Carbenes as one of the most important class of intermediates have been widely utilized in various organic synthetic transformations.Carbene insertion-initiated ring-opening reactions of cyclic ethers offer a valuable ...Carbenes as one of the most important class of intermediates have been widely utilized in various organic synthetic transformations.Carbene insertion-initiated ring-opening reactions of cyclic ethers offer a valuable strategy for constructing new carbon-oxygen bonds.In comparison with traditional thermal or metal-mediated carbene transfer reactions,visible-light-promoted multi-component reaction strategy provides a mild and eco-friendly approach to access densely functionalized molecules.Recently,visible-light-induced multi-component carbene transfer reactions of diazo compounds have been rapidly developed and attracted a great deal of research interest of chemists owing to their advantages of simple operation,mild condition,high atom economy and rich structural diversity.This paper summarizes the recent research progress on the visible-light-promoted multi-component carbene transfer reactions of diazo compounds via ring-opening of cyclic ethers with various nucleophiles.The reaction patterns of different nucleophiles and their corresponding mechanism are described in this review.The future research direction and challenges in this area are also discussed.展开更多
In the realm of nonlinear integrable systems,the presence of decompositions facilitates the establishment of linear superposition solutions and the derivation of novel coupled systems exhibiting nonlinear integrabilit...In the realm of nonlinear integrable systems,the presence of decompositions facilitates the establishment of linear superposition solutions and the derivation of novel coupled systems exhibiting nonlinear integrability.By focusing on single-component decompositions within the potential BKP hierarchy,it has been observed that specific linear superpositions of decomposition solutions remain consistent with the underlying equations.Moreover,through the implementation of multi-component decompositions within the potential BKP hierarchy,successful endeavors have been undertaken to formulate linear superposition solutions and novel coupled Kd V-type systems that resist decoupling via alterations in dependent variables.展开更多
Multi-component transition group metal borides(MMB_(2))have become a research hotspot due to their new composition design concepts and superior properties compared with conventional ceramics.Most of the current method...Multi-component transition group metal borides(MMB_(2))have become a research hotspot due to their new composition design concepts and superior properties compared with conventional ceramics.Most of the current methods,however,are complicated and time-consuming,the mass production remains a chal-lenge.Herein,we proposed a new high-efficiency strategy for synthesis of MMB_(2)using molten aluminum as the medium for the first time.The prepared Al-containing multi-component borides(TiZrHfNbTa)B_(2)microcrystals had a homogeneous composition with a hexagonal AlB_(2)structure and ultra-high hardness value of∼35.3 GPa,which was much higher than data reported in the literature and the rule of mix-ture estimations.Furthermore,combined with the First-principles calculation results,we found that the Poisson’s ratio(v)values exhibit a clearly ascending trend from 0.17 at VEC=3.5 to 0.18 at VEC=3.4,then to 0.201 at VEC=3.2 with the increasing of Al content.This indicates that the intrinsic toughness of multi-component boride microcrystals is obviously enhanced by the trace-doped Al elements.Besides,the fabricated Al-containing multi-component boride microcrystals have superior oxidation activation en-ergy and structural stability.The enhanced oxidation resistance is mainly attributed to the formation of a protective Al2 O3 oxide layer and the lattice distortion,both of which lead to sluggish diffusion of O_(2).These findings propose a new unexplored avenue for the fabrication of MMB_(2)materials with supe-rior comprehensive performance including ultra-hardness and intrinsically improved thermo-mechanical properties.展开更多
BACKGROUND Indolent T-cell lymphoma of the gastrointestinal tract(iTCL-GI)is a rare mature T-cell lymphoma that has been formally recognized as a distinct entity in the 5th Edition World Health Organization Classifica...BACKGROUND Indolent T-cell lymphoma of the gastrointestinal tract(iTCL-GI)is a rare mature T-cell lymphoma that has been formally recognized as a distinct entity in the 5th Edition World Health Organization Classification of Tumours of Haematolymphoid Tumours.However,the coexistence of iTCL-GI with epithelial malignancies is rare in clinical practice.This study reports a case of iTCL-GI with gastric signet-ring cell carcinoma(SRCC).We aim to increase diagnostic awareness among clinicians and pathologists regarding multiple primary tumors.CASE SUMMARY A 65-year-old female presented with a 5-month history of lower abdominal pain,bloating,and vomiting.An abdominal computed tomography scan revealed irregular thickening of the gastric wall.Endoscopy revealed diffuse mucosal edema and rigid mucosa along the lesser curvature of the gastric body.There was a 1.5 cm mucosal protrusion on the greater curvature.Biopsy revealed that the lamina propria was expanded by a dense,nondestructive infiltrate of small lymphocytes in the greater curvature,which were characterized by a CD3+/CD8+/TIA-1+immunophenotype with a low Ki-67 index.Clonal T-cell receptor rearrangement was detected,but the Epstein-Barr virus encoded RNA's was negative.Lesions on the lesser curvature of the gastric body were confirmed to be SRCCs.After three months of follow-up,the patient completed four cycles of chemotherapy targeting the SRCC.While her abdominal pain improved,she experienced a weight loss of 5 kg.CONCLUSION Clinicians and pathologists must integrate assessment of these rare cases to prevent misdiagnosis and guide clinical practice.展开更多
The hardening mechanism of multi-component carbide ceramic has been investigated in detail through a combination of experiments,first-principles calculations,and ab initio molecular dynamics(AIMD).Eight dense carbide ...The hardening mechanism of multi-component carbide ceramic has been investigated in detail through a combination of experiments,first-principles calculations,and ab initio molecular dynamics(AIMD).Eight dense carbide ceramics were prepared by spark plasma sintering.Compulsorily,all the multi-component carbide samples have similar carbon content,grain size,and uniform compositional distribution by optimizing the sintering process and adjusting the initial raw materials.Hence the interference of other factors on the hardness of multi-component carbide ceramics is minimized.The effects of changes in the elemental species on the lattice distortion,bond strength,bonding properties,and electronic structure of multi-component carbide ceramics were thoroughly analyzed.These results show that the hardening of multi-component carbide ceramic can be attributed to the coupling of solid solution strengthening caused by lattice distortion and covalent bond strengthening.Besides,the“host lattice”of multi-component carbide ceramics is defined based on the concept of supporting lattice.The present work is of great significance for a deeper understanding of the hardening mechanism of multi-component carbide ceramics and the design of superhard multi-component carbides.展开更多
A convenient photocatalytic multi-component reaction of alkenes,quinoxalin-2(1H)-ones,and diazo compounds has been developed in the presence of water.A number of ester-containing quinoxalin-2(1H)-ones could be efficie...A convenient photocatalytic multi-component reaction of alkenes,quinoxalin-2(1H)-ones,and diazo compounds has been developed in the presence of water.A number of ester-containing quinoxalin-2(1H)-ones could be efficiently obtained in moderate to good yields at room temperature.This metal-free visiblelight-driven tandem reaction was conducted through proton-coupled electron transfer(PCET)process using water as the hydrogen donor and 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene(4CzIPN)as the photocatalyst.展开更多
The construction of a borehole correction library for the multi-component array induction tool in deviated boreholes involves extensive 3D forward modeling and typically requires significant computational resources.To...The construction of a borehole correction library for the multi-component array induction tool in deviated boreholes involves extensive 3D forward modeling and typically requires significant computational resources.To address this challenge,this paper proposes an efficient algorithm for the library construction based on the 3D finite volume method(FVM)and contraction high-order Born approximation(CHBA).First,the electromagnetic(EM)field solution region is divided into two symmetric subregions based on the symmetry of the correction library model and the EM field.Numerical solution on a single subregion,combined with the symmetry boundary extension technique,enhances the efficiency of the 3D numerical simulation.Second,three reference mud conductivities are selected based on the mud conductivity range,and the CHBA is applied to calculate the EM responses at all mud conductivity nodes rapidly.Third,the number of forward simulation operations is further reduced by exploiting the principle that models with different frequencies and different formation conductivities have equivalent EM responses.Numerical experiments demonstrate the correctness and feasibility of the proposed algorithm.Compared to conventional 3D modeling,the proposed algorithm achieves approximately a 20-fold speedup in library construction,effectively reducing computational resources and time consumption.展开更多
Three-quasiparticle K-isomeric states in odd-mass N=106 isotones within the A~180 mass region were systematically investigated using configuration-constrained potential energy surface calculations.The calculations suc...Three-quasiparticle K-isomeric states in odd-mass N=106 isotones within the A~180 mass region were systematically investigated using configuration-constrained potential energy surface calculations.The calculations succes sfully reproduced the excitation energies and deformations of the known high-K isomers in nuclei from 175Tm to 181Re.For the nuclei closer to the Z=82 shell closure(^(183)Ir,^(185)Au,and^(187)Tl),predictions of the configurations of the observed and yet-to-be-observed isomers are provided.The results reveal strong shape polarization,where the three-quasiparticle states are driven to larger deformations compared to the often shape-soft or spherical ground states.A particularly rich spectrum of shape coexistence is predicted in^(187)Tl,where several high-K three-quasiparticle configurations with distinct prolate,oblate,and triaxial shapes are found to coexist at similar excitation energies.Notably,the oblate-deformed K^(π)=29/2^(+)configuration at E_(x)=1839 keV was proposed to be responsible for a long-lived isomer.This study provides a comprehensive picture of shape evolution and coexistence in high-K multi-quasiparticle states,offering valuable insights for future experimental studies.展开更多
Halogens are common in industrial thermal processes and can induce formation of toxic organic pollutants.Currently,the specific effects of coexisting halogens on toxic pollutant formation are unclear.In this study,we ...Halogens are common in industrial thermal processes and can induce formation of toxic organic pollutants.Currently,the specific effects of coexisting halogens on toxic pollutant formation are unclear.In this study,we found the boosting effects of halogens on organic pollutants formation during thermal processes.In situ electron paramagnetic resonance spectroscopy was used to distinguish the organic free radical intermediates of organic pollutants during thermal processes.The pure chlorine-containing reaction system dominantly induce the formation of highly chlorinated phenoxy radicals,whereas the pure bromine-containing reaction system induce the formation of semiquinone radicals.The results provide clear evidence for the molecular mechanisms by which halogen coexistence boosts pollutants formation.Coexisting halogens made the reactions much more complex.Bromine atom radicals(Br·)can enhance the level of active chlorine atoms radicals(Cl·),then(1)facilitating highly chlorinated organic radicals and toxic pollutants formation,(2)activating polycyclic aromatic hydrocarbons molecules for subsequent ring growth and(3)accelerating oxidation reactions.Combining the identification of organic free radical intermediates and characteristics of products,detailed mechanisms of halogens on the formations of organic pollutants during thermal-related processes were clarified,which can be helpful for their efficient control in the widespread bromines and chlorines co-existence reaction system.展开更多
A multi-component system has the long fixed maintenance time, so the opportunistic maintenance policy is adopted to put preventive replacement and corrective replacement together, so that the long fixed maintenance ti...A multi-component system has the long fixed maintenance time, so the opportunistic maintenance policy is adopted to put preventive replacement and corrective replacement together, so that the long fixed maintenance time can be shared by more than one component, and the system availability can be improved. Then, the generation characteristics of the random failure time are researched based on the replacement maintenance and the minima[ maintenance. Furthermore, by choosing the opportunistic replacement ages of each component as opti- mized variables, a simulation algorithm based on an opportunistic maintenance policy is designed to maximize the total availability. Finally, the simulation result shows the validity of the algorithm by an example.展开更多
Six surfaces were prepared with defferent surface division patterns for the experimental investigationof steam condensation heat transfer characteristics for dropwise and filmwise coexisting(DFC)condensationsurfaces u...Six surfaces were prepared with defferent surface division patterns for the experimental investigationof steam condensation heat transfer characteristics for dropwise and filmwise coexisting(DFC)condensationsurfaces under atmospheric pressure Dropwise condensation(DWC)was promoted with an ultrathin polytetrafluoroethylene(PTFE)film,which was prepared by the dynamic ion-beam mixed implantation(DIMI)method.The results showed that the condensation phenomena at the intersection between the dropwise andfilmwise condensation regios were quite different for different relative positions of the dropwise and filmwisecondensation regions.The experimental results revealed that the condensation heat transfer characteristics werehighly influenced by the surface division number and the relative area ratio of the dropwise and filmwise conden-sation regions.The impact of thesc findings on heat transfer enhancement mechanism for condensation heattransfer is discussed in detail.展开更多
This review focuses on the recent research progress in the multi-component assembly of luminescent rare earth hybrid materials, which is based on the luminescent rare earth compounds and two or more other building uni...This review focuses on the recent research progress in the multi-component assembly of luminescent rare earth hybrid materials, which is based on the luminescent rare earth compounds and two or more other building units, including the other photoactive species. It covers the multi-component luminescent rare earth hybrids which was assembled with different(a) organic-inorganic polymeric units,(b)nanoporous units,(c) nanoparticle composites or(d) other developing special units. Finally, future challenges and opportunities in this field are discussed. Herein it mainly focuses on the work of Yan's group in recent years.展开更多
With the increase of system scale, time delays have become unavoidable in nonlinear power systems, which add the complexity of system dynamics and induce chaotic oscillation and even voltage collapse events. In this p...With the increase of system scale, time delays have become unavoidable in nonlinear power systems, which add the complexity of system dynamics and induce chaotic oscillation and even voltage collapse events. In this paper, coexisting phenomenon in a fourth-order time-delayed power system is investigated for the first time with different initial conditions.With the mechanical power, generator damping factor, exciter gain, and time delay varying, the specific characteristic of the time-delayed system, including a discontinuous ＂jump＂ bifurcation behavior is analyzed by bifurcation diagrams, phase portraits, Poincar′e maps, and power spectrums. Moreover, the coexistence of two different periodic orbits and chaotic attractors with periodic orbits are observed in the power system, respectively. The production condition and existent domain of the coexistence phenomenon are helpful to avoid undesirable behavior in time-delayed power systems.展开更多
A general scheme for generating a multi-component integrable equation hierarchy is proposed. A simple 3M- dimensional loop algebra ~X is produced. By taking advantage of ~X a new isospectral problem is established and...A general scheme for generating a multi-component integrable equation hierarchy is proposed. A simple 3M- dimensional loop algebra ~X is produced. By taking advantage of ~X a new isospectral problem is established and then by making use of the Tu scheme the multi-component Dirac equation hierarchy is obtained. Finally, an expanding loop algebra ~FM of the loop algebra ~X is presented. Based on the ~FM, the multi-component integrable coupling system of the multi-component Dirac equation hierarchy is investigated. The method in this paper can be applied to other nonlinear evolution equation hierarchies.展开更多
Seismic AVO analysis now is one of the major criteria for recognizing potential hydrocarbon reservoirs. Volume scattering information that carries information of stratigraphic structure, lithology, and pore fluid is m...Seismic AVO analysis now is one of the major criteria for recognizing potential hydrocarbon reservoirs. Volume scattering information that carries information of stratigraphic structure, lithology, and pore fluid is more useful for seismic exploration. However, traditional AVO analysis is based on the Zoeppritz equation, which only contains single-interface information. Quantitative interpretation of the thin bed thickness is essential to thin bed structure interpretation, reservoir description, and lateral reservoir prediction. The reflectance spectrum equation based on the elastic wave propagation matrix in the frequency domain derived in this paper shows that both interfaces and intervals have an effect on amplitude. The equation includes information about both single interfaces and volume scattering. Since the reflectance spectrum equation is a continuous function of thin bed thickness and frequency, it is convenient to analyze the effects of a single frequency and bed thickness on the reflectance spectrum. Bed thickness is analyzable until the bed thickness is vanishingly small. These characteristics can＇t be achieved by Fourier transform. The propagation of seismic waves is complex and various wave modes exist simultaneously. The reflectance spectrum includes various propagating wave modes and multiples and is better for simulating multi-component thin bed AVO responses than the ray tracing method.展开更多
Arsenic（As）-contaminated wastewater and groundwater pose a pressing environmental issue and worldwide concern. Adsorption of As using TiO_2materials, in combination with filtration,introduces a promising technology ...Arsenic（As）-contaminated wastewater and groundwater pose a pressing environmental issue and worldwide concern. Adsorption of As using TiO_2materials, in combination with filtration,introduces a promising technology for the treatment of As-contaminated water. This review presents an overview on the recent progress of the application of TiO_2for removal of As from wastewater and groundwater. The main focus is on the following three pressing issues that limit the field applications of TiO_2for As removal： coexisting ions, simulation of breakthrough curves, and regeneration and reuse of spent TiO_2materials. We first examined how the coexisting ions in water, especially high concentrations of cations in industrial wastewater,affect the efficacy of As removal using the TiO_2materials. We then discussed As breakthrough curves and the effect of compounded ions on the breakthrough curves. We successfully simulated the breakthrough curves by PHREEQC after integrating the CD-MUSIC model. We further discussed challenges facing the regeneration and reuse of TiO_2media for practical applications. We offer our perspectives on remaining issues and future research needs.展开更多
The conventional digital core models are usually small in size and have difficulty in representing the complex structures of heterogeneous rocks;Therefore,the parameters of simulated rock physics are difficult to be r...The conventional digital core models are usually small in size and have difficulty in representing the complex structures of heterogeneous rocks;Therefore,the parameters of simulated rock physics are difficult to be referenced.In this study,we propose a feasible simulation method for obtaining multi-scale and multi-component digital cores based on three types of sandstone samples.In the proposed method,the plug and subplug samples are scanned via micro-computed tomography at different resolutions.Furthermore,the images are precisely registered using the proposed hybrid image registration method.In case of high-resolution images,the traditional segmentation method is used to segment the cores into pores and minerals.Subsequently,we established the relations between the gray values and the porosity/mineral content in case of the low-resolution images based on the registered domains and the relation curves were applied to the segmentation of the low-resolution images.The core images constitute the multi-scale and multi-component digital core models after segmentation.Further,the elastic properties of the three samples were simulated at both fine and coarse scales based on the multi-scale and multi-component digital core models,and four component models were considered.The results show that the multi-scale and multi-component digital core models can overcome the representative limits of the conventional digital core models and accurately characterize pores and minerals at different scales.The numerical results of the elastic modulus are more representative at large scales,and considerably reliable results can be obtained by appropriately considering the minerals.展开更多
We investigated the synchronization dynamics of a coupled neuronal system composed of two identical Chay model neurons. The Chay model Showed coexisting period-1 and period-2 bursting patterns as a parameter and initi...We investigated the synchronization dynamics of a coupled neuronal system composed of two identical Chay model neurons. The Chay model Showed coexisting period-1 and period-2 bursting patterns as a parameter and initial values are varied. We simulated multiple periodic and chaotic bursting patterns with non-（NS）, burst phase （BS）, spike phase （SS）, complete （CS）, and lag synchronization states. When the coexisting behavior is near period-2 bursting, the transitions of synchronization states of the coupled system follows very complex transitions that begins with transitions between BS and SS, moves to transitions between CS and SS, and to CS. Most initial values lead to the CS state of period-2 bursting while only a few lead to the CS state of period-I bursting. When the coexisting behavior is near period-1 bursting, the transitions begin with NS, move to transitions between SS and BS, to transitions between SS and CS, and then to CS. Most initial values lead to the CS state of period-1 bursting but a few lead to the CS state of period-2 bursting. The BS was identified as chaos synchronization. The patterns for NS and transitions between BS and SS are insensitive to initial values. The patterns for transitions between CS and SS and the CS state are sensitive to them. The number of spikes per burst of non-CS bursting increases with increasing coupling strength. These results not only reveal the initial value- and parameter- dependent synchronization transitions of coupled systems with coexisting behaviors, but also facilitate interpretation of various bursting patterns and synchronization transitions generated in the nervous system with weak coupling strength.展开更多
Approximately 10% of patients with gastrointestinal stromal tumors (GIST) develop other neoplasms, either synchronously or metachronously. In this report we describe coexistence of a gastrointestinal stromal tumor and...Approximately 10% of patients with gastrointestinal stromal tumors (GIST) develop other neoplasms, either synchronously or metachronously. In this report we describe coexistence of a gastrointestinal stromal tumor and a hepatic perivascular epithelioid cell tumor (PEComa) in a 51-year-old woman with no evidence of tuberous sclerosis. A subcapsular hepatic nodule (0.8 cm in diameter) was found during surgery for symptomatic gastric neoplasm (15 cm in diameter) arising from the lesser curvature. Both tumors revealed histomorphological and immunohistochemical features confirming a diagnosis of a small incidental hepatic PEComa and a high risky extramural gastric GIST, respectively. The patient remained disease-free 25 mo after surgery with no evidence of tumor recurrence or new neoplasms. To our knowledge, this is the first report of PEComa in a patient with GIST. Hepatic lesions detected synchronously or metachronously in patients with GISTs may represent histogenetically distinct lesions and should be sampled to confirm or exclude metastatic GISTs.展开更多
Systematic total Routhian surface calculations for even–even N = 104 midshell isotones with 66≤Z≤82 have been carried out based on a more realistic diffuse-surface deformed Woods–Saxon nuclear potential in (β_2, ...Systematic total Routhian surface calculations for even–even N = 104 midshell isotones with 66≤Z≤82 have been carried out based on a more realistic diffuse-surface deformed Woods–Saxon nuclear potential in (β_2, γ, β_4) deformation space, focusing on the rotation-induced shapecoexisting phenomena. As an example and basic test, the oblate property at the ground state in ^(184)Hg is well reproduced and the microscopic origin is analyzed from the single-particle structure. The present calculated results are compared with available experimental information, showing a good agreement. It is systematically found that in this isotonic chain several bands with different shapes(e.g., prolate, oblate and superdeformed prolate bands, seven non-collective band) may show a strong competition and coexisting phenomenon at a certain domain of the rotational frequency.展开更多
基金Science and Technology Foundation of Guizhou Province(No.QKHJC-ZK[2024]654)Guizhou Provincial University Key Laboratory of Advanced Functional Electronic Materials(No.QJJ[2023]021).
文摘Carbenes as one of the most important class of intermediates have been widely utilized in various organic synthetic transformations.Carbene insertion-initiated ring-opening reactions of cyclic ethers offer a valuable strategy for constructing new carbon-oxygen bonds.In comparison with traditional thermal or metal-mediated carbene transfer reactions,visible-light-promoted multi-component reaction strategy provides a mild and eco-friendly approach to access densely functionalized molecules.Recently,visible-light-induced multi-component carbene transfer reactions of diazo compounds have been rapidly developed and attracted a great deal of research interest of chemists owing to their advantages of simple operation,mild condition,high atom economy and rich structural diversity.This paper summarizes the recent research progress on the visible-light-promoted multi-component carbene transfer reactions of diazo compounds via ring-opening of cyclic ethers with various nucleophiles.The reaction patterns of different nucleophiles and their corresponding mechanism are described in this review.The future research direction and challenges in this area are also discussed.
基金sponsored by the National Natural Science Foundations of China under Grant Nos.12301315,12235007,11975131the Zhejiang Provincial Natural Science Foundation of China under Grant No.LQ20A010009。
文摘In the realm of nonlinear integrable systems,the presence of decompositions facilitates the establishment of linear superposition solutions and the derivation of novel coupled systems exhibiting nonlinear integrability.By focusing on single-component decompositions within the potential BKP hierarchy,it has been observed that specific linear superpositions of decomposition solutions remain consistent with the underlying equations.Moreover,through the implementation of multi-component decompositions within the potential BKP hierarchy,successful endeavors have been undertaken to formulate linear superposition solutions and novel coupled Kd V-type systems that resist decoupling via alterations in dependent variables.
基金financially supported by the National Natural Science Foundation of China(Nos.52271033 and 52071179)the Key program of National Natural Science Foundation of China(No.51931003)+2 种基金Natural Science Foundation of Jiangsu Province,China(No.BK20221493)Jiangsu Province Leading Edge Technology Basic Research Major Project(No.BK20222014)Foundation of“Qinglan Project”for Colleges and Universities in Jiangsu Province.
文摘Multi-component transition group metal borides(MMB_(2))have become a research hotspot due to their new composition design concepts and superior properties compared with conventional ceramics.Most of the current methods,however,are complicated and time-consuming,the mass production remains a chal-lenge.Herein,we proposed a new high-efficiency strategy for synthesis of MMB_(2)using molten aluminum as the medium for the first time.The prepared Al-containing multi-component borides(TiZrHfNbTa)B_(2)microcrystals had a homogeneous composition with a hexagonal AlB_(2)structure and ultra-high hardness value of∼35.3 GPa,which was much higher than data reported in the literature and the rule of mix-ture estimations.Furthermore,combined with the First-principles calculation results,we found that the Poisson’s ratio(v)values exhibit a clearly ascending trend from 0.17 at VEC=3.5 to 0.18 at VEC=3.4,then to 0.201 at VEC=3.2 with the increasing of Al content.This indicates that the intrinsic toughness of multi-component boride microcrystals is obviously enhanced by the trace-doped Al elements.Besides,the fabricated Al-containing multi-component boride microcrystals have superior oxidation activation en-ergy and structural stability.The enhanced oxidation resistance is mainly attributed to the formation of a protective Al2 O3 oxide layer and the lattice distortion,both of which lead to sluggish diffusion of O_(2).These findings propose a new unexplored avenue for the fabrication of MMB_(2)materials with supe-rior comprehensive performance including ultra-hardness and intrinsically improved thermo-mechanical properties.
基金Supported by Key Disciplines of The Sixth Cycle of Tongji Hospital,No.ZDTS24-BLShanghai Municipal Science and Technology Commission 2021"Science and Technology Innovation Action Plan"Medical Innovation Research Project,No.21Y11908800Clinical Research Project of Tongji Hospital of Tongji University,No.ITJ(ZD)2206.
文摘BACKGROUND Indolent T-cell lymphoma of the gastrointestinal tract(iTCL-GI)is a rare mature T-cell lymphoma that has been formally recognized as a distinct entity in the 5th Edition World Health Organization Classification of Tumours of Haematolymphoid Tumours.However,the coexistence of iTCL-GI with epithelial malignancies is rare in clinical practice.This study reports a case of iTCL-GI with gastric signet-ring cell carcinoma(SRCC).We aim to increase diagnostic awareness among clinicians and pathologists regarding multiple primary tumors.CASE SUMMARY A 65-year-old female presented with a 5-month history of lower abdominal pain,bloating,and vomiting.An abdominal computed tomography scan revealed irregular thickening of the gastric wall.Endoscopy revealed diffuse mucosal edema and rigid mucosa along the lesser curvature of the gastric body.There was a 1.5 cm mucosal protrusion on the greater curvature.Biopsy revealed that the lamina propria was expanded by a dense,nondestructive infiltrate of small lymphocytes in the greater curvature,which were characterized by a CD3+/CD8+/TIA-1+immunophenotype with a low Ki-67 index.Clonal T-cell receptor rearrangement was detected,but the Epstein-Barr virus encoded RNA's was negative.Lesions on the lesser curvature of the gastric body were confirmed to be SRCCs.After three months of follow-up,the patient completed four cycles of chemotherapy targeting the SRCC.While her abdominal pain improved,she experienced a weight loss of 5 kg.CONCLUSION Clinicians and pathologists must integrate assessment of these rare cases to prevent misdiagnosis and guide clinical practice.
基金financially supported by the National Natural Science Foundation of China(Nos.52032002,52372060,51972081,and U22A20128)the National Safety Academic Foundation(No.U2130103)+1 种基金the National Key Laboratory of Precision Hot Processing of Metals(No.61429092300305)Heilongjiang Touyan Team Program are gratefully acknowledged.
文摘The hardening mechanism of multi-component carbide ceramic has been investigated in detail through a combination of experiments,first-principles calculations,and ab initio molecular dynamics(AIMD).Eight dense carbide ceramics were prepared by spark plasma sintering.Compulsorily,all the multi-component carbide samples have similar carbon content,grain size,and uniform compositional distribution by optimizing the sintering process and adjusting the initial raw materials.Hence the interference of other factors on the hardness of multi-component carbide ceramics is minimized.The effects of changes in the elemental species on the lattice distortion,bond strength,bonding properties,and electronic structure of multi-component carbide ceramics were thoroughly analyzed.These results show that the hardening of multi-component carbide ceramic can be attributed to the coupling of solid solution strengthening caused by lattice distortion and covalent bond strengthening.Besides,the“host lattice”of multi-component carbide ceramics is defined based on the concept of supporting lattice.The present work is of great significance for a deeper understanding of the hardening mechanism of multi-component carbide ceramics and the design of superhard multi-component carbides.
基金supported by Sichuan Science and Technology Program(No.2023NSFSC0101)the 2024 Provincial platform project of Chengdu Normal University(No.GNFZ202404)+1 种基金Natural Science Foundation of Shandong Province(No.ZR2021MB065)National Natural Science Foundation of China(No.22101237)。
文摘A convenient photocatalytic multi-component reaction of alkenes,quinoxalin-2(1H)-ones,and diazo compounds has been developed in the presence of water.A number of ester-containing quinoxalin-2(1H)-ones could be efficiently obtained in moderate to good yields at room temperature.This metal-free visiblelight-driven tandem reaction was conducted through proton-coupled electron transfer(PCET)process using water as the hydrogen donor and 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene(4CzIPN)as the photocatalyst.
基金funded by the Forward-looking Basic Science and Technology Research Project of PetroChina Company Limited(2025DJ104)the National Natural Science Foundation of China(42174150)the National Science and Technology Major Project for Deep Earth Probe and Mineral Resources Exploration(2024ZD1003005).
文摘The construction of a borehole correction library for the multi-component array induction tool in deviated boreholes involves extensive 3D forward modeling and typically requires significant computational resources.To address this challenge,this paper proposes an efficient algorithm for the library construction based on the 3D finite volume method(FVM)and contraction high-order Born approximation(CHBA).First,the electromagnetic(EM)field solution region is divided into two symmetric subregions based on the symmetry of the correction library model and the EM field.Numerical solution on a single subregion,combined with the symmetry boundary extension technique,enhances the efficiency of the 3D numerical simulation.Second,three reference mud conductivities are selected based on the mud conductivity range,and the CHBA is applied to calculate the EM responses at all mud conductivity nodes rapidly.Third,the number of forward simulation operations is further reduced by exploiting the principle that models with different frequencies and different formation conductivities have equivalent EM responses.Numerical experiments demonstrate the correctness and feasibility of the proposed algorithm.Compared to conventional 3D modeling,the proposed algorithm achieves approximately a 20-fold speedup in library construction,effectively reducing computational resources and time consumption.
基金supported by the National Natural Science Foundation of China(No.12275369)。
文摘Three-quasiparticle K-isomeric states in odd-mass N=106 isotones within the A~180 mass region were systematically investigated using configuration-constrained potential energy surface calculations.The calculations succes sfully reproduced the excitation energies and deformations of the known high-K isomers in nuclei from 175Tm to 181Re.For the nuclei closer to the Z=82 shell closure(^(183)Ir,^(185)Au,and^(187)Tl),predictions of the configurations of the observed and yet-to-be-observed isomers are provided.The results reveal strong shape polarization,where the three-quasiparticle states are driven to larger deformations compared to the often shape-soft or spherical ground states.A particularly rich spectrum of shape coexistence is predicted in^(187)Tl,where several high-K three-quasiparticle configurations with distinct prolate,oblate,and triaxial shapes are found to coexist at similar excitation energies.Notably,the oblate-deformed K^(π)=29/2^(+)configuration at E_(x)=1839 keV was proposed to be responsible for a long-lived isomer.This study provides a comprehensive picture of shape evolution and coexistence in high-K multi-quasiparticle states,offering valuable insights for future experimental studies.
基金supported by the National Key Research and Development Program of China(No.2023YFC3707004)the National Natural Science Foundation of China(Nos.22376204,22076201 and 92143201)+1 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences(Nos.XDB0750400,XDB0750100 and XDB0750000)the Second Tibetan Plateau Scientific Expedition and Research Program(STEP)(No.2019 QZKK0605).
文摘Halogens are common in industrial thermal processes and can induce formation of toxic organic pollutants.Currently,the specific effects of coexisting halogens on toxic pollutant formation are unclear.In this study,we found the boosting effects of halogens on organic pollutants formation during thermal processes.In situ electron paramagnetic resonance spectroscopy was used to distinguish the organic free radical intermediates of organic pollutants during thermal processes.The pure chlorine-containing reaction system dominantly induce the formation of highly chlorinated phenoxy radicals,whereas the pure bromine-containing reaction system induce the formation of semiquinone radicals.The results provide clear evidence for the molecular mechanisms by which halogen coexistence boosts pollutants formation.Coexisting halogens made the reactions much more complex.Bromine atom radicals(Br·)can enhance the level of active chlorine atoms radicals(Cl·),then(1)facilitating highly chlorinated organic radicals and toxic pollutants formation,(2)activating polycyclic aromatic hydrocarbons molecules for subsequent ring growth and(3)accelerating oxidation reactions.Combining the identification of organic free radical intermediates and characteristics of products,detailed mechanisms of halogens on the formations of organic pollutants during thermal-related processes were clarified,which can be helpful for their efficient control in the widespread bromines and chlorines co-existence reaction system.
文摘A multi-component system has the long fixed maintenance time, so the opportunistic maintenance policy is adopted to put preventive replacement and corrective replacement together, so that the long fixed maintenance time can be shared by more than one component, and the system availability can be improved. Then, the generation characteristics of the random failure time are researched based on the replacement maintenance and the minima[ maintenance. Furthermore, by choosing the opportunistic replacement ages of each component as opti- mized variables, a simulation algorithm based on an opportunistic maintenance policy is designed to maximize the total availability. Finally, the simulation result shows the validity of the algorithm by an example.
文摘Six surfaces were prepared with defferent surface division patterns for the experimental investigationof steam condensation heat transfer characteristics for dropwise and filmwise coexisting(DFC)condensationsurfaces under atmospheric pressure Dropwise condensation(DWC)was promoted with an ultrathin polytetrafluoroethylene(PTFE)film,which was prepared by the dynamic ion-beam mixed implantation(DIMI)method.The results showed that the condensation phenomena at the intersection between the dropwise andfilmwise condensation regios were quite different for different relative positions of the dropwise and filmwisecondensation regions.The experimental results revealed that the condensation heat transfer characteristics werehighly influenced by the surface division number and the relative area ratio of the dropwise and filmwise conden-sation regions.The impact of thesc findings on heat transfer enhancement mechanism for condensation heattransfer is discussed in detail.
基金Project supported by the National Natural Science Foundation of China(21571142)the Developing Science Fund of Tongji University,the Natural Science Foundation of Zhejiang Province(LQ14B010001)the Natural Science Foundation of Ningbo,China(2016A610105)
文摘This review focuses on the recent research progress in the multi-component assembly of luminescent rare earth hybrid materials, which is based on the luminescent rare earth compounds and two or more other building units, including the other photoactive species. It covers the multi-component luminescent rare earth hybrids which was assembled with different(a) organic-inorganic polymeric units,(b)nanoporous units,(c) nanoparticle composites or(d) other developing special units. Finally, future challenges and opportunities in this field are discussed. Herein it mainly focuses on the work of Yan's group in recent years.
基金supported by the National Natural Science Foundation of China(Grant Nos.51475246 and 51075215)the Natural Science Foundation of Jiangsu Province of China(Grant No.Bk20131402)the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry of China(Grand No.[2012]1707)
文摘With the increase of system scale, time delays have become unavoidable in nonlinear power systems, which add the complexity of system dynamics and induce chaotic oscillation and even voltage collapse events. In this paper, coexisting phenomenon in a fourth-order time-delayed power system is investigated for the first time with different initial conditions.With the mechanical power, generator damping factor, exciter gain, and time delay varying, the specific characteristic of the time-delayed system, including a discontinuous ＂jump＂ bifurcation behavior is analyzed by bifurcation diagrams, phase portraits, Poincar′e maps, and power spectrums. Moreover, the coexistence of two different periodic orbits and chaotic attractors with periodic orbits are observed in the power system, respectively. The production condition and existent domain of the coexistence phenomenon are helpful to avoid undesirable behavior in time-delayed power systems.
文摘A general scheme for generating a multi-component integrable equation hierarchy is proposed. A simple 3M- dimensional loop algebra ~X is produced. By taking advantage of ~X a new isospectral problem is established and then by making use of the Tu scheme the multi-component Dirac equation hierarchy is obtained. Finally, an expanding loop algebra ~FM of the loop algebra ~X is presented. Based on the ~FM, the multi-component integrable coupling system of the multi-component Dirac equation hierarchy is investigated. The method in this paper can be applied to other nonlinear evolution equation hierarchies.
基金The research was supported by the Notion's Fifteenth Scientific and Technological Breakthrough Project: Research of Vector and Mountain Seismic Exploration (No.2001BA605A-12).
文摘Seismic AVO analysis now is one of the major criteria for recognizing potential hydrocarbon reservoirs. Volume scattering information that carries information of stratigraphic structure, lithology, and pore fluid is more useful for seismic exploration. However, traditional AVO analysis is based on the Zoeppritz equation, which only contains single-interface information. Quantitative interpretation of the thin bed thickness is essential to thin bed structure interpretation, reservoir description, and lateral reservoir prediction. The reflectance spectrum equation based on the elastic wave propagation matrix in the frequency domain derived in this paper shows that both interfaces and intervals have an effect on amplitude. The equation includes information about both single interfaces and volume scattering. Since the reflectance spectrum equation is a continuous function of thin bed thickness and frequency, it is convenient to analyze the effects of a single frequency and bed thickness on the reflectance spectrum. Bed thickness is analyzable until the bed thickness is vanishingly small. These characteristics can＇t be achieved by Fourier transform. The propagation of seismic waves is complex and various wave modes exist simultaneously. The reflectance spectrum includes various propagating wave modes and multiples and is better for simulating multi-component thin bed AVO responses than the ray tracing method.
基金supported by the National Basic Research Program (973) of China (No. 2015CB932003)the Strategic Priority Research Program of the Chinese Academy of Sciences (No. XDB14020201)the National Natural Science Foundation of China (Nos. 41373123, 41425016, and 21321004)
文摘Arsenic（As）-contaminated wastewater and groundwater pose a pressing environmental issue and worldwide concern. Adsorption of As using TiO_2materials, in combination with filtration,introduces a promising technology for the treatment of As-contaminated water. This review presents an overview on the recent progress of the application of TiO_2for removal of As from wastewater and groundwater. The main focus is on the following three pressing issues that limit the field applications of TiO_2for As removal： coexisting ions, simulation of breakthrough curves, and regeneration and reuse of spent TiO_2materials. We first examined how the coexisting ions in water, especially high concentrations of cations in industrial wastewater,affect the efficacy of As removal using the TiO_2materials. We then discussed As breakthrough curves and the effect of compounded ions on the breakthrough curves. We successfully simulated the breakthrough curves by PHREEQC after integrating the CD-MUSIC model. We further discussed challenges facing the regeneration and reuse of TiO_2media for practical applications. We offer our perspectives on remaining issues and future research needs.
基金supported by the National Natural Science Foundation of China Research(Nos.41574122 and 41374124)National Science and Technology major Project(No.2016ZX05006002-004)。
文摘The conventional digital core models are usually small in size and have difficulty in representing the complex structures of heterogeneous rocks;Therefore,the parameters of simulated rock physics are difficult to be referenced.In this study,we propose a feasible simulation method for obtaining multi-scale and multi-component digital cores based on three types of sandstone samples.In the proposed method,the plug and subplug samples are scanned via micro-computed tomography at different resolutions.Furthermore,the images are precisely registered using the proposed hybrid image registration method.In case of high-resolution images,the traditional segmentation method is used to segment the cores into pores and minerals.Subsequently,we established the relations between the gray values and the porosity/mineral content in case of the low-resolution images based on the registered domains and the relation curves were applied to the segmentation of the low-resolution images.The core images constitute the multi-scale and multi-component digital core models after segmentation.Further,the elastic properties of the three samples were simulated at both fine and coarse scales based on the multi-scale and multi-component digital core models,and four component models were considered.The results show that the multi-scale and multi-component digital core models can overcome the representative limits of the conventional digital core models and accurately characterize pores and minerals at different scales.The numerical results of the elastic modulus are more representative at large scales,and considerably reliable results can be obtained by appropriately considering the minerals.
基金supported by the National Natural Science Foundation of China(Grant Nos.11372224 and 11402039)the Fundamental Research Funds for Central Universities designated to Tongji University(Grant No.1330219127)
文摘We investigated the synchronization dynamics of a coupled neuronal system composed of two identical Chay model neurons. The Chay model Showed coexisting period-1 and period-2 bursting patterns as a parameter and initial values are varied. We simulated multiple periodic and chaotic bursting patterns with non-（NS）, burst phase （BS）, spike phase （SS）, complete （CS）, and lag synchronization states. When the coexisting behavior is near period-2 bursting, the transitions of synchronization states of the coupled system follows very complex transitions that begins with transitions between BS and SS, moves to transitions between CS and SS, and to CS. Most initial values lead to the CS state of period-2 bursting while only a few lead to the CS state of period-I bursting. When the coexisting behavior is near period-1 bursting, the transitions begin with NS, move to transitions between SS and BS, to transitions between SS and CS, and then to CS. Most initial values lead to the CS state of period-1 bursting but a few lead to the CS state of period-2 bursting. The BS was identified as chaos synchronization. The patterns for NS and transitions between BS and SS are insensitive to initial values. The patterns for transitions between CS and SS and the CS state are sensitive to them. The number of spikes per burst of non-CS bursting increases with increasing coupling strength. These results not only reveal the initial value- and parameter- dependent synchronization transitions of coupled systems with coexisting behaviors, but also facilitate interpretation of various bursting patterns and synchronization transitions generated in the nervous system with weak coupling strength.
基金Fundao para o Desenvolvimento da UNESP-FUNDUNESP, So Paulo, Brazil
文摘Approximately 10% of patients with gastrointestinal stromal tumors (GIST) develop other neoplasms, either synchronously or metachronously. In this report we describe coexistence of a gastrointestinal stromal tumor and a hepatic perivascular epithelioid cell tumor (PEComa) in a 51-year-old woman with no evidence of tuberous sclerosis. A subcapsular hepatic nodule (0.8 cm in diameter) was found during surgery for symptomatic gastric neoplasm (15 cm in diameter) arising from the lesser curvature. Both tumors revealed histomorphological and immunohistochemical features confirming a diagnosis of a small incidental hepatic PEComa and a high risky extramural gastric GIST, respectively. The patient remained disease-free 25 mo after surgery with no evidence of tumor recurrence or new neoplasms. To our knowledge, this is the first report of PEComa in a patient with GIST. Hepatic lesions detected synchronously or metachronously in patients with GISTs may represent histogenetically distinct lesions and should be sampled to confirm or exclude metastatic GISTs.
基金supported by the Natural Science Foundation of China(Nos.11675148 and 11505157)the Project of Youth Backbone Teachers of Colleges and Universities of Henan Province(No.2017GGJS008)+2 种基金the Foundation and Advanced Technology Research Program of Henan Province(No.162300410222)the Outstanding Young Talent Research Fund of Zhengzhou University(No.1521317002)the Physics Research and Development Program of Zhengzhou University(No.32410017)
文摘Systematic total Routhian surface calculations for even–even N = 104 midshell isotones with 66≤Z≤82 have been carried out based on a more realistic diffuse-surface deformed Woods–Saxon nuclear potential in (β_2, γ, β_4) deformation space, focusing on the rotation-induced shapecoexisting phenomena. As an example and basic test, the oblate property at the ground state in ^(184)Hg is well reproduced and the microscopic origin is analyzed from the single-particle structure. The present calculated results are compared with available experimental information, showing a good agreement. It is systematically found that in this isotonic chain several bands with different shapes(e.g., prolate, oblate and superdeformed prolate bands, seven non-collective band) may show a strong competition and coexisting phenomenon at a certain domain of the rotational frequency.
