.This improvement is attributed to Exf-Gr’s high surface area,favorable catalytic activity,and excellent dispersion on the ACP substrate.Surface modification with electrochemically exfoliated graphene is a highly effective strategy for improving the electrode performance in VRFB systems,with significant implications for large-scale energy storage.展开更多
Large-eddy simulation(LES)is conducted to study the statistical properties of mixed-phase turbulence induced by the breaking of bow waves in flow past a partially submerged plate.The simulation is performed using a fi...Large-eddy simulation(LES)is conducted to study the statistical properties of mixed-phase turbulence induced by the breaking of bow waves in flow past a partially submerged plate.The simulation is performed using a finite difference method,with the air-water interface captured by a coupled level-set and volume-of-fluid method.Four cases are conducted to investigate the effects of Froude number on turbulent statistics,including the mean velocity,turbulence kinetic energy,and turbulence mass flux(TMF),which is an additional unclosed term in the Reynolds-averaged momentum equation.The TMF,especially its vertical component,shows a complex behaviour with respect to the Froude number.This property of the TMF imposes high demands on the robustness of the closure model of TMF.The present LES data is further used to examine a closure model of the TMF production term,which shows a high correlation with the data obtained from LES.展开更多
Multiscale mixing of the turbine blade tip leakage and mainstream flows causes considerable aerodynamic loss.Understanding it is crucial to correctly estimating the mixing loss and thus improving the turbine's per...Multiscale mixing of the turbine blade tip leakage and mainstream flows causes considerable aerodynamic loss.Understanding it is crucial to correctly estimating the mixing loss and thus improving the turbine's performance.The multiscale mixing phenomenon in a typical high-pressure turbine rotor flow was studied in this work.The contributions of various scale flows to entropy production and mixing properties were identified.The corresponding physical mechanisms at different scales were explored.It is shown that the large-scale and time-averaged flow contributions to mixing are significant,accounting for approximately 37.1% and 25% of the total.Time-averaged and large-scale flows cause the majority of the fluid deformation of the material surface,while mesoand small-scale flows just generate finer deformations.It raises the area stretch coefficient and the virtual concentration gradient.Thus,mixing is enhanced.Furthermore,time-averaged and large-scale flows account for the majority of the losses in the upstream and downstream regions of the blade tip respectively,accounting for approximately 53.8%and 33.5%of the total.The sheet-like structures—rather than the tip leaking vortex—are the primary source of the loss.High-dissipation regions are produced by the sheet-like structures via the pressure Hessian term and the self-amplification terms.展开更多
A 3D mathematical model was established to investigate the gas-liquid two-phase flow in Ruhrstahl-Heraeus(RH)vacuum refining process.The flow characteristics of molten steel were calculated using the coupled standard...A 3D mathematical model was established to investigate the gas-liquid two-phase flow in Ruhrstahl-Heraeus(RH)vacuum refining process.The flow characteristics of molten steel were calculated using the coupled standard k-εmodel and volume of fluid model.The bubble distribution was tracked by discrete phase model.Electromagnetic field was applied in the up-leg snorkel to enhance the effect of vacuum refining.The effect of swirling flow nozzles combined with electromagnetic stirring(EMS)on the flow characteristics of molten steel and bubble distribution was analyzed.The erosion of the up-leg snorkel was compared.The results show that when the swirling flow nozzles are used,the bubbles exhibit a distinct adherent rising behavior,and the refining efficiency decreases.In addition,the electromagnetic field can significantly improve the refining efficiency,but it brings stronger erosion to the up-leg snorkel.Nevertheless,when using the swirling flow nozzles combined with EMS,the refining performance is further optimized,and the erosion of the up-leg snorkel is also reduced due to its characteristic of bubble distribution.Compared to conventional nozzles,the mixing time was shortened by 16.2%,the recirculation rate increased by 12.5%.and the swirling intensity was strengthened by 8.9%.展开更多
Slug flow represents one of the most critical and operationally challenging regimes in oil-gas-water multiphase pipelines.To advance both mechanistic understanding and predictive capability,this study integrates physi...Slug flow represents one of the most critical and operationally challenging regimes in oil-gas-water multiphase pipelines.To advance both mechanistic understanding and predictive capability,this study integrates physical analysis with data-driven modeling to elucidate the conditions governing slug formation and to enable its rapid and accurate prediction.A systematic review of existing research is first undertaken to clarify the mechanisms responsible for slug initiation.The influences of gas superficial velocity,liquid velocity,liquid viscosity,liquid surface tension,and the axial component of gravity are examined to characterize their roles in interfacial instability and flow transition.Then,the effects of temperature,total flow rate,water cut,gas-liquid ratio,and pipeline inclination angle are quantitatively assessed,revealing the dominant trends that promote or inhibit slug development.Building on this foundation,a comprehensive three-phase oil-gas-water flow model is constructed.Numerical simulations are performed for 243 operating conditions encompassing a broad range of temperatures,water cuts,gas-liquid ratios,liquid flow rates,and inclination angles.These simulated cases constitute the training dataset for nine machine learning algorithms.To evaluate generalization performance,108 additional randomly generated operating conditions are predicted,covering temperatures of 80–150◦C,water cuts of 40–90%,gas-liquid ratios of 3–30,liquid flow rates of 100–200 t/d,and inclination angles of 5–15.Comparative validation reveals marked differences in predictive accuracy.The BP neural network achieves the highest accuracy,95%,substantially outperforming XGBoost,83.3%,Random Forest and Decision Tree,81.5%,Logistic Regression and Support Vector Machine,80.6%,K-Nearest Neighbor and Naive Bayes 78.7%,and K-Means,63%.Overall,the BP neural network demonstrates superior robustness and precision in predicting previously unseen operating conditions,effectively combining the physical consistency of mechanistic modeling with the efficiency and adaptability of machine learning approaches.展开更多
Interregional supply chains are associated with large carbon emissions,resulting in regional inequalities and sustainable development challenges.Quantifying interregional carbon flow is essential for setting equitable...Interregional supply chains are associated with large carbon emissions,resulting in regional inequalities and sustainable development challenges.Quantifying interregional carbon flow is essential for setting equitable carbon reduction targets and ensuring fairness among regions.However,as China advances its industrial transformation,the effects of industrial structural changes on regional carbon flow through supply chains remain insufficiently understood.Using Shanghai from 2012 to 2017 as a case study,this research investigates spatial patterns,sectoral characteristics and driving forces of carbon flow within interregional supply chains.Results reveal a 46.9%decrease in carbon inflows and a 70.2%increase in outflows,particularly to high-tech regions,indicating Shanghai's transition from a downstream recipient to an upstream supplier in industrial networks.Reduced inflows were mainly driven by decreased carbon intensity in northern energy and metal sectors,whereas increased outflows were associated with growing demand from southern equipment and construction industries.Energy structure optimization contributed to over 75%of carbon flow reductions,while increased carbon intensity in the digital economy accounted for only around 10%,insufficient to alter flow pathways.The findings indicates that industrial restructuring can support regional climate mitigation.As a pilot carbon trading cities with relatively low environmental cost,Shanghai can collaborate with other regions through carbon markets along key carbon pathways,leveraging financial resources for low-carbon technologies and promoting supply chain-wide emission reduction.This study provides a framework for designing targeted,region-specific mitigation strategies that align with the dynamics of industrial supply chains and contribute to equitable carbon reduction efforts.展开更多
To clarify fluid flow mechanisms and establish effective development conditions in continental shale oil reservoirs,a high-temperature,high-pressure steady-state flow system integrated with nuclear magnetic resonance(...To clarify fluid flow mechanisms and establish effective development conditions in continental shale oil reservoirs,a high-temperature,high-pressure steady-state flow system integrated with nuclear magnetic resonance(NMR)technology has been developed.The apparatus combines sample evacuation,rapid pressurization and saturation,and controlled displacement,enabling systematic investigation of single-phase shale oil flow under representative reservoir conditions.Related experiments allow proper quantification of the activation thresholds and relative contributions of different pore types to flow.A movable fluid index(MFI),defined using dual T_(2) cutoff values,is introduced accordingly and linked to key flow parameters.The results reveal distinct multi-scale characteristics of single-phase shale oil transport,namely micro-scale graded displacement and macro-scale segmented nonlinear behavior.As the injection-production pressure difference increases,flow pathways are activated progressively,beginning with fractures,followed by large and then smaller macropores,leading to a pronounced enhancement in apparent permeability.Although mesopores and micropores contribute little to direct flow,their indirect influence becomes increasingly important,and apparent permeability gradually approaches a stable limit at higher pressure difference.It is also shown that the MFI exhibits a strong negative correlation with the starting pressure gradient and a positive correlation with apparent permeability,providing a rapid and reliable indicator of shale oil flow capacity.Samples containing through-going fractures display consistently higher MFI values and superior flowability compared with those dominated by laminated fractures,highlighting the pivotal role of well-connected fracture networks generated by large-scale hydraulic fracturing in improving shale oil production.展开更多
Investigating the wind-sand flow response regularity in the longitudinal slope sections of desert highways provides a scientific basis for selecting the slope of desert roads.This study uses the Tengger Desert section...Investigating the wind-sand flow response regularity in the longitudinal slope sections of desert highways provides a scientific basis for selecting the slope of desert roads.This study uses the Tengger Desert section of the Wuhai-Maqin Expressway as a case study,employing CFD numerical simulation methods to calculate and analyze the wind-sand flow field distribution characteristics in different longitudinal slope sections.The results show that:(1)Along with the direction of the incoming flow,the windward and leeward slope toes of the embankment are low-wind-speed zones,with the wind speed at the leeward slope toe being even lower.The higher the embankment,the larger the low-wind-speed zone at the windward and leeward slope toes.As the longitudinal slope increases,the extent of the lowwind-speed zone at the same location along the route also increases.(2)Along the route direction,the wind speed at the windward and leeward slope toes decreases as embankment height increases.At the embankment toe,sand particles are transported from the top to the bottom of the longitudinal slope,and the greater the longitudinal slope,the stronger the transport effect.(3)Along the route direction,the sand accumulation around the embankment gradually gathers toward the bottom of the longitudinal slope as the slope increases.When the longitudinal slope is 3%and 4%,the trend of sand accumulation moving from the windward side at the end of the route to the leeward side at the start of the route is more significant.When the longitudinal slope is less than or equal to 3%,severe sand accumulation within the embankment range is reduced by 86.4%or more compared to when the slope is 4%.(4)Under the same longitudinal slope,the higher the embankment height,the smaller its transport rate.When the embankment height is the same,the greater the longitudinal slope,the greater the embankment transport rate.展开更多
The newly formulated non-Newtonian rivulet flows streaming down an inclined planar surface,with additional periodic perturbations arising from the application of the 2nd Stokes problem to the investigation of rivulet ...The newly formulated non-Newtonian rivulet flows streaming down an inclined planar surface,with additional periodic perturbations arising from the application of the 2nd Stokes problem to the investigation of rivulet dynamics,are demonstrated in the current research.Hereby,the 2nd Stokes problem assumes that the surface,with a thin shared layer of the fluid on it,oscillates in a harmonic manner along the x-axis of the rivulet flow,which coincides with the main flow direction streaming down the underlying surface.We obtain the exact extension of the rivulet flow family,clarifying the structure of the pressure field,which fully absorbs the arising perturbation.The profile of the velocity field is assumed to be Gaussian-type with a non-zero level of plasticity.Hence,the absolutely non-Newtonian case of the viscoplastic flow solution,which satisfies the motion and continuity equations,is considered(with particular cases of exact solutions for pressure).The perturbed governing equations of motion for rivulet flows then result in the Riccati-type ordinary differential equation(ODE),describing the dynamics of the coordinate x(t).The approximated schematic dynamics are presented in graphical plots.展开更多
文摘The dynamics of inviscid multi-component relativistic fluids may be modeled by the relativistic Euler equations, augmented by one (or more) additional species equation(s). We use the high-resolution staggered central schemes to solve these equations. The equilibrium states for each component are coupled in space and time to have a common temperature and velocity. The current schemes can handle strong shocks and the oscillations near the interfaces are negligible, which usually happens in the multi-component flows. The schemes also guarantee the exact mass conservation for each component, the exact conservation of total momentum, and energy in the whole particle system. The central schemes are robust, reliable, compact and easy to implement. Several one- and two-dimensional numerical test cases are included in this paper, which validate the application of these schemes to relativistic multi-component flows.
基金Science and Technology Foundation of Guizhou Province(No.QKHJC-ZK[2024]654)Guizhou Provincial University Key Laboratory of Advanced Functional Electronic Materials(No.QJJ[2023]021).
文摘Carbenes as one of the most important class of intermediates have been widely utilized in various organic synthetic transformations.Carbene insertion-initiated ring-opening reactions of cyclic ethers offer a valuable strategy for constructing new carbon-oxygen bonds.In comparison with traditional thermal or metal-mediated carbene transfer reactions,visible-light-promoted multi-component reaction strategy provides a mild and eco-friendly approach to access densely functionalized molecules.Recently,visible-light-induced multi-component carbene transfer reactions of diazo compounds have been rapidly developed and attracted a great deal of research interest of chemists owing to their advantages of simple operation,mild condition,high atom economy and rich structural diversity.This paper summarizes the recent research progress on the visible-light-promoted multi-component carbene transfer reactions of diazo compounds via ring-opening of cyclic ethers with various nucleophiles.The reaction patterns of different nucleophiles and their corresponding mechanism are described in this review.The future research direction and challenges in this area are also discussed.
文摘We extend the traditional kinetic scheme for ideal gases to the Euler equations with the equation of state for a multi-component stiffened gas. Based on a careful analysis of the oscillation mechanism of the traditional kinetic scheme across contact discontinuities, we propose a new non-oscillatory kinetic （NOK） scheme for multi-component stiffened gases. The basic idea in the construction is to use a flux splitting technique to construct numerical fluxes which do not depend on the concrete form of the equilibrium state. The new scheme can not only can avoid spurious oscillations of the pressure and velocity near a material interface which are observed in the traditional kinetic schemes such as the kinetic flux vector splitting （KFVS） and BGK schemes, but also can deal with the stiffened gas equation of state. Moreover, we also carry out a careful analysis on the consistency condition, truncation error and positivity of the NOK scheme. A number of 1D and 2D numerical tests are presented which demonstrate the accuracy and robustness of the new scheme in the simulation of problems with smooth, weak and strong shock wave regions.
基金sponsored by the National Natural Science Foundations of China under Grant Nos.12301315,12235007,11975131the Zhejiang Provincial Natural Science Foundation of China under Grant No.LQ20A010009。
文摘In the realm of nonlinear integrable systems,the presence of decompositions facilitates the establishment of linear superposition solutions and the derivation of novel coupled systems exhibiting nonlinear integrability.By focusing on single-component decompositions within the potential BKP hierarchy,it has been observed that specific linear superpositions of decomposition solutions remain consistent with the underlying equations.Moreover,through the implementation of multi-component decompositions within the potential BKP hierarchy,successful endeavors have been undertaken to formulate linear superposition solutions and novel coupled Kd V-type systems that resist decoupling via alterations in dependent variables.
基金financially supported by the National Natural Science Foundation of China(Nos.52271033 and 52071179)the Key program of National Natural Science Foundation of China(No.51931003)+2 种基金Natural Science Foundation of Jiangsu Province,China(No.BK20221493)Jiangsu Province Leading Edge Technology Basic Research Major Project(No.BK20222014)Foundation of“Qinglan Project”for Colleges and Universities in Jiangsu Province.
文摘Multi-component transition group metal borides(MMB_(2))have become a research hotspot due to their new composition design concepts and superior properties compared with conventional ceramics.Most of the current methods,however,are complicated and time-consuming,the mass production remains a chal-lenge.Herein,we proposed a new high-efficiency strategy for synthesis of MMB_(2)using molten aluminum as the medium for the first time.The prepared Al-containing multi-component borides(TiZrHfNbTa)B_(2)microcrystals had a homogeneous composition with a hexagonal AlB_(2)structure and ultra-high hardness value of∼35.3 GPa,which was much higher than data reported in the literature and the rule of mix-ture estimations.Furthermore,combined with the First-principles calculation results,we found that the Poisson’s ratio(v)values exhibit a clearly ascending trend from 0.17 at VEC=3.5 to 0.18 at VEC=3.4,then to 0.201 at VEC=3.2 with the increasing of Al content.This indicates that the intrinsic toughness of multi-component boride microcrystals is obviously enhanced by the trace-doped Al elements.Besides,the fabricated Al-containing multi-component boride microcrystals have superior oxidation activation en-ergy and structural stability.The enhanced oxidation resistance is mainly attributed to the formation of a protective Al2 O3 oxide layer and the lattice distortion,both of which lead to sluggish diffusion of O_(2).These findings propose a new unexplored avenue for the fabrication of MMB_(2)materials with supe-rior comprehensive performance including ultra-hardness and intrinsically improved thermo-mechanical properties.
基金financially supported by the National Natural Science Foundation of China(Nos.52032002,52372060,51972081,and U22A20128)the National Safety Academic Foundation(No.U2130103)+1 种基金the National Key Laboratory of Precision Hot Processing of Metals(No.61429092300305)Heilongjiang Touyan Team Program are gratefully acknowledged.
文摘The hardening mechanism of multi-component carbide ceramic has been investigated in detail through a combination of experiments,first-principles calculations,and ab initio molecular dynamics(AIMD).Eight dense carbide ceramics were prepared by spark plasma sintering.Compulsorily,all the multi-component carbide samples have similar carbon content,grain size,and uniform compositional distribution by optimizing the sintering process and adjusting the initial raw materials.Hence the interference of other factors on the hardness of multi-component carbide ceramics is minimized.The effects of changes in the elemental species on the lattice distortion,bond strength,bonding properties,and electronic structure of multi-component carbide ceramics were thoroughly analyzed.These results show that the hardening of multi-component carbide ceramic can be attributed to the coupling of solid solution strengthening caused by lattice distortion and covalent bond strengthening.Besides,the“host lattice”of multi-component carbide ceramics is defined based on the concept of supporting lattice.The present work is of great significance for a deeper understanding of the hardening mechanism of multi-component carbide ceramics and the design of superhard multi-component carbides.
基金supported by Sichuan Science and Technology Program(No.2023NSFSC0101)the 2024 Provincial platform project of Chengdu Normal University(No.GNFZ202404)+1 种基金Natural Science Foundation of Shandong Province(No.ZR2021MB065)National Natural Science Foundation of China(No.22101237)。
文摘A convenient photocatalytic multi-component reaction of alkenes,quinoxalin-2(1H)-ones,and diazo compounds has been developed in the presence of water.A number of ester-containing quinoxalin-2(1H)-ones could be efficiently obtained in moderate to good yields at room temperature.This metal-free visiblelight-driven tandem reaction was conducted through proton-coupled electron transfer(PCET)process using water as the hydrogen donor and 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene(4CzIPN)as the photocatalyst.
基金funded by the Forward-looking Basic Science and Technology Research Project of PetroChina Company Limited(2025DJ104)the National Natural Science Foundation of China(42174150)the National Science and Technology Major Project for Deep Earth Probe and Mineral Resources Exploration(2024ZD1003005).
文摘The construction of a borehole correction library for the multi-component array induction tool in deviated boreholes involves extensive 3D forward modeling and typically requires significant computational resources.To address this challenge,this paper proposes an efficient algorithm for the library construction based on the 3D finite volume method(FVM)and contraction high-order Born approximation(CHBA).First,the electromagnetic(EM)field solution region is divided into two symmetric subregions based on the symmetry of the correction library model and the EM field.Numerical solution on a single subregion,combined with the symmetry boundary extension technique,enhances the efficiency of the 3D numerical simulation.Second,three reference mud conductivities are selected based on the mud conductivity range,and the CHBA is applied to calculate the EM responses at all mud conductivity nodes rapidly.Third,the number of forward simulation operations is further reduced by exploiting the principle that models with different frequencies and different formation conductivities have equivalent EM responses.Numerical experiments demonstrate the correctness and feasibility of the proposed algorithm.Compared to conventional 3D modeling,the proposed algorithm achieves approximately a 20-fold speedup in library construction,effectively reducing computational resources and time consumption.
文摘To investigate the influence of Al-Zn-Mg-Cu alloy with as-homogenized and as-rolled initial microstructures on the tensile flow behavior,isothermal tensile tests were conducted on a GLEEBLE-3500 isothermal simulator at temperatures of 380-440℃and strain rates of 0.05-1 s^(−1).The Johnson-Cook model,Hensel-Spittel model,strain-compensated Arrhenius model,and critical fracture strain model were established.Results show that through the evaluation of the models using the correlation coefficient(R)and the average absolute relative error,the strain-compensated Arrhenius model can represent the flow behavior of the alloy more accurately.Shear bands are more pronounced in the as-homogenized specimens,whereas dynamic recrystallization is predominantly observed in as-rolled specimens.Fracture morphology analysis reveals that a mixed fracture mechanism is prevalent in the as-homogenized specimen,whereas a ductile fracture mechanism is predominant in the as-rolled specimen.The processing maps indicate that the unstable region is reduced in the as-rolled specimens compared with that in the as-homogenized specimens.The optimal hot working windows for the as-homogenized and as-rolled specimens are determined as 410-440℃/0.14-1 s^(−1)and 380-400℃/0.05-0.29 s^(−1),respectively.
基金supported by the University of Seoul’s 2025 Research Fund.
文摘Vanadium redox flow batteries(VRFBs)are a means of large-scale energy storage due to their excellent scalability,safety,long cycling life,and decoupled power and energy capacities.However,the slow redox kinetics of vanadium species on conventional carbon electrodes remains a major limitation to their performance.We investigated the deposition of carbon black,carbon nanotubes,and electrochemically exfoliated graphene(Exf-Gr)onto thermally-activated carbon paper(ACP)by spray coating to increase the electrode electrocatalytic activity.The modified electrodes were characterized using scanning electron microscopy,X-ray diffraction,Raman spectroscopy,X-ray photoelectron microscopy,and surface area analysis,while their electrochemical properties were evaluated by cyclic voltammetry,electrochemical impedance spectroscopy,and singlecell VRFB testing.Among the modified electrodes,Exf-Gr/ACP had the best performance,achieving a 2.9-fold reduction in charge transfer resistance compared to pristine ACP and delivering 2.5 times the discharge capacity in single-cell tests.This improvement is attributed to Exf-Gr’s high surface area,favorable catalytic activity,and excellent dispersion on the ACP substrate.Surface modification with electrochemically exfoliated graphene is a highly effective strategy for improving the electrode performance in VRFB systems,with significant implications for large-scale energy storage.
基金supported by the National Natural Science Foundation of China(NSFC)Basic Science Center Program for‘Multiscale Problems in Nonlinear Mechanics’(Grant No.11988102)NSFC project(Grant No.11972038)Chinese Academy of Sciences Project for Young Scientists in Basic Research(Grant No.YSBR-087).
文摘Large-eddy simulation(LES)is conducted to study the statistical properties of mixed-phase turbulence induced by the breaking of bow waves in flow past a partially submerged plate.The simulation is performed using a finite difference method,with the air-water interface captured by a coupled level-set and volume-of-fluid method.Four cases are conducted to investigate the effects of Froude number on turbulent statistics,including the mean velocity,turbulence kinetic energy,and turbulence mass flux(TMF),which is an additional unclosed term in the Reynolds-averaged momentum equation.The TMF,especially its vertical component,shows a complex behaviour with respect to the Froude number.This property of the TMF imposes high demands on the robustness of the closure model of TMF.The present LES data is further used to examine a closure model of the TMF production term,which shows a high correlation with the data obtained from LES.
基金supported by the National Science and Technology Major Project,China(No.J2019-Ⅱ-0012-0032)。
文摘Multiscale mixing of the turbine blade tip leakage and mainstream flows causes considerable aerodynamic loss.Understanding it is crucial to correctly estimating the mixing loss and thus improving the turbine's performance.The multiscale mixing phenomenon in a typical high-pressure turbine rotor flow was studied in this work.The contributions of various scale flows to entropy production and mixing properties were identified.The corresponding physical mechanisms at different scales were explored.It is shown that the large-scale and time-averaged flow contributions to mixing are significant,accounting for approximately 37.1% and 25% of the total.Time-averaged and large-scale flows cause the majority of the fluid deformation of the material surface,while mesoand small-scale flows just generate finer deformations.It raises the area stretch coefficient and the virtual concentration gradient.Thus,mixing is enhanced.Furthermore,time-averaged and large-scale flows account for the majority of the losses in the upstream and downstream regions of the blade tip respectively,accounting for approximately 53.8%and 33.5%of the total.The sheet-like structures—rather than the tip leaking vortex—are the primary source of the loss.High-dissipation regions are produced by the sheet-like structures via the pressure Hessian term and the self-amplification terms.
基金support from the National Natural Science Foundation of China(No.52174305).
文摘A 3D mathematical model was established to investigate the gas-liquid two-phase flow in Ruhrstahl-Heraeus(RH)vacuum refining process.The flow characteristics of molten steel were calculated using the coupled standard k-εmodel and volume of fluid model.The bubble distribution was tracked by discrete phase model.Electromagnetic field was applied in the up-leg snorkel to enhance the effect of vacuum refining.The effect of swirling flow nozzles combined with electromagnetic stirring(EMS)on the flow characteristics of molten steel and bubble distribution was analyzed.The erosion of the up-leg snorkel was compared.The results show that when the swirling flow nozzles are used,the bubbles exhibit a distinct adherent rising behavior,and the refining efficiency decreases.In addition,the electromagnetic field can significantly improve the refining efficiency,but it brings stronger erosion to the up-leg snorkel.Nevertheless,when using the swirling flow nozzles combined with EMS,the refining performance is further optimized,and the erosion of the up-leg snorkel is also reduced due to its characteristic of bubble distribution.Compared to conventional nozzles,the mixing time was shortened by 16.2%,the recirculation rate increased by 12.5%.and the swirling intensity was strengthened by 8.9%.
基金funded by the Hubei Provincial Department of Education Science and Technology Plan Project(Young and Middle-aged Talent Program)(https://jyt.hubei.gov.cn/),grant number Q20241308the National Natural Science Foundation of China(https://www.nsfc.gov.cn/),grant number 52174064.
文摘Slug flow represents one of the most critical and operationally challenging regimes in oil-gas-water multiphase pipelines.To advance both mechanistic understanding and predictive capability,this study integrates physical analysis with data-driven modeling to elucidate the conditions governing slug formation and to enable its rapid and accurate prediction.A systematic review of existing research is first undertaken to clarify the mechanisms responsible for slug initiation.The influences of gas superficial velocity,liquid velocity,liquid viscosity,liquid surface tension,and the axial component of gravity are examined to characterize their roles in interfacial instability and flow transition.Then,the effects of temperature,total flow rate,water cut,gas-liquid ratio,and pipeline inclination angle are quantitatively assessed,revealing the dominant trends that promote or inhibit slug development.Building on this foundation,a comprehensive three-phase oil-gas-water flow model is constructed.Numerical simulations are performed for 243 operating conditions encompassing a broad range of temperatures,water cuts,gas-liquid ratios,liquid flow rates,and inclination angles.These simulated cases constitute the training dataset for nine machine learning algorithms.To evaluate generalization performance,108 additional randomly generated operating conditions are predicted,covering temperatures of 80–150◦C,water cuts of 40–90%,gas-liquid ratios of 3–30,liquid flow rates of 100–200 t/d,and inclination angles of 5–15.Comparative validation reveals marked differences in predictive accuracy.The BP neural network achieves the highest accuracy,95%,substantially outperforming XGBoost,83.3%,Random Forest and Decision Tree,81.5%,Logistic Regression and Support Vector Machine,80.6%,K-Nearest Neighbor and Naive Bayes 78.7%,and K-Means,63%.Overall,the BP neural network demonstrates superior robustness and precision in predicting previously unseen operating conditions,effectively combining the physical consistency of mechanistic modeling with the efficiency and adaptability of machine learning approaches.
基金supported by the National Natural Science Foundation of China[grant numbers 52270185,41971257].
文摘Interregional supply chains are associated with large carbon emissions,resulting in regional inequalities and sustainable development challenges.Quantifying interregional carbon flow is essential for setting equitable carbon reduction targets and ensuring fairness among regions.However,as China advances its industrial transformation,the effects of industrial structural changes on regional carbon flow through supply chains remain insufficiently understood.Using Shanghai from 2012 to 2017 as a case study,this research investigates spatial patterns,sectoral characteristics and driving forces of carbon flow within interregional supply chains.Results reveal a 46.9%decrease in carbon inflows and a 70.2%increase in outflows,particularly to high-tech regions,indicating Shanghai's transition from a downstream recipient to an upstream supplier in industrial networks.Reduced inflows were mainly driven by decreased carbon intensity in northern energy and metal sectors,whereas increased outflows were associated with growing demand from southern equipment and construction industries.Energy structure optimization contributed to over 75%of carbon flow reductions,while increased carbon intensity in the digital economy accounted for only around 10%,insufficient to alter flow pathways.The findings indicates that industrial restructuring can support regional climate mitigation.As a pilot carbon trading cities with relatively low environmental cost,Shanghai can collaborate with other regions through carbon markets along key carbon pathways,leveraging financial resources for low-carbon technologies and promoting supply chain-wide emission reduction.This study provides a framework for designing targeted,region-specific mitigation strategies that align with the dynamics of industrial supply chains and contribute to equitable carbon reduction efforts.
基金supported by the National Science and Technology Major Project of China(Grant No.2024ZD 1004302)the Key Scientific and Technological Research project of SINOPEC(Grant No.P25186).
文摘To clarify fluid flow mechanisms and establish effective development conditions in continental shale oil reservoirs,a high-temperature,high-pressure steady-state flow system integrated with nuclear magnetic resonance(NMR)technology has been developed.The apparatus combines sample evacuation,rapid pressurization and saturation,and controlled displacement,enabling systematic investigation of single-phase shale oil flow under representative reservoir conditions.Related experiments allow proper quantification of the activation thresholds and relative contributions of different pore types to flow.A movable fluid index(MFI),defined using dual T_(2) cutoff values,is introduced accordingly and linked to key flow parameters.The results reveal distinct multi-scale characteristics of single-phase shale oil transport,namely micro-scale graded displacement and macro-scale segmented nonlinear behavior.As the injection-production pressure difference increases,flow pathways are activated progressively,beginning with fractures,followed by large and then smaller macropores,leading to a pronounced enhancement in apparent permeability.Although mesopores and micropores contribute little to direct flow,their indirect influence becomes increasingly important,and apparent permeability gradually approaches a stable limit at higher pressure difference.It is also shown that the MFI exhibits a strong negative correlation with the starting pressure gradient and a positive correlation with apparent permeability,providing a rapid and reliable indicator of shale oil flow capacity.Samples containing through-going fractures display consistently higher MFI values and superior flowability compared with those dominated by laminated fractures,highlighting the pivotal role of well-connected fracture networks generated by large-scale hydraulic fracturing in improving shale oil production.
基金financially supported by Youth Science“Research on Failure Mechanism and Evaluation Method of Sand Control Measures for Railway Machinery in Sandy Area”(12302511)Ningxia Transportation Department Science and Technology Project(20200173)The Central Guidance on Local Science and Technology Development Funds(22ZY1QA005)。
文摘Investigating the wind-sand flow response regularity in the longitudinal slope sections of desert highways provides a scientific basis for selecting the slope of desert roads.This study uses the Tengger Desert section of the Wuhai-Maqin Expressway as a case study,employing CFD numerical simulation methods to calculate and analyze the wind-sand flow field distribution characteristics in different longitudinal slope sections.The results show that:(1)Along with the direction of the incoming flow,the windward and leeward slope toes of the embankment are low-wind-speed zones,with the wind speed at the leeward slope toe being even lower.The higher the embankment,the larger the low-wind-speed zone at the windward and leeward slope toes.As the longitudinal slope increases,the extent of the lowwind-speed zone at the same location along the route also increases.(2)Along the route direction,the wind speed at the windward and leeward slope toes decreases as embankment height increases.At the embankment toe,sand particles are transported from the top to the bottom of the longitudinal slope,and the greater the longitudinal slope,the stronger the transport effect.(3)Along the route direction,the sand accumulation around the embankment gradually gathers toward the bottom of the longitudinal slope as the slope increases.When the longitudinal slope is 3%and 4%,the trend of sand accumulation moving from the windward side at the end of the route to the leeward side at the start of the route is more significant.When the longitudinal slope is less than or equal to 3%,severe sand accumulation within the embankment range is reduced by 86.4%or more compared to when the slope is 4%.(4)Under the same longitudinal slope,the higher the embankment height,the smaller its transport rate.When the embankment height is the same,the greater the longitudinal slope,the greater the embankment transport rate.
文摘The newly formulated non-Newtonian rivulet flows streaming down an inclined planar surface,with additional periodic perturbations arising from the application of the 2nd Stokes problem to the investigation of rivulet dynamics,are demonstrated in the current research.Hereby,the 2nd Stokes problem assumes that the surface,with a thin shared layer of the fluid on it,oscillates in a harmonic manner along the x-axis of the rivulet flow,which coincides with the main flow direction streaming down the underlying surface.We obtain the exact extension of the rivulet flow family,clarifying the structure of the pressure field,which fully absorbs the arising perturbation.The profile of the velocity field is assumed to be Gaussian-type with a non-zero level of plasticity.Hence,the absolutely non-Newtonian case of the viscoplastic flow solution,which satisfies the motion and continuity equations,is considered(with particular cases of exact solutions for pressure).The perturbed governing equations of motion for rivulet flows then result in the Riccati-type ordinary differential equation(ODE),describing the dynamics of the coordinate x(t).The approximated schematic dynamics are presented in graphical plots.
