The development of a library of basic building units with distinct compositional and structural characteristics for the preparation of polyoxometalates remains a challenging and attractive endeavor.Herein,the first mo...The development of a library of basic building units with distinct compositional and structural characteristics for the preparation of polyoxometalates remains a challenging and attractive endeavor.Herein,the first molybdovanadate cluster(1)modified by bisphosphonate(BP)ligands in a new[Mo^(V)V^(IV)O_(4)]building unit is successfully synthesized based on one V substituting for one Mo in the classical[Mo_(2)^(V)O_(4)]building unit.展开更多
基金supported by the National Natural Science Foundation of China(22171122)the Liaoning Revitalization Talents Program(XLYC2007130)Talent Scientific Research Fund of Liaoning Petrochemical University(2016XJJL-019).
文摘The development of a library of basic building units with distinct compositional and structural characteristics for the preparation of polyoxometalates remains a challenging and attractive endeavor.Herein,the first molybdovanadate cluster(1)modified by bisphosphonate(BP)ligands in a new[Mo^(V)V^(IV)O_(4)]building unit is successfully synthesized based on one V substituting for one Mo in the classical[Mo_(2)^(V)O_(4)]building unit.
