Carbon dots(CDs)have been attracted much attention and widely studied due to their excellent fluorescence(FL)properties,better biocompatibility and outstanding photo/chemical stability.However,the disadvantage of lowe...Carbon dots(CDs)have been attracted much attention and widely studied due to their excellent fluorescence(FL)properties,better biocompatibility and outstanding photo/chemical stability.However,the disadvantage of lower quantum yield(QY)still limits its wide application.Herein,we reported a novel and convenient strategy to prepare photo-induced Ag/CDs(p-Ag/CDs)by irradiating the mixed Ag+and hydrophobic CDs(h-CDs)acetone solution with ultraviolet(UV)light.The obtained p-Ag/CDs exhibit a greatly enhanced FL emission together with a blue shift(460 nm)than h-CDs(520 nm).The QY of p-Ag/CDs is measured to be 51.1%,which is 10.4 times higher than that of h-CDs(4.9%),indicating that photo-induced Ag modulation can effectively improve the optical properties of CDs.The mechanisms for the FL enhancement and blue shift of h-CDs are studied in detail.The results prove that the greatly enhanced FL emission is from the generated Ag nanoparticles(AgNPs)by UV light irradiation based on metal-enhanced fluorescence(MEF),and the increased oxygen-contained groups in this process lead to the blue shift in CDs fluorescence.Interestingly,the p-Ag/CDs exhibit higher sensitivity and selectivity for sulfide ions(S2-)detection than that of h-CDs,which have a lower response to S2-.This work not only offers a novel strategy to improve the FL properties of materials but also endows them with new functions and broadens their application fields.展开更多
Photovoltaic(PV)modules age with time for various reasons such as corroded joints and terminals and glass coating defects,and their ageing degrades the PV array power.With the help of the PV array numerical model,this...Photovoltaic(PV)modules age with time for various reasons such as corroded joints and terminals and glass coating defects,and their ageing degrades the PV array power.With the help of the PV array numerical model,this paper explores the effects of PV module ageing on the PV array power,and the power gains and costs of rearranging and recabling aged PV modules in a PV array.The numerical PV array model is first revised to account for module ageing,rearrangement and recabling,with the relevant equations presented herein.The updated numerical model is then used to obtain the array powers for seven different PV arrays.The power results are then analysed in view of the attributes of the seven PV array examples.A guiding method to recommend recabling after rearranging aged modules is then proposed,leading to further significant power gains,while eliminating intra-row mismatches.When certain conditions are met,it was shown that recabling PV modules after rearranging them may lead to further significant power gains,reaching 57%and 98%in two considered PV array examples.Higher gains are possible in other arrays.A cost-benefit analysis weighing annual power gains versus estimated recabling costs is also given for the seven considered PV array examples to guide recabling decisions based on technical and economic merits.In the considered examples,recabling costs can be recovered in<4 years.Compared with the powers of the aged arrays,power gains due to our proposed rearranging and recabling the PV arrays ranged between 73%and 131%in the considered examples—well over the gains reported in the literature.Moreover,the cost of our static module rearrangement and recabling method outshines the costs of dynamic reconfiguration methods recently published in the literature.展开更多
基金the National Natural Science Foundation of China(Nos.U1833202 and 21876117)the Open Research Fund of the School of Chemistry and Chemical Engineering,Henan Normal University(No.2021YB05).
文摘Carbon dots(CDs)have been attracted much attention and widely studied due to their excellent fluorescence(FL)properties,better biocompatibility and outstanding photo/chemical stability.However,the disadvantage of lower quantum yield(QY)still limits its wide application.Herein,we reported a novel and convenient strategy to prepare photo-induced Ag/CDs(p-Ag/CDs)by irradiating the mixed Ag+and hydrophobic CDs(h-CDs)acetone solution with ultraviolet(UV)light.The obtained p-Ag/CDs exhibit a greatly enhanced FL emission together with a blue shift(460 nm)than h-CDs(520 nm).The QY of p-Ag/CDs is measured to be 51.1%,which is 10.4 times higher than that of h-CDs(4.9%),indicating that photo-induced Ag modulation can effectively improve the optical properties of CDs.The mechanisms for the FL enhancement and blue shift of h-CDs are studied in detail.The results prove that the greatly enhanced FL emission is from the generated Ag nanoparticles(AgNPs)by UV light irradiation based on metal-enhanced fluorescence(MEF),and the increased oxygen-contained groups in this process lead to the blue shift in CDs fluorescence.Interestingly,the p-Ag/CDs exhibit higher sensitivity and selectivity for sulfide ions(S2-)detection than that of h-CDs,which have a lower response to S2-.This work not only offers a novel strategy to improve the FL properties of materials but also endows them with new functions and broadens their application fields.
文摘Photovoltaic(PV)modules age with time for various reasons such as corroded joints and terminals and glass coating defects,and their ageing degrades the PV array power.With the help of the PV array numerical model,this paper explores the effects of PV module ageing on the PV array power,and the power gains and costs of rearranging and recabling aged PV modules in a PV array.The numerical PV array model is first revised to account for module ageing,rearrangement and recabling,with the relevant equations presented herein.The updated numerical model is then used to obtain the array powers for seven different PV arrays.The power results are then analysed in view of the attributes of the seven PV array examples.A guiding method to recommend recabling after rearranging aged modules is then proposed,leading to further significant power gains,while eliminating intra-row mismatches.When certain conditions are met,it was shown that recabling PV modules after rearranging them may lead to further significant power gains,reaching 57%and 98%in two considered PV array examples.Higher gains are possible in other arrays.A cost-benefit analysis weighing annual power gains versus estimated recabling costs is also given for the seven considered PV array examples to guide recabling decisions based on technical and economic merits.In the considered examples,recabling costs can be recovered in<4 years.Compared with the powers of the aged arrays,power gains due to our proposed rearranging and recabling the PV arrays ranged between 73%and 131%in the considered examples—well over the gains reported in the literature.Moreover,the cost of our static module rearrangement and recabling method outshines the costs of dynamic reconfiguration methods recently published in the literature.
