To investigate the influence of coarse aggregate parent rock properties on the elastic modulus of concrete,the mineralogical properties and stress-strain curves of granite and dolomite parent rocks,as well as the stre...To investigate the influence of coarse aggregate parent rock properties on the elastic modulus of concrete,the mineralogical properties and stress-strain curves of granite and dolomite parent rocks,as well as the strength and elastic modulus of mortar and concrete prepared with mechanism aggregates of the corresponding lithology,and the stress-strain curves of concrete were investigated.In this paper,a coarse aggregate and mortar matrix bonding assumption is proposed,and a prediction model for the elastic modulus of mortar is established by considering the lithology of the mechanism sand and the slurry components.An equivalent coarse aggregate elastic modulus model was established by considering factors such as coarse aggregate particle size,volume fraction,and mortar thickness between coarse aggregates.Based on the elastic modulus of the equivalent coarse aggregate and the remaining mortar,a prediction model for the elastic modulus of the two and three components of concrete in series and then in parallel was established,and the predicted values differed from the measured values within 10%.It is proposed that the coarse aggregate elastic modulus in highstrength concrete is the most critical factor affecting the elastic modulus of concrete,and as the coarse aggregate elastic modulus increases by 27.7%,the concrete elastic modulus increases by 19.5%.展开更多
Hard tissue repair materials that balance high strength with low modulus are highly promising,representing a transformative focus in applied biomaterials research.In this study,Ti-Nb alloys with high performance are p...Hard tissue repair materials that balance high strength with low modulus are highly promising,representing a transformative focus in applied biomaterials research.In this study,Ti-Nb alloys with high performance are prepared by a low-cost process for orthopedic applications.Phase composition,modulus,compressive strength and recovery properties are effectively manipulated by tailoring trace amounts of interstitial oxygen.With increasing oxygen concentration in sintered Ti-Nb alloys,theβ(body centered cubic)phase was stabilized due to the lattice distortion.The elastic modulus declined from 91 to 24 GPa.The compressive strength slightly decreased from 1595 to 1404 MPa and yield strength increased from 760 to 904 MPa.Additionally,the recovery properties were enhanced by the interstitial oxygen as a shape memory alloy.The utilization of trace oxygen serves to modulate the thermoelastic martensitic transformation in Ti-Nb alloys,thereby obtaining appropriate mechanical properties.A notable reduction in modulus is achieved while maintaining high strength,which facilitates the development of orthopedic implants capable of withstanding more complex forces.展开更多
Alkali-free SiO_(2)-Al_(2)O_(3)-CaO-MgO with different SiO_(2)/Al_(2)O_(3)mass ratios was prepared by conventional melt quenching method.The glass network structure,thermodynamic properties and elastic modulus changes...Alkali-free SiO_(2)-Al_(2)O_(3)-CaO-MgO with different SiO_(2)/Al_(2)O_(3)mass ratios was prepared by conventional melt quenching method.The glass network structure,thermodynamic properties and elastic modulus changes with SiO_(2)and Al_(2)O_(3)ratios were investigated using various techniques.It is found that when SiO_(2)is replaced by Al_(2)O_(3),the Q^(4) to Q^(3) transition of silicon-oxygen network decreases while the aluminum-oxygen network increases,which result in the transformation of Si-O-Si bonds to Si-O-Al bonds and an increase in glass network connectivity even though the intermolecular bond strength decreases.The glass transition temperature(T_(g))increases continuously,while the thermal expansion coefficient increases and high-temperature viscosity first decreases and then increases.Meanwhile,the elastic modulus values increase from 93 to 102 GPa.This indicates that the elastic modulus is mainly affected by packing factor and dissociation energy,and elements with higher packing factors and dissociation energies supplant those with lower values,resulting in increased rigidity within the glass.展开更多
Conductive hydrogel-based stretchable electronics have been extensively investigated,among which strain sensors are the most prominently studied.While the mechanical properties significantly affect the performance of ...Conductive hydrogel-based stretchable electronics have been extensively investigated,among which strain sensors are the most prominently studied.While the mechanical properties significantly affect the performance of these devices,the systematic correlation between specific mechanical parameters and sensing performance remains rarely explored.This work compares the influences of Young’s modulus and mechanical hysteresis on the sensing performance between highly entangled PAM-Li and double-network PAM-Li-Agar-3 strain sensors.Owing to the brittle agar network,which imparts a higher Young’s modulus and pronounced mechanical hysteresis to the double-network PAMLi-Agar-3 hydrogel,the corresponding sensor requires a greater driving force for deformation and yields signals with poor reproducibility.In comparison,the PAM-Li hydrogel,characterized by highly entangled polymer chains,exhibits a lower Young’s modulus and negligible mechanical hysteresis.Consequently,signals from the PAM-Li strain sensor demonstrate enhanced sensitivity and stability.Therefore,this work demonstrates that a low Young’s modulus and minimal mechanical hysteresis are critical factors for achieving superior sensing performance in strain sensors,as systematically validated through comparative analyses across diverse application scenarios.展开更多
s:A divide- by- 12 8/ 12 9or6 4/ 6 5 dual- modulus prescaler based on new optimized structure and dynam ic circuit technique im plem ented in 0 .2 5 μm CMOS digital technology is described.New optimized structure re...s:A divide- by- 12 8/ 12 9or6 4/ 6 5 dual- modulus prescaler based on new optimized structure and dynam ic circuit technique im plem ented in 0 .2 5 μm CMOS digital technology is described.New optimized structure reduces the propagation delay and has higher operating speed.Based on this structure,an im proved D- flip- flop(DFF) using dynam ic circuit technique is proposed.A prototype is fabricated and the measured results show that this prescaler works well in gigahertz frequency range and consumes only35 m W(including three power- hungry output buffers) when the input frequency is2 .5 GHz and the power supply voltage is2 .5 V.Due to its excellent perform ance,the prescaler could be applied to many RF system s.展开更多
杂种优势利用是提高大豆产量的有效策略之一,细胞质雄性不育(Cytoplasmic-nuclear Male Sterility,CMS)在大豆杂种优势利用中具有重要作用,为了阐明大豆CMS发生的分子机制,利用大豆CMS系W931A及其保持系W931B的单核小孢子(Uninucleate M...杂种优势利用是提高大豆产量的有效策略之一,细胞质雄性不育(Cytoplasmic-nuclear Male Sterility,CMS)在大豆杂种优势利用中具有重要作用,为了阐明大豆CMS发生的分子机制,利用大豆CMS系W931A及其保持系W931B的单核小孢子(Uninucleate Microspore,UM)和二胞花粉期(Binucleate Pollen,BP)花蕾进行代谢组学研究,并与转录组数据联合分析,挖掘大豆CMS相关基因及代谢途径。代谢组分析结果显示,在CMS系W931A的UM和BP阶段分别鉴定到147和305个差异代谢物,主要包括脂质及类脂分子化合物、苯丙烷及聚酮化合物和有机杂环化合物等。转录组和代谢组联合分析揭示,差异表达基因(Differentially Expressed Genes,DEGs)和差异代谢物主要参与黄酮类化合物生物合成、苯丙氨酸代谢和苯丙烷类生物合成。在花粉发育过程中,黄酮类及衍生物的合成被显著抑制,F3H(Glyma.01G166200)和FLS(Glyma.06G110600)基因在CMS系W931A中显著下调表达,推测其在相应代谢途径中发挥关键调控作用,导致花药中相关代谢物的差异,进而引发不育系花粉的败育。研究结果有助于构建大豆CMS分子调控网络,并推动大豆CMS分子机制的研究进程。展开更多
Micro-mechanical properties of a claystone were tested after undergoing alkaline perturbation on site(Tournemire,CD borehole)for 18 years.In a saturated context and outside the excavation disturbed zone(EDZ),the clays...Micro-mechanical properties of a claystone were tested after undergoing alkaline perturbation on site(Tournemire,CD borehole)for 18 years.In a saturated context and outside the excavation disturbed zone(EDZ),the claystone exhibits a 11.6-mm black rim at the cement/paste interface,which shows a different mechanical behaviour from the rest of the claystone.Three sets of measurements of elastic modulus were performed using:(i)nano-indentation tests with a constant indentation depth of 2 mm,(ii)microindentation tests with a constant indentation depth of 20 mm,and(iii)meso-compression tests with a constant displacement of 200 mm.The increase of the modulus of deformability in the black rim is between 15 GPa and 20 GPa according to the scale.Moreover,an overall decrease of the modulus of deformability from the smallest to the largest scale is observed in each zone.In view of the mineralogy and petrographic observations,higher values of modulus of deformability in the black rim are related to carbonate content and its distribution.Precipitation of cementitious carbonates as inclusions and very thin partings leads to hardening of the claystone.展开更多
基金Funded by State Railway Administration Research Project(No.2023JS007)National Natural Science Foundation of China(No.52438002)+1 种基金Research and Development Programs for Science and Technology of China Railways Corporation(No.J2023G003)New Cornerstone Science Foundation through the XPLORER PRIZE。
文摘To investigate the influence of coarse aggregate parent rock properties on the elastic modulus of concrete,the mineralogical properties and stress-strain curves of granite and dolomite parent rocks,as well as the strength and elastic modulus of mortar and concrete prepared with mechanism aggregates of the corresponding lithology,and the stress-strain curves of concrete were investigated.In this paper,a coarse aggregate and mortar matrix bonding assumption is proposed,and a prediction model for the elastic modulus of mortar is established by considering the lithology of the mechanism sand and the slurry components.An equivalent coarse aggregate elastic modulus model was established by considering factors such as coarse aggregate particle size,volume fraction,and mortar thickness between coarse aggregates.Based on the elastic modulus of the equivalent coarse aggregate and the remaining mortar,a prediction model for the elastic modulus of the two and three components of concrete in series and then in parallel was established,and the predicted values differed from the measured values within 10%.It is proposed that the coarse aggregate elastic modulus in highstrength concrete is the most critical factor affecting the elastic modulus of concrete,and as the coarse aggregate elastic modulus increases by 27.7%,the concrete elastic modulus increases by 19.5%.
基金Project(52501069)supported by the National Natural Science Foundation of ChinaProject(GZC20233172)supported by the Postdoctoral Fellowship Program of China Postdoctoral Science Foundation(CPSF)Project(21B0121)supported by Hunan Provincial Education Department,China。
文摘Hard tissue repair materials that balance high strength with low modulus are highly promising,representing a transformative focus in applied biomaterials research.In this study,Ti-Nb alloys with high performance are prepared by a low-cost process for orthopedic applications.Phase composition,modulus,compressive strength and recovery properties are effectively manipulated by tailoring trace amounts of interstitial oxygen.With increasing oxygen concentration in sintered Ti-Nb alloys,theβ(body centered cubic)phase was stabilized due to the lattice distortion.The elastic modulus declined from 91 to 24 GPa.The compressive strength slightly decreased from 1595 to 1404 MPa and yield strength increased from 760 to 904 MPa.Additionally,the recovery properties were enhanced by the interstitial oxygen as a shape memory alloy.The utilization of trace oxygen serves to modulate the thermoelastic martensitic transformation in Ti-Nb alloys,thereby obtaining appropriate mechanical properties.A notable reduction in modulus is achieved while maintaining high strength,which facilitates the development of orthopedic implants capable of withstanding more complex forces.
基金Supported by the National Key Research Program(No.2024-1129-954-112)National Natural Science Foundation of China(No.52372033)Guangxi Science and Technology Major Program(No.AA24263054)。
文摘Alkali-free SiO_(2)-Al_(2)O_(3)-CaO-MgO with different SiO_(2)/Al_(2)O_(3)mass ratios was prepared by conventional melt quenching method.The glass network structure,thermodynamic properties and elastic modulus changes with SiO_(2)and Al_(2)O_(3)ratios were investigated using various techniques.It is found that when SiO_(2)is replaced by Al_(2)O_(3),the Q^(4) to Q^(3) transition of silicon-oxygen network decreases while the aluminum-oxygen network increases,which result in the transformation of Si-O-Si bonds to Si-O-Al bonds and an increase in glass network connectivity even though the intermolecular bond strength decreases.The glass transition temperature(T_(g))increases continuously,while the thermal expansion coefficient increases and high-temperature viscosity first decreases and then increases.Meanwhile,the elastic modulus values increase from 93 to 102 GPa.This indicates that the elastic modulus is mainly affected by packing factor and dissociation energy,and elements with higher packing factors and dissociation energies supplant those with lower values,resulting in increased rigidity within the glass.
基金supported by the National Natural Science Foundation of China(52303145,52403083)the Natural Science Foundation of Sichuan Province(2025ZNSFSC1400)supported by the start-up funding at Chengdu University(T202207)。
文摘Conductive hydrogel-based stretchable electronics have been extensively investigated,among which strain sensors are the most prominently studied.While the mechanical properties significantly affect the performance of these devices,the systematic correlation between specific mechanical parameters and sensing performance remains rarely explored.This work compares the influences of Young’s modulus and mechanical hysteresis on the sensing performance between highly entangled PAM-Li and double-network PAM-Li-Agar-3 strain sensors.Owing to the brittle agar network,which imparts a higher Young’s modulus and pronounced mechanical hysteresis to the double-network PAMLi-Agar-3 hydrogel,the corresponding sensor requires a greater driving force for deformation and yields signals with poor reproducibility.In comparison,the PAM-Li hydrogel,characterized by highly entangled polymer chains,exhibits a lower Young’s modulus and negligible mechanical hysteresis.Consequently,signals from the PAM-Li strain sensor demonstrate enhanced sensitivity and stability.Therefore,this work demonstrates that a low Young’s modulus and minimal mechanical hysteresis are critical factors for achieving superior sensing performance in strain sensors,as systematically validated through comparative analyses across diverse application scenarios.
文摘s:A divide- by- 12 8/ 12 9or6 4/ 6 5 dual- modulus prescaler based on new optimized structure and dynam ic circuit technique im plem ented in 0 .2 5 μm CMOS digital technology is described.New optimized structure reduces the propagation delay and has higher operating speed.Based on this structure,an im proved D- flip- flop(DFF) using dynam ic circuit technique is proposed.A prototype is fabricated and the measured results show that this prescaler works well in gigahertz frequency range and consumes only35 m W(including three power- hungry output buffers) when the input frequency is2 .5 GHz and the power supply voltage is2 .5 V.Due to its excellent perform ance,the prescaler could be applied to many RF system s.
文摘Micro-mechanical properties of a claystone were tested after undergoing alkaline perturbation on site(Tournemire,CD borehole)for 18 years.In a saturated context and outside the excavation disturbed zone(EDZ),the claystone exhibits a 11.6-mm black rim at the cement/paste interface,which shows a different mechanical behaviour from the rest of the claystone.Three sets of measurements of elastic modulus were performed using:(i)nano-indentation tests with a constant indentation depth of 2 mm,(ii)microindentation tests with a constant indentation depth of 20 mm,and(iii)meso-compression tests with a constant displacement of 200 mm.The increase of the modulus of deformability in the black rim is between 15 GPa and 20 GPa according to the scale.Moreover,an overall decrease of the modulus of deformability from the smallest to the largest scale is observed in each zone.In view of the mineralogy and petrographic observations,higher values of modulus of deformability in the black rim are related to carbonate content and its distribution.Precipitation of cementitious carbonates as inclusions and very thin partings leads to hardening of the claystone.
