Stable porphyrinoid-based radicals and diradicaloids that possess delocalizedπ-systems can be highly advantageous for use in spintronic and electronic applications.In this work,we present the facile synthesis of a ne...Stable porphyrinoid-based radicals and diradicaloids that possess delocalizedπ-systems can be highly advantageous for use in spintronic and electronic applications.In this work,we present the facile synthesis of a neutral 17π-electron nickel corrole monoradical with a SOMO-HOMO degenerate electronic configuration.展开更多
基金supported by the National Natural Science Foundation of China(Grants.22271140,22071103,22001119 and 21911540069)the Program A for Outstanding PhD Candidate of Nanjing University(Grant.202201A006).
文摘Stable porphyrinoid-based radicals and diradicaloids that possess delocalizedπ-systems can be highly advantageous for use in spintronic and electronic applications.In this work,we present the facile synthesis of a neutral 17π-electron nickel corrole monoradical with a SOMO-HOMO degenerate electronic configuration.